KR20100104721A - Removal of harmful substances using ionized minerals and preparation method thereof - Google Patents
Removal of harmful substances using ionized minerals and preparation method thereof Download PDFInfo
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- KR20100104721A KR20100104721A KR1020090023331A KR20090023331A KR20100104721A KR 20100104721 A KR20100104721 A KR 20100104721A KR 1020090023331 A KR1020090023331 A KR 1020090023331A KR 20090023331 A KR20090023331 A KR 20090023331A KR 20100104721 A KR20100104721 A KR 20100104721A
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- A—HUMAN NECESSITIES
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- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
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- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3562—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
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- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
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- A23L5/20—Removal of unwanted matter, e.g. deodorisation or detoxification
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L5/00—Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
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Abstract
Description
본 발명은 이온화 미네랄을 이용한 유해물질 제거제를 함유하는 것을 특징으로 하는 농약 및 환경호르몬 분해제에 관한 것으로, 국내에서 다빈도로 사용되는 농약 및 각종 환경호르몬에 적용할 경우 탁월한 분해 효과가 있는 이온화 미네랄을 이용한 유해물질 제거제를 함유하는 것을 특징으로 하는 농약 및 환경호르몬 분해제에 관한 것이다.The present invention relates to a pesticide and an environmental hormone decomposer, characterized in that it contains a toxic substance removal agent using an ionized mineral, and when applied to pesticides and various environmental hormones used in the domestic frequency, the ionized mineral having an excellent decomposition effect It relates to a pesticide and an environmental hormone decomposer, characterized in that it contains a used toxic substance remover.
종래에는 과실, 야체, 또는 농산물 등에는 무기질인 화학비료를 전적으로 시비하여 온 한편 상균, 살충을 위한 유독성 농약을 대량 살포함으로써 식물병해의 방제기법이 크게 발달하였으나 이로 인한 토양, 하천수 및 지하수의 오염이 극에 달하여 국토의 환경이 크게 황폐되고 앞으로 더욱 황폐되어 생태계의 사슬이 단절되어 인명이 위협을 받게 되는 상태에 이르렀다. 더구나 독성 높은 농약을 매년 대량 살포함에 따라 병충, 병균의 사멸과 동시에 토양 속의 미생물까지 죽게 되어 유기비료를 시비하여도 이를 분해하여 무기물화할 미생물이 없으므로 토양에 농약이 잔류하게 되고 그 결과로서 농약이 과실, 야채, 또는 농산물 등에 잔류하는 이른바 잔류농약이 심각한 문제로 대두하게 되었다. 즉, 잔류 농약은, 잔류독성이라고 하 는 중독증세를 일으키고, 농약이 직접 몸 속에 들어와서 경구 독성, 경피 독성, 흡입독성이라고 하는 중독증세를 일으키기 때문에, 잔류 농약은 인명을 위협하게 되었다.Conventionally, fruit, vegetables, or agricultural products have been completely fertilized with mineral fertilizers, while large-scale spraying of toxic pesticides for fungi and insecticides has greatly developed the method of controlling plant diseases. At the extreme, the land environment was severely devastated and further devastated, and the chain of ecosystems was cut off, threatening lives. In addition, as a large amount of toxic pesticides are sprayed every year, as well as the killing of pests and germs, the microorganisms in the soil are killed and there are no microorganisms to decompose and mineralize organic fertilizers. So-called residual pesticides remaining in fruits, vegetables, or agricultural products have become a serious problem. In other words, residual pesticides cause toxic symptoms called residual toxicity, and pesticides directly enter the body and cause toxic symptoms such as oral toxicity, transdermal toxicity, and inhalation toxicity.
잔류 농약의 종류에는 농약 그 자체가 잔류하고 있는 경우와 농약의 성분이 화학적으로 변화하여 생성된 물질이 잔류하는 경우가 있으며, 농약의 잔류성은 농약에 따라 다른 것으로, 유기염소제 농약은 잔류성이 길고 유기인제 농약은 비교적 짧다.There are two types of pesticide residues: the pesticide itself remains, and the chemicals of the pesticides are changed chemically. The pesticide residues are different depending on the pesticides. Organophosphorus pesticides are relatively short.
일반적으로 농작물에 살포된 농약의 잔류상태는 다음의 3가지로 나눌 수 있다. 첫째, 농작물의 표면에 부착하고 있는 것과 둘째, 식물표면층에 용해되어 있는 것과, 셋째, 식물체 내에 침투되어 있는 것으로 구분된다. 첫 번째, 또는 두 번째 경우의 잔류 농약에 대해서는, 종래의 방법을 사용하여도 그 제거가 용이하였다. 즉, 물로 씻거나, 껍질을 벗겨서 먹거나, 가열하는 것에 의해서도 잔류 농약을 제거하기가 용이하였다. 그러나, 세 번째 경우의 잔류 농약에 대해서는, 기존의 방법을 사용해서는 그 제거가 용이하지 않다는 단점이 있었다.In general, the residual state of pesticides applied to crops can be divided into three categories. Firstly, they are attached to the surface of the crop, secondly, dissolved in the plant surface layer, and thirdly, infiltrated into the plant. For residual pesticides in the first or second case, removal was easy even with conventional methods. In other words, it was easy to remove residual pesticides by washing with water, peeling and heating. However, for the residual pesticide in the third case, there is a disadvantage that the removal is not easy using the existing method.
이에, 원적외선 방사 효과를 응용한 바이오 세라믹 제품이 개발되었으나, 원적외선은 대부분 고온(50℃ 내지 300℃)에서 방사되는 반면에, 인간, 농산물 등의 생명체는 대부분 실온 및 상온(20℃ 내지 30℃)에서 활동이 왕성해지므로 고온에서 방사되는 바이오 세라믹의 원적외선 효과는 기대할 수가 없었다.Thus, although a bio-ceramic product having a far-infrared radiation effect has been developed, far-infrared rays are mostly emitted at a high temperature (50 ° C to 300 ° C), while most of living organisms such as humans and agricultural products are at room temperature and room temperature (20 ° C to 30 ° C). As the activity increases, the far-infrared effect of bio-ceramic radiated at high temperatures could not be expected.
본 발명은, 전술한 문제점들과 필요성을 해결하기 위한 것으로, 국내에서 다빈도로 사용되는 농약 및 각종 환경호르몬에 적용할 경우 탁월한 분해 효과가 있는 이온화 미네랄을 이용한 유해물질 제거제를 함유하는 것을 특징으로 하는 농약 및 환경호르몬 분해제에 관한 것이다.The present invention is to solve the above problems and necessity, it characterized in that it contains a harmful substance removal agent using ionized minerals having excellent decomposition effect when applied to pesticides and various environmental hormones used in the domestic frequency It relates to pesticides and environmental hormone breakdown.
상기의 목적을 달성하기 위해 본 발명은 구연산칼륨, 염화칼륨, 염화칼슘 , 탄산나트륨, 락티톨을 포함하는 농약 및 환경호르몬 분해제를 제공한다.In order to achieve the above object, the present invention provides a pesticide and an environmental hormone decomposing agent including potassium citrate, potassium chloride, calcium chloride, sodium carbonate, lactitol.
본 발명의 조성물의 구성비는 제한되지 않는다. 본 발명의 이온화 미네랄을 이용한 유해물질 제거제의 각 구성 성분의 함량비는 상기 범위를 벗어날 경우 인체에 유해한 영향은 없다. 다만, pH의 변화와 함께 제품 성능이 저하될 우려가 있으므로 바람직하지는 않다.The composition ratio of the composition of the present invention is not limited. The content ratio of each component of the toxic substance removing agent using the ionized mineral of the present invention does not have a harmful effect on the human body outside the above range. However, it is not preferable because there is a possibility that product performance may decrease with the change of pH.
상기 정제된 물 50-60 중량부, 구연산칼륨 2-5 중량부, 염화칼륨 4-8 중량부, 염화칼슘 2-5 중량부, 탄산나트륨 15-20 중량부 및 락티톨 4-8 중량부인 것을 특징으로 하는 것이 보다 바람직하다.50-60 parts by weight of purified water, 2-5 parts by weight of potassium citrate, 4-8 parts by weight of potassium chloride, 2-5 parts by weight of calcium chloride, 15-20 parts by weight of sodium carbonate and 4-8 parts by weight of lactitol It is more preferable.
상기 중량의 물 80-95℃로 물을 가열한 후에, 상기 조성물들을 첨가하여 용해시킴으로써 물로 희석하여 사용할 수 있다. 희석시킨 후 이온화되지 않은 물질은 여과하여 제거함으로써 본 발명은 액상으로 제조될 수 있다.After heating the water to 80-95 ° C. of the weight of water, it can be used diluted with water by adding and dissolving the compositions. After dilution, the non-ionized material can be prepared by liquid phase by filtration to remove it.
본 발명은 유기인계 및 유기염소계 농약을 분해하는 것을 특징으로 하는 농약 분해제 및 환경호르몬 분해제를 제공한다.The present invention provides a pesticide decomposing agent and an environmental hormone decomposing agent, which decomposes organophosphorus and organochlorine pesticides.
바람직하게는 상기 유기인계는 다이아지온이고 유기염소계는 엔도썰판인 것 을 분해하는 것을 특징으로 하는 농약 분해제 및 환경호르몬 분해제를 제공한다.Preferably, the organophosphorus is a diazion, and the organochlorine is an pesticide decomposing agent and an environmental hormone decomposing agent, characterized in that decomposing the endoslot.
본 발명의 농약 및 환경호르몬 분해제는 pH가 11∼12 범위내인 것을 특징으로 하는 것이 더욱 바람직하다.The pesticides and environmental hormone breakers of the present invention are more preferably characterized in that the pH is in the range of 11 to 12.
본 발명에 따라 제조된 이온화 미네랄을 이용한 유해물질 제거제는 강알칼리성인 pH 11-12 정도의 강알칼리성 무독성 제제로서 물에 희석함에 따라 pH 10 정도 까지도 내려가게 된다.Hazardous substances removal agent using the ionized mineral prepared according to the present invention is a strong alkaline non-toxic agent of about pH 11-12, which is strongly alkaline, and is lowered to about pH 10 by dilution in water.
그러므로, 산성비와 공해물질 유입 등으로 인한 산성화된 환경 특히 물, 땅 등을 모든 생명체의 생명활동에 가장 적합하도록 중화하여 산성 물질을 제거하여 중화시켜주게 된다.Therefore, the acidified environment due to acid rain and pollutant inflow, especially water and land, is neutralized to be most suitable for the life activities of all living organisms, thereby removing and neutralizing acidic substances.
본 발명은 농가에서 수확전 잔류농약의 무독성화 제재로서 사용될 수도 있으며, 뿐만아니라 인체에 유해한 영향이 없으므로 야채와 과일의 전용 세척제로도 사용될 수 있다.The present invention can be used as a non-toxic agent of the pesticide residues before harvesting in farms, as well as can be used as a cleaning agent for vegetables and fruits since there is no harmful effect on the human body.
한편, 본 발명의 농약 분해제는 약 37℃에서도 90.7％의 원적외선을 방출하므로 각종 기능성 제품의 주성분으로서 사용될 수 있으며, 윈적외선은 농약제거의 효과로 미생물의 발생을 활발하게 함으로써 토양에 잔류하는 농약을 중화 조정하여 중성, 약알칼리성으로 변화시킴으로써 잔류 농약을 제거하기도 한다.On the other hand, since the pesticide decomposition agent of the present invention emits 90.7% of far infrared rays at about 37 ℃, it can be used as a main component of various functional products, Win infrared is a pesticide remaining in the soil by activating the generation of microorganisms by the effect of pesticide removal It is also neutralized and adjusted to neutral and weak alkaline to remove residual pesticides.
원적외선은 각각의 미네랄 성분에서 방사된다. 원적외선은 적외선 중 파장이 긴 것을 말한다. 적외선은 가시광선의 적색 영역보다 파장이 길어 열작용이 큰 전자파의 일종으로, 파장이 짧은 것은 근적외선이라 한다. 눈에 보이지 않고 물질에 잘 흡수되며 유기화합물 분자에 대한 공진(共振) 및 공명(共鳴) 작용이 강한 것이 특징이다.Far infrared rays are emitted from each mineral component. Far infrared rays mean long wavelengths among infrared rays. Infrared radiation is a kind of electromagnetic waves with a greater thermal effect due to longer wavelengths than the red region of visible light. Shorter wavelengths are called near infrared rays. It is invisible, absorbs well into the material, and has strong resonance and resonance effects on organic compound molecules.
본 발명에 사용되는 이온화 미네랄을 이용한 유해물질 제거제의 제조방법에 대하여 일 실시예를 들어 설명한다. 단, 실시예는 본 발명을 예시하기 위한 것이지 이들만으로 한정하는 것은 아니다.An example of a method for preparing a toxic substance remover using an ionized mineral used in the present invention will be described. However, an Example is for illustrating this invention and is not limited only to these.
(성분 조성)(Component composition)
물 2000 ccWater 2000 cc
구연산칼륨 160 g160 g potassium citrate
염화칼륨 320 gPotassium chloride 320 g
염화칼슘 160 g160 g of calcium chloride
락티톨 320 gLactitol 320 g
탄산나트륨 640 g640 g of sodium carbonate
정제된 물(pH 7.0 - 7.5) 약 2000 cc를 80-95℃로 가열한 후, 여기에 구연산칼륨, 염화칼륨, 염화칼슘 , 탄산나트륨, 락티톨을 상기 성분조성비에 맞추어 순서대로 미량씩 첨가하면서 교반하여 용해시켰다. 이 용액을 24-48시간 정도 방치하여 이온화시키고, 이온화되지 않는 물질들은 여과하여 제거함으로써 본 발명의 조성물을 액상으로 제조하였다. 제조된 용액의 pH는 약 11.45 였다.After heating about 2000 cc of purified water (pH 7.0-7.5) to 80-95 ° C., potassium citrate, potassium chloride, calcium chloride, sodium carbonate, and lactitol were added thereto in small amounts in order according to the above composition ratio, followed by stirring. I was. The solution was left to stand for 24-48 hours to ionize, and the non-ionized materials were filtered to remove the composition of the present invention in liquid form. The pH of the prepared solution was about 11.45.
[산화환원전위][Redox potential]
산화환원전위의 측정 결과, 기존의 생수는 -2, 증류수는 -27의 산화환원전위 를 보이는 반면, 상기 제조된 용액은 -304의 측정결과를 나타냈다. 이로써 본 발명의 농약 분해제가 환원력이 매우 높다는 사실을 알 수 있다.As a result of the measurement of the redox potential, the existing bottled water showed a redox potential of -2 and distilled water of -27, whereas the prepared solution showed a measurement result of -304. This shows that the pesticide decomposition agent of the present invention has a very high reducing power.
[이온화 미네랄을 이용한 유해물질 제거제를 함유하는 농약 및 환경호르몬 분해제의 농약 및 환경호르몬 제거 효과 시험][Test of Pesticide and Environmental Hormone Removal Effects of Pesticides and Environmental Hormone Degradants Containing Hazardous Substances Using Ionized Minerals]
국내에서 다빈도로 사용되며, 독성이 강한 것으로 알려진 2종의 농약(다이아돈 및 바이엘지오릭스)에 대하여 농약 분해제의 잔류 농약제거 능력을 시험하였다.Two pesticides (Diadon and Bayer Geox), which are used frequently in Korea and are known to be highly toxic, were tested for their ability to remove residual pesticides.
＜시험예 1-1＞<Test Example 1-1>
유기인계 살충제(성분: 다이아지온; 다이아돈(상품명), 성보화학제조) 2㎖, 물 1648㎖, 및 본 발명의 농약 분해제 50㎖(29400ppm)을 혼합하여 농작물에 살포한 후 HPLC 및 GC에 의해 농약 제거 효과를 측정하였다.2 ml of organophosphorus insecticide (components: Diazion; Diadon (trade name), manufactured by Sungbo Chemical Co., Ltd.), 1648 ml of water, and 50 ml (29400 ppm) of the pesticide disintegrating agent of the present invention were mixed and sprayed on the crop, followed by HPLC and GC. The pesticide removal effect was measured by
＜시험예 1-2＞<Test Example 1-2>
본 발명의 농약 분해제의 농도를 2940ppm으로 한 것을 제외하고는 시험예 1-1에서와 같이 하여 농약 제거 효과를 측정하였다.The pesticide removal effect was measured as in Test Example 1-1 except that the concentration of the pesticide decomposing agent of the present invention was 2940 ppm.
＜시험예 1-3＞<Test Example 1-3>
본 발명의 농약 분해제의 농도를 294ppm으로 한 것을 제외하고는 시험예 1-1에서와 같이 하여 농약 제거 효과를 측정하였다.The pesticide removal effect was measured as in Test Example 1-1 except that the concentration of the pesticide decomposing agent of the present invention was 294 ppm.
＜비교예 1＞<Comparative Example 1>
본 발명의 농약 분해제를 첨가하지 않은 것을 제외하고는 시험예 1-1에서와 같이 하여 농약 제거 효과를 측정하였다.Except that the pesticide decomposition agent of the present invention was not added, the pesticide removal effect was measured as in Test Example 1-1.
＜시험예 2-1＞<Test Example 2-1>
유기염소계 살균제(성분: 엔도썰판; 바이엘지오릭스(상품명), 크롭사이언스 코리아 주식회사 제조) 4㎖, 물 1646㎖ 및 본 발명의 농약 제거제 50㎖(29400ppm)을 혼합하여 농작물에 살포한 후 10시간 뒤에 HPLC 및 GC에 의해 농약 제거 효과를 측정하였다.Organochlorine disinfectant (component: endosulpang; Bayer Geox (trade name), CropScience Korea Co., Ltd.) 4ml, 1646ml of water and 50ml (29400ppm) of pesticide remover of the present invention was mixed and sprayed on the crop after 10 hours The pesticide removal effect was measured by HPLC and GC.
＜시험예 2-2＞<Test Example 2-2>
본 발명의 농약 분해제의 농도를 2940ppm으로 한 것을 제외하고는 시험예 2-1에서와 같이 하여 농약 제거 효과를 측정하였다.The pesticide removal effect was measured as in Test Example 2-1 except that the concentration of the pesticide decomposing agent of the present invention was 2940 ppm.
＜시험예 2-3＞<Test Example 2-3>
본 발명의 농약 분해제의 농도를 294ppm으로 한 것을 제외하고는 시험예 2-1에서와 같이 하여 농약 제거 효과를 측정하였다.The pesticide removal effect was measured in the same manner as in Test Example 2-1, except that the concentration of the pesticide decomposition agent of the present invention was 294 ppm.
＜비교예 2＞<Comparative Example 2>
본 발명의 농약 분해제를 첨가하지 않은 것을 제외하고는 시험예 2-1에서와 같이 하여 농약 제거 효과를 측정하였다.Except that the pesticide decomposition agent of the present invention was not added, the pesticide removal effect was measured as in Test Example 2-1.
그 결과는 하기 표 1에 나타나 있다.The results are shown in Table 1 below.
[발명의 효과][Effects of the Invention]
이상에서 살펴본 바와 같이, 본 발명의 이온화 미네랄을 이용한 유해물질 제거제를 함유하는 농약 분해제의 구성과 작용에 의하면, 국내에서 다빈도로 사용되는 농약과 혼합하여 사용하는 경우 탁월한 농약 분해 효과가 있다.As described above, according to the constitution and action of the pesticide decomposing agent containing the harmful substance removing agent using the ionized mineral of the present invention, when used in combination with pesticides used in the domestic frequency, there is an excellent pesticide decomposition effect.
Claims (5)
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| KR1020090023331A KR20100104721A (en) | 2009-03-19 | 2009-03-19 | Removal of harmful substances using ionized minerals and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20220089324A (en) | 2020-12-21 | 2022-06-28 | 주식회사 이엔케이글로벌 | Base components for mixing inorganic materials and products compring the same |
| KR102637027B1 (en) * | 2023-01-05 | 2024-02-15 | 이승진 | Method and composition for removing residual pesticides using microorganism from agricultural products |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20220089324A (en) | 2020-12-21 | 2022-06-28 | 주식회사 이엔케이글로벌 | Base components for mixing inorganic materials and products compring the same |
| KR102637027B1 (en) * | 2023-01-05 | 2024-02-15 | 이승진 | Method and composition for removing residual pesticides using microorganism from agricultural products |
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