KR20100111062A - Composition for decomposing melamine - Google Patents

Abstract

PURPOSE: It has the effect that the food or the safe drink can be offered to consumers in case of effectively resentfuling and using the harmful component to human body which, becomes among the food manufacture process over the standard value melamine in the composition. CONSTITUTION: The manufacturing process of the food or drink the composition for the melamine analysis comprises the KCL 8~10 parts by weight, the potassium carbonate 40~60 parts by weight, the magnesium chloride 1~2 parts by weight, the calcium lactate 1~2 parts by weight, the sodium citrate 3~7 parts by weight, the white sugar 15~30 parts by weight about the purified water 100 parts by weight heated with 50~60°C and purified glucose 2~5 parts by weight.

Description

Composition for decomposing melamine {Composition for decomposing melamine}

The present invention relates to a composition for decomposing melamine.

Melamine is one of the basic organic compounds, 1,3,5-triazine-2,4,6-triamine having a molecular formula of C ₃ H ₆ N ₆ (1,3,5-triazine-2,4 , 6-triamine). It is slightly soluble in normal room temperature water, but has a tendency to melt relatively well when the water temperature increases. These melamines have a trimer form of cyanamide and, like cyanamide, 66% of its mass is nitrogen and is used in the fire extinguisher as a component of the resin because it emits nitrogen when burned. Melamine has also been known to be produced in the body when ingested with a mammalian insecticide, cyromazine.

On the other hand, melamine is defined as a substance that cannot be used in food manufacturing and processing because it is toxic if a mammal ingests a certain amount or more, especially when a large amount is ingested, causing urolithiasis and bladder stones. have. In addition, long-term intake of large amounts of kidney failure will lead to death. But small amounts of melamine aren't harmful to the human body every day, experts say.

In general, the allowable daily intake is set by the government agencies for non-carcinogenic substances. The allowable daily intake refers to an intake that has no side effects even if consumed daily for life. Most animals use NOAER (No Observed Adverse Effect). Level). The permissible daily intake of melamine has also been suggested by the US FDA. The results of animal studies show a 63 mg / kg / day harmless dose that does not cause kidney stones. When applied to humans, for safety reasons, the permissible daily dose is set to approximately 1,000 times lower, depending on the toxicity information.

In 2006, melamine was used to exaggerate the amount of protein in foods with high crude protein, such as wheat gluten, which is a raw material for livestock feed to be exported to the United States, by cheating protein. As a result, an accident occurred in which the animals ingesting such feeds died due to kidney abnormalities. In 2007, measures were taken to recover the feeds nationwide.

In addition, melamine diluted with water was added by dairy farmers and milk-related dairy farmers in China in order to hide milk protein content by adding unknown substances. This is because the nitrogen content in the milk can be increased beyond what is normally achieved. Thus, in September 2008, four infants died of kidney stones in China, causing about 53,000 pediatric patients due to melamine's renal adverse effects. Melamine has also been found in dairy products and everyday milk and confectionery.

Therefore, as a result of the recent detection of a large amount of food containing melamine components exceeding the safety standards, the situation is threatening the health of consumers.

Accordingly, the inventors of the present invention are developing a method for decomposing or removing melamine due to the detection of melamine exceeding a reference content in a large amount of food and causing a worldwide melamine wave, and thus, potassium chloride, potassium carbonate, magnesium chloride, calcium lactate, The present invention was completed by confirming that the composition including sodium citrate, white sugar, refined glucose, and water has an effect of effectively degrading melamine.

Accordingly, an object of the present invention is to provide a composition for decomposing melamine comprising potassium chloride, potassium carbonate, magnesium chloride, calcium lactate, sodium citrate, white sugar, refined glucose and water.

In addition, the present invention is to provide a food or beverage prepared using the composition for degradation melamine.

In order to achieve the object of the present invention as described above, the present invention provides a composition for decomposing melamine comprising potassium chloride, potassium carbonate, magnesium chloride, calcium lactate, sodium citrate, white sugar, refined glucose and water.

In addition, the present invention provides a food prepared by adding the melamine decomposition composition in the form of an additive.

In addition, the present invention provides a beverage prepared by adding the melamine decomposition composition in the form of an additive.

Melamine decomposition composition comprising potassium chloride, potassium carbonate, magnesium chloride, calcium lactate, sodium citrate, white sugar, refined glucose, and water according to the present invention effectively decomposes and dissolves melamine, which is a harmful component contained in humans, exceeding the standard value during the food manufacturing process. As it can be removed, it can be used to make food or beverages safe for consumers.

The present invention provides a composition for decomposing melamine comprising potassium chloride, potassium carbonate, magnesium chloride, calcium lactate, sodium citrate, white sugar, refined glucose, and water. More preferably, 8 to 10 parts by weight of potassium chloride, 40 to 60 parts by weight of potassium carbonate, 1 to 2 parts by weight of magnesium chloride, 1 to 2 parts by weight of calcium lactate, and citric acid to 100 parts by weight of purified water heated to 50 to 60 ° C. It provides a melamine decomposition composition comprising 3 to 7 parts by weight of sodium, 15 to 30 parts by weight per white and 2 to 5 parts by weight of refined glucose.

In one embodiment of the present invention, based on 1 liter of purified water heated to 50 ~ 60 ℃ potassium chloride 80 ~ 100g, potassium carbonate 400 ~ 600g, magnesium chloride 10 ~ 20g, sodium citrate 30 ~ 70g, calcium lactate 10 ~ 20g, 150 per white Melamine decomposition composition was prepared by adding ˜300 g and 20-50 g of purified glucose, dissolving, and ionizing the same.

The water for producing a melamine decomposition composition according to the present invention can be purified according to a method known in the art raw water sent from the intake source to remove the protists and foreign substances present in the water. Preferably, it may be carried out through filtration, and more preferably, it may be performed using an activated carbon filtration tank or an ultra-precision filtration device. Thereafter, the composition of the present invention may be prepared by dissolving mineral substances in purified water from which foreign substances have been removed through filtration, and preferably, the purified water may be heated to be used. The reason for using the heated purified water in the preparation of the melamine decomposition composition according to the present invention is that when cold purified water is used, the mineral components may remain as precipitates without being completely dissolved, and thus the heating is carried out with the mixed mineral components. It is preferable to heat the purified water to such an extent that it is not precipitated, and more preferably to a temperature of 50 ℃ to 60 ℃.

Therefore, the melamine decomposition composition of the present invention prepared by the above method includes mineral components of potassium, sodium, magnesium and calcium that are ionized in water and exhibit alkalinity.

In particular, potassium in the mineral component used in the present invention is involved in the control of osmotic pressure and water equilibrium together with sodium, the main cation of intracellular fluid, as the main cation of intracellular fluid, and plays an essential role in maintaining the balance between acid and alkali. However, deficiency of potassium can lead to histolysis, diarrhea and vomiting, whereas excess potassium in the body can cause hypothyroidism. Therefore, the composition of the present invention preferably contains 80 to 100 g of potassium chloride with respect to 1000 ml of purified water so that there are no side effects in the body, and preferably contains 400 to 600 g of potassium carbonate.

Sodium, together with potassium, functions to regulate osmotic pressure, plays an important role in cell mass exchange, and is involved in maintaining normal muscle irritation and excitability. Therefore, lack of sodium may cause anorexia, indigestion, muscle atrophy, intestinal gas accumulation, etc., and excessive sodium may cause fatigue, nervousness, seizures, headaches and gum disease. Therefore, it is preferable that the composition of this invention contains 30-70 g of sodium citrate with respect to 1000 ml of purified water.

Calcium plays the most important role in maintaining the skeletal system in the body, and is involved in muscle contraction and relaxation, enzyme activation and regulation of immunity and hormone secretion. In the case of calcium deficiency, it causes growth, depression, insomnia and various pains, and excessive calcium causes loss of appetite, weight loss and constipation. On the other hand, since such calcium reacts violently with water, it cannot generally be used for the preparation of alkaline solutions. However, in the present invention, an appropriate amount of calcium can be added to make an alkaline solution in a short time with other mineral components. Therefore, in view of such a point, it is preferable that the composition of this invention contains 10-20 g of calcium lactates with respect to 1000 ml of purified water.

Magnesium is the most important component of cellular metabolism, plays an important role in enzyme activity and constitutes the skeleton and teeth. Lack of magnesium causes nerve hypersensitivity, convulsions, seizures and atherosclerosis, and lack of magnesium causes coma, vomiting and anorexia. In addition, magnesium reacts with water in water to form hydroxide ions as the magnesium is oxidized, and water is alkaline due to the hydroxide ions formed, and at the same time, it has a reducing power by the hydrogen molecules formed. Therefore, when such magnesium is included in the composition of the present invention in too large a quantity, the ability to make alkalinity is rapidly lowered because it is easily oxidized to magnesium oxide in water to form an oxide film on the surface of magnesium, whereas when included in too small There is a problem that the effect of alkalizing the solution is insignificant. In view of such a point, the composition of the present invention preferably contains 10 to 20 g of magnesium chloride with respect to 1000 ml of purified water.

Furthermore, glucose and white sugar serve to stabilize the solution by preventing the ionized mineral components from recombining. Therefore, it is preferable that the composition of this invention contains 150-300 g of white sugar with respect to 1000 ml of purified water, and 20-50 g of refined glucose is preferable.

Melamine decomposition composition according to the present invention has a feature that can decompose or remove the melamine component. Therefore, when a melamine component is included in the food or beverage during the manufacturing process, the side effects and diseases occurring to consumers who consume the same may be prevented.

Therefore, the melamine decomposition composition according to the present invention can be produced during the manufacturing process of food or beverage in the form of food additives to produce a food or beverage with the melamine component removed or reduced.

The composition according to the present invention may be formulated using a method known in the art as powders, granules, tablets, pills, dragees, capsules, solutions, gels, syrups, slurries, suspensions and injections.

In addition, when the composition of the present invention is added during the manufacturing process of the food, it can be added by dipping, spraying or mixing the food in the form of food additives.

The foods are fruits, vegetables, dried or cut products of fruits or vegetables, fruit juices, vegetable juices, mixed juices or beverages containing acidic beverages, cookies, candies, caramels, gums, etc. Products, fermented milk products such as tea, yogurt, dairy foods, condiments, alcoholic beverages, canned or bottled foods, noodles, livestock processed foods, fish processed foods, microbial fermented foods, soybean foods, cereals, meat processed foods, licorice Or one or more of herbs

Hereinafter, the present invention will be described in detail by way of examples. However, these examples are intended to illustrate the present invention in more detail, and the scope of the present invention is not limited to these examples.

<Examples 1 to 3>

Preparation of Melamine Decomposition Composition According to the Present Invention

To prepare a melamine decomposition composition according to the present invention in a composition ratio as shown in Table 1. First, 1000 ml of purified water was kept at 50 to 60 ° C., and then potassium chloride, potassium carbonate, magnesium chloride, sodium citrate, calcium lactate, white sugar and refined glucose were added in turn according to the following composition ratio, and gradually stirred to dissolve. After stabilization, the composition of the present invention was prepared by filtering with a membrane filter having a pore diameter of 0.2 μm to obtain a clear pale off-white liquid mixture in which impurities were removed.

Components and Contents of Melamine Decomposition Compositions According to the Present Invention ingredient Example 1 Example 2 Example 3 Purified water 1000 ml 1000 ml 1000 ml Potassium chloride 100 g 100 g 80 g Potassium carbonate 600 g 540 g 400 g Magnesium chloride 20g 15 g 20g Sodium citrate 50 g 70 g 30 g Calcium lactate 20g 10g 20g White sugar 150 g 180 g 300 g Refined Glucose 30 g 20g 50 g

Experimental Example 1

Determination of Melamine Degradation Effect of Compositions According to the Present Invention

It was investigated whether the melamine decomposition composition according to the present invention had an effect of degrading melamine (C ₃ H ₆ N ₆ ), which is a basic organic compound. To this end, commercially available melamine was dissolved in water to achieve a melamine concentration of 10 ppm per liter. After dividing the solution into 100 ml each of the five beakers, the composition according to the present invention in each beaker 0.1% (v / v), 0.5% (v / v), 1% (v / v), 2% (v / v) and 5% (v / v). At this time, the control was used was not added to the composition of the present invention. Since the melamine content of each beaker was measured using a GC-mass analyzer, the results are shown in Table 2 and FIG.

Melamine Degradation Effect Result Of the present invention added
% Concentration of composition (v / v) 0% 0.1% 0.5% One% 2% 5% Melamine content (ppm) 10 9.3 5.9 4.6 1.3 Not detected Melamine Reduction Rate - 7% 41% 54% 87% 94%

Melamine content of less than 1ppm is marked as not detected by the Food Sanitation Law.

As a result, as shown in Table 2, it was confirmed that the composition according to the present invention has the effect of degrading melamine, in particular, even at a low concentration of 1% appeared to reduce the content of melamine by 54%, 5 In the case of% no melamine content was detected. Therefore, through the above results, the composition of the present invention was found to have a very good effect of degrading melamine (see Fig. 4).

So far I looked at the center of the preferred embodiment for the present invention. Those skilled in the art will appreciate that the present invention can be implemented in a modified form without departing from the essential features of the present invention. Therefore, the disclosed embodiments should be considered in an illustrative rather than a restrictive sense. The scope of the present invention is shown in the claims rather than the foregoing description, and all differences within the scope will be construed as being included in the present invention.

1 is a graph showing the melamine degradation effect by the composition in the present invention.

Claims (4)

Melamine decomposition composition comprising potassium chloride, potassium carbonate, magnesium chloride, calcium lactate, sodium citrate, white sugar, refined glucose and water. According to claim 1, 8 to 10 parts by weight of potassium chloride, 40 to 60 parts by weight of potassium carbonate, 1 to 2 parts by weight of magnesium chloride, 1 to 2 parts by weight of calcium lactate, based on 100 parts by weight of purified water heated to 50 to 60 ° C, Melamine decomposition composition comprising sodium citrate 3-7 parts by weight, per white sugar 15-30 parts by weight and refined glucose 2-5 parts by weight. Food prepared by adding the melamine decomposition composition of claim 1 in the form of an additive. A beverage prepared by adding the melamine decomposition composition of claim 1 or 2 in the form of an additive.

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