KR20100042321A - The uncarbonized charcoal having the eco-friendly and functional properties - Google Patents

The uncarbonized charcoal having the eco-friendly and functional properties Download PDF

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KR20100042321A
KR20100042321A KR1020080101411A KR20080101411A KR20100042321A KR 20100042321 A KR20100042321 A KR 20100042321A KR 1020080101411 A KR1020080101411 A KR 1020080101411A KR 20080101411 A KR20080101411 A KR 20080101411A KR 20100042321 A KR20100042321 A KR 20100042321A
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charcoal
eco
friendly
raw materials
prepared
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KR1020080101411A
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Korean (ko)
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최재영
배성재
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최재영
배성재
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • C10L5/447Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/10Treating solid fuels to improve their combustion by using additives
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: An uncarbonated charcoal having environment-friendly and functional properties is provided to sterilize foods by generating flavor of raw materials, to be continuously combusted without smoke, and to obtain excellent quality without carbonization of charcoal. CONSTITUTION: An uncarbonated charcoal having environment-friendly and functional properties comprises raw materials, combustion improver, and other additives. The combustion improver is a mixture of polyvinyl alcohol, rosin, rosin ester class, fatty acid, fatty acid salt, alcohols, polyhydric alcohol series, organic acid, or a catalyst. The combustion improver 1 ~ 40 parts by weight is used. The raw materials is a mixture of sawdust, rice hulls, rice straw, cinnamomi Cortex, glycyrrhizae radix, menthae Herba, Atractylodis Rhizoma, Perilla frutescens var. acuta, ginger, hinoki cypress leaf, thuja orientalis leaf, pine needles, material of herbal medicine, grains residue, and other vegetable cellulose.

Description

탄화하지 않은 친환경 기능성 생탄숯{The uncarbonized charcoal having the eco-friendly and functional properties}The uncarbonized charcoal having the eco-friendly and functional properties

본 발명은 톱밥, 왕겨, 볏집, 한약재 찌꺼기, 곡물찌꺼기, 기타 식물성셀루로오즈 등을 원료로 한 것을 탄화하지 않고 화학적인 약품 처리로만 하여 종래의 숯과 같은 기능을 하도록 한 것에 관한 것이다. 여기서 사용되는 화학약품은 C, H, O의 원소로만 구성 것을 사용하여서 연소과정에서 유해물질이 배출되지 않도록 한 것이 특징이다.The present invention relates to a saw charcoal, chaff, crest, Chinese herbal remnants, grain remnants, and other vegetable cellulose as a raw material without the carbonization of the chemical treatment only to function as a conventional charcoal. The chemicals used here consist of only C, H, and O elements, so that no hazardous substances are emitted during combustion.

산업화가 시작되면서 석탄에서부터 석유와 가스의 사용이 시작되고 그리고 모든 일상생활은 간편화를 추구하게 되었고 이와 더불어 조리방법도 간편한 방법을 선호하게 되었다. 그러나 최근에 들어서 웰빙문화가 전 세계적으로 확산되면서 식품에 대한 건강성에 대하여 보다 많은 관심을 보이고 있는 가운데 음식의 조리 방법과 재료의 웰빙화에도 신경을 많이 쓰게 되었다. 이러한 최근의 동향에 따라서 과거의 원시자연적인 생활방식으로 돌아가고자 하는 경향이 있게 되었고 이로 인하여 자연식과 과거의 조리방법을 추구하는 경향이 있게 되었다. 이러한 경향에 따라서 숯을 사용한 음식 조리방법이 가장 좋은 것으로 여겨지고 있으며 더욱이 허브향 또는 한약향이 나는 숯을 사용하여 음식의 살균과 미각의 향상, 그리고 풍미증진을 향상시키고자 하는 경향이 있게 되었다. 그러나 허브향 또는 한약재의 향이 나는 재료를 사용하여 숯을 만들었을 때에 고온의 탄화과정에서 허브향 또는 한약재의 향은 전부 휘발되기 때문에 별로 효과가 없었다.As industrialization began, the use of oil and gas began from coal, and all daily life sought to be simplified, and the method of cooking was also preferred. However, with the recent spread of well-being cultures around the world, more attention has been paid to the health of foods, and more attention has been paid to the cooking of foods and the well-being of ingredients. These recent trends have led to a tendency to return to the primitive natural lifestyles of the past, and to the pursuit of natural food and past cooking methods. According to this tendency, the cooking method using charcoal is considered to be the best and moreover, there is a tendency to improve the sterilization, taste improvement and flavor enhancement of food by using charcoal with herbal or herbal flavor. However, when the charcoal was made using the ingredients of herbal or herbal medicines, all of the herbal or herbal medicines were volatilized during the high temperature carbonization process.

본 발명에서는 이러한 문제점을 해결하기 위하여 원재료의 물성을 그대로 살리기 위하여 원재료를 탄화하지 않고 연소시키는 기술을 소개하고자 함이 목적이다. 이 목적을 달성하기 위해서는 우선적으로 탄화해야만 되는 종래의 숯의 개념을 바꾸는 것이 가장 중요한 과제이었다. 즉, 원재료를 그대로 이용하는 생탄이라는 개념을 고취시켜서 생탄숯이라는 술어를 새로이 정의하였다.In order to solve this problem, an object of the present invention is to introduce a technique for burning raw materials without carbonization in order to preserve the physical properties of the raw materials. In order to achieve this object, it was the most important task to change the concept of conventional charcoal which must be carbonized first. That is, the term "coal charcoal" was newly defined by inspiring the concept of coal charcoal using raw materials as it is.

본 발명의 생탄숯을 제조하는데 필요한 약품은 필연적으로 인체에 해롭지 않는 자연 재료를 사용하고 유해한 재료는 배제하도록 하였다. 특히 종래의 착화제와 고형연료에 있어서 폭팔적인 연소 현상을 일으키기 위하여 여러 형태의 유해한 약품을 사용하였는데 이들을 유형별로 열거해 보면 한국 공개특허공보 1989-0001765호 에서는 화약재료로 사용되는 금속염으로서 금속마그네슘을 사용하였으며 그리고 조연제로서 헥사메틸렌테트라민을 사용하였다. 이 헥사메틸렌테트라아민은 1차 재료로서는 무해하더라도 연소과정에서 2차적으로 NOx로 표현되는 질소산화물을 발생하여서 폐기종과 기관지염을 유발시키고 오존층을 파괴하는 유해한 물질이다. 그리고 한국 공개특허공보 89-002833호 에서는 초산바륨, 초산칼륨, 과망간산 칼륨, 중 크롬산 컬륨과 같은 다수의 화약재료를 사용하였다.The drug required to prepare the charcoal of the present invention is to use natural materials that are not harmful to the human body and to exclude harmful materials. In particular, in the conventional complexing agents and solid fuels, various types of harmful chemicals were used to cause explosive combustion. In the case of the types listed by Korean Patent Application Publication No. 1989-0001765, metal magnesium is used as the metal salt as the explosive material. And hexamethylenetetramine was used as a supporting agent. Although hexamethylenetetraamine is harmless as a primary material, it is a harmful substance that generates nitrogen oxides expressed as NOx secondaryly during combustion, causing emphysema, bronchitis, and destroying the ozone layer. In Korean Laid-Open Patent Publication No. 89-002833, a number of gunpowder materials such as barium acetate, potassium acetate, potassium permanganate, and cerium bichromate were used.

본 발명에서는 C, H, O의 원소로 구성된 화합물을 사용하였고 특히 연소 시에 2차적으로 발생하는 질소산화물(NOx)을 발생하는 질소화합물은 전혀 사용하지 않도록 하였으며 그리고 화약재료를 사용되는 금속염을 사용하는 대신에 완전연소가 가능한 알콜류 또는 다가알콜류를 사용하여 문제를 해결하였다.In the present invention, a compound composed of elements of C, H, and O is used. Particularly, a nitrogen compound which generates nitrogen oxides (NOx), which are generated secondarily during combustion, is not used at all, and a metal salt using explosive material is used. Instead, the problem was solved by using complete burning alcohols or polyhydric alcohols.

그리고 원재료의 향을 내기위하여 쑥, 계피, 감초, 박하, 창출, 자소, 생강, 편백잎, 측백잎, 솔잎, 한약찌꺼기 등을 탄화하지 않고 원료 그대로 연소시켜 이들의 향으로 살균과 미각을 돋우는 동시에 풍미증진 효과를 부여하도록 하였다.And in order to smell the raw materials, mugwort, cinnamon, licorice, mint, creation, charcoal, ginger, cypress leaves, cypress leaves, pine needles, Chinese herbal remnants, etc. are burned as raw materials without carbonization, and their fragrance and taste are enhanced. It was to give a flavor enhancing effect.

새로운 개념의 친환경 기능성 생탄숯으로서 원재료의 향을 발생시켜 음식의 살균과 미각을 향상시키는 새로운 웰빙조리방법을 제공하게 될 것이다. 그리고 숯의 탄화공정이 없게 되어 질과 가격 면에서 보다 경쟁력이 있는 상품으로서 종래의 검정 숯을 대체하게 될 것이다.As a new concept of eco-friendly functional charcoal, it will provide a new well-being cooking method that improves the sterilization and taste of food by generating the fragrance of raw materials. And there will be no charcoal carbonization process will replace the conventional black charcoal as a more competitive product in terms of quality and price.

일반적으로 숯의 제조에 있어서, 원재료, 조연제, 발화제, 성형제, 그리고 기타첨가제 등으로 구성된다. 그러나 본 발명에서 조연제는 발화제와 성형제의 기능을 모두 동시에 만족시키도록 한다. 특히, 종래에 사용되는 발화제들은 대부분 화약재료로서 아민 또는 질산염 계통의 질소화합물과 금속염 또는 중금속염으로 구성되어 있기 때문에 이들 화합물을 알콜계열의 자연화합물로 대체하기 때문이다.Generally in the production of charcoal, it is composed of raw materials, a supporting agent, a ignition agent, a molding agent, and other additives. However, in the present invention, the softening agent satisfies both the functions of the firing agent and the molding agent at the same time. In particular, since conventionally used ignition agents are composed of amine or nitrate-based nitrogen compounds and metal salts or heavy metal salts as the explosive materials, these compounds are replaced by alcohol-based natural compounds.

조연제는 폴리비닐알콜, 로진, 로진에스테르류, 지방산, 지방산염, 알콜류, 다가알콜류, 유기산, 그리고 촉매제를 하나 또는 둘 이상의 혼합물로서 1 내지 40 중량부로 사용함이 바람직하고 하다.It is preferable to use polyvinyl alcohol, rosin, rosin esters, fatty acids, fatty acid salts, alcohols, polyhydric alcohols, organic acids, and a catalyst in an amount of 1 to 40 parts by weight as one or more mixtures.

여기서 알콜류로는 메틸알콜, 에틸알콜, 이소프로필알콜, 부탄올, 헥사놀, 사이크로헥사놀 등이 있으며 이것에 국한하는 것은 아니다.Alcohols include, but are not limited to, methyl alcohol, ethyl alcohol, isopropyl alcohol, butanol, hexanol, cyclohexanol, and the like.

다가알콜류로는 에틸렌글리콜, 글리세린. 폴리에틸렌글리시딜, 폴리프로필렌글리콜, 글루코스, 솔비톨, 솔비탄, 전분, 맥아당, 덱스트린, 글리코겐, 과당, trimethylol propane, trimethylol ethane, pentaerythritol 등이 있으며 이것에 국한하는 것은 아니다.Polyhydric alcohols include ethylene glycol and glycerin. Polyethylene glycidyl, polypropylene glycol, glucose, sorbitol, sorbitan, starch, maltose, dextrin, glycogen, fructose, trimethylol propane, trimethylol ethane, pentaerythritol, and the like.

유기산으로는 구연산과 글루코닉산 등이 있으며 이것에 국한하는 것은 아니다.Organic acids include, but are not limited to, citric acid and gluconic acid.

연소 촉매제로는 제오라이트, 벤토나이트, 플라이애쉬, 실리카흄, 황토, 질석 등이 있으며 이것에 국한하는 것은 아니다.Combustion catalysts include, but are not limited to zeolite, bentonite, fly ash, silica fume, loess, vermiculite, and the like.

원재료로는 톱밥, 왕겨, 볏집, 쑥, 계피, 감초, 박하, 창출, 자소, 생강, 편백잎, 측백잎, 솔잎, 한약재 또는 한약재 찌꺼기, 곡물찌꺼기, 기타 식물성 셀루로오즈를 하나 또는 둘 이상의 혼합물을 40 내지 90 중량부로 사용함이 바람직하고 하다. 여기서 톱밥은 침엽수와 활엽수로 구분되어 사용된다.Ingredients include one or more mixtures of sawdust, rice hulls, crests, mugwort, cinnamon, licorice, peppermint, creation, shiso, ginger, cypress leaves, cypress leaves, pine needles, herbal or herbal remnants, grain dregs and other vegetable cellulose. It is preferable to use 40 to 90 parts by weight. Sawdust is used here as a conifer and hardwood.

기타첨가제로는 가성소오다를 경우에 따라서 사용 할 수가 있으며 본 발명에서 유일하게 사용되는 금속염이지만 나트륨은 우리가 매일 일정량 섭취하여야 하고 배출하는 무해한 금속이다.Other additives are caustic soda, which may be used in some cases, and are the only metal salts used in the present invention, but sodium is a harmless metal that must be consumed in a certain amount every day.

[실시예 1]Example 1

[표 1]TABLE 1

Figure 112008505158624-PAT00001
Figure 112008505158624-PAT00001

상기 표1과 같은 조성비로 구성된 혼합물을 로터리 킬른에서 80℃로 30분간 가열하면서 혼합하고 130℃에서 30분간 가열 혼합하면서 성형기로 지름 30mm 시린더 형으로 성형하였다. 상기 성형물을 5개 포개어서 연소하였을 때, 쑥향기와 함께 80분간 일정한 발열량을 유지하면서 연소되었다.The mixture consisting of the composition ratio as shown in Table 1 was mixed in a rotary kiln while heating at 80 ° C. for 30 minutes and heated and mixed at 130 ° C. for 30 minutes to form a 30 mm diameter cylinder with a molding machine. When the molded products were burned by stacking five of them, they were burned while maintaining a constant calorific value for 80 minutes together with mugwort.

[실시예 2][Example 2]

[표 2]TABLE 2

Figure 112008505158624-PAT00002
Figure 112008505158624-PAT00002

상기 표1과 같은 조성비로 구성된 혼합물을 로터리 킬른에서 80℃로 30분간 가열하면서 혼합하고 130℃에서 30분간 가열 혼합하면서 성형기로 지름 30mm 시린더 형으로 성형하였다. 상기 성형물을 5개 포개어서 연소하였을 때, 실시예 1 에 비교하여 불꽃이 보다 안정적으로 유지되었고 한약재 향기와 함께 90분간 일정한 발열량을 유지하면서 연소되었다.The mixture consisting of the composition ratio as shown in Table 1 was mixed in a rotary kiln while heating at 80 ° C. for 30 minutes and heated and mixed at 130 ° C. for 30 minutes to form a 30 mm diameter cylinder with a molding machine. When the molded product was burned by stacking five, the flame was more stably compared with Example 1 and burned while maintaining a constant calorific value for 90 minutes with the scent of the herbal medicine.

Claims (5)

본 발명에서는 탄화하지 않고 원재료에 화학적인 처리로만 하여 원재료의 고유성질을 그대로 살리고 연기가 나지 않고 지속적으로 연소될 수 있도록 한 새로운 개념의 생탄숯에 관한 것으로서 원재료, 조연제, 그리고 기타첨가제 등으로 구성된다.The present invention relates to fresh charcoal charcoal of a new concept that can be burned without smoke without any carbonization, but by chemical treatment of the raw material as it is, and keeps the unique properties of the raw material. do. 조연제는 폴리비닐알콜, 로진, 로진에스테르류, 지방산, 지방산염, 알콜류, 다가알콜류, 유기산, 그리고 촉매제를 하나 또는 둘 이상의 혼합물로서 1 내지 40 중량부로 사용함을 특징으로 하고,The fuel retardant is characterized in that polyvinyl alcohol, rosin, rosin esters, fatty acids, fatty acid salts, alcohols, polyhydric alcohols, organic acids, and catalysts are used in an amount of 1 to 40 parts by weight as one or two or more mixtures. 원재료로는 톱밥, 왕겨, 볏집, 쑥, 계피, 감초, 박하, 창출, 자소, 생강, 편백잎, 측백잎, 솔잎, 한약재 또는 한약재 찌꺼기, 곡물찌꺼기, 기타 식물성 셀루로오즈를 하나 또는 둘 이상의 혼합물을 40 내지 90 중량부로 사용함을 특징으로 하여 제조되는 친환경 기능성 생탄숯에 관한 것이다.Ingredients include one or more mixtures of sawdust, rice hulls, crests, mugwort, cinnamon, licorice, peppermint, creation, shiso, ginger, cypress leaves, cypress leaves, pine needles, herbal or herbal remnants, grain dregs and other vegetable cellulose. It relates to an eco-friendly functional charcoal charcoal prepared by using 40 to 90 parts by weight. 제 1항에 있어서, 상기의 알콜류는 메틸알콜, 에틸알콜, 이소프로필알콜, 부탄올, 헥사놀, 사이크로헥사놀 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되는 친환경 기능성 생탄숯.According to claim 1, wherein the alcohol is methyl alcohol, ethyl alcohol, isopropyl alcohol, butanol, hexanol, cyclohexanol and the like, characterized in that the eco-friendly functional charcoal is prepared by using one or more. 제 1항에 있어서, 상기의 다가알콜류는 에틸렌글리콜, 글리세린. 폴리에틸렌글리시딜, 폴리프로필렌글리콜, 글루코스, 솔비톨, 솔비탄, 전분, 맥아당, 덱스트 린, 글리코겐, 과당, trimethylol propane, trimethylol ethane, pentaerythritol 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되는 친환경 기능성 생탄숯.The method of claim 1, wherein the polyhydric alcohols are ethylene glycol, glycerin. Eco-friendly manufactured by using one or more of polyethyleneglycidyl, polypropylene glycol, glucose, sorbitol, sorbitan, starch, maltose, dextrin, glycogen, fructose, trimethylol propane, trimethylol ethane, pentaerythritol, etc. Functional charcoal. 제 1항에 있어서, 상기의 유기산은 구연산과 글루코닉산 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되는 친환경 기능성 생탄숯.The eco-friendly functional charcoal charcoal according to claim 1, wherein the organic acid is prepared by using one or more of citric acid and gluconic acid. 제 1항에 있어서, 상기의 연소 촉매제는 제오라이트, 벤토나이트, 플라이애쉬, 실리카흄, 황토, 질석 등을 하나 또는 둘 이상을 사용함을 특징으로 하여 제조되는 친환경 기능성 생탄숯.The eco-friendly functional charcoal charcoal according to claim 1, wherein the combustion catalyst is prepared by using one or more of zeolite, bentonite, fly ash, silica fume, loess, vermiculite and the like.
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104804796A (en) * 2015-03-25 2015-07-29 天津神侬环保科技有限公司 Special environment-friendly slag and ash removal agent for biomass boiler
CN105154164A (en) * 2015-09-30 2015-12-16 寿宁县南阳镇光辉环能木屑加工厂 Bio-mass granular fuel additive and preparation method thereof
CN106281532A (en) * 2015-06-05 2017-01-04 许成荫 A kind of feces makes fuel combination

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104804796A (en) * 2015-03-25 2015-07-29 天津神侬环保科技有限公司 Special environment-friendly slag and ash removal agent for biomass boiler
CN104804796B (en) * 2015-03-25 2017-12-15 天津神侬环保科技有限公司 A kind of biomass boiler special environment protection scarfing cinder deashing agent
CN106281532A (en) * 2015-06-05 2017-01-04 许成荫 A kind of feces makes fuel combination
CN105154164A (en) * 2015-09-30 2015-12-16 寿宁县南阳镇光辉环能木屑加工厂 Bio-mass granular fuel additive and preparation method thereof

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