KR20080009585A - A manufacturing method of bathtub - Google Patents
A manufacturing method of bathtub Download PDFInfo
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- KR20080009585A KR20080009585A KR1020060069364A KR20060069364A KR20080009585A KR 20080009585 A KR20080009585 A KR 20080009585A KR 1020060069364 A KR1020060069364 A KR 1020060069364A KR 20060069364 A KR20060069364 A KR 20060069364A KR 20080009585 A KR20080009585 A KR 20080009585A
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- bathtub
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- mixing
- diatomaceous earth
- unsaturated polyester
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K3/00—Baths; Douches; Appurtenances therefor
- A47K3/02—Baths
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/769—Sanitary equipment
- B29L2031/7692—Baths
Abstract
Description
본 발명은 UPR(불포화 폴리에스테르 수지)를 활용한 기능성 욕조에 관한 것으로, 더욱 상세하게는 욕조의 겔 코트시에 규조토 및 이산화 티탄, 음이온석등의 기능성 원료를 겔 코팅제와 함께 에멀젼제와 계면활성제를 첨가하여 코팅되는 코팅층을 조성하고, 주형층은 불포화폴리에스테르수지와 석분 그리고 원적외선을 발산하는 황토가 혼합된 주형물을 경화된 코팅면에 부어 경화시킴으로써 항균, 탈취, 음이온, 원적외선을 방출효과를 도모할 있는 환경친화적인 기능성 욕조에 관한 것이다.The present invention relates to a functional bath utilizing UPR (unsaturated polyester resin), and more particularly, a functional raw material such as diatomaceous earth, titanium dioxide, and anionic stone may be used together with a gel coating agent to form an emulsion and a surfactant. The coating layer is added to form a coating layer, and the mold layer pours and cures a mold mixed with unsaturated polyester resin, stone powder, and ocher emitting far infrared rays on the cured coating surface, thereby releasing antibacterial, deodorizing, anion and far infrared rays. It is about environmentally friendly functional bathtub.
일반적으로 욕조는 내부에 물을 채운 후에 몸을 담가 몸을 씻는 기능으로 사용되며, 기타 목적, 용도 및 기능에 따라 다양한 크기와 형태로 사용되고, 사용된 재료에 따라서 친환경 제품으로도 사용되고 있다.In general, the bathtub is used as a function to wash the body by filling the body with water after filling the inside, it is used in various sizes and forms according to other purposes, uses and functions, and is also used as an eco-friendly product depending on the materials used.
최근 친환경욕조는 두 가지의 타입으로 생산되고 있다.Recently, eco-friendly bathtubs are produced in two types.
첫번째는 월풀이나 스파등 시스템을 활용한 환경친화적인 기능성 욕조이며, 두번째는 친환경 재료를 사용하여 만든 환경친화적인 기능성 욕조로 이루어지고 있다. The first is an eco-friendly functional bathtub using a system such as a whirlpool or a spa, and the second is an eco-friendly functional bathtub made of eco-friendly materials.
종래의 욕조는 마불 또는 FRP제 욕조가 주로 제조되고 있었으나 제법의 특수성으로 인해 수작업의 의존도가 높아 생산성이 떨어지는 문제점이 있고, 제품 자체의 강도와 내구성이 비교적 낮고 질감과 색상도 고급스럽지 못한 결점이 있었다.Conventional bathtubs are mainly made of Mabul or FRP bathtubs, but due to the specificity of the manufacturing method, there is a problem that the productivity is low due to the dependence of manual labor, and the strength and durability of the product itself is relatively low, and the texture and color are not as luxurious. .
그리고 이러한 제품들은 주로 일반적인 겔 코트로 인해 시간이 지남에 따라 표면이 약화되고 때가 쉽게 생기고 세척성이 떨어지는 점이 있었다.In addition, these products were mainly due to the general gel coat, over time, the surface was weakened, the time is easily generated and the washability is poor.
그리고 환경친화적인 기능성 욕조 적용기술 부분에서는 단지 코팅면 보다는 주형층에 기능성 원료를 혼합하여 성형하는 경우가 대부분이고 겔 코트한 코팅면에 친환경 소재를 적용하더라도 친환경 소재가 제대로 도포되지 않거나 표면으로 나오는 현상이나 내탕성이 떨어지는 단점이 있다.In the environmentally friendly functional bath application technology, the functional material is mostly mixed with the mold layer rather than the coating surface, and even if the eco-friendly material is applied to the gel-coated surface, the eco-friendly material is not applied properly or comes to the surface. It also has the disadvantage of poor water resistance.
상기한 종래의 문제점을 해소하고자 본 발명은 규조토, 음이온, 이산화티탄, 황토 등의 기능성 원료를 중심으로 활용한 욕조를 제조하여 기존의 은 나노 제품에 비하여 더욱더 기능이 향상된 환경친화적인 기능성 욕조를 제공하는 것을 그 목적으로 하고 있다.In order to solve the above problems, the present invention provides an environment-friendly functional bathtub, which is more functionally improved than conventional silver nano products by manufacturing a bathtub utilizing a functional material such as diatomaceous earth, anion, titanium dioxide, and ocher. The purpose is to.
이를 위해서, 본 발명에서는 기존의 불포화폴리에스테르 수지 올소 타입과 이소 타입중 이소타입이 주로 쓰였는데 이것을 이소타입과 아크릴 타입을 혼합하여 내구성 및 강도 품질을 향상시킨 수지를 사용하고, 기존의 은나노와 같은 효과를 낼 수 있는 규조토는 과거 흡수제, 여과제로 주로 사용되어 왔지만 현재에 이르면서 다공성을 활용하여 다양한 방면으로 응용된고 있다. To this end, in the present invention, the isotype of the conventional unsaturated polyester resin olso type and iso type was mainly used, and this resin is mixed with the isotype and acrylic type to improve the durability and strength quality, and the same Diatomaceous earth, which can make an effect, has been used mainly as an absorbent and a filter agent in the past, but has been applied to various aspects by utilizing porosity.
이러한 규조토와 음이온석, 이산화 티탄 등의 기능성 원료를 사용하여 살균, 항균, 탈취 등의 특성을 부여하고, 또한 겔코트 수지와 혼합할 때 재료 분리현상의 문제점을 해결하기 위하여 에멀젼화제와 계면활성제를 이용하여 에멀젼 현상을 유도하여 경화시켜 표면에 효과적으로 코팅이 됨으로써 전체적으로 기능성을 나타나도록 하였다.Functional ingredients such as diatomaceous earth, anionic stone and titanium dioxide are used to impart disinfection, antibacterial and deodorization properties, and also to add emulsifiers and surfactants to solve the problem of material separation when mixed with gel coat resin. The emulsion phenomenon was used to induce and harden to effectively coat the surface to show overall functionality.
또한 황토라는 천연 기능성 물질을 주형층에 불포화폴리에스테르수지와 석분(Al(OH)3+ SiO2)과 함께 혼합하여 기존의 물 온도를 적정선에서 오랫동안 유지시킬 수 있게하고, 원적외선을 통하여 피로를 풀어 줄 수 있는 환경친화적인 기능성 욕조를 제공하고자 한다.In addition, natural functional materials called ocher are mixed with unsaturated polyester resin and stone powder (Al (OH) 3 + SiO 2 ) in the mold layer to maintain the existing water temperature for a long time in a proper line, and to release fatigue through far infrared rays An environmentally friendly functional bathtub is provided.
상기한 목적에 따라 본 발명은 욕조 표면을 겔 코트 하는 것에 있어서, 규조토 2~3%, 음이온석 2~3%, 이산화티탄 2~3%, 불포화 폴리에스테르수지 91~94%를 혼합하고, 여기에 분산제와 첨가제를 각각 1~10%에서 투입한 후 교반기로 혼합 믹싱하여 욕조 표면에 균일하게 겔 코트되는 코팅층을 조성하며, 상기 불포화에스테르수지는 이소타입과 아크릴타입을 2:1 비율로 혼합하여 사용하고, 상기 규조토와 불포화에스테르수지 혼합시 규조토의 균일한 분산을 위해 에멀젼제와 계면활성제를 1~3% 넣어서 분산시키고, 상기 겔코팅제는 0.2~0.4mm 두께로 표면 코팅하는 것을 특징으로 하는 환경친화적인 기능성 욕조 제조방법을 제공한다.According to the above object, in the present invention, in the gel coat of the bath surface, 2 to 3% of diatomaceous earth, 2 to 3% of anionite, 2 to 3% of titanium dioxide, 91 to 94% of unsaturated polyester resin are mixed, and 1 to 10% of a dispersant and an additive were added to each other, followed by mixing and mixing with a stirrer to form a coating layer uniformly gel-coated on the surface of the bath. The unsaturated ester resin was mixed with an isotype and an acryl type in a 2: 1 ratio. In the case of mixing the diatomaceous earth and unsaturated ester resin, dispersing by adding 1 ~ 3% of an emulsifier and a surfactant for uniform dispersion of diatomaceous earth, the gel coating agent is characterized in that the surface coating to 0.2 ~ 0.4mm thickness It provides a friendly functional bathtub manufacturing method.
또한, 본 발명은 상기한 방법으로 겔 코팅후 경화된 코팅면에 불포화 폴리에스테르 수지액 55~70%중량부, 석분 15~30%중량부, 황토 15~20%중량부로 혼합한 후 진공믹서를 이용하여 콤파운드 내의 공기를 제거한 주형물을 이용하여 균일하게 도포되는 주형층을 조성하고, 상기 주형층 두께는 10~15mm인 것을 특징으로 하는 환경친화적인 환경친화적인 기능성 욕조 제조방법을 제공한다.In addition, the present invention is a vacuum mixer after mixing 55 to 70% by weight of unsaturated polyester resin solution, 15 to 30% by weight of stone powder, 15 to 20% by weight of ocher on the coating surface cured after gel coating by the method described above. It provides a mold layer that is uniformly applied by using a mold removed air in the compound, the thickness of the mold layer is 10 ~ 15mm provides an environmentally friendly environmentally friendly functional bath manufacturing method.
이와 같이 본 발명은 효과적인 기능성을 부여하기 위하여 코팅면에 인체에 유해한 화학물질 사용을 줄이면서 자연 친화적인 원료인 규조토와 음이온석을 일정량의 분산제와 첨가물이 혼합되는 표면 코팅제를 제조하여 코팅층을 조성한다.As such, the present invention prepares a coating layer by preparing a surface coating agent in which a predetermined amount of dispersant and additives are mixed with diatomaceous earth and anionite, which are natural friendly raw materials, while reducing the use of chemicals harmful to the human body on the coating surface in order to provide effective functionality. .
상기 코팅층에 도포되는 주형물은 원적외선이 방출되며 외관상 자연적인 느낌을 주는 황토를 활용하여 석분을 적정 비율로 혼합하여 불포화에스테르수지를 진공 혼합한 주형물을 부어 경화시키는 주형층을 조성한다. The mold applied to the coating layer is a far-infrared ray is emitted and by utilizing the ocher to give a natural feeling in appearance by mixing the stone powder in an appropriate ratio to form a mold layer to pour the mold mixed with vacuum unsaturated unsaturated resin.
따라서 본 발명은 규조토, 음이온, 이산화티탄을 겔 코트 수지와 함께 분산제를 첨가하여 표면에 균일하게 도포하여 기능성을 향상시키고, 황토와 불포화에스테르수지와 석분과 혼합하여 주형층을 성형할 수 있게 된다.Therefore, in the present invention, diatomaceous earth, anion, and titanium dioxide are added together with a dispersing agent together with a gel coat resin to uniformly apply the surface to improve functionality, and the mold layer can be formed by mixing with yellow clay, unsaturated ester resin and stone powder.
본 발명에 이용되는 규조토는 주로 규조의 유해로 된 연질의 암석 또는 토양으로 해수에서 생성되는 것과 담수성의 것이 있으며 양질의 것은 이산화규소 SiO2를 90% 이상 함유하고 있다. 상기 규조토는 일반적으로 50~100마이크로 정도의 크기를 가지지만 겔코트을 위해서 제트밀을 사용하여 20마이크로 정도의 작은 입자로 분쇄하여 사용한다. Diatomaceous earth used in the present invention is a soft rock or soil that is mainly harmful to diatoms, and is produced in seawater and has fresh water. The high quality one contains more than 90% of silicon dioxide SiO2. The diatomaceous earth generally has a size of about 50 to 100 micrometers, but is used by pulverizing to 20 micrometers of small particles using a jet mill for gel coat.
음이온석은 일반에게 잘 알려지지 않은 모나자이트를 사용하고. 모나자이트는 음이온이 발생되는 천연 광물로서 Ce같은 희토류 원소의 방사능 물질이 들어 있어 주변에 있는 공기의 산소분자를 이온화시켜서 음이온이 발생한다.The anion stone uses monazite, which is not well known to the general public. Monazite is a natural mineral that generates negative ions and contains radioactive materials of rare earth elements such as Ce, which ionize oxygen molecules in the surrounding air to generate negative ions.
불포화폴리에스테르는 불포화 다염기산 또는 그 무수물을 필수 성분으로서 함유하는 다염기산 성분과 다가 알콜 중 축합 반응시켜 제조되는 불포화폴리에스테르수지를 이용하되, 이소타입과 아크릴타입을 혼합하여 기존 제품의 내구성 및 경도를 강화하여 사용한다.Unsaturated polyester is a polybasic acid component containing unsaturated polybasic acid or its anhydride as an essential component and unsaturated polyester resin prepared by condensation reaction in polyhydric alcohol, but isotype and acrylic type are mixed to enhance durability and hardness of existing products. Use it.
본 발명에서 바람직한 폴리에스테르의 수평균 분자량(Mn)은 1,200~4600의 범위인 것이다. 수평균 분자량이 1200보다 낮으면 증점제를 적량 첨가하여도 점도가 증가되지 않고, 수평균 분자량이 4,600보다 크면 점도가 높아지고, 보강재인 유리 섬유에 함침 불량을 일으키기 쉬우며 성형 후 표면 광택성이 저하되는 경향이 있다.The number average molecular weight (Mn) of polyester preferable in this invention is a thing of 1,200-4600. If the number average molecular weight is lower than 1200, the viscosity does not increase even when a suitable amount of thickener is added, and if the number average molecular weight is higher than 4,600, the viscosity is high, and it is easy to cause impregnation impregnation in the glass fiber as a reinforcing material, and the surface glossiness is reduced after molding. There is a tendency.
또한 희석된 불포화에스테르수지는 통상, 열과 압력 하에서 상기 불포화에스테르수지의 경화반응을 시작하게 하는 경화제와 촉진제가 첨가, 함유된다. 상기 경화제로서는 MEKPO이며 촉진제로는 CO로서 그 사용량은 성형재료의 보존성과 성형 사이클 면에서 상기 불포화 폴리에스테르에 대하여 1~6%의 경화제와 0.5~3%의 촉진제가 첨가된다.In addition, the diluted unsaturated ester resin usually contains and contains a curing agent and an accelerator for starting the curing reaction of the unsaturated ester resin under heat and pressure. The curing agent is MEKPO, and the accelerator is CO. The amount of the curing agent is 1 to 6% of the curing agent and 0.5 to 3% of the accelerator in terms of the preservation of the molding material and the molding cycle.
본 발명은 이러한 재료를 활용하여 코팅면과 주형층으로 구성되며, 코팅면은 불포화 폴리에스테르 수지에 규조토, 음이온석, 이산화티탄을 혼합하여 믹싱을 하고 표면에 균일하게 겔 코트 시공을 하였다. 경화된 후 그 코팅면에 불포화 폴리에스테르 수지와 황토를 균일하게 진공 혼합한 주형물을 부어 경화되는 주형층을 조성한다.The present invention is composed of a coating surface and a mold layer by using such a material, the coating surface was mixed by mixing diatomaceous earth, anion stone, titanium dioxide in unsaturated polyester resin and uniformly gel-coated on the surface. After curing, the casting layer is poured into the coating surface of the unsaturated polyester resin and the ocher uniformly to form a mold layer to be cured.
본 발명에서 사용되는 재료의 정의 및 특성은 다음과 같다.Definitions and properties of materials used in the present invention are as follows.
이하, 본 발명에 대한 실시 예를 설명한다.Hereinafter, embodiments of the present invention will be described.
본 발명은 표면층을 규조토와 음이온 및 이산화티탄을 활용하여 분산제와 함께 5분정도 고속 교반하고, 0.2~0.4mm 두께로 표면 코팅후 황토와 석분이 혼합되어 있는 주형물을 부어 욕조를 제조한다.The present invention uses a diatomaceous earth, anion and titanium dioxide, and stirred for about 5 minutes at high speed with a dispersant, the surface coating to a thickness of 0.2 ~ 0.4mm and pour the mold mixed with ocher and stone powder to prepare a bath.
따라서 본 발명은 규조토와 음이온 및 이산화티탄을 활용하여 욕조표면에 코팅하고, 주성형층에 황토를 혼합하여 탈취율이 최대 90%이상 음이온은 600~700개 이상 발생하는 원적외선을 방사하게 된다.Therefore, the present invention is coated on the surface of the bath using diatomaceous earth, anion and titanium dioxide, and by admixing ocher to the main molding layer, the deodorization rate is up to 90% or more, the anion radiates far infrared rays of 600 to 700 or more.
상기 구성처럼 주형층을 구성하는 배합비는 황토:석분:불포화폴리에스테르는 1:1:3 ~ 1:2:4의 비율을 유지할 수 있도록 하는 것이 바람직하다.As described above, the blending ratio constituting the mold layer is preferably such that ocher: stone powder: unsaturated polyester can maintain a ratio of 1: 1: 3 to 1: 2: 4.
이와 같이 본 발명의 UPR(불포화 폴리에스테르 수지)를 활용한 욕조는 겔코팅층에 규조토 및 이산화 티탄, 음이온석등의 기능성 원료를 겔코팅제와 함께 에멀젼제나 계면활성제를 첨가 및 혼합하여 코팅하고, 주형층에는 불포화 폴리에스테르 수지와 석분 그리고 원적외선을 발산하는 황토가 혼합된 주형물을 제조하여 경화된 코팅면에 도포되는 경화층을 조성함으로써 항균, 탈취, 음이온, 원적외선을 방출효과를 도모할 있는 것이다.As described above, the bath using UPR (unsaturated polyester resin) of the present invention is coated with a gel coating layer by adding and mixing an emulsifier or a surfactant with a gel coating agent and a functional raw material such as diatomaceous earth, titanium dioxide, and anionic stone. It is possible to produce antibacterial, deodorant, anion, and far infrared rays by preparing a casting layer containing unsaturated polyester resin, stone powder and loess emitting far infrared rays, and forming a hardened layer applied to the cured coating surface.
이상에서 설명한 바와 같이. 본 발명에 의하면, 환경친화형 환경친화적인 기능성 욕조 제조를 위해서 규조토, 황토, 음이온석, 이산화티탄과 같은 천연광물질을 활용하여 욕실에서 발생되는 유해 물질인 VOC 저감시키고, 욕조내의 항균 효과, 탈취 효과 세척성이 강해지고 실내공기의 청정화하는데 뛰어난 효과를 발휘하는 장점이 있다.As explained above. According to the present invention, by using natural minerals such as diatomaceous earth, ocher, anion stone, titanium dioxide, and the like to reduce the VOCs, which are harmful substances generated in the bathroom, and antibacterial and deodorizing effects in the bathtub for the production of environment-friendly eco-friendly functional bathtubs. There is an advantage that the washability is strong and exerts an excellent effect to clean the indoor air.
또한 본 발명은 음이온석에 의해서 음이온이 발생하고, 욕조의 조성물에 황토가 포함되어서 보온 효과 및 원적외선 방사 효과는 욕조 사용시 몸의 피로를 효과적으로 풀어주게 되므로 일반 욕조보다 더욱더 인체의 유익하면서 웰빙시대에 가장 적합한 친환경적인 기능성 욕조를 제공할 수 있는 효과를 갖는 매우 유용한 발명인 것이다.In addition, the present invention anion is generated by the anion stone, and the thermal composition and far-infrared radiation effect of the ocher is included in the composition of the bath to effectively release the fatigue of the body when using the bathtub is more beneficial to the human body than the general bathtub and well-being era It is a very useful invention having the effect of providing a suitable eco-friendly functional bath.
Claims (6)
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WO2014104498A1 (en) * | 2012-12-26 | 2014-07-03 | 김혁중 | Eco-friendly water-soluble paint composition for interior finishing material of building |
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KR19990073599A (en) * | 1999-07-28 | 1999-10-05 | 강선태 | Bathtub of changing color according to water temperature and method of manupacturing it |
JP2005040427A (en) * | 2003-07-24 | 2005-02-17 | Makku:Kk | Bathtub and manufacturing method thereof |
KR20060020459A (en) * | 2004-08-31 | 2006-03-06 | 주식회사 엔텍 | Yellow earth, ceramics of water tank |
KR20060020457A (en) * | 2004-08-31 | 2006-03-06 | 주식회사 엔텍 | Water tank |
KR200425182Y1 (en) | 2006-04-27 | 2006-09-01 | 김형복 | Bathtub |
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WO2014104498A1 (en) * | 2012-12-26 | 2014-07-03 | 김혁중 | Eco-friendly water-soluble paint composition for interior finishing material of building |
JP2015519408A (en) * | 2012-12-26 | 2015-07-09 | サン ジョン,ミン | Environmentally-friendly water-based paint composition for interior finishing materials of buildings |
US9249312B2 (en) * | 2012-12-26 | 2016-02-02 | Hyeok Jung Kim | Eco-friendly water-based paint composition for interior finishing materials of buildings |
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