KR20090099023A - Celadon Glaze Composition Using Cow Manure - Google Patents

Celadon Glaze Composition Using Cow Manure Download PDF

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KR20090099023A
KR20090099023A KR20080024129A KR20080024129A KR20090099023A KR 20090099023 A KR20090099023 A KR 20090099023A KR 20080024129 A KR20080024129 A KR 20080024129A KR 20080024129 A KR20080024129 A KR 20080024129A KR 20090099023 A KR20090099023 A KR 20090099023A
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celadon
glaze
cow manure
powder
limestone
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KR20080024129A
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KR100940167B1 (en
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김복한
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김복한
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

A method for preparing a celadon glaze using cow manure is provided to facilitate a baking process of celadon at reduced costs. A celadon glaze is composed of 20% of cow manure ashes, 70% of pillar pottery stone, 24% of limestone and 6% of silica. A method for preparing the celadon glaze using cow manure comprises the following steps of: mixing a base material and 20% of cow manure ashes, wherein the base material consists of 70% of pillar pottery stone, 24% of limestone and 6% of silica; preparing a celadon sintered at 900°C; and coating the prepared glaze on the celadon to a thickness of 0.1mm and reduction-sintering at the temperature of 1240°C-1260°C. A sintering oven is slowly heated up to 1,000°C and maintained at 1240°C-1250°C.

Description

우(牛)분료를 이용한 청자(靑磁)유약의 제조 방법{x}Manufacturing method of celadon glaze using milk powder {x}

본 발명은 우(牛)분료를 이용하여 분료를 재로 만들어 청자유약를 제조하는 조성물에 관한 것으로 , 본 발명의 특징은 처리가 심각한 우(牛)분료를 이용해 청자 유약으로 제조하여 청자의 고유의 색상과 질감을 지키며 작업할 수 있는 유약이다.The present invention relates to a composition for preparing celadon glaze by making a powder from ash by using a milk powder, and features of the present invention are made of celadon glaze using cough powder, which is seriously treated, It is a glaze that can work while keeping the texture.

유약이라 함은 도자기류나 타일류 등의 성형하여 소성하기 전에 표면을 피복시키기 위해 사용하는 유리질 소재를 말하는 것으로, 도자기를 제조할 때 성형하여 구운 소지위에 엷게 피복,밀착시키기 위해 바르는 유리질의 잿물을 말한다.Glaze is a glassy material used to coat the surface before molding and firing ceramics or tiles. It refers to glassy lye that is applied to lightly coat and adhere to baked material that is formed and molded in ceramics. .

유약을 바르는 목적은 표면에 광택을 주어 제품을 아름답게 하는 것 외에도 강도를 더하고 표면을 반질반질하게 하여 더러워지는 것을 방지하는 데 있으며, 또한 흡수성을 없애서 물이나 화학약품에 대한 저항성을 증가시킨다는 실용면에도 도움이 된다.The purpose of applying glaze is not only to make the product beautiful by giving the surface luster, but also to increase the strength and to make the surface semi-finished, to prevent it from becoming dirty, and also to remove the absorbency to increase the resistance to water or chemicals. It helps.

청자유약의 성질로서는 도자기에 유약을 바르고 구웠을 때 잘 녹아 유동하여 소지 에 밀착함으로써 표면에 엷은 청록색을 띄는 유리막을 생성하는 것이라야 한다.The nature of celadon glaze should be that when glaze is applied to porcelain glaze and melts well, it flows and adheres closely to the base to create a light blue-green glass film on the surface.

상기 유약의 배합이 잘못되어 청록색이 없이 투명하게 되는 유약를 투명유라 한다. 이런 유약은 분청도자기에서 많이 사용하고 있다.A glaze that is transparent without a turquoise color due to a wrong formulation of the glaze is referred to as a transparent oil. Such glazes are widely used in pottery ceramics.

청자유약은 청록색를 띄는 유약이지만 유백유,색유,결정유,무염유,균열유 등이 있는 바, 이러한 유약의 조성은 소성온도의 고저와 토질에 따라서 조합과 조성이 다르며, 일반적으로 자기류와 도기류로 분류되고, 이의 주성분은 규산화합물이고, 사용되는 원료로 자기와 도기류로 분류되고, 이의 주성분은 규산화합물이고, 사용되는 원료로 자기와 같이 고온도(1,200∼1,500 ℃)에서 소성하는 것으로서 장석,석영,석회석,고령토 등이 있으며, 도기와 같이 저온도(960∼1,000 ℃) 소성에는 고령토,붕사,장석,석회석 등이 사용된다.청자유약을 제조하는데는 색채를 가하는 화합물이 필요한데 철,구리,코발트,망간 등 이에 해당된다.Celadon glaze has a turquoise glaze, but there are milk milk, color oil, crystalline oil, unsalted oil, cracked oil, etc.The composition and composition of these glazes differ in combination and composition depending on the elevation of the baking temperature and soil. Its main component is silicic acid compound, and it is classified as porcelain and pottery as a raw material used. Its main ingredient is silicic acid compound, and its raw material is calcined at high temperature (1,200 ~ 1,500 ℃) like porcelain. Kaolin, Borax, Feldspar, Limestone are used for calcination at low temperature (960 ~ 1,000 ℃) like pottery.In order to manufacture celadon glaze, it is necessary to add a color compound, iron, copper, and cobalt. Such as manganese.

또한 청자 등의 제조용 유약의 경우는 대부분 화학약품을 사용하게 되므로 환경을 오염시키는 요인이 될 뿐만 아니라 원래 목적으로 하는 자연적인 청자의 고유색상이나 질감을 득하기란 거의 불가능한 실정이다.In addition, in the case of manufacturing glazes such as celadon, most of them use chemicals, which not only contaminates the environment, but it is almost impossible to obtain the natural color or texture of the natural celadon.

도자기나 청자,타일 등과 같은 물품을 제조하기 위해 근자에 들어 주로 사용하는 재는 소나무,참나무와 볏짚의 재와 산화장석,도석,석회석,제2산화철,산화코발트,산화크롬 등을 미세한 분말상태로 분쇄하여 적정의 비율로 희석한 상태에서 유약을 조성하는 바, 이러한 상기와 같이 조성된 유약은 청자의 청록색을 내기 위한 색채료인 철,구리,코발트.망간 등이 들어가 환경오염의 원인이 되기도 한다.Ash used mainly in the roots to manufacture items such as pottery, celadon, and tile is pulverized with fine powder of pine, oak and rice straw, feldspar, pottery, limestone, ferric oxide, cobalt oxide, and chromium oxide. The glaze is formed in a diluted state at an appropriate ratio. The glaze formed as described above may contain iron, copper, cobalt, manganese, etc., which are used to produce a cyan blue color, and may cause environmental pollution.

이와 같은 조성물로 이루어진 유약은 과거부터 사용되어 오는 청자와 같은 도자기류와 유사한 색상이나 질감을 얻을 수 있으나, 색채료인 철,구리,코발트,망간 등은 재료비도 비싸고 성분도 일정하지가 않아 새로운 색채료를 찾아야 하는 실정이다. Glaze made of such a composition can obtain a color or texture similar to porcelain, such as celadon, which has been used in the past, but color, iron, copper, cobalt, and manganese are expensive, and their ingredients are not constant. I have to find.

우(牛)분료의 총중량의 20%의 재와 광주도석 70%, 석회석 24%, 규석 6%와 혼합한 유약의 원료를 특징으로 하는 청자 유약.A celadon glaze characterized by the raw material of the glaze mixed with 20% of the total weight of bovine powder, 70% of gwangju stone, 24% of limestone, and 6% of silica.

본 발명은 재료의 구입에 있어 철과 코발트등과 같은 고가의 화학약품보다 구이도 쉽고 저가의 비용으로 일정한 성분비를 갖고 있는 우(牛)분료를 재로 만들어 청자 유약의 색채료로 사용할 수 있게 되었다.The present invention can be used as a colorant of celadon glaze by making a powder made of wood powder, which is easier to roast than expensive chemicals such as iron and cobalt, and has a constant ingredient ratio at low cost.

본 발명은 우분료의 재를 주재로 한 청자유약의 제조방법에 관한 것으로 특히 우분료재의 분말에 광주도석, 석회석, 와목점토 등을 혼합 교반(攪拌)하여 150메쉬인 체로 걸러 젤 상태로 만들어서 청자소지에 입혀 고온으로 소성시켜 청자 도자기를 제조하는 방법에 관한 것이다.The present invention relates to a manufacturing method of celadon glaze mainly made of ash of milk powder, and especially, the powder of the powder of milk powder is mixed with stirring Gwangju stone, limestone, and granite clay to make a gel with a sieve of 150 mesh. It relates to a method of producing celadon porcelain by coating on a substrate and firing at high temperature.

종래의 청자유약의 제조방법에 있어서는 소나무재 및 화공약품을 혼합하여 사용하는 방법이 있는데 철,구리,코발트,망간 등 이에 해당된다.In the conventional method of manufacturing celadon glaze there is a method of mixing and using pine wood and chemicals, such as iron, copper, cobalt, manganese and the like.

또한 청자유약등의 제조용 유약의 경우는 대부분 화학약품을 사용하게 되므로 환경을 오염시키는 요인이 될 뿐만 아니라 원래 목적으로 하는 자연적인 청자의 고유색상이나 질감을 득하기란 거의 불가능한 실정이다.In addition, since most of the manufacturing glazes, such as celadon glaze, use chemicals, it is not only a pollutant to the environment, but it is almost impossible to obtain the natural color or texture of the natural celadon of the intended purpose.

상기한 바의 우분료를 이용하여 청자유약을 제조하는 목적을 달성하기 위해 본 발명은 기본유인 광주도석 70%, 석회석 24%, 규석 6%를 교반한 유약에 우분료 재 분말을 20% In order to achieve the object of manufacturing the celadon glaze using the above-mentioned milk powder, the present invention is 20% by weight of powdered milk powder in the glaze stirring the basic oil Gwangju-doseok 70%, limestone 24%, silica 6%

혼합교반하여 900℃로 소성한 기물에 0.1mm의 두깨로 피복시켜서 1240℃-1260℃로 환원소성한다.The mixture is stirred and calcined at 900 DEG C and coated with 0.1 mm of thickness to reduce baking to 1240 DEG C-1260 DEG C.

또한 소성가마의 온도 분포는 직접적으로 제품의 질을 좌우하는 것이므로 본발명에서는 초기시작부터 서서히 1,000℃의 온도까지 가열한 다음에 1240℃-1250℃까지 소성을 한다.In addition, since the temperature distribution of the kiln directly affects the quality of the product, the present invention is gradually heated to a temperature of 1,000 ° C. from the initial start and then fired to 1240 ° C.-1250 ° C.

본 발명은 목장에서 키우고 있는 우분료를 이용하여 청자유약의 착색물인 철과 같은 화공약품의 대체 재료을 이용한 제조방법에 대해서 상세히 설명하기로 한다. The present invention will be described in detail with respect to a manufacturing method using an alternative material of a chemical such as iron, which is a coloring product of celadon glaze using a cow manure grown in a ranch.

[실시예1] Example 1

목장에서 짚을 주식으로 하는 우분료로 자연 건조된 분료를 수거하여 용기에 넣어 우분료를 분말상태로 만들기 위해서 재로 만든다. On the ranch, straw powder is used to collect naturally-dried powder and put it in a container to make the powder into powder.

분말상태인 재를 물과 섞어 교반하여 분쇄과정을 거쳐 150메쉬인 채로 걸러 준다. The powdered ash is mixed with water, stirred and filtered to be 150 mesh.

상기와 같이 걸러준 우분료의 재를 가라앉힘 과정을 거쳐 하단에 가라앉은 재만 남기고 물만 따라 내어 건조 과정인 자연건조를 시켜 분말 상태로 만든것이 청자유약의 착색물로 사용되는 재가 되는것이다.After removing the ash of the filtered manure as described above, leaving only the ash submerged at the bottom, leaving only the water, followed by water drying, and drying it to a powder form is used as a coloring material of celadon glaze.

[실시예2]Example 2

상기와 같이 우분료의 재를 준비하여 청자의 기본유가 되는 광주도석 70%, 석회석 24%, 규석 6%의 혼합물에 우분료 재를 16%-26%의 범위에 5%씩 증가시킨 혼합물을 1240℃-1250℃소성을 한다.1240 was prepared by increasing the amount of powdered ash by 5% in the range of 16% -26% in the mixture of 70% Gwangju-doseok, limestone 24%, and quartzite 6%, which are the basic oils of celadon. It fires at -1250 ℃.

상기와 같이 실시 한 결과 우분료 20%의 혼합물의 유약에서 청자의 유약으로 사용할 수 있는 유리질의 청자유약의 결과가 나왔다.As a result, the result of the glassy blue glaze that can be used as the glaze of celadon in the glaze of the mixture of 20% milk powder.

실험결과와 같이 우(牛)분료가 착색물로 사용할수 있음은 물론 환경의 오염이 되고 있는 축산분료의 활용성을 보여 주는것이다.As shown in the experimental results, the right powder can be used as a coloring material and shows the utility of the livestock powder that is polluting the environment.

도1은 본 발명에 따른 우분료를 이용한 청자유약의 제조 공정1 is a manufacturing process of celadon glaze using milk powder according to the present invention

Claims (1)

우(牛)분료의 총중량의 20%의 재와 광주도석 70%, 석회석 24%, 규석 6%와 혼합한 유약의 원료를 특징으로 하는 청자 유약.A celadon glaze characterized by the raw material of the glaze mixed with 20% of the total weight of bovine powder, 70% of gwangju stone, 24% of limestone, and 6% of silica.
KR20080024129A 2008-03-16 2008-03-16 Compositions of Toceladon's Glaze using Excrement of Cattle KR100940167B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101238266B1 (en) * 2010-12-03 2013-03-04 경기도 Glaze composition for ceramic ware comprising ashes from the excrements of silkworm and preparation method thereof
CN110228993A (en) * 2019-04-25 2019-09-13 龙泉市青瑜瓷坊 A kind of crackle celadon bottle for cosmetics processing technology with the non-crack glaze of inner face

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KR101208350B1 (en) 2010-10-11 2012-12-05 경기도 Glaze composition for ceramic ware comprising ashes from the excrements of earthworm and preparation method thereof
KR101401260B1 (en) * 2012-06-15 2014-05-30 김광훈 Glaze composition for ceramic ware comprising ashes from fowl excrement and preparation method thereof

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KR100524514B1 (en) * 2003-05-09 2005-11-01 김부남 Manufacturing Method for Black Marbles and Tiles Using Excretions
KR100759053B1 (en) 2006-03-29 2007-09-14 신규식 Glaze composition producing crystal and manufacturing method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101238266B1 (en) * 2010-12-03 2013-03-04 경기도 Glaze composition for ceramic ware comprising ashes from the excrements of silkworm and preparation method thereof
CN110228993A (en) * 2019-04-25 2019-09-13 龙泉市青瑜瓷坊 A kind of crackle celadon bottle for cosmetics processing technology with the non-crack glaze of inner face
CN110228993B (en) * 2019-04-25 2021-10-29 龙泉市青瑜瓷坊 Processing technology of crackle celadon cosmetic bottle with inner non-crackle glaze

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