KR100850378B1 - A manufacturing method of alkaline reduced ionized water for drinking, from the deep sea water - Google Patents

Abstract

The present invention relates to a method for producing a reduced alkali ion beverage, and more particularly, to a method for producing a reduced alkali ion beverage by taking deep sea water deeper than 200 m.

To this end, the present invention is to take the deep sea water deeper than 200m depth and warm it to 20 ~ 30 ℃, and then the sand filter (micro filter) or ultra filtration (Ultra filter) Sulfate, which is a problem of scale generation in reverse osmosis filter by removing suspended solids (SS) in water by filtration combined with more than one kind, and performing nano filtration (Nano filter) Remove CaSO ₄ ) and divalent or more mineral salts, and then send them to the first reverse osmosis filtration process to send brine to the salt and mineral salt manufacturing process, and desalted filtration water to the first pH adjustment process to adjust the pH to 9-11. When the boric acid is converted to polyboric acid and sent to the secondary reverse osmosis filtration process, the filtered water from which the boron compound is removed is supplied to the cathode chamber 3 of the electrolytic apparatus 1, and a direct current is applied from the rectifier 7. It is switched to the re-water (electrolytic reduced water).

The reducing alkaline ionized water discharged from the cathode chamber (3) of the electrolysis device (1) is sent to the secondary pH adjustment and mineral adjustment tank (8), which is the only one of citric acid, tartaric acid, succinic acid, malic acid, lactic acid, ascorbic acid, gluconic acid or amino acid. Or by injecting a mixture of two or more organic acids to adjust the pH to a slightly alkaline range in the range of 7.3 to 8.5 while injecting a mineral modifier mixed with at least one type of non-reducing disaccharides such as sucrose or trehalose. After adjusting, the high-voltage constant voltage and magnetization were performed to subpopulate the cluster of water molecules to prepare a reducing alkali ion beverage.

Deep sea water, reducing alkaline ionized beverages, nanofiltration, reverse osmosis filtration, electrodialysis, electrolysis, constant voltage, magnetization

Description

A manufacturing method of alkaline reduced ionized water for drinking, from the deep sea water}

1 is a manufacturing process diagram of a reduced alkali ion beverage from deep sea water

Figure 2 is a process for adjusting the production and neutralization of the electrolytic reduced water and mineral components in the electrolysis process.

3 is a process chart for constant voltage and magnetization

<Description of the symbols for the main parts of the drawings>

One; Electrolysis device 2; Anode chamber

3; Cathode chamber 4; anode

5; Cathode 6; Diaphragm

7; Rectifier 8; Second pH adjustment and mineral adjustment tank

9; Stirrer 10; Electronic Treatment Tank Supply Pump

11; Electronic treatment tank 12; electrode

13; Insulator 14; Stainless steel sheet

15 foundation concrete structures 16; Earth

17; Constant voltage generator (electron charger)

17a; Variable resistor 17b; grounding

17c; Primary winding 17d; Iron core

17e; Secondary winding 18; Intermediate Treatment Tank

19; Magnetizer feed pump 20; Magnetizer

21; Treated water reservoir 22; Treated water transfer pump

Ⓢ; Solenoid valve FI; Flow indicator

PCV; Pressure control valve

pHI; PH indicator

pHIS; PH indicating switch

ORPI; Oxidation reduction potential indicator

ORPIS; Oxidation reduction potential indicating switch

BI; Baumedo Baume indicator

BIS; Baumedo Bay indicating switch

ECIS; Electric conductivity indicating switch

The present invention relates to a method for producing a reduced alkaline ionized beverage, and more particularly, to collect deep sea water at a depth of more than 200 m and warm it to 20 to 30 ° C, followed by sand filtration (sand filter), microfiltration ( Electrolysis of demineralized water desalted by removing suspended solids (SS) from water by micro filter), ultrafiltration, etc., and by nano-filter and reverse osmosis filter. It is sent to the cathode chamber of the device to make reductive alkaline ionized water, which is electrolytic reduction water, and then sent to a secondary pH adjustment and mineral adjustment tank, and an organic acid mixed singly or two or more of citric acid, tartaric acid, succinic acid, malic acid, lactic acid, ascorbic acid, gluconic acid or amino acid. In the pH range of 7.3 to 8.5 to adjust the pH to weakly alkaline, while reducing the mineral content in the sucrose or trehalose, which are non-reducing disaccharides. Injecting a mineral regulator mixed with one or more types in to adjust the hardness, and then a high-pressure constant voltage and magnetization process to make a small group of water molecules to produce a reducing alkaline ion beverage that can be used as a beverage It is about.

Adults 60-70% of body weight and newborn baby 80% of the body consists of water, 80% of brain cells and 92% of the retina (water) is composed of water, water waste from body temperature adjustment in the body It has various functions such as exclusion, and water is the source of great vitality improvement in the human body. Therefore, what water is consumed every day does not have a great influence on the body itself and health.

Famous waters such as Lourdes in France, Nordenau in Germany, Tracote in Mexico, and Nadana in India are known to be healthy water in the world, including cancer, rheumatism, atopy and diabetes. It is true that it is widely known that there is a therapeutic effect of incurable diseases such as the above.

Therefore, in the present invention, the pH is 7.5-8.5 and the oxidation-reduction potential (ORP) value is -150 to-using deep ocean water containing a large amount of useful minerals without being contaminated with contaminants. The present invention proposes a method for producing reducing alkaline alkaline water in the range of 250 kV.

Reducible alkaline ionized water has characteristics such as emulsification, dispersing, desorption, and reduction of surface tension. Particularly, the surface tension at 20 ° C is ordinary water. Equivalent to surface tension of 80 ° C.

Reducible alkaline ionized water generates hydrogen at the cathode side of the electrolysis device to generate high water with reducing penetration. Reducible water containing minerals such as calcium and magnesium is suitable for drinking and cooking, and abnormal fermentation in the stomach, It is known to have effects and effects such as excessive stomach acid, chronic diarrhea, indigestion, and antacids.

Deep sea water is a seawater that does not reach sunlight and does not mix with surface seawater. Sea deep water is generally called deep sea water with a depth of more than 200 m. Growth of fermented microorganisms as shown in Table 1 "Analysis of Deep Seawater and Superficial Seawater" without containing any contaminants and harmful bacteria compared to seawater. It contains various minerals such as calcium (Ca), magnesium (Mg), iron (Fe), zinc (Zn), sodium (Na), etc. There is a characteristic.

Table 1 Depth analysis of deep seawater and surface seawater

division Ulleungdo Hyunpo Deep Sea Water, Hokkaido Tokai-Mashi, Japan Deep Sea Water, Nyuzen, Toyama Prefecture, Japan Murodo, Koji Prefecture, Japan 650m deep sea water Surface waters 374m deep sea water Surface waters General Item Water temperature (℃) 0.5 23 0.5 3.2 11.5 20.3 pH 7.5 7.98 8.15 DO dissolved oxygen (mg / l) 6 8 8.1 7.80 8.91 TOC Organic Carbon (mg / L)  -  - 0.6 0.962 1.780 COD _Mn (mg / L) 0.2 0.6  -  -  - Soluble eluent residue (mg / l) 37,000 47,750 37,590 M-alkalido (mg / l)  - 114.7 110.5 Main element Cl chloride ion (wt%) 3.41 with NaCl 3.45 with NaCl 3.41 with NaCl 1.960 2.237 2.192 Na sodium (wt%) 1.080 1.080 1.030 Mg magnesium (mg / l) 1,320 1,280 1,300 1,290 1,300 1,310 Ca calcium (mg / L) 393 403 378 400 456 441 K potassium (mg / L) 380 571 380 414 399 Br Cancel (mg / L) 60 65 68.8 68.1 Sr Strontium (mg / L) 7.0 9.9 7.77 7.61 B boron (mg / L) 4.7 4.44 4.48 Ba barium (mg / l) 0.1 or less 0.010 0.044 0.025 F Fluorine (mg / l) 1.0 1.2 0.53 0.56 SO ₄ ^2- (mg / L) 2,630 2,833 2,627 Nutrient salts NH ₄ ⁺ ammonia nitrogen (mg / l) 0.05 0.05 0.03 NO ₃ ^- Nitrogen Nitrate (mg / l) 0.28 0.04 0.227 0.3 1.158 0.081 PO ₄ ^3- phosphate (mg / l) 0.06 0.012 0.175 0.176 0177 0.028 Si silicon (mg / l) 2.8 0.44 4.53 2.6 1.89 0.32 Trace element Pb lead (μg / ℓ) 0.11 0.02 0.102 0.087 Cd cadmium (µg / l) 0.05 0.03 0.028 0.008 Cu copper (µg / l) 0.26 0.10 0.153 0.272 Fe iron (㎍ / ℓ) 0.20 0.217 0.355 Mn manganese (㎍ / ℓ) 0.45 0.265 0.313 Ni nickel (µg / l) 0.36 0.31 0.387 0.496 Zn zinc (µg / l) 0.45 1.40 0.624 0.452 As arsenic (㎍ / ℓ) 0.04 1.80 1.051 0.440 Mo molybdenum (µg / l) 7.60 5.095 5.565 Cr chromium (µg / l) 0.021 0.02 Number of bacteria Number of live bacteria (dog / ml) 0 520 0 540 E. coli count (pcs / ml) voice voice voice voice

In general, deep sea water of 200m or less deep seawater does not mix with surface seawater due to high density of nutrients and high density of nutrients due to the high temperature of nutrients because Plankton and life do not grow unlike surface seawater. There are no contaminants present in the soil, and the inorganic nutrients that are very important for plant growth are low temperature stability, very low in contaminants, harmful bacteria and organic matters, and very important for plant growth. It has a good balance of minerals with abundant eutrophicity and various minerals, and has a small surface tension due to small clusters of water molecules for a long time under high pressure and low temperature. It has characteristics such as ripening matured with good permeability (water), and the details are as follows.

1. Low temperature safety

While the surface temperature of surface seawater fluctuates greatly with the seasons, deep ocean waters are stable at low temperatures without changing the water temperature with the seasons.

In particular, deep sea waters in the East Sea of Korea settled by dense differences in cold seawater that melted drift ice in the Sea of Okhotsk, off the coast of Vladivostok between Ostrov Sakhalin and Hokkaido. As the deep water flows in and blocks the Japanese archipelago, the water flow is slower than 300m, and the water temperature is 1 ~ 2 ℃ throughout the year.The deep sea water off the coast of Muroto, Kouchi Prefecture, on the Hawaiian and Japanese Pacific coasts. Compared with 8-11 degreeC, it has a characteristic low.

2. Cleanliness

Because it is deep, it is difficult to receive pollution from river water and air on land, and there are few chemicals, pollutants and bacteria.

① physical cleanliness

Physical cleanliness is said to include less suspended matter and suspended matter. Deep sea water has less suspended solids than surface seawater.

② biological cleanliness

The biggest problem in the intake of seawater is the propagation of adherent organisms. In general, in surface water intake systems, the adherent organisms propagate in the intake pipe, and the resistance of the pipe increases and it becomes impossible to take in water. The total number of viable bacteria, such as (pathogenic) microorganisms, chlorella, etc., is small, from one tenth to one hundredth of surface water.

③ chemical cleanliness

Since deep seawater does not mix with contaminated surface waters, it is not contaminated with so-called environmental pollutants such as dioxins, PCBs, organic chlorine compounds, and organic tin.

3. eutrophicity

The deep ocean water contains about 5 to 10 times more inorganic nutrients than nitrogen, phosphorus, and silicic acid, which are the nutrient sources of phytoplankton (mainly diatoms, microscopic single-celled plants with chlorophyll), which are the source of sea life compared to surface seawater. There is a characteristic that abundant salt is contained.

At depths of more than 150 m, the amount of light is less than 1%, and at further depths, phytoplankton are unable to photosynthesize, so nutrients are not consumed by phytoplankton, but accumulate and accumulate in the deeper layers below, resulting in concentrations of inorganic nutrients. high.

4. Characteristics of minerals

Sea water contains more than 70 kinds of elements, and deep sea water has such characteristics that it contains various kinds of elements.

Although there are many important elements necessary for the growth of animals and plants, they are necessary, but mineral traces that contain very small amounts of deeply related to human health, such as copper and zinc, essential trace elements that are harmful to intake in large quantities. There is a good character.

5. Aging

Deep sea water has a lower pH than surface sea water (around pH 7.8), low organic matter content, and deep sea water separates from surface sea water, resulting in small clusters of small water molecules for many years under low pressure and high pressure. Micro-clustered water (小集團 化) is the water quality is stable.

The number of populations of water molecules is measured indirectly by measuring the value of the Nuclear magnetic resonance (NMR) ¹⁷ O-NMR half-width.

In general, in the case of river water and tap water, the half-height width of nuclear magnetic resonance ¹⁷ O-NMR is 130-150∼, whereas in deep sea water, the half-width of nuclear magnetic resonance ¹⁷ O-NMR is 70-80㎐.

One-tenth of the value of the nuclear magnetic resonance ¹⁷ O-NMR half-width of water is known as the number of molecules of water, and the nuclear magnetic resonance ¹⁷ O-NMR half-width of 130-150 kPa, such as river water and tap water, is known. 13-15 water molecules are clustered by hydrogen bond, and the large water is called bound water, whereas nuclear magnetic resonance ¹⁷ O-NMR Water with a small value of half width and a small group of water molecules is called microclustered water.

Therefore, deep sea water can be a high-quality functional drink by removing salt and some harmful substances (boron) and adjusting only the mineral balance and redox potential.

Examining the conditions for the production of reducing alkaline beverages are as follows.

1. It should not contain harmful substances.

Unhealthy organic chlorine compounds, pesticides, heavy metal ions (arsenic, lead, cadmium, mercury, chromium…), bacteria, viruses… It should not contain harmful substances such as

2. Mineral balance necessary for human body should be suitable.

(1) Water having a hardness of 10 to 300 mg / L, which represents the concentration of calcium (Ca) and magnesium (Mg), is preferable.

② Water with a ratio of (Ca + K + SiO ₂ ) / (Mg + SO ₄ ), which is the index of good taste (OI), of 2.0 or more, has a good taste.

③ The index of health (KI) Ca-0.87Na value of 5.2 or more water is good for health.

④ The concentration of evaporation residue should be 30 ～ 300㎎ / ℓ.

3. The pH is 7.2 ~ 7.4 weak alkaline water is good for your health.

The pH of human blood is 7.3-7.45, which is weakly alkaline. The concentration of hydrogen ions in the body always maintains weak alkalinity and physiological control. Therefore, weakly alkaline water is easily absorbed by the body. Acidic water with a pH of less than 7 is not good because of the easy growth of bacteria and viruses.

4. Water of microclustered water is preferred where the cluster of water molecules is subpopulated.

When the group of water molecules are small grouped, surface tension decreases, and the penetration force is improved in the cell, thereby promoting metabolism. Also, the water with good penetration power has a refreshing feeling and the taste of water is good. NMR) ¹⁷ O-NMR Half width (半 値 幅) The water treated to 60 kPa or less is preferable.

5. Oxidation Reduction Potential (ORP) value of + 100 ~ -250㎷ is good for health.

Higher redox potential means higher oxidizing power, while lower redox potential means stronger reducing power.

Water is a compound of hydrogen and oxygen, hydrogen has a strong reducing power at a potential of -420 kV, oxygen exhibits a strong oxidizing power at a potential of +820 kPa, from which water represents a potential of -420 to +820 kPa. The potential of water in the state of no reduction is +200 kPa which is halfway between the potential of hydrogen and oxygen.

Although the potential of the biological water varies slightly from person to person, depending on the part of the human body and the state of health, it usually shows a minus potential of less than or equal to 0 μs. Dislocation increases, and as a result, the dislocation of urine immediately after excretion in vitro is about 0 to +100 kPa in a healthy person.

The water quality of living water is a major factor in determining the health of the human body, and drinking water also changes to the living body water after a few seconds, so it is good to take good quality water that is not oxidized.

Normally, the potential of tap water is high in the oxidation state of +300 to +600 kPa, and the tongue of a healthy person has potential of around -100 kPa, so the water in the range of -100 to +100 kPa feels delicious, and intake of reduced water of -100 kPa or less When the diuretic effect increases, blood is purified, and the osmotic pressure of water increases, solubility of minerals is significantly increased, and mineral absorption efficiency is improved. When drinking a large amount, it acts on the oxidized part of the body to improve the constitution.

Reducible water with a low redox potential (ORP) is good for health because it has the ability to oxidize cells in the body and eliminate active oxygen that promotes aging, and in particular, the redox potential value is from +100 to Water in the range of -250 kPa is good.

6. High wave water is good, especially water with high immune waves (免疫 波動) is good for health.

7. Water taste is good if free carbonate dissolves 3-30 mg / l and dissolved oxygen 5-6 mg / l.

8. The concentration of COD _Mn , which indicates the organic content, is 3 mg / l or less, the concentration of free chlorine is 0.4 mg / l or less, the odor is 3 or less, and the chromaticity is Is less than or equal to 5 degrees, turbidity is less than or equal to 2 degrees, iron is less than 0.05 mg / l, and manganese (Mn) is less than 0.01 mg / l.

9. Water temperature is 20 ℃ or less, the taste is good.

The water temperature is correlated with the water taste, the water temperature of 10 ~ 14 ℃ is the best water taste.

Generally, the characteristics of deep sea water refer to low temperature safety, cleanliness, eutrophicity, mineral properties, and maturation. The characteristics are as follows.

1. It is very clean and contains various minerals necessary for the human body.

The deep sea contains various minerals necessary for the human body, and it is a clean state with no contaminants such as living wastewater or environmental hormones, and no pathogenic microorganisms exist at low temperature and high pressure without sunlight being transmitted. It's water.

2. Deep sea water has an infinite amount of mineral water and river water on land, and it can produce high quality sanitary drinks.

3. It has been shown to activate the proliferation of macrophage.

4. Aged under mineral and low temperature and high pressure for a long time, the value of Nuclear magnetic resonance (NMR) ¹⁷ O-NMR half width is 75 ~ 80㎐, and it is 130 ~ 150㎐ of ¹⁷ O-NMR half width of general tap water. In comparison, groups of water molecules are subpopulated.

5. Oxidation Reduction Potential (ORP) is somewhat lower than that of regular tap water.

The redox potential of ordinary tap water has a value of +165 to + 175㎷, which is somewhat lower than that of +500 to + 700㎷.

6. Compared with surface water, deep water has a large amount of divalent trivalent iron while repeating the oxidation-reduction reaction. Therefore, when the magnetization treatment is performed with high wave water, small grouping efficiency of water molecules is increased. Can be treated with high water.

The human body consists of four elements, carbon (C), hydrogen (H), oxygen (O), and nitrogen (N), about 96% of the total and 4% of the minerals. Minerals are proteins, fats, carbohydrates, vitamins and one of the five major nutrients, and are part of the body. Minerals are indispensable for the adjustment of fluid volume, acid and alkalinity, and muscle and nerve function. In addition, it is deeply involved in the metabolism of carbohydrates, proteins, fats, etc., and the amount of minerals is very small, but it is indispensable for the maintenance of life. Deficiency can lead to osteoporosis, delayed intelligence development, tooth decay, back or joint pain, muscle spasms, seizures, insomnia, emotional anxiety, and high blood pressure.

In other words, minerals play an important role, which can be referred to as `` body's lubricant '' as an indispensable nutrient for the smooth movement of the body's functions, such as metabolism, hormone production, and osteoporosis. The body cannot function smoothly, and minerals can not be made in the body, so it has no choice but to supplement it with food, drinking water, salt, etc.Insufficient intake can cause deficiency and cause various diseases. In order to do this, the mineral balance is appropriate and the necessary minerals are ingested.

The constituent elements of the human body are 65% oxygen, 18% carbon, 10% hydrogen, 3% nitrogen, and important minerals: 1.5-2.1% calcium, 0.8-1.2% phosphorus, 0.3-0.4% potassium, 0.25-0.3% sulfur Trace minerals other than 0.15 to 0.2% sodium, 0.15 to 0.2% chlorine and 0.05 to 0.1% magnesium, 0.006% iron, 0.002% zinc, selenium 0.0003%, manganese 0.0003%, copper 0.00015%, urethra 0.00004%, other molybdenum, Cobalt, chromium, etc. are in extremely small amounts.

The daily requirement of minerals is calcium 600-700 mg, phosphorus 700 mg, potassium 2000 mg, sodium 1.5 g, magnesium 250-320 mg and trace minerals iron 10-12 mg, zinc 10-12 mg, copper 1.6-1.8 Mg, manganese 3.0-4.0 mg, urethra 150 µg, selenium 45-60 µg, molybdenum 25-30 µg, and chromium 30-35 µg.

In particular, the lack of calcium among the mineral components may cause osteoporosis, calcium (Ca) is a problem of lack of intake, calcium intake is required 600 ~ 700 ㎎ / day, magnesium is 250 ~ 320 ㎎ / day It is important to consume magnesium at a ratio of 2 to 2.4: 1 by weight.

In the case of drinking water, water with a ratio of (Ca + K + SiO ₂ ) / (Mg + SO ₄ ^2- ), which is a good water index (OI) of 2.0 or more, tastes good, and Ca-0.87Na, which is an index of health (KI). Water with a value of 5.2 or more is known to be good for health.

However, in the case of deep sea water, the concentration of magnesium (MgCl ₂ and MgSO ₄ ) is about three times higher than that of calcium (Ca) salt while the NaCl concentration is high.

In other words, in order to mix the minerals in food, or used as a mineral-adjusting liquid to the drinking water while at least a weight ratio of Ca / Mg 2.0 sulfuric acid ion (SO ₄ ^{2 -),} as is preferred that the low concentrations of, but in Table 1 ocean In deep water, the Ca / Mg weight ratio is 0.35 and the concentration of sulfate ion is high at about 2,800mg / ℓ. Therefore, the mineral balance of Ca / Mg and the mineral salt free of sulfate ions must be made to be used as a mineral regulator in food or drink. There is a problem that can be.

NaCl in drinking water shall remind the salty taste, magnesium (MgCl _2, MgSO ₄₎ has a bitter taste, potassium (KCl) has a sour taste, a sulfate ion (SO ₄ ^{2 -)} which is tteurige dropped mulmat to remind the acidity (酸味) On the other hand, the calcium component is characterized by softening the taste of water to improve the taste of water.

The following are the considerations to be taken into consideration when producing deep-water withdrawals.

1, yet at least a weight ratio of Ca / Mg 2.0, sulfate ion (SO ₄ ^{2 -)} and the concentration should be low.

2. Reverse osmosis filtration process causes fouling of membrane due to scale generation during operation, so that the operating conditions do not cause rise of pressure loss coefficient, drift of feed water, and deterioration of reverse osmosis membrane. You must drive.

3. A method to reduce the membrane resistance in reverse osmosis filtration should be devised with low surface tension and viscosity.

4. Heat treatment should not be carried out to prevent thermal decomposition of heat-sensitive substances such as amino acids and trehalose.

5. Inorganic mineral salts are poor in absorption efficiency, so organic complex salts are preferred.

And in addition to the above-mentioned problems of mineral balance of Ca / Mg when producing a beverage from deep sea water, there are the following problems.

1. Boric acid, known as a substance that causes disorders in the digestive or nervous system of the human body when ingested in large quantities, is a small molecule particle and cannot be completely removed by simple nanofiltration, reverse osmosis filtration, and electrodialysis.

Since boron has a small particle size of 0.23Å, it is difficult to process water below the standard of 0.3 mg / l by simple nanofiltration and reverse osmosis filtration. Boron compounds (H ₃ BO ₃₎ ), And the dissociation constant pKa has a value of about 9, which is almost undissolved in seawater and almost never in an ionic state. There is a problem that the treatment is difficult to mg / L or less.

2. The value of redox potential is + 500 ~ + 700㎷ in general drinks such as tap water, which is somewhat lower as + 165 ~ + 175㎷, but higher than the optimum value of + 100 ~ -250㎷.

3. Nuclear Magnetic Resonance (NMR) ¹⁷ The value of O-NMR half width is 75 ~ 80㎐ and the small grouping rate of water molecules is not very high.

Until the filing of the present invention, no technology related to the production or production of reducible alkaline ionized water for drinking water using deep sea water has been searched. As a method for producing electrolytic functional water using general fresh water, 11-319831 and 11-57720 are presented, but the purpose and purpose of producing electrolytically oxidized water with bactericidal properties are somewhat different from those of the present invention.

In the case of the removal of boron compounds, which are the biggest problem when treating deep sea water with drinking water, the method of reverse osmosis filtration treatment with Amberlite resin of Japanese Patent Publication No. 2002-361246 and Japanese Patent Publication No. 2001-300264 However, the method of adjusting the pH at the front end of the reverse osmosis process of the final stage while performing reverse osmosis filtration has been proposed, but there is a problem of high mineral balance, small grouping of water molecules, and an ORP value.

In the present invention, the Bomedo (° Be) of the Baume's hydrometer representing the specific gravity of seawater is expressed as a numerical value of the scale when the Bomedo hydrometer is floated in the liquid to measure the specific gravity of the liquid, Heavy bomedoes for heavy liquids and light bomedoes for light liquids that are lighter than the specific gravity of water. Among them, pure liquids are pure water. 0 ° Be, 15% saline solution to 15 ° Be, with 15 divisions between them. For liquid solution, 10% saline solution to 0 ° Be and pure water to 10 ° Be. The scale is divided into 15 equal parts between them, and BOME (° Be) is widely used as a measure of concentration because seawater approximates salt concentration (wt%).

The relationship between the Bume (° Be) and the specific gravity (d) of the liquid is

For heavy media, where the specific gravity of the liquid is heavier than the specific gravity of water,

d = 144.3 / (144.3-° Be). … … … … … … … … … … … … … … … … … ①

In the case of an alarm field where the specific gravity of the liquid is less than the specific gravity of the water,

d = 144.3 / (134.3 + ° Be). … … … … … … … … … … … … … … … … … ②

The electrical conductivity measured by the electric conductivity indicating switch (ECIS) is an indicator of the degree of conduction of an aqueous solution by conducting electricity. The unit represents the salt concentration in water. The unit is the inverse of the electrical resistivity of the aqueous solution. Corresponding Siemens / meter, and the relationship between the electrical conductivity (EC) and the total soluble salt (TSS) in water is as follows.

TSS (ppm) = 640 X EC (mm / cm). … … … … … … … … … … … … … … … ③

The double salinity concentration (NaCl ppm) can be estimated simply by the following equation (4).

Salinity concentration (NaCl ppm) = 552 x EC (cc / cm)-200. … … … … … … … … … ④

The conductivity value is expressed in units of millimenss / meter, or microsiemens / centimeter, which is an international system of units, and ㎳ / m = 10 μs / cm (or 10 μmhos / cm).

It is an object of the present invention to provide a method for producing reduced alkaline ionized water having good health and water taste by using deep sea water containing various mineral components without contaminants being contaminated at all.

In order to achieve the above object, the present invention is to collect the deep sea water deeper than 200m deep and warmed to 20 ~ 30 ℃ and sand filtration-microfiltration-ultrafiltration pretreatment step, nano filtration and pH adjustment from 9 to 11 and desalination step to remove salt from secondary reverse osmosis process, production of reducing alkaline ionized water, secondary pH adjustment and mineral adjustment step, constant voltage treatment and magnetization treatment step, sterilization, inspection, container It is characterized by producing reducing alkaline ionized water for beverages by the filling and packaging steps.

Considering the considerations for the production of reducible alkaline ionized beverages using deep sea water are as follows.

1. The boron compound should be treated with the drinking water standard below 0.3mg / l.

Deep seawater contains boron in the form of boric acid (H ₃ BO ₃ ) while containing boron in the range of 4-5 mg / l. Since boron has a small particle size of 0.23 이온, nanofiltration and reverse osmosis filtration In the final reverse osmosis filtration treatment, the pH is treated with alkali (Alkali) in the range of 9-11, so that the boric acid is in the gel state. (Poly) Convert to boric acid for treatment.

When boric acid in water is subjected to alkali treatment, it is converted into polyboric acid in gel state by the reaction of ⑤ as follows.

B (OH) ₃ + OH ^_ → [B (OH) ₄ ] ^- → [B ₃ O ₃ (OH) ₄ ] ^- → [B ₄ O ₅ (OH) ₄ ] ^2- → [B ₅ O ₆ (OH ) ₄ ] ^- … ⑤

2. Mineral balance should be suitable.

Lack of calcium among minerals may cause osteoporosis, lack of intake of calcium (Ca) is the most important problem, calcium intake required in adults is 600 ~ 700mg / day, magnesium is 250 ~ 320mg / day The weight ratio of calcium (Ca) / magnesium (Mg) is preferably ingested at a ratio of two or more.

In order to use a mineral adjustment minerals to beverages Ca / Mg ion sulfuric acid while the weight ratio is 2.0 or more of (SO ₄ ^{2 -)} preferably is of low level, however, the deep sea water, as shown in Table 1, the weight of the Ca / Mg Since the ratio of magnesium is much higher than that of calcium at 0.35 and the concentration of sulfate ions is about 2,800 mg / l, it is possible to adjust the balance of Ca / Mg and to use the mineral regulator made of the mineral salt in which the sulfate ion is removed as much as possible. It is preferable.

In water, calcium gives a mild and mellow taste while magnesium makes bitter, potassium sour and salt salty.

In the present invention, the mineral balance is adjusted to a hardness range of 10 to 1,000 mg / L, while the water balance index (OI) is 2.0 or more and the health index (KI) is 5.2 or more. Adjust it.

Index of good water taste (OI) = (Ca + K + SiO ₂ ) / (Mg + SO ₄ ). … … … ⑥

Index of health (KI) = Ca-0.87 Na... … … … … … … … … … … … … … … ⑦

3. Adjust the Oxidation Reduction Potential (ORP) value from -150 to -250∼.

Water with a redox potential of less than + 200㎷ is called reducing water, and reducing water has the ability to eliminate free radicals in the body, which is good for health.If the redox potential is less than -250㎷, it tastes like water. In the present invention, the redox potential is adjusted to be in the range of -150 to -200 mA.

The redox potential value of deep sea water is slightly lower (+165 to +175 ㎷) compared to +500 to +700 ㎷ for general beverages such as tap water, but higher than the optimum value of +100 to -250 ㎷.

4. Nuclear Magnetic Resonance (NMR) ^{17 The} O-NMR half-value width is treated with microclustered water in the range of 48 to 60 Hz.

When the cluster of water molecules is small grouped, the surface tension is decreased and the penetration is improved, so that the absorption of the cell is increased and the metabolic activity is activated.

Nuclear Magnetic Resonance (NMR) ¹⁷ 1/10 of the half-width of the O-NMR is equal to the number of molecules of water, and ¹⁷ O-NMR half-width of 60 The number of molecules is 6 microclustered water.

In the case of tap water, the nuclear magnetic resonance ¹⁷ O-NMR half-width ranges from 130 to 150 ㎐, and the mineral waters of Lourdes and Evian in France and Nordenau in Germany ), Nadana, India, and Tracote, Mexico, have a nuclear magnetic resonance ¹⁷ O-NMR half-width of 60 to 70㎐, which is lower than that of ordinary tap water. Is 75 ~ 80㎐ and small grouping rate is not high.

In general, as running water nuclear magnetic resonance ¹⁷ O-NMR half-width value of the 130~150㎐ yet, and the number of groups of water molecules, this class of molecules of water 13 to 15 open-circuit LA can combine spate (Bound water), while the ¹⁷ O The value of -NMR half-width is 60 microns or less, and the number of water molecules is 6 or less, and the water molecules are small. Microclustered water is called.

In the present invention, a population of water molecules is treated with a small number of populations whose nuclear magnetic resonance ¹⁷ O-NMR half width is in the range of 48 to 60 Hz.

Hereinafter, described in detail by the accompanying drawings as follows.

I. Pretreatment stage

1. Intake and warming process

In the pretreatment process, the deep seawater with a depth of more than 200m is taken out, and warming and pretreatment filtration are performed to smoothly carry out subsequent treatments such as nanofiltration, reverse osmosis filtration, desalination of NaCl, concentration and removal of sulfate ion do.

In FIG. 1, the deep sea water is taken in from the deep seabed deeper than 200m deep, and the intake method is to take down the pipe deeper than 200m below the seabed or install the pipe to the deeper seabed 200m deeper. It is collected by (Pump) or pipe is installed deeper than 200m below sea level, and the intake well is installed below sea level, and it is collected by siphon principle.

The deep ocean water collected in the sump is warmed to 20 ~ 30 ℃ because of its low viscosity and high filtration efficiency.

In reverse osmosis filtration, when the water temperature rises by 1 ° C, the membrane permeate increases by about 3%.

The heating method may be supplied with heat from a boiler, or may use surface water in the summer.

2. Pretreatment Filtration Process

Pretreatment filtration process is performed by sand filtration, micro filtration, or ultra filtration alone or a combination of two or more of them, followed by nanofiltration and reverse osmosis filtration. Reverse osmosis filtration (SS) removes suspended solids (SS) that can cause fouling of membranes.

At this time, the filtration pressure is determined in consideration of the pressure loss of the filter and the pressure loss of the pipe according to the operating conditions.The filtration speed of sand filtration is 6-10 m / hour, and the effective diameter of the filter sand is 0.3-0.45 mm, the uniformity coefficient shall be 2.0 or less, and the thickness of the filtrate layer shall be 0.5-1.0 m.

At this time, if the turbidity of the deep ocean water taken is 2 mg / ℓ or less, it is not necessary to sand filtration.

Micro-filter and ultra-filter are not limited to the type of filtration membrane, and the supply pressure of the pump is decided by considering the filtration speed and the pressure loss according to the vendor's specifications. do.

In microfiltration or ultrafiltration, the FI (Fouling index) value of the water supplied to the nanofiltration and reverse osmosis filtration process is treated in the range of 2-4.

The FI value is a numerical value representing the fine turbidity concentration in the target water, and is expressed by the following equation.

FI = (1-T ₀ / T ₁₅ ) x 100/15... … … … … … … … … … ⑧

T ₀ is the time required for filtration of the first 500 ml of sample water when the sample water was filtered under pressure of 0.2 MPa using a 0.45 μm microfiltration membrane, and T ₁₅ was filtered for 15 minutes in the same state as T _0. It is the time required for the filtration of 500 ml of sample water later.

II. Desalting Step

The membrane modules of nanofiltration and reverse osmosis filtration are tubular, hollow fiber, spiral wound, flat plate and Any form such as a frame may be used, and the material of the film is not particularly limited.

The material of the nanofiltration membrane may be polyamide, polypiperazineamide, polyesteramide, or water-soluble vinyl polymer crosslinked. Is a non-asymmetric membrane having a dense layer on one side of the membrane, and gradually having micropores of large pore diameter from the dense layer toward the membrane or on one side of the membrane, or on the dense layer of such asymmetric membrane. A composite membrane having a very thin separation functional layer formed of another material can be used, and piperazine polyamide-based composite membranes are preferred, but the material and structure of the membrane are not particularly limited in the present invention.

1. Nanofiltration Process

The deep seawater from which the suspended solids are removed from the pre-filtration is sent to the nanofiltration process, where the unfiltered sulfate-containing brine is discharged, and the filtered water is sent to the first reverse osmosis filtration process.

Transmission sequence of the ion in the nanofiltration membrane, if the cation is ^{Ca 2 + ≥Mg 2 +> Li} +> Na +> K +> and NH ₄ ^+, if the anion is _{^{SO 4 2 - »HCO 3 ->}} F - ^{> Cl -> Br -> NO} 3 -> and SiO _2, a sulfate ion (SO ₄ ^{2 -),} if the it is difficult to permeate than Mg ^{+ 2} and Ca ^{+ 2.}

In the first nanofiltration process, the solubility is small, such as CaCO ₃ , CaSO ₄ , and SrSO ₄ dissolved in the deep ocean water, and scale is formed in the membrane during salt concentration in the reverse osmosis filtration process. remove the ^- (SO ₄ ²⁾ the sulfate ions in order to suppress as much as possible the membrane clogging (Fouling) phenomenon.

In the first nanofiltration process, the supply pressure is 15 to 20 atmospheres (atm), which is lower than the osmotic pressure 25 atmospheres (atm) of the deep seawater with a salt concentration of 3.5wt%. If it is 0.7-1.4m <3> / m <2> * day, the membrane permeate amount will be 70 to 80% of the inflow amount.

Example 1

After warming the deep seawater of Table 1 to 25 ° C, the filtrate pretreated with FI value of 3.2 by ultrafiltration was obtained from the cross-linked polyamide of Toray Co., Ltd. When the membrane permeate was 1.18m 3 / m 2 · day by supplying pressure to the membrane at 18㎏ / ㎠G using a spiral nanofiltration membrane, the membrane permeate amount was 76% of the inflow rate. Analytical values of the components are shown in Table 2 below.

           Table 2 Analysis of Principal Components of Raw Water and Filtrate in Nanofiltration

 Item Pre-treated deep sea water (raw water)      Filtered water   % Removal      pH        7.80         7.23      - Na ⁺ (mg / L)   10,820    9,620     11.10 Cl ^- (㎎ / ℓ)   22,373   17,248     22.90 Ca ^{2 +} (㎎ / ℓ)      457      336     26.47 Mg ^{2 +} (㎎ / ℓ)    1,302    1,052     19.20 K ⁺ (mg / L)      413      356     13.80 _{^{SO 4 2 - (㎎ / ℓ}} )    2,830      602     78.73  B (mg / L)        4.44        4.43       0.23

As shown in Table 2, nano-filtration treatment of deep sea water showed almost no removal of boron compounds, and low removal rates of salts, calcium, and magnesium, such as 10-26%, but 78.73% of sulfate ions. It was quite high.

2. First Reverse Osmosis Filtration Process

When the filtered water filtered in the nanofiltration process is supplied to the first reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 50 to 60 atmospheres (atm), and in the case of the spiral filtration membrane, the membrane permeability is 0.5 to 0.8 m 3 / m 2. In operation, the salinity is removed in the range of 99.0 to 99.85wt%, the concentrated brine concentrated without filtration is sent to the salt and mineral manufacturing process, and the filtered salt desalted is sent to the first pH adjustment process.

Example 2

The pressure of 58 kg / cm 2 was determined using a spiral reverse osmosis membrane of high-pressure reverse osmosis membrane model No. SU-810 of Toray Corporation, Japan, which was filtered filtration water in the nanofiltration of Example 1. When the membrane permeated water amount was 0.70㎥ / ㎡ · day, the membrane permeated water amounted to 50% of the inflowed water amount, and as a result of filtration, the main component analysis of the water quality of the filtered demineralized water was shown in Table 3 below. Same as the content.

 Table 3 Analysis of Principal Components of Demineralized Water as Filtered Water in Primary Reverse Osmosis Filtration

 Item  Influent (Desulfate Ion Brine)    Filtrate (Deionized Water)   % Removal      pH        7.24         7.20      - Na ⁺ (mg / L)    9,620       36.2     99.62 Cl ^- (㎎ / ℓ)   17,248       68.22     99.60 Ca ^{2 +} (㎎ / ℓ)      336        0.58     99.83 Mg ^{2 +} (㎎ / ℓ)    1,052        1.86     99.82 K ⁺ (mg / L)      356        1.68     99.53 _{^{SO 4 2 - (㎎ / ℓ}} )      602        3.63     99.40  B (mg / L)        4.43        1.78     59.82

As shown in Table 3, most of the substances were removed by the reverse osmosis filtration of the deep sea water more than 99%, but the boron compound was 1.78mg / l, the removal rate was very low, below 60%, and the drinking water standard value 0.3mg / l. It was not possible to use it for beverage production because it exceeded 6 times.

3. First pH Adjustment Process

In the first pH adjustment process, one of NaOH, NaHCO ₃ and Na ₂ CO ₃ is supplied as an alkali agent to adjust the pH to a range of 9-11, and the boric acid component in the water is treated with polyboric acid for secondary reverse osmosis. Send to filtration process.

The operating conditions of the first pH adjustment process is that the pH adjustment method is to inject alkali into the demineralized water of the first reverse osmosis process while stirring with a propeller stirrer with a stirring time (retention time) for 15 to 30 minutes and 180 to 360 RPM (rotational speed). To adjust the pH to 9-11.

4. Second Reverse Osmosis Filtration Process

When the pH is adjusted to 9-11 in the first pH adjustment process and supplied to the second reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 10-20 atmospheres (atm). Boron-containing water not filtered by operation at ˜0.8 m 3 / m 2 · day was discharged to the original position deeper than 200 m after the neutralization treatment, and the filtered water filtered at the boron concentration below 0.3 mg / l, the drinking water standard, was electrolyzed. To the cathode chamber 3 of the apparatus 1.

In the second reverse osmosis filtration process, even if the pH is supplied in an alkaline state of 9 to _{11 ,} scale generation is a problem because the materials such as CaCO ₃ , CaSO _{4 , and} SrSO ₄ , which generate scale, are removed in the nanofiltration process. It doesn't work.

Example 3

In the first reverse osmosis filtration of Example 2, demineralized water, which was filtered water, was adjusted to pH 9.5 in a first pH adjustment step to convert the boron compound in water into the form of polyboric acid, followed by Toray Corporation of Japan. Low pressure reverse osmosis membrane of model No. SU-710 using a spiral reverse osmosis filtration membrane to supply pressure to the membrane at 25㎏ / ㎠G, and the membrane permeation amount was 0.72㎥ / ㎡ · day %, And the concentration of boron (B) in the filtered water (deboron water) was measured to be 0.12 mg / L or less at 0.3 mg / L boron in the beverage and used as a beverage.

III. Producing reducing alkaline ionized water

The filtered water filtered in the second reverse osmosis filtration process is supplied to the cathode chamber 3 of the electrolysis device 1 separated by the diaphragm 6 between the anode chamber 2 and the cathode chamber 3, and the anode chamber In (2), the deep sea water is supplied to the electrolyte, and 4-20 volts of direct current is applied from the rectifier 7 to supply the redox potential of the cathode chamber 3 to the oxidation-reduction potential. Reduction strong alkaline ionized water, an electrolytic reduction water produced by adjusting the current applied from the rectifier (7) with an reduction reduction potential indicating switch (ORPIS) so that the value of the reduction potential (ORP) is in the range of -150 to -250 ㎷. Is sent to the secondary pH adjustment and mineral adjustment tank (8), wherein the pH appears in the pH indicator (pH indicator, pHI) of the cathode chamber 3 is in the range of 10 to 13.

The anode chamber water supplied to the anode chamber 2 is a pH indicating switch (pHIS), and the anode chamber water is adjusted by adjusting the solenoid valve (ⓢ) at the inflow side so that the pH is in the range of 1.5 to 3.0. At this time, the redox potential value displayed on the oxidation reduction potential indicator (ORPI) generates electrolytic oxidation water in the range of +850 to +1,100 ㎷.

Mechanism of the electrochemical reaction occurring in the above-described electrolysis device 1 is as follows.

Water dissociates in the electrolyte solution as in the following reaction equation ⑨.

^{_{H 2 O ↔ 2H + + OH}} - ... … … … … … … … … … … … … … … … … … … … ⑨

Reaction in anode chamber 3

_{^{2OH - → H 2 O + [}} O] + 2e - → H 2 O + 1 / 2O 2 (g) ↑ + 2e - ... … … … … … ⑩

^{_{2Cl - (aq) → Cl 2}} (aq) + 2e - → Cl 2 (g) ↑ + 2e ... … … … … … … … … … ⑪

Anode Chamber (3) Solution Reaction

Cl _{2 ( aq )} + [O]-&gt; HClO _{( aq )} . … … … … … … … … … … … … … … … … … ⑫

Here, [O] means active oxygen dissolved in water, and O _{2 (g)} ↑ means oxygen in a state of being discharged to the atmosphere in a gaseous state.

And Cl _{2 ( aq )} refers to chlorine dissolved in water, and Cl _{2 (g)} ↑ refers to chlorine in a gaseous state.

Cathode Chamber (2) Reaction

^{_{2H 2 O + 2e - → 2OH}} - + 2 [H] → 2OH - + 2H 2 (g) ↑ ... … … … … … … … ⑬

Here, [H] means active hydrogen dissolved in water, and H _{2 (g)} ↑ means hydrogen in a state of being discharged to the atmosphere.

The material of the electrolysis device 1 is acrylic resin, polypropylene (PP), acrylonitrile butadiene styrene copolymer (PE), polyethylene (PE), polyvinylechloride (PVC), fiber glass reinforced plastic (FRP), and bakelite. Coated or lined with FRP, epoxy resin, rubber in Bakelite, Ebonite, steel or concrete structures.

An anode chamber (2), the anode (4) is installed in a corrosion resistance (耐蝕性) material while oxygen and chlorine overvoltage occurs (Overvoltage) high plate titanium (Titanium plate) _2, TiO ₂ -SnO ₂ -RuO seizures coding to DSA ( A dimensionally stable anode electrode is used, and the cathode 5 uses an electrode coated or lined with Raney nickel on a steel sheet having high hydrogen generating overvoltage.

The diaphragm 6 uses one type of resin from woven fabric, nonwoven fabric, polypropylene, polyethylene, polyolefin or perfluorosulfonic acid, and has a physical void. Alternatively, one having a void and having a function capable of transmitting and transporting charges is used as a solid electrolyte membrane and has a function capable of transmitting and transporting charges.

Example 4

The size of the anode chamber 2 is 1,000 mm (length) × 500 mm (width) × 1,000 mm (depth), and the size of the cathode chamber 3 is also 1,000 mm (length) × equal to the size of the anode chamber 2. Insulated with a diaphragm (6) of Nafion-115 perfluorosulfonic acid-based Nafion-Resin of Dupont between 500 mm (width) x 1,000 mm (depth) in size. and the positive electrode 4 is 800㎜ (width) × 1,000㎜ (height) using a DSA electrode TiO ₂ -RuO ₂ -SnO ₂ seizures coding the titanium plate of 5㎜ × (thickness), and the cathode 3 As the anode chamber 2 of the electrolytic decomposition apparatus 1 using an electrode lined with a 3 mm thick sheet of Raney nickel on a steel plate of 800 mm (width) x 1,000 mm (height) x 10 mm (thickness) Deep seawater subjected to pretreatment filtration is supplied, and deionized water filtered in the second reverse osmosis filtration process treated in Example 3 is supplied to the cathode chamber 3 at a flow rate of 1 m 3 / hr from the rectifier 7 to 6 to 10. Redox by applying DC electricity of Volt The above (ORP) value was producing a strong alkaline reducing water -200~-220㎷ range electrolytic reduced water.

At this time, pHI of the cathode chamber 2 was 12.6 to 12.8, and when the pH of pHIS of the anode chamber 2 was adjusted to be in the range of 2 to 2.5, the deep ocean water introduced was 0.82m 3 / hr, and the oxidation of ORPI was performed. Reduction potential values were +1,020 to +1,030 mA.

Ⅳ. Second pH adjustment and mineral adjustment stage

Tartaric acid, which reacts with metals (minerals) to form complex salts when reducing strong alkaline ionized water, which is electrolytic reduced water discharged from the cathode chamber 3 of the electrolysis device 1, is supplied to the secondary pH adjusting and mineral adjusting tank 8 ), Succinic acid, malic acid, citric acid, citric acid, lactic acid, ascorbic acid, ascorbic acid, gluconic acid or amino acid The concentrated brine concentrated in the reverse osmosis filtration step was prepared using a stirrer (9) while injecting the organic acid mixed above to adjust the pH to about alkaline in the range of 7.3 to 8.5. The divalent or higher mineral salts from which NaCl and KCl were removed from were prepared from sucrose or trehalose, which are nonreducing disaccharides, based on the weight of Ca / Mg in the range of 2-6. Bell Reducing properties of the mineral regulator made by mixing more than one or more kinds of mixtures in the range of 3-10 wt% by adjusting the electric conductivity indicating switch (ECIS) to the hardness of 30-1,000 mg / l. The alkaline ionized water is supplied to the electronic treatment tank 11 in the constant voltage treatment and the magnetization treatment.

The stirring is carried out by mixing and mixing the flow rate Q / volume V at a speed of 180 to 360 RPM for 0.5 to 2 hours with a stirring time (retention time) in a range of 1 to 5 minutes with a propeller stirrer.

The material of the stirrer 9 uses one of corrosion-resistant materials such as stainless steel, titanium or bronze alloy.

In the case of omitting the constant voltage treatment and the magnetization treatment step, reducing (about) alkaline ionized water having pH and hardness adjusted is sent to sterilization, inspection, container filling, and packing to prepare a reducing alkali ion beverage product.

Example 5

Reducing strong alkaline ionized water prepared in Example 4 was supplied to the secondary pH adjustment and mineral adjustment tank 8 of 800 mm (width) x 800 mm (length) x 1,000 mm (depth) at a flow rate of 1 m 3 / hr, Mineral salts supplied with ascorbic acid while stirring at Q / V = 1.5, 360 RPM with a stainless steel propeller stirrer to adjust the pH to 7.8-8.0 and mineral salts with less than 2wt% NaCl removed on a dry basis from deep sea water The mineral modifier prepared by mixing 5 wt% of trehalose with the addition of calcium agent to Ca / Mg was adjusted to 4, and injected with ECIS while adjusting the conductivity to the range of 250 to 260 kW / cm. Water quality analysis values are shown in Table 4 below.

Table 4 Analysis of Water Quality of Reducing Alkaline Ionized Water with pH and Mineral Adjustment

   Item  Reducing alkaline ionized water  Remarks (Water Standard)          pH     7.9    5.8 to 8.5  Conductivity (㎲ / ㎝)   256 Redox potential value (㎷)  -211  Hardness (mg / ℓ)   212.6  300 or less Na ⁺ (mg / L)    31.8  200 or less (WHO standard) Cl ^- (㎎ / ℓ)    56.4  250 or less Ca ^{2 +} (㎎ / ℓ)    42.6 Mg ^{2 +} (㎎ / ℓ)    16.6 K ⁺ (mg / L)     1.1 SiO ₂ (mg / L)     2.3 _{^{SO 4 2 - (㎎ / ℓ}} )     5.1  200 or less  B (mg / l)     0.12    0.3 or less

Reviewing the results of processing of the information in Table 4 Index of good mulmat of the aforementioned formula ⑥ (OI) = (Ca + K + SiO ₂₎ / (Mg + SO ₄ ^{2 -)} was (42.6 + 1.1 + 2.3) value for the /(16.6 + 5.1) = 2.12, which is greater than or equal to 2.0 for the good water index, and the index of health (KI) in formula ⑦ = Ca- 0.87Na = 42.6 -0.87 × 31.8 ≒ 15, which is greater than or equal to 5.2 for the mineral balance. Was adjusted appropriately, and the redox potential was properly treated as -211㎷.

In addition, the concentration of boron (B) was also treated to 0.12 mg / L below the drinking water reference value 0.3 mg / l.

Ⅴ. Constant voltage and magnetization steps

In order to subpopulate the water molecular cluster of the water treated with the reducing alkaline ionized water, the high pressure constant voltage treatment and the constant voltage conductive tube of the reducing alkaline ionized water in the constant voltage treatment and the magnetization treatment process are performed. The magnetization treatment is performed by one type of magnetizer, either magnetizer or permanent magnetizer, and the cluster of water molecules is treated with microclustered water to reduce the surface tension and viscosity to improve the cooling feeling. .

In the process of combining the high pressure constant voltage treatment and the magnetization treatment in the magnetizer 20, water treated with reducing alkaline ionized water is injected into the electronic treatment tank 10, and the high voltage AC constant voltage is supplied from the constant voltage generator 17 to the electrode ( 12), a voltage of 3,000 to 5,000 volts and a current of 0.4 to 1.6 mA are applied, and the electrostatic fields of + and-are alternately repeated around the electrode 12, and the water molecules are 4 to 10 When applied for a period of time, the water molecules themselves vibrate and rotate repeatedly, thereby partially cutting the hydrogen bonds of the water molecules, and sending them to the intermediate treatment water storage tank 18 to supply the magnetizer supply pump 19 Magnetization is sent to a magnetizer 20 that applies alternating or direct current low voltage in the range of 0.5 to 5 volts to a coil wound around a constant voltage conductive tube. Afterwards, some of them were returned to the electronic treatment tank 11 to carry out nuclear magnetic resonance. When the half-value width of ¹⁷ O-NMR of the Esonance (NMR) is produced in the microclustered water in the range of 48 to 60 kV, the remainder is sent to the treated water storage tank 11 and treated. It is sent to the sterilization process of sterilization, inspection, container filling and packaging by water transfer pump 22.

The flow rate sent from the intermediate treatment water storage tank 18 to the magnetizer 20 by the magnetizer supply pump 19 and returned to the electronic treatment water tank 11 is 1 to 4 times the inflow water flow rate.

The material of the electrolytic treatment tank 11 is made of stainless steel, and the stainless steel electrode 12 filled with charcoal having high conductivity inside is made of stainless steel. To the bottom of the insulator 13 is selected from polyethylene (polyethylene), polyvinyl chloride (PVC), styrofoam (Styrofoam) is installed, and the lower part of the insulator (13) is a conductor and a corrosion-resistant material A steel sheet 14 is installed between the foundation concrete structures 15, and the stainless steel sheet 14 is grounded 16 to the ground.

The constant voltage conductor magnetizer 20 is 0.5 to 5 in a coil wound on a cylindrical conductive tube of one type of insulating material of synthetic resin (PVC, PE, styrene resin, etc.), ebonite, FRP, or Bakelite. When a low voltage of alternating current or direct current of a voltage range is applied, a magnetic field is formed inside the coil. When water (fluid) is passed through it, the water is treated as a small group water.

Instead of the constant voltage conductor tube magnetizer 20, a permanent magnet magnetizer 20 magnetized in the range of 12,000 to 15,000 G (Gauss) may be provided.

When the capacity of the treated water is large, the electronic treatment water tank 11 in which the net of the electrode 12 of stainless steel filled with charcoal is embedded is treated by installing multiple stages.

As in the present invention, when the group of water molecules by the high-pressure constant voltage treatment and the magnetization treatment is small grouped and treated with small group water, the surface tension and viscosity of the water are reduced and the penetration force is reduced. As the strength is improved, various mineral components are activated by magnetization, and when ingested, minerals having excellent absorption rate are generated.

Example 6

2,000 mm (width) × 2,000 mm (length) × 1,200 mm (depth) in which the electrode 12 containing the reduced alkaline ionized water treated in Example 5 was filled with 2 m 3 of charcoal in a stainless steel net at a flow rate of 1 m 3 / hr. It is injected into the electronic treatment tank 11 of the size, and the high voltage AC constant voltage is applied from the constant voltage generator 17 to the electrode 2 for processing for 3 hours by applying a voltage of 3,500 Volt and a current of 0.5 μA for 4.8 hours. After sending to the treated water storage tank 18 and the magnetizer supply pump 19 to the magnetizer 20 applied a direct current of 0.6 Volt range to the coil wound around the constant voltage conductive tube at a flow rate of 4 ㎥ / hr 3㎥ / hr is 1,000㎜ × (length) × ¹⁷ 1,200㎜ size of the nuclear magnetic resonance of the reducing alkaline water sent to the process water storage tank 21 of the treatment tank and conveyed to the electronic processing unit 11 1,000㎜ (width) The full width at half maximum of the O-NMR was measured and treated at 52 kHz.

Ⅵ. Sterilization, Inspection, Container Filling and Packaging

The reduced alkaline ionized water treated with the small group water in the constant voltage treatment and the magnetization treatment is subjected to one type of sterilization treatment, either ultraviolet sterilization treatment or heat sterilization treatment, and then filled into a container after inspection and packed and shipped as a reducing alkali ion beverage product. do.

As described above, the present invention is widely used in this field because it is possible to produce high-quality reducing alkaline ionized beverages from deep sea water where contaminants are not contaminated with reducing alkaline ionized beverages, which are widely known as healthy beverages. It is expected to be effective.

Claims (4)

In the production of reducible alkali ion beverages from deep sea water, Filtration of the deep sea water taken and warmed at 20 to 30 ° C. was performed using a sand filter, a micro filter, or an ultra filtration alone or a combination of two or more thereof. A pretreatment step for processing, The first reverse osmosis filtration, the pH was adjusted to a range of 9 to 11, and the desalting treatment step of sequentially treating the second reverse osmosis filtration to produce fresh water; The fresh water desalted in the desalting step is supplied to the cathode chamber 3 of the electrolysis device 1, and the deep chamber is supplied with direct current from the rectifier 7 while supplying deep sea water from the electrolyte to the anode chamber 2 ( Producing a reducing alkaline ionized water having a redox potential in the cathode chamber 3 in the range of -150 to -250 ㎷, While reducing alkaline ionized water produced in the step of producing the reduced alkaline ionized water is supplied to the secondary pH adjusting and mineral adjusting tank (8), the organic acid is injected to adjust the pH to about alkaline in the range of 7.3 to 8.5. For example, the concentrated deep brine concentrated in the reverse osmosis filtration process of the deep sea water was dissolved in the salt and mineral salt manufacturing process, and the divalent or higher mineral salt from which NaCl and KCl were removed was prepared based on the weight ratio of Ca / Mg in the range of 2-6. 2nd pH adjustment and mineral adjustment step to produce reducing alkaline ionized water with hardness adjusted to 30 ~ 1,000mg / l by injecting mineral regulator made by mixing nonreducing disaccharide in the range of 3 ~ 10wt% Wow, The reduced alkaline ionized water produced in the secondary pH adjusting and mineral adjusting steps is injected into the electronic treatment tank 10, and the high-pressure alternating-current constant voltage from the constant voltage generator 17 is built into the electronic treatment tank 10. A constant voltage process for applying a high-voltage current to the electrode 12 of stainless steel filled with wood and processing it to a constant voltage conductive tube magnetizer 20 to magnetize the process; Magnetization step, Reducing alkaline ionized water treated with small group water produced in the constant voltage treatment and magnetization treatment step by UV sterilization or heat sterilization, and then filling into the container after inspection, inspection, container filling and packaging step Method for producing a reduced alkali ion beverage from deep sea water characterized in that. The method of claim 1, wherein the deep alkaline water is reduced from the deep sea water by a treatment process in which the constant voltage treatment and the magnetization treatment step are omitted. The method of claim 1, wherein in the constant voltage processing and magnetization processing step, instead of the constant voltage conductor tube magnetizer 20, the permanent magnet magnetizer 20 magnetized in the range of 12,000 to 15,000 G (Gauss) is installed to provide Method for producing a reduced alkali ion beverage from deep water. The electronic treatment tank 11 in which the electrodes 12 of stainless steel filled with charcoal are embedded when the capacity of the treated water is large in the constant voltage treatment and magnetization treatment. A method for producing a reduced alkali ion beverage from deep sea water by installing multiple stages).

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