KR20070061947A - Water based coating materials and manufacturing method thereof - Google Patents
Water based coating materials and manufacturing method thereof Download PDFInfo
- Publication number
- KR20070061947A KR20070061947A KR1020050121480A KR20050121480A KR20070061947A KR 20070061947 A KR20070061947 A KR 20070061947A KR 1020050121480 A KR1020050121480 A KR 1020050121480A KR 20050121480 A KR20050121480 A KR 20050121480A KR 20070061947 A KR20070061947 A KR 20070061947A
- Authority
- KR
- South Korea
- Prior art keywords
- weight
- water
- coating composition
- soluble coating
- cellulose resin
- Prior art date
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000000463 material Substances 0.000 title claims abstract description 7
- 238000000576 coating method Methods 0.000 title claims description 60
- 239000011248 coating agent Substances 0.000 title claims description 54
- 239000011521 glass Substances 0.000 claims abstract description 89
- 239000008199 coating composition Substances 0.000 claims abstract description 50
- 239000012461 cellulose resin Substances 0.000 claims abstract description 45
- 239000007788 liquid Substances 0.000 claims abstract description 41
- -1 hydroxypropyl Chemical group 0.000 claims abstract description 23
- 239000004014 plasticizer Substances 0.000 claims abstract description 16
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 7
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims abstract description 7
- 239000004973 liquid crystal related substance Substances 0.000 claims abstract description 4
- 239000010409 thin film Substances 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 32
- 239000000758 substrate Substances 0.000 claims description 24
- 239000000203 mixture Substances 0.000 claims description 21
- 238000004140 cleaning Methods 0.000 claims description 20
- 238000005507 spraying Methods 0.000 claims description 17
- 229920002678 cellulose Polymers 0.000 claims description 16
- 239000001913 cellulose Substances 0.000 claims description 16
- 239000011253 protective coating Substances 0.000 claims description 14
- 239000007864 aqueous solution Substances 0.000 claims description 12
- 239000002518 antifoaming agent Substances 0.000 claims description 11
- 239000003995 emulsifying agent Substances 0.000 claims description 11
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 7
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 238000007598 dipping method Methods 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000003906 humectant Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 230000009477 glass transition Effects 0.000 claims description 5
- 239000000080 wetting agent Substances 0.000 claims description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 claims description 4
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical group COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 claims description 4
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 claims description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 claims description 2
- WOFPPJOZXUTRAU-UHFFFAOYSA-N 2-Ethyl-1-hexanol Natural products CCCCC(O)CCC WOFPPJOZXUTRAU-UHFFFAOYSA-N 0.000 claims description 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 claims description 2
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 claims description 2
- BQSLMFSQEBXZHN-UHFFFAOYSA-N bis(8-methylnonyl) butanedioate Chemical compound CC(C)CCCCCCCOC(=O)CCC(=O)OCCCCCCCC(C)C BQSLMFSQEBXZHN-UHFFFAOYSA-N 0.000 claims description 2
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 claims description 2
- 229960001826 dimethylphthalate Drugs 0.000 claims description 2
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 claims description 2
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 claims description 2
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 2
- 235000011187 glycerol Nutrition 0.000 claims description 2
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 claims description 2
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920000136 polysorbate Polymers 0.000 claims description 2
- 229950008882 polysorbate Drugs 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 claims 1
- 229920001577 copolymer Polymers 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 238000002360 preparation method Methods 0.000 claims 1
- 239000002585 base Substances 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 42
- 230000000052 comparative effect Effects 0.000 description 8
- 230000001681 protective effect Effects 0.000 description 7
- 238000003860 storage Methods 0.000 description 6
- 238000005259 measurement Methods 0.000 description 5
- 238000003618 dip coating Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 229920002284 Cellulose triacetate Polymers 0.000 description 3
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 238000004383 yellowing Methods 0.000 description 3
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000012459 cleaning agent Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229940008099 dimethicone Drugs 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- GRVDJDISBSALJP-UHFFFAOYSA-N methyloxidanyl Chemical group [O]C GRVDJDISBSALJP-UHFFFAOYSA-N 0.000 description 2
- 125000005498 phthalate group Chemical group 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 229910021642 ultra pure water Inorganic materials 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- 238000004506 ultrasonic cleaning Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000004141 Sodium laurylsulphate Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Natural products CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012776 electronic material Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000000399 optical microscopy Methods 0.000 description 1
- ZFACJPAPCXRZMQ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O.OC(=O)C1=CC=CC=C1C(O)=O ZFACJPAPCXRZMQ-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 238000002411 thermogravimetry Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/02—Processes for applying liquids or other fluent materials performed by spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D1/00—Processes for applying liquids or other fluent materials
- B05D1/18—Processes for applying liquids or other fluent materials performed by dipping
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
- B05D3/02—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
- B05D3/0254—After-treatment
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
- C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
- C08L71/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/06—Polysiloxanes containing silicon bound to oxygen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D101/00—Coating compositions based on cellulose, modified cellulose, or cellulose derivatives
- C09D101/08—Cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/80—Processes for incorporating ingredients
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
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Abstract
Description
도 1은 종래의 베어글라스 또는 PCB 기판을 나타내는 도면1 is a view showing a conventional bare glass or PCB substrate
도 2는 베어글라스 또는 PCB 기판 양면에 본 발명의 보호코팅제가 코팅된 상태를 나타내는 도면2 is a view showing a state in which the protective coating of the present invention is coated on both sides of the bare glass or PCB substrate
- 도면의 상세한 부호의 설명 --Explanation of Detailed Symbols in Drawings-
2 : 베어글라스 또는 PCB 기판2: bare glass or PCB board
4 : 코팅제4: coating agent
본 발명은 액정표시소자(Liquid crystal display device; 이하 LCD라 함) 및 박막트랜지스터(Thin film transistor; 이하 TFT라 함)의 기본재료인 베어글라스와 전자기기 전반에 사용되는 PCB기판의 손상을 최소화 시킬 수 있도록 한 보호 코팅제 조성물 및 그의 제조 방법에 관한 것이다.The present invention is to minimize the damage of the PCB and the PCB used in the overall electronic glass and bare glass, which is the base material of the liquid crystal display device (hereinafter referred to as LCD) and thin film transistor (hereinafter referred to as TFT) To a protective coating composition and a method of making the same.
현재 셀룰로오스에 관련된 특허는 주로 의약관련 코팅제와 산업분야 시멘트 배합제 등 관련 특허가 많이 존재하고 있으나, 실제 전자재료소재 분야의 보호를 위한 코팅제에 관한 특허는 찾아보기 힘들며, 주로 셀룰로오스 관련 필름에 관하여 나와 있다. 일본특허 제 10-2004-0051774호에서는 전도성 셀룰로오스계 필름의 제조방법에 관하여 기술되어 있다. 주로 솔벤트(solvent)를 사용하여 코팅액을 제조하였고, 이를 그라비어 코팅법에 따라 트리아세틸 셀룰로오스 필름상에 적용하는 방법으로 전기전도성을 지닌 셀룰로오스계 필름 제조에 관한 내용을 기술하고 있다. 또한 국내특허 제 10-2002-0051529호에서는 투명 대전방지 트리아세틸 셀룰로오스 필름에 관한 것으로 이 또한 solvent와 기타 첨가제를 사용하여 투명한 대전방지 트리아세틸 셀룰로오스 필름 제조에 관한 내용을 기술하고 있다. 미국특허 제 6,715,316호를 보면 LCD 유리의 스크래치 방지목적에 관한 코팅제에 관하여 기술하고 있으나, 주 사용재료의 정확한 함량이 나와 있지 않으며, 콘텍앵글(Contact angle)을 강조하고 있다. 그러나 콘텍앵글은 코팅과는 무관하고 LCD 유리를 세정하는 과정에서 사용하는 세정제(SEMICLEAN KG)에 따라 LCD유리의 표면특성이 달라지는 특성을 지니고 있으므로 미국특허 제 6,715,316호에서 주장하는 코팅제에 의한 콘텍앵글의 감소효과라 보기 어려운 실정이다. Currently, there are many patents related to cellulose, such as pharmaceutical-related coatings and cement compoundings, but there are few patents on coatings for the protection of electronic materials. have. Japanese Patent No. 10-2004-0051774 describes a method for producing a conductive cellulose film. The coating solution was mainly prepared by using a solvent, and the content of the cellulose-based film having electrical conductivity was described by applying the same on a triacetyl cellulose film according to the gravure coating method. In addition, Korean Patent No. 10-2002-0051529 relates to a transparent antistatic triacetyl cellulose film, which also describes the contents of the production of a transparent antistatic triacetyl cellulose film using a solvent and other additives. U.S. Patent No. 6,715,316 describes a coating agent for the purpose of scratch prevention of LCD glass, but the exact content of the main material is not disclosed, and the contact angle is emphasized. However, the contact angle is independent of the coating and has the characteristics that the surface characteristics of the LCD glass vary depending on the cleaning agent (SEMICLEAN KG) used in the process of cleaning the LCD glass. Therefore, the contact angle of the contact angle by the coating agent claimed in US Patent No. 6,715,316 It is difficult to see the reduction effect.
일반적으로 LCD 및 TFT의 기본재료인 베어글라스 보호용 필름은 베어글라스 제조공정과 베어글라스에 필름을 도포하는 공정 그리고 도포된 필름을 제거하는 공정을 수반하며, 베어글라스의 이송중에 발생할 수 있는 이물부착과 미세유리 파티클로부터 베어글라스 표면을 보호하기 위해 사용되고 있다.In general, the bare glass protective film, which is the basic material of LCD and TFT, involves the manufacturing process of the bare glass, the process of applying the film to the bare glass, and the process of removing the applied film, and the adhesion of foreign substances that may occur during the transportation of the bare glass. It is used to protect bare glass surfaces from microglass particles.
그러나 이러한 보호필름은 베어글라스 제조시 도포되는 과정에서 공기중에 존재하는 이물이 베어글라스와 보호필름 사이에 침입(존재)하게 되어 적재시 스크래치 현상을 초래하게 된다. 이렇게 양면에 도포된 필름은 점착성을 띄고 있어 제품출하 후 사용처(전자회사 ; LCD 혹은 TFT 제조라인)에서 도포된 필름을 제거하는 과정에서 베어글라스의 파손을 야기 시켜 이의 교환에 따른 작업성 저하현상, 필름제거 후 베어글라스 표면에 점착성으로 인한 필름 이물 존재와 이를 제거고자 사용되는 solvent(아세톤과 이소프로필 알코올) 세정공정에 따른 환경오염 및 원가 손실 문제 등의 문제점의 개선이 요구되고 있다. 또한 현재 0.5T의 베어글라스가 0.3T로 얇아질 경우, 보호필름의 두께와 베어글라스의 두께가 같아져 보호 필름 제거시 베어글라스의 파손에 따른 문제를 안고 있는 현실이므로 이의 개선이 시급히 요구되고 있다.However, such a protective film is foreign matter present in the air in the process of applying during the manufacturing of the bare glass infiltrates (exists) between the bare glass and the protective film, causing a scratch phenomenon during loading. Thus, the film coated on both sides has adhesiveness, which causes the breakage of bare glass in the process of removing the coated film at the place of use (electronic company; LCD or TFT manufacturing line) after shipping the product, resulting in deterioration of workability due to the exchange of After removing the film, there is a need to improve the problems such as the presence of foreign substances on the surface of the bare glass due to the adhesion and environmental pollution and cost loss problems due to the solvent (acetone and isopropyl alcohol) cleaning process used to remove them. In addition, when the bare glass of 0.5T is thinned to 0.3T, the thickness of the protective film is the same as the thickness of the bare glass, which is a problem that is caused by the damage of the bare glass when the protective film is removed. .
가전기기 전반에 사용되는 PCB기판의 경우 특별히 보호 코팅제 및 보호필름을 사용하고 있지 않아 이송 중 기판간의 접촉으로 인해 회로 손상으로 인한 전기 전송능력이 상실되는 결과를 초래하고 있으며, 기판의 회로 구성성분인 동(copper)의 공기중에 노출로 인해 산화막을 형성하므로 이를 방지하고자 기판에 표면처리를 하고 있는 실정이므로 이의 개선 또한 시급히 요구되고 있는 실정이다.PCB boards used in general home appliances do not use special protective coatings or protective films, resulting in the loss of electrical transmission capacity due to circuit damage due to contact between boards during transport. Since an oxide film is formed due to exposure to copper air, the surface treatment is performed on the substrate to prevent this, and thus an improvement thereof is urgently required.
따라서 본 발명의 목적은 상기의 문제점을 해결하기 위하여, 베어글라스 또는 PCB 기판에 코팅처리하여 이송 중 발생할 수 있는 손상과 산화막 형성으로 인한 문제를 최소화시키며, 기존 필름제거 과정에서 발생하는 베어글라스의 파손을 예방 하기 위하여 세정시 물에 용해될 수 있는 보호코팅제 및 그의 코팅방법을 제공하는데 있다.Accordingly, an object of the present invention, in order to solve the above problems, by coating the bare glass or PCB substrate to minimize the problems caused by the damage and oxide film formation that may occur during transfer, the damage of the bare glass generated in the existing film removal process In order to prevent the present invention to provide a protective coating agent and its coating method that can be dissolved in water during cleaning.
또한 본 발명은 코팅 조성물의 유동성 및 흐름성을 좋게 하기 위하여 습윤제를 첨가함으로써 저온의 베어글라스 또는 기판에서도 코팅성능이 우수한 코팅 조성물을 제공하는 것을 그 목적으로 한다.In addition, an object of the present invention is to provide a coating composition having excellent coating performance even in low temperature bare glass or a substrate by adding a humectant to improve the flowability and flowability of the coating composition.
상기의 목적을 달성하기 위하여 본 발명에 따른 보호 코팅제는 베어글라스 또는 PCB 기판의 표면에 스프레이 코팅 또는 디핑 코팅 방법을 사용하여 양면을 코팅하는 것으로, 이와 같이 코팅시킨 경우 적재 및 이송과정에서 발생할 수 있는 이물질 부착과 스크래치로 인한 불량률 및 회로의 전기 전송능력 상실을 획기적으로 예방할 수 있는 것을 특징으로 한다.In order to achieve the above object, the protective coating according to the present invention is to coat both surfaces by using a spray coating or a dipping coating method on the surface of a bare glass or a PCB substrate, and in this case, the coating may occur during loading and conveying. It is characterized by the fact that the defect rate due to foreign matter adhesion and scratch and the loss of electric transmission capacity of the circuit can be prevented.
본 발명에 따른 보호코팅제의 박리 방법은 상기와 같이 양면에 코팅된 베어글라스 또는 PCB 기판을 세정라인에 투입하여 세정하는 과정동안 사용하는 세정제의 pH에 관계없이 용해되어 제거되는 것을 특징으로 한다. 특히 상기 코팅 조성물은 pH 1.2 내지 pH 13.0의 수용액에서 잘 용해된다.The peeling method of the protective coating agent according to the present invention is characterized in that it is dissolved and removed regardless of the pH of the cleaning agent used during the cleaning process by putting the bare glass or PCB substrate coated on both sides as described above in the cleaning line. In particular, the coating composition is well dissolved in an aqueous solution of pH 1.2 to pH 13.0.
본 발명의 보호코팅 조성물은 셀룰로오스 수지 또는 셀룰로오스 수지 유도체를 물에 용해한 액상의 수용성 코팅 조성물이며, 본 발명의 다른 양태로는 상기의 액상 셀룰로오스 수지 또는 액상 셀룰로오스 수지 유도체와 가소제의 혼합물이고, 또 다른 양태는 상기 액상 셀룰로오스 수지 또는 액상 셀룰로오스 수지 유도체와 가소제의 혼합물에 유화제를 더 추가하여 사용하는 것이다. The protective coating composition of the present invention is a liquid water-soluble coating composition in which a cellulose resin or a cellulose resin derivative is dissolved in water, and in another embodiment of the present invention, a liquid cellulose resin or a mixture of the liquid cellulose resin derivative and a plasticizer is used. Is used by adding an emulsifier to the mixture of the liquid cellulose resin or the liquid cellulose resin derivative and the plasticizer.
상기 본 발명의 각각의 양태는 유화제, 소포제에서 선택된 하나 이상을 더 혼합하여 사용할 수 있다.Each aspect of the present invention may be used by further mixing one or more selected from an emulsifier and an antifoaming agent.
즉, 본 발명의 코팅 조성물의 일 양태는That is, one aspect of the coating composition of the present invention
1) 반응기에 탈이온수 65 ~ 90 중량%와 가소제 2 ~ 8 중량%를 혼합하여 40 ~ 80 ℃에서 교반하여 수용액을 제조하는 단계;1) mixing 65 to 90% by weight of deionized water and 2 to 8% by weight of a plasticizer in the reactor and stirred at 40 ~ 80 ℃ to prepare an aqueous solution;
2) 상기 수용액에 메톡시 함량이 18.0 중량% 내지 35.0 중량%, 히드록시프로필 함량이 4.0 중량% 내지 13.0 중량%, 중량 평균 분자량이 1,000 내지 2,000,000인 셀룰로오스 수지 2 ~ 8 중량% 또는 프탈레이트 함량이 20.0 내지 35.0 중량%, 메톡시 함량이 18.0 ~ 24.0 중량%이며, 하이드록시프로필 5.0 ~ 10.0 중량%이고, 중량평균분자량이 1,000 내지 3,000,000인 셀룰로오스 수지 유도체 5 ~ 20 중량%를 서서히 적하하여 교반하는 단계;2) 2-8 wt% of cellulose resin or 20.0 wt% of cellulose resin having a methoxy content of 18.0 wt% to 35.0 wt%, a hydroxypropyl content of 4.0 wt% to 13.0 wt%, and a weight average molecular weight of 1,000 to 2,000,000 To 35.0% by weight, methoxy content of 18.0 to 24.0% by weight, hydroxypropyl 5.0 to 10.0% by weight, and slowly dropping and stirring 5 to 20% by weight of a cellulose resin derivative having a weight average molecular weight of 1,000 to 3,000,000;
에 의하여 제조할 수 있으며, 또 다른 양태로는It can be prepared by, in another embodiment
1) 반응기에 탈이온수 65 ~ 90 중량%와 가소제 2 ~ 8 중량% 습윤제 1 ~ 5 중량%를 혼합하여 40 ~ 80 ℃에서 교반하여 고형분 9 ~ 10%의 수용액을 제조하는 단계;1) mixing 65 to 90% by weight of deionized water and 1 to 5% by weight of a
2) 상기 수용액에 메톡시 함량이 18.0 내지 35.0 중량%, 히드록시프로필 함량이 4.0 내지 13.0 중량%, 중량 평균 분자량이 1,000 내지 2,000,000인 셀룰로오스 수지 2 ~ 8 중량% 또는 프탈레이트 함량이 20.0 내지 35.0 중량%, 메톡시 함량이 18.0 ~ 24.0 중량%이며, 하이드록시프로필 5.0 ~ 10.0 중량%이고, 중량평균분 자량이 1,000 내지 3,000,000인 셀룰로오스 수지 유도체 5 ~ 20 중량%를 서서히 적하하여 교반하는 단계;2) 2 to 8% by weight of cellulose resin having a methoxy content of 18.0 to 35.0% by weight, hydroxypropyl content of 4.0 to 13.0% by weight, a weight average molecular weight of 1,000 to 2,000,000 or phthalate content of 20.0 to 35.0% by weight , 5 to 20% by weight of a cellulose resin derivative having a methoxy content of 18.0 to 24.0% by weight, hydroxypropyl 5.0 to 10.0% by weight, and a weight average molecular weight of 1,000 to 3,000,000;
에 의하여 제조할 수 있다.It can manufacture by.
또한 상기 각각의 양태에 3) 상기 2)단계의 혼합물에 유화제 0.1 ~ 3 중량%, 소포제 0.1 ~ 3 중량%에서 선택된 어느 하나 이상을 가하여 교반하는 단계; 를 더 추가하는 것도 가능하다.Also in each of the embodiments 3) adding at least one selected from 0.1 to 3% by weight of the emulsifier, 0.1 to 3% by weight of the defoaming agent to the mixture of step 2) and stirring; It is also possible to add more.
이하에서 본 발명을 보다 구체적으로 설명하기로 한다.Hereinafter, the present invention will be described in more detail.
본 발명은 액정표시소자 및 박막트랜지스터의 기본재료인 베어글라스와 전자기기 전반에 사용되는 PCB기판의 손상을 보호하기 위한 조성물로서,The present invention is a composition for protecting the damage to the PCB substrate used in the bare glass and electronic devices as a base material of the liquid crystal display device and the thin film transistor,
메톡시(Methoxyl) 함량이 18.0 내지 35.0 중량%, 3히드록시프로필(Hydroxypropyl) 함량이 4.0 내지 13.0 중량%, 중량 평균 분자량이 1,000 내지 2,000,000인 액상 셀룰로오스 수지 또는 프탈레이트(Phthalate) 함량이 20.0 내지 35.0 중량%, 메톡시 함량이 18.0 ~ 24.0 중량%이며, 하이드록시프로필 5.0 ~ 10.0 중량%, 중량평균분자량이 1,000 내지 3,000,000인 액상 셀룰로오스 수지 유도체를 사용하는 것을 특징으로 하는 베어글라스 및 PCB기판 보호용 코팅 조성물에 관한 것이다. Methoxyl content of 18.0 to 35.0 wt%, 3 hydroxypropyl content of 4.0 to 13.0 wt%, weight average molecular weight of 1,000 to 2,000,000 liquid cellulose resin or phthalate content of 20.0 to 35.0 wt% %, Methoxy content of 18.0 ~ 24.0% by weight, hydroxypropyl 5.0 ~ 10.0% by weight, the weight average molecular weight of 1,000 to 3,000,000 liquid cellulose resin derivative, characterized in that the coating composition for bare glass and PCB substrate protection It is about.
본 발명에 따른 베어글라스 및 PCB기판 보호용 코팅 조성물은 도 2에 나타낸 바와 같이 상/하부(4)를 코팅함으로써 베어글라스 또는 PCB 기판(2)을 보호할 수 있다.The coating composition for bare glass and PCB substrate protection according to the present invention can protect the bare glass or
본 발명에서 상기 액상 셀룰로오스 수지의 평균분자량은 1,000 내지 2,000,000이고, 액상 셀룰로오스 수지 유도체의 평균 분자량은 1,000 내지 3,000,000가 적당하다. 좀더 바람직하게는 각각 5,000에서 1,000,000 사이가 가장 적당하다. 평균 분자량이 1000이하인 경우 분자량이 낮아 코팅제의 내구성 및 코팅 후 강도가 저하되어 코팅제의 물성을 발현하지 못하며, 2,000,000을 초과하는 경우 베어글라스 코팅 후 이를 제거하는 단계인 세정단계에서 세정시간이 너무 길어지는 역효과를 보이므로 상기 범위를 사용하는 것이 바람직하다. In the present invention, the average molecular weight of the liquid cellulose resin is 1,000 to 2,000,000, the average molecular weight of the liquid cellulose resin derivative is suitably 1,000 to 3,000,000. More preferably between 5,000 and 1,000,000 each is most suitable. If the average molecular weight is less than 1000, the molecular weight is low, the durability of the coating agent and the strength after coating is lowered to express the physical properties of the coating agent, if it exceeds 2,000,000 cleaning time is too long in the cleaning step to remove it after coating the bare glass It is preferable to use the above range because it has an adverse effect.
또한, 이들의 유리전이온도(Tg)는 5℃ 내지 100℃가 적당하며, 보다 바람직하게는 45℃ 내지 75℃ 정도 가장 좋다. Tg가 5℃ 미만인 경우 상온 이하의 Tg를 가지므로 상온에서 마르지 않고 끈끈한 형태를 계속 유지하며, 100℃ 이상인 경우 필름화되는 온도가 높으며 높은 온도에 따라 코팅제의 황변효과가 발생하므로 상기 범위를 사용하는 것이 좋다. In addition, the glass transition temperature (T g ) of these is preferably from 5 ° C to 100 ° C, more preferably from 45 ° C to 75 ° C. If T g is less than 5 ° C., it has a T g of room temperature or less, so it does not dry at room temperature and maintains a sticky form. If T g is more than 100 ° C., the filming temperature is high and the yellowing effect of the coating occurs depending on the high temperature. It is good to use.
또한, 본 발명에서 사용된 액상 셀룰로오스 수지(AnyCoat A~E) 및 액상 셀룰로오스 수지 유도체(Anycoat F) 점도 범위는 2% 수용액의 점도가 2 내지 60cP가 적당하여 좀더 바람직하게는 3 내지 50cP가 가장 적당하다. 점도가 2cP이하면 물과 같아 코팅시 흘러내림 현상이 심하고 코팅액 건조시간이 많이 걸리며, 60cP이상시 거의 유동성을 잃어버려 코팅을 할 수 없게 되므로 상기의 범위를 사용하는 것이 좋다. 또한 액상 셀룰로오스 수지 유도체(Anycoat F)의 경우 원액의 점도범위는 150~300cP이며 150cP이하인 경우 위와 같은 현상을 초래하며 300cP이상의 경우 유 동성이 없어 코팅하기 어려운 관계로 상기범위를 사용하는 것이 좋다.In addition, the liquid cellulose resin (AnyCoat A ~ E) and liquid cellulose resin derivative (Anycoat F) viscosity range used in the present invention is 2 to 60 cP of 2% aqueous solution is suitable, more preferably 3 to 50 cP is most suitable Do. If the viscosity is less than 2cP, the same phenomenon as water flows down during coating and the coating liquid takes a long time to dry, and when it is 60cP or more, it almost loses fluidity, so coating cannot be used. In addition, in the case of the liquid cellulose resin derivative (Anycoat F), the viscosity range of the undiluted solution is 150 to 300 cP, and if it is 150 cP or less, it causes the above phenomenon.
본 발명에서 상기 액상 셀룰로오스 수지는 메톡시(Methoxyl, -OCH3) 함량이 18.0 내지 35.0 중량%가 적당하며 바람직하게는 26.0 내지 31.5 중량%가 정도를 사용한다. 메톡시 함량이 18.0 중량% 미만의 경우 용해도가 낮아져 물에 잘 녹지 않는 특성을 보이며, 35 중량% 이상의 경우 셀룰로오스 치환체에 결합할 수 있는 범위를 넘기 때문에 미반응 상태로 존재하므로 상기의 범위를 사용하는 것이 좋다.In the present invention, the liquid cellulose resin is suitably methoxy (Methoxyl, -OCH 3 ) 18.0 to 35.0% by weight, preferably 26.0 to 31.5% by weight. When the methoxy content is less than 18.0% by weight, the solubility is low, so that it is insoluble in water, and when it is more than 35% by weight, since it exists in an unreacted state because it exceeds the range capable of binding to the cellulose substituent, the above range is used. It is good.
히드록시프로필(Hydroxypropyl, -OCH2CHOHCH3) 함량이 4.0 내지 13.0 중량%가 적당하며, 보다 바람직하게는 7.0 내지 12.0 중량%가 적당하다. 히드록시프로필 함량이 4.0 중량%미만의 경우 필름형성시 강도가 증가하여 깨지는 현상을 초래하게 되고, 13.0 중량%이상의 경우에는 유연성이 증가하여 건조과정에서 필름화되는 시간이 길어지는 현상을 초래하여 상기의 범위를 사용하는 것이 좋다. A suitable content of hydroxypropyl (Hydroxypropyl, -OCH 2 CHOHCH 3 ) is 4.0 to 13.0% by weight, more preferably 7.0 to 12.0% by weight. When the hydroxypropyl content is less than 4.0% by weight, the strength increases when forming a film, which causes cracking. In the case of more than 13.0% by weight, the flexibility is increased, resulting in a long film forming time during the drying process. It is better to use the range of.
또한, 상기 액상 셀룰로오스 수지를 이용한 액상 셀룰로오스 유도체도 본 발명의 범위에 포함되며, 이는 프탈레이트(Phthalate) 함량이 20.0 내지 35.0 중량%가 바람직하며, 보다 바람직하게는 25.0 내지 32.0 중량%가 가장 적당하다. 20.0 중량%이하의 경우 셀룰로오스의 치환체에 플탈레이트 그룹이 규칙적으로 분포하지 않게 되며 35.0 중량%이상의 경우 치환되지 않고 잔류하는 프랄레이트 그룹이 존재하게 되어 불순물로 작용하므로 상기의 범위를 사용하는 것이 좋다. 상기 셀룰로오스 수지 유도체는 메톡시 치환도가 1.3 ~ 2.0이고, 히드록시프로필 몰 치환도가 0.1 ~ 0.35인 것이 좋다.In addition, the liquid cellulose derivative using the liquid cellulose resin is also included in the scope of the present invention, which is preferably phthalate (Phthalate) 20.0 to 35.0% by weight, more preferably 25.0 to 32.0% by weight is most suitable. In the case of 20.0 wt% or less, the phthalate group is not regularly distributed in the substituent of cellulose, and in the case of 35.0 wt% or more, the remaining phthalate group remains as an impurity, so it is preferable to use the above range. The cellulose resin derivative may have a methoxy substitution degree of 1.3 to 2.0 and a hydroxypropyl molar substitution degree of 0.1 to 0.35.
특히, 프탈레이트가 치환된 액상 셀룰로오스 유도체를 사용하는 경우, 가소제 등의 첨가제와 혼합특성이 증가되어 유리 표면에 코팅시 고르게 코팅되는 균일도가 특히 증가되어 작업성이 매우 좋고, 경제적으로 제조 가능하다.In particular, in the case of using the phthalate-substituted liquid cellulose derivative, the mixing properties of additives such as plasticizers are increased, so that the uniformity of coating evenly on the glass surface is particularly increased, so that the workability is very good and economically manufactured.
본 발명에서 상기 코팅 조성물의 제 1양태는 상기 액상 셀룰로오스 수지 2 ~ 8 중량%와 가소제 2 ~ 8 중량%, 물 65 ~ 90 중량%를 혼합한 것이다. 또는 상기 액상 셀룰로오스 수지 유도체 5 ~ 20 중량%와 가소제 2 ~ 8 중량%, 물 65 ~ 90 중량%를 혼합한 것이다.In the present invention, the first aspect of the coating composition is a mixture of 2 to 8% by weight of the liquid cellulose resin, 2 to 8% by weight of a plasticizer, and 65 to 90% by weight of water. Or 5 to 20% by weight of the liquid cellulose resin derivative, 2 to 8% by weight of plasticizer, and 65 to 90% by weight of water.
또한 본 발명의 코팅 조성물의 제 2 양태는 제 1양태에 습윤제 1 ~ 5 중량%를 더 추가한 것이다.In addition, a second aspect of the coating composition of the present invention is the addition of 1 to 5% by weight of a humectant to the first aspect.
또한 본 발명의 코팅 조성물의 제 3양태는 상기 제 1양태와 제 2 양태에 각각 유화제 0.1 ~ 3 중량%, 소포제 0.1 ~ 3 중량%를 더 추가하여 혼합하여 사용한다.In addition, in the third aspect of the coating composition of the present invention, 0.1 to 3% by weight of an emulsifier and 0.1 to 3% by weight of an antifoaming agent are further added and mixed to the first and second embodiments, respectively.
또한, 본 발명에서는 프탈레이트가 치환된 액상 셀룰로오스 유도체가 신속히 수용액화하기 위하여 알칼리 수용액을 사용할 수도 있다. 이때 알칼리 수용액은 상기 조성물에서 1 ~ 20 중량%를 사용한다.In addition, in the present invention, an aqueous alkaline solution may be used to rapidly form an aqueous solution of the cellulose derivative-substituted liquid cellulose derivative. At this time, the aqueous alkali solution is used 1 to 20% by weight in the composition.
본 발명에서 상기 가소제는 디메틸 프탈레이트(dimethyl phthalate), 디에틸 프탈레이트(diethyl phthalate), 디-2-에틸 헥실 프탈레이트(di-2-ethylhexyl phthalate), 디-n-옥틸프탈레이트(di-n-octyl phthalate), 디노닐 프탈레이트(dinonyl phthalate)와 같은 프탈릭 에스터(phthalate ester) 타입, 디이소데실 석시네이트(diisodecyl succinate), 디옥틸 에디페이트(dioctyl adipate), 디옥틸 세 바케이트(dioctyl sebacate)와 같은 디베이직 패티 에스터(dibasic fatty ester) 타입, 디에틸 글리콜 디벤조네이트(diethylene glycol dibenzoate)와 같은 글리콜 에스터(glycol ester) 타입, 폴리에틸렌 글리코올(polyethylene glycol), 디-2-에틸헥소네이트(di-2-ethylhexonate), 폴리에틸렌 글리코올 디-2-스테레이트(polyethylene glycol di-2-stearate)와 같은 폴리이서-에스터(polyether-ester) 타입, 부틸 올레이트(butyl oleate), 메틸 아세틸니시노네이트(methyl acrtylricinolate)와 같은 페티에시드(fatty acid) 타입에서 선택되는 어느 하나 이상을 사용한다. 그 함량은 2 ~ 8 중량%를 사용하는 것이 바람직하며, 2중량% 미만으로 사용하는 경우 건조된 필름의 유연성이 없어 강도가 증가하여 깨지는 현상을 초래하며, 8 중량%를 초과하는 경우 건조과정 및 코팅된 베어글라스 세정과정에서 가소제에 의한 버블현상을 초래하므로 상기 범위에서 사용하는 것이 좋다.In the present invention, the plasticizer is dimethyl phthalate, diethyl phthalate, di-2-ethylhexyl phthalate, di-n-octyl phthalate ), Phthalate ester type such as dinonyl phthalate, diisodecyl succinate, dioctyl adipate, dioctyl sebacate Dibasic fatty ester type, glycol ester type such as diethylene glycol dibenzoate, polyethylene glycol, di-2-ethylhexanate (di- 2-ethylhexonate, polyether-ester type such as polyethylene glycol di-2-stearate, butyl oleate, methyl acetyl nisinonateUse at least one selected from a type of fatty acid, such as acrtylricinolate. It is preferable to use the content of 2 to 8% by weight, and when used at less than 2% by weight, there is no flexibility of the dried film, leading to the phenomenon of cracking due to the increase in strength, and when it exceeds 8% by weight, the drying process and It is preferable to use in the above range because it causes a bubble phenomenon by the plasticizer during the coated bare glass cleaning process.
본 발명에서 상기 습윤제는 2-에틸-1-헥산올, 2-부톡시에탄올, 디프로필렌글리콜, 에틸렌글리콜, n-프로필알콜, 이소프로필알콜, 프로필렌글리콜, 폴리이서 실록산 공중합체계열 예를 들면, Wet 265(데구사)에서 선택되는 어느 하나 이상을 사용한다. 그 함량은 1 ~ 5 중량%를 사용하는 것이 바람직하며, 1 중량% 미만으로 사용하는 경우 베어글라스 코팅시 습윤현상이 발생하여 코팅이 고루 되지 않으며, 5 중량%를 초과하는 경우 코팅 습윤현상은 없어지나 습윤제로 인한 코팅면의 흘러내림 현상이 심해지므로 상기 범위에서 사용하는 것이 좋다. 본 발명은 상기 셀룰로오스와 가소제의 성분에 더하여 극성 특성을 나타내는 습윤제를 더 포함하는 것을 특징으로 하며, 이를 본 발명의 또 다른 발명으로 제시한다. 상기 극성기를 가지는 습윤제는 유리 또는 기판과의 친화력이 우수하며 코팅제에 함입시키는 경우 유리 또는 기판의 표면에 균일하게 도포되며, 적은 양으로도 충분히 흐름성이 유지되어 표면을 고르게 코팅할 수 있는 효과를 가지게 되었다.In the present invention, the humectant is 2-ethyl-1-hexanol, 2-butoxyethanol, dipropylene glycol, ethylene glycol, n-propyl alcohol, isopropyl alcohol, propylene glycol, polyacer siloxane copolymerization system. Use any one or more selected from Wet 265 (Degussa). It is preferable to use the content of 1 to 5% by weight, and if it is used below 1% by weight, the wet phenomenon occurs during the coating of the bare glass, so that the coating is not uneven. If the content exceeds 5% by weight, the coating wet phenomenon disappears. Spilling phenomenon of the coating surface due to the wetting agent is worse, so it is good to use in the above range. The present invention is characterized in that it further comprises a humectant exhibiting polar properties in addition to the components of the cellulose and the plasticizer, which is presented as another invention of the present invention. The wetting agent having the polar group has an excellent affinity with glass or a substrate and is uniformly applied to the surface of the glass or the substrate when it is incorporated into the coating agent, and maintains sufficient flowability even in a small amount to coat the surface evenly. Had.
본 발명에서 상기 유화제는 소디움라우릴 셀페이트, 폴리솔베이트, 글리세린 지방산 에스테르계열에서 선택되는 어느 하나 이상을 사용한다. 이는 액상 셀룰로오스 수지의 안정성을 주는 역할을 하는 것으로 장기보관시 셀룰로오스 액상 조성물의 분리되는 현상을 방지함과 동시에 코팅된 베어글라스의 세정과정에서 빠른 속도로 용해되는 특징을 부각시키기 위해 사용되었다. 함량은 0.1 ~ 3.0 중량%를 사용하는 것이 바람직하며, 0.1 중량% 미만으로 사용하는 경우 셀룰로오스의 액상 조성물 장기보관시 분리를 초래하며, 3.0 중량%를 초과하는 경우 코팅된 베어글라스의 세정과정에서 기포발생을 야기시키므로 상기 범위에서 사용하는 것이 좋다.In the present invention, the emulsifier is at least one selected from sodium lauryl cellulose, polysorbate, glycerin fatty acid ester series. This plays a role of providing stability of the liquid cellulose resin, and was used to prevent the phenomenon of separating the cellulose liquid composition during long-term storage, and at the same time, to highlight the feature of dissolving rapidly during the cleaning of the coated bare glass. It is preferable to use the content of 0.1 to 3.0% by weight, and when used at less than 0.1% by weight, the liquid composition of cellulose causes long-term storage, and when it exceeds 3.0% by weight, bubbles in the cleaning process of the coated bare glass It is preferable to use the above range because it causes generation.
본 발명에서 상기 소포제는 액상 셀룰로오스 제조와 베어글라스에 코팅시 분사되는 액상 조성물의 기포발생을 제어하는 목적으로 사용되었으며, 폴리이서 실록산 공중합체계열 예를들면, TEGOPREN® 5840 (데구사) 또는 실리콘 계열 예를들면, 디메티콘(시네츠사)을 사용하였다. 그 함량은 0.1 ~ 3.0 중량%를 사용하는 것이 바람직하며, 0.1 중량% 미만으로 사용하는 경우 소포제의 역할을 하지 못하며, 3.0 중량%를 초과하는 경우 소포제의 과다 현상으로 코팅물성에 영향을 미치므로 상기 범위에서 사용하는 것이 좋다.In the present invention, the antifoaming agent was used for the purpose of controlling the generation of liquid cellulose and foaming of the liquid composition sprayed upon coating the bare glass, polyser siloxane copolymerization system such as TEGOPREN ® 5840 (Degussa) or silicone-based For example, dimethicone (Sinetsu) was used. It is preferable to use the content of 0.1 to 3.0% by weight, the use of less than 0.1% by weight does not act as an antifoaming agent, if it exceeds 3.0% by weight of the antifoaming agent due to the excessive phenomenon affects the coating properties It is good to use in the range.
다음으로 본 발명의 보호용 코팅 조성물을 코팅하는 방법에 대하여 설명한다.Next, a method of coating the protective coating composition of the present invention will be described.
본 발명에 따른 코팅 조성물은 스프레이 코팅 및/또는 디핑 코팅방법을 사용할 수 있으며, 공정을 구체적으로 설명하면,The coating composition according to the present invention may use a spray coating and / or dipping coating method, when the process will be described in detail,
1) 베어글라스 또는 PCB기판을 미리 세척하는 공정;1) pre-cleaning the bare glass or PCB substrate;
2) 본 발명에 따른 보호코팅 조성물을 베어글라스 또는 PCB기판의 양면에 스프레이(spray) 및/또는 디핑 (dipping)코팅하는 공정;2) spraying and / or dipping the protective coating composition according to the present invention on both sides of the bare glass or the PCB substrate;
3) 베어글라스 또는 PCB기판에 코팅된 보호 코팅제를 가열하여 필름화 시키는 공정;3) heating and filming the protective coating coated on the bare glass or PCB substrate;
에 의해 코팅시킨다.By coating.
이때, 상기 가열온도 조건은 각각 상온 ~ 80℃에서 진행하는 것이 바람직하다.At this time, the heating temperature conditions are preferably carried out at room temperature ~ 80 ℃, respectively.
상기 코팅은 0.5 ㎛이하의 두께가 되도록 하는 것이 좋으며, 그 이유는 0.5 ㎛이상의 경우 코팅된 도막이 너무 두꺼운 관계로 이를 제거하는 세정과정이 길어지는 단점이 있기 때문에 상기의 범위를 사용하는 것이 좋다. The coating is preferably to have a thickness of 0.5 ㎛ or less, because the reason is that the coating process is too thick in the case of 0.5 ㎛ or more because it has a disadvantage in that the cleaning process to remove it is long to use the above range.
이하는 본 발명에 따른 구체적인 실시예를 들어 본 발명을 설명하는 바, 본 발명이 하기의 실시예에 의하여 한정되는 것은 아니다.Hereinafter, the present invention will be described with reference to specific examples according to the present invention, but the present invention is not limited to the following examples.
본 실시예에서 사용된 측정방법은 다음과 같다.The measuring method used in this example is as follows.
- 점도 측정 : 브룩필드 점도계(브룩필드 점도계 LV-type, UL-Adapter 부착하여 사용하였다. -Viscosity measurement: Brookfield viscometer (Brookfield viscometer LV-type, UL-Adapter attached and used.
- 분자량 측정 : GPC(gel permeation chromatography, Agilent, Waters 515 HPLC pump, Waters 2410 differential refractometer, Waters 717plus auto-sampler)를 사용하여 분자량과 분자량 분포를 측정하였다.Molecular weight measurement: Molecular weight and molecular weight distribution were measured using GPC (gel permeation chromatography, Agilent, Waters 515 HPLC pump, Waters 2410 differential refractometer, Waters 717plus auto-sampler).
- 유리전이온도(Tg) 측정 : DSC(Differential scanning calorimetry, TA Instruments, DSC 2920)를 이용 유리전이온도를 확인하였다. -Glass transition temperature (T g ) measurement: The glass transition temperature was confirmed using DSC (Differential scanning calorimetry, TA Instruments, DSC 2920).
- 분해도 측정 : TGA(Thermogravimetric Analysis, TA Instruments, TGA 2050)를 이용 열분해도를 관찰하였다. -Degradation measurement: The thermal decomposition was observed using TGA (Thermogravimetric Analysis, TA Instruments, TGA 2050).
- 용해도 측정 : 코팅된 베어글라스를 세정라인에 직접투입 pH별 용해도를 관찰하였다.-Solubility measurement: The coated bare glass was directly injected into the washing line.
- 기존 필름 제거시 베어글라스 파손 (%) : 기본 필름 도포된 베어글라스의 필름을 제거, 이에 파손되는 확률을 계산하였다.-Bare glass breakage (%) when removing the existing film: The film of the bare glass applied to the base film was removed, the probability of breakage was calculated.
- 기존 필름 제거시 베어글라스에 남아 있는 필름 잔사 (%) : 육안검사-Film residue remaining on bare glass when removing existing film (%): Visual inspection
- 기존 필름 제거 및 세정 후 베어글라스에 남아 있는 파티클 수 (갯수) : Optical microscopy를 이용하여 측정하였다.Number of particles remaining in the bare glass after removing and cleaning the existing film: The number was measured using optical microscopy.
본 발명의 실시예 1 내지 6에서 사용된 셀룰로오스는 AnyCoat A ~ F로서 그 조성은 하기 표 1과 같다. 하기 표 1에서 메톡시, 하이드록시프로필, 프탈레이트 함량 및 점도는 평균값 나타낸 것이다.Cellulose used in Examples 1 to 6 of the present invention is AnyCoat A ~ F as its composition is shown in Table 1 below. In Table 1 below, methoxy, hydroxypropyl, phthalate content and viscosity are shown as average values.
표 1 Table 1
[[ 실시예Example 1] One]
열교환기가 설치된 자켓으로 온도조절이 가능한 반응기에 탈이온수 85 중량%와 가소제로 폴리에틸렌 글리콜 5중량%, 습윤제(Wet 265, 데구사) 4중량%를 넣고 60℃에서 150rpm으로 2시간이상 교반하여 수용액을 제조하였다. 상기 수용액을 교반설비가 잘 갖추어진 설비에 옮긴 후 삼성정밀화학(주)의 셀룰로오스 수지인 AnyCoat A 5중량%를 서서히 적하시켜 잘 섞이도록 충분히 교반 한 후, 여기에 유화제(소디움라우릴 셀페이트, 대정화금) 1중량%와 소포제(디메티콘, 시네츠)를 넣고 교반하였다. 최종적으로 고형분 15%의 수용성 코팅 조성물을 제조하였다. In a jacket equipped with a heat exchanger, add 85% by weight of deionized water, 5% by weight of polyethylene glycol as a plasticizer, and 4% by weight of a wetting agent (Wet 265, Degussa) into a reactor capable of temperature control. Prepared. After transferring the aqueous solution to a well-equipped facility, 5% by weight of AnyCoat A, a cellulose resin of Samsung Fine Chemicals, was slowly added dropwise and stirred sufficiently to be mixed well, followed by an emulsifier (sodium lauryl sulfate, 1 wt% of large purified gold) and an antifoaming agent (dimethicone, Shinnets) were added thereto and stirred. Finally, a water-soluble coating composition having a solid content of 15% was prepared.
이렇게 제조된 코팅 조성물의 용해도 분석 및 유리전이온도를 측정하여 하기 표 2에 나타내었다.The solubility analysis and glass transition temperature of the coating composition thus prepared are shown in Table 2 below.
상기의 수용성 코팅 조성물을 스프레이(spray) 코팅기를 이용하여 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)에 분사 코팅하고 온도는 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. Spray coating the water-soluble coating composition on the test bare glass (370x470 mm, Samsung Corning Precision Glass) using a spray coating machine and the temperature is heated at room temperature, 60, 80, 100, 150, 200, 250 ℃ Coating work was completed.
또는 베어글라스(370x470 mm, 삼성코닝정밀유리)를 수용성 코팅 조성물이 담 긴 저장조에 담가 딥 코팅하고 이를 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. Alternatively, the bare glass (370 x 470 mm, Samsung Corning Precision Glass) was dip coated in a reservoir containing a water-soluble coating composition and then dip coated and heated at room temperature, 60, 80, 100, 150, 200, and 250 ° C to complete the coating operation.
[[ 실시예Example 2] 2]
삼성정밀화학(주)의 셀룰로오스 수지인 AnyCoat B 5중량%를 사용한 것을 제외하고는 실시예 1과 동일한 방법으로 수용성 코팅 조성물을 제조하였으며, 동일한 방법으로 스프레이(spray) 코팅 또는 저장조에 담가 딥 코팅하고 이를 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. A water-soluble coating composition was prepared in the same manner as in Example 1 except for using 5% by weight of AnyCoat B, a cellulose resin of Samsung Fine Chemicals Co., Ltd., and dip coating in a spray coating or a storage tank in the same manner. It was heated at room temperature, 60, 80, 100, 150, 200, 250 ℃ to complete the coating.
[[ 실시예Example 3] 3]
삼성정밀화학(주)의 셀룰로오스 수지인 AnyCoat C 5중량%를 사용한 것을 제외하고는 실시예 1과 동일한 방법으로 수용성 코팅 조성물을 제조하였으며, 동일한 방법으로 스프레이(spray) 코팅 또는 저장조에 담가 딥 코팅하고 이를 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. A water-soluble coating composition was prepared in the same manner as in Example 1 except for using 5% by weight of AnyCoat C, a cellulose resin of Samsung Fine Chemicals Co., Ltd., and dip coating in a spray coating or a storage tank in the same manner. It was heated at room temperature, 60, 80, 100, 150, 200, 250 ℃ to complete the coating.
[[ 실시예Example 4] 4]
삼성정밀화학(주)의 셀룰로오스 수지인 AnyCoat D 5중량%를 사용한 것을 제외하고는 실시예 1과 동일한 방법으로 수용성 코팅 조성물을 제조하였으며, 동일한 방법으로 스프레이(spray) 코팅 또는 저장조에 담가 딥 코팅하고 이를 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. A water-soluble coating composition was prepared in the same manner as in Example 1, except for using 5% by weight of AnyCoat D, a cellulose resin of Samsung Fine Chemicals Co., Ltd., and dip dip coating in a spray coating or a storage tank in the same manner. It was heated at room temperature, 60, 80, 100, 150, 200, 250 ℃ to complete the coating.
[[ 실시예Example 5] 5]
삼성정밀화학(주)의 셀룰로오스 수지인 AnyCoat E 5중량%를 사용한 것을 제외하고는 실시예 1과 동일한 방법으로 수용성 코팅 조성물을 제조하였으며, 동일한 방법으로 스프레이(spray) 코팅 또는 저장조에 담가 딥 코팅하고 이를 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. A water-soluble coating composition was prepared in the same manner as in Example 1, except that 5% by weight of AnyCoat E, a cellulose resin of Samsung Fine Chemicals Co., Ltd., was dip-coated in a spray coating or a storage tank in the same manner. It was heated at room temperature, 60, 80, 100, 150, 200, 250 ℃ to complete the coating.
[[ 실시예Example 6] 6]
열교환기가 설치된 자켓으로 온도조절이 가능한 반응기에 탈이온수 68.5 중량%와 삼성정밀화학(주)의 프탈레이트가 32중량% 치환된 셀룰로오스 수지 유도체인 AnyCoat F 15 중량%를 넣고 60℃에서 150rpm으로 교반하면서 알카리 수용액 11.5 중량%(28% NH4OH)을 서서히 투입 충분히 섞이도록 교반한다. 이에 폴리에틸렌글리코올 2.0 중량%와 유화제(소디움라우릴 셀페이트, 대정화금) 3.0중량%를 투입하여 고형분 20%의 수용성 코팅 수지를 제조하였다. In a jacket equipped with a heat exchanger, 68.5% by weight of deionized water and 15% by weight of AnyCoat F, a cellulose resin derivative substituted with 32% by weight of phthalate of Samsung Fine Chemicals Co., Ltd., were stirred at 60 rpm at 150 ° C. Slowly add 11.5% by weight of aqueous solution (28% NH 4 OH) to the mixture and stir well. 2.0% by weight of polyethylene glycol and 3.0% by weight of an emulsifier (sodium lauryl sulphate, large purified gold) were added to prepare a water-soluble coating resin having a solid content of 20%.
상기의 수용성 코팅 조성물을 스프레이(spray) 코팅기를 이용하여 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)에 분사 코팅하고 온도 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다.Spray coating of the water-soluble coating composition on the test bare glass (370x470 mm, Samsung Corning Precision Glass) using a spray coating machine and the coating by heating at room temperature, 60, 80, 100, 150, 200, 250 ℃ The work was completed.
또한, 베어글라스(370x470 mm, 삼성코닝정밀유리)를 수용성 코팅 조성물이 담긴 저장조에 담가 딥 코팅하고 이를 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하였다. In addition, the bare glass (370x470 mm, Samsung Corning Precision Glass) was dip coated in a reservoir containing a water-soluble coating composition and dip coating and heated at room temperature, 60, 80, 100, 150, 200, 250 ℃ to complete the coating work.
[[ 실시예Example 7] 7]
실시예 1에서 유화제와 소포제를 사용하지 않은 것을 제외하고는 동일하게 제조하였다.Except for not using an emulsifier and antifoaming agent in Example 1 was prepared in the same manner.
[[ 비교예Comparative example 1] One]
기존의 베어글라스 필름지를 이용하여 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)에 필름지를 상온에서 도포함으로 코팅작업을 완료하였다.The coating was completed by applying film paper at room temperature to test bare glass (370x470 mm, Samsung Corning Precision Glass) using the existing bare glass film paper.
[[ 비교예Comparative example 2] 2]
기존의 베어글라스 필름지를 이용하여 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)에 기존공정을 이용 필름지를 도포하고 베어글라스 온도를 60℃로 올려 코팅작업을 완료하였다.Using the existing bare glass film paper, the film was applied to the test bare glass (370x470 mm, Samsung Corning Precision Glass) using the existing process and the bare glass temperature was raised to 60 ° C to complete the coating work.
[[ 비교예Comparative example 3] 3]
기존의 베어글라스 필름지를 이용하여 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)에 기존공정을 이용 필름지를 도포하고 베어글라스 온도를 100℃로 올려 코팅작업을 완료하였다.Using the existing bare glass film paper, the film was applied to the test bare glass (370x470 mm, Samsung Corning Precision Glass) using the existing process, and the bare glass temperature was raised to 100 ° C to complete the coating work.
[[ 실험예Experimental Example 1] One]
상기 실시예 1 내지 실시예 7의 코팅 조성물이 코팅된 베어글라스 및 비교예 1 내지 3의 필름지가 부착된 베어글라스의 pH 별 용해도 및 유리전이온도(Tg)를 측정하여 하기 표 2에 나타내었다.The solubility and glass transition temperature (T g ) of each of the bare glass coated with the coating composition of Examples 1 to 7 and the bare glass to which the film paper of Comparative Examples 1 to 3 were attached are measured and shown in Table 2 below. .
표 2TABLE 2
상기 표에서 보이는 바와 같이, 본 발명에 따른 코팅 조성물은 pH 1.2 내지 pH 13.0의 수용액에서 용해되므로, 기존의 코팅제에 비하여 환경오염 없이 쉽게 제거할 수 있는 특징이 있다.As shown in the table, since the coating composition according to the invention is dissolved in an aqueous solution of pH 1.2 to pH 13.0, there is a feature that can be easily removed without environmental pollution compared to conventional coatings.
[[ 실험예Experimental Example 2] 2]
실시예 1 내지 7의 수용성 코팅 조성물을 스프레이(spray) 코팅기를 이용하여 코팅된 것과, 비교예 1 내지 3을 이용하여 세정기에 투입 초순수 세정에 의해서 베어글라스 표면에 도포된 코팅을 세정(제거) 한 후 코팅액이 제거된 베어글라스를 다시 SEMICLEAN KG(회명산업) 3%의 세정조에 투입 초음파 세정으로 세정한 후 베어글라스의 크랙(%)와 파손(%), 잔사 및 파티클을 측정하여 하기 표 3에 나타내었다.The water-soluble coating composition of Examples 1 to 7 was coated with a spray coating machine, and the Comparative Examples 1 to 3 were added to the cleaner to clean (remove) the coating applied to the bare glass surface by ultrapure water cleaning. After the coating glass was removed, the bare glass was added to a SEMICLEAN KG 3% cleaning bath. After cleaning by ultrasonic cleaning, the cracks (%), breakage (%), residues and particles of the bare glass were measured. Indicated.
표 3TABLE 3
표에서 보이는 바와 같이 본 발명에 따른 실시예의 경우 코팅 제거시 크랙 또는 파손이 발생하지 않는 것을 알 수 있었으며, 세정 후 잔사 또는 파티클이 전혀 남아있지 않는 것을 알 수 있었다. 비교예 1-3의 경우 잔사되는 것은 기존 필름 지의 슬립에이젼트로 사용되는 유라카마이드로 인하여 잔사가 되는 것을 알 수 있었다.As shown in the table, in the case of the embodiment according to the present invention, it was found that no crack or breakage occurred when the coating was removed, and no residue or particles remained after cleaning. In Comparative Example 1-3, the residue was found to be residue due to the uracamide used as a slip agent of the conventional film paper.
[[ 실험예Experimental Example 3] 3]
실시예 1 내지 7의 수용성 코팅 조성물을 스프레이(spray) 코팅기를 이용하여 코팅된 것과, 비교예 1 내지 3을 온도별로 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하여 상태를 관찰한 후 표 4에 나타내었다. Coating the water-soluble coating composition of Examples 1 to 7 using a spray coating machine, and Comparative Examples 1 to 3 by heating at room temperature, 60, 80, 100, 150, 200, 250 ℃ by temperature It is shown in Table 4 after the completion of state observation.
표 4Table 4
상기 표에서 보이는 바와 같이, 본 발명에 따른 코팅 조성물의 경우 코팅온도가 100 ℃이상인 경우 약간의 황변이 발생하다가 그 이상의 온도에서 불투명하게 되는 것을 알 수 있었으나 종래의 필름을 사용하는 경우 저온에서도 불투명해지는 것을 알 수 있었다.As shown in the above table, in the case of the coating composition according to the present invention, when the coating temperature is 100 ° C. or more, a slight yellowing occurs, but it becomes opaque at a higher temperature. However, when using a conventional film, it becomes opaque even at a low temperature. I could see that.
[[ 실험예Experimental Example 4] 4]
실시예 1 내지 7의 수용성 코팅 조성물을 스프레이(spray) 코팅기를 이용하여 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)에 분사 코팅하고 코팅 도포된 베어글래스(A)와 수욕조에 담가 테스트용 베어글라스(370x470 mm, 삼성코닝정밀유리)를 코팅한 베어글라스(B)를 각각 기존의 필름 제거공정 없이 세정기에 투입 초순수 세정에 의해서 베어글라스 표면에 도포된 코팅을 세정(제거) 한 후 코팅액이 제거된 베어글라스를 다시 SEMICLEAN KG(회명산업) 3%의 세정조에 투입 초음파 세정으로 세정한 후 코팅된 표면의 녹는 속도를 측정하여 하기 표 5에서 비교하였다.Spray coating of the water-soluble coating composition of Examples 1 to 7 in a test bare glass (370x470 mm, Samsung Corning Precision Glass) using a spray coating machine and immersed in the bare glass (A) and the water bath coated with a coating Insert bare glass (B) coated with bare glass (370x470 mm, Samsung Corning Precision Glass) into the cleaner without the conventional film removal process. After cleaning (removing) the coating applied to the bare glass surface by ultrapure water cleaning, The removed bare glass was again put into a washing tank of SEMICLEAN KG (Himyung Industrial Co., Ltd.) 3%, cleaned by ultrasonic cleaning, and the melting rate of the coated surface was measured and compared in Table 5 below.
표 5Table 5
상기 표에서 보이는 바와 같이, 본 발명의 코팅 조성물은 스프레이 코팅을 하는 경우와 디핑 코팅을 하는 경우 두 방법 모두 사용 가능하며, 용해도에서 큰 차이가 없는 것을 알 수 있었다.As shown in the table, the coating composition of the present invention can be used both when spray coating and dipping coating, it can be seen that there is no significant difference in solubility.
[[ 실험예Experimental Example 5] 5]
실시예 1 내지 7의 수용성 코팅 조성물을 수욕조에 담가(dipping) 코팅된 것과, 비교예 1 내지 3을 온도별로 상온, 60, 80, 100, 150, 200, 250℃에서 가열하여 코팅작업을 완료하여 상태를 관찰한 후 하기 표 6에 나타내었다.Dipping and coating the water-soluble coating composition of Examples 1 to 7 in a water bath, and Comparative Examples 1 to 3 by heating at room temperature, 60, 80, 100, 150, 200, 250 ℃ to complete the coating operation After observing the state is shown in Table 6.
표 6Table 6
상기 표에서 보이는 바와 같이, 디핑 코팅을 하는 경우 100 ℃에서 황변이 발생하지 않았으며, 150℃ 이상에서 불투명한 것을 알 수 있었다.As shown in the table, when the dipping coating, yellowing did not occur at 100 ℃, it was found that at 150 ℃ or more opaque.
상술한 바와 같이, 본 발명에 의한 액상 셀룰로오스 수지 및 그 액상 유도체를 포함하는 보호 코팅제를 사용함으로써 기존 베어글라스 보호필름으로 인한 문제점(필름 도포시 필름지에 의한 잔사, 필름제거시 파손, 크랙으로 인한 문제점)개선과 PCB 기판 손상 방지 및 공기 접촉으로 인한 산화막 형성을 방지할 수 있었다. 또한 본 액상 셀룰로오스 수지 및 그 액상 유도체는 pH 1.2 내지 pH 13.0에서 녹는 특징을 지니고 있어 작업 환경 개선과 수율 향상 등 PCB기판 및 베어글라스 보호용 코팅제를 제공할 수 있다. As described above, by using a protective coating comprising a liquid cellulose resin and a liquid derivative thereof according to the present invention problems caused by the existing bare glass protective film (residue due to film paper when applying the film, breakage when removing the film, problems due to cracks) Improvements could be made to prevent damage to PCB substrates and oxide formation due to air contact. In addition, the liquid cellulose resin and its liquid derivatives are characterized by melting at pH 1.2 to pH 13.0 to provide a PCB substrate and a bare glass protective coating, such as improved working environment and yield.
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