KR20080060633A - Method of forming semiconductor device using the tungsten layer - Google Patents
Method of forming semiconductor device using the tungsten layer Download PDFInfo
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- KR20080060633A KR20080060633A KR1020060134974A KR20060134974A KR20080060633A KR 20080060633 A KR20080060633 A KR 20080060633A KR 1020060134974 A KR1020060134974 A KR 1020060134974A KR 20060134974 A KR20060134974 A KR 20060134974A KR 20080060633 A KR20080060633 A KR 20080060633A
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- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 229910052721 tungsten Inorganic materials 0.000 title claims abstract description 60
- 239000010937 tungsten Substances 0.000 title claims abstract description 60
- 239000004065 semiconductor Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 49
- 230000004888 barrier function Effects 0.000 claims abstract description 14
- 238000005229 chemical vapour deposition Methods 0.000 claims abstract description 9
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 239000010408 film Substances 0.000 claims description 49
- 238000000427 thin-film deposition Methods 0.000 claims description 11
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 238000000231 atomic layer deposition Methods 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000011800 void material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 description 4
- 238000000151 deposition Methods 0.000 description 3
- 230000008021 deposition Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000013508 migration Methods 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000010354 integration Effects 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 238000007517 polishing process Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000007736 thin film deposition technique Methods 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76877—Filling of holes, grooves or trenches, e.g. vias, with conductive material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28512—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table
- H01L21/28556—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic Table by chemical means, e.g. CVD, LPCVD, PECVD, laser CVD
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76843—Barrier, adhesion or liner layers formed in openings in a dielectric
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/70—Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
- H01L21/71—Manufacture of specific parts of devices defined in group H01L21/70
- H01L21/768—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics
- H01L21/76838—Applying interconnections to be used for carrying current between separate components within a device comprising conductors and dielectrics characterised by the formation and the after-treatment of the conductors
- H01L21/76841—Barrier, adhesion or liner layers
- H01L21/76871—Layers specifically deposited to enhance or enable the nucleation of further layers, i.e. seed layers
- H01L21/76876—Layers specifically deposited to enhance or enable the nucleation of further layers, i.e. seed layers for deposition from the gas phase, e.g. CVD
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Abstract
Description
도 1a 내지 도 1d는 본 발명의 실시 예에 따른 텅스텐 막을 이용한 반도체 소자 형성 방법을 단계적으로 나타내는 도면.1A through 1D are diagrams illustrating a method of forming a semiconductor device using a tungsten film according to an exemplary embodiment of the present invention.
<도면의 주요 부분에 대한 설명>Description of the main parts of the drawing
110 : 반도체 기판 120 : 절연막110
122 : 콘택홀 124 : 트렌치122: contact hole 124: trench
130 : 베리어층 140 : 제 1 텅스텐 막130: barrier layer 140: the first tungsten film
150 : 제 2 텅스텐 막 152 : 텅스텐 배선150: second tungsten film 152: tungsten wiring
본 발명은 반도체 소자의 형성 방법에 관한 것으로, 특히 작은 크기의 콘택홀에 텅스텐을 채울 수 있도록 한 텅스텐 막을 이용한 반도체 소자 형성 방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a semiconductor device, and more particularly, to a method for forming a semiconductor device using a tungsten film to fill tungsten in a small contact hole.
반도체 소자에 있어서, 플러그 및 배선등은 저항이 작은 알루미늄, 구리 및 텅스텐 등과 같은 금속으로 형성된다. 금속들 중에 텅스텐은 우수한 스텝 커버리지 특성을 가지므로 반도체 소자의 고집적화에 따라 점점 사용 빈도가 높아지고 있다. In semiconductor devices, plugs and wirings are made of metals such as aluminum, copper, tungsten, and the like having low resistance. Among the metals, tungsten has excellent step coverage characteristics, and thus the frequency of use of tungsten increases with increasing integration of semiconductor devices.
또한 텅스텐은 융점이 3400℃ 이상으로 매우 높아 내열성이 좋으며 전자이동(Electro-migration)에 대한 저항이 매우 큰 장점을 갖는다.In addition, tungsten has a very high melting point of more than 3400 ℃ good heat resistance and has a very large resistance to electro-migration (Electro-migration).
반도체 소자에서 텅스텐막을 형성하는 방법은 화학기상증착(Chemical Vapor Deposition, CVD) 방법 또는 원자박막증착(Atomic Layer Deposition, ALD) 방법 등이 있다.A method of forming a tungsten film in a semiconductor device includes a chemical vapor deposition (CVD) method or an atomic layer deposition (ALD) method.
화학기상증착 방법의 경우 반도체 소자의 크기가 작아지면서 점점 작아지는 콘택홀에 텅스텐막을 채우는 것은 매우 어렵다.In the case of the chemical vapor deposition method, it is very difficult to fill a tungsten film in a contact hole that is getting smaller as the size of the semiconductor device becomes smaller.
원자박막증착 방법의 경우 그 자체의 우수한 스텝 커버리지를 갖고 있어서 콘택홀을 충전하는데 매우 유리하나 콘택홀과 트렌치 구조를 채우기에는 그 쓰루풋(throughput)이 작기 때문에 실제 공정에 적용하기에는 어렵다.The atomic thin film deposition method has an excellent step coverage of its own, which is very advantageous for filling contact holes, but its throughput is small for filling contact holes and trench structures, and thus it is difficult to apply to actual processes.
본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 작은 크기의 콘택홀에 텅스텐을 채울 수 있도록 한 텅스텐 막을 이용한 반도체 소자 형성 방법을 제공하는데 그 목적이 있다.The present invention has been made to solve the above problems, and an object thereof is to provide a method of forming a semiconductor device using a tungsten film to fill tungsten in a small contact hole.
상기와 같은 목적을 달성하기 위한 본 발명에 따른 텅스텐 막을 이용한 반도체 소자의 형성 방법은 반도체 기판 상에 절연막을 형성하는 단계와, 상기 절연막을 선택적으로 제거하여 콘택홀 및 트렌치를 형성하는 단계와, 상기 콘택홀 및 상기 트렌치가 형성된 상기 절연막의 전면에 베리어층을 형성하는 단계와, 원자박막 증착 공정을 이용하여 상기 베리어층에 제 1 텅스텐 막을 형성하는 단계와, 화학기상증착 공정을 이용하여 제 1 텅스텐 막에 제 2 텅스텐 막을 형성하는 단계와, 평탄화 공정을 수행하여 상기 콘택홀 및 상기 트렌치 내부에 텅스텐 배선을 형성하는 단계를 포함하여 이루어진 것을 특징으로 한다.A method of forming a semiconductor device using a tungsten film according to the present invention for achieving the above object comprises the steps of forming an insulating film on a semiconductor substrate, selectively removing the insulating film to form contact holes and trenches, Forming a barrier layer on the entire surface of the insulating film on which the contact hole and the trench are formed, forming a first tungsten film on the barrier layer using an atomic thin film deposition process, and using a chemical vapor deposition process; And forming a second tungsten film in the film, and forming a tungsten wire in the contact hole and the trench by performing a planarization process.
상기 제 1 텅스텐 막은 상기 베리어층 상에 1000Å 이하의 두께로 형성되는 것을 특징으로 한다.The first tungsten film is formed on the barrier layer to a thickness of less than 1000Å.
상기 제 1 텅스텐 막은 상기 콘택홀에 채워짐과 아울러 상기 트렌치의 측벽에 형성됨을 특징으로 한다.The first tungsten film is formed on the sidewalls of the trench while being filled in the contact hole.
상기 제 1 텅스텐 막은 상기 제 2 텅스텐 막의 시드층인 것을 특징으로 한다.The first tungsten film is characterized in that the seed layer of the second tungsten film.
상기 제 2 텅스텐 막은 상기 트렌치의 나머지 부분에 형성됨을 특징으로 한다.The second tungsten film is formed in the remaining portion of the trench.
상기 베리어층은 Ti, TiN, Ta, TaN 및 WNx 중 어느 하나의 재질인 것을 특징으로 한다.The barrier layer is characterized in that the material of any one of Ti, TiN, Ta, TaN and WNx.
이하, 첨부된 도면을 참고하여 본 발명에 의한 텅스텐 막을 이용한 반도체 소자의 형성방법을 보다 상세히 설명하면 다음과 같다.Hereinafter, a method of forming a semiconductor device using a tungsten film according to the present invention will be described in detail with reference to the accompanying drawings.
도 1a 내지 도 1d는 본 발명의 실시 예에 따른 텅스텐 막을 이용한 반도체 소자 형성 방법을 단계적으로 나타내는 도면이다.1A to 1D are diagrams illustrating a method of forming a semiconductor device using a tungsten film according to an exemplary embodiment of the present inventive concept.
먼저, 도 1a에 도시된 바와 같이, 반도체 기판(110) 상에 절연막(120)을 형성한 후, 절연막(120)의 표면이 소정부분 노출되도록 듀얼 다마신(dual damascene) 공정에 의해 절연막(120)을 선택적으로 제거하여 콘택홀(122) 및 트렌치(124)를 형성한다. 여기서, 포토 및 식각공정을 이용하여 콘택홀(122)과 트렌치(124)를 각각 형성한다. 이때, 콘택홀(122)을 형성한 후 그 인접영역을 선택적으로 제거하여 트렌치(124)를 형성하거나 트렌치(124)를 형성한 후 트렌치(124) 폭보다 좁게 콘택홀(122)을 형성한다.First, as shown in FIG. 1A, after the
이어, 트렌치(124) 및 콘택홀(122)이 형성된 절연막(120)의 전면에 텅스텐(W) 증착을 위한 베리어층(130)을 형성한다. 이때, 베리어층(130)은 Ti, TiN, Ta, TaN, WNx 등의 재질로 형성된다.Subsequently, a
이어, 도 1b에 도시된 바와 같이, 원자박막증착 공정을 이용하여 콘택홀(122)만을 채우는 것을 목적으로 베리어층(130) 상에 약 1000Å 이하의 두께로 제 1 텅스텐 막(140)을 증착한다. 원자박막증착 공정에 의한 제 1 텅스텐 막(140)의 증착은 소스 가스 공급 공정과, 1차 퍼지 공정과, 환원 가스 공급 공정, 2차 퍼지 공정을 순차 수행하는 증착 사이클을 통하여 원하는 두께의 막이 얻어질 때까지 반복적으로 수행한다. 이때 원자박막증착 공정에 의해서 콘택홀(122) 부분에는 제 1 텅스텐 막(140)이 완전히 채워지게 되고, 트렌치(124) 부분에는 아직 두께가 충분하지 않아 제 1 텅스텐 막(140)이 완전히 채워지지 않은 상태로 증착된다. 또한 원자박막증착 공정은 스텝 커버리지가 매우 좋기 때문에 제 1 텅스텐 막(140)이 트렌치(124)의 측벽(sidewall)에 균일하게 증착된다. 이러한, 제 1 텅스텐 막(140)은 시드층(seed layer)의 역할을 한다.Subsequently, as illustrated in FIG. 1B, the
이어, 도 1c에 도시된 바와 같이, 화학기상증착 공정을 이용하여 트렌 치(124)의 나머지 부분을 채우기 위한 목적으로 제 1 텅스텐 막(140)이 증착된 반도체 기판(110) 상에 제 2 텅스텐 막(150)을 증착한다. 이때, 트렌치(124)의 측벽에는 원자박막증착 공정에 의해 시드층 역할을 하는 제 1 텅스텐 막(140)이 매우 균일하게 증착되어 있으므로, 시드층 역할을 하는 제 1 텅스텐 막(140)에 매우 균일하게 증착된다. 이때, 비록 트렌치(124)라 하더라도 콘택홀(122)보다 좀 더 텅스텐을 채우는데 용이하지만 0.15um급에서는 그 폭이 0.19um 이하이고 두께가 3000Å 이상이므로, 화학기상증착 공정을 이용함으로써 후속 공정인 화학적 기계 연마 공정시 키-홀(key-hole)이 드러나지 않도록 무리 없이 증착할 수 있다.Subsequently, as shown in FIG. 1C, the second tungsten is deposited on the
이어, 도 1d에 도시된 바와 같이, 제 2 텅스텐 막(150)이 형성된 반도체 기판(110)의 전면에 화학적 기계 연마(CMP: Chemical Mechanical Polishing) 공정을 실시하여 트렌치(124) 및 콘택홀(122)의 내부에 텅스텐 배선(152)을 형성하여 완성한다.Subsequently, as illustrated in FIG. 1D, a chemical mechanical polishing (CMP) process is performed on the entire surface of the
그리고 화학적 기계 연막 공정에 의해 유발된 표면결함 및 불순물입자(particle)를 제거하기 위하여 세정공정을 실시한다.In addition, a cleaning process is performed to remove surface defects and impurity particles caused by the chemical mechanical smoke process.
한편, 이상에서 설명한 본 발명은 상술한 실시예 및 첨부된 도면에 한정되는 것이 아니고, 본 발명의 기술적 사상을 벗어나지 않는 범위 내에서 여러 가지 치환, 변형 및 변경이 가능하다는 것이 본 발명이 속하는 기술 분야에서 통상의 지식을 가진 자에게 있어 명백할 것이다.On the other hand, the present invention described above is not limited to the above-described embodiment and the accompanying drawings, it is possible that various substitutions, modifications and changes within the scope without departing from the technical spirit of the present invention It will be apparent to those of ordinary skill in Esau.
이상에서 설명한 바와 같은 본 발명의 실시 예에 따른 텅스텐 막을 이용한 반도체 소자의 형성방법은 다음과 같은 효과가 있다.The method of forming a semiconductor device using a tungsten film according to the embodiment of the present invention as described above has the following effects.
첫째, 작은 크기의 콘택홀에 텅스텐을 채울 수 있다.First, small contact holes can be tungsten-filled.
둘째, 원자박막증착 공정을 트렌치에 텅스텐을 채우기 위한 시드층을 형성하는 공정으로 사용할 수 있다.Second, the atomic thin film deposition process may be used as a process for forming a seed layer for filling tungsten in the trench.
셋째, 원자박막증착 공정의 낮은 쓰루-풋을 작은 크기의 콘택홀에 텅스텐을 채우는데 사용함으로써 필요에 따라서 콘택홀의 크기를 원자박막증착 공정에 맞추어 작게 맞추도록 설계에 반영할 수 있으므로 반도체 소자의 크기를 감소시킬 수 있다.Third, the size of the semiconductor device can be reflected in the design so that the low through-put of the atomic thin film deposition process is used to fill tungsten in the small sized contact hole, so that the size of the contact hole can be made small according to the atomic thin film deposition process if necessary. Can be reduced.
넷째, 원자박막증착 공정과 화학기상증착을 조합하여 균일한 텅스텐 배선을 형성함으로써 후속 공정인 화학적 기계 연막 공정 후 키-홀 또는 보이드(void )/심(seam)에 의한 결함을 완벽히 제거할 수 있다.Fourth, by combining the atomic thin film deposition process and chemical vapor deposition to form a uniform tungsten wiring, defects caused by key-holes or voids / seams can be completely removed after the subsequent chemical mechanical smoke deposition process. .
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