KR200398392Y1 - necklace - Google Patents

Abstract

The present invention relates to a necklace (10) that a person wears on the neck. The material of the necklace (10) is variously released in various types and capacities such as metal plastic, synthetic resin, minerals, jewelry, silicone, and rubber. .

The present invention is a silver nano to the body of the necklace 10 made of at least one material or a mixture of any one of metal, plastic, synthetic resin, minerals, gems, silicone, rubber poly-based material of the necklace (10) (20) Mixing 160 or coating 0.01 to 30% by weight of the liquid or powder of the raw material of the vegetable fragrance (30), such as a fruit or aroma, herbal, or floral fragrance, or 0.01 to 10% by weight (240) relates to a method for producing a functional necklace 10 having an antibacterial effect and an antitoxic effect.

Description

Necklace {necklace}

The present invention relates to a necklace (10) that is usually worn on the neck to make a person as fashionable as described above, the silver nano (20) is mixed (160) or coated (240) during the manufacture of the necklace (10), antibacterial and far-infrared and silver The present invention relates to a method of manufacturing a functional necklace 10 which continuously maintains a function of emitting ions. The origin and background of the necklace 10 will be described in detail as follows.

Necklace (necklace) is a string or ring of ornaments that decorate the neck or breasts. The necklace (10) is not only intended for aesthetic effects, but also by religious witchcraft, to protect the neck, sex. There are various kinds of things, such as to show sexuality and status.

The generation of the necklace 10 is long with human history.

In the beginning, humanity devotes attention to the fetishism that supernatural forces are attached to objects, and on the other hand, to the neck, which is an important part of the human body. You can guess.

This can be seen by looking at the stone age artifacts, or by looking at the customs of existing savages, such as the tree fruit, shells, animal bones, horns, teeth or stones, and pieces of baked goods found in the artifacts. to be.

The necklace 10 is thus one of the most common ornaments for mankind regardless of the East or the West, and it is speculated that the necklace 10 was used in advance of the garment based on the connected beads. As technology has advanced, these have been replaced by glass, pottery, amber and other jewellery. Furthermore, with the advent of the metal age, coexistence and mixing with metals has been achieved.

For example, among the remains of Mesopotamian upper class women from 4000 BC to 3000 BC, there were chokers of glass, ruby, gold, etc. bib (a bib) or chaplet was found in many places, especially the ancient Egyptian dynasty lords who thought of the necklace (10) as a kind of property, and a string of necklaces made of beautiful stones (turquoise, agate, malachite, etc.) 10) showed off their wealth and power.

In China, he used holes in molars, rice, horns, shells, and purgatory in the Neolithic era. In Henan, Henan province, carvings of monsters were found in jade and ivory.

In prehistoric northern Europe, heavy color was used, which was completely different in style. It is a twist of bronze called torque, twisted into a ring shape, and the color of U-shaped iron plate.

Also, with Egypt, the ancient necklace (10) is Southern Europe, and with the development of materials and technology the formal foundations are nearing completion in this age.

In particular, the chains of Etruscque and those made of granulated gold are famous, and chain necklaces (10) with various diamonds, such as Greek diamonds, sapphires, garnets and opals, and cameo and Roman The use of pearls is noted.

Since the Middle Ages, these techniques have been passed down to Byzantine and have spread throughout Europe. In addition to gold and precious stones with elaborate geometrical connections, the technology of colorful artificial gemstones, such as glass and cloisonne, was highly developed in Byzantine, greatly affecting the work of the early European medieval necklace (10). At the end of the Middle Ages, attention is paid to elaborate carcanets, and a multi-ply chain necklace (10), particularly popular in Germany. However, the necklace (10) up until this time only symbolized the status of a certain upper class.

After that, the renaissance tended to subside somewhat,

In Italy, which was spread again to the common people as a sign, and especially in the early days of exchanges with the East, gold and silver craftsmanship, cameo, pearls, glass, etc., developed sophisticated craftsmanship, which led to the European jewelry technology. It had a lot of influence. Among them, cameo and pearl are representative of the modern age necklace (10).

With the simplification of the dress in the early eighteenth century, the temporary stagnation necklace (10) changed to a simple ribbon at the end of the year, and by the nineteenth century no previous splendor was restored. At the end of the 19th century, the evaluation of handwork increased, and as the science and technology such as artificial jewelry developed, the necklace (10) became noticeably popularized after World War II.

 The present application relates to a functional necklace (10) containing silver nano (20) which anti-sterilizes with far infrared rays and silver ions by mixing (160) silver nano (20) in the manufacture of the necklace (10)

As described above, the necklace 10 of the present invention is not simply physical or electrical sterilization of the machine, but is simply input at the time of manufacture of the body of the necklace 10. Containing the material, you can continue to get the following outstanding benefits anytime, anywhere, without wasting electrical power or waste of time:

Silver nano (20) is harmless to the human body and has a sterilizing power tens of times stronger than the chlorine series. If so, the following is a list of preferred features of the necklace 10 of the present invention.

  As described above, the present invention relates to a necklace 10 that a person usually wears to fashion a neck. The silver nano 20 is mixed into the body of the necklace 10 (160) or

It relates to a manufacturing method of the necklace 10 by the coating 240, the action of anti-sterilizing the necklace 10 is maintained continuously.

The present application relates to a functional necklace (10) containing silver nano (20) mixed (160) or coated (240) silver nano (20) in the manufacture of the necklace (10),

As described above, the necklace 10 of the present invention is not simply physical or electrical sterilization of the machine, but is simply input at the time of manufacture of the body of the necklace 10. Containing the material, you can continue to get the following outstanding benefits anytime, anywhere, without wasting electrical power or waste of time:

Silver nano (20) is harmless to the human body and has a sterilizing power tens of times stronger than the chlorine series. If so, the following is a list of preferred features of the necklace 10 of the present invention.

  First, the necklace (10) containing silver nano (20) generates healthy silver ions and far-infrared rays, which increases blood circulation and endocrine activity when used, and more than 90% of forum aldate, an environmental hormone that has become a problem recently. It has many advantages of blocking and protecting the skin by anti-viral and anti-allergic vitamin B6, the soft touch, deodorizing effect and the disinfecting effect in repeated washing.

Secondly, it reacts sensitively according to the pollution level of the environment and shows continuous antiseptic action by destroying bacterial cell membranes or disturbing cell functions.

 Recent research has shown that silver nano (20) can sterilize 650 bacteria and viruses, and prevents secondary infections in hospitals where it is a problem due to its excellent anti-bacterial and antibacterial function of harmful bacteria and microorganisms. Silver catalyzes the conversion of oxygen into active oxygen, which prevents germs from propagating by germ and germ propagated by sweat, saliva or dust secreted by the human body.

Third: silver nano (20) is very easy to coating (240), mixing (160), injection, etc. with the material, metal, plastic, synthetic resin, minerals, jewelry, silicon, rubber which is the material of the necklace 10 of the present invention The material and the mixture 160 or coating 240 of the body of the necklace 10 made of a poly-based is made well.

Fourth: Deodorant effect and fragrance divergence effect. Necklace 10 of the present invention is a user from time to time

Even when washing or disinfecting from time to time, a bacterial film is formed on the surface of the necklace 10 due to the pollutants secreted from the human body of the human body, and in particular, in the hot summer, a bad smell is generated by the human sweat.

Silver nano 20 of the present invention and the necklace containing the fragrance 10 is a liquid of the vegetable fragrance (30) raw material such as fruit or aroma, herbal, flower fragrance in any one of the preferred process during the manufacturing process or final process B. The powder is added in a weight ratio of 0.01 to 10% by weight, so that the subtle scent is always emitted.Therefore, the necklace (10) of our head office enjoys the effect of pleasing the smell of users and others and maintains the lasting sterilizing power. It is effective to let.

 Fifth: It has a sunscreen effect. Nanoized silver has excellent UV protection, so it is used in textiles, cosmetics, sunglasses, etc.

Necklace (10) prevents the phenomenon of fading or discoloration by preventing corrosion by ultraviolet rays of the sun.

 The present invention is to solve the conventional problems as described above

 Silver or aged silver nano (20) is used to mix the material of the body of the necklace (10) body made of metal, synthetic resin, plastic, minerals, jewelry, silicone, rubber poly series of the body of the necklace (10) (160) Alternatively, the coating 240 may be used to sterilize the neck of the human body to which the necklace 10 is caught. More specifically, silver powder or silver ions, which are different from silver powder or silver ions, may be formed in the form of nano powder or nano silver ( After the Ag) solution, 0.01 to 30 weight of silver nano 20 is added to the material of the necklace 10 body made of metal, plastic, synthetic resin, minerals, gems, silicone, and rubber poly based materials of the necklace 10 body. % And the liquid or powder of the vegetable fragrance (30) raw materials such as fruit or aroma, herb, flower, etc. in a weight ratio of 0.01 to 10% by weight (160) or coating (240) and the silver nano (20) The particle size of the fine particles is 0.01 to 300 When the coating 240 has a particle size of the coating 240 is a thickness of 0.0l㎛ ~ 50㎛ (micrometer) is characterized in that to form a silver nano (20) coating film 240 on the necklace 10 body As a result, the antiseptic power is made continuously.

The present invention is 100% by weight of the entire material of the body of the necklace (10) consisting of at least one material of any one of metals, plastics, synthetic resins, minerals, jewelry, silicone, rubber poly-based or mixed (160) 0.01 to 30% by weight of the silver nano (20) and liquid or powder of the raw material of natural vegetable fragrances (30) such as fruit or aroma, herbal or flower, and the weight ratio of 0.01 to 10% by weight of the necklace ( 10) relates to a necklace 10, characterized in that the mixture is put into the material of the body (160) or coating (240).

Detailed description of the silver and silver nano (20) which is a constituent of the present invention in order to help understanding of the present invention is as follows.

    Nanotechnology is a technology that identifies and controls substances at the molecular and atomic levels.It comes from the Greek word dwarf, lanose, and 1 nanometer 'corresponds to one-tenth of the thickness of the hair. It is made of silver solution (colloid), which is a chemical decomposition method or a fine particle state in nano units, and is widely used in industrial fields.

Silver, the main component of silver (20), has been recognized as a precious metal of high value from ancient times, and has been the object of extraction, and it is recognized as an important industrial material in modern industry as well as its value as a currency. The production of silver is proportional to the production of gold in many ways.

Silver was mined early in Europe's Mediterranean coast, where silver was produced from the Incas and Aztecs before the discovery of the Americas, and then silver from Peru and Bolivia entered Europe and flowed out from 1520 to 1800.

It has grown steadily, but has declined since the discovery of large amounts of silver in the early 19th century.

Currently, the world's major silver producers are Russia (13.8%), Canada (13.5%), Mexico (13%), Peru (13%), United States (11%), Australia (8%), Poland (6%). The country's silver reserves are 17 million tons, and its mining capacity is about 1.2 million tons. As of 2002, silver produced in Korea is about 5,000 kg, which accounts for 1.2% of the total domestic demand. The amount is so small that the rest of the silver is imported from abroad.

Characteristics of silver: The color of silver is gray in the case of elegant gray-white metal or powder, specific gravity is 10-12, Mohs hardness is 2.5-3, melting point 280 is 960.5 ℃.

In particular, the melting point (280) of silver is very important for the temperature compensation of high thermometers, and it is the standard of scientific and industrial temperature. Silver is the best conductor of metal, and is used comprehensively for mechanical contacts and other electronics. .

Silver is optically 90% of visible light, which is one of the most excellent metals like platinum. Pure silver does not rust even when left in the air or heated (100), but it reacts with sulfur and hydrogen sulfide to emulsify it. Silver is made and turns black.

     In addition, the mechanical properties change according to the amount of impurities (O₂) contained in the silver, and the hardness of the high-purity silver obtained by thermal annealing is Brinell hardness HBS (10/500) 25-27, tensile strength 12-16kgf / mm2. The cast strength of the cast was up to about 29 kgf / mm 2, the combustion rate was 48 to 54%, and the recrystallization temperature was 150 ° C.

    In particular, in the case of pure silver, the processed hardened material is softened by recrystallization at normal room temperature and softened softly. The malleability and flexibility are rich after gold.

     The effect of silver has been used as a tool to check the imbalance of the body that one cannot feel because the gloss or color changes depending on the condition of the body when worn on the body from ancient times. This fatigue or low rhythm), Dongbobogam said that it is effective in the prevention and treatment of mental disorders and women's diseases such as epilepsy and game. The five chapters are said to be comfortable, the mind and body are stabilized, and the main body records that the body is lengthened by chasing morale and lightening the body.

      Also, when the Black Plague prevailed in the Middle Ages, nobility of the black aristocrats and royals, who had many silverware and silver utensils, did not have black plague, which released silver to the extent that it was able to sterilize the Black Plague bacteria, making it relatively safe from infectious diseases. In the place where the royal family and the state guests were served, silver products were used habitually.

In order to help the understanding of the silver nano (20) briefly described the silver nano (20) (Nano silver) extraction method and features in the present invention as follows.

The atomic weight of silver is 107.87 amu and the fact that silver (Ag) is bactericidal has been known for a long time.

Silver nano (20) was first developed by a biotechnology company, a government-affiliated organization in our country, and was named silver nano (20) as a compound name of the brand name Na no-technology and silver. ;

  Silver nano (20) is a field of Na no-technology and is an advanced antimicrobial agent that utilizes silver's strong antibacterial and bactericidal function and excellent electrical conductivity mechanism. Silver nano (20) is unlikely to be resistant to bacteria, unlike conventional antibiotics. Silver nano (20) has been shown to kill almost all single cell germs on the ground in a short time. .

 Currently, a variety of products based on silver nano (20) consisting of powder and solution have been devised and produced in real life. This technology, called silver nano (20), uses silver nanometer (1 billion won). It is a small particle size of 1m / min), that is, 0.000000001mm. When one gram of silver is aged, ten particles can be produced.

Therefore, silver nano (20), which is made of silver in the form of ultra fine particles, is a new concept that is made by utilizing the excellent efficacy of antibacterial ability, deodorization range, and extension of food preservation time among many characteristics of silver. .

 Since ancient times, silver has been recognized as a disinfecting material that not only prevents bacteria but also East and West. Currently, the extraction method of silver (20) (Age 99.9%) is added to distilled water. It generates low current at low temperature, electrolyzes compounds containing silver, and conducts electrophoresis using + and-poles of each molecule to collect silver (Age 99.9%). In addition, liquid reduction and grinding It can be manufactured by the physical method such as, and the electrolysis method is used a lot to obtain a stable silver nano (20) (Nano silver).

Silver ions are also used in general sterilization concept machines and disinfectants, and all silver products currently used are silver obtained by decomposition, and the sterilization power of silver varies depending on the product, but can obtain up to 99%.

 The silver nano 20 of the present invention is a silver fine particle having a particle size of 0.01 to 300 nm, which acts directly on harmful bacteria, directly dissolves the cell membranes of harmful bacteria and interferes with the electron transfer system of the harmful bacteria, thereby making it safe. It has an excellent antibacterial and fungicidal range (99.9%). (The virus size is about 10 nm.)

     The main antimicrobial mechanism of silver nano (20) is to dissolve harmful bacteria cell membranes and interact with enzymes in the cells to block the metabolic function of nutrients, ie, the influx and discharge of nutrients, and to stop the respiratory function and production of harmful bacteria. And destroys regenerating ability to kill harmful bacteria.

     In addition, the silver nano (20) by controlling the harmful bacteria by releasing the antimicrobial power continuously from the fine particles is excellent in the antimicrobial, antimicrobial sustainability.

Therefore, silver nano (20) does not produce resistance and silver nano (20) is effective to perform a surface reaction and kill all the germs 99%, particularly effective in the general E. coli or food poisoning.

   The smaller the nanoparticles, the better the bactericidal and antimicrobial activity. Based on the experimental data so far, Escherichia coli, Staphylococcus aureus, Salmonella, Vibrio bacillus, Heterogeneous bacteria, Pneumococcus, Typhoid bacillus and the most resistant MRSA Resistant Staphylococcus aureus) can be 99.9% antibacterial and sterilized.

     Even if silver exists in an ionic state or a metal state, it can be referred to as colloidal silver if it exists in a colloidal state by a solvent.

In silver nano (20) (Nano silver), the silver nano (20) with the minimized particles is the best antibacterial activity.

   In addition, unlike the general chemical antibacterial or chlorine disinfectant, silver nano (20) is a pure silver ultra fine particle, has excellent antibacterial and bactericidal zone (99.9%) even at high temperature, non-toxic and non-irritating to the human body, bacteria and E. coli virus fungus It has been reported that bacteria cannot live in contact with silver nano 20 for more than 5 minutes.

The present application, as described above, silver nano to a material of the body of the necklace (10) made of at least one material of any one of the above metals, plastics, synthetic resins, minerals, gems, silicones, rubber poly series or mixed (160) (20) Coating (240) or mixing (160) solutions or powders to antiseptic bacteria and harmful substances attached to the necklace (10) body, to soften water and to release good silver ions and far infrared rays It relates to a functional necklace 10 containing silver nano (20) for;

Hereinafter, with reference to the accompanying drawings will be described in detail the most preferred embodiment of the present invention. First, in describing each of the drawings, the same reference numerals refer to the same reference numerals and components even though they are shown in different drawings.

Figure 1 is a perspective view showing the overall configuration of the necklace 10 according to the present invention, the metal, plastic, synthetic resin, minerals, jewelry, silicon made of a fastening portion 40 that can be hanged or dismantled the neck and the body of the necklace , Is a diagram showing the body of the necklace 10 made of at least one material of any one of the rubber poly series or mixed (160),

2 is a process diagram 160 of mixing the metal necklace 10 according to the present invention, the material of the necklace 10 body made of the mineral and precious metals (gold, platinum, iridium, platinum) is put into the barrel 50 and Heating (100) to melt (60) or dissolving (80) to soften (120) and then stirring (140), wherein the silver nano (20) is 0.01 to 30 weight based on 100 weight percent of the total weight of the necklace (10). % And 0.01 to 10% by weight of the liquid or powder of the vegetable fragrance (30) raw materials such as fruit or aroma, herb, flower, etc., by weight ratio and the particle size of the silver nano (20) is 0.01 to 300nm It is characterized in that it is characterized in that it is put into the mold or molding (200) module after the injection (180) by molding (200) at this time the finished nano (10) necklace (10) to enhance the sterilizing power of the silver nano (20 It is also possible to coat 240 once again.

3 is a process diagram of the mixing 160 of the synthetic resin, plastic, silicone, rubber poly-based necklace 10 according to the present invention, and the resin or powder material of the material is introduced into the barrel 50 and then heated (100) to soften ( 120) and 0.1 to 5% by weight of pigment (not shown) to give the color of the necklace 10. 0.1% to 5% by weight of paint, crosslinking agent, curing agent or flocculant and other additives are added to the material. 0.01 to 30% by weight of silver nano (20) material and 0.01 to 10% by weight of liquid or powder of natural vegetable fragrance (30) raw materials such as fruit, aroma, herb and flower And the particle size of the silver nano 20 to have a particle size of 0.01 to 300nm, and after stirring the injection (200) or injection molding (180) or the molding module 180 or a mold module that is pre-molded (200) 200 or after extrusion 230 through an extruder Cold-finished and there is 380 and dried 280. The injected is to be completed (380) and characterized in that it has a particle diameter of the particle size of the nano (20) is in the range of 0.01 to 300㎚.

In addition, it is also possible to coat (240) the silver nano (20) once again in order to enhance the sterilization power and corrosion resistance and surface strengthening of the finished necklace (10) body.

Referring to the type and method of the injection molding 200, which is a method of mixing the necklace 10 made of the plastic or synthetic resin, plastic, mineral, silicon, rubber, poly-based material of FIG.

1, injection molding

 Suitable for mass production of complex shaped products by molding method of molding (200) material of the necklace (10) by heating (100) melting (60), injection filling into a cavity of a pre-closed mold, and then solidifying or curing to form a molded product. In addition to the extrusion process, forming a large field of molding process.

 The molding materials used in the injection molding 200 are thermoplastic resins, which are mainly applied to almost all molding materials such as main resins, thermosetting resins, rubbers, foam molding materials, etc. Is being developed.

Molding is a standard type of line screw type injection molding machine which is ① mold, ② injection, ③ holding pressure (this series of processes to prevent backflow of material filled in cavity and extract by cooling is repeated as one cycle). When retracting and injecting by plasticizing the material, the screw advances to extrude the molding material, and this type of molding machine is also used for molding the thermosetting resin.

Compared to the thermoplastic resin, when the mold is heated (100) to cure the resin, the temperature of the heating cylinder is lowered so that the resin does not solidify. Therefore, the heating method of the cylinder and the shape of the screw are somewhat different. have.

Next, as a method of determining the injection molding conditions;

1, extrusion

 After the silver nano 20 was put into a thermoplastic material on the surface of various thin substrates such as paper, cloth, cellophane, plastic, vinyl, film, metal film, etc. It is a processing method in which it is extruded into a thin film form at the same time and simultaneously crimped continuously. The combination of the properties of the substrate and the characteristics of the extruded and compressed thermoplastics (water resistance, moisture resistance, chemical resistance, flexibility toughness, breathability, heat seal synthesis, and others) creates a packaging volume layer material adapted to a variety of applications, but is currently in practical use. Mainstream products are low density polyethylene, polypropylene, vinylene chloride resin and the like.

2, compression-molding

 In the most common molding method of the thermosetting resin, the molding material into which the silver nano 20 is put is put into a pot (called a cavity) of a heated mold and press-molded by a compression molding machine (press).

 The molding machine is heated in the cavity and once flowed, spreads to every corner of the cavity and causes a simultaneous chemical reaction to cure.Then open the mold after a suitable time (called curing time) and remove the molded product after finishing flash removal. Processing to obtain the product. If the molding process is largely divided into molding process and finishing process.

The molding process is carried out by ① molding material processing weighing (in some cases, it may be processed by a turret using a turret machine) ② loading of material into the cavity (preheated before)

 ③ Pressurization operation (low pressure pressurization, high pressure pressurization) ④ Curing process ⑤ Remove molded product It is to clean the mold.

Finishing process includes ① flash 뗌 ② gloss, etc., and for molding large and thick products, high frequency preheating is usually performed for efficiency and quality improvement. It should be decided properly. In the case of thermoplastic products, compression molding is performed in the case of molding thick products or producing a silicon film. In this case, the trick is to remove the molded article by cooling the mold after heating and pressing the molding material. In general, the compression molding is characterized by less molding of the dielectric material or molecules compared to injection molding or transfer molding, so that it is easy to obtain a molded article having a low internal stress.

 3, extrusion-blow molding

 The plastic material or poly, synthetic resin, rubber, and silicon into which the silver nano 20 is injected are heated and melted (60) and inserted into one or two or more molds of flies continuously extruded into a tube from an extruder, and then closed and sealed. By blowing air into the fly's hand from the rear mandrel, the fly's hand sticks to the mold's inner wall, making it a product and the most popular blow molding method.

 4, blow molding

 Softening 120 as a heating in the split mold to inflate a fly hand or sheet into which thermoplastic or synthetic resin, rubber, poly, mineral, silicon material and silver nano 20 are injected using air pressure, Cooling is a method of obtaining an aerial body. Called blow molding or blow molding. Ordinarily extruded or melted thermoplastic plastic molding material or insert a flyson or two sheets of preformed into a tube according to the injection method into a molding die by heat into the molding die, and then heat softened (120) and blows in the air therein. To form a hollow product. There are various types of blow molding according to the Parisian state shaping method, and typical examples thereof include injection blow molding, extrusion blow molding, sheet blow method (sheet fly hand method), and direct blow molding.

5, vacuum forming

 After heating and softening 120 of the thermoplastic plastic material into which the silver nano 20 was injected, it was placed on the mold module 180. The gap between the tongue and the sheet was immediately vacuumed to closely adhere to the surface of the mold and cooled to fix the phenomenon of the molded product. On the contrary, if a female is used to take out the molded article by inhaling air on the contrary, it is called a straight forming, and a male is called a drape forming.

6. vacuum deposition;

A brief overview of vacuum deposition refers to the heating of a small piece of metal or nonmetal to which silver nano 20 is injected in a vacuum to attach the vapor to an object surface.

That is, a current flows through a high-vacuum state in which a current is applied to an object to be coated in a high vacuum state (an object to be deposited) and a tungsten coil inserted with a piece of metal (Al) or chromium (Cr) to be attached to the surface thereof. I'm using the way.

In the vacuum deposition process, the paint used in BASE and TOP consists of urethane acrylates and monomas, which can represent various types of products depending on whether the paint is glossy or matte.

In addition, dyes can be added during TOP PAINT spraying to represent any color desired.

4 is a process diagram of the coating 240 of plastic, synthetic resin, minerals, gems, silicone, rubber poly-based necklace 10 according to the present invention through the molding 200 process and injection 220 process and the extruder of FIG. After extruded 230, the body of the finished necklace 380 is removed, and the foreign material is removed from the surface, and then put into the container 50, and the flocculant or coating agent is added based on 100% by weight of the total weight of the necklace 10. Into 0.1 to 5% by weight and the total weight in the necklace (10) body of the nano-nano (20) material 0.01 to 30% by weight and natural vegetable fragrances such as fruit or aroma, herbal, floral fragrance (30 A) agitation 140 by adding a weight ratio of 0.01 to 10% by weight of the liquid or powder of the raw material. The particle size of the silver nano 20 has a particle size of 0.01 to 300 nm so that it is sprayed or deposited on the surface of the necklace 10. (260) and completely coated (240) the silver nano (20) and then slowly cooled to dry (280 After the process, inspection and packaging and completion (380) is shown as a block diagram showing the step.

5 is a process diagram of a coating 240 of the metallic necklace 10 according to the present invention. When this is described, the coating 10 of the necklace 10 or the necklace 10 of the finished necklace 380 is coated with silver nano 20 The wet coating 240 method of the electrical coating 240) or the dry coating method 240 using the plasma can be used.

First, look at the wet coating 240 of the present invention as follows.

 The coating 240 can be divided into electro-coating and electroless coating. The silver coating 240 requires a solution containing silver ions and the gold coating 240 requires a solution containing gold ions. To the necklace (10) silver nano (20) coating (240) to put the necklace (10) on the positive side,-to the silver side on the pole side of the necklace (10) is a solution containing silver ions Put it in the + and-poles to flow electricity and slowly become a coating (240).

The electroless coating 240 has a substitution coating and a reduction coating, and the substitution coating, for example, when iron powder is added to the iron powder, iron tends to be more ionized, so electrons are given to the copper ions, and magnetic is dissolved, and copper is reduced to iron powder. Stick on and this is a substitution coating.

 First, the coating 240 is to prevent corrosion (or oxidation), and silver is less reactive than iron, so the oxidation rate is slow, and if scratches occur on the coated portion 240, water vapor or oxygen enters between them. .

First, the negative electrode of the battery is attached to the object (necklace) to be coated (240), the positive electrode of the silver to the metal (AG) to be coated (240) on the silver metal, and the anion of the silver, where the electron is the negative pole Of course, the aqueous solution contains silver ions, and of course, the silver coating 240 may be used as the aqueous solution containing silver ions.

When the electrons come to the pole, the silver ions in the aqueous solution are attached to the necklace 10 around the wet coating 240. Thus, the amount of silver ions in the aqueous solution is not changed after the reaction. Will be reduced.

Next, the plasma of the necklace 10 containing the silver nano 20 of the present invention

Or with respect to the sputtering coating method 240 is as follows.

Plasma and stuffing are gaseous states that are separated into electrons with positive charges and positively charged ions at high temperature, and have a high degree of charge separation but a neutral gas with the same number of positive and positive charges. Since the coulomb force acts between charges, it is characterized by the collective action of the whole moving under the influence of the distant state rather than the local state of the short distance. In 1928, I. Lang Muir of the United States first applied the concept of plasma to ionized gases produced during electrical discharges.

It is derived from the Greek words πλσμα, -ατos, τ and its original meaning is that it is built and assembled, and as the nature of the collective behavior suggests, it is easily controlled externally to deal with plasma. Rather, it is common that plasma itself behaves freely, and the original name is wrong. Plasma is the fourth material state after solid, liquid, and gas (three states of matter).

Gradually increasing the temperature, almost all objects change from solid to liquid and gaseous. At tens of thousands of degrees Celsius, the gas is separated into electrons and atomic nuclei, resulting in a plasma state. Plasma is not common in everyday life, but it is common throughout the universe. That's because 99% of the universe is estimated to be plasma.

For example, conduction gases that carry current in fluorescent lamps, ionized gases mixed in rockets or lightning strikes, aurora borealis in the atmosphere, ionospheres in the atmosphere, and out of the atmosphere are trapped by ions in the Earth's magnetic field. Plasma is present in the solar wind that pours intermittently from the sun, and the gas inside the star, the surrounding gas surrounding it, and the hydrogen gas filling the space between the stars are plasma states.

Each individual object of the plasma is electric, which is very different from the neutral gas, has a high electrical conductivity, and is confined to the surface like a metal conductor.The current flows only on the surface. As the charge density increases, it is easily influenced by the force, but as the charge density increases, the group movement differs from the individual movement. The self-closing required by nuclear fusion is used by the charge along the magnetic force line. will be.

To confine the plasma there by deforming the magnetic field lines appropriately and confining them to a place in space. Previously, plasma research has been conducted in geophysics and astrophysics related to plasma around the earth and celestial bodies, but recently, the development of electromagnetic fluid dynamics (MHD) using the electrical properties of plasma, ion engines and nuclear fusion research of space rockets for space travel. Research is underway for this purpose.

As such, the high temperature and active chemical properties of plasma can be used to provide extreme environments that are difficult to obtain by conventional methods, and to give physical and chemical properties different from those of the main body by changing the synthesis of new materials and the properties of metal or polymer surfaces.

Diamond, for example, is an important material not only for jewelry but also for industry because of its excellent properties such as high hardness, thermal conductivity, refractive index and large band gap. Artificial synthesis of diamond has been mainly used by the high temperature and high pressure method developed by GE of the United States in the 1950s, but it was found that diamond can be obtained in the form of thin film at low pressure from methane gas plasma in the Soviet Union in the early 80s. , Tool coatings, optical component coatings, and acoustic equipment are actively pioneering new applications.

In addition, Tin, which is used as a diffusion barrier at the contact point in the wear-resistant coating of a tool, a decorative coating, and a semiconductor device, can be made dry by Tim's reactive ion plating, sputtering, or Pecvd method.

In addition, if the surface of the polymer is treated with nitrogen or oxygen plasma, it can give hydrophilicity or hydrophobicity to the surface of the polymer, or it can improve the antistatic, dichroic, deep color, etc., and the metal material is contacted with nitrogen or methane gas plasma. When the bias is applied to the surface, a layer of nitride or necklace 10 is formed on the surface to improve the hardness, wear resistance, and corrosion resistance of the metal.

Some of the effects that can be obtained by surface coating 240 and modification techniques using plasma can be obtained by conventional wet methods, but considering the environmental problems, dry methods using plasma have many advantages. Welding, cutting and processing of materials using high temperature of plasma and plasma can be sprayed. High melting point powder is melted by plasma and coated on solid surface to greatly increase heat resistance, corrosion resistance and abrasion resistance. It can be increased.

 In addition, it is possible to manufacture ultra-fine particles, using the high temperature, high activity of the thermal plasma to quench the particles synthesized by the gas phase reaction to synthesize the ultra-fine particles to plasma chemistry or physical vapor deposition: to create a functional film using the plasma, high temperature, high activity of the thermal plasma The advantage is that the waste can be broken down and vitrified using.

If so, look at the plasma coating 240 process of the necklace 10 of the present invention having a number of advantages as follows.

Plasma coating 240 injects argon and other gases into the vacuum chamber 300 and then causes an electrical discharge, the gases injected into the chamber 300 are ionized, and the silver target (silver plate) and the ionized gas is ionized The collision of silver atoms protrudes in a gaseous state and is coated 240 on the coating body (necklace), and the thickness of the coating 240 may be drastically controlled in nano units according to the coating time 240.

On the other hand, the plasma coating process 240 will be described briefly as follows.

 In order to wash the foreign substance on the surface of the finished necklace 380, the necklace 10 is put into the washing tub and the cleaning solution is injected, and in the manufacturing process of the inside of the necklace 10, which is the metal ash necklace 10, using an ultrasonic vibrator. After the washing process (320) for washing the attached impurities, the rinsing process and drying (280) in the drying machine (280) to evaporate the water and then the necklace (10) to the chamber 300 in the state attached to the holder After the sterilization process on the inside or outside of the necklace (10) with an oxygen plasma under vacuum, the first silver nano-surface coating (340) was performed and the coating of the necklace (10) coated (240) with silver nano (20). Plasma secondary surface coating (360) and reinforcement treatment are performed to improve the surface adhesion and increase the strength of the necklace (10).

Next, in the plasma coating 240 of the silver nano 20 finally by the vacuum macnetron sputtering plasma coating method, the plasma is coated with a desired thickness of 0.0 l (micrometer) µm to 50 µm (micrometer) in the plasma coating thickness. 0.01 to 30% by weight of the silver nano 20 to the entire material of the necklace 10 made of metal (10) by coating (240) or a natural vegetable fragrance such as fruit or aroma, herb, flower (30) To the liquid or powder of the raw material is added 0.01 to 10% by weight, and other metals are alloyed by adding 10 to 99% by weight of stainless steel, 10 to 99% by weight of iridium, 10 to 99% by weight of titanium. Preferably, 0.01 to 30% by weight of silver nano 20 is added to the entire material of the necklace 10 made of metal and gold or gold nano 0.0 to the entire material of the necklace 10 made of metal. 1 to 10% by weight of zinc or zinc nano 0.01 to 10% by weight, platinum or platinum nano (20) 0.01 to 10% by weight of the body of the necklace 10 may be a nano alloy.

 The necklace 10 body is deposited 260 in the barrel 50 or injected into the injector and sprayed onto the surface of the necklace 10 body to perform a coating 240 operation and drying 280 after completion 380 In this case, the coating 240 has a thickness of 0.0 l (micrometer) μm to 50 μm (micrometer) and the particle diameter of the silver nano 20 particles to a particle size of 0.01 to 300 nm.

The following is a photograph taken by electron microscope of the cross section, side and surface of the silver nano 20 of the present invention is shown in the drawings for the understanding of the present invention.

Figure 6 is a photograph taken at 60.000 times magnification cross section of the silver nano 20 of the present invention.

Figure 7 is a photograph taken by magnification of 80.000 times the side of the silver nano 20 of the present invention.

Figure 8 is a photograph taken by magnified 50.000 times the surface of the silver nano 20 of the present invention.

Figure 9 is a photograph of the antimicrobial activity of the strain into which the silver nano (20) of the present invention.

Figure 10 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano (20) of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

11 is a three-dimensional structure diagram of the silver nano 20 of the present invention.

As a result, the block diagram of the silver nano (20) and the coating containing the fragrance (240) and the photos and the antimicrobial data of the silver nano (20) were examined. ) The manufacturing method and process of the body will be followed.

[Example]

Applicant was able to know the schematic process of necklace 10 in order to experiment with this, and purchased silver nanotechnology product name Cocosilver silver nano ion generator maker which stably produces silver ions with high purity and distilled water Prepare silver nano ionized water by electrolysis method using D / C current, and add 100% by weight of distilled water to 30% by weight of silver nano ionized water, and add 10% of natural aromatic fragrance purchased from Samhwa perfumery. (160) and the sterilized tank was mixed with 20L of the silver nano (20) solution number and the aromatic fragrance material prepared in the sterilized tank and made of jade necklace (10) And the necklace (10) body of the plastic material of the female college students in their 20s with a high standard range of bacteria was immersed in the nano silver solution prepared for 60 minutes (260) to immerse silver ions. After drying (280) and drying (280) for 60 minutes in the drying (280) phase, the average value obtained by measuring Staphylococcus aureus, pneumococci, bacteria, and MRSA (Methicillin-resistant Staphylococcus aureus) bacteria before and after silver solution treatment It is briefly shown in the analysis table below, the soft aroma of the natural aroma and smoothness of the surface was confirmed that the applicant can be fully applied to the industry with good results expected by the applicants to complete the present invention (380).

The present invention is made of silver, nano (20) in various necklaces (10) made of at least one material of any one of metals, plastics, synthetic resins, minerals, jewelry, silicone, rubber poly-based or mixed (160) ) Is added or coated 240 to have a sterilization and antimicrobial function and a necklace 10 which is silver ions and far infrared radiation.

As described above, silver nano (20) powder or nano (20) having a number of advantages according to the present invention (Ag) solution of the material of the necklace (10) body metal, synthetic resin, plastics, minerals , Raw material of a natural vegetable fragrance such as 0.01 to 30% by weight of silver nano 20 and a fruit or aroma, herbal or floral fragrance To a liquid or powder of 0.01 to 10% by weight, the particle size of the silver nano 20 has a particle diameter of 0.01 to 300nm and the coating 240 of the silver nano 20 thickness of 0.0l (micrometer) It is characterized in that the coating 240 to a thickness of about 50 to 50 ㎛ (micrometer), the production and reproduction of bacteria and pathogens and microorganisms can be used to clean and hygienically the body of the necklace (10).

In the above description of the embodiments or preferred embodiments of the present invention

Those skilled in the art to which the present invention pertains will understand that the present invention can be variously modified or modified without departing from the spirit and scope of the present invention as described in the claims and the scope of the patent.

The table below shows one example of a diagram in which Staphylococcus aureus, pneumococci, bacteria, and MRSA (Methicillin-resistant Staphylococcus aureus) bacteria were killed at 30% by 30% of silver nanoparticles. Nano 20 was found to have excellent sterilizing power.

test subject unit Number of strains  30% of nano addition (after 60 minutes) Staphylococcus aureus CFU / mL 3.4 X 10 ³ 0 Pneumonia group CFU / mL 3.1 X 10 ³ 0 MRSA (Methicillin Resistant Staphylococcus Aureus) CFU / mL 1.3 X 10 ² 0 bacteria CFU / mL 3.4 X 10 ² 0

  (This test report is the analysis data of Korea Testing Institute)

1 is a perspective view of a necklace according to the present invention.

Figure 2 is a mixing process of the metal necklace according to the present invention.

Figure 3 is a mixing process of the plastic, synthetic resin, poly, silicone, necklace according to the present invention.

Figure 4 is a coating process of the plastic, synthetic resin, poly, silicone, necklace according to the present invention.

5 is a coating process of the metal necklace according to the present invention.

Figure 6 is a photograph taken at 60.000 times magnification cross section of the silver nano of the present invention.

7 is a photograph taken by magnification of 80.000 times with an electron microscope of the side of the silver nano of the present invention.

Figure 8 is a photograph taken by magnification 50.000 times the surface of the silver nano of the present invention.

Figure 9 is a photograph of the antimicrobial activity of the strain into which the silver nano of the present invention.

10 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

11 is a three-dimensional structural diagram of the silver nano of the present invention.

* Description of the symbols for the main parts of the drawings *

10: necklace body 20: silver nano

30: Fragrance 40: Fastening part

50: cylinder 60: melting

80: melting 100: heating

120: softening 140; stirring

160: Mix 180: Module input

200: molding 220: injection

230: Extrusion 240: Coating

260: Deposition 280: Drying

300: chamber 320: washing process

340: 1 Secondary Surface Coating 360: Secondary Surface Coating

380: finished

Claims (12)

 In the necklace (10) made of at least one material of any one of metals, plastics, synthetic resins, minerals, gems, silicones, rubber poly-based or mixed (160). 0.01 to 30% by weight of the silver nano 20 material and 0.01 to 10% by weight of the natural vegetable fragrance base are mixed (160) on the necklace 10 body based on 100% by weight of the necklace 10. Characteristic necklace. The necklace (10) is characterized in that the necklace further comprises a coating (240) of the necklace (10) body of 0.01 to 30% by weight of the silver nano (20) material based on 100% by weight of the total. The method according to claim 1 or 2, The silver nano (20) injected into the necklace (10) is a necklace characterized in that it has a particle diameter of 0.01 to 300nm. The method according to claim 2, The coating 240 of the silver nano (20) material has a thickness of 0.0l μm to 50 μm (micrometers), characterized in that the silver nano coating film 240 is formed on the necklace 10 body. The method according to claim 1, Silver nano 20 is added in an amount of 0.01 to 10% by weight or 0.01 to 20% by weight to the entire material of the necklace 10 made of metal, and other metals are 10 to 99% by weight of stainless steel and 10 to 99% by weight of iridium titanium. The necklace is characterized in that the body of the necklace 10 is alloyed into 10 to 99% by weight. The method of claim 5, wherein 0.01 to 10% by weight or 0.01 to 20% by weight of silver nano 20 is added to the entire material of the necklace 10 made of metal, and other metals are 0.01 to 10% by weight of zinc or zinc nano or 0.01 to 100% zinc. To 10% by weight, platinum or platinum nano (20) 0.01 to 10% by weight of the body of the necklace 10 is mixed with the nano alloy 160 The necklace characterized by the structure.  The method according to claim 2, In order to coat (240) the necklace 10 made of a metallic material, a wet coating (240) by electrolysis of the body of the necklace (10) extruded (230) through a molding (200) process, an injection (220) process, or an extruder (240). Necklace, characterized in that the necklace body is selected by any one of the coating method of the dry coating (240) by the sputtering, plasma. The method according to claim 2   Crosslinking agent, pressure-sensitive adhesive and silver nano (10) in the process of completing the necklace (10) consisting of at least one material of any one of plastics, synthetic resins, minerals, jewelry, silicone, rubber poly-based or mixed (160) 20) The necklace, characterized in that the structure of the mixed structure (160) by spraying or depositing (260) on the body of the necklace 10 to the silver nano (20) coating film 240. The method of claim 8, The surface of the necklace 10 is coated with a ground color, followed by drying (280) to dry it (280) and a rough surface of the necklace (10) to reduce the surface resistance from the surface resistance coating (240) characterized in that the necklace body is shaped Necklace. The method according to claim 1, After removing this material in plastic or synthetic resin, it is added to the container 50 and melted 60 so as to be softened 120. Then, 0.1 to 5% by weight of paint, crosslinking agent and curing agent are added, and the color of the necklace 10 is changed. In order to produce the pigment is added to the 0.1 to 5% by weight, stirred 140, and injected into the mold module 200 is molded (180) by injection 220 or extrusion 230 through an extruder, characterized in that the molded shape necklace. The method of claim 2.  The wet coating method of the necklace 10 is a method of attaching a metal necklace 10 to the positive side and attaching a target silver lump to the pole side to attach the necklace 10 and the silver lump to a solution containing silver ions. +,-Put the electricity to the pole, the necklace characterized in that the shape of the necklace was wet-coated (240). The method of claim 2. Dry coating, stuffing or plasma coating 240 through the washing process 320 and the rinsing process after drying (280) and then attached to the necklace (10) holder and then introduced into the chamber 300 is the necklace (10) body Necklace characterized in that the coating 240 has a shape.