KR20110076661A - Method for forming micropattern in semiconductor device - Google Patents
Method for forming micropattern in semiconductor device Download PDFInfo
- Publication number
- KR20110076661A KR20110076661A KR1020090133415A KR20090133415A KR20110076661A KR 20110076661 A KR20110076661 A KR 20110076661A KR 1020090133415 A KR1020090133415 A KR 1020090133415A KR 20090133415 A KR20090133415 A KR 20090133415A KR 20110076661 A KR20110076661 A KR 20110076661A
- Authority
- KR
- South Korea
- Prior art keywords
- forming
- pattern
- hard mask
- semiconductor device
- fine pattern
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 108
- 239000004065 semiconductor Substances 0.000 title claims abstract description 41
- 238000005530 etching Methods 0.000 claims abstract description 50
- 238000009966 trimming Methods 0.000 claims abstract description 41
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 230000002159 abnormal effect Effects 0.000 claims abstract description 19
- 239000000758 substrate Substances 0.000 claims abstract description 13
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 18
- 229920002120 photoresistant polymer Polymers 0.000 claims description 12
- 238000004140 cleaning Methods 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000009832 plasma treatment Methods 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 238000000151 deposition Methods 0.000 claims 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 229910003481 amorphous carbon Inorganic materials 0.000 description 60
- 230000002093 peripheral effect Effects 0.000 description 25
- 150000004767 nitrides Chemical class 0.000 description 12
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 8
- 229920005591 polysilicon Polymers 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- -1 tungsten nitride Chemical class 0.000 description 3
- 239000012535 impurity Substances 0.000 description 2
- 229910017855 NH 4 F Inorganic materials 0.000 description 1
- 239000006117 anti-reflective coating Substances 0.000 description 1
- 230000003667 anti-reflective effect Effects 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
Images
Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/70—Microphotolithographic exposure; Apparatus therefor
- G03F7/70425—Imaging strategies, e.g. for increasing throughput or resolution, printing product fields larger than the image field or compensating lithography- or non-lithography errors, e.g. proximity correction, mix-and-match, stitching or double patterning
- G03F7/70433—Layout for increasing efficiency or for compensating imaging errors, e.g. layout of exposure fields for reducing focus errors; Use of mask features for increasing efficiency or for compensating imaging errors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/033—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
- H01L21/0334—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/0337—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane characterised by the process involved to create the mask, e.g. lift-off masks, sidewalls, or to modify the mask, e.g. pre-treatment, post-treatment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/033—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers
- H01L21/0334—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising inorganic layers characterised by their size, orientation, disposition, behaviour, shape, in horizontal or vertical plane
- H01L21/0338—Process specially adapted to improve the resolution of the mask
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31144—Etching the insulating layers by chemical or physical means using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32139—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Drying Of Semiconductors (AREA)
- Electrodes Of Semiconductors (AREA)
Abstract
In the method of forming a fine pattern of a semiconductor device to which the trimming process is applied, the formation of the fine pattern of the semiconductor device can prevent the etched layer from being trimmed to a desired critical dimension due to abnormal polymers sticking to the sidewall of the etched layer. To provide a method, the present invention provides a step of providing a substrate on which the etched layer is formed, forming a hard mask pattern on the etched layer, both side walls of the hard mask pattern when forming the hard mask pattern A method of forming a fine pattern of a semiconductor device, the method comprising: removing an abnormal polymer adhering to and reducing a width of the hard mask pattern to a target threshold by performing a trimming etching process.
Description
BACKGROUND OF THE
In the semiconductor device manufacturing process, the reduction of line width is a key factor for improving yield. Due to this reduction in line width, masks are also increasingly smaller in size. However, due to the limitation of photo equipment, a lot of difficulties are involved in the etching process in the device of 40 nm or less. For this reason, the most popular technology in recent years is the trimming technology.
Trimming technology can reduce the critical dimension of the final etched layer pattern by the etching process by etching a side of the lower stack of the mask through a separate etching process even if the patterning is large in the mask process. That is the process method. This trimming technique was introduced to overcome the limitations of photo equipment and to improve the critical dimension.
In particular, such a trimming technique is currently usefully applied when forming a gate electrode for a transistor in a peripheral circuit region. The reason is that the gate electrode threshold of not only the cell region but also the peripheral circuit region must be reduced due to the reduction of the line width due to the high integration of the semiconductor device. Here, the cell region represents a region where a memory cell of a semiconductor device is formed, and the peripheral circuit region represents an region where a peripheral circuit including a driving circuit for driving a cell is formed.
Hereinafter, a method of forming a fine pattern of a semiconductor device to which a trimming process according to the related art is applied will be described as an example of a method of forming a gate electrode in a current peripheral circuit region.
First, an amorphous carbon (AC) film is sequentially formed on the semiconductor substrate using a nitride film as a gate oxide film, a conductive film for forming a gate electrode, and a hard mask for protecting a gate electrode, and then a SiON film thereon. And an antireflection film and a photosensitive film pattern for forming a gate electrode.
Subsequently, the antireflection film and the SiON film are etched using the photoresist pattern as an etching mask. As a result, an antireflection film pattern and a SiON film pattern are formed.
Subsequently, after removing the photoresist pattern and the anti-reflection film pattern, the amorphous carbon film is etched through the SiON film pattern. As a result, an amorphous carbon film pattern is formed.
Subsequently, a separate trimming etching process is performed to trim the amorphous carbon film pattern to a desired critical dimension.
Subsequently, after the nitride film is etched through the amorphous carbon film pattern to form the nitride film pattern, the conductive film is etched using the nitride film pattern as an etching mask. This completes the gate electrode.
However, when the method for forming a micropattern of a semiconductor device using the trimming process according to the prior art is applied, the following problem occurs. That is, as shown in FIG. 1, the amorphous carbon film pattern AC does not trim to a desired target threshold even after a separate trimming etching process is performed for trimming after forming the amorphous carbon film pattern AC. Occurs. Thus, a problem arises in that the gate electrode is not patterned to a desired target threshold.
Specifically, (a) of FIG. 1 is a scanning electron microscope (SEM) photograph showing a gate electrode of a peripheral circuit region after forming an amorphous carbon film pattern (AC), and FIG. 1 (b) is for trimming. A SEM photograph showing the gate electrode of the peripheral circuit region after the amorphous carbon film pattern AC is etched with the O 2 / HBr / Ar mixed gas separately. At this time, as in FIGS. 1A and 1B, the amorphous carbon film patterns AC have the same width W. FIG. Referring to this, it can be seen that the amorphous carbon film pattern AC is not trimmed even after the amorphous carbon film pattern AC is formed and the trimming etching process is performed.
The reason why the trimming is not performed even after the trimming etching process is performed is that the abnormal polymers (foreign materials, polymers) generated by etching the nitride film at the bottom of the amorphous carbon film pattern during the formation of the amorphous carbon film pattern may be formed in the amorphous carbon film pattern. It sticks to both sidewalls and remains because these abnormal polymers are not removed during the trimming etching process.
The present invention has been proposed to solve the above problems of the prior art, and in the method of forming a micropattern of a semiconductor device to which a trimming process is applied, the etched layer has a desired critical dimension due to abnormal polymers that adhere to sidewalls of the etched layer. It is an object of the present invention to provide a method for forming a fine pattern of a semiconductor device which can prevent the trimming.
According to an aspect of the present invention, there is provided a substrate on which an etched layer is formed, forming a hard mask pattern on the etched layer, and forming the hard mask pattern when the hard mask pattern is formed. It provides a method of forming a fine pattern of a semiconductor device comprising the step of removing the abnormal polymer adhering to both side walls of the, and reducing the width of the hard mask pattern to a target threshold dimension by performing a trimming etching process.
According to another aspect of the present invention, there is provided a method of forming an etching target layer on a substrate including a first region and a second region, and forming a hard mask pattern on the etching layer. Removing the abnormal polymer stuck to both sidewalls of the hard mask pattern when the hard mask pattern is formed, forming a photoresist pattern having a structure in which the second region is opened, and etching the photoresist pattern into an etch mask. A method of forming a fine pattern of a semiconductor device, the method comprising: reducing the width of the hard mask pattern of the second region to a target threshold by performing a trimming etching process.
According to the present invention described above, the amorphous carbon film pattern used as a sacrificial hard mask pattern when forming the fine pattern of the semiconductor device to remove the abnormal polymer generated by etching the etching layer of the bottom portion of the amorphous carbon film pattern partially formed By applying a trimming etching process for trimming the amorphous carbon film pattern after the separate cleaning process, it is possible to prevent the amorphous carbon film pattern from being trimmed to a desired target critical dimension by the abnormal polymers. Thus, the etched layer pattern can be trimmed to a desired target threshold.
DETAILED DESCRIPTION Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art may easily implement the technical idea of the present invention. In addition, in the drawings, the thicknesses of layers and regions are exaggerated for clarity, and in the case where the layers are said to be "on" another layer or substrate, they may be formed directly on another layer or substrate or Or a third layer may be interposed therebetween. Also, throughout the specification, the same reference numerals denote the same elements.
Example
2A to 2F are cross-sectional views illustrating a method of forming a fine pattern of a semiconductor device to which a trimming process according to an embodiment of the present invention is applied. As an example, a method of selectively trimming the gate electrode of the peripheral circuit region will be described.
First, as shown in FIG. 2A, a gate insulating layer (not shown) is formed on a
Subsequently, the
Next, the
Subsequently, after forming the
Subsequently, a bottom anti-reflective coating (BARC) 16 is formed on the SiON film 15, and then the
Subsequently, as shown in FIG. 2B, the antireflection film 16 (see FIG. 2A) and the SiON film 15 (see FIG. 2A) are etched using the photoresist pattern 17 (see FIG. 2A) as an etching mask. As a result, an antireflection film pattern (not shown) and a
Subsequently, a strip process is performed to remove the
When the amorphous
Subsequently, as shown in FIG. 2C, the abnormal polymers 18 (see FIG. 2B) adhered to both side walls of the amorphous
At this time, the wet cleaning process uses a chemical containing HF. For example, BOE (Buffered Oxdie Etchant)-a solution in which HF and NH 4 F are mixed at 100: 1 or 300: 1. In the plasma treatment, a gas containing fluorine (F), such as CF 4 gas, is used.
Meanwhile, the cleaning process may be performed after the subsequent photosensitive film pattern 19 (see FIG. 2D) forming process.
Subsequently, as illustrated in FIG. 2D, a
Subsequently, as shown in FIG. 2E, the amorphous
In this case, O 2 gas is used as an etching gas for trimming, and HBr or N 2 gas is used as a passivation gas.
Here, the critical dimension of the amorphous
In addition, in the trimming etching process, the substrate temperature is maintained at about −30 to 100 ° C., the pressure is 1 to 50 mTorr, the power is applied in the range of 200 to 1500 W, and the process is preferably performed for about 60 seconds.
Subsequently, as shown in FIG. 2F, a strip process is performed to remove the photoresist pattern 19 (see FIG. 2E).
Subsequently, although not shown in the figure, the nitride film pattern (not shown) is formed by etching the
Subsequently, the
In this case, the gate electrode forming hard mask and the conductive layer as the etched layer may be trimmed to a desired final target dimension in the peripheral circuit region PERI. This is because the gate electrode is patterned using the amorphous
On the other hand, Figure 3 is a SEM photograph showing the structure of the peripheral circuit region in the state of Figure 2b is completed, Figure 4 is a SEM photograph showing the structure of the peripheral circuit region in the state of Figure 2c is completed, Figure 5 FIG. 2E is a SEM photograph showing the structure of the peripheral circuit region in which the process of FIG. 2E is completed.
3 to 5, the amorphous carbon film after the amorphous carbon film pattern AC has the largest width W 1 , and the abnormal polymer removal step is performed. The width W 2 of the pattern AC is reduced than immediately after the formation of the amorphous carbon film pattern AC, and the width W 3 of the amorphous carbon film pattern AC after applying the trimming etching process is abnormal. It can be seen that the decrease than after proceeding. This indicates that the amorphous carbon film pattern (AC) width in the peripheral circuit region is trimmed to normal in the case of the embodiment of the present invention.
Although the technical spirit of the present invention has been described in detail in the preferred embodiments, it should be noted that the above-described embodiments are for the purpose of description and not of limitation. In addition, it will be understood by those skilled in the art that various embodiments are possible within the scope of the technical idea of the present invention.
Figure 1 (a) is a SEM (Scanning Electron Microscope) photograph showing the gate electrode of the peripheral circuit region after forming the amorphous carbon film pattern by applying a method for forming a micro pattern of a semiconductor device according to the prior art.
Figure 1 (b) is a gate electrode of the peripheral circuit region after etching the amorphous carbon film pattern by O 2 / HBr / Ar mixed plasma separately for trimming by applying a method of forming a fine pattern of a semiconductor device according to the prior art SEM photograph shown.
2A to 2F are cross-sectional views illustrating a method of forming a fine pattern of a semiconductor device to which a trimming process according to an embodiment of the present invention is applied.
Figure 3 is a SEM photograph showing the structure of the peripheral circuit area in the process of Figure 2b is completed.
Figure 4 is a SEM photograph showing the structure of the peripheral circuit area in the process of Figure 2c is completed.
5 is a SEM photograph showing the structure of the peripheral circuit area in the state of FIG. 2E is completed.
<Explanation of symbols for the main parts of the drawings>
CELL: Cell area PERI: Peripheral circuit area
10
12
14: amorphous carbon film 15: SiON film
16:
18: or
14A: amorphous carbon film pattern
Claims (17)
Priority Applications (1)
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KR1020090133415A KR20110076661A (en) | 2009-12-29 | 2009-12-29 | Method for forming micropattern in semiconductor device |
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KR1020090133415A KR20110076661A (en) | 2009-12-29 | 2009-12-29 | Method for forming micropattern in semiconductor device |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8906757B2 (en) | 2011-12-06 | 2014-12-09 | Samsung Electronics Co., Ltd. | Methods of forming patterns of a semiconductor device |
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2009
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8906757B2 (en) | 2011-12-06 | 2014-12-09 | Samsung Electronics Co., Ltd. | Methods of forming patterns of a semiconductor device |
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