KR20070018169A - Manufacturing method of deep sea drinking microclustered water from the deep-sea water - Google Patents

Abstract

It is an object of the present invention to provide a method for producing a deeply-collected small group water (beverage), which is excellent in freshness and healthy, using deep ocean water of 200 m or less in depth.

To this end, the present invention, the deep solid material in the water by pre-treatment filtration process, such as sand filtration, micro filtration, ultra filtration after taking the deep sea water of 200m or less and warming to 20 ~ 30 ℃ (SS; Suspended solid) is removed, and then the primary pH is adjusted to a weak acidity of 5.5 to 6.5, which is sent to a nano-filtration process and supplied to the filtration membrane at an operating pressure of 20 to 25 atmospheres to provide a divalent or more mineral ( Minerals) of ^{Mg 2 +, Ca 2 +,} Fe 2 +, Fe 3+ ... The concentrated mineral water containing a lot of divalent or more minerals by separating NaCl and KCl, which is a monovalent substance, and the like, is sent to a concentrated mineral water storage tank and a decontamination process, and filtered to remove as much as 80% or more of the divalent or more minerals. Mineral water is sent to the first reverse osmosis filtration process.

In the first reverse osmosis filtration process, when the operating pressure is supplied to the reverse osmosis membrane at 50 to 60 atmospheres (atm), 99.0 to 99.7% of the salinity is removed, and the filtered demineralized water is sent to the second pH adjustment process. The unfiltered brine is sent to the brine concentrated reverse osmosis process, and the operating pressure is sent to the reverse osmosis membrane at 80-120, the concentrated brine is sent to the decontamination process, and the filtered brine is returned to the first pH adjustment process.

In the second pH adjustment process, the boron compound in water is adjusted to poly boric acid by adjusting the pH to 9-11. In the second reverse osmosis filtration process, the boron compound is supplied to the filtration membrane at an operating pressure of 10 to 15 atm. It is processed to mg / less and sent to the mineral mixing and final pH adjustment process, the brine is drained (discharged) after adjusting the pH to neutral.

In the mineral mixing and final pH adjustment process, concentrated mineral water is supplied from a concentrated mineral water storage tank, and the pH is adjusted to a range of 5.0 to 8.5 while adjusting the hardness to 100 to 300 mg / L, and sent to a small grouping process of water molecules.

In the small grouping process of water molecules, the small grouping treatment of water molecules is performed by high pressure constant voltage treatment and magnetization treatment, and the microclustered water having a ¹⁷ O-NMR value of 48 nm to 60 Hz of nuclear magnetic resonance (NMR) is in the range of 48 to 60 Hz. After the treatment, send it to the deep-dwelling group to be eaten, sterilize it, fill it in a container, package it, inspect it, and then ship it as a deep-dwelling group to be eaten.

The deep-drinking water produced in the present invention is suitable for mineral balance while treating boron, which has been a problem up to 0.2 mg / l or less, and is composed of a small group of water molecules and a surface tension. It is expected that it will be widely used in the deep water manufacturing process because of the refreshing taste and improved water taste.

 Deep ocean water, deep sea water to eat, nanofiltration, reverse osmosis filtration, subpopulation water, nuclear magnetic resonance

Description

Manufacturing method of deep sea drinking microclustered water from the deep-sea water}

1 is a process chart of deep subpopulations eaten from deep sea water

Figure 2 is a process chart for adjusting the mineral balance in concentrated mineral water

3 is a small grouping process chart of water molecules

4 is a model diagram of an aggregate of water molecules

<Explanation of symbols for main parts of drawing>

One; Concentrated mineral water storage tank 2; Mineral reaction tower

3; Filler 4; Diffuser

5; Concentrated mineral water transfer pump with adjusted mineral balance

10; Electronic treatment tank 11; electrode

12; Insulator 13; Stainless steel sheet

14; Foundation concrete structures 15; grounding

16; Constant voltage generator (Electron charger)

16a; Variable resistor 16b; grounding

16c; Primary winding 16d; Iron core

16e; Secondary winding 17; Intermediate Treatment Water Storage Tank

18; Intermediate treated water transfer pump 19; Charging tower

20; Filling

21; Constant Voltage Conduit Magnetizer

22; In-depth population reservoirs 23; In-depth small group transfer pump

FI; Flow indicator

PCV; Pressure control valve

pHI; pH indicator

pHIS; pH indicating switch

ORPI; Oxidation Reduction Potential Indicator

The present invention removes suspended solids (SS; Suspended solid) in water by sand filtration (sand filter), micro filtration, ultra filtration, etc. In-depth subpopulations of drinking water, which are small-scaled clusters of water molecules after removal of salts by filtration and RO filter, followed by adjustment of minerals balance. It relates to a method of manufacturing).

Deep seawater and surface seawater with a depth of 200 m or less are similar to those of salinity (NaCl) and most minerals, as shown in Table 1, "Analysis of Components of Deep Sea Water and Surface Water," but nutrients (nitrogen nitrogen, Phosphoric acid, silicon), viable cell number, and water temperature are significantly different.

Table 1 Component Analysis of Deep Sea Water and Surface Sea Water

            Item   Deep ocean water     Surface seawater General item Water temperature （℃） 9 16.5-24.0 pH 7.80 8.15 DO dissolved oxygen (mg / L) 7.80 8.91 TOC Organic Carbon (mg / L) 0.962 1.780 Soluble evaporation residue (mg / L) 40750 37590 M-alkalido (mg / L) 114.7 110.5 Major element Cℓ chloride ion (wt%) 2.237 2.192 Na sodium (wt%) 1.080 1.030 Mg magnesium (wt%) 0.130 0.131 Ca Calcium (mg / L) 456 441 K potassium (mg / L) 414 399 Br cancel (mg / L) 68.8 68.1 Sr Strontium (mg / L) 7.77 7.61 B boron (mg / L) 4.44 4.48 Ba barium (mg / L) 0.044 0.025 F Fluorine (mg / L) 0.53 0.56 SO₄ (mg / L) 2833 2627 Nutrients NH₄ ammonia nitrogen (mg / L) 0.05 0.03 NO₃Nitrate Nitrate (mg / L) 1.158 0.081 PO₄ Phosphate (mg / L) 0.177 0.028 Si silicon (mg / L) 1.89 0.32 Trace elements Pb lead (μg / L) 0.102 0.087 Cd Cadmium (μg / L) 0.028 0.008 Cu copper (μg / L) 0.153 0.272 Fe iron (μg / L) 0.217 0.355 Mn Manganese (μg / L) 0.265 0.313 Ni nickel (μg / L) 0.387 0.496 Zn Zinc (μg / L) 0.624 0.452 As Arsenic (μg / L) 1.051 0.440 Mo molybdenum (μg / L) 5.095 5.555 Bacteria Viable count (pcs / ml) 10² 10³ to 10⁴

※ The above analysis data is obtained by analyzing the deep seawater and surface seawater of 374m below the Murodo-Gap seabed in Kochi Prefecture, Japan.

The water temperature of deep ocean water is almost constant throughout the year, and the surface water temperature of sea surface water is 16 ℃ ~ 28 ℃, but the water temperature of 374m deep water is 9 ℃, which shows low temperature stability and is low in plankton, microorganisms, especially pathogenic bacteria. There is cleanliness.

Deep seawater was not detected in the test of 10 kinds of bacteria including pathogenic Escherichia coli and pathogenic virus. The total viable count is clean water from 1/10 to 100% of surface water.

In addition, deep sea water contains about 5 to 10 times more inorganic nutrients than surface water and contains more than 70 different minerals, which can be harmful if consumed in large quantities. Deep mineral water, which contains only a small amount, has a deep relationship to human health, such as copper and zinc, which are essential trace elements.

In addition, deep sea water is matured for a long period of time at low temperature and high pressure in the deep sea, and the organic content is low and pH is lower than surface water (around pH 7.8), and it is a cluster of water molecules compared to terrestrial or mineral water. ) Has a small characteristic.

Therefore, deep sea water is considered to be a good drink if only salt is properly removed.

The conditions for producing high quality beverages using deep sea water are as follows.

1. It should not contain harmful substances.

Unhealthy organic chlorine compounds, pesticides, heavy metal ions (arsenic, lead, cadmium, mercury, chromium…), bacteria, viruses… It should not contain harmful substances such as

2. Mineral balance necessary for human body should be suitable.

(1) Water having a hardness of 10 to 100 mg / l, which represents the concentration of calcium (Ca) and magnesium (Mg), is preferable.

② Water with a ratio of (Ca + K + SiO ₂ ) / (Mg + SiO ₄ ), which is an index of good water taste (OI) of 2.0 or more, tastes good.

③ Ca-0.87Na, which is the index of health (KI), is more than 5.2.

④ The concentration of evaporation residue should be 30 ～ 200㎎ / ℓ.

3. The pH ranges from 7.2 to 7.4 with weakly acidic water.

The pH of human blood is 7.3-7.45, which is weakly alkaline. The concentration of hydrogen ions in the body always maintains weak alkalinity and physiological control. Therefore, weakly alkaline water is easily absorbed by the body. Because of the easy growth of bacteria and viruses, it is best to avoid acidic foods with a pH of less than 7.3.

4. Water of microclustered water is preferred where the cluster of water molecules is subpopulated.

When the group of water molecules are small grouped, surface tension decreases, and the penetration force is improved in the cell, thereby promoting metabolism. Also, the water with good penetration power has a refreshing feeling and the taste of water is good. NMR) Water treated with ¹⁷ O-NMR values below 60 Hz is preferred.

5. Oxidation Reduction Potential (ORP) value of + 100 ~ -200㎷ is good for health.

High redox potential means strong oxidative power, while low redox potential means strong reducing power.

Water is a compound of hydrogen and oxygen, hydrogen has a strong reducing power at a potential of -420 mV, oxygen has a strong oxidation power at a potential of +820 mV, from which water shows a potential of -420 mV to +820 mV, The potential of water in the state of no reduction is +200 mV between the potentials of hydrogen and oxygen.

Although the potential of the biological water varies slightly from person to person, depending on the part of the human body and the state of health, it usually shows a minus potential of 0 mV or less. The potential rises, and as a result, the potential of urine immediately after excretion in vitro is about 0 to +100 mV in a healthy person.

The quality of the living water is a big factor in determining the health of the human body. If drinking water also changes into the living water after a few seconds, it is better to take good quality water that is not oxidized.

Normally, the potential of tap water is high in the range of +300 to +600 mV, and the healthy person's tongue is around -100 mV, so water in the range of -100 to +100 mV feels delicious, and intake of reduced water of -100 mV or less When the diuretic effect increases, blood is purified, and the osmotic pressure of water increases, solubility of minerals is significantly increased, and mineral absorption efficiency is improved. When drinking a large amount, it acts on the oxidized part of the body to improve the constitution.

Reducible water with a low redox potential (ORP) is good for health because it has the ability to oxidize cells in the body and eliminate active oxygen that promotes aging, and in particular, the redox potential value is from +100 to Water in the range of -200㎷ is good.

6. High wave water, especially water with high immune waves (免疫 波動) is good for health.

7. Water taste is good if free carbonate dissolves 3-30mg / l and dissolved oxygen 5-6mg / l.

8. The concentration of COD _Mn , which indicates the organic content, is 3 mg / l or less, the concentration of free chlorine is 0.4 mg / l or less, the odor is 3 or less, and the chromaticity is Is less than or equal to 5 degrees, turbidity is less than or equal to 2 degrees, iron is less than 0.05 mg / l, and manganese (Mn) is less than 0.01 mg / l.

9. Water temperature should be below 20 ℃.

The water temperature is correlated with the water taste, and the water temperature of 10 to 14 is the optimum water taste.

Generally, the characteristics of deep sea water refer to low temperature safety, cleanliness, eutrophicity, mineral properties, and maturation. The characteristics are as follows.

1. It is very clean and contains various minerals necessary for the human body.

The deep sea contains various minerals necessary for the human body, and it is a clean state without contaminants such as domestic wastewater and environmental hormones, with little or no pathogenic microorganisms at low temperature and high pressure without sunlight being transmitted. It's water.

2. Deep sea water has an infinite amount of mineral water and river water on land, and it can produce high quality sanitary drinks.

3. It has been shown to activate the proliferation of macrophage.

4. Aged under mineral and low temperature and high pressure for a long time, the Nuclear Magnetic Resonance (NMR) ¹⁷ O-NMR value is 75 ~ 80Hz, and the group of water molecules is smaller than 130 ~ 150Hz of ¹⁷ O-NMR value of general tap water. It is small grouped.

5. Oxidation Reduction Potential (ORP) is somewhat lower than that of regular tap water.

The redox potential of ordinary tap water has a value of +165 to + 175㎷, which is somewhat lower than that of +500 to + 700㎷.

6. Compared with surface water, deep water has a large amount of divalent trivalent iron while repeating the oxidation-reduction reaction. Therefore, when the magnetization treatment is performed with high wave water, small grouping efficiency of water molecules is increased. Can be treated with high water.

And not only has the same characteristics as described above in the treatment of deep sea water with drinking water, but also has the following problems.

1. Molecular particles such as boric acid cannot be completely removed by simple nanofiltration, reverse osmosis filtration and electrodialysis.

Since boron has a small particle size of 0.23 Å, it is difficult to process water below the standard of 0.3 mg / l by simple nanofiltration and reverse osmosis filtration. Boron compounds (H ₃ BO ₃ ) It is in the form of, and the dissociation constant pKa value is about 9, so it is almost undissolved in seawater and almost does not exist in ionic state. There is a problem that is difficult to process below / l.

2. Among the minerals contained in deep sea water, magnesium (Mg) is much higher than calcium (Ca).

3. The redox potential value is somewhat lower as +165 to +175 ㎷ compared to +500 to +700 ㎷ in general beverages such as tap water, but higher than the appropriate value at +100 to -200 ㎷.

4. Nuclear Magnetic Resonance (NMR) ¹⁷ O-NMR value is 75-80Hz, so the small grouping rate of water molecules is not very high.

In Japanese Patent Laid-Open No. 2005-52130 and Japanese Patent Laid-Open No. 2002-369671, in order to solve the problem of boron contained in the above-described deep sea water, fresh water and fresh water collected from the deep water of the deep sea water and streams are used. ), A method of mixing water such as mineral water, tap water, and the like has been proposed, but such a beverage has a problem in that it can not fully exhibit the characteristics of deep sea water.

In the case of Japanese Patent Application Laid-Open No. 2004-65196g, the treatment was performed while adjusting the conductivity to less than 10 mS / cm in an electrodialysis apparatus using a membrane that selectively permeates only monovalent ions. It was not possible to process less than 0.2mg /, and there was a problem that the concentration of Mg ion is higher than the Ca ion concentration, in the case of Japanese Patent Laid-Open Publication No. 2002-238515 while the seawater was treated by adjusting the electrical conductivity by electrodialysis. This method also did not solve the above problem.

The method of reverse osmosis filtration treatment with Amberlite resin of Japanese Patent Publication No. 2002-361246 and Japanese Patent Publication No. 2001-300264 for removing boron compound is carried out in the final stage of reverse osmosis process by three stage reverse osmosis filtration. Although a method of adjusting the pH has been proposed, these also have problems that mineral balance, small grouping of water molecules, and redox potential have not been properly solved.

In order to solve the above problems, the present invention treats the concentration of boron compound from the deep sea water to the drinking water standard value of 0.3 mg / l or less, adjusts the optimal mineral balance, and treats the population of water molecules with 5 to 6 small groups. It is an object of the present invention to provide a method for producing a deep-dip population (beverage) which is good for health and has excellent water taste by treating redox potential with reduced water in the range of -200 to +100 kV.

In order to achieve the above object, the present invention is to take the deep sea water of 200m or less depth and warm it to 20 ~ 30 ℃, sand filtration-microfiltration-pretreatment filtration step by ultrafiltration, the primary pH of 5.5 to 6.5 Adjusting to weak acidity, filtering in nanofiltration process, adjusting mineral balance of concentrated mineral water discharged from nanofiltration process, and demineralized water filtered in nanofiltration process To the brine discharged from the first reverse osmosis process to concentrate the brine by the brine concentrated reverse osmosis process, the demineralized water filtered in the first reverse osmosis process to the second pH adjustment process to send the pH to 9 ~ Adjusting to 11, sending the pH-adjusted brine to the second reverse osmosis filtration process, filtering the mineral mixture and adjusting the final pH, water molecules The step of grouping, the sterilization step, the container filling step, packaging step, is characterized in consisting of a check step.

First, considering the matters to be considered in order to manufacture a high-quality eating deep small population using the deep sea water as follows.

1. The boron compound should be treated with the drinking water standard below 0.3mg / l.

Deep sea water contains 4 to 5 mg / l of boron and is present in the form of boric acid (H ₃ BO ₃ ), and has a small particle size of about 0.23 0.2, so nanofiltration and reverse osmosis are used to treat drinking water. Since it is difficult to treat it below the standard value of 0.3mg / l, resin adsorption method, coagulation sedimentation method, and alkali treatment with pH of 9 ~ 11 are used to convert boric acid to gel boric acid and reverse osmosis. There is a method of treatment by reverse osmosis filtration, and in the present invention, a method of removing boric acid converted to polyboric acid by reverse osmosis filtration by alkali treatment is selected.

When boric acid in water is subjected to alkali treatment, it is converted to polyboric acid in gel state by the following reaction.

B (OH) ₃ + OH ^_ → [B (OH) ₄ ] ^- → [B ₃ O ₃ (OH) ₄ ] ^- → [B ₄ O ₅ (OH) ₄ ] ^2- → [B ₅ O ₆ (OH ) ₄ ] ^- … ①

2. Mineral balance should be appropriate.

The salt (mineral component) contained in the deep sea water contains 77.9 wt% of salt (NaCl), 9.6 wt% of magnesium chloride (MgCl ₂ ), 6.1 wt% of magnesium sulfate (MgSO ₄ ), 2.1 wt% of potassium chloride (KCl), In addition, it is 2.1wt%, and the concentration of magnesium (Mg) component is 1,250 ~ 1,300mg / l, and calcium (Ca) is 460 ~ 480mg / l, which has a much higher content of magnesium than calcium. There is.

In water, calcium gives a mild and mellow taste while magnesium makes bitter, potassium sour and salt salty.

In the present invention, the mineral balance in the hardness range of 10 ~ 100mg / ℓ, while the concentration of evaporation residues in the range of 30 ~ 200mg / ℓ while the good water index (OI) is 2.0 or more The mineral balance is adjusted so that the health index (KI) is above 5.2.

Index of good taste (OI) = (Ca + K + SiO ₂ ) / (Mg + SiO ₄ ). … … … ②

Index of health (KI) = Ca- 0.87 Na... … … … … … … … … … … … … … … … ③

3. Adjust the Oxidation Reduction Potential (ORP) value within the range of +100 to -200 mA.

Water with a redox potential of less than + 200㎷ is called reducing water, and reducing water has good ability to eliminate free radicals in the body, which is good for health.If the redox potential is below -200㎷, it tastes like water. In the present invention, the redox potential value is adjusted to be in the range of +100 to -200 mA.

The redox potential of deep sea water is slightly lower (+165 to +175 kPa) compared to +500 to +700 kPa of general beverages such as tap water, but higher than the appropriate value of +100 to -200 kPa.

4. Nuclear Magnetic Resonance (NMR) ¹⁷ O-NMR values are treated with microclustered water in the range of 48 to 60 Hz.

Small clusters of water molecules have been shown to decrease surface tension and improve penetration, increasing absorption into cells, and promoting metabolic activity.

Nuclear Magnetic Resonance (NMR) ^{17 One} -tenth of the N-NMR value is equal to the number of water molecules, and a small group of six groups of water molecules with ¹⁷ O-NMR values of 60 Hz It is water (小集團 水).

For tap water, the nuclear magnetic resonance ¹⁷ O-NMR value is from 130 to 150 Hz, mineral water from Lourdes and Evian in France, known as the world's most famous water, Nordenau, India in Germany Nadana of Nara, Tlacote of Mexico, and Lee Myung-su of Mt. Baekdu have nuclear magnetic resonance ¹⁷ O-NMR values of 60-70 Hz, which are lower than those of ordinary tap water. In the case of deep water, the small grouping rate is not so high at 75 to 80 Hz.

In general, nuclear magnetic resonance, such as tap water ¹⁷ O - NMR value 130~150Hz, yet can be a group of a water molecule cluster of water molecules Grand Mass this spate 13 to 15 pieces (Bound water) and la, while the ¹⁷ O - NMR value Is a microclustered water that has less than six groups of water molecules with less than six groups of water molecules below 60 Hz.

In the present invention, the population of water molecules is treated with a small group number of nuclear magnetic resonance ¹⁷ O-NMR values in the range of 48 to 60 Hz.

Hereinafter, the contents of the present invention will be described in detail with reference to the drawings.

In FIG. 1, the deep sea water is taken from the deep seabed of 200 m or less, and the intake method is to take the pipe down to 200 m or less from the ship's bottom, or install the pipe to the sea level 200 m or less, and then take it with a pump. Or, pipes are installed up to 200m below sea level, and the intake wells are installed below sea level to take water according to siphon principle.

The deep sea water collected in the sump is warmed to 20 to 30 ° C because of its low viscosity (0 to 10 ° C) and its high viscosity and low filtration efficiency.

The warming method may be supplied with heat from a boiler, or may use sea surface water in the summer.

The warmed deep ocean water is filtered through sand filter, micro filter, ultra filtration alone or a combination of the two. Pretreat the suspended solids (SS) that may cause fouling in Reverse Osmosis filter.

At this time, the filtration pressure is determined in consideration of the pressure loss of the filter and the pressure loss of the pipe according to the operating conditions.The filtration speed of sand filtration is 6-10 m / hour, and the effective diameter of the filter sand is 0.3-0.45 mm, the uniformity coefficient shall be 2.0 or less, and the thickness of the filtrate layer shall be 0.5-1.0 m.

Microfiltration and ultrafiltration are independent of the type of filtration membrane, and the supply pressure is determined in consideration of the filtration rate and the pressure loss according to the specifications of the vendor.

Deep seawater from which suspended solids have been removed from the pre-filtration process is sent to the first pH adjustment process to adjust the pH to 5.5-6.5 so that no scale is generated in the nanofiltration membrane or the reverse osmosis membrane. Zero uses hydrochloric acid (HCl) in an inorganic acid.

In the pH adjustment method, the pH is adjusted to 5.5 to 6.5 while injecting the pre-filtered deep sea water and the pH adjuster while stirring the stirring time (retention time) for 15 to 30 minutes with a propeller agitator of 180 to 360 RPM (rotation speed). Sent to the nanofiltration process.

Membrane modules of the nano filter and reverse osmosis filter used are tubular, hollow fiber, spiral, and spiral. It does not matter in any form, such as wound or plate and frame, and the material of the film is not particularly limited.

Nano filter is a solution of CaCO ₃ and CaSO ₄ dissolved in deep ocean water. As the solubility is small, the scale is formed in the membrane during the concentration of the salt in the reverse osmosis filtration process, so that the pH is adjusted from 5.5 to 6.5 in the first pH adjustment process in order to minimize the fouling phenomenon. The mineral acid, such as CaCO ₃ , CaSO ₄ , MgCl ₂ , MgSO ₄ , is removed by 90% by weight.

The pressure supplied to the nanofiltration process is 15 to 25 atm, and in the case of spiral wound type, the membrane permeation amount is 0.7 to 1.4 m 3 / m 2 · day.

In the nanofiltration process, concentrated mineral water enriched with minerals such as CaCO ₃ , CaSO ₄ , MgCl ₂ and MgSO ₄ is sent to the decontamination process along with the concentrated brine discharged from the brine concentrated reverse osmosis process. Send to (1) to adjust mineral balance, and then send to mineral mixing and final pH adjustment process to use for mineral adjustment.

In the concentrated mineral water storage tank 1, a single or two or more kinds of tuff, green tuff, rhyolite, or large-sided pumice are mixed. A mineral reaction tower 2 and a pH adjustment system are installed in which the packing 3 is charged with 20 to 40 kg per 100 m3 of the concentrated mineral water storage tank 1.

When the concentrated mineral water discharged from the nanofiltration process is supplied to the concentrated mineral water storage tank (1), the air is concentrated from the blower to the concentrated mineral water storage tank (1) with aeration intensity of 1.5 to 2.0 Nm3 (air) / m3 (crude capacity), In the lower part of the mineral reaction tower (2), by supplying 0.25 to 0.5 Nm3 of air per 20 kg of fillings, aeration is supplied to the first pH adjustment process while aeration to maintain the pH at a weak acidity of 5.5 to 6.5. The ratio of (Ca + K + SiO ₂ ) / (Mg + SiO ₄ ), which is the good water taste index (OI) of equations ( ₂ ) and ( ₃ ), is equal to or greater than 2.0, Aeration to at least 5.2.

Demineralized water filtered in the nanofiltration process is sent to the first reverse osmosis filtration process.

The operating pressure of the first reverse osmosis filtration process is supplied to the filtration membrane at 50 to 60 atm (atm), and in the case of the spiral filtration membrane, the salinity is removed from 99.0 to 99.85 wt% when the membrane permeate is operated at 0.5 to 0.8 ㎥ / m². do.

Demineralized desalted water is sent to the secondary pH adjustment process, and brine is sent to the brine concentrated reverse osmosis process.

The operating pressure of the brine supplied to the brine concentrated reverse osmosis filtration process is 80 ~ 120 atm (atm), and it is supplied to the filtration membrane. In the case of the spiral filtration membrane, the membrane permeability is 0.7 ~ 0.8㎥ / ㎡ Once concentrated in the% range, it is sent to the decontamination process, and demineralized water, which is a dehydration filtrate, is returned to the first pH adjustment process.

The primary demineralized water supplied to the secondary pH adjustment process supplies one of NaOH, NaHCO ₃ and Na ₂ CO ₃ as an alkali (Alkali) to treat unremoved boric acid with polyboric acid. The range is adjusted and sent to the second reverse osmosis filtration process.

Operation conditions of the second pH adjustment process As in the first pH adjustment process, the pH adjustment method is a first reverse osmosis while stirring with a propeller stirrer of 180 to 360 RPM (rotational speed) for 15 to 30 minutes and a stirring time (retention time). The pH is adjusted to 9-11 while injecting demineralized water and a pH adjuster in the process.

When the pH is adjusted to 9 ~ 11 in the secondary pH adjustment process and supplied to the secondary reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 10-20 atm, and in the case of the spiral filtration membrane, the membrane permeate amount is 0.6 to 0.8. The demineralized water filtered by boron concentration below 0.3mg / ℓ, which is operated at ㎥ / ㎡ · day, is sent to the mineral mixing and final pH adjustment process, and the unfiltered brine is drained to its original position below 200m after neutralization treatment. (Eject).

In the second reverse osmosis process, even if the pH is supplied in an alkaline state of 9 to ₁₁ , scale generation is not a problem because nanomaterials such as CaCO ₃ and CaSO ₄ , which generate scales, are removed in the nanofiltration process.

When the demineralized water filtered in the second reverse osmosis process flows into the mineral mixing and final pH adjustment process, the concentrated mineral water is supplied from the concentrated mineral water storage tank (1) to adjust the hardness to the range of 50 to 300 ㎎ / ℓ. While supplying the acid to be injected into the primary pH adjustment step, the pH is adjusted to 5.8 to 8.5, which is the reference value of the beverage, and sent to the electronic treatment tank 10 of the small grouping process of the water molecules.

In the mineral mixing and final pH adjustment process, the capacity of the mineral mixing and final pH adjustment tank is 20-30 minutes, and the concentrated mineral water storage tank (1) is stirred with a propeller stirrer of 180 to 360 RPM (rotation speed). Concentrated mineral water with an adjusted mineral balance is supplied, and the hardness is adjusted to a range of 50 to 300 mg / L by the electrical conductivity of the electrical conductivity meter.

Electric conductivity is related to total dissolved solids (TDS) as follows.

Electrical conductivity = (0.5 to 0.8) x TDS. … … … … … … … … … … … … … … … ④

When the electrical conductivity is 5 to 20 mS / cm, the hardness is 100 to 200 mg / l.

In the mineral mixing and final pH adjustment process, when the hardness and pH are adjusted and introduced into the electronic treatment tank 10 of the small grouping process of water molecules, a high-pressure alternating-current constant voltage is generated from an electrostatic charger (16). A voltage of 3,000 to 5,000 Volt (field strength of 0.3 to 15 KV / m) and a current of 0.4 to 1.6 μA are applied to the electrode 11 to alternately repeat the positive and negative electrostatic fields around the electrode 11. When applied to the molecule for 4 hours or more, the water molecules themselves vibrate and rotate, and when the hydrogen bonds of the water molecules are partially broken, they are sent to the intermediate treatment water storage tank 17 and the intermediate treatment water transfer pump 18 To the filling tower (19) filled with the filler 20 mixed with minerals emitting far-infrared rays, minerals emitting negative ions, magnetite or magnetic ceramics at the same weight ratio. After the treatment, the constant voltage conductor tube magnetizer 21 to the electronic treatment tank 10 after magnetizing by applying a low voltage of AC or DC in the range of 0.5 to 5V to the coil wound on the conductive tube, In-depth small group storage tank (17), which produces a small group number of microclustered water in the range of 48 to 60 Hz, when the measurement of ¹⁷ O-NMR of Nuclear magnetic resonance (NMR) is returned during transportation. ) And then sent to the sterilization process to eat deep small group transfer pump (23).

The flow rate sent from the intermediate treatment water storage tank 17 to the intermediate treatment water transfer pump 18 to the charging tower 19 and the constant voltage conductive tube magnetizer 21 and returned to the electronic treatment tank 10 is 1 to 4 times the inflow flow rate. do.

The small grouped water thus produced is treated with reduced energy having a high alkaline oxidation frequency and high energy redox potential of +100 to -200 mV.

The applied voltage of the constant voltage generator 16 is adjusted in accordance with the values of pHI (7.4-7.8) and ORPI (+100 mV or less) provided in the intermediate treatment water storage tank 17.

The capacity of the filler 20 to fill the packed tower 19 is charged so that the contact time is 30 minutes or more.

The electronic treatment tank 10 is made of stainless steel, and there is stainless steel filled with charcoal or activated charcoal having high conductivity. A net of the electrode 11, and select one of polyethylene, polyvinyl chloride (PVC), and styrofoam, which are insulators 12, and install a conductor under the insulator 12. At this time, a corrosion resistant stainless steel plate 13 is installed between the concrete structure 14, and the stainless steel plate 12 is grounded 15 to the ground.

The constant voltage conductor magnetizer 21 is in a range of 0.5 to 5 V in a coil wound around a cylindrical conductive tube made of an insulating material such as synthetic resin (PVC, PE, styrene resin, etc.), ebonite, FRP, and Bakelite. When a low voltage of AC or DC is applied, a magnetic field is formed inside the coil, and when water passes through the water, the water is treated as a deep small number of drinking water.

In the case where the capacity of the treated water is large, the electronic treatment tank 10 and the filler 20 in which the mesh of the electrode 11 of stainless steel filled with charcoal or activated carbon are embedded Charged charging tower 19 is installed in multiple stages to process.

The water treated with the deep deep population water (beverage water) treated in the small grouping process of water molecules described above is sent to the sterilization process by the deep deep water transfer pump 23 for eating, and sterilized at 120 to 135 ° C. for 0.5 to 10 minutes at high temperature. Treatment or UV sterilization.

The sterilized in-depth subpopulations are sent to a container filling process and filled into containers (cans or plastic bottles), then inspected, packaged and shipped as products.

In the case of seabed rocks (sometimes called seawater, 海洋 深層 巖 盤 水 or 海底 深層 化石 海水), excavated under 200m of island or coastal rock, Although there are some differences depending on the characteristics of the rock and soil, the Na ⁺ ions are mainly replaced with the Ca in the rock or soil, so the Na ⁺ ions are slightly decreased, and the Ca ^{2 +} ions are increased. In the above-described deep seawater treatment process using the deep sea water, the same deep seawater population can be produced by using sea bedrock water instead of deep sea water.

In the case of manufacturing deep subpopulations that take in deep sea bedrock, the contaminated sea surface water may flow into the well, so the pipes of the well should be installed up to 200m below the seabed to prevent the inflow of sea surface water. do.

As described above, in the present invention, the deep ocean water has an infinite amount, and contains various minerals useful for cleanliness and human body, and the value of ¹⁷ O-NMR of nuclear magnetic resonance under high water pressure for many years. Since the population of water molecules is aged from 7 to 8 at 75 to 80 Hz, the treatment of salt and boron within the drinking water standard limits the effect of being widely used as drinking water [water to eat, deep water to eat]. It is expected to be.

Claims (2)

After warming up to 20-30 ℃ of deep seawater collected at depths of 200 m or below, pretreatment filtration of sand filtration, microfiltration and ultrafiltration alone or a combination of two or more types is performed. The primary pH is adjusted to 5.5 to 6.5. Mineral deionized water subjected to nanofiltration and primary reverse osmosis was adjusted to 9 to 11, and demineralized water subjected to secondary reverse osmosis was concentrated to mineral minerals discharged from nanofiltration and concentrated in mineral water storage tank (1). Supplying concentrated mineral water to adjust the hardness to 50 ~ 300 ㎎ / ℓ while adjusting the pH to 5.8 ~ 8.5 When the water flows into the electronic treatment tank 10 of the small grouping process of water molecules, constant voltage generator From the (Electron charger) 16, a high-pressure AC constant voltage was applied to the electrode 11 by applying a voltage of 3,000 to 5,000 Volt (field strength of 0.3 to 15 KV / m) and a current of 0.4 to 1.6 µA for 4 hours or more. Intermediate treatment of partially cleaved hydrogen bonds Filling the filling (20) mixed with minerals emitting far-infrared rays, minerals emitting negative ions, magnetite or magnetic ceramics in the same weight ratio, respectively, sent to the water storage tank 17 and the intermediate treatment water transfer pump 18 ( Iv) sent to the charging tower 19 for processing, and then sent to a constant voltage conductive tube magnetizer 21 to coils wound around the conductive tube in an AC or DC range of 0.5 to 5V. After the magnetization treatment while applying a low voltage, some of the measured values of ¹⁷ O-NMR of Nuclear Magnetic Resonance (NMR) ranged from 48 to 60 Hz while being returned to the electronic treatment tank 10. A method for producing deep small group water which is eaten by sterilizing water treated with microclustered water. The method according to claim 1, wherein the deep subpopulations are eaten using subsea bedrock of 200 m or less instead of deep ocean water.

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