KR20070068881A - Composition for hairdye using natural plant materials - Google Patents

Abstract

A composition for hair dye by using natural plant materials is provided to reduce side effects including skin irritation caused by chemical hair dye, and improve hair affinity, hair conditioning and dye fastness, so that the hair having an excellent color is safely obtained. The composition for hair dye comprises powder, hot water extract or alcohol extract of at least one natural plant material selected from pine tree(Pinus densiflora), Ginkgo biloba L., Eucommia ulmoides, Acorus calamus var. angustatus, Acanthopanax sessiliflorus, Japanese persimmon, Rubus coreanus, Lycium chinense, Epimedium koreanum, Perilla frutescens Britton var. crispa Decne, Saururus chinensis and Artemisia princeps var. orientalis, wherein the composition further comprises 0.5-3 wt.% of a dye and is formulated as hair dye, shampoo or hair rinse.

Description

Composition for hair dye using natural plant material {Composition for hairdye using natural plant materials}

The present invention relates to a hair dye composition using a natural plant material, and more specifically, pine, ginkgo, cedar, irises, organza, persimmon, bokbunja, wolfberry, yin and yang, perilla, triticale, eoseongcho, wormwood It relates to a composition for hair dye comprising leaves, fruit, stem, root, stem bark or root bark hot water or alcohol extract or powder.

In general, hair dyes may be classified into permanent hair dyes, semi-permanent hair dyes, and temporary hair dyes according to differences in dyeing effects.

Permanent hair dyes are those in which the pigment-forming substance penetrates into the cortex or anhydrous layer inside the hair and may cause chemical changes to form insoluble pigments. Semipermanent hair dyes are those in which the pigment itself penetrates into the cuticle layer of the cortex or hair surface and is physically adsorbed. Temporary hair dyes are also those that physically adsorb the pigment only to the cuticle layer, which is the surface of the hair.

Among these, permanent hair dyes can be further divided into three types: vegetable hair dyes, metallic hair dyes and oxidative hair dyes. Vegetable hair dyes include henna and chamomile, which have a low dyeing effect and are difficult to lightly dye. Metallic hair dyes use the principle of blackening when lead is oxidized. Toxic harmful to humans is rarely used at present. Finally, oxidative hair dyes have excellent dyeing effect, can be dyed in bright colors, and are currently the most widely used.

Oxidative hair dyes comprise the main components of the first and second agents, as shown in Tables 1 and 2 below.

Main ingredients of permanent hair dye (Part 1) division Characteristic Dye intermediates It is not a pigment itself, but a substance that turns into a pigment when oxidized, eg p-phenylenediamine, p-aminophenol, p-toluenediamine Dye modifier Substances that react with dye intermediates to vary color, eg resorcin, m-aminophenol, m-phenylenediamine Alkali It opens the cuticles and allows the pigmentation reaction to occur quickly. Ex) ammonia, monoethanolamine (MEA) Higher fatty acids Reacts with alkaline agents to form higher fatty acid salts. It facilitates the penetration of dye intermediates or dye modifiers and facilitates cleaning on trituration. Gelling agent When mixed with a second agent it forms a gel. Isocetyl alcohol solvent Helps dissolve dye intermediates, dye modifiers. Ex) isopropyl alcohol

Main ingredients of permanent hair dye (Part 2) division Characteristic Oxidant Destroys the melanin pigment in the hair, decolorizing the hair and at the same time reacting the dye intermediates and dye modifiers to make new pigments. pH regulator The pH is adjusted to around 4.0 to stabilize hydrogen peroxide.

However, the dye intermediates and dye modifiers of the diamine-based organic dyes of the main components as described above irritate the skin and bind to the skin cells to act as antigens, such as redness, rash, pruritus, heart margin, inflammation, blisters, etc. It is already known that people with sensitive skin may suffer from contact allergic dermatitis because it causes side effects, namely contact dermatitis. In addition, due to the irritation it is likely to cause side effects such as showing a large side effect on the eyes when entering the eye.

Therefore, in order to improve such a problem, it is recommended to use only a person who is negatively tested by performing a skin patch test before using the hair dye. However, there is a problem in that it is not only cumbersome to carry out the above test whenever it is desired, but also has to spend a lot of time verifying the judgment result. Also, be very careful not to get into eyes.

On the other hand, the applicant has found that it is possible to manufacture a hair dye that can be substituted for the conventional hair dye using the leaves, berries, stems, roots, stem bark and root bark of various plants readily available in Korea, which It has been found that obtained from natural substances can solve the side effects on the skin and the problems of conventional oxidative hair dyes.

An object of the present invention is to solve the conventional problems, to provide a composition for hair dye comprising a natural plant material without side effects.

Specifically, an object of the present invention is pine, ginkgo biloba, cedar, iris, organa or radish, persimmon, bokbunja, wolfberry, umyangcho, perilla, triticale, eoseongcho, wormwood leaves, berries, stems, roots, stem bark Or it provides a composition for hair dye, including the root bark hot water or alcohol extract or powder, a preparation method thereof and its use.

In order to achieve the above object, the present invention provides a composition for hair dye comprising a leaf, fruit, stem, root, stem bark or hot water of the plant material or alcohol extract or powder, a preparation method thereof and use thereof. .

Hereinafter, the present invention will be described in detail.

First, the present invention provides a composition for hair dye comprising a leaf, fruit, stem, root, stem bark or hot water of the plant material or alcohol extract or powder as an active ingredient.

In the present invention, the plant material includes pine, ginkgo biloba, cedar, iris, organo, persimmon, bokbunja, wolfberry, yin and yang, perilla, triticale, eoseongcho, mugwort.

More specifically, pine needles, pine bark, ginkgo biloba, ginkgo bark, cedar leaf, cedar berry, cedar bark, iris leaf, iris stem, iris root, organ leaf, organ leaf, organ bark, persimmon leaf, persimmon, persimmon Blood, Bokbunja leaf, Bokbunja fruit, Bokbunja tree bark, Goji leaf, Goji fruit, Goji tree bark, Yin yang leaf, Yin yang stem, Yin yang root, Leafy leaf, Soja, Perilla perilla, Perilla root, Triticale leaf, Triticale stem, Triticale root, It provides a composition for hair dyes comprising any one or more powders, hot water extracts or alcohol extracts selected from the group consisting of Echo leaf, Echo stem, Echo root, Mugwort, Mugwort and Mugwort as an active ingredient.

The alcohol extract refers to an extract obtained by using an alcohol which can be used for hair dye, shampoo or rinse, wherein the alcohol may be any one or more selected from the group consisting of ethyl alcohol, propyl alcohol, benzyl alcohol and polyalcohol. have.

Pine needles refer to the leaves of pine and pine to the stem or root bark.

Pine tree ( Pinus densiflora ) grows in almost all regions of Korea and is found in a variety of varieties. Other names of pine are yuksong, red pine, yeosong, pine, pine, sol and amsol. Red pine is similar to pine tree, but the name is given because the color of the bark is red compared to Gomsol, which is gray with winter snow, and because the larvae are common in inland, the pine is softer than other varieties. On the other hand, there are such well-known varieties include Geumgang pine tree trunk upright growing (pd for. Erecta), drooping pine branches sagging under the (pd for. Pendula), conveying a lot of things that diverge from the bottom stem (pd for. Multicaulis) .

Ginkgo leaves refer to the leaves of Ginkgo biloba, and ginkgo biloba refers to the stem or root bark of Ginkgo biloba.

Ginkgo is the only living tree in the Ginkgo tree. Peeled and dried seeds are called encyclopaedia (百果), cleans the lungs and stomach, and is effective for Jinhae and expectoration. Careful hulls that surround the seeds have an unpleasant smell and can cause skin irritation. The leaves contain various compounds, especially butyl acid, which is known to act as an insect repellent, and when the leaves are placed in a book, the moths do not eat in the book. Some flavonoids are known to help human blood circulation. .

Cedar leaves are the leaves of cedars, cedars are the fruits of cedars, and cedars are the stems or roots of cedars.

Eucommia ulmoides ) is a deciduous tree belonging to the genus Eucommiaceae . Generally, the bark is planted as a medicine, and the leaves and seeds are dried and used as medicine. In Chinese medicine, the bark of the larvae is commonly called the larvae. The bark of the larvae is generally collected in May-June and is poisonous, sweet and spicy. Mainly enter the meridians of the liver and liver, the effect is interpolation (補 肝腎), gangeungol (强 筋骨), antenatal (安胎: to stabilize the fetus). Toothache is mainly used for low back pain and is especially necessary for low back pain caused by Xinyangheo (腎陽虛). At this time, Sokdan (속), earth and sand (兎 絲 子), breeding, etc. are used.

Iris uses leaves, stems and roots.

Calamus (Acorus calamus var . angustatus ) is a perennial herb belonging to the Tiannan Province (天南星 科, Araceae ), which is fragrant and grows in ponds, waterways, and wetlands. Underground stems have many nodes and beard roots. Root is used as a swelling, toothache, typhoon, remedy for treatment, and as a medicinal agent, soothing agent, supplement, etc., and leaves from the stem are used as fragrance.

Ogapi leaves refer to the leaves of the Ogapi tree, Ogapi fruit refers to the fruit of the Ogapi tree, and Ogapi bark refers to the stem or root bark of the Ogapi tree.

Acanthopanax sessiliflorus is a deciduous shrub belonging to the family Araliaceae, also known as the Ogapi. Trees are planted for ornamental purposes, young leaves are eaten as herbs, and bark (樹皮) is used to soak ogalpiju. Bark and fruit are used for the treatment of pain, soothing, cardiac and bruise in Chinese medicine.

Persimmon leaves refer to the leaves of persimmon tree, the fruit of the persimmon tree, and the stem or root bark of the persimmon tree.

Persimmon tree ( Japanese persimmon ) is a deciduous tree belonging to the Ebenaceae family. In folk medicine, green juices and leaves of persimmons are used for the treatment and prevention of stroke, hypertension, etc. In addition, persimmons, persimmon bark and roots are widely used. Persimmon vinegar, persimmon, persimmon, persimmon, and other foods made with persimmons are also good medicines to protect your health. Juicy juice is effective in preserving, dampening and converging. It is used to treat burns, frostbite and bruises. Juicy juice burns well without leaving scars, and when you're drunk, the juice goes away. In addition, when a person falls down due to a stroke, drinking juice from half a hop to one hop can take effect immediately.

The bokbunja leaves are the leaves of the bokbunja tree, the bokbunja fruit is the fruit of the bokbunja tree, and the stem or root bark of the bokbunja tree is the bokbunja tree.

Rubus coreanus is a deciduous shrub belonging to the family Rosacea , with some thorns on the reddish stems. The leaves are alternated with the leaf of 3 ~ 7 leaves, and the fruit is called Bokbunja. It is used as a bosin (補 身 劑) in Chinese medicine.

The leaves of the wolfberry are the leaves of the wolfberry, the berries of the wolfberry are the fruit of the wolfberry, and the stem or root bark of the wolfberry is called.

Wolfberry ( Lycium) chinense ) is a deciduous shrub belonging to the Solanaceae family . Fruits and root bark are harvested in the autumn and dried in the sun, called gojija and phalanges, respectively. It is used to treat pulmonary tuberculosis and diabetes. Goji berries are known to boost energy, especially for fatigue and lower blood pressure. In the spring, young leaves are picked and eaten as herbs, dried leaves and berries are drunk with tea, or soaked goji berries. Fruits, leaves, and bark are sometimes used to make goji-jacha (주로), but mainly fruit and leaves. The leaves are roasted slightly, and the fruits are dried well and then slowly roasted. It is said that gojijacha has been effective in preventing arteriosclerosis and keeping blood pressure normal.

Yin and Yang use leaves, stems, or roots.

Trilobite leaf koreanum ) is a perennial herb belonging to the Berberidaceae family. It is a well-known tonic and tonic tablet that has been widely known since ancient times, and it has been used as a tea brewing or drinking alcohol.

The leaflets refer to the leaves of the perilla, the elements of the perilla, the stems of the perilla, and the roots of the perilla roots.

Perilla, Beefsteak plant, Perilla frutescens Britton var . crispa Decne ) is an annual herb of Lamiaceae . In oriental medicine, the leaves are called foliar and seeds are used for sweating, antitussive, dry stomach, diuresis, soothing and analgesic. The sugar made from peryl aldehyde in the perilla is 2,000 times stronger than normal sugar, so it is used for tobacco, intestines and toothpaste. Leaves that are not purplish and green are called clear leaves (for. Viridis ). Sweep leaves are white and have a stronger scent than perilla and are used as a medicinal herb.

Three hundred seconds uses leaves, stems, or roots.

Sambaekcho (三 白草, Saururus chinensis) is saururaceae (三白草科, the perennial second in China belong to the Saururaceae) using whole plants or used as an antidote to cure beriberi in Japan, and is writing a diuretic. It is called three hundred seconds because two or three leaves running on the top of the stem are white.

Echoweed uses leaves, stems, or roots.

Eoseongcho is a perennial plant belonging to the Three Hundred Perennials and is called Eoseongcho because it smells like fishy fishy smell from leaves and stems. In addition, there are many names such as Chinese herbal medicine, juice and ten. Echoseong is very effective for various inflammatory diseases such as urethritis, cystitis, uterus, pneumonia, sinusitis, bronchitis, fistula, redness, and swelling. It is also effective in hypertension, strong detoxification effect and lowers blood sugar levels of diabetes. Antibacterial activity is one of the strongest plants. It is known to have several times higher antimicrobial activity than antibiotics "sulfamine", and it has been proven to inhibit or kill E. coli, E. coli, Paratyphos, Gonococcus, Staphylococcus aureus, Filamentous fungi, Ringworm, Athlete's foot, and the like. The unusual odor of the grass is due to decanoylacetaldehyde and laurinaldehyde, both of which are contained only in fresh grass, and distilled with water vapor changes the composition.

Mugwort uses leaves, stems or roots.

Artemisia princeps var . orientalis is a perennial herb belonging to the Asteraceae family, and in addition to mugwort, A. montana , A. lavandulaefolia and A. rubripes are also called mugwort. Mugwort is also used as a medicine, also called wormwood. The stems and leaves are cut and dried in the shade before and after Dano, which is called zirconia () 艾). It is also used for abdominal pain, vomiting, and hemostasis. I also write. Only dried leaves are called Yeopyeop (艾葉), and the slightly injured wounds are applied with the juice of the leaves.

Plants that can be used in the present invention are not limited to varieties.

It has not been reported that the plant material is used in the field of hair dyes.

Plant material in the present invention is used in the form of dry powder, hot water extract or alcohol extract, the form of hot water extract is most preferred in terms of hair dye effect.

Plant material in the present invention can be used in the form of a powder, which is to facilitate the dyeing, to facilitate the transport of the final product produced, and to powder to a level obtainable by a conventional powder machine, In contrast, the present invention is not limited.

In the present invention, the hot water extract refers to a material obtained by heating 50 to 150 parts by weight of water based on 1 part by weight of plant material. At this time, the heating temperature is preferably about 100 ℃ or more and the heating time is preferably 10 hours or more, but more preferably it is heated for 10 to 15 hours at 100 ℃.

In the present invention, the alcohol extract refers to a material obtained by extracting 30-100 parts by weight of alcohol with respect to 1 part by weight of plant material. At this time, the extraction conditions are preferably extracted for 5 to 10 hours at 40 ~ 50 ℃, more preferably for 8 hours at 45 ℃.

In the present invention, the plant material powder may be used in a form dyed by the plant material hot water extract, which refers to the plant material powder obtained by dyeing the plant material hot water extract into the plant material powder and heating it. At this time, the dyeing is carried out until the plant material powder is dyed about 50% to 80%. The dyeing will be readily understood by those skilled in the art as it implies the meaning of adsorption. The dyeing degree of the plant material powder by the plant material hot water extract is an effective range to show the hair dyeing effect. When the plant material powder is dyed below the above range, the dyeing effect on the hair is reduced, or the required color is made. It takes a lot of time, and if it exceeds the above range, it takes too much time to dye the plant material hot water extract on the plant material powder, causing economic problems, the dyeing effect on the hair is too excessive to produce a light color Problems may occur.

The present invention further includes dyes in the hair dye compositions described above. Dyes are added to exhibit a variety of colors, and the type of dye may include all dyes that can be commonly used in the field of hair dyes. In addition, the amount of dye added may be adjusted according to the type of dye and the color of hair to be represented, preferably 0.5 to 3% by weight, more preferably 1% by weight based on the total hair dye composition. If it is out of the above range, a problem arises that it is difficult to obtain desirable color and dyeing effects.

When it is directly used for hair dyeing, it is used in admixture with an additive comprising a hair dye composition and water commonly used in the art.

The hair dye composition of the present invention thus obtained includes a novel substance which can be used as a hair dye from a natural substance, and uses a substance used as a conventional medicament in terms of side effects, thereby minimizing side effects of a chemical added thereto. Not only are the side effects on the skin minimized, but also the irritation to the eyes is so small that it may have fewer side effects than with conventional chemical dyes. In addition, compared to conventional hair dyes containing natural materials, the material can be easily obtained in the country and has an economically superior effect. Moreover, the use of plant material in the form of a powder has the advantage of being easier to use and transport.

The present invention also provides a method for preparing the hair dye composition.

More specifically, preparing a powder of plant material, hot water extract and alcohol extract; And

It provides a method for producing a hair dye composition comprising the step of preparing a hair dye composition by adding a dye to at least one selected from the group consisting of powder of plant material, hot water extract and alcohol extract prepared in the step.

At this time, the dye is added to indicate the color of the hair dye, and may include all conventional dyes used in the art. The amount added is preferably about 0.5 to 3% by weight based on the total hair dye composition, for example, 1% by weight.

In addition, heating the plant material in water to obtain a plant material hot water extract (first step);

Adding a plant material powder to the plant material hot water extract, reacting and stirring while heating to obtain a plant material powder dyed with the plant material hot water extract (second step); And

It provides a method for producing a hair dye composition comprising the step (third step) of preparing a hair dye composition by adding a dye to the obtained plant material powder.

The first step is to obtain a plant material hot water extract, first wash the plant material with water, then put in a container filled with water and heated to about 100 ℃ or more. At this time, the heating time is preferably such that the plant material hot water extract can be sufficiently obtained, it can be adjusted according to the amount of plant material and the amount of water. For example, it is preferable to heat about 10 hours or more, but more preferably 10-20 hours.

The second step is a step of dyeing the plant material hot water extract obtained in the first step to the plant material powder, by heating the plant material powder in the container of the first step and applying heat to heat until the plant material powder is sufficiently dyed Stir. At this time, the heating time is preferably to be dyed about 50% to 80% of the whole plant material powder, for example, it is preferable to heat about 2 hours or more, but more preferably 2-5 hours.

After dyeing as above, the plant material hot water extract and the dyed plant material powder are separated by forced circulation. The dyed plant material powder thus obtained is dried with hot air to obtain a dried plant material powder.

The third step is a step of adding a dye to the plant material powder obtained in the second step, the dye is added to indicate the color of the hair dye, and may include all conventional dyes used in the art. . The amount added is preferably about 0.5 to 3 parts by weight based on 100 parts by weight of the total hair dye composition, for example, 1 part by weight.

After the addition of the dye in the production method of the present invention, it is diluted using a conventional powder group and then powdered, for example, a jet powder may be used.

Thereafter, the hair dye composition prepared as described above may be packaged in a standardized wrapping paper and stored until actual dyeing, or may be commercialized.

The present invention also provides a hair dye, a shampoo and a rinse comprising the hair dye composition as an active ingredient.

At the time of hair dyeing, the composition for hair dyes of this invention can be added to the well-known hair dye composition containing diamine organic dye, surfactant, fragrance | flavor, aqueous ammonia, hydrogen peroxide, ammonium thioglycolate, fatty acid alcohol, etc. In the term, diamine-based organic dyes include P-phenylenediamine, M-phenylenediamine, O-phenylenediamine, P-nitro-O-phenylenediamine, N-phenyl-P-phenylenediamine, and 4-sulfuric acid. Methoxy-m-phenylenediamine, toluene sulfate 2,5-diamine and the like. In one example, a hydrogen peroxide solution, water, N-phenyl-p-phenyleneamine, potassium alum, alcohol, and the like are added to an effective amount of the hair dye composition. At this time, the effective amount of the composition for the hair dye composition of the present invention is preferably 10 to 40 parts by weight based on 100 parts by weight of the total hair dye, but if the amount is less than 10 parts by weight, the hair dye effect is lowered. There is no need to add more.

Furthermore, the composition for hair dyes of the present invention may be added to a shampoo or rinse composition to provide a shampoo or rinse further comprising a dyeing effect. The shampoo or rinse composition includes everything that can be used conventionally, and is preferably 3 to 40 parts by weight based on 100 parts by weight of the appropriate amount required for dyeing, preferably 100 parts by weight of the total shampoo or rinse composition. Shampoo or rinse can provide a shampoo or rinse composition that adds a subtle hair dye effect even if the addition of about 3 parts by weight because hair dye itself is not an essential purpose. However, even when added in more than 40 parts by weight, such as a hair dye does not improve the hair dye effect and shampoo or rinse inherent role is better than 40 parts by weight should not be added. At this time, the hair dye composition is characterized in that it is contained in the form of an aqueous solution. As described above, the amount of the hair dye composition to be added may be appropriately adjusted depending on the amount used and the degree of dyeing, which is easily controlled by those skilled in the art.

Hereinafter, one specific example of the present invention will be described in detail, but the scope of the present invention is not limited thereto.

Example  1: powder of plant material, Hot Water Extract  And alcohol extract manufacturing

Powder manufacturing

Pine needles, pine bark, ginkgo biloba, ginkgo bark, cedar leaf, cedar berry, cedar bark, iris leaf, iris stem, iris root, scabbard leaf, scabbard bark, scabbard bark, persimmon leaf, persimmon, persimmon bark, bokbunja leaf, Bokbunjaberry, Bokbunja bark, Gojiberry, Gojiberry, Goji tree bark, Yin-Yang leaf, Yin-Yang stem, Yin-Yang root, Small leaf, Element, Perilla stem, Cha-Ji root, Triticale leaf, Triticale stem, Triticale root, Echo leaf, Estuary stem , Echo roots, mugwort leaves, mugwort stems and mugwort roots were dried and powdered in the shade.

Hot Water Extract  Produce

Pine needles, pine bark, ginkgo biloba, ginkgo bark, cedar leaf, cedar berry, cedar bark, iris leaf, iris stem, iris root, scabbard leaf, scabbard bark, scabbard bark, persimmon leaf, persimmon, persimmon bark, bokbunja leaf, Bokbunjaberry, Bokbunja bark, Gojiberry, Gojiberry, Goji tree bark, Yin-Yang leaf, Yin-Yang stem, Yin-Yang root, Small leaf, Element, Perilla stem, Cha-Ji root, Triticale leaf, Triticale stem, Triticale root, Echo leaf, Estuary stem , Eochocho root, mugwort leaf, mugwort stem and mugwort root were put into 1kg each container, poured with 10L of water, heated at 100 ° C for 10 hours, and filtered to prepare hot water extract.

Alcohol extract  Produce

Pine needles, pine bark, ginkgo biloba, ginkgo bark, cedar leaf, cedar berry, cedar bark, iris leaf, iris stem, iris root, scabbard leaf, scabbard bark, scabbard bark, persimmon leaf, persimmon, persimmon bark, bokbunja leaf, Bokbunjaberry, Bokbunja bark, Gojiberry, Gojiberry, Goji tree bark, Yin-Yang leaf, Yin-Yang stem, Yin-Yang root, Small leaf, Element, Perilla stem, Cha-Ji root, Triticale leaf, Triticale stem, Triticale root, Echo leaf, Estuary stem , Eochocho root, mugwort leaf, mugwort and mugwort root were put in 1kg of ethyl alcohol 10L and extracted for 8 hours at 45 ° C. After distilling the alcohol, the remaining extract was filtered to prepare an alcohol extract.

Example  2: the present invention using a single plant material For hair dye  Preparation of the composition

Powder composition of the single plant material prepared in Example 1, hot water extract or alcohol extract was mixed with 1 part by weight of dyes based on 100 parts by weight of the mixture as shown in Table 3 to prepare a composition for the hair dye of the present invention.

Mixing ratio of the composition for hair dyeing of the present invention using a single plant material (unit: parts by weight) powder Hot Water Extract Alcohol extract Composition number for the present hair dye pine needles 100 0 0 One Pine 0 100 0 2 Ginkgo leaves 0 0 100 3 Ginkgo 80 20 0 4 Tomb leaf 80 0 80 5 Two caterpillars 50 50 0 6 Cedar bark 0 50 50 7 Iris leaves 0 100 0 8 Iris stem 0 0 100 9 Iris 0 20 80 10 Ogapi Leaf 100 0 0 11 Organ fruit 0 50 50 12 Ogapi 20 80 0 13 Persimmon leaf 80 20 0 14 feeling 50 20 30 15 Persimmon 20 30 50 16 Bokbunja Leaf 20 20 60 17 Bokbunja Fruit 60 30 10 18 Bokbunja Tree Blood 0 100 0 19 Wolfberry 0 100 0 20 Goji berries 0 20 80 21 Wolfberry 20 30 50 22 Yin Yang Maple Leaf 100 0 0 23 Yin Yang Stem 90 0 10 24 Yin Yang Root 100 0 0 25 Leaflets 0 100 0 26 device 100 0 0 27 Perilla stem 50 5 45 28 Perilla root 100 0 0 29 Three hundred leaf 0 100 0 30 Three hundred stalks 0 0 100 31 Three hundred vine roots 20 50 30 32 Echo leaves 20 10 70 33 Eotseong Stem 100 0 0 34 Eoseongcho Root 0 100 0 35 Mugwort leaf 0 100 0 36 Mugwort 20 50 30 37 Wormwood Root 0 40 60 38

Example  3: the present invention using a mixed plant material For hair dye  Preparation of the composition

To prepare a composition for the hair dye of the present invention by mixing 1 part by weight of the dye with respect to a total of 100 parts by weight of the powder of the plant material prepared in Example 1 as shown in Table 4.

Blending ratio of the composition for hair dyeing of the present invention using mixed plant material (unit: parts by weight) division Plant material pine needles Ginkgo Two caterpillars Iris stem Ogapi Leaf feeling Bokbunja Tree Blood Wolfberry Yin Yang Maple Leaf Leaflets Three hundred leaf Echo leaves Mugwort leaf Composition 39 50 50 0 0 0 0 0 0 0 0 0 0 0 Composition 40 0 0 50 0 50 0 0 0 0 0 0 0 0 Composition 41 10 20 30 0 0 40 0 0 0 0 0 0 0 Composition 42 0 0 0 0 20 30 10 40 0 0 0 0 0 Composition 43 0 0 0 0 0 0 0 0 0 0 50 20 30 Composition 44 0 0 0 0 0 0 0 0 0 50 10 20 20 Composition 45 0 20 0 0 0 50 0 0 10 0 20 0 0 Composition 46 10 10 10 5 5 10 5 10 10 5 10 5 5

Example  4: plant material With hot water extract  With dyed powder For hair dye  Preparation of the composition

Pine needles, pine bark, ginkgo biloba, ginkgo bark, cedar leaf, cedar berry, cedar bark, iris leaf, iris stem, iris root, scabbard leaf, scabbard bark, scabbard bark, persimmon leaf, persimmon, persimmon bark, bokbunja leaf, Bokbunja fruit, Bokbunja bark, Gojiberry, Gojiberry, Goji tree bark, Yinyang leaf, Yinyang stalk, Yinyang root, Small leaf, Soja, Perilla stem, Perilla root, Triticale leaf, Triticale stem, Triticale root, Eocho leaf, Eocho stem Selected one or more selected from the group consisting of eoseongcho root, wormwood leaves, wormwood stems and wormwood roots to prepare a dyeing composition of the present invention by manufacturing a powder dyed with hot water extract in the following method, but pine pine sole material And using the mixture of iris leaves and leaflets were prepared compositions 47 and 48 for the hair dye of the present invention, respectively.

Step 1: Preparation of plant material hot water extract

10 kg of plant material was placed in a container and 2,000 L of water was poured. This was heated for 10 hours at 100 ℃ or more to obtain a plant material hot water extract.

Second Step: Preparation of Plant Material Powder Dyed by Plant Material Hot Water Extract

Stirring  process

Into the plant material hot water extract 1000L obtained in step 1 300kg of plant material powder was reacted and stirred while heating for 2 hours or more. The obtained plant material powder was about 70% dyed by the plant material extract.

Dewatering Classification Process

The plant material powder and plant material hot water extract dyed by the plant material hot water extract, which had undergone the above steps, were forced to be separated into plant material powder and plant material hot water extract. The plant material powder thus dyed and the plant material hot water extract were separated to obtain a plant material powder having dyeing ability.

Hot air drying process

The plant material powder dyed (adsorption) of the plant material hot water extract was dried with hot air to obtain a dried plant material powder.

Step 3: Raw Material Reprocessing Process

1 part by weight of a dye was added to 100 parts by weight of the fine plant material powder prepared in the second step, and diluted with a jet mill powder to make a powder.

Step 4: Packing Process

The final hair dye composition prepared in the third step was packaged in a standardized packaging.

Production Example  1: of the present invention For hair dye  With composition Hair dye  Produce

Each of hair dye compositions 1 to 48 prepared in Examples 2 to 4 was mixed in a composition as shown in Table 5 to prepare hair dyes 1 to 48.

ingredient weight% Remarks Composition for hair dye of the present invention 23% ICID Hydrogen peroxide solution 3% ICID water 61.5% ICID N-phenyl-p-phenylenediamine 5% ICID Potassium alum 2.5% ICID Alcohol 5% ICID

Production Example  2: of the present invention For hair dye  Preparation of Shampoos Using Compositions

The shampoo compositions 1 to 48 were prepared by mixing the hair dye compositions 1 to 48 prepared in Examples 2 to 4, respectively, in the compositions shown in Table 6 below.

Formulation ratio of shampoo composition (unit: parts by weight) Raw material name Compounding cost Composition for hair dye of the present invention 1.0 Silicone oil (100,000cst) 1.5 Silicon sword 1.0 Ammonium Lauryl Sulfate 12.0 Polyoxyethylene lauryl ammonium sulfate 4.0 Cocamide Diei 3.0 Glycolstearate 1.0 Lauramidor Popilbetaine 3.0 Lauro Ampocarboxyglycinate 3.0 Coloring, fragrance, preservative Quantity Distilled water Remaining amount

Production Example  3: of the present invention For hair dye  Preparation of Rinse Using Composition

Each of the hair dye compositions 1 to 48 prepared in Examples 2 to 4 was mixed to a composition as shown in Table 7 to prepare a rinse composition 1 to 48.

Rinse composition blending ratio (unit: parts by weight) Raw material name Compounding cost Composition for hair dye of the present invention 1.0 Myristic acid isopropyl 1.0 Liquid paraffin 4.0 Dimethicone (10,000 cst) 1.0 Cetearyl Alcohol 3.5 Ketonesage 0.02 Spices 1.0 Citric acid 0.01 Distilled water Remaining amount

Experimental Example  1: present invention Hair dye , Shampoo and rinse Dyeing , Hair conditioning effect and color fastness Degree  Research

The dyeing properties, hair conditioning effects, and fastnesses of the hair dyes 1 to 48, shampoos 1 to 48, and rinses 1 to 48 prepared in Preparation Examples 1 to 3 were measured.

As a comparative example, a hair dye purchased from a commercially available hair dye is a hair dye sold by Mugens (a brand name: Mugens Moving Hair Color), and a shampoo sold by LG Household & Health Care Co., Ltd. ) And rinse (trade name: Elastin) were used respectively. Ten hair dyes, shampoos and rinses purchased as described above were used for 10 people, and dyeing, hair conditioning effect, and color fastness were compared with those used for 10 people for each of the products of the present invention.

The comparison of the dyeability is based on the color difference, and the comparison of the hair conditioning effect and the color fastness is performed by the 5-point scale (5 = the best effect; 4 = the effect is very good; 3 = the effect is moderate; 2 = the effect is slightly good; 1 = ineffective) and scored 10 sensory evaluation specialists and averaged the scores.

1) dyeability

In the case of the hair dye, the hair dyes 1 to 48 prepared in Preparation Example 1 were mixed with water and applied to black hair and white hair, and after 1 hour, washed with running water using a commercially available shampoo, and dried with a hair dryer. Thereafter, the color difference (ΔE) between the dyed hair and the untreated hair was measured using a spectrophotometer. The larger the color difference, the better the dyeing property of the hair dye.

In the case of shampoo and rinse, hair was dried using a shampoo composition 1 to 48 and rinse compositions 1 to 48 prepared in Preparation Examples 2 and 3 and then dried using a hair dryer. Thereafter, the color difference (ΔE) between the treated hair and the untreated hair was measured using a spectrophotometer. The larger the color difference, the better the dyeing property.

2) hair conditioning effect

In the case of the hair dye, hair dyes 1 to 48 prepared in Preparation Example 1 were mixed with water and applied to black hair and white hair, and after 1 hour, washed with running water using a commercially available shampoo, and dried with a hair dryer. Thereafter, the hand hair of the dyed hair was compared with the texture by combing hard 20 times to evaluate the occurrence of static electricity.

In the case of shampoo and rinse, after shampooing using shampoos 1 to 48 and rinses 1 to 48 prepared in Preparation Examples 2 and 3, the hair was dried with a hair dryer. Thereafter, the hair was hand-combed with the hand 20 times, and the degree of static electricity was evaluated.

3) color fastness

In the case of the hair dye, the hair dyes 1 to 48 prepared in Preparation Example 1 were mixed with water and applied to black hair and white hair, and after 1 hour, washed with running water using a commercially available shampoo, and dried with a hair dryer. Thereafter, the dyed hair was immersed in an acidic solution similar to the sweat component, and after a predetermined time, the degree of discoloration was observed.

In the case of shampoo and rinse, after shampooing using shampoos 1 to 48 and rinses 1 to 48 prepared in Preparation Examples 2 and 3, the hair was dried with a hair dryer. Thereafter, the dyed hair was immersed in an acidic solution similar to the sweat component, and after a predetermined time, the degree of discoloration was observed.

The results are shown in Tables 8 to 11 below.

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye Evaluation item Hair dye Comparative example One 2 3 4 5 6 7 8 Dyeing (ΔE) 62 59 60 59 60 61 63 62 42 Hair conditioning effect 4.3 4.0 4.2 4.0 4.3 4.4 4.1 4.0 2.3 Dyeing fastness 4.5 4.3 4.4 4.4 4.5 4.0 4.1 4.4 2.1

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye Evaluation item Hair dye Comparative example 9 10 11 12 13 14 15 16 Dyeing (ΔE) 59 57 60 61 62 59 58 63 42 Hair conditioning effect 4.2 4.4 4.3 4.5 4.0 3.9 3.7 4.0 2.3 Dyeing fastness 4.4 4.4 4.0 3.7 4.0 4.1 4.2 3.9 2.1

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye Evaluation item Hair dye Comparative example 17 18 19 20 21 22 23 24 Dyeing (ΔE) 60 48 50 62 60 63 57 63 42 Hair conditioning effect 4.0 4.0 4.1 4.5 4.2 4.4 4.6 4.0 2.3 Dyeing fastness 4.4 4.5 4.0 4.7 4.0 4.0 3.7 4.2 2.1

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye Evaluation item Hair dye Comparative example 25 26 27 28 29 30 31 32 Dyeing (ΔE) 59 57 60 61 65 67 64 59 42 Hair conditioning effect 4.0 4.1 4.2 4.0 4.4 4.0 3.7 4.0 2.3 Dyeing fastness 4.4 4.0 4.3 3.7 4.0 4.0 4.2 4.5 2.1

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye Evaluation item Hair dye Comparative example 33 34 35 36 37 38 39 40 Dyeing (ΔE) 59 59 60 63 64 60 71 72 42 Hair conditioning effect 4.5 4.0 4.2 4.3 4.0 3.6 4.0 4.2 2.3 Dyeing fastness 4.0 4.0 3.8 3.9 4.0 4.1 4.5 4.8 2.1

Comparison of dyeing, hair conditioning effect and dyeing fastness of hair dye Evaluation item Hair dye Comparative example 41 42 43 44 45 46 47 48 Dyeing (ΔE) 72 69 67 68 63 67 63 62 42 Hair conditioning effect 4.0 3.7 4.0 4.1 4.0 4.1 4.0 3.9 2.3 Dyeing fastness 4.6 4.8 4.5 4.6 4.4 4.7 4.0 4.2 2.1

Comparison of dyeing, hair conditioning effect and color fastness of shampoo Evaluation item shampoo Comparative example One 2 3 4 5 6 7 8 Dyeing (ΔE) 22 23 19 18 20 23 17 19 0 Hair conditioning effect 4.0 4.2 3.9 4.0 3.7 4.0 3.5 3.7 3.6 Dyeing fastness 4.0 3.9 3.7 3.9 4.0 4.1 3.8 3.9 0

Comparison of dyeing, hair conditioning effect and color fastness of shampoo Evaluation item shampoo Comparative example 9 10 11 12 13 14 15 16 Dyeing (ΔE) 20 20 18 20 21 22 18 22 0 Hair conditioning effect 4.1 3.8 3.8 4.1 3.9 4.1 4.0 4.1 3.6 Dyeing fastness 3.8 3.9 4.0 3.8 4.1 4.0 3.8 4.2 0

Comparison of dyeing, hair conditioning effect and color fastness of shampoo Evaluation item shampoo Comparative example 17 18 19 20 21 22 23 24 Dyeing (ΔE) 22 23 24 30 19 25 19 20 0 Hair conditioning effect 4.0 3.9 4.0 4.2 3.8 4.0 3.8 4.0 3.6 Dyeing fastness 3.9 4.0 3.9 3.9 4.0 4.1 3.9 4.1 0

Comparison of dyeing, hair conditioning effect and color fastness of shampoo Evaluation item shampoo Comparative example 25 26 27 28 29 30 31 32 Dyeing (ΔE) 25 30 27 21 25 18 17 23 0 Hair conditioning effect 4.1 4.0 3.9 4.1 3.9 4.2 4.0 3.6 3.6 Dyeing fastness 3.7 4.2 4.2 3.7 4.2 4.0 3.7 4.0 0

Comparison of dyeing, hair conditioning effect and color fastness of shampoo Evaluation item shampoo Comparative example 33 34 35 36 37 38 39 40 Dyeing (ΔE) 22 31 20 19 18 25 35 30 0 Hair conditioning effect 4.0 3.9 3.0 3.9 4.2 4.0 4.1 4.0 3.6 Dyeing fastness 3.0 4.1 4.0 4.3 4.0 4.2 4.3 4.5 0

Comparison of dyeing, hair conditioning effect and color fastness of shampoo Evaluation item shampoo Comparative example 41 42 43 44 45 46 47 48 Dyeing (ΔE) 32 40 32 25 29 27 23 25 0 Hair conditioning effect 4.1 4.0 3.8 3.7 4.0 3.9 4.3 4.1 3.6 Dyeing fastness 4.3 4.5 4.4 4.5 4.0 4.7 4.3 4.2 0

Comparison of Rinsing Dye, Hair Conditioning Effect and Color Fastness Evaluation item Rinse Comparative example One 2 3 4 5 6 7 8 Dyeing (ΔE) 20 18 15 20 22 20 13 15 0 Hair conditioning effect 4.1 4.1 3.9 4.0 4.1 4.0 3.9 4.0 3.5 Dyeing fastness 3.0 3.5 3.4 3.5 3.2 3.7 3.3 3.8 0

Comparison of Rinsing Dye, Hair Conditioning Effect and Color Fastness Evaluation item Rinse Comparative example 9 10 11 12 13 14 15 16 Dyeing (ΔE) 25 22 25 21 16 21 19 19 0 Hair conditioning effect 4.0 3.1 3.5 4.2 3.8 3.1 3.2 4.2 3.5 Dyeing fastness 3.2 3.9 4.2 3.9 3.0 3.5 4.3 3.9 0

Comparison of Rinsing Dye, Hair Conditioning Effect and Color Fastness Evaluation item Rinse Comparative example 17 18 19 20 21 22 23 24 Dyeing (ΔE) 20 15 16 22 29 22 27 21 0 Hair conditioning effect 3.6 3.9 4.0 4.1 3.5 3.3 3.9 3.2 3.5 Dyeing fastness 3.3 3.4 3.2 3.7 3.5 3.7 4.0 4.0 0

Comparison of Rinsing Dye, Hair Conditioning Effect and Color Fastness Evaluation item Rinse Comparative example 25 26 27 28 29 30 31 32 Dyeing (ΔE) 18 17 20 14 25 20 18 15 0 Hair conditioning effect 3.2 4.0 3.6 4.0 3.5 3.0 3.7 3.8 3.5 Dyeing fastness 3.2 3.0 4.0 3.8 3.2 3.2 4.1 3.5 0

Comparison of Rinsing Dye, Hair Conditioning Effect and Color Fastness Evaluation item Rinse Comparative example 33 34 35 36 37 38 39 40 Dyeing (ΔE) 22 19 21 22 15 22 29 27 0 Hair conditioning effect 3.7 3.9 4.3 4.1 3.9 4.0 3.5 4.0 3.5 Dyeing fastness 3.9 4.0 3.7 3.2 3.0 3.9 4.0 3.4 0

Comparison of Rinsing Dye, Hair Conditioning Effect and Color Fastness Evaluation item Rinse Comparative example 41 42 43 44 45 46 47 48 Dyeing (ΔE) 29 30 25 24 19 32 19 20 0 Hair conditioning effect 4.0 3.5 4.0 3.7 3.0 3.7 3.2 3.9 3.5 Dyeing fastness 4.3 4.5 4.3 4.5 4.7 4.3 3.9 3.7 0

As described above, the hair dye composition using the natural plant material of the present invention is a natural vegetable material that is harmless to the human body used as a conventional medicine as a dye, pine, ginkgo, cedar, iris, organo, persimmon, bokbunja Powder, hot water extract or alcohol extract such as Gojiberry, Eumyangkwa, Perilla, Trichophytium, Eochocho, Mugwort, etc., and not only reduce the side effects of chemicals, but also have excellent dyeing, hair conditioning effect and dyeing fastness It has an excellent effect of eliminating side effects such as skin irritation caused by the colorant of the ingredient. In addition, it can be used not only for hair dyes, but also for shampoo or rinse, etc. It is a very useful invention in the chemical industry.

Claims (4)

Pine needles, pine bark, ginkgo biloba, ginkgo bark, cedar leaf, cedar berry, cedar bark, iris leaf, iris stem, iris root, scabbard leaf, scabbard bark, scabbard bark, persimmon leaf, persimmon, persimmon bark, bokbunja leaf, Bokbunja fruit, Bokbunja bark, Gojiberry, Gojiberry, Goji tree bark, Yinyang leaf, Yinyang stalk, Yinyang root, Small leaf, Soja, Perilla stem, Perilla root, Triticale leaf, Triticale stem, Triticale root, Eocho leaf, Eocho stem , Eochocho root, mugwort leaves, mugwort stems and mugwort root, any one or more powders, hot water extract or alcohol extract composition comprising a hair extract as an active ingredient. A hair dye comprising the hair dye composition of claim 1 as an active ingredient. A shampoo comprising the hair dye composition of claim 1 as an active ingredient. Rinse comprising the hair dye composition of claim 1 as an active ingredient.