KR100833458B1 - Manufacturing method of reduced korean wine using deep-ocean water - Google Patents

Abstract

A manufacturing method of reduced Korean wine(Soju) is provided to improve refreshment feeling by reducing the binding number of water molecule and alcohol molecule groups, and oxidation-reduction potential value of the Soju, and enhance sanitization of the Soju by using deep-ocean water, so that the taste of the Soju is enhanced. A manufacturing method of reduced Korean wine(Soju) comprises the steps of: collecting deep-ocean water and, filtering and desalting it through nano-filtration, reverse osmosis filtration, electrodialysis or freezing method to prepare desalted deep-ocean water; subjecting the desalted deep-ocean water to electrolysis to prepare electrolytic reduced water; diluting the electrolytic reduced water with alcohol to prepare diluted alcohol; and preparing the final product by regulating alcohol concentration to 15-35% and adding into the diluted alcohol, wherein the additive is selected from inorganic salt, amino acid, glycerin, dextrin, hop, sorbitol, stevioside, aspartame, sucralose, acesulfame potassium, erythritol, xylitol, non-reducing saccharides, glucose, fructose, glutinous rice jelly, sugar alcohol, sugar syrup, oligosaccharide, honey, fusel oil, ester, aldehyde and tea.

Description

Manufacturing method of reduced Korean wine using deep-ocean water

1 is a process chart for producing reducing shochu using deep sea water

2 is a process diagram of electrolysis and pH adjustment

3 is a process chart for manufacturing the final product (reducing shochu)

4 is a half-width measure of nuclear magnetic resonance ¹⁷ O-NMR in Suzhou.

<Explanation of symbols for main parts of drawing>

One; Electrolysis device 2; Anode chamber

3; Cathode chamber 4; Anode

5; Cathode 6; Diaphragm

7; Electrolytic oxidation water storage tank 8; Electrolytic Oxidation Water Transfer Pump

9; pH adjusting tank 10; pH adjustment tank stirrer

11; Electrolytic reduced water transfer pump 12; Final alcohol concentration adjustment and additive mixing tank

13; Final alcohol concentration adjustment and additive mixing tank stirrer

14; Dilution spirit transfer pump 15; Electronic Processing Tank

16; Stainless steel wire mesh (electrode) 17; Insulator

18; Stainless steel sheet 19; Foundation concrete structure

20; Ground 21; Constant voltage generator (electron charger)

21a; Transformer 21b; Voltage regulator

21c; Primary winding 21d; Iron core

21e; Secondary winding 21f; grounding

21 g; Output line 21h; Insulation Terminal

22; Intermediate treatment tank 23; Magnetizer Supply Pump

24; Magnetizer 25; Coil former

26; Coil 27; Filling

28; Suzhou reservoir 29; Suzhou Transfer Pump

Ⓢ: Solenoid valve M: Motor

FI; Flow indicator pHI: pH indicator

pHIS; PH indicating switch

ORPI; Oxidation reduction potential indicator

ORPIS; Oxidation reduction potential indicating switch

The present invention relates to a method for producing dilute reducible shochu using deep sea water, and more particularly, to desalination by taking deep sea water deeper than 200 m deep from the sea surface. Electrolyzed demineralized water, diluted distilled alcohol with electrolytic reduced water, was deodorized and filtered. The present invention relates to a method for preparing dilution-reducing shochu by adjusting the mixing of alcohol and the concentration of alcohol, and then subpopulating the cluster of water and alcohol molecules.

Shochu is a liquor made by fermenting cereals or diluting alcohol with water. Wine, wine, Hanju, white wine Also known as the host (기 酒), Arakju. Ordinary brew alcohol (낮아 酒) has a low alcohol content, so if left for a long time will usually become vinegar (食醋) or decay (腐敗). It is a distilled liquor that is designed to eliminate these drawbacks.

It is said that the soju originated in Persian for the first time. The reason for this came to the East was that the Mongols accepted the Islamic culture of Persia and distilled it. It is said that it was a chance to bring in alcohol together. Since the soju originated in the Korean Won Dynasty, along with the traditional liquor (在 제조 酒), the variety of shochu liquor has been used as a high-quality liquor and medicinal liquor.

Hereinafter, in the present invention, the "degree" number representing the concentration of alcohol means a dose of alcohol contained in the raw dose of 100 minutes at 15 ° C, and "%" indicating a percentage means volume%. do.

There are distillation and dilution in soju, which is a dilution of 20% to 35% of the alcohol content obtained by removing almost all impurities when distilled by today's continuous distillation. .

Distillation is a product distilled by a simple distillation, which has been used for a long time, and contains a volatile substance as an impurity in raw materials and various alcoholic fermentation by-products derived therefrom. As the dilution developed suddenly due to the raw material replacement measures in the 1960s, almost no distillation was found, and in the present invention, electrolytic reduced water produced by electrolysis of demineralized water obtained by desalting deep sea water from alcohol containing about 95% alcohol concentration. After diluting with (電解 還 元 水), and subdividing the group of water and alcohol molecules, the method for producing a dilute reducing shochu is proposed.

In general, dilute shochu ferments starch ingredients such as rice and barley, and sweet potato, potato, and tapioca (Tapioca), and then distills it to make spirits, and dilutes it. It is a liquor made by adding additives to make up for it, and adding flavor and taste. As additives in the main tax method, sugar, glucose, citric acid, amino acids (Alanine, Glycine), and sorbitol (Sorbitol), inorganic salts, Stevioside, Aspartame, Sucralose, Acesulfame potassium, Erythritol, Xylitol, Tea (single leach) Only tea materials can be added).

In addition, it is prescribed by the Enforcement Decree of the Liquor Tax Act to be able to add up to 2 g in 100 ml of sake wine at 15 ° C. The amount and type of addition varies depending on the manufacturing site, but usually 0.05 to 0.15% is added.

When distilled alcohol is diluted to 20-35% alcohol with water to make shochu, the water contained in the soju is 65-80%, and the role of water may be very important.

When using purified water or groundwater (mineral water), the water used in the production of soju cannot be completely removed from contaminants and the nuclear magnetic resonance of most rivers and groundwater. NMR) ¹⁷ O-NMR half-width (130) value of 130 ~ 150 ㎐ because of the large water molecule population has a refreshing feeling, there is a problem of high oxidation reduction potential (ORP) value.

Therefore, in the present invention, electrolyzed demineralized water obtained by desalination of deep ocean water with small group of water molecules with nuclear magnetic resonance ¹⁷ O-NMR half-value width in the range of 70 to 80 ㎐ with almost no contaminants contaminated. Let's present a method of making soju by diluting alcohol with electrolytic reduced water.

Deep sea water is a deep seawater that is not exposed to sunlight and does not mix with the surface sea water. Sea deep sea water, which is deeper than 200 m in sea level, is called deep sea water. And calcium (Ca), magnesium (Mg), iron (Fe), zinc (Zn), sodium (Na) as shown in Table 1 "Analysis of Deep Sea Water and Surface Seawater" without any harmful bacteria. Nutritive salts, live bacteria, water temperature, etc., have various characteristics.

            Table 1. Depth analysis of deep sea and surface seawater

           division       Ulleungdo Hyunpo Murodo, Koji Prefecture, Japan 650m deep ocean deep water Surface waters 374m deep ocean deep water Surface waters  General Item  Water temperature (℃)  0.5  23  11.5  20.3  pH  7.15  8.1  7.98  8.15  DO dissolved oxygen (mg / l)  6  8  7.80  8.91  TOC Organic Carbon (mg / L)    -   -  0.962  1.780 COD _Mn (mg / L)  0.2  0.6    -    -  Soluble evaporation residue (mg / l)  37,000   -  47,750  37,590  M-alkalido (mg / l)    -   -  114.7  110.5  Main element  Cl chloride ion (wt%)  3.41 with NaCl  3.40 with NaCl  2.237  2.192  Na sodium (wt%)  1.080  1.030  Mg magnesium (wt%)  0.132  0.128  0.130  0.131  Ca calcium (mg / L)  393  403  456  441  K potassium (mg / L)  380  356  414  399  Br Cancel (mg / L)  65   -  68.8  68.1  Sr Strontium (mg / L)  9.9   -  7.77  7.61  B boron (mg / L)  4.7   -  4.44  4.48  Ba barium (mg / l)  0.01   -  0.044  0.025  F Fluorine (mg / l)  1.2   -  0.53  0.56 SO ₄ ^2- sulfate ion (mg / l)  2,630   -  2,833  2,627  Nutrient salts NH ₄ ⁺ ammonia nitrogen (mg / l)  0.05   -  0.05  0.03 NO ₃ ^- Nitrogen Nitrate (mg / l)  0.28  0.04  1.158  0.081 PO ₄ ^3- phosphate (mg / l)  0.16  0.026  0.177  0.028  Si silicon (mg / l)  2.8  0.44  1.89  0.32  Trace element  Pb lead (μg / ℓ)  0.11   -  0.102  0.087  Cd cadmium (µg / l)  0.05   -  0.028  0.008  Cu copper (µg / l)  0.26   -  0.153  0.272  Fe iron (㎍ / ℓ)  0.20   -  0.217  0.355  Mn manganese (㎍ / ℓ)  0.45   -  0.265  0.313  Ni nickel (µg / l)  0.36   -  0.387  0.496  Zn zinc (µg / l)  0.45   -  0.624  0.452  As arsenic (㎍ / ℓ)  0.04   -  1.051  0.440  Mo molybdenum (µg / l)  7.60   -  5.095  5.565  Cr chromium (µg / l)  0.021   - Number of bacteria  Number of live bacteria (dog / ml)    0  520   0  540  E. coli count (pcs / ml)   voice  voice    voice    voice

Deep sea water deeper than 200m deep at sea level, unlike surface sea water, is not exposed to sunlight, so Plankton and life do not proliferate. Buyoung is rich in inorganic nutrients, which are very important for low temperature stability and plant growth compared to the surface seawater, with cleanliness with little contaminants in surface seawater due to incompatibility. Good balance of minerals with good balance of benign and diverse minerals and small clusters of water molecules for a long time under high pressure and low temperature. It has characteristics such as ripening matured with good water. Specific contents are as follows.

1. Low temperature safety

While the surface temperature of surface seawater fluctuates greatly with the seasons, deep ocean waters are stable at low temperatures without changing the water temperature with the seasons.

In particular, deep sea waters in the East Sea of Korea settled by dense differences in cold seawater that melted drift ice in the Sea of Okhotsk, off the coast of Vladivostok between Ostrov Sakhalin and Hokkaido. As the deep water flowed in and blocked the Japanese archipelago, the flow was slow. At 300m or less, the water temperature was 1 ~ 2 ℃ throughout the year, compared to the deep sea water of Muroto in Kouchi Prefecture on the Hawaiian and Japanese Pacific coasts. There is a characteristic low about -11 degreeC.

2. Cleanliness

Because it is deep, it is difficult to receive pollution from river water and air on land, and there are few chemicals, pollutants and bacteria.

① physical cleanliness

Physical cleanliness is said to include less suspended matter and suspended matter, and the deep sea water contains less suspended solids than the surface seawater.

② biological cleanliness

The biggest problem in the intake of seawater is the propagation of adherent organisms. In general, in the surface seawater intake system, the adherent organisms propagate in the intake pipe, and the resistance of the pipe increases, making it impossible to take in water. The total number of viable organisms such as, (pathogenic) microorganisms, chlorella, etc. is small, from one tenth to one hundredth of surface waters.

③ chemical cleanliness

Since deep seawater does not mix with contaminated surface waters, it is not contaminated with so-called environmental pollutants such as dioxins, PCBs, organic chlorine compounds, and organic tin.

3. eutrophicity

The deep ocean water contains about 5 to 10 times more inorganic nutrients than nitrogen, phosphorus, and silicic acid, which are the nutrient sources of phytoplankton (mainly diatoms, microscopic single-celled plants with chlorophyll), which are the source of sea life compared to surface seawater. There is a characteristic that abundant salt is contained.

At a depth of 150 m or less, the amount of light is less than 1%, and at further depths, phytoplankton cannot photosynthesis, so nutrients are not consumed by phytoplankton and are accumulated in the deep layers below, High concentration of nutrients

4. Characteristics of Mineral

Sea water contains more than 70 kinds of elements, and deep sea water has such characteristics that it contains various kinds of elements.

Although there are many important elements necessary for the growth of animals and plants, they are necessary, but mineral traces that contain very small amounts of deeply related to human health, such as copper and zinc, essential trace elements that are harmful to intake in large quantities. There is a good character.

5. Aging

Deep sea water has a lower pH than surface sea water (around pH 7.8), low organic matter content, and deep sea water separates from surface sea water, causing the clusters of water molecules to nucleate for a long time under low temperature and high pressure. Magnetic Resonance ¹⁷ The half-value width of O-NMR ranges from 70 to 80 microseconds and is small in size, and the water quality is stable with microclustered water.

Water molecules form clusters by hydrogen bonds, and the number of clusters is indirect by measuring the value of nuclear magnetic resonance ¹⁷ O-NMR half-width. Measure with

In general, the half width of nuclear magnetic resonance ¹⁷ O-NMR in the case of river water and tap water is 130-150 반면, whereas in the deep sea water, the half-width of nuclear magnetic resonance ¹⁷ O-NMR is 70-80 소.

Nuclear Magnetic Resonance ¹⁷ O-NMR half-width of water is known as the number of molecules of water, and nuclear magnetic resonance ¹⁷ O-NMR half-width of 130 ~ 150㎐ is known as river water and tap water. 13-15 water molecules form a group by hydrogen bonding, and the large group of water is called bound water, whereas the value of nuclear magnetic resonance ¹⁷ O-NMR half-width ( Water with a small number of molecules of water with little ㎐) is called microclustered water.

Oxidation-reduction potential values of deep ocean waters vary slightly depending on depth and location, but are lower than that of general tap water or groundwater, although the values are -90 ° C to + 120 ° C. Because it is not in the range of 100-250 kV, deep ocean water can be of good quality for use in the production of soju by removing salts and adjusting only the redox potential to an appropriate value.

Considering the conditions of the water for producing reducing alkaline water is as follows.

1. The water used must not contain harmful substances.

Unhealthy organic chlorine compounds, pesticides, heavy metal ions (arsenic, lead, cadmium, mercury, chromium…), bacteria, viruses… It should not contain harmful substances such as

2. The pH is in the range of 7.2-7.4 weak alkaline water is good for health and tastes good.

The pH of human blood is 7.3-7.45, which is weakly alkaline. The concentration of hydrogen ions in the body always maintains weak alkalinity and physiological control. Therefore, weakly alkaline water is easily absorbed by the body. Acidic water with a pH of less than 7 is not good because of the easy growth of bacteria and viruses.

3. Water of microclustered water is preferred where the cluster of water molecules is subpopulated.

When the group of water molecules are small grouped, surface tension decreases, and the penetration force is improved in the cell, thereby promoting metabolism. Also, the water with good penetration power has a refreshing feeling and the taste of water is good. NMR) ¹⁷ O-NMR Half width (半 値 幅) The water treated to 60 kPa or less is preferable.

4. Oxidation Reduction Potential (ORP) is treated with -100 ~ -250-water.

Higher redox potential means higher oxidizing power, while lower redox potential means stronger reducing power.

Water is a compound of hydrogen and oxygen, and the potential value of hydrogen is -420 kW, which has a strong reducing power, and the potential value of oxygen shows a strong oxidation power of +820 kW, from which water is -420- + 820 kW redox. The potential value of water in the state where neither the oxidation nor the reduction is shown is +200 kPa, which is halfway between the hydrogen and oxygen potential values.

Although the potential of the biological water varies slightly from person to person, depending on the part of the human body and the state of health, it usually shows a minus potential of less than or equal to 0 μs. Dislocation increases, and as a result, the dislocation of urine immediately after excretion in vitro is about 0 to +100 kPa in a healthy person.

The water quality of living water is a major factor in determining the health of the human body, and drinking water also changes to the living body water after a few seconds, so it is good to take good quality water that is not oxidized.

Normally, the potential of tap water is high in the oxidation state of +300 to +600 kPa, and the tongue of a healthy person has potential of around -100 kPa, so the water in the range of -100 to +100 kPa feels delicious, and intake of reduced water of -100 kPa or less When the diuretic effect increases, blood is purified, and the osmotic pressure of water increases, solubility of minerals is significantly increased, and mineral absorption efficiency is improved. When drinking a large amount, it acts on the oxidized part of the body to improve the constitution.

Reducible water with a low redox potential (ORP) is good for health because it has the ability to oxidize cells in the body and eliminate active oxygen that promotes aging, and in particular, the redox potential is -100 to Water in the range -250㎷ is good.

5. High wave water is good. In particular, water with high immune waves is good for your health.

6. Water taste is good if free carbonate dissolves 3-30 mg / l and dissolved oxygen 5-6 mg / l.

7. The concentration of COD _Mn , which indicates the organic content, is 3 mg / l or less, the concentration of free chlorine is 0.4 mg / l or less, the odor is 3 or less, and the chromaticity is Should be less than 5 degrees, turbidity less than 2 degrees, iron less than 0.05 mg / l, and manganese (Mn) less than 0.01 mg / l.

8. Water temperature of 20 degrees C or less tastes good.

The water temperature is correlated with the water taste, the water temperature of 10 ~ 14 ℃ is the best water taste.

Generally, the characteristics of deep sea water refer to low temperature safety, cleanliness, eutrophicity, mineral properties, and maturation. The characteristics of the water used are as follows.

1. It is clean without harmful pollutants and harmful microorganisms.

In the deep sea, it contains various minerals necessary for the human body, does not penetrate sunlight, has low temperature and high pressure, almost no pathogenic microorganisms exist, and is free of contaminants such as domestic wastewater and environmental hormones. Exists as water.

2. The deep ocean water has an infinite quantity compared to the terrestrial mineral water and the river water, and it can sanitarily produce high quality soju.

3. It has been found to contain traces of useful substances that can activate the proliferation of macrophage such as trehalose.

4. is aged under the mineral and the low temperature and high pressure for a long period of time NMR ^{(Nuclear magnetic resonance; NMR) 17} O-NMR of the general ground water or tap water to the full width at half maximum value of the nuclear magnetic resonance 75~80㎐ ¹⁷ O-NMR half-width value of Compared with 130-150 microliters, the population of water molecules is small.

5. Oxidation Reduction Potential (ORP) value is lower than that of general tap water.

The redox potential value of deep tap water shows a lower value of +90 to +120 mA than that of general tap water, compared to +500 to +700 mA.

In particular, since iron present in the deep ocean water exists in the form of divalent trivalent iron, it can be treated with high wave water when the magnetization treatment is performed, and it can be treated with water having high efficiency of small grouping of water molecules. There are also characteristics.

Until the filing of the present invention, the technology for producing reducing soju using deep sea water has not been searched. As a method of manufacturing reducing soju using general water, the Korean Patent Registration No. 10-0618329 uses raw water as groundwater ( (Mineral water), there is a problem that can not be completely removed when contaminants are contaminated, and most of the water on the land has a problem such as a refreshing feeling because the group of water molecules are present in a large binding water have.

The present invention is to provide a method for producing a reducing soju with a small redox potential value and a small number of alcohol molecules and alcohol groups by using the deep sea water of the seabed deeper than 200m in the sea surface to solve the above problems It is an object of the present invention.

The present invention for achieving the above object, the step of taking the deep sea water of the seabed deeper than 200m depth from the sea surface to produce desalted water by desalination, producing electrolytic reduced water by electrolysis of demineralized water, electrolytic reduced water It is characterized by consisting of diluting the ethanol to produce a distilled alcohol, the final product (reducing shochu).

Take the deep sea water of the seabed deeper than 200m from the sea surface and desalination to produce demineralized water, electrolyze the demineralized water to produce electrolytic reduced water, and dilute the alcohol in electrolytic reduced water to produce dilute spirit And, the final product (reduced shochu) consists of the steps, each step relates to a method for producing a reducing shochu where each of the following steps sequentially, described in detail by the accompanying drawings as follows.

I. Desalination by taking deep ocean water and producing demineralized water

1. Intake and heating treatment process

In the pretreatment process, warm seawater and pretreatment filtration are taken to collect the deep sea water of the seabed deeper than 200m deep from the sea surface so that the subsequent treatment can be smoothly processed.

Deep sea water is taken from the deep seabed of the deep seabed deeper than 200m deep from the sea surface, and the intake method is to take down the pipe deeper than 200m below the seabed or install the pipe to the deep seabed deeper than 200m deep from the sea surface. It is withdrawn by pump, or pipe is installed from the bottom of the sea to the bottom of the sea, which is deeper than 200m, and the intake well is installed below the sea level to take the water according to the siphon principle.

The deep sea water collected in the sump is low in temperature and high in viscosity, so that the filtration efficiency is lowered. Therefore, it is heated to 20 ~ 30 ℃ and sent to the pretreatment filtration process.

In reverse osmosis filtration, when the water temperature rises by 1 ° C, the membrane permeate increases by about 3%.

The heating method may be supplied with heat from a boiler, or may use surface water in the summer.

However, the desalination treatment by the freezing method does not require warming treatment, so that the deep sea water taken is sent to the pretreatment filtration process.

2. Pretreatment Filtration Process

When the deep sea water warmed by the intake and warming process is supplied to the pretreatment filtration process, a sand filter, a micro filter, an ultra filtration alone or two or more types are used. The combined filtration results in a FI (Fouling index) value of 2 for suspended solids (SS), which can cause membrane fouling in nanofiltration and reverse osmosis filtration. It is removed in the range of ˜4 and then sent to the anode chamber 2 of the desalting step and the electrolysis step.

At this time, the filtration pressure is determined in consideration of the pressure loss of the filter and the pressure loss of the pipe according to the operating conditions.The filtration speed of sand filtration is 6-10 m / hour, and the effective diameter of the filter sand is 0.3-0.45 mm, the uniformity coefficient shall be 2.0 or less, and the thickness of the filtrate layer shall be 0.5-1.0 m.

At this time, if the turbidity of the deep ocean water taken is 2 mg / ℓ or less, it is not necessary to sand filtration.

Micro-filter and ultra-filter are not limited to the type of filtration membrane, and the supply pressure of the pump is decided by considering the filtration speed and the pressure loss according to the specification of the vendor. do.

In microfiltration or ultrafiltration, the FI (Fouling index) value of the water supplied to the nanofiltration and reverse osmosis filtration processes is treated in the range of 2 to 4, and the FI value is a numerical value representing the fine turbidity concentration in the target water. It is expressed as

FI = (1-T ₀ / T ₁₅ ) x 100/15... … … … … … … … … … … … … … … … … … … … ①

T ₀ is the time required for filtration of the first 500 ml of sample water when the sample water was filtered under pressure of 0.2 MPa using a 0.45 μm microfiltration membrane, and T ₁₅ was filtered for 15 minutes in the same state as T _0. It is the time required for the filtration of 500 ml of sample water later.

3. Desalination Process

When the filtered water filtered in the pretreatment filtration process is supplied to the desalination process, the desalting method by nano-filtration and 1, 2 reverse osmosis filtration, 1 in an electrodialysis apparatus using an ion exchange diaphragm. Desalination by secondary reverse osmosis treatment of primary demineralized water by secondary reverse osmosis, cooling deep sea water to -2 ℃ produces sherbet ice, and when temperature reaches -11∼-12 ℃ Desalination by dissolving sherbet ice until semi-solid ice is produced. Desalination is one of the desalination methods by the freezing method. The salt contained in the deep sea water is removed. Send to (3).

Another desalination method for deep seawater is the evaporation and condensation method of evaporating deep seawater and condensing steam. However, in the present invention, the demineralized water produced by this method loses most of the deep seawater. Demineralized water produced by the desalination method by law is not applicable.

Example 1

After warming the deep seawater as shown in Table 1 at 25 ° C and pretreating the FI value to 3.2 by ultrafiltration, it is a cross-linked polyamide material manufactured by Toray Industries, Ltd. The membrane permeate was 80% of the influent when the membrane permeate was 1.2㎥ / ㎡ · day by supplying pressure to the membrane at 20㎏ / ㎠G using the spiral nanofiltration membrane of SU-610. Analysis of the main components of the non-sulfate-containing water and the filtered desulphate-ion brine are shown in Table 2 below.

Table 2. Analysis of Principal Components of Filtered Desulfurized Ion Saline by Nanofiltration

 Item   Pre-treated deep sea water (raw water)  Filtered desulphurized ion      pH        7.80         7.24 Na ⁺ (mg / L)   10,800    9,650 Cl ^- (㎎ / ℓ)   22,370   17,300 Ca ^{2 +} (㎎ / ℓ)      456      338 Mg ^{2 +} (㎎ / ℓ)    1,300    1,060 K ⁺ (mg / L)      414      355 _{^{SO 4 2 - (㎎ / ℓ}} )    2,833      319  B (mg / L)        4.44        4.10

As shown in Table 2, nanofiltration of the deep seawater resulted in almost no removal of boron compounds, 28.5% Na, 41% calcium (Ca) and 35% magnesium (Mg). More than 90% of sulfate ions were removed.

Example 2

Desulfuric acid ionized salt, which is filtrate filtered in the nanofiltration of Example 1, is a crosslinked polyamide-based composite membrane in a high pressure reverse osmosis filtration membrane of Toray Corporation, Japan. The membrane permeate was 52% of the influent when the membrane permeate was 0.72㎥ / ㎡ · day by supplying pressure to the membrane at 60㎏ / ㎠G using the spiral reverse osmosis filtration membrane of model number SU-810. Analysis of the main components of filtered demineralized and concentrated unfiltered brine is shown in Table 3.

Table 3. Analysis of Principal Components of Demineralized Water as Filtrate in First Reverse Osmosis

 Item  Influent Water (Desulphurized Salt Water)   Filtered demineralized water      pH        7.24         7.20 Na ⁺ (mg / L)    9,650       38.7 Cl ^- (㎎ / ℓ)   17,300       71.6 Ca ^{2 +} (㎎ / ℓ)      338        0.6 Mg ^{2 +} (㎎ / ℓ)    1,060        1.9 K ⁺ (mg / L)      355        1.7 _{^{SO 4 2 - (㎎ / ℓ}} )      319        3.7  B (mg / L)        4.1        1.8

As shown in Table 3, most of the salts were removed highly by 99% or more in the reverse osmosis filtration of deep sea water, but the boron compound was 1.8 mg / l and the removal rate was very low, which is less than 80%. Since it was doubled, it was not possible to use it as distilled water in alcohol itself.

Example 3

The filtrate filtered in the first reverse osmosis filtration step of Example 2 was adjusted to pH 9.5 in the pH adjustment step to convert the boron compound in water into the form of polyboric acid, and then the second reverse osmosis filtration was carried out in Toray, Japan. Membrane when the membrane permeate was 0.72㎥ / ㎡ · day by supplying pressure to the membrane at 20㎏ / ㎠G using the spiral reverse osmosis filtration membrane of Model No. SU-710. The permeation rate was 82% of the influent, and the results of the analysis of the main components of the filtered water were shown in Table 4 below.

Table 4. Water Quality Analysis of Demineralized Water with Neutralization of Filtrate in Secondary Reverse Osmosis Filtration

   Item  Filtrate of Second Reverse Osmosis Filtration Membrane  Remarks (Water Standard)          pH           8.4    5.8 to 8.5  Conductivity (㎲ / ㎝)          82 ¹⁷ O-NMR (㎐)          78  Redox potential value (㎷)          210  Hardness (mg / ℓ)          14.8  300 or less Na ⁺ (mg / L)          28.96  200 or less (WHO standard) Cl ^- (㎎ / ℓ)          50.82  250 or less Ca ^{2 +} (㎎ / ℓ)           0.86 Mg ^{2 +} (㎎ / ℓ)           3.08 K ⁺ (mg / L)           0.98 SiO ₂ (Mg / l)           0.25 _{^{SO 4 2 - (㎎ / ℓ}} )           3.32  200 or less  B (mg / l)           0.12    0.3 or less

In reviewing the treatment results of demineralized water in Table 4, the concentration of boron (B) was treated at 0.12 mg / l, which is 0.3 mg / l or less of the drinking water standard, and it was confirmed that there is no problem in using the remaining components as distilled water of alcohol.

II. Electrolyzed demineralized water to produce electrolytic reduced water

1. Production of alkaline electrolytic reduced water

The deep sea water desalted in the desalination process is supplied to the cathode chamber 3 of the electrolysis apparatus 10, and the deep sea water filtered in the pretreatment filtration process is supplied to the anode chamber 2, while being supplied. Direct current of 3 to 20 volts from the positive electrode 4 and the negative electrode so that the value of the oxidation reduction potential indicating switch (ORPIS) of the negative electrode chamber 3 is in the range of -250 to -100 kV. The electrolytic reduced water of the cathode chamber (3) applied and processed in (5) is sent to the pH adjusting tank (9).

At this time, the value of the pH indicator pHI provided in the cathode chamber 3 becomes alkaline in the range of 11-14.

The anode chamber 2 is treated by supplying the deep ocean water filtered in the pretreatment filtration step of the pretreatment process such that the pH indicating switch (pHIS) installed in the anode chamber 2 is in the range of 2-3. The electrolyzed oxidation water is sent to the electrolytic oxidation water storage tank (7) and then sent to the electrolytic oxidation water utilization process by the electrolytic oxidation water transfer pump (8). At this time, the value of the oxidation reduction potential indicator (ORPI) installed in the anode chamber 2 is in the range of +800 to +1,200 Hz.

The electrolytic oxidation water produced here is used as sterilizing water, bath water, lotion, and foliar sprays of crops.

At this time, the electrochemical reaction occurring in the electrolysis process is as follows.

The salts contained in the deep ocean water are hydrolyzed as follows.

^{_{H 2 O ⇔ 2H + + OH}} - ... … … … … … … … … … … … … … … … … … ②

_{^{M a X b ⇔ aM b +}} + bX a - ... … … … … … … … … … … … … … … … … … ③

Where M is Na, K, Ca, Mg, Fe, Zn... Cation material such as Cl, Br, CO ₃ , SO ₄ . For anionic materials such as, a means the number of cation (+) valence, b means the number of anion (-) atoms.

1) Reaction in anode chamber (2)

^{_{H 2 O → 2H + + [}} O] (aq) + 2e - → 1 / 2O 2 (g) ↑ + 2e - ... … … … … … … ④

Here, [O] _{( aq )} means active oxygen dissolved in an aqueous solution, and O _{2 (g)} ↑ means oxygen released to the atmosphere in a gas (Gas) state when an excessive current is applied. .

^{_{bX a - → X b (aq}} ) + be - → X b (g) ↑ + be - ... … … … … … … … … … ⑤

In the case of X ^{a -} is Cl ^- ion, considering the electrolytic reaction is as follows.

^{_{2Cl - → Cl 2 (aq)}} + 2e - → Cl 2 (g) ↑ + 2e - ... … … … … … … … … … ⑥

Here, Cl _{2 ( aq )} means chlorine dissolved in an aqueous solution, Cl _{2 (g)} ↑ means chlorine released to the atmosphere in the gas state when an excess current is applied.

2) Solution reaction in the anode chamber (2)

_{Cl 2 (aq) + 2H 2} O → H + + Cl - + HClO (aq) ... … … … … … … … … … … … … ⑦

2) Reaction in cathode chamber 3

^{_{2H 2 O + 2e - → 2}} [H] (aq) + 2OH - → H 2 (g) ↑ + 2OH - ... … … … … … ⑧

Here, [H] _{( aq )} means active hydrogen dissolved in water, and H _{2 (g)} ↑ means hydrogen generated in a gaseous state when an excessive current is applied.

^{M a + + aOH - → M} (OH) a ... … … … … … … … … … … … … … … … … ⑨

When M ^{a +} is Na ⁺ ion, considering the electrolytic reaction is as follows.

Na ^{+ +} OH ^- → NaOH ... … … … … … … … … … … … … … … … … … … … ⑩

The electrolysis device (1) is made of PVC (Poly vinyl chlorite), PE (Polyethylene), PP (Polypropylene), ABS resin (Acrylonitrile butadiene styrene copolymer), butadiene resin (Bakelite) ), Ebonite and Acrylic resin can be used.

The anode 4 of the anode chamber 2 is a corrosion resistant material and is subjected to baking coating of RuO ₂ -TiO ₂ on a titanium plate having a high chlorine and oxygen generation overvoltage. One dimensionally stable anode (DSA) electrode or a platinum plated electrode is used.

The cathode 5 of the cathode chamber 3 is made of Raney nickel or stainless steel sheet with high hydrogen generation overvoltage.

The diaphragm 6 is an exchange membrane that selectively permeates only a monovalent cation while suppressing the permeation of divalent or higher polyvalent cations. The main chain of the polystyrene-divinylbenzene system is main. Grafts such as polyethyleneimine or polyvinylpyridine have side chains on the side of the negatively charged membrane, which holds the negatively charged R-SO ₃ ⁻ in the chain. An ion exchange membrane synthesized from a graft polymer or a graft polymer whose main chain is polyethyleneimine or polyvinyl pyridine and whose side chain is polystyrene. It can be used without limitation, and preferably, polyethylene, polypropylene, polyvinyl chloride, polystyrene Negatively charged R-SO ₃ in the ^Molecular Structure of polyvinylpyridine (Polyvinylpyridine) having the same molecular structure in the main chain or a side chain only one cation permeability (透過能) with a polymer consisting of a cation exchange membrane is fixed to, polyvinyl A membrane modified with a cationic resin such as amine (Polyethyleneamine) or polyethyleneimine (Polyethyleneimine) can be used, and in particular, polystyrene-graft-ethylene imine of polystyrene-divinylbenzene can be most preferably used.

In the case of using the diaphragm 6 which simultaneously transmits a bivalent or higher polyvalent cation, multivalent ions such as Ca, Sr, Mg, Fe, and Fe move to the negative electrode chamber 3 to form a negative electrode. (5) The use of the diaphragm 6 that permeates polyvalent ions should be avoided because scale is generated in the plate, which increases the electrical resistance and decreases the processing efficiency.

Example 4

The size of the anode chamber 2 is 1,000 mm (length) × 500 mm (width) × 1,000 mm (depth), and the size of the cathode chamber 3 is also 1,000 mm (length) × equal to the size of the anode chamber 2. Isolated with a diaphragm (6) of Nafion-115 perfluorosulfonic acid Nafion-Resin from Dupont between 500 mm (width) × 1,000 mm (depth) in size. In addition, the anode 4 uses a DSA electrode baked-coated TiO ₂ -RuO ₂ on a titanium plate of 800 mm (width) x 1,000 mm (height) x 5 mm (thickness), and the cathode 5 is 800 mm. The anode chamber 2 of the electrolysis apparatus 1 using the electrode lined with a Raney nickel 3 mm thick on a steel plate of (width) × 1,000 mm (height) × 10 mm (thickness) was pretreated. Supplying deep sea water and supplying desalted water of deep sea water produced in Example 3 to the cathode chamber 3 at a flow rate of 1 m 3 / hr, a redox potential was applied by applying a DC electric power of 6 to 10 volts from the rectifier. (ORP) value between -200 and -220 Hz We were producing a reduced water.

At this time, pHI of the cathode chamber 3 was 12.6 to 12.8, and when the pH of the pH chamber of the anode chamber 2 was adjusted to be in the range of 2 to 2.5, the deep ocean water introduced was 0.82m 3 / hr, and the oxidation of ORPI was performed. Reduction potential values were +1,020 to +1,030 mA.

2. pH adjustment process

Since the electrolytic reduced water produced in the cathode chamber 3 of the electrolysis process has an alkaline pH in the range of 11 to 14, the electrolytic reduced water discharged from the cathode chamber 3 of the electrolytic apparatus 1 has a pH adjusting tank 9. Lactic acid, succinic acid, acetic acid, fumaric acid, gluconic acid, tartaric acid, Citric acid, malic acid, tannic acid, aspartic acid, and ascorbic acid are supplied with a mixture of one or two or more of them. The pH indicating switch; pHIS) is adjusted to a range of 7.3 to 8.5 and sent to the distillation process, final alcohol concentration adjustment, and the additive mixing tank 12.

Lactic acid, succinic acid, vinegar acid, fumaric acid, gluconic acid, tartaric acid, citric acid, malic acid, tannic acid, aspartic acid and ascorbic acid, which are organic acids used as the pH adjuster described above, may be used alone. It can also be used.

The pH adjusting tank stirrer 10 is stirred with a propeller agitator for 20 to 40 minutes and 180 to 360 RPM (rotation speed), and the material of the stirrer is made of corrosion-resistant stainless steel. use.

Example 5

In Example 4, electrolytic reduced water having a pH of 12.7 and a redox potential (ORP) of -210 kPa was supplied with citric acid to 6 m 3 to adjust the pH to 7.5.

III. Dilution of alcohol in electrolytic reduced water to produce diluted alcohol

1. Distillation process

In the pH adjustment step, the pH of the electrolytic reduced water is adjusted to dilute alcohol of alcohol of 95 ° C. or higher and alcohol content of 30 to 60 ° C.

2. Deodorization process

Distilled alcohol in the dilution process is rough and taste is not constant according to the quality of the raw alcohol is refined to stabilize the flavor and to refine the taste, brown oak, stone oak, oyster oak, water oak, sol oak, oak Wood, oak, chestnut, beech, apricot, plum, bamboo, cherry, birch (birch) is a mixture of one or two or more kinds of wood kiln temperature at 800 ~ 1,000 ℃ 2 to 3 passes through a deodorization tower filled with charcoal or granular activated carbon produced by carbonization, or powdered carbon obtained by pulverizing the charcoal in the range of 300 to 400 mesh or 200 to 400 mesh activated carbon. It feeds in the range of -1,500 mg / L, deodorizes, stirring and mixing for 1-3 days, and sends to a filtration process.

Oak charcoal, oyster oak charcoal, oak charcoal, chestnut charcoal, beech charcoal, apricot charcoal, plum charcoal, bamboo charcoal, cherry charcoal, oak charcoal, oak charcoal, prunus charcoal, oak charcoal, birch In the group consisting of charcoal and granular activated charcoal, the deodorizing tower filling one or two or more types of charcoal has a residence time of 1 to 4 hours, and the line speed passing through the tower is 2 to 6 m / hour. Design the tower.

And oak charcoal, oyster oak charcoal, oak charcoal, chestnut charcoal, beech charcoal, apricot charcoal, plum charcoal, bamboo charcoal, cherry charcoal, oak charcoal, oak charcoal, pruning oak charcoal, oak charcoal, bamboo When using a powder obtained by grinding 300-400 meshes of charcoal, birch charcoal or activated charcoal in a group consisting of charcoal, birch charcoal and activated charcoal, stir for 3 to 20 minutes in a deodorization tank equipped with a stirrer. Once every six hours, deodorizing treatment is carried out for 1 to 3 days and then sent to the filtration process.

Stirring is carried out with a propeller stirrer and the stirring time (retention time) is stirred at 180 to 360 RPM for 20 to 40 minutes, and the material of the stirrer and the deodorizing tank is made of corrosion-resistant stainless steel.

3. Filtration process

When the deodorizing process in the deodorizing process is supplied to the filtration process, the filter media is filtered through a pressure filter (Filter press) or a vacuum filter (Pre-coating) pre-coated with diatomaceous earth and the carbon powder ( Iii) is removed and filtered dilution spirit is sent to final alcohol concentration adjustment and additive mixing process.

Instead of the filter precoated with diatomaceous earth, the filter membrane may have a pore diameter of 0.05 to 20 μm, or a cartridge or sheet filter.

Example 6

600 liters of alcohol at 95 degrees, 825 liters of electrolytic reduced water produced in Example 5, which was adjusted to 7.5, were injected into a 1.5m3 tank equipped with a propeller stirrer, and then bamboo crushed with 350 mesh. 2 kg of the powder was injected, and the deodorizing treatment was carried out by stirring for 3 days at 360 RPM for 30 minutes every 6 hours, and the pores were filtered through a filter paper of 0.05 to 0.06 μm to make 1.300 L of the first diluted alcohol.

Ⅳ. Step of manufacturing the final product (reducing shochu)

1. Final alcohol concentration adjustment and additive mixing process

When the first diluted alcohol in the filtration step is supplied to the final alcohol concentration adjustment and the additive mixing tank 12 of the additive mixing process and the final alcohol concentration adjustment and the additive mixing tank stirrer 13 while stirring In order to improve the taste and aroma of shochu, the alcohol concentration is adjusted to 15 to 35 degrees by supplying an electrolytic return with a pH adjusted in the pH adjustment step, and inorganic salts such as salts and amino acids according to preference. , Glycerin, Dextrin, Hop, Sorbitol, Stebitol, Stevioside, Aspartame, Sucralose, Acesulfame potassium, Erythritol , Xylitol, Non-reducing saccharides (Sugar, Trehalose, Sucrose), Glucose, Fructose, Sugar, Sugar alcohol, Sugar syrups, Oligosaccharides, Additives mixed with one or two or more kinds from the group consisting of Fusel oil, esters, aldehydes, and polysaccharides at 15 ° C. It is added on the basis of the range of 0.05-2 g per 100 ml, and is supplied to the dilution alcohol transfer pump 14 to the electronic treatment tank 15 of the small grouping process of the water molecule population.

When the population of water molecules is not highly subpopulated, the final alcohol concentration adjustment and the additive mixing tank 12 finally adjust the alcohol concentration and mix the additives with the distilled alcohol transfer pump 14 Instead of being supplied to the electronic treatment tank 15 of the group small grouping process, it is sent to the soju storage tank 28.

2. Small Group Treatment Process of Water Molecule Population

In the final alcohol concentration adjustment and additive mixing step, the soju, which finally adjusts the alcohol concentration and the additives, is injected into the electronic treatment tank 15 of the small grouping treatment step of the water molecule group, and the high pressure is generated from the constant voltage generator 21. AC constant voltage is applied to the stainless steel wire mesh (electrode) 16 by applying a voltage of 3,500 to 5,000 volts and a current of 0.4 to 1.6 kV to generate positive and negative electrostatic fields around the stainless steel wire mesh 16. Alternately and repeatedly applied to water molecules for 4 to 10 hours, this causes the water molecules themselves to vibrate and rotate repeatedly while partially breaking hydrogen bonds in the water molecules. After being sent to the treatment tank 22 and sent to the magnetizer 24 by the magnetizer supply pump 23 for magnetization treatment, the flow rate of 1 to 4 times the inflow flow rate is returned to the electronic treatment tank 15. Nuclear magnetic resonance (NMR) ¹⁷ O-NMR half-width of the number of sub-group (半値幅) is 48~60㎐ range (小集團水; microclustered water) when treated with a sent to Suzhou reservoir 28.

The small grouped soju produced in this way is treated with reducing energy of high energy Oxidation Reduction Potential (ORP) with high alkaline high frequency in the range of -100 to -250 Hz.

The material of the electronic treatment tank 15 is made of stainless steel, and there is provided a stainless steel wire mesh 16 filled with charcoal having high conductivity, and at the bottom thereof. The insulator 17 is installed by selecting one of polyethylene, polyvinyl chloride (PVC), and styrofoam, and a base concrete structure based on a stainless steel plate (18), which is a conductor and a corrosion resistant material, under the insulator (17). Installed between the 19, the stainless steel plate 18 is grounded to the ground (20).

The transformer 21a of the constant voltage generator 21 includes an iron core 21d, a primary winding 21c, a secondary winding 21e, an output line 21g of the secondary winding 21e, and a secondary winding 21e. And the voltage regulator 21b is connected to the primary winding 21c, and the output line 21g of the secondary winding 21e is provided on the insulator 17. The stainless steel wire mesh (electrode) 16 built in 15 is connected.

The output line 21g of the secondary winding 21e of the transformer 21a is connected to the stainless steel wire 16 embedded in the electronic processing tank 15, and the insulation treatment terminal 21h of the secondary winding 21e is connected. ) Is insulated in the insulator in the transformer 21a, and the electronic treatment tank 15 is installed on the insulator 17 insulated from the ground 20 by the insulator 17, and the stainless steel plate 18 Silver is earthed on the ground 20 side, and the capacitor | condenser is formed between the ground 20 with the stainless steel wire mesh 16 in the electronic processing tank 15. As shown in FIG.

A secondary winding 21e on the high voltage side is formed at the same time as forming a capacitor in which the insulation terminal 21h, which is one end of the secondary winding 21e on the high voltage side in the transformer 21a, is insulated from the insulator in the transformer 21a. The remaining one end of the output line 21g is connected to the stainless steel wire net 16 in the electronic processing tank 15 insulated from the ground 20 by the insulator 17, thereby forming a capacitor, and as a result, the output line 21g. Since the voltage between the ground and the ground 20 is 250 to 3,500 volts and the current is a weak current of 10 to 150 mA, there is no danger even when a person contacts the electronic processing tank 15 in the ground state.

In electrostatic induction, when the charged material approaches an electrically neutral material, a charge having a polarity opposite to that of the charged material appears on the surface of the material close to the charged material. In addition, even when an electric field exists in the outside instead of a large charge, a charge opposite to the external charge appears. The charges appearing at this time are called inductive charges. Neutral materials have inductive charges, which induce charges to the material by external electrical action that is not in contact, resulting in polarization of positive and negative charges. This phenomenon is said to be subjected to electrostatic induction, and applying this phenomenon, applying an alternating current voltage to a material causes rotation and vibration of the molecule of the material, promoting the dimerization of molecules, and physical properties of the material ( Changing the characteristics is also called electrostatic induction treatment.

In other words, according to the present invention, as the constant voltage generator, the transformer 21a is of an external iron circular coil transformer type using an iron core 21d of a stratified layer, and the primary winding of the circuit of the primary side of the transformer 21a ( 21c is connected to the AC power supply via the voltage regulator 21b to insulate the insulation terminal 21h of the first stage of the secondary winding 21e of the secondary circuit of the transformer 21a from the insulator in the transformer 21a. Simultaneously with the processing, the output line 21g of the secondary winding 21e of the secondary side circuit is connected to the insulator 17 insulated by connecting the insulator 17 to the ground 20 in the electronic processing tank 15. When the electrostatic induction treatment is performed on the stainless steel wire mesh 16 by flowing a voltage of 250 to 3,500 volts and a current of 10 to 150 mA, the stainless steel wire mesh 16 of the electronic treatment tank 15 is formed of water and alcohol molecules. The population becomes small and highly permeable.

The transformer 21a inserts a cylindrical insulating film into the center of the iron core 21d, winds up the primary winding 21c and the secondary winding 21e on the outer circumferential surface of the insulating film, and then the primary winding 21c. ), For example, 220-240 windings using copper wire coated with a polyester of 0.6 mm in diameter, and the secondary winding 21e uses copper wire coated with an enamel of 0.09 mm in diameter, for example. 40,000 times of the secondary winding 21e, but the first secondary winding 21e may be 22,000, and the second secondary winding 21e may be 18,000. The diameter, type, number of turns of the copper wire, etc. are determined according to the processing capacity, the processing time, the applied voltage, and the like.

In general, such a copper coil may be used in the range of 0.03 to 3 mm, and the copper wire may be made of polyester or enamel coated copper wire, and the number of turns of the copper wire coil may be 200 to 300 mm. It is set as 250 windings, and the secondary winding 21e is made into 28,000-40,000 windings, or the secondary winding 21e is made into 16, 800-22,000 windings of the 1st secondary winding 21e, and the 2nd secondary The winding 21e may be 11,200 to 18,000 turns.

The insulated terminal 21h of the secondary winding 21e is in the transformer 21a. After winding the tip of the secondary winding 21e with insulating tape, an insulating material such as tar pitch is filled in the transformer 21a to fill the secondary winding 21e. The insulation treatment terminal 21h is covered to cover and insulated. However, the insulating material can be used in addition to tar pitch, insulating oil, unsaturated polyester, polyurethane resin, and the like.

The stainless steel wire mesh 16 is preferably a box on a wire mesh made of SUS-316 or SUS-304, but may be a slit-shaped porous plate or other grit.

When an alternating current flows through the transformer 21a and the primary voltage of the transformer 21a is operated by the voltage regulator 21b to adjust 100 to 220 volts, the terminal of the secondary winding 21e on the secondary side is adjusted. A voltage of 12,000 to 18,000 volts is generated between 21g and 21h, but the insulation terminal 21h of the secondary winding 21e of the secondary side circuit is insulated, and thus is insulated with the insulator 17. A voltage of about 3,500 to 5,000 volts and a current of 10 to 150 mA flow between the stainless steel wire net 16 and the ground 20 which are connected to the output line 21g in the electronic processing tank 15.

The voltage of 12,000 to 18,000 volts generated on the secondary side described above is between 3 and 500 to 5,000 volts between the stainless steel wire net 16 and the ground 20 in the electronic processing tank 15 and 10 to volts. The current of 150 mA is a capacitor formed at the portion of the insulation terminal 21h of the secondary winding 21e and a capacitor formed at the lower portion of the insulator 17, the resistance of the secondary winding 21e and the coil. It is by AC resistance circuit.

In other words, the circuit described above has a capacitor formed at the portion of the insulating terminal 21h that is one end of the secondary winding 21e and the portion of the portion where the output line 21g of the secondary winding 21e is insulated with the insulator 17. Electrostatic induction is caused by the resonance frequency caused by the discharge from the output voltage by the capacitor.

Depending on the size of the stainless steel wire mesh 16 in the electronic treatment tank 15, the capacity of the electronic treatment tank 15, and the height of the insulator 17, the stainless steel wire mesh 16 and the ground 20 in the electronic treatment tank 15 may vary. The voltage varies from 3,500 to 5,000 volts and the current also varies from 10 to 150 mA. In addition, the voltage and the current can be varied by adjusting the input power supply in the range of 0 to 220 volts with the voltage regulator 21b.

As described above, the voltage of the stainless steel mesh 16 in the electronic processing tank 15 generated by the AC resistance circuit is 3,500 to 5,000 volts at no load, but the current is 10 to 150 Because of the weak current in the range of ㎂, it is safe for the human body, and there is no fear of causing trouble such as electric shock or fire. In addition, the voltage and current applied to the stainless steel wire mesh 16 are the capacity of the electronic processing tank 15. The voltage is regulated by the voltage regulator 21b according to the electrostatic induction processing condition, but in the usual case, the voltage between the stainless steel wire mesh 16 and the ground 20 is in the range of 550 to 1600 volts and a current of 30 to 100 mA. By using this, an alternating electric field suitable for inducing electrostatic induction in the electronic processing tank 15 can be configured.

When the stainless steel wire mesh 16 (electrode) becomes positively charged with respect to the stainless steel wire mesh 16 in the electronic processing tank 15, negative charges are dielectric on the ground 20 side, and conversely, the stainless steel wire mesh 16 When the charge is grounded, + charge is inherited on the ground (20) side, and according to the frequency of the AC power source, the stainless steel wire mesh 16 changes the + charge and the-charge by the frequency (50 to 60 times) for 1 second. Therefore, the charge on the ground 20 side is also inherited, and the + charge and the − charge are changed.

In general, matter is formed by atoms, which are composed of atoms and electrons, which in turn are composed of neutrons and protons, and electrons with negative charges around the nucleus are circles. In the normal state in which the movement and the external electric field do not work, both positive and negative charges of the electrons are stabilized in the same amount, but when a high voltage is applied from the outside, the electrons move to one side, In addition, the protons move to one side, and thus the electric centers of the atoms do not coincide. As a result, the atoms form one electric dipole, and an internal electric field is generated by the balance of charges. It will cause polarization.

In this case, since the atom is polarized by an external electric field, this is called electron polarization or atomic polarization, and a high constant voltage is applied to the stainless steel wire mesh 16 in the electron processing tank 15. When all molecules are applied, they try to comply with the change of + and-charges by electrostatic induction, but there is a difference between strong and weak of the binding force between molecules, so that the water molecule cluster has a partial hydrogen bond. It is cut into small groups and treated with microclustered water, so that the surface tension is reduced and the viscosity is low, resulting in a highly permeable soju solution.

In the case where the processing capacity is large, a plurality of electronic processing tanks 15 with stainless steel wire meshes 16 filled with charcoal are installed and processed.

When a high-pressure alternating-current constant voltage is applied to the electronic processing tank 15 from the transformer 21a of the constant voltage generator 21 described above, when microorganisms are present in the aqueous solution in the electronic processing tank 15, the microorganism is sterilized by the high-voltage constant voltage. Is processed.

The magnetizer 24 applies a direct current electric current by placing two coaxial coils apart from each other by a radius thereof in two parallel ring coil formers 25. A device filled with magnetite filler 27, which is a magnetic material, inside a circular vessel wound around a coil 26 which induces a uniform magnetic field in the space when it is sealed. Consists of

The coil former 25 of the magnetizer 24 is made of non-magnetic polyvinyl chloride, polypropylene, polyethylene, ABS resin (Acrylonitrile butadiene styrene copolymer) or fluororesin. Fluororesin, Acrylic resin, Bakelite, Ebonite, Fiber glass reinforced plastic, Titanium, Nonmagnetic steel, Ceramics Select one type of inorganic material.

The voltage and current applied from the rectifier to the coil 26 vary depending on the processing capacity, but the coercive force is applied within the magnetizer 24 to be in the range of 5,000 to 20,000 Gauss, and the frequency of the current. Is in the range of 30 ~ 350㎐, and heat is generated when current is applied more than 5 Amperes, so air-cooled or water-cooled cooling equipment should be provided.

Magnetizer 24 Vessel material is non-magnetic polyvinyl chloride (Polyvinyl chloride), polypropylene (Polypropylene), polyethylene (Polyethylene), ABS resin (Acrylonitrile butadiene styrene copolymer), fluororesin (Fluororesin), acrylic One of the inorganic materials of acrylic resin, Bakelite, Ebonite, Fiber glass reinforced plastic, Titanium, Nonmagnetic steel, Ceramics Select to use.

The residence time is meaningless because the molecular population of water passing through the magnetic field inside the magnetizer 24 is instantaneously subpopulated in picoseconds.

In the present invention, the height (length) of the magnetizer 24 is 50 to 120 cm, and the passage speed (flow rate) of the fluid improves the processing efficiency as the passage speed of the magnetic field is faster, but the flow path is in the range of 1.5 to 4 m / sec. Determine the cross-sectional area of.

The magnetic material to be filled in the magnetizer 24 is filled with a crushed magnetite or magnetic ceramics having a size of 2 to 10 mmφ.

When the capacity of the treated water is large, the electronic treatment tank 15 in which the stainless steel wire mesh 16 filled with charcoal is installed is treated by installing multiple stages.

As in the present invention, when the group of the water molecules by the high-voltage constant voltage treatment and the magnetizer is small grouped, the surface tension and the viscosity of the water are reduced, the penetration force is improved, and the reducing shochu with excellent refreshing feeling is produced. .

3. Precision filtration process, container filling and packaging process

The reducing shochu of the soju storage tank 28 is sent to the soju transfer pump 29 in a micro-filtration process to finally remove the solids, and then to the container filling and packing process to be filled in a container, and then packed to reduce Manufacture shochu.

Example 7

In Example 6, to 1,300 l of the first diluted alcohol, 1360 L of electrolytic reduced water adjusted to pH 7.5 in Example 5 was added to make a 20 degree soju, followed by 0.2 kg of salt, 0.5 kg of aspartic acid, and alanine. (Alanine) 0.2 kg, Stevioside, 1.2 kg, 1 kg of glucose and 0.2 kg of Trehalose were added, and the stirred and dissolved pieces were filled with charcoal in a stainless steel wire 16 having a capacity of 1 m 3. 1.5 m 3 of the electronic processing tank 15 having a capacity of 2 m 3 in which it was incorporated was injected, and the remaining 1.16 m 3 was injected into the intermediate processing tank 22 having a capacity of 1.5 m 3.

Then, a voltage of 3,500 volts and a current of 0.56 kV are applied from the constant voltage generator to the stainless steel wire 16 filled with charcoal embedded in the electronic treatment tank 15, and the coercivity within the magnetizer 24 is 10,000. The magnetizer feed pump 23 is supplied to the magnetizer at a flow rate of 2.5 m 3 / hour while applying a voltage of 0.8 Volt and a current of 1.5 Ampere from the rectifier to the coil 26 so as to maintain Gauss. The batch was operated for two hours while being returned to the 100% electronic treatment tank 15 for small groups of water molecules, followed by microfiltration, to thereby produce a reducing shochu.

The pH of the reducing shochu was 7.5 and the half-width of the nuclear magnetic resonance (NMR) O-NMR was 54 kPa as shown in Fig. 4, and the water molecules were subpopulated, and the redox potential (ORP) was -211 kPa. Reducing shochu was prepared,

Example 8

As a result of supplying the soju prepared in Example 7 to restaurant B, 20 ordinary customers were allowed to sample reducing soju produced by electrolytic reduction treatment of mineral water on sale by Company D. The freshness and umami were excellent.

As described above, the present invention, desalination of deep sea water to dilute the alcohol with electrolytic reduced water by electrolysis to make a reducing shochu, and then a small group of groups of water molecules has a refreshing taste and taste It is expected to be widely used in the production of shochu because it can be produced hygienically safe shochu with an improved effect.

Claims (6)

Taking deep sea water and desalting to produce demineralized water, electrolyzing demineralized water to produce electrolytic reduced water, diluting alcohol into electrolytic reduced water to produce diluted liquor, producing final product (reducible soju) It is made of a step, each step is a method for producing a reducing shochu made of each of the following steps sequentially. I. Desalination by taking deep ocean water and producing demineralized water 1. Intake and heating treatment process In the pretreatment process, the deep sea water of the seabed deeper than 200m deep from the sea surface is collected and warmed to 20 ~ 30 ℃ and sent to the pretreatment filtration process. 2. Pretreatment Filtration Process When the deep sea water warmed by the intake and warming process is supplied to the pretreatment filtration process, a sand filter, a micro filter, an ultra filtration alone or two or more types are used. Filtration was combined to remove the FI (Fouling index) value in the range of 2 to 4, and then sent to the anode chamber (2) of the desalting step and the electrolysis step. 3. Desalination Process When the filtered water filtered in the pretreatment filtration process is supplied to the desalination process, the desalting method by nano-filtration and 1, 2 reverse osmosis filtration, 1 in an electrodialysis apparatus using an ion exchange diaphragm. Desalination by secondary reverse osmosis treatment of primary demineralized water by secondary reverse osmosis, cooling deep sea water to -2 ℃ produces sherbet ice, and when temperature reaches -11∼-12 ℃ Desalination by dissolving sherbet ice until semi-solid ice is produced. Desalination is one of the desalination methods by the freezing method. The salt contained in the deep sea water is removed. Send to (3). II. Electrolyzed demineralized water to produce electrolytic reduced water 1. Production of alkaline electrolytic reduced water The deep sea water desalted in the desalination process is supplied to the cathode chamber 3 of the electrolysis apparatus 10, and the deep sea water filtered in the pretreatment filtration process is supplied to the anode chamber 2, while being supplied. Direct current of 3 to 20 volts from the positive electrode 4 and the negative electrode so that the value of the oxidation reduction potential indicating switch (ORPIS) of the negative electrode chamber 3 is in the range of -250 to -100 kV. The electrolytic reduced water of the cathode chamber (3) applied and processed in (5) is sent to the pH adjusting tank (9). 2. pH adjustment process When the electrolytic reduction water discharged from the cathode chamber (3) of the electrolysis device (1) is supplied to the pH adjusting tank (9) while stirring with a pH adjusting tank stirrer (10), lactic acid, succinic acid, vinegar acid (Acetic acid), fumaric acid, gluconic acid, tartaric acid, citric acid, citric acid, malic acid, tannic acid, aspartic acid, ascorbic acid One or two or more kinds of acidic acid are supplied and the pH indicating switch (pHIS) is adjusted in the range of 7.3 to 8.5 to adjust the dilution process and final alcohol concentration. It is sent to the additive mixing tank 12. III. Dilution of alcohol in electrolytic reduced water to produce diluted alcohol 1. Distillation process In the pH adjustment step, the electrolyzed water of which pH is adjusted is first diluted with alcohol content of alcohol of 95 ° C. or more, and alcohol content of 30 ° to 60 °. 2. Deodorization process Oak, stone oak, oyster, oak, oak, oak, oak, chestnut, beech, apricot, plum, bamboo, cherry, birch (birch) In the group consisting of one or two or more kinds of carbonized by the temperature of the wood kiln at 800 to 1,000 ℃ produced by passing through a deodorizing tower filled with charcoal or granular activated carbon two or three times, The powdered charcoal obtained by pulverizing the charcoal in the range of 300 to 400 mesh or the powdered activated carbon of 300 to 400 mesh is supplied in the range of 200 to 1,500 mg / L, and deodorizing is carried out while stirring and mixing for 1 to 3 days and sent to the filtration process. 3. Filtration process When the deodorizing process in the deodorizing process is supplied to the filtration process, the filter media is filtered through a pressure filter (Filter press) or vacuum filter (Vacuum filter) pre-coated with diatomaceous earth (carbon dust). Iii) is removed and filtered dilution spirit is sent to final alcohol concentration adjustment and additive mixing process. Ⅳ. Steps to manufacture the final product 1. Final alcohol concentration adjustment and additive mixing process When the first diluted alcohol in the filtration step is supplied to the final alcohol concentration adjustment and the additive mixing tank 12 of the additive mixing process and the final alcohol concentration adjustment and the additive mixing tank stirrer 13 while stirring In the pH adjustment process, by adjusting the pH of the electrolytic return to adjust the alcohol concentration to 15 to 35 degrees, then inorganic salts, amino acids (Amino acid), glycerin (Glycerin), dextrin (Hop), Hop (Hop) Sorbitol, stevioside, aspartame, aspartame, sucralose, acesulfame potassium, erythritol, xylitol, non-reducing saccharides; Sugar, Trehalose, Sucrose, Glucose, Fructose, Sugar, Sugar alcohol, Sugar syrups, Oligosaccharides, Honey, Fuselle oil, Ester (Ester), aldehydes (Aldehyde), teas ( In the group consisting of (i), one or two or more kinds of additives are added at a temperature of 0.05 to 2 g per 100 ml of the sake liquor at 15 ° C. It is supplied to the electronic processing tank 15 of a group small grouping process. 2. Small Group Treatment Process of Water Molecule Population In the final alcohol concentration adjustment and additive mixing step, when the soju, which finally adjusts the alcohol concentration and the additives, is supplied to the electronic treatment tank 15 of the small grouping treatment step of the water molecule group, the high pressure from the constant voltage generator 21 AC constant voltage was applied to the stainless steel wire mesh (electrode) 16 at a voltage of 3,500 to 5,000 volts and a current of 0.4 to 1.6 mA for 4 to 10 hours, and then sent to the intermediate treatment tank 22. After the magnetic feed treatment is carried out by the firearm supply pump 23 to the magnetizer 24, nuclear magnetic resonance is carried out while conveying the flow rate of 1 to 4 times the inflow flow rate to the electronic treatment tank 15; When the half width of ¹⁷ O-NMR of Nuclear Magnetic Resonance (NMR) is treated with microclustered water in the range of 48 to 60 kV, it is sent to the soju storage tank 28. 3. Precision filtration process, container filling and packaging process The reducing shochu of the soju storage tank 28 is sent to the soju transfer pump 29 in a micro-filtration process to finally remove the solids, and then to the container filling and packing process to be filled in a container, and then packed to reduce Manufacture shochu. The distilled liquor transfer pump 14 is used for the electronic processing of the small grouping process of the water molecule group in the final alcohol concentration adjustment and the additive mixing tank 12. A method of producing reducing shochu by the step of sending it to the shochu storage tank (28) instead of feeding it to the tank (15). delete delete delete delete

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