KR20060125126A - Hair accessory and bend - Google Patents

Abstract

A hair accessory and band containing nano-silver liquid or powder are provided to represent sterilization and detoxification properties and to send forth fragrance, thereby preventing generation or proliferation of bacteria, germs or microorganisms, by comprising typical raw materials such as metal, synthetic resin, jewels, etc., nano-silver liquid or powder and additional plant fragrant materials. The hair accessory or band is fabricated by a process comprising the steps of: preparing body(10) of the hair accessory or hair band by using typical raw materials selected from metal, synthetic resin, plastic, mineral, jewels, silicone, rubber or polymeric materials; adding 0.01-30wt.% of nano-silver material(20) to total 100wt.% of the accessory or band to form a nano-silver coating(240) on the body; and further adding 0.01-10wt.% of plant fragrant materials such as fruit scent, aroma flavor, herbal scent, flower scent, etc. to the body. The powder type of nano-silver material has particle diameter ranging from 0.01 to 300nm. The nano-silver coating has thickness ranging from 0.01 to 50 micrometers.

Description

 Hair accessory and bend}

1 is a perspective view of head ornaments in accordance with the present invention.

2 is a mixing process diagram of metal hair ornaments according to the present invention.

Figure 3 is a mixing process of plastic, synthetic resin, poly, silicone, hair ornaments according to the present invention.

Figure 4 is a coating process of plastic, synthetic resin, poly, silicone, hair ornaments according to the present invention.

Figure 5 is a coating process of the metal hair ornaments according to the present invention.

Figure 6 is a photograph taken by magnification of 60.000 times with an electron microscope of the cross section of the silver nano of the present invention.

Figure 7 is a photograph of the side of the silver nano of the present invention magnified 80.000 times with an electron microscope.

Figure 8 is a photograph taken by magnification 50.000 times the surface of the silver nano of the present invention.

Figure 9 is a photograph of the antimicrobial activity of the strain into which the silver nano of the present invention.

10 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

11 is a three-dimensional structural diagram of silver nano of the present invention.

* Description of the symbols for the main parts of the drawings *

10: head ornament body 20: silver nano

30: Fragrance 40: Fastening part

50: cylinder 60: melting

80: melting 100: heating

120: softening 140; stirring

160: Mix 180: Module input

200: molding 220: injection

230: Extrusion 240: Coating

260: Deposition 280: Drying

300: chamber 320: washing process

340: 1 Secondary Surface Coating 360: Secondary Surface Coating

380: finished

The present invention relates to a hair ornament (accessory) consisting of a hairpin, hair straps, hair drops and bands, which are a kind of hair ornaments that women usually use when tying or fixing hair when they dress or wash their face.

  More specifically, in the manufacture of the hair ornaments 10, the functional hair ornaments 10, in which the antimicrobial power and the action of releasing far infrared rays and silver ions are maintained by mixing 160 or coating 240 with the silver nano20. The method, the history and the origin and the background of the hair ornaments 10 of the West are described in detail as follows.

History of hair ornaments in our country,

Humans have cared for and scattered hair scattered by spontaneous acts, and ornaments developed as the desire for unique human beauty was added.

According to <Reinforcement Documents Remarks>, 'Dangun taught the nations how to unilateralize and repair, and the hairpin made of deer horns is found in the Neolithic ruins. . Hair styles varied in each age, and hair ornaments changed accordingly. The jewelry was also a sign of his identity, depending on the material and use.

 There are two kinds of hairpins: sleep and chaya. Sleep is a hairline with an elongated body, and a chaff is a decoration on the upper part of a two-strand body. Chae was widely used during the Goryeo Dynasty and sleep was used until the Joseon Dynasty.

This is because the basic two-headed type of the usual wife of Joseon Dynasty is the head and the flat head. High-class wives used jade, silver, silver chilbo and plated hairpins. The use of pure gold hairpins was royal only, but parasitic garnishes were allowed to decorate gold hairpins.

 The hairpin's head was deeply symbolic, indicating the identity and character of the person wearing the hairpin. The phoenix and dragon were only available to the queen, but even ordinary people could only get a new wedding. The distracted wife put in slumber and porridge sleep. The court also rewarded the eldest daughter with a slumber or porridge sleep.

 In addition, Daenggi is a kind of ornament made of cloth on the end of braided hair. In the `` North Korea, '' Baekje's virgin said that the Baekje virgin braided her hair backwards, and the wife was split in two. It is said to be braided around the head and decorated with silk and pearls, but the Goguryeo murals were decorated with strings, indicating that the Three Kingdoms used daenggi.

 In the Goryeo Dynasty, it was generalized under the influence of Mongolia. In the Joseon Dynasty, virgins and bachelors used braided hair as well as the tops and shreds of their wives. Used.

 The rear part is a modified product that is added to the back of the side of the side of the hair, and the side of the hair is fixed by the hairpin. The rear end is divided into not only a decorative but also a practical role, and the most common endorsement for the decoration is a flower arrangement and a salary back. It is made of thin silver with a round chrysanthemum and plum blossoms symmetrically on the head, with the shape of a swallowtail butterfly on it, and the salvation of a lotus flower.

    In addition, there are various varieties such as Bon (닭), chicken, Bulchocho, nectarines. The backrest, which also serves as a practical premise, includes a backrest for a bitter tooth, a backrest for an earpick, and a pile-shaped stake that has a sharp tip. Many of the materials for the backing are blue with silver and white jade, jade, coral, gold plaques, beeswax, plating, silver, and white copper. The rear end is plugged in to match the hairpin.

  Cucumber is a kind of upholstered body with silver body and pointed tip. The head is decorated with treasures, and corals, jade, beeswax, gold plaques, pumpkins, etc. have been used to make lotus, chrysanthemum, butterfly, and nectarines. It is laid on the back of the head and shows only the tip of the shellfish, giving the impression that beautiful jewelry is embedded. In an emergency, it was said to prevent the sergeant by stabbing the man's nose wall.

 A hinge is a kind of ornament that the queen and the inside and the outside are dressed in a scalloped head. Depending on their shape and material, they may be identified. At the time of ceremonies, corollas and spiders are fixed so as not to flow down, but the queen used plated pouches, and the rain and bins used plated pouches. Internal and external registers used black and white or frog patch. The shape is different but the size is similar.

 The comb was not only necessary for the woman to split the karma and to cleanse her hair, but also as a tool for applying oil. It is usually used as one of the modifications to make a small form suitable for decorating a head by attaching it to a normal or lean head with a comb, a comb, a cotton mirror, tweezers, a stick, and a powder.

 A drowsiness is one of the headdresses worn by sub-queens when they wear big suits or big hair, and they are attached to both the front center and left and right sides. It is also known as 'Sulchulbanja'. There is a butterfly-shaped spearhead in the center and a half-blade on both sides, and the material is elegantly attached with pearls, coral, jade, and cloisonne on the jade plate, and swinged with a spring.

 The most innocent hairstyle that suits Hanbok is the ups, or up-styles. Even if you have short hair, you can use a wig called Dalbi. The hairpin has a decorative meaning besides the excuse to fix and fix the hair on the rear side. There are many materials for hairpins such as gold, silver, wood, baekbaek, coral, jade, etc. In the past, the material and length were used to identify the status of identity.

The hairpin is divided into convexly decorated parts and body, and the decoration of the part determines the fashion of the hairpin. The royal women used dragons and phoenixes, and the general women used bamboo and plum trees and flowers. A back accessory, a hair accessory that is put on top of the hair along with hairpin, is also a decoration that enhances the beauty of the hanbok.

Drips and wraps

The dwarf depicts a star and a butterfly flying in the middle of a pair of mandarin ducks. Also known as `` Dull Iron Man '', dunjam is used by women in the upper classes, including the queen. ' When I was a 'big hair' or 'big hair', I put them in the center and both sides of the front cover, and I put pieces like stars and butterflies at the end of the spring, and it was as if the stars and butterflies were flying on the head. A mop is a piece of jewelry that plugs into the center of a forehead's forehead.

On the other hand, Western hair ornaments include head coverings such as hair, veils, turbans, bandanas, including flowers, flowers, feathers, combs, lace, jewelry, ribbons, pins, etc.

Wigs (wigs, hairpieces), and the like and are classified according to their shape: ① hair pins, ② ribbons, hair bands, ③ decorative tubes, crowns, hair rings, ④ It can be divided into other. The hairpin is an accessory to fix the hair and was also worn by women of ancient Egypt, Greece, Rome and Germanic countries. Mostly metal, carved or jeweled.

Ancient Greek diademas or tiaras are ceremonial headdresses made of precious metals, in the form of hair bands with jewels in the pointed part of the forehead. It began in the Orient and symbolized status in ancient civilizations. Hairnets were also found in the Bronze Age relics, and have practical and decorative meanings.

Medieval men's heads were mostly short-haired, with the aristocrats wearing hats and the commoners

Many hoods were worn. The hood was favored by both men and women, and as a variant of it, the coif began to be favored by upper class women, who were very small and tied to the chin like a young child's hat. The woman's head was predominantly ligated with a karma from the front, with two or three strands of hair.In religious practices, nuns, widows, and ordinary women were white veils called wimples when going out or religious. Wrote.

A 13th-century man curled his head in the center, curled it down to his shoulders,

The phrygian bonnet, which has come down from Romanesque times,

Use a calotte, toque, or change to a new form to fit the sense of the times

He wrote chaperon, chapeau and so on. In the 14th century, clothing gradually became

Brilliant and extravagant, resulting in new and exaggerated forms of hair and ornaments

Started.

Medieval hairnets were embroidered in gold and embroidered with colorful embroideries. In the Renaissance, they were usually embroidered with pearls or gems, as was the case with Italian paintings of the time. Woolnets, non-rods, and thin hairnets reappeared in the 20th century with the resurrection of long hair. Along with this decorative hairnet, an invisible and practical hairnet made of human hair or nylon was used.

As a beauty instrument used to fix or wave the curls of women's hair from ancient times, there are branches such as pins, strings, and hair bands. Hairpins used in hair sets have U-shaped crosses and open ends. It is closed and there is an r-shape to fix the hair with the force of the spring. The hair bundle strap is made of elastic material rubber and binds droplets of metal, plastic, or synthetic resin material. It can also be used to wash your face by raising your bangs, and it's often worn by men lately.

The present invention contains silver nano (20) for anti-sterilization with far-infrared and silver ions by mixing (160) the silver nano (20) in the manufacture of the hair ornament (10) consisting of the pins, drops, braids, hair bands Functional hair ornaments (10) As described above, the hair ornaments 10 of the present invention is not economical or sterilizing because it is simply put during the manufacture of the body of the hair ornaments (10) rather than physical or electrical sterilization of the machine. Containing unprecedented powerful silver nano (20) material, you can get the following excellent benefits continuously without wasting electric power or time anytime, anywhere.

Silver nano (20) is harmless to the human body and has a sterilizing power tens of times stronger than the chlorine series. If so, the following lists the preferred features of the head ornament 10 of the present invention.

  As described above, the present invention relates to a hair ornament (bend) and a hair ornament (10) that women typically use when tying the hair to fix hair and hair. The present invention relates to a method for manufacturing the hair ornament 10 in which the anti-sterilization effect of the hair ornament 10 is maintained by mixing 160 or coating 240.

As described above, the head ornament 10 of the present invention is not simply physical or electrical sterilization of the machine, but is simply introduced during the manufacture of the body of the head ornament 10, so that the economical and sterilizing power of the nanoparticles is unpredictable. 20) Because it contains materials, you can achieve the following excellent benefits continuously without wasting electric power or time anytime, anywhere.

Silver nano (20) is harmless to the human body and has a sterilizing power tens of times stronger than the chlorine series. If so, the following lists the preferred features of the head ornament 10 of the present invention.

  First: The hair ornament (10) containing silver nano (20) generates healthy silver ions and far infrared rays, which makes the blood circulation and endocrine activity of the scalp clear during use, which clears the head and is an environmental hormone that has recently become a problem. It has many advantages that it blocks more than 90% of infor- mation data, and the antibacterial and anti-allergic vitamin B6 protects the skin, keeps the skin soft, deodorant and washes repeatedly.

Secondly, it reacts sensitively according to the pollution level of the environment and shows continuous antiseptic action by destroying bacterial cell membranes or disturbing cell functions.

 Recent research has shown that silver nano (20) can sterilize 650 bacteria and viruses, and prevents secondary infections in hospitals where it is a problem due to its excellent anti-bacterial and antibacterial function of harmful bacteria and microorganisms. Silver catalyzes the conversion of oxygen into active oxygen, which prevents germs from propagating by germ and germ propagated by sweat, saliva or dust secreted by the human body.

Third: silver nano (20) is very easy to coating 240, mixture 160, and the like with the material, metal, plastic, resin, minerals, jewelry, silicon, Rubber ornaments made of poly-based hair ornaments (10) the material of the body and mixing 160 or coating 240 is made well.

Fourth: Deodorant effect and fragrance divergence effect. The hair ornaments 10 of the present invention are formed on the surface of the hair ornaments 10 due to contaminants secreted from the scalp of the human body even if the user washes from time to time, and in particular, in the hot summer, odor caused by sweat of the scalp I'm going to

The silver nano 20 of the present invention and the hair ornament 10 containing the fragrance are liquids or powders of vegetable fragrance base materials such as fruit, aroma, herb, flower, etc. It is added in a weight ratio of 0.01 to 10% by weight to always emit a subtle fragrance, the hair ornament (10) of the present invention has the advantage of pleasing the smell of users and others, and has the advantage of maintaining the lasting sterilizing power to increase national health It is effective to let.

 Fifth: It has a sunscreen effect. Nanonized silver has excellent UV protection, so it is used in textiles, cosmetics, sunglasses, etc.

Hair ornaments (10) prevents the phenomenon of fading or discoloration by preventing corrosion by ultraviolet rays of the sun.

 The present invention is to solve the above conventional problems as described above

 Using silver or aged silver nano (20) mixed with the material of the body of the hair ornaments (10) body made of metal, synthetic resin, plastic, minerals, jewelry, silicone, rubber poly-based material of the body of the hair ornaments (10) ( 160) or coating 240 to sterilize hair ornaments 10 contaminated by dandruff, keratin, bacteria, etc. of the hair. After making powder or nano silver (Ag) solution in the form of Nano), the material of the hair ornament 10 body made of metal, plastic, synthetic resin, mineral, gem, silicone, rubber poly-based material of the hair ornament 10 body 0.01 to 30% by weight of the silver nano 20 in a liquid or powder of vegetable fragrance base material such as fruit aroma, aroma, herb, flower, etc. in a weight ratio of 0.01 to 10% by weight to mix (160) or The coating 240 and the particle size of the silver nano (20) fine particles have a particle diameter of 0.01 to 300nm and when the coating 240, the coating 240 thickness is 0.0l㎛ ~ 50㎛ (micrometer) thickness of hair ornaments (10) It is characterized in that the silver nano (20) coating film 240 formed on the body, the antiseptic power is made continuously.

The present invention binds or fastens the head consisting of hairpins, drops, strings, and bands made of at least one material of any one of metals, plastics, synthetic resins, minerals, gemstones, silicones, and rubber poly-based materials or mixed (160). 100% by weight of the total material of the hair ornament body used for fashioning, the silver nano (20) 0.01 to 30% by weight of vegetable fragrance base material such as fruit or aroma, herb, flower fragrance It is related to the hair ornaments 10, characterized in that the mixture (160) or coating 240 by adding a liquid or powder in a weight ratio of 0.01 to 10% by weight into the material of the body of the ornaments (10).

In order to help the understanding of the present invention will be described in detail the silver and silver nano (20) constituents of the present invention.

    Nanotechnology is a technology that identifies and controls substances at the molecular and atomic levels.It comes from the Greek word dwarf, lanose, and 1 nanometer 'corresponds to one-tenth of the thickness of the hair. It is made of silver solution (colloid), which is a chemical decomposition method or a fine particle state in nano units, and is widely used in industrial fields.

Silver, the main component of silver (20), has been recognized as a precious metal of high value from ancient times, and has been the object of extraction, and it is recognized as an important industrial material in modern industry as well as its value as a currency. The production of silver is proportional to the production of gold in many ways.

Silver was mined early in Europe's Mediterranean coast, where silver was produced from the Incas and Aztecs before the discovery of the Americas, and then silver from Peru and Bolivia entered Europe and flowed out from 1520 to 1800.

It has grown steadily, but has declined since the discovery of large amounts of silver in the early 19th century.

Currently, the world's major silver producers are Russia (13.8%), Canada (13.5%), Mexico (13%), Peru (13%), United States (11%), Australia (8%), Poland (6%). The country's silver reserves are 17 million tons, and its mining capacity is about 1.2 million tons. As of 2002, silver produced in Korea is about 5,000 kg, which accounts for 1.2% of the total domestic demand. The amount is so small that the rest of the silver is imported from abroad.

Characteristics of silver: The color of silver is gray in the case of elegant gray-white metal or powder, specific gravity is 10-12, Mohs hardness is 2.5-3, melting point 280 is 960.5 ℃.

In particular, the melting point (280) of silver is very important for the temperature compensation of high thermometers, and it is the standard of scientific and industrial temperature. Silver is the best conductor of metal, and is used comprehensively for mechanical contacts and other electronics. .

Silver is optically 90% of visible light, which is one of the most excellent metals like platinum. Pure silver does not rust even when left in the air or heated (100), but it reacts with sulfur and hydrogen sulfide to emulsify it. Silver is made and turns black.

     In addition, the mechanical properties change according to the amount of impurities (O₂) contained in the silver, and the hardness of the high-purity silver obtained by thermal annealing is Brinell hardness HBS (10/500) 25-27, tensile strength 12-16kgf / mm2. The cast strength of the cast was up to about 29 kgf / mm 2, the combustion rate was 48 to 54%, and the recrystallization temperature was 150 ° C.

    In particular, in the case of pure silver, the processed hardened material is softened by recrystallization at normal room temperature and softened softly. The malleability and flexibility are rich after gold.

     The effect of silver has been used as a tool to check the imbalance of the body that one cannot feel because the gloss or color changes depending on the condition of the body when worn on the body from ancient times. This fatigue or low rhythm), Dongbobogam said that it is effective in the prevention and treatment of mental disorders and women's diseases such as epilepsy and game. The five chapters are said to be comfortable, the mind and body are stabilized, and the main body records that the body is lengthened by chasing morale and lightening the body.

      Also, when the Black Plague prevailed in the Middle Ages, nobility of the black aristocrats and royals, who had many silverware and silver utensils, did not have black plague, which released silver to the extent that it was able to sterilize the Black Plague bacteria, making it relatively safe from infectious diseases. In the place where the royal family and the state guests were served, silver products were used habitually.

In order to help the understanding of the silver nano 20, the present invention will be described briefly with respect to the silver nano 20 (Nano silver) extraction method and features.

The atomic weight of silver is 107.87 amu and the fact that silver (Ag) is bactericidal has been known for a long time.

Silver nano (20) was first developed by a biotechnology company, a government-affiliated organization in our country, and was named silver nano (20) as a compound name of the brand name Na no-technology and silver. ;

  Silver nano (20) is a field of Na no-technology and is an advanced antimicrobial agent that utilizes silver's strong antibacterial and bactericidal function and excellent electrical conductivity mechanism. Silver nano (20) is unlikely to be resistant to bacteria, unlike conventional antibiotics. Silver nano (20) has been shown to kill almost all single cell germs on the ground in a short time. .

 Currently, a variety of products based on silver nano (20) consisting of powder and solution have been invented and commercialized and produced in real life. This technology, called silver nano (20), converts silver to nanometers (1 billion won). It is a small particle size of 1m / min), that is, 0.000000001mm. When one gram of silver is aged, ten particles can be produced.

Therefore, silver nano (20), which is made of silver in the form of ultra fine particles, is a new concept that is made by utilizing the excellent efficacy of antibacterial ability, deodorization range, and extension of food preservation time among many characteristics of silver. .

 Since ancient times, silver has been recognized as a disinfecting material that not only prevents bacteria but also East and West. Currently, the extraction method of silver (20) (Age 99.9%) is added to distilled water. It generates low current at low temperature, electrolyzes compounds containing silver, and conducts electrophoresis using + and-poles of each molecule to collect silver (Age 99.9%). In addition, liquid reduction and grinding It can be manufactured by the physical method such as, and the electrolysis method is used a lot to obtain a stable silver nano (20) (Nano silver).

Silver ions are also used in general sterilization concept machines and disinfectants, and all silver products currently used are silver obtained by decomposition, and the sterilization power of silver varies depending on the product, but can obtain up to 99%.

 The silver nano 20 of the present invention is an ultra-fine particle of silver having a particle size of 0.01 to 300 nm, which acts directly on harmful bacteria, directly dissolves the cell membranes of harmful bacteria, and interferes with the electron transfer system of the harmful bacteria, thereby making it safe. It has an excellent antibacterial and fungicidal range (99.9%). (The virus size is about 10 nm.)

     The main antimicrobial mechanism of silver nano (20) is to dissolve harmful bacteria cell membranes and interact with enzymes in the cells to block the metabolic function of nutrients, ie, the influx and discharge of nutrients, and to stop the respiratory function and production of harmful bacteria. And destroys regenerating ability to kill harmful bacteria.

     In addition, the silver nano (20) by controlling the harmful bacteria by releasing the antimicrobial power continuously from the fine particles is excellent in the antimicrobial, antimicrobial sustainability.

Therefore, silver nano (20) does not produce resistance and silver nano (20) has a surface reaction is effective and can kill all 99% of the bacteria, and particularly effective for the common E. coli or food poisoning.

   The smaller the nanoparticles, the better the bactericidal and antimicrobial activity. Based on the experimental data so far, Escherichia coli, Staphylococcus aureus, Salmonella, Vibrio bacillus, Heterogeneous bacteria, Pneumococcus, Typhoid bacillus and the most resistant MRSA Resistant Staphylococcus aureus) can be 99.9% antibacterial and sterilized.

     Even if silver exists in an ionic state or a metal state, it can be referred to as colloidal silver if it exists in a colloidal state by a solvent.

In silver nano (20) (Nano silver), the silver nano (20) with the minimized particles is the best antibacterial activity.

   In addition, unlike the general chemical antibacterial or chlorine disinfectant, silver nano (20) is a pure silver ultra fine particle, has excellent antibacterial and bactericidal zone (99.9%) even at high temperature, non-toxic and non-irritating to the human body, bacteria and E. coli virus fungus It has been reported that bacteria cannot live in contact with silver nano 20 for more than 5 minutes.

The present invention, as described above, the silver, metal, plastic, synthetic resin, minerals, gems, silicone, rubber material of any one of the material of the poly-based or at least one material of the mixture (160) of the material of the body of the head ornament (10) Coating (240) or mixing (160) nano (20) solution or powder to anti-sterilize bacteria and harmful substances attached to the hair ornaments (10) body, soften water, and release good silver ions and far infrared rays To a functional hair ornament 10 containing silver nano 20 to make;

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. First, in describing each of the drawings, the same reference numerals refer to the same reference numerals and components even though they are shown in different drawings.

1 is a perspective view showing the overall configuration of the hair ornaments 10 according to the present invention, the hair ornaments composed of a fastening head 40 and hair straps and hair drops and bands are made of metal, plastic, synthetic resin, minerals, Figure shows the body of the hair ornaments (10) made of at least one material of any one of jewelry, silicone, rubber poly series or mixed (160),

2 is a process diagram of the mixing 160 of the metal hair ornaments 10 according to the present invention. The material of the body of the hair ornaments 10 made of the above-mentioned minerals and precious metals (gold, platinum, iridium, platinum) is used in the barrel 50. Injected, heated (100), melted (60) or dissolved (80), softened (120), and stirred (140). At this time, the silver nano (20) is 0.01 based on 100% by weight of the total weight of the head ornament (10). To 30% by weight of a liquid or powder of a vegetable aroma base material such as fruit or aroma, herbal or flower flavor in a weight ratio of 0.01 to 10% by weight and the particle size of the silver nano 20 is 0.01 to 300nm It is characterized in that it is characterized by having a stirring and then put into a mold or molding (200) module (180) by molding (200) at this time the finished (380) head ornament (10) to enhance the sterilization power of the body silver nano ( It is also possible to coat 240 once again.

3 is a process diagram of mixing 160 of synthetic resins, plastics, minerals, silicones, and rubber poly-based hair ornaments 10 according to the present invention. The resin or powder material of the material is introduced into the barrel 50 and then heated 100. By softening (120) and the silver nano (20) to 0.01 to 30% by weight based on 100% by weight of the total weight of the hair ornaments (10) vegetable fragrance base material such as fruit or aroma, herbal, floral fragrance In order to add a liquid or powder in a weight ratio of 0.01 to 10% by weight and give the color of the hair ornaments (10)

0.1 to 5% by weight of the pigment (not shown), 0.1% to 5% by weight of the paint, the crosslinking agent, the curing agent or the flocculant, and other additives, and 0.01 to 5% of the silver nano 20 material in the total weight of the material. 30% by weight of the liquid or powder of vegetable fragrance-based raw materials such as fruit or aroma, herb, flower, etc. in a weight ratio of 0.01 to 10% by weight, the particle size of the silver nano (20) is 0.01 to 300nm After stirring to give a degree to the molding module 180 or the mold module 180 is molded in advance (200) by injection (220) or molding (200) or extruded through an extruder (230) and then slowly cooled After the drying 280 is completed 380, the particle diameter of the silver nano 20 is added is completed 380, characterized in that having a particle diameter of 0.01 to 300nm.

In addition, it is also possible to coat (240) the silver nano (20) once again in order to enhance the antiseptic power and corrosion resistance and surface reinforcement of the finished hair ornament (10) body.

Referring to the type and method of the injection molding 200 which is a method of mixing the hair ornament 10 made of plastic or synthetic resin, plastic, mineral, silicon, rubber poly-based material of FIG. 3 as follows.

1, injection molding

 The molding 200 material of the head ornament 10 is heated (100) and melted (60), and injected into the cavity of a previously closed mold, and then solidified or cured to form a product of a complex shape by a molding method of forming a molded product. It is suitable for forming a large field of molding processing together with the extrusion molding method.

 The molding materials used in the injection molding 200 are thermoplastic resins, which are mainly applied to almost all molding materials such as main resins, thermosetting resins, rubbers, foam molding materials, etc. Is being developed.

Molding is a standard type of line screw type injection molding machine which is ① mold, ② injection, ③ holding pressure (this series of processes to prevent backflow of material filled in cavity and extract by cooling is repeated as one cycle). When retracting and injecting by plasticizing the material, the screw advances to extrude the molding material, and this type of molding machine is also used for molding the thermosetting resin.

Compared to the thermoplastic resin, when the mold is heated (100) to cure the resin, the temperature of the heating cylinder is lowered so that the resin does not solidify. Therefore, the heating method of the cylinder and the shape of the screw are somewhat different. have.

Next, as a method of determining the injection molding conditions;

1, extrusion

 After the silver nano 20 was put into a thermoplastic material on the surface of various thin substrates such as paper, cloth, cellophane, plastic, vinyl, film, metal film, etc. It is a processing method in which it is extruded into a thin film form at the same time and simultaneously crimped continuously. The combination of the properties of the substrate and the characteristics of the extruded and compressed thermoplastics (water resistance, moisture resistance, chemical resistance, flexibility toughness, breathability, heat seal synthesis, and others) creates a packaging volume layer material adapted to a variety of applications, but is currently in practical use. Mainstream products are low density polyethylene, polypropylene, vinylene chloride resin and the like.

2, compression-molding

 In the most common molding method of the thermosetting resin, the molding material into which the silver nano 20 is put is put into a pot (called a cavity) of a heated mold and press-molded by a compression molding machine (press).

 The molding machine is heated in the cavity and once flowed, spreads to every corner of the cavity and causes a simultaneous chemical reaction to cure.Then open the mold after a suitable time (called curing time) and remove the molded product after finishing flash removal. Processing to obtain the product. If the molding process is largely divided into molding process and finishing process.

The molding process is carried out by ① molding material processing weighing (in some cases, it may be processed by a turret using a turret machine) ② loading of material into the cavity (preheated before)

 ③ Pressurization operation (low pressure pressurization, high pressure pressurization) ④ Curing process ⑤ Remove molded product It is to clean the mold.

Finishing process includes ① flash 뗌 ② gloss, etc., and for molding large and thick products, high frequency preheating is usually performed for efficiency and quality improvement. You must decide appropriately. In the case of thermoplastic products, compression molding is performed in the case of molding thick products or producing a silicon film. In this case, the trick is to remove the molded article by cooling the mold after heating and pressing the molding material. In general, the compression molding is characterized by less molding of the dielectric material or molecules compared to injection molding or transfer molding, so that it is easy to obtain a molded article having a low internal stress.

 3, extrusion-blow molding

 The plastic material or poly, synthetic resin, rubber, and silicon into which the silver nano 20 is injected are heated and melted (60) and inserted into one or two or more molds of flies continuously extruded into a tube from an extruder, and then closed and sealed. By blowing air into the fly's hand from the rear mandrel, the fly's hand sticks to the mold's inner wall, making it a product and the most popular blow molding method.

 4, blow molding

 Softening 120 as a heating in the split mold to inflate a fly hand or sheet into which thermoplastic or synthetic resin, rubber, poly, mineral, silicon material and silver nano 20 are injected using air pressure, Cooling is a method of obtaining an aerial body. Called blow molding or blow molding. Ordinarily extruded or melted thermoplastic plastic molding material or insert a flyson or two sheets of preformed into a tube according to the injection method into a molding die by heat into the molding die, and then heat softened (120) and blows in the air therein. To form a hollow product. There are various types of blow molding according to the Parisian state shaping method, and typical examples thereof include injection blow molding, extrusion blow molding, sheet blow method (sheet fly hand method), and direct blow molding.

5, vacuum forming

 After heating and softening 120 of the thermoplastic plastic material into which the silver nano 20 was injected, it was placed on the mold module 180. The gap between the tongue and the sheet was immediately vacuumed to closely adhere to the surface of the mold and cooled to fix the phenomenon of the molded product. On the contrary, if a female is used to take out the molded article by inhaling air on the contrary, it is called a straight forming, and a male is called a drape forming.

6. vacuum deposition;

A brief overview of vacuum deposition refers to the heating of a small piece of metal or nonmetal to which silver nano 20 is injected in a vacuum to attach the vapor to an object surface.

That is, a current flows through a high-vacuum state in which a current is applied to an object to be coated in a high vacuum state (an object to be deposited) and a tungsten coil inserted with a piece of metal (Al) or chromium (Cr) to be attached to the surface thereof. I'm using the way.

In the vacuum deposition process, the paint used in BASE and TOP consists of urethane acrylates and monomas, which can represent various types of products depending on whether the paint is glossy or matte.

In addition, dyes can be added during TOP PAINT spraying to represent any color desired.

Figure 4 is a coating 240 process diagram of plastic, synthetic resin, minerals, gems, silicone, rubber poly-based hair ornaments 10 according to the present invention, the molding 200 process and injection 220 process and the extruder of FIG. After extruded through 230, the body of the finished hair ornaments 10 (380) after removing the foreign matter on the surface and put into the barrel 50 (not shown) the flocculant or coating agent hair ornaments (10) total weight 100 weight 0.1% to 5% by weight, based on the percentage of the nano-20 material of the silver nano (20) to the total weight of the hair ornaments (10) body, such as fruit or aroma, herb, flower fragrance A liquid or powder of a fragrance raw material is added in a weight ratio of 0.01 to 10% by weight, and the particle size of the silver nano 20 has a particle size of 0.01 to 300 nm so as to be sprayed or deposited on the surface of the hair ornament 10. After completely coating (240) the silver nano (20) by slow cooling to dry 280 is a block diagram showing the steps to go through the process, after the inspection and packaging (380) is shown in the figure.

5 is a process diagram illustrating the coating 240 of the metallic hair ornament 10 according to the present invention.

 In order to coat (240) the interior and exterior of the finished hair ornaments (10) or hair ornaments (10), wet coating (240) method of electrocoating (240) silver nano (20) or dry coating using plasma All 240 methods may be used.

First, the wet coating 240 of the present invention will be described.

 The coating 240 can be divided into electro-coating and electroless coating. The silver coating 240 requires a solution containing silver ions and the gold coating 240 requires a solution containing gold ions. To the hair ornaments (10) silver nano (20) coating (240) to put the hair ornaments (10) on the positive side,-to the silver on the pole side of the hair ornaments (10) and silver ions Put the solution into the +,-to the electricity to the pole and slowly become the coating 240.

The electroless coating 240 has a substitution coating and a reduction coating, and the substitution coating, for example, when iron powder is added to the iron powder, iron tends to be more ionized, so electrons are given to the copper ions, and magnetic is dissolved, and copper is reduced to iron powder. Stick on and this is a substitution coating.

 First, the coating 240 is to prevent corrosion (or oxidation), and silver is less reactive than iron, so the oxidation rate is slow, and if scratches occur on the coated portion 240, water vapor or oxygen enters between them. .

First, the negative electrode of the battery is attached to the object (head ornament) to be coated (240), the positive electrode of the silver (AG) to the coating (240) on the silver metal, the silver cations and anions of the silver metal is separated, where the electron Go to the iron side of course, the aqueous solution contains silver ions, of course, if the silver coating (240) can be used as the aqueous solution containing silver ions.

-When the electrons come to the pole, the silver ions in the aqueous solution are attached to the hair ornaments (10) around the wet coating (240) and thus the amount of silver ions in the aqueous solution after the reaction does not change, but the mass of the silver metal Will be reduced.

Next, the plasma of the hair ornament 10 containing the silver nano 20 of the present invention

Or with respect to the sputtering coating method 240 is as follows.

Plasma and stuffing are gaseous states that are separated into electrons with positive charges and positively charged ions at high temperature, and have a high degree of charge separation but a neutral gas with the same number of positive and positive charges. Since the coulomb force acts between charges, it is characterized by the collective action of the whole moving under the influence of the distant state rather than the local state of the short distance. In 1928, I. Lang Muir of the United States first applied the concept of plasma to ionized gases produced during electrical discharges.

It is derived from the Greek words πλσμα, -ατos, τ and its original meaning is that it is built and assembled, and as the nature of the collective behavior suggests, it is easily controlled externally to deal with plasma. Rather, it is common that plasma itself behaves freely, and the original name is wrong. Plasma is the fourth material state after solid, liquid, and gas (three states of matter).

Gradually increasing the temperature, almost all objects change from solid to liquid and gaseous. At tens of thousands of degrees Celsius, the gas is separated into electrons and atomic nuclei, resulting in a plasma state. Plasma is not common in everyday life, but it is common throughout the universe. That's because 99% of the universe is estimated to be plasma.

For example, conduction gases that carry current in fluorescent lamps, ionized gases mixed in rockets or lightning strikes, aurora borealis in the atmosphere, ionospheres in the atmosphere, and out of the atmosphere are trapped by ions in the Earth's magnetic field. Plasma is present in the solar wind that pours intermittently from the sun, and the gas inside the star, the surrounding gas surrounding it, and the hydrogen gas filling the space between the stars are plasma states.

Each individual object of the plasma is electric, which is very different from the neutral gas, has a high electrical conductivity, and is confined to the surface like a metal conductor.The current flows only on the surface. As the charge density increases, it is easily influenced by the force, but as the charge density increases, the group movement differs from the individual movement. The self-closing required by nuclear fusion is used by the charge along the magnetic force line. will be.

To confine the plasma there by deforming the magnetic field lines appropriately and confining them to a place in space. Previously, plasma research has been conducted in geophysics and astrophysics related to plasma around the earth and celestial bodies, but recently, the development of electromagnetic fluid dynamics (MHD) using the electrical properties of plasma, ion engines and nuclear fusion research of space rockets for space travel. Research is underway for this purpose.

As such, the high temperature and active chemical properties of plasma can be used to provide extreme environments that are difficult to obtain by conventional methods, and to give physical and chemical properties different from those of the main body by changing the synthesis of new materials and the properties of metal or polymer surfaces.

Diamond, for example, is an important material not only for jewelry but also for industry because of its excellent properties such as high hardness, thermal conductivity, refractive index and large band gap. Artificial synthesis of diamond has been mainly used by the high temperature and high pressure method developed by GE of the United States in the 1950s, but it was found that diamond can be obtained in the form of thin film at low pressure from methane gas plasma in the Soviet Union in the early 80s. , Tool coatings, optical component coatings, and acoustic equipment are actively pioneering new applications.

In addition, Tin, which is used as a diffusion barrier at the contact point in the wear-resistant coating of a tool, a decorative coating, and a semiconductor device, can be made dry by Tim's reactive ion plating, sputtering, or Pecvd method.

In addition, if the surface of the polymer is treated with nitrogen or oxygen plasma, it can give hydrophilicity or hydrophobicity to the surface of the polymer, or it can improve the antistatic, dichroic, deep color, etc., and the metal material is contacted with nitrogen or methane gas plasma. When a bias is applied to the surface, a layer of nitriding or a carbon ornament 10 is formed on the surface to improve the hardness, wear resistance, corrosion resistance, and the like of the metal.

Some of the effects that can be obtained by surface coating 240 and modification techniques using plasma can be obtained by conventional wet methods, but considering the environmental problems, dry methods using plasma have many advantages. Welding, cutting and processing of materials using high temperature of plasma and plasma can be sprayed. High melting point powder is melted by plasma and coated on solid surface to greatly increase heat resistance, corrosion resistance and abrasion resistance. It can be increased.

 In addition, it is possible to manufacture ultra-fine particles, using the high temperature, high activity of the thermal plasma to quench the particles synthesized by the gas phase reaction to synthesize the ultra-fine particles to plasma chemistry or physical vapor deposition: to create a functional film using the plasma, high temperature, high activity of the thermal plasma The advantage is that the waste can be broken down and vitrified using.

If so, look at the plasma coating 240 process of the head ornament 10 of the present invention having many of the advantages as follows.

Plasma coating 240 injects argon and other gases into the vacuum chamber 300 and then causes an electrical discharge, the gases injected into the chamber 300 are ionized, and the silver target (silver plate) and the ionized gas is ionized The collision of silver atoms protrudes in a gaseous state and is coated 240 on a coating body (head ornament), and the thickness of the coating 240 may be dramatically controlled in nano units according to time.

On the other hand, the plasma coating process 240 will be described briefly as follows.

 In order to wash the foreign substances on the surface of the finished hair ornament 10, the hair ornament 10 is put into the washing tub, and the cleaning solution is injected to the inside or outside of the metal ornament 10 which is a metal ash using an ultrasonic vibrator. After the washing process (320) for washing the impurities attached in the manufacturing process, the rinsing process and drying (280) in the drying machine (280) to evaporate the moisture and then the hair ornaments (10) in the chamber attached to the holder (300) was subjected to the first silver nano-surface coating (340) after the sterilization process inside or outside the head ornament (10) with oxygen plasma under vacuum and then coated (240) with silver nano (20) Plasma secondary surface coating (360) and reinforcement treatment are performed to improve the surface adhesion of the head ornament (10) and to increase the strength of the head ornament (10).

Next, in the plasma coating 240 of the silver nano 20 finally by the vacuum macnetron sputtering plasma coating method, the plasma is coated with a desired thickness of 0.0 l (micrometer) µm to 50 µm (micrometer) in the plasma coating thickness. By coating (240) to complete (380) or to the total material of the hair ornaments 10 made of metal with silver nano (20) 0.01 to 30% by weight of vegetable flavors such as fruit or aroma, herb, flower flavor The liquid or powder of the base material is added in a weight ratio of 0.01 to 10% by weight, and other metals are alloyed by adding 10 to 99% by weight of stainless steel, 10 to 99% by weight of iridium, and 10 to 99% by weight of titanium. Silver to the total material of the hair ornament (10) made of a metal 0.01 to 30% by weight of liquid or vegetable aroma based raw materials such as fruit or aroma, herbal or floral Horses are added in a weight ratio of 0.01 to 10% by weight and 0.01 to 10% by weight of gold or gold nano zinc or 0.01 to 10% by weight zinc or zinc nano, platinum or platinum nano 20 to the entire material of the hair ornament 10 made of metal It is also possible to add 0.01 to 10% by weight of the body of the head ornament 10 is a nano alloy.

 The head ornament 10 is deposited on the container 50, 260 or injected into the injector and sprayed onto the surface of the head ornament 10 body to perform the coating 240 and drying 280 after completion In this case, the coating 240 has a thickness of 0.0 l (micrometer) µm to 50 µm (micrometer) and the particle diameter of the silver nano 20 particles to a particle diameter of 0.01 to 300 nm.

The following is a photograph taken with an electron microscope of the cross section, side, and surface of the silver nano 20 of the present invention, respectively, is shown in the drawings for the understanding of the present invention.

FIG. 6 is a photograph taken at 60.000 times magnification of a cross section of the silver nano 20 according to the present invention. FIG.

Figure 7 is a photograph taken on the side of the silver nano 20 of the present invention magnified 80.000 times.

Figure 8 is a photograph taken by magnified 50.000 times the surface of the silver nano 20 of the present invention.

Figure 9 is a photograph of the antimicrobial activity of the strain into which the silver nano (20) of the present invention.

10 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano 20 of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

11 is a three-dimensional structure diagram of the silver nano 20 of the present invention.

As a result, the block diagram of the silver nano (20) and the coating containing the fragrance 240 of the present invention and the photos and antimicrobial data of the silver nano (20) were examined, and the method of manufacturing the hair ornament (10) of the present invention is conventional hair ornaments (10) The manufacturing method and process of the body will be followed.

[Example]

Applicants were able to know the schematic process of the body of the head ornament 10 in order to experiment with this, and purchased silver ions of nano technology Cocosilver silver nano ion generator and stable distilled water In order to prepare silver nano ion water by electrolysis using D / C current, add 100% by weight of distilled water to 30% by weight of silver nano ion water and mix it with natural aromatic fragrance purchased from Samwha fragrance. Mixing (160) to 10% by weight and 20L of the material mixed with the number of the prepared silver nano (20) solution and the aromatic fragrance in a sterilized tank

 It is made of plastic head band worn by women in their 40s for 1 year, hairpin body of plastic metal material worn by 3 years of female college students of 20s with high standard of bacteria and cloth and synthetic resin worn by 6th graders. After immersing the made hair drops in the prepared nano-silver solution for 60 minutes (260), ions of silver ions (260) and then drying (280) for 60 minutes in a drying machine (280), and before and after the silver solution treatment Staphylococcus aureus The average values obtained by measuring pneumococcal bacteria, bacteria, and methicillin-resistant Staphylococcus aureus strains are shown briefly in the table below, and they can be applied industrially due to the good results expected by the applicant and the subtle natural emanation. It was confirmed that the present invention and completed the present invention (380).

The present invention is a silver nano (20) (Nano) in a variety of hair ornaments 10 made of at least one material of any one of metals, plastics, synthetic resins, minerals, jewelry, silicone, rubber poly-based or mixed 160 of them Silver) is added or coated (240) is characterized by having a hair ornament 10 that is sterilizing and antibacterial and silver ions and far infrared radiation.

As described above, silver nano (20) powder or nano (20) having a number of advantages according to the present invention is a (Ag) solution of hair ornaments (10) the material of the body metal, synthetic resin, plastic, 0.01 to 30% by weight of silver nano (20) in the body of the hair ornaments (10) made of mineral, jewelry, silicone, rubber poly-based material, the raw material of vegetable fragrance base materials such as fruit or aroma, herbal or flower The particle size of the silver nano 20 has a particle diameter of 0.01 to 300 nm and the thickness of the coating 240 of the silver nano 20 is 0.01 (micrometer) μm to 50 It is characterized in that the coating 240 to a thickness of (μm) (micrometer), the production and propagation of bacteria, pathogens and microorganisms can be used to clean and hygienically the head ornament 10 body.

In the above, the embodiments or preferred embodiments of the present invention are easily described.

Those skilled in the art to which the present invention pertains will understand that the present invention can be variously modified or modified without departing from the spirit and scope of the present invention and the scope of the patent described in the claims below.

The table below shows one example of a diagram in which Staphylococcus aureus, pneumococci, bacteria, and MRSA (Methicillin-resistant Staphylococcus aureus) bacteria were killed at 30% by 30% of silver nanoparticles. Nano 20 was found to have excellent sterilizing power.

test subject unit Number of strains  30% nano addition (after 60 minutes) Staphylococcus aureus CFU / mL 3.4 X 10 ³ 0 Pneumonia group CFU / mL 3.1 X 10 ³ 0 MRSA (Methicillin Resistant Staphylococcus Aureus) CFU / mL 1.3 X 10 ² 0 bacteria CFU / mL 3.4 X 10 ² 0

  (This test report is the analysis data of Korea Testing Institute)

Claims (12)

 To the hair ornaments 10 used for fixing the hair made of any one material of metal, plastic, resin, minerals, gems, silicone, rubber poly-based or at least one material mixed (160) In. Based on the hair ornament (10) 100% by weight of the hair nano (20) material 0.01 to 30% by weight and the fragrance base material 0.01 to 10% by weight of the hair ornament (10) is characterized in that the mixture 160 in the body accessories.  In normal hair ornaments divided into hairpins, hair straps, hair drops, and bands, Hair ornaments, characterized in that it further comprises a silver nano (20) material based on the total 100% by weight of the jewelry material 0.01 to 30% by weight of the hair ornaments (10) the body is coated (240). The method according to claim 1 or 2, Silver nano-injected to the hair ornaments (10) is characterized in that the hair ornaments having a particle diameter of 0.01 to 300nm. The method according to claim 2, The coating 240 of the silver nano (20) material is a hair ornament, characterized in that the coating film 240 is formed on the body of the hair ornament (10) to a thickness of 0.0l㎛ to 50㎛ (micrometer). The method according to claim 1, Silver nano 20 is added in an amount of 0.01 to 10% by weight or 0.01 to 20% by weight to the entire material of the hair ornament 10 made of metal, and other metals are 10 to 99% by weight of stainless steel and 10 to 99% by weight of iridium. Titanium 10 to 99% by weight is added to the hair ornaments, characterized in that the body of the hair ornaments 10 is alloyed. The method of claim 5, wherein 0.01 to 10% by weight or 0.01 to 20% by weight of silver nano 20 is added to the entire material of the hair ornament 10 made of metal, and other metals are 0.01 to 10% by weight of zinc or zinc nano. 0.01 to 10% by weight, platinum or platinum nano (20) 0.01 to 10% by weight of the hair ornaments, characterized in that the body of the hair ornaments (10) is mixed with a nano alloy (160).  The method according to claim 2, In order to coat 240 the hair ornament 10 made of a metal material, a wet coating by electrolysis of the body of the hair ornament 10 extruded 230 through a molding 200 process, an injection 220 process, or an extruder Hair ornaments characterized in that the coating method of any one of the 240, the stuffing, the dry coating by plasma (240). The method according to claim 2   Crosslinking agent, pressure-sensitive adhesive and silver nano in the process of completing (380) the hair ornament 10 made of at least one material of any one of plastics, synthetic resins, minerals, gems, silicone, rubber poly-based or mixed (160) (20) Hair ornaments, characterized in that by mixing (160) by spraying or depositing (260) on the body to the hair ornaments (10) the silver nano (20) coating film 240 is formed. The method of claim 8, Hair ornaments (10) After coating the ground color on the surface after drying (280) and drying (280) and the hair ornaments characterized in that the surface resistance coating 240 to lower the surface resistance from the rough hair ornaments (10) surface. The method according to claim 1, After removing this material in plastic or synthetic resin, it is added to the container 50, melted 60, softened 120, and the paint, crosslinking agent and curing agent are added at 0.1 to 5% by weight, and the color of the hair ornament 10 is removed. Pigment is added to 0.1 to 5% by weight in order to produce agitation 140, and the head ornament, characterized in that the injection (220) by injection into the mold module 200 is molded (200) or extruded (230) through an extruder . The method of claim 2.  The wet coating method of the hair ornament 10 is a method of attaching a metal hair ornament 10 on the positive side and attaching a target silver lump to the pole side to include the hair ornament 10 and the silver lump in the silver tube. The hair ornaments, characterized in that the wet coating (240) by putting in the prepared solution +,-electricity to the poles. The method of claim 2. Dry coating, stuffing or plasma coating 240 through the washing process 320 and the rinsing process, after drying (280) attached to the hair ornaments 10, the holder and then introduced into the chamber 300, the hair ornaments (10) Hair ornaments, characterized in that to coat (240) the body.

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