KR20080001328A - Al-alloy for forging - Google Patents

Al-alloy for forging Download PDF

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KR20080001328A
KR20080001328A KR1020060059689A KR20060059689A KR20080001328A KR 20080001328 A KR20080001328 A KR 20080001328A KR 1020060059689 A KR1020060059689 A KR 1020060059689A KR 20060059689 A KR20060059689 A KR 20060059689A KR 20080001328 A KR20080001328 A KR 20080001328A
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weight
alloy
forging
aluminum alloy
aluminum
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KR1020060059689A
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Korean (ko)
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이원의
박희석
정태인
김준현
서영명
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(주)알루텍
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/10Alloys containing non-metals
    • C22C1/1036Alloys containing non-metals starting from a melt
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Forging (AREA)

Abstract

A method for manufacturing a forging aluminum alloy is provided to improve forging efficiency of an aluminum-magnesium alloy and to cut down a cost by increasing productivity of the forging aluminum alloy. A method for manufacturing a forging aluminum alloy includes a casting process, a leveling process, and a cooling process. The leveling process is performed at 470~490 degrees for 10~14 hours. The aluminum alloy is formed by 2.8~3.0 weight% of magnesium, under 0.03 weight% of silicon, under 0.03 weight% of iron, 0.07~0.08 weight% of copper, 0.018~0.022 weight% of titanium, 0.01 weight% of each inevitable element, and extra aluminum. The cooling process is performed at cooling speed over 200 degrees per hour to prevent a solidified compound from being precipitated.

Description

단조용 알루미늄 합금의 제조 방법{Al-alloy for forging}Manufacturing method of forging aluminum alloy {Al-alloy for forging}

도 1은 균질화 처리 온도와 경도의 상관 관계 그래프.1 is a correlation graph of homogenization treatment temperature and hardness.

본 발명은, 단조성이 우수하여 자동차용 경량화 부품 소재로 최적화한 Al-Mg 계 알루미늄 합금에 관한 것이다.The present invention relates to an Al-Mg-based aluminum alloy that is excellent in forging properties and optimized as a lightweight component material for automobiles.

알루미늄은, 철강 다음으로 많이 사용되고 있는 금속으로서, 가볍고 내식성과 가공성이 좋으며 전기 및 열 전도도가 높을 뿐 아니라 Cu, Mg, Si, Zn, Mn, Ni 등의 원소와 다양한 종류의 고강도, 고내식성 합금을 만들어 항공기, 가정용품, 건축, 차량, 기계, 전기 등 가정과 산업 전분야에 걸쳐 사용되고 있다.Aluminum is the second most used metal after steel, and it is lightweight, has good corrosion resistance and workability, and has high electrical and thermal conductivity. It also contains elements such as Cu, Mg, Si, Zn, Mn, and Ni, and various kinds of high strength and high corrosion resistance alloys. It is used throughout the home and industry fields such as aircraft, household goods, construction, vehicles, machinery, and electricity.

상기와 같은 알루미늄은 함금의 종류에 따라 분류되는 바, 1000번대는 99.00wt% 이상의 알루미늄을 함유한 순수 알루미늄, 2000번대는 Al-Cu계 합금, 3000번대는 Al-Mn계 합금, 4000번대는 Al-Si게 합금, 5000번대는 Al-Mg계 합금, 6000번대는 Al-Mg-Si계 합금, 7000번대는 Al-Zn계 합금으로 분류, 표시하는 방법이 널리 사용되고 있다.The aluminum is classified according to the type of alloy, bar 1000 is pure aluminum containing more than 99.00wt% aluminum, 2000 is Al-Cu alloy, 3000 is Al-Mn alloy, 4000 is Al It is widely used to classify and mark Si-alloy alloys, Al-Mg-based alloys for No. 5000, Al-Mg-Si-based alloys for No. 6000, and Al-Zn-based alloys for No. 7000.

상기와 같이 분류되는 알루미늄 합금의 가장 큰 장점은 철강에 비하여 그 무게는 약 1/3 정도이나, 각종 합금원소의 첨가에 따라 철강에 비하여 뒤지지 않거나 더욱 우수한 기계적 성질을 갖는다는 점으로서, 특히, 근래에 들어 자동차 부품에 적용되고 있는 비율이 증가하고 있다.The greatest advantage of the aluminum alloys classified as above is that the weight is about one third of that of steel, but it does not lag behind or have better mechanical properties than steel depending on the addition of various alloying elements. For example, the proportion applied to auto parts is increasing.

자동차는 현대 문명을 이루고 있는 가장 기본적인 요소인 운송 수단으로서 많은 발전을 거듭해 왔으며, 자동차가 없는 현대 문명은 존재할 수 없는 정도이나, 자동차의 배출가스는 지구 온난화에 지대한 영향을 미치고 있으며, 대기 오염의 주범들 중 하나로서, 자동차 배출가스를 감소시키기 위한 각종 규제가 시행되거나 준비 중에 있다.Automobiles have evolved as a means of transportation, the most basic element of modern civilization, and modern civilization without automobiles cannot exist, but the emissions of automobiles have a great influence on global warming and are the main culprit of air pollution. Among them, various regulations are being implemented or in preparation for reducing automobile emissions.

따라서, 자동차 메이커는 전기, 연료전지, 수소 등을 에너지원으로 사용하는 자동차 또는 화석연료와 전기를 병행하여 사용하는 하이브리드 자동차 등을 개발하고 있으며, 그들 중 일부는 현재 시판되고 있기도 하다.Accordingly, car makers are developing automobiles using electricity, fuel cells, hydrogen, etc. as energy sources, or hybrid vehicles using fossil fuels and electricity in parallel, and some of them are currently on the market.

그러나, 상기와 같이 공해 배출이 없거나 극히 적은 자동차가 보편화되기 위해서는 여전히 많은 시간을 필요로 하는 바, 그 중간 단계로서, 자동차의 경량화에 의한 연비의 향상을 통하여 배출가스를 감소시키기 위하여 각종 자동차 부품을 철강에서 알루미늄으로 대체해 나가고 있다.However, as described above, many vehicles are still required to have no pollution emission or very few automobiles, and as an intermediate step, various automobile parts may be used to reduce emissions through improved fuel efficiency due to lighter weight of automobiles. It is replacing steel with aluminum.

상기와 같은 자동차 경량화 요구에 따라 자동차 부품은 주로 저압주조 방식으로 제조하였으나, 단조용 알루미늄을 사용하게 되면, 저압주조 방식에 의해 제조된 것보다 강도가 강한 알루미늄 부품을 제조할 수 있다.According to the above-mentioned demand for lightening automobiles, auto parts are mainly manufactured by a low pressure casting method. However, when forging aluminum is used, an aluminum part having a stronger strength than that produced by the low pressure casting method may be manufactured.

즉, 저압주조에서는 주로 Al-Si 계 다이캐스팅용 알루미늄 합금이 주로 사용되었으며, Si 첨가량의 범위가 크기 때문에 유동성과 용탕 충진이 용이한 합금이나 주조균열이 적은 합금을 Si 함량을 조절하여 선택적으로 제조할 수 있었다.In other words, Al-Si die casting aluminum alloys were mainly used in low pressure casting.Since the range of Si addition amount is large, alloys with easy flowability and melt filling or alloys with low casting crack can be selectively manufactured by controlling the Si content. Could.

그러나, 상기 기존의 저압주조 방식으로는 소재 회수율이 낮고 후공정 비용이 높은 단점이 있으며, 저압주조로 제조된 Al-Si 계 합금은 중량이 무겁기 때문에 자동차 경량화에 기여하지 못하는 단점이 있다.However, the conventional low pressure casting method has a disadvantage in that the material recovery rate is low and the post-process cost is high, and the Al-Si-based alloy manufactured by the low pressure casting has a disadvantage in that it does not contribute to the weight reduction of the automobile.

본 발명은 상기와 같은 종래의 저압주조용 알루미늄 합금이 가지고 있는 제반 문제점들을 해결하기 위하여 창안된 것으로, 전신용 합금인 Al-Mg계 합금의 단조성을 향상시키고, 단조성 향상으로 인해 생산성을 높이면서 원가를 절감할 수 있으며, 특히, 자동차 경량화 부품인 알루미늄 휠 등에 사용할 수 있도록 단조성이 우수한 알루미늄 합금의 제조 방법을 제공하는데 그 목적이 있다.The present invention was devised to solve all the problems of the conventional low-pressure casting aluminum alloy as described above, to improve the forgeability of the Al-Mg-based alloy of the whole-body alloy, and to increase the productivity by improving the forgeability The purpose of the present invention is to provide a method of manufacturing an aluminum alloy having excellent forging ability to be used, for example, an aluminum wheel, which is an automobile light weight component.

본 발명의 상기 목적은, 합금 성분들 중 Mg, Si, Fe, Cu 및 Ti 함량의 제어와, 주조 후의 균질화 처리에 의하여 달성된다.The above object of the present invention is achieved by controlling the Mg, Si, Fe, Cu and Ti content of the alloying components and the homogenization treatment after casting.

본 발명 단조용 알루미늄 합금의 제조 방법은, 주조 단계와 균질화 처리 단계 및 냉각 단계 등의 순차적인 공정들로 이루어지는 바, 균질화 처리 온도를 470∼490 ℃에서 10∼14 시간동안 실시함에 본 발명의 기술적 특징이 있으며, 상기의 균질화 처리에 의해 우수한 단조성을 가질 수 있도록 합금의 조성을 다음과 같이 제한하여야만 한다.The method of manufacturing the forging aluminum alloy of the present invention comprises a sequential process such as a casting step, a homogenization treatment step, and a cooling step, and the homogenization treatment temperature is performed at 470 to 490 ° C. for 10 to 14 hours. There is a characteristic, and the composition of the alloy should be limited as follows to have excellent forging property by the homogenization treatment.

즉, 본 발명 방법에 의한 알루미늄 합금은, Mg 2.8∼3.0중량%, Si 0.03중량% 이하, Fe 0.03중량% 이하, Cu 0.07∼0.08중량%, Ti 0.018∼0.022중량%, 기타 불가피한 각 성분 0.01중량% 이하 및 잔량의 Al으로 조성되는데, 상기와 같이 각 성분의 함량을 한정한 이유는 다음과 같다.That is, the aluminum alloy according to the method of the present invention, Mg 2.8 to 3.0% by weight, Si 0.03% by weight or less, Fe 0.03% by weight or less, Cu 0.07 to 0.08% by weight, Ti 0.018 to 0.022% by weight, 0.01% of other unavoidable components 0.01% It is composed of% or less and the residual amount of Al, and the reason for limiting the content of each component as described above is as follows.

Mg는, 고용강화 원소로서, 함량이 2.8중량%에 미치지 못하면 그 효과가 미미하고, Mg 함량이 증가하면서 열간 가공 하에서의 변형저항이 높아져 가공이 어렵게 되닌데, 그 함량이 3중량%를 초과하게 되면 저온 열처리 또는 고온에서의 냉각시 Mg2Al3가 석출하면서 기게적 특성치를 저하시키게 될 뿐 아니라, 과잉의 Mg가 Mg2Si의 고용도를 떨어뜨려 적절한 균질도를 얻을 수 없게 된다.Mg is a solid solution strengthening element. If the content is less than 2.8% by weight, its effect is insignificant, and as the Mg content increases, the deformation resistance under hot processing becomes high, making it difficult to process. When the content exceeds 3% by weight, Mg 2 Al 3 precipitates during the low temperature heat treatment or cooling at high temperature, thereby lowering the mechanical characteristic value, and excessive Mg decreases the solid solubility of Mg 2 Si so that an appropriate homogeneity cannot be obtained.

Si는, Mg와 결합하여 시효에 의해 Mg2Si로 석출되어 기계적 성질을 좌우하며, Mg와 결합하고 남은 잔류 Si는 단독으로 석출되어 기계적 성질을 향상시키고, 용탕의 유동성 개선에 유효한 성분이나, 0.03중량%를 초과하게 되면, Mg2Si를 형성하면서 강도를 필요 이상으로 상승시키면서 인성을 떨어뜨려 단조성에 악영향을 미치게 된다.Si is combined with Mg and precipitated as Mg 2 Si by aging to influence the mechanical properties, and the remaining Si combined with Mg is precipitated alone to improve the mechanical properties and effective for improving the fluidity of the melt, but 0.03 When the weight percentage is exceeded, toughness is lowered while increasing the strength more than necessary while forming Mg 2 Si, which adversely affects forging properties.

Fe는, 재결정립의 조대화를 억제하고 주조시 결정립을 미세화하는데 효과가 있으나, 0.03중량%를 초과하게 되면 불순물로서 작용할 뿐 합금화 효과가 미미하면서 연성을 저하시킬 뿐 아니라 도전율을 떨어뜨리는 동시에 Al의 접촉 부식을 촉진 하게 된다. 또한, AlFeSi 화합물을 형성하여, 열간가공성을 떨어뜨려 금형의 마모를 촉지하게 된다.Fe is effective in suppressing coarsening of recrystallized grains and miniaturizing grains in casting, but when it exceeds 0.03% by weight, Fe acts as an impurity, while alloying effects are insignificant, and ductility is reduced. It will promote contact corrosion. In addition, the AlFeSi compound is formed, which degrades the hot workability and promotes wear of the mold.

Cu는, Al-Mg계 합금의 응력부식균열을 억제하는 목적으로 첨가되는 성분으로서, 그 함량이 0.07중량%에 미치지 못하면 그 효과가 미미하나, 0.08중량%를 초과하게 되면 경도를 필요 이상으로 상승시켜 가공성을 떨어뜨리게 된다.Cu is a component added for the purpose of suppressing the stress corrosion cracking of Al-Mg alloy. If the content is less than 0.07% by weight, the effect is insignificant, but when it exceeds 0.08% by weight, the hardness is increased more than necessary. The workability will be reduced.

Ti는, 결입립 미세화에 효과가 있는 성분으로서, 0.018중량%에 미치지 못하면 첨가 효과를 얻을 수 없고, 0.022중량%를 초과하게 되면 가공성을 떨어뜨리게 된다.Ti is a component that is effective for fine graining, and when it is less than 0.018% by weight, the effect of addition cannot be obtained. When Ti exceeds 0.022% by weight, the workability is deteriorated.

그리고, 상기와 같은 조성의 알루미늄 합금을 주조한 후 규질화 처리를 실시하게 되는데, 균질화 처리시 그 온도가 470℃에 미치지 못하는 경우에는 합금 표면과 내부 조직 사이의 불균일성이 커지게 되면서 단조성이 떨어지게 되며, 490℃를 초과하게 되면 합금 내부의 저융점 화합물이 국부적으로 용해되면서 주조된 형상의 원형이 유지되지 못하게 될 수 있다.And, after casting the aluminum alloy of the composition as described above is subjected to silicidation treatment, if the temperature does not reach 470 ℃ during the homogenization treatment, the nonuniformity between the alloy surface and the internal structure becomes large and the forging is inferior When the temperature exceeds 490 ° C., the low melting point compound in the alloy may be locally dissolved, thereby preventing the original shape of the cast shape from being maintained.

또한, 고온 산화에 의해 합금 표면에 두꺼운 산화층이 형성되면서 단조성은 물론 표면 품질 저하가 초래될 수 있으며, 제조 원가가 상승된다.    In addition, as a thick oxide layer is formed on the surface of the alloy by high temperature oxidation, forging property as well as surface quality deterioration may be caused, and manufacturing cost is increased.

균질화 처리의 다른 변수인 균질 시간의 경우, 10시간에 미치지 못하면 충분한 균질화 조직을 얻을 수 없으며, 14시간을 초과하는 경우에는 불필요한 에너지 소모에 의해 제조 원가가 상승된다. 특히, 최소 시간에 미치지 못하는 경우, 합금 성분의 불균일로 인해 편석 및 역편석 층이 존재하게 되면서 가공성에 악영향을 미치게 된다.In the case of homogeneous time, another variable of the homogenization treatment, if it does not reach 10 hours, sufficient homogenized tissue cannot be obtained, and if it exceeds 14 hours, the manufacturing cost is increased by unnecessary energy consumption. In particular, when less than the minimum time, the non-uniformity of the alloying components will result in the presence of segregation and reverse segregation layer adversely affects the workability.

최종 단계인 냉각은 가능한 급랭이 바람직한데, 이는 기지내에 고용된 화합물들이 냉각 과정에서 석출되는 것을 방지하기 위한 것으로, 200℃/hr 이상의 냉각 속도가 바람직하다.Cooling, which is the final step, is preferably possible because of quenching, which is to prevent precipitation of compounds dissolved in the matrix during the cooling process.

상기와 같은 방법으로 제조된 알루미늄 합금의 특성을 다음의 실시예로서 살펴보기로 한다.The characteristics of the aluminum alloy manufactured by the above method will be described as follows.

실시예Example

에어 슬립법으로 빌렛트를 제조하였는 바, 그 조성 및 제조 조건은 각각 다음의 표 1 및 표 2와 같다.Since the billet was manufactured by the air slip method, its composition and production conditions are as shown in Table 1 and Table 2, respectively.

구 분  division 합금 번호Alloy number 성분 함량 (중량%)                     Ingredient Content (wt%) Cu  Cu Si  Si Fe  Fe Mn  Mn Mg  Mg Zn  Zn Cr  Cr Ti  Ti Ni  Ni 비 교 예   Comparative Example 1  One 0.0800.080 0.0500.050 0.1730.173 0.0110.011 2.9052.905 0.0140.014 0.0210.021 0.0490.049 -- 2  2 0.0790.079 0.0490.049 0.1420.142 0.0110.011 2.9892.989 0.0190.019 0.0160.016 0.0880.088 -- 3  3 0.0830.083 0.0500.050 0.0760.076 0.0080.008 2.9632.963 0.0110.011 0.0020.002 0.0280.028 -- 4  4 0.2000.200 6.9526.952 0.1850.185 0.0860.086 0.3100.310 -- -- 0.1250.125 0.0240.024 실시예 Example 5  5 0.0700.070 0.0200.020 0.0400.040 0.0010.001 2.9502.950 0.0020.002 0.0030.003 0.0100.010 --

구 분 division 합금 번호 Alloy number 주조속도 (mm/min)Casting speed (mm / min) 냉각조건Cooling condition 용탕온도 (℃)   Melting temperature (℃) 균질/냉각조건     Homogeneous / cooling condition 냉각수량 (l/min) Cooling water amount (l / min) 냉각수 온 도 (℃)Coolant temperature (℃) 초기Early 정상normal 초기Early 정상normal 홀딩로Holding furnace 분배통Distribution box 온도 (℃) Temperature (℃) 유지 시간Retention time 냉각시간 (hr)Cooling time (hr) 비 교 예  Comparative Example 1  One 50 50 63 63 900 900 22702270 21  21 730 730 715 715 560 560 11.511.5 4   4 2  2 50 50 64 64 700 700 21302130 26  26 745 745 735 735 560 560 1515 4   4 3  3 52 52 64 64 800 800 19001900 21  21 730 730 715 715 540 540 1414 4   4 4  4 - - - - -  - -- -  - -  - -  - -  - - - -   - 실시예Example 5  5 50 50 65 65 750 750 17501750 22  22 700 700 -  - 480 480 1212 4   4

상기 표 2에서 비교예 4는 종래의 저압 주조법으로 제조된 알루미늄 합금의 일반적인 화학성분을 보여주고 있다.Comparative Example 4 in Table 2 shows the general chemical composition of the aluminum alloy prepared by a conventional low pressure casting method.

Al-Mg계 알루미늄 합금의 특성상, 균질화 열처리 온도가 높을수록 재결정 온도가 감소하기 때문에, 단조성을 고려하여, 합금번호 1∼3과 같이 균질화 열처리 온도를 변화하여 실험하였으며, 나머지 주조 조건들은 동일하게 하였다.Due to the characteristics of the Al-Mg-based aluminum alloy, the recrystallization temperature decreases as the homogenization heat treatment temperature increases. Therefore, the homogeneous heat treatment temperature was changed as shown in Alloy Nos. 1 to 3 in consideration of the forging property, and the rest of the casting conditions were the same. .

그리고, 합금번호 1∼3의 실험 결과를 바탕으로 하여 본 발명의 실시예인 합금번호 5의 합금 성분과 주조 조건, 균질화 열처리 조건을 도출하였다.Based on the experimental results of Alloy Nos. 1 to 3, alloy components, casting conditions, and homogenization heat treatment conditions of Alloy No. 5, which are examples of the present invention, were derived.

균질화 열처리 온도를 변화하여 주조된 개량 합금에 대해 경도시험을 하여 측정된 결과를 도 1에 나타내었는 바, 균질화 열처리 온도가 낮을수록 경도가 감소하는 것을 볼 수 있으며, 이러한 결과로 인해 단조 가공시, 단조에 필요한 압력 또한 감소하게 됨을 알 수 있다.As a result of the hardness test for the improved alloy cast by varying the homogenization heat treatment temperature is shown in Figure 1, the lower the homogenization heat treatment temperature can be seen that the hardness decreases. It can be seen that the pressure required for forging is also reduced.

이상에서 살펴본 바와 같이, 본 발명에 의해 제조된 알루미늄 합금은, 종래의 동일계 알루미늄 합금에 비하여 단조성이 향상됨은 물론, 단조성 향상에 의해 생산성을 향상시킴으로써 제조 원가를 절감할 수 있는 장점이 있다.As described above, the aluminum alloy manufactured according to the present invention has advantages in that the forging property is improved as compared with the conventional in situ aluminum alloy, and the manufacturing cost can be reduced by improving productivity by improving the forging property.

Claims (2)

알루미늄 합금을 용융하여 주조하는 단계와;Melting and casting the aluminum alloy; 470∼490℃에서 10∼14 시간동안 균질화 처리하는 단계와;Homogenizing at 470-490 ° C. for 10-14 hours; 200℃/hr 이상의 냉각 속도로 냉각하는 단계를 포함하여 이루어짐을 특징으로 하는 단조용 알루미늄 합금의 제조 방법.Method for producing a forging aluminum alloy comprising the step of cooling at a cooling rate of 200 ℃ / hr or more. 제 1항에 있어서, 상기 알루미늄 합금은, Mg 2.8∼3.0중량%, Si 0.03중량% 이하, Fe 0.03중량% 이하, Cu 0.07∼0.08중량%, Ti 0.018∼0.022중량%, 기타 불가피한 각 성분 0.01중량% 이하 및 잔량의 Al으로 조성됨을 특징으로 하는 단조용 알루미늄 합금의 제조 방법.According to claim 1, The aluminum alloy, Mg 2.8 to 3.0% by weight, Si 0.03% by weight or less, Fe 0.03% by weight or less, Cu 0.07 to 0.08% by weight, Ti 0.018 to 0.022% by weight, 0.01% of other unavoidable components 0.01% A method for producing an aluminum alloy for forging, characterized in that the composition of less than% and the remaining amount of Al.
KR1020060059689A 2006-06-29 2006-06-29 Al-alloy for forging KR20080001328A (en)

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