KR20060125132A - Bracelet - Google Patents

Abstract

A bracelet or ankle bracelet containing nano-silver liquid or powder is provided to represent sterilization and detoxification properties and to send forth fragrance, thereby preventing generation or proliferation of bacteria, germs or microorganisms, by comprising typical raw materials such as metal, synthetic resin, jewels, etc., nano-silver liquid or powder and additional plant fragrant materials. The bracelet or ankle bracelet is fabricated by a process comprising the steps of: preparing body(10) of the bracelet by using typical raw materials selected from metal, synthetic resin, plastic, mineral, jewels, silicone, rubber or polymer materials; adding 0.01-30wt.% of nano-silver material(20) to total 100wt.% of the bracelet to form a nano-silver coating(240) on the body; and further adding 0.01-10wt.% of plant fragrant materials including fruit, herb or flower like scent or aroma flavor to the body. The powder type of nano-silver material has particle diameter ranging from 0.01 to 300nm. The nano-silver coating has thickness ranging from 0.01 to 50 micrometers.

Description

 Bracelet {bracelet}

1 is a perspective view of a bracelet according to the present invention.

2 is a mixing process diagram of a metal bracelet according to the present invention.

Figure 3 is a mixing process of the plastic, synthetic resin, poly, silicone, bracelet according to the present invention.

Figure 4 is a coating process of the plastic, synthetic resin, poly, silicone, bracelet according to the present invention.

5 is a coating process chart of a metal bracelet according to the present invention.

Figure 6 is a photograph taken by magnification of 60.000 times with an electron microscope of the cross section of the silver nano of the present invention.

Figure 7 is a photograph of the side of the silver nano of the present invention magnified 80.000 times with an electron microscope.

Figure 8 is a photograph taken by magnification 50.000 times the surface of the silver nano of the present invention.

Figure 9 is a photograph of the antimicrobial activity of the strain into which the silver nano of the present invention.

10 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

11 is a three-dimensional structural diagram of silver nano of the present invention.

* Description of the symbols for the main parts of the drawings *

10: bracelet, anklet body 20: silver nano

30: Fragrance 40: Fastening part

50: cylinder 60: melting

80: melting 100: heating

120: softening 140; stirring

160: Mix 180: Module input

200: molding 220: injection

230: Extrusion 240: Coating

260: Deposition 280: Drying

300: chamber 320: washing process

340: 1 Secondary Surface Coating 360: Secondary Surface Coating

380: finished

As described above, the present invention relates to a bracelet 10 which is usually worn on the arm and ankle in order to fashion a person. In the manufacture of the bracelet 10, the silver nano 20 is mixed (160) or coated (240) to antibacterial and far-infrared rays. The present invention relates to a method of manufacturing a functional bracelet 10 in which a function of releasing silver and silver is continuously maintained. The origin and background of the bracelet 10 will be described in detail as follows.

Bracelets [bracelets] are accessories worn on the cuffs. They have been used since the primitive ages as ornaments of the body, such as necklaces and ankles. In ancient Egypt, you can see bracelets made of seashells already lined up around 3500 BC. In other words, it is similar to that of existing savages. After a while, they changed their materials to ivory, bronze, etc. as the times developed. In the 300 BC, metals including gold appeared.

As such, many designs, such as chains, spirals, and ring patterns, have appeared in ancient societies, especially in the use of jewelry from the upper classes. However, when it became important to enter the Middle Ages to cover themselves with clothing, it disappeared temporarily and began to reappear in the 15th century. Since then, with the change of times, the trend has been repeated, but bracelets were popular in the age when the exposed parts of clothing were large and the style of dress was simple. In this respect, it can be said that modern times belong to that time.

Types of bracelets are shaped like chains (chains), rings (rings), wenges (hinges), bangles (rings), loves (hearts connected to chains), and slaves (arms and ankles). There is a ring shape that fits tightly. In Korea, they were worn from the ruins of Dongsan-dong, Busan and piles of Tongyeong clams. They were worn from the Neolithic age, widely worn in the Three Kingdoms, and rarely worn in the Joseon Dynasty.

A bracelet 10 is a string or ring ornament for decorating a wrist or ankle, and the bracelet 10 is not only intended for aesthetic effect, but also by religious witchcraft, to protect arms and ankles. There are many different types, such as to indicate gender or status.

The generation of the bracelet 10 is old with human history.

From the fetishism that humans first attach supernatural forces to objects, and on the other hand, the meaning of the height, they devoted themselves to the arms and ankles, which are important parts of the human body. You can guess that it would have been cultivated.

This can be seen by looking at the stone age artifacts, or by looking at the customs of existing savages, such as the tree fruit, shells, animal bones, horns, teeth or stones, and pieces of baked goods found in the artifacts. to be.

The bracelet 10 is thus one of the most common ornaments for mankind regardless of the East or the West, and it is speculated that the bracelet 10 was used in advance of the garment based on the connected beads. As technology has advanced, these have been replaced by glass, pottery, amber and other jewellery. Furthermore, with the advent of the metal age, coexistence and mixing with metals have been achieved.

 The present invention relates to a functional bracelet (10) containing silver nano (20) which anti-sterilizes with far infrared rays and silver ions by mixing (160) silver nano (20) in the manufacture of the bracelet (10)

As described above, the bracelet 10 of the present invention is not simply physical or electrical sterilization of the machine, but is simply input at the time of manufacture of the bracelet 10 body. Containing the material, you can continue to get the following outstanding benefits anytime, anywhere, without wasting electrical power or waste of time:

Silver nano (20) is harmless to the human body and has a sterilizing power tens of times stronger than the chlorine series. If so, the following is a list of preferred features of the bracelet 10 of the present invention.

  As described above, the present invention relates to a bracelet 10 which a person wears on the arm and ankle in order to dress up normally, and mixes the silver nano 20 to the body of the bracelet 10 (160).

The present invention relates to a method of manufacturing a bracelet 10 in which an action of anti-sterilizing the bracelet 10 by coating 240 is continuously maintained.

The present invention relates to a functional bracelet 10 containing the silver nano 20 mixed 160 or coating 240 of the silver nano 20 in the manufacture of the bracelet 10,

As described above, the bracelet 10 of the present invention is not simply physical or electrical sterilization of the machine, but is simply input at the time of manufacture of the bracelet 10 body. Containing the material, you can continue to get the following outstanding benefits anytime, anywhere, without wasting electrical power or waste of time:

Silver nano (20) is harmless to the human body and has a sterilizing power tens of times stronger than the chlorine series. If so, the following is a list of preferred features of the bracelet 10 of the present invention.

  First: The bracelet (10) containing silver nano (20) generates healthy silver ions and far-infrared rays, which increases blood circulation and endocrine activity when used, and more than 90% of forum aldate, an environmental hormone that has become a problem recently. It has many advantages of blocking and protecting the skin by anti-viral and anti-allergic vitamin B6, the soft touch, deodorizing effect and the disinfecting effect in repeated washing.

Secondly, it reacts sensitively according to the pollution level of the environment and shows continuous antiseptic action by destroying bacterial cell membranes or disturbing cell functions.

 Recent research has shown that silver nano (20) can sterilize 650 bacteria and viruses, and prevents secondary infections in hospitals where it is a problem due to its excellent anti-bacterial and antibacterial function of harmful bacteria and microorganisms. Silver catalyzes the conversion of oxygen into active oxygen, which prevents germs from propagating by germ and germ propagated by sweat, saliva or dust secreted by the human body.

Third: silver nano (20) is very easy to coating 240, mixture 160, and the like with the material, metal, plastic, synthetic resin, minerals, jewelry, silicon, rubber which is the material of the bracelet 10 of the present invention The material of the bracelet 10 made of a poly-based and the mixture 160 or the coating 240 is made well.

Fourth: Deodorant effect and fragrance divergence effect. Bracelet 10 of the present invention is a bacterial film formed on the surface of the bracelet 10 due to contaminants secreted from the hands and feet of the human body, even if the user from time to time to wash from time to time, especially in the hot summer odor by sweat of hands and feet Will occur,

Silver nano 20 and the bracelet 10 containing the flavor of the present invention is a raw material of the vegetable natural fragrance base 30, such as fruit aroma, aroma, herb, flower fragrance during the manufacturing process or any one of the final process preferred The liquid or powder is added in a weight ratio of 0.01 to 10% by weight, so that the subtle scent is always divergent. The bracelet 10 of the present invention has the advantage of pleasing the smell of the user and others and maintains the lasting sterilizing power. It has a synergistic effect.

 Fifth: It has a sunscreen effect. Nanonized silver has excellent UV protection, so it is used in textiles, cosmetics, sunglasses, etc.

Bracelet 10 prevents the phenomenon of fading or discoloration by preventing corrosion by ultraviolet rays of the sun.

 The present invention is to solve the above conventional problems as described above

 Silver or aged silver nano (20) is used to mix the material of the body of the bracelet (10) body consisting of metal, synthetic resin, plastic, minerals, jewelry, silicone, rubber poly-based material (160) Alternatively, the coating 240 may be used to sterilize the arm and ankle of the human body on which the bracelet 10 is applied. More specifically, silver powder or silver ion, which is a different technology from silver powder or silver ions, may be formed in a nano powder or nano form. After the silver (Ag) solution is made, the silver nano 20 on the material of the bracelet 10 body made of metal, plastic, synthetic resin, mineral, gem, silicone, and rubber poly-based material of the bracelet 10 body is 0.01 to 30 to 100% by weight of the liquid or powder of the natural vegetable fragrance base 30, such as fruit or aroma, herbal or floral fragrance 30, by mixing the weight ratio of 0.01 to 10% by weight (160) or coating (240) and The particle size of the silver nano (20) fine particles is 0.0 When the coating 240 has a particle diameter of 1 to 300nm and the coating 240 has a thickness of 0.0l μm to 50 μm (micrometer), the silver nano 20 coating film 240 is applied to the bracelet 10 body. It is characterized by the fact that the antibacterial power is made continuously is its purpose.

The present invention 100% by weight of the entire material of the body of the bracelet 10 made of at least one material of any one of metal, plastic, synthetic resin, minerals, jewelry, silicone, rubber poly-based or mixed (160) 0.01 to 30% by weight of silver nano 20 and the liquid or powder of the raw material of the natural vegetable fragrance base 30, such as fruit or aroma, herbal or floral, and 0.01 to 10% by weight of the bracelet ( 10) relates to a bracelet or anklet 10 characterized by being put into the material of the body mixed (160) or coated (240).

In order to help the understanding of the present invention will be described in detail the silver and silver nano (20) constituents of the present invention.

    Nanotechnology is a technology that identifies and controls substances at the molecular and atomic levels.It comes from the Greek word dwarf, lanose, and 1 nanometer 'corresponds to one-tenth of the thickness of the hair. It is made of silver solution (colloid), which is a chemical decomposition method or a fine particle state in nano units, and is widely used in industrial fields.

Silver, the main component of silver (20), has been recognized as a precious metal of high value from ancient times, and has been the object of extraction, and it is recognized as an important industrial material in modern industry as well as its value as a currency. The production of silver is proportional to the production of gold in many ways.

Silver was mined early in Europe's Mediterranean coast, where silver was produced from the Incas and Aztecs before the discovery of the Americas, and then silver from Peru and Bolivia entered Europe and flowed out from 1520 to 1800.

It has grown steadily, but has declined since the discovery of large amounts of silver in the western United States in the early 19th century.

Currently, the world's major silver producers are Russia (13.8%), Canada (13.5%), Mexico (13%), Peru (13%), United States (11%), Australia (8%), Poland (6%). The country's silver reserves are 17 million tons, and its mining capacity is about 1.2 million tons. As of 2002, silver produced in Korea is about 5,000 kg, which accounts for 1.2% of the total domestic demand. The amount is so small that the rest of the silver is imported from abroad.

Characteristics of silver: The color of silver is gray in the case of elegant gray-white metal or powder, specific gravity is 10-12, Mohs hardness is 2.5-3, melting point 280 is 960.5 ℃.

In particular, the melting point (280) of silver is very important for the temperature compensation of high thermometers, and it is the standard of scientific and industrial temperature. Silver is the best conductor of metal, and is used comprehensively for mechanical contacts and other electronics. .

Silver is optically 90% of visible light, which is one of the most excellent metals like platinum. Pure silver does not rust even when left in the air or heated (100), but it reacts with sulfur and hydrogen sulfide to emulsify it. Silver is made and turns black.

     In addition, the mechanical properties change according to the amount of impurities (O₂) contained in the silver, and the hardness of the high-purity silver obtained by thermal annealing is Brinell hardness HBS (10/500) 25-27, tensile strength 12-16kgf / mm2. The cast strength of the cast was up to about 29 kgf / mm 2, the combustion rate was 48 to 54%, and the recrystallization temperature was 150 ° C.

    In particular, in the case of pure silver, the processed hardened material is softened by recrystallization at normal room temperature and softened softly. The malleability and flexibility are abundant after gold, and the thin silver plate, which is thin silver plate, can be spread to a thickness of 0.2 μm.

     The effect of silver has been used as a tool to check the imbalance of the body that one cannot feel because the gloss or color changes depending on the condition of the body when worn on the body from ancient times. This fatigue or low rhythm), Dongbobogam said that it is effective in the prevention and treatment of mental disorders and women's diseases such as epilepsy and game. The five chapters are said to be comfortable, the mind and body are stabilized, and the main body records that the body is lengthened by chasing morale and lightening the body.

      Also, when the Black Plague prevailed in the Middle Ages, nobility of the black aristocrats and royals, who had many silverware and silver utensils, did not have black plague, which released silver to the extent that it was able to sterilize the Black Plague bacteria, making it relatively safe from infectious diseases. In the place where the royal family and the state guests were served, silver products were used habitually.

In order to help the understanding of the silver nano 20, the present invention will be described briefly with respect to the silver nano 20 (Nano silver) extraction method and features.

The atomic weight of silver is 107.87 amu and the fact that silver (Ag) is bactericidal has been known for a long time.

Silver nano (20) is the first material name developed by a biotechnology company, a government-affiliated organization of our country, and is named silver nano (20) as a compound of brand name Na no-technology and silver. Became;

  Silver nano (20) is a field of Na no-technology and is an advanced antimicrobial agent that utilizes silver's strong antibacterial and bactericidal function and excellent electrical conductivity mechanism. Silver nano (20) is unlikely to be resistant to bacteria, unlike conventional antibiotics. Silver nano (20) has been shown to kill almost all single cell germs on the ground in a short time. .

 Currently, a variety of products based on silver nano (20) consisting of powder and solution have been invented and commercialized and produced in real life. This technology, called silver nano (20), converts silver to nanometers (1 billion won). It is a small particle size of 1m / min), that is, 0.000000001mm. When one gram of silver is aged, ten particles can be produced.

Therefore, silver nano (20), which is made of silver in the form of ultra fine particles, is a new concept that is made by utilizing the excellent efficacy of antibacterial ability, deodorization range, and extension of food preservation time among many characteristics of silver. .

 Since ancient times, silver has been recognized as a disinfecting material that not only prevents bacteria but also East and West. Currently, the extraction method of silver (20) (Age 99.9%) is added to distilled water. It generates low current at low temperature, electrolyzes compounds containing silver, and conducts electrophoresis using + and-poles of each molecule to collect silver (Age 99.9%). In addition, liquid reduction and grinding It can be manufactured by the physical method such as, and the electrolysis method is used a lot to obtain a stable silver nano (20) (Nano silver).

Silver ions are also used in general sterilization concept machines and disinfectants, and all silver products currently used are silver obtained by decomposition, and the sterilization power of silver varies depending on the product, but can obtain up to 99%.

 The silver nano 20 of the present invention is an ultra-fine particle of silver having a particle size of 0.01 to 300 nm, which acts directly on harmful bacteria, directly dissolves the cell membranes of harmful bacteria, and interferes with the electron transfer system of the harmful bacteria, thereby making it safe. It has an excellent antibacterial and fungicidal range (99.9%). (The virus size is about 10 nm.)

     The main antimicrobial mechanism of silver nano (20) is to dissolve harmful bacteria cell membranes and interact with enzymes in the cells to block the metabolic function of nutrients, ie, the influx and discharge of nutrients, and to stop the respiratory function and production of harmful bacteria. And destroys regenerating ability to kill harmful bacteria.

     In addition, the silver nano (20) by controlling the harmful bacteria by releasing the antimicrobial power continuously from the fine particles is excellent in the antimicrobial, antimicrobial sustainability.

Therefore, silver nano (20) does not produce resistance and silver nano (20) is effective to perform a surface reaction and kill all the germs 99%, particularly effective in the general E. coli or food poisoning.

   The smaller the nanoparticles, the better the bactericidal and antimicrobial activity. Based on the experimental data so far, Escherichia coli, Staphylococcus aureus, Salmonella, Vibrio bacillus, Heterogeneous bacteria, Pneumococcus, Typhoid bacillus and the most resistant MRSA (methicillin Resistant Staphylococcus aureus) can be 99.9% antibacterial and sterilized.

     Even if silver exists in an ionic state or a metal state, it can be referred to as colloidal silver if it exists in a colloidal state by a solvent.

In silver nano (20) (Nano silver), the silver nano (20) with the minimized particles is the best antibacterial activity.

   In addition, unlike the general chemical antibacterial or chlorine disinfectant, silver nano (20) is a pure silver ultra fine particle, has excellent antibacterial and bactericidal zone (99.9%) even at high temperature, non-toxic and non-irritating to the human body, bacteria and E. coli virus fungus It has been reported that bacteria cannot live in contact with silver nano 20 for more than 5 minutes.

The present invention is silver nano to the material of the body of the bracelet 10 made of at least one material of any one of the above-mentioned metal, plastic, synthetic resin, minerals, gems, silicone, rubber poly-based or mixed (160) as described above (20) Coating (240) or mixing (160) a solution or powder to antiseptic bacteria and harmful substances attached to the bracelet (10) body, to soften water and to release good silver ions and far infrared rays For functional bracelet 10 containing silver nano 20 for;

Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings. First, in describing each of the drawings, the same reference numerals refer to the same reference numerals and components even though they are shown in different drawings.

1 is a perspective view showing the overall configuration of the bracelet 10 according to the present invention, at least one material of any of the above metals, plastics, synthetic resins, minerals, gems, silicones, rubber poly series or mixed 160 of them It is shown as a picture of the bracelet 10 made of one or more materials,

2 is a process diagram 160 of mixing the metal bracelet 10 according to the present invention, the material of the bracelet 10 body made of the mineral and precious metals (gold, platinum, iridium, platinum) is put into the barrel 50 and Heat (100) to melt (60) or melt (80) to soften (120) and then agitate (140), wherein the silver nano (20) is 0.01 to 30 weight based on 100% by weight of the total weight of the bracelet (10) % And a liquid or powder of a natural vegetable fragrance base 30, such as fruit or aroma, herb, or flower, in a weight ratio of 0.01 to 10% by weight, and the particle size of the silver nano 20 is 0.01 to 300 nm. It is characterized by having a particle diameter, and then stirred and put into a mold or molding (200) module (180) by molding (200), in this case (380) to enhance the sterilizing power of the bracelet (10) body silver nano ( It is also possible to coat 240 once again.

3 is a process diagram 160 for mixing 160 of synthetic resins, plastics, minerals, silicones, and rubber poly-based bracelets 10 according to the present invention. Softening (120) and the silver nano (20) 0.01 to 30% by weight based on 100% by weight of the total weight of the bracelet 10, and natural vegetable fragrance base such as fruit or aroma, herbal, floral fragrance (30 ) 0.01 to 10% by weight of the liquid or powder of the raw material is added and 0.1 to 5% by weight of the pigment (not shown) to give the color of the bracelet 10, 0.1 to 5% by weight of paint, crosslinking agent, curing agent or flocculant 5 weight% and other additives are added to the material, and the total weight of the silver nano 20 material is 0.01 to 30 weight%, and the natural vegetable fragrance base 30 raw material such as fruit or aroma, herbal, and floral aromas. Add 0.01 to 10% by weight of liquid or powder The particle size of the silver nano 20 has a particle size of 0.01 to 300nm, and after stirring, it is injected into a molding module 180 or a mold module, which is pre-molded (200), by injection (180) or molding ( 200) or extruded through an extruder 230 and then slowly cooled to dry 280 and then completed 380. At this time, the particle size of the injected silver nano 20 is characterized in that it has a particle diameter of 0.01 to 300nm ( 380).

In addition, it is also possible to coat (240) the silver nano (20) once again in order to enhance the antiseptic power and corrosion resistance and surface strengthening of the finished bracelet (10) body.

Referring to the type and method of the injection molding 200, which is a method of mixing the bracelet 10 made of the plastic or synthetic resin, plastic, mineral, silicon, rubber poly-based material of FIG.

1, injection molding

 Suitable for mass production of complex shaped products by molding method of molding (200) material of the bracelet (10) by heating (100) melting (60), injection filling into a cavity of a pre-closed mold, and then solidifying or curing to form a molded product. In addition to the extrusion process, forming a large field of molding process.

 The molding materials used in the injection molding 200 are thermoplastic resins, which are mainly applied to almost all molding materials such as main resins, thermosetting resins, rubbers, foam molding materials, etc. Is being developed.

Molding is a standard type of line screw type injection molding machine which is ① mold, ② injection, ③ holding pressure (this series of processes to prevent backflow of material filled in cavity and extract by cooling is repeated as one cycle). When retracting and injecting by plasticizing the material, the screw advances to extrude the molding material, and this type of molding machine is also used for molding the thermosetting resin.

Compared to the thermoplastic resin, when the mold is heated (100) to cure the resin, the temperature of the heating cylinder is lowered so that the resin does not solidify. Therefore, the heating method of the cylinder and the shape of the screw are somewhat different. have.

Next, as a method of determining the injection molding conditions;

1, extrusion

 After the silver nano 20 was put into a thermoplastic material on the surface of various thin substrates such as paper, cloth, cellophane, plastic, vinyl, film, metal film, etc. It is a processing method in which it is extruded into a thin film form at the same time and simultaneously crimped continuously. The combination of the properties of the substrate and the characteristics of the extruded and compressed thermoplastics (water resistance, moisture resistance, chemical resistance, flexibility toughness, breathability, heat seal synthesis, and others) creates a packaging volume layer material adapted to a variety of applications, but is currently in practical use. Mainstream products are low density polyethylene, polypropylene, vinylene chloride resin and the like.

2, compression-molding

 In the most common molding method of the thermosetting resin, the molding material in which the silver nano 20 is added is put into a depression (called a cavity) of a heated mold and press-molded by a compression molding machine (press).

 The molding machine is heated in the cavity and once flowed, spreads to every corner of the cavity and causes a simultaneous chemical reaction to cure.Then open the mold after a suitable time (called curing time) and remove the molded product after finishing flash removal. Processing to obtain the product. If the molding process is largely divided into molding process and finishing process.

The molding process is carried out by ① molding material processing weighing (in some cases, it may be processed by a turret using a turret machine) ② loading of material into the cavity (preheated before)

 ③ Pressurization operation (low pressure pressurization, high pressure pressurization) ④ Curing process ⑤ Remove molded product It is to clean the mold.

Finishing process includes ① flash 뗌 ② gloss, etc., and for molding large and thick products, high frequency preheating is usually performed for efficiency and quality improvement. It should be decided properly. In the case of thermoplastic products, compression molding is performed in the case of molding thick products or producing a silicon film. In this case, the trick is to remove the molded article by cooling the mold after heating and pressing the molding material. In general, the compression molding is characterized by less molding of the dielectric material or molecules compared to injection molding or transfer molding, so that it is easy to obtain a molded article having a low internal stress.

 3, extrusion-blow molding

 The plastic material or poly, synthetic resin, rubber, and silicon into which the silver nano 20 is injected are heated and melted (60) and inserted into one or two or more molds of flies, which are continuously extruded into a tube from an extruder, and closed. After sealing, it is expanded by blowing air into the fly hand from the mandrel, and the fly hand adheres to the mold inner wall to make a product and is the most popular blow molding method.

 4, blow molding

 Softening 120 as a heating in the split mold to inflate a fly hand or sheet into which thermoplastic or synthetic resin, rubber, poly, mineral, silicon material and silver nano 20 are injected using air pressure, Cooling is a method of obtaining an aerial body. Called blow molding or blow molding. Ordinarily extruded or melted thermoplastic plastic molding material or insert a flyson or two sheets of preformed into a tube according to the injection method into a molding die by heat into the molding die, and then heat softened (120) and blows in the air therein. To form a hollow product. There are various types of blow molding according to the Parisian state shaping method, and typical examples thereof include injection blow molding, extrusion blow molding, sheet blow method (sheet fly hand method), and direct blow molding.

5, vacuum forming

 After heating and softening 120 of the thermoplastic plastic material into which the silver nano 20 was injected, it was placed on the mold module 180. The gap between the tongue and the sheet was immediately vacuumed to closely adhere to the surface of the mold and cooled to fix the phenomenon of the molded product. On the contrary, if a female is used to take out the molded article by inhaling air on the contrary, it is called a straight forming, and a male is called a drape forming.

6. vacuum deposition;

A brief overview of vacuum deposition refers to the heating of a small piece of metal or nonmetal to which silver nano 20 is injected in a vacuum to attach the vapor to an object surface.

That is, a current flows through a high-vacuum state in which a current is applied to an object to be coated in a high vacuum state (an object to be deposited) and a tungsten coil inserted with a piece of metal (Al) or chromium (Cr) to be attached to the surface thereof. I'm using the way.

In the vacuum deposition process, the paint used in BASE and TOP consists of urethane acrylates and monomas, which can represent various types of products depending on whether the paint is glossy or matte.

In addition, dyes can be added during TOP PAINT spraying to represent any color desired.

Figure 4 is a process of coating 240 of plastic, synthetic resin, minerals, jewelry, silicone, rubber poly-based bracelet 10 according to the present invention through the molding 200 process and injection 220 process and the extruder of FIG. After extrusion 230, the body of the finished bracelet 380 is removed, and the foreign material is removed from the surface, and then put into the container 50, and the flocculant or coating agent is based on 100% by weight of the bracelet 10 total weight. 0.1 to 5% by weight and the total weight in the bracelet (10) body of the nano-nano (20) material 0.01 to 30% by weight and natural vegetable fragrances such as fruit or aroma, herbal or floral fragrance (30 ) A liquid or powder of a raw material is added in a weight ratio of 0.01 to 10% by weight, and the particle size of the silver nano 20 has a particle size of 0.01 to 300 nm so as to be sprayed or deposited on the surface of the bracelet 10 to obtain silver 260. After completely coating the nano (240) (240), and then slowly cooled to dry (280) process and after inspection Block diagram showing the steps of loading and completing (380) is shown in the figure.

5 is a process diagram illustrating the coating 240 of the metallic bracelet 10 according to the present invention.

 In order to coat 240 on the inside or outside of the bracelet 10 or the finished bracelet 380, the wet coating method 240 or the dry coating method 240 using plasma or the electrical coating 240 of the silver nano 20. Can be used.

First, the wet coating 240 of the present invention will be described.

 The coating 240 can be divided into electro-coating and electroless coating. The silver coating 240 requires a solution containing silver ions and the gold coating 240 requires a solution containing gold ions. To the bracelet 10, silver nano (20) coating (240) to put the bracelet 10 on the positive side,-to the silver side on the pole side of the bracelet (10) and the silver lump solution containing silver ions Put it in the + and-poles to flow electricity and slowly become a coating (240).

The electroless coating 240 has a substitution coating and a reduction coating, and the substitution coating, for example, when iron powder is added to the iron powder, iron tends to be more ionized, so electrons are given to the copper ions, and magnetic is dissolved, and copper is reduced to iron powder. Stick on and this is a substitution coating.

 First, the coating 240 is to prevent corrosion (or oxidation), and silver is less reactive than iron, so the oxidation rate is slow, and if scratches occur on the coated portion 240, water vapor or oxygen enters between them. .

First, the negative electrode of the battery is attached to the object (bracelet) to be coated 240, and the positive electrode and the negative electrode of the silver (AG) on the metal to be coated 240 are separated. Of course, the aqueous solution contains silver ions, and of course, the silver coating 240 may be used as the aqueous solution containing silver ions.

-When the electrons come to the pole, the silver ions in the aqueous solution are attached to the bracelet 10 around the wet coating 240. Thus, the amount of silver ions in the aqueous solution after the reaction does not change, but the mass of the silver metal is not changed. Will be reduced.

Next, the plasma of the bracelet 10 containing the silver nano 20 of the present invention

Or with respect to the sputtering coating method 240 is as follows.

Plasma and stuffing are gaseous states that are separated into electrons with positive charges and positively charged ions at high temperature, and have a high degree of charge separation but a neutral gas with the same number of positive and positive charges. Since the coulomb force acts between charges, it is characterized by the collective action of the whole moving under the influence of the distant state rather than the local state of the short distance. In 1928, I. Lang Muir of the United States first applied the concept of plasma to ionized gases produced during electrical discharges.

It is derived from the Greek words πλσμα, -ατos, τ and its original meaning is that it is built and assembled, and as the nature of the collective behavior suggests, it is easily controlled externally to deal with plasma. Rather, it is common that plasma itself behaves freely, and the original name is wrong. Plasma is the fourth material state after solid, liquid, and gas (three states of matter).

Gradually increasing the temperature, almost all objects change from solid to liquid and gaseous. At tens of thousands of degrees Celsius, the gas is separated into electrons and atomic nuclei, resulting in a plasma state. Plasma is not common in everyday life, but it is common throughout the universe. That's because 99% of the universe is estimated to be plasma.

For example, conduction gases that carry current in fluorescent lamps, ionized gases mixed in rockets or lightning strikes, aurora borealis in the atmosphere, ionospheres in the atmosphere, and out of the atmosphere are trapped by ions in the Earth's magnetic field. Plasma is present in the solar wind that pours intermittently from the sun, and the gas inside the star, the surrounding gas surrounding it, and the hydrogen gas filling the space between the stars are plasma states.

Each individual object of the plasma is electric, which is very different from the neutral gas, has a high electrical conductivity, and is confined to the surface like a metal conductor.The current flows only on the surface. As the charge density increases, it is easily influenced by the force, but as the charge density increases, the group movement differs from the individual movement. The self-closing required by nuclear fusion is used by the charge along the magnetic force line. will be.

To confine the plasma there by deforming the magnetic field lines appropriately and confining them to a place in space. In the past, plasma research has been conducted in geophysics and astrophysics related to plasma around the earth and celestial bodies, but recently, the development of electromagnetic fluid dynamics (MHD) using the electrical properties of plasma, ion engine and nuclear fusion research of space rocket Research is underway for this purpose.

As such, the high temperature and active chemical properties of plasma can be used to provide extreme environments that are difficult to obtain by conventional methods, and to give physical and chemical properties different from those of the main body by changing the synthesis of new materials and the properties of metal or polymer surfaces.

Diamond, for example, is an important material not only for jewelry but also for industry because of its excellent properties such as high hardness, thermal conductivity, refractive index and large band gap. Artificial synthesis of diamond has been mainly used by the high temperature and high pressure method developed by GE of the United States in the 1950s, but it was found that diamond can be obtained in the form of thin film at low pressure from methane gas plasma in the Soviet Union in the early 80s. , Tool coatings, optical component coatings, and acoustic equipment are actively pioneering new applications.

In addition, Tin, which is used as a diffusion barrier at the contact point in the wear-resistant coating of a tool, a decorative coating, and a semiconductor device, can be made dry by Tim's reactive ion plating, sputtering, or Pecvd method.

In addition, if the surface of the polymer is treated with nitrogen or oxygen plasma, it can give hydrophilicity or hydrophobicity to the surface of the polymer, or it can improve the antistatic, dichroic, and deep color. When a bias is applied to the surface, a layer of nitrided or bracelet 10 is formed on the surface to improve the hardness, wear resistance, and corrosion resistance of the metal.

Some of the effects that can be obtained by surface coating 240 and modification techniques using plasma can be obtained by conventional wet methods, but considering the environmental problems, dry methods using plasma have many advantages. Welding, cutting and processing of materials using high temperature of plasma and plasma can be sprayed. High melting point powder is melted by plasma and coated on solid surface to greatly increase heat resistance, corrosion resistance and abrasion resistance. It can be increased.

 In addition, it is possible to manufacture ultra-fine particles, using the high temperature, high activity of the thermal plasma to quench the particles synthesized by the gas phase reaction to synthesize the ultra-fine particles to plasma chemistry or physical vapor deposition: to create a functional film using the plasma, high temperature, high activity of the thermal plasma The advantage is that the waste can be broken down and vitrified using.

If so, look at the plasma coating 240 process of the bracelet 10 of the present invention having many of the advantages as follows.

Plasma coating 240 injects argon and other gases into the vacuum chamber 300 and then causes an electrical discharge, the gases injected into the chamber 300 are ionized, and the silver target (silver plate) and the ionized gas is ionized The collision of silver atoms protrudes in a gaseous state and is coated 240 on a coating body (bracelet), thereby dramatically controlling the thickness in nano units according to the coating 240 time.

On the other hand, the plasma coating process 240 will be described briefly as follows.

 In order to wash the foreign substance on the surface of the finished bracelet 380, the bracelet 10 is put into the washing tub and the cleaning solution is injected to use the ultrasonic vibrator in the manufacturing process of the inner or outer metal bracelet 10 After the washing process (320) for washing the attached impurities, the rinsing process and drying (280) in the drying machine (280) to evaporate the moisture and then to the chamber (300) in the state attached to the bracelet 10 to the holder After the sterilization process inside or outside the bracelet 10 with an oxygen plasma under vacuum, the first silver nano surface coating 340 is performed and the coating of the bracelet 10 coated with silver nano 20 240. Plasma secondary surface treatment coating 360 and reinforcement treatment are performed to improve surface adhesion and increase the strength of the bracelet 10.

Next, in the plasma coating 240 of the silver nano 20 finally by the vacuum macnetron sputtering plasma coating method, the plasma is coated with a desired thickness of 0.0 l (micrometer) µm to 50 µm (micrometer) in the plasma coating thickness. 0.01 to 30% by weight of the silver nano 20 to the entire material of the bracelet 10 made of metal or finished with a coating (240) or a natural vegetable fragrance such as fruit or aroma, herbal or floral The liquid or powder of the base 30 is added in an amount of 0.01 to 10% by weight, and the other metals are alloyed by adding 10 to 99% by weight of stainless steel, 10 to 99% by weight of iridium, and 10 to 99% by weight of titanium. Preferably, the liquid of the raw material of the natural vegetable fragrance base 30 such as 0.01-30 wt% of the silver nano 20 to the entire material of the bracelet 10 made of metal and a fruit or aroma, herbal or floral fragrance Me 0.01 to 10% by weight of the powder is added to the total material of the bracelet 10 made of metal and 0.01 to 10% by weight of zinc or zinc nano or 0.01 to 10% by weight of zinc or zinc nano, platinum or platinum nano (20) 0.01 It is also possible that the body of the bracelet 10 is a nano alloy is added to 10% by weight.

 The bracelet 10 body is deposited 260 in the barrel 50 or injected into the injector and sprayed onto the surface of the bracelet 10 body to perform a coating 240 operation and drying 280 and then finished 380. In this case, the coating 240 has a thickness of 0.0 l (micrometer) μm to 50 μm (micrometer) and the particle diameter of the silver nano 20 particles to a particle size of 0.01 to 300 nm.

The following is a photograph taken with an electron microscope of the cross section, side, and surface of the silver nano 20 of the present invention, respectively, is shown in the drawings for the understanding of the present invention.

FIG. 6 is a photograph taken at 60.000 times magnification of a cross section of the silver nano 20 according to the present invention. FIG.

Figure 7 is a photograph taken on the side of the silver nano 20 of the present invention magnified 80.000 times.

Figure 8 is a photograph taken by magnified 50.000 times the surface of the silver nano 20 of the present invention.

Figure 9 is a photograph of the antimicrobial activity of the strain into which the silver nano (20) of the present invention.

10 is Staphylococcus aureus, pneumococci, bacteria in which the silver nano 20 of the present invention is added.

MRSA (Methicillin-Resistant Staphylococcus Aureus) Bacteria Antimicrobial Test Picture.

11 is a three-dimensional structure diagram of the silver nano 20 of the present invention.

As a result, the block diagram of the silver nano 20 and the fragrance-containing coating 240 of the present invention and the photos and antimicrobial data of the silver nano 20 were examined. The method of manufacturing the bracelet 10 of the present invention is a conventional bracelet (10). ) The manufacturing method and process of the body will be followed.

[Example]

Applicant was able to know the schematic process of the bracelet 10 in order to test this, and the company to produce silver ions stably with high purity) purchased the silver nano-technology brand coco silver silver nano ion generator, and distilled water as a solution Prepare silver nano ionized water by electrolysis method using D / C current, and add 100% by weight of distilled water to 30% by weight of silver nano ionized water, and add 10% of natural aromatic fragrance purchased from Samhwa perfumery. And mixed with 160% of the silver nano 20 solution prepared in the sterilized tank and 20L of the mixed material of the aromatic fragrance and a bracelet made of a metallic material coated with a cloisonne worn by a woman in their 30s for 1 year. The body of a metal foot foot bracelet worn by a female college student in her 20s who has a high standard of bacteria, and a plastic bracelet and anklet worn by a 28 year old female After depositing (260) the bracelet and anklets (260) for 60 minutes in the tank containing the prepared nano-silver solution, and sufficiently depositing (260) silver ions, drying (280) for 60 minutes in a drying (280) and then using silver The average values obtained by measuring Staphylococcus aureus, pneumococci, bacteria, and MRSA (Methicillin-resistant Staphylococcus aureus) bacteria before and after the liquid treatment are briefly shown in the analysis table below. It has been confirmed that the present invention can be completed (380).

The present invention is a silver nano 20 (Nano silver) in a variety of bracelets 10 made of at least one material of any one of metals, plastics, synthetic resins, minerals, jewelry, silicone, rubber poly-based or mixed 160 of them ) Is added or coated (240) to have a bracelet 10 that is sterilized and antibacterial and silver ions and far-infrared radiation.

As described above, silver nano (20) powder or nano (20) having a number of advantages according to the present invention is a (Ag) solution of the material of the bracelet 10 body metal, synthetic resin, plastics, minerals Silver nano (20) in the body of the bracelet (10) body made of jewelry, silicone, rubber poly-based material, and natural vegetable fragrance base material (30) such as fruit or aroma, herbal or flower To a liquid or powder of 0.01 to 10% by weight, the particle size of the silver nano 20 has a particle diameter of 0.01 to 300nm and the coating 240 of the silver nano 20 thickness of 0.0l (micrometer) It is characterized in that the coating 240 with a thickness of about 50 to 50 ㎛ (micrometer), the production and propagation of bacteria and pathogens and microorganisms can be used to clean and sanitary bracelet 10 body.

In the above, the embodiments or preferred embodiments of the present invention are easily described.

Those skilled in the art to which the present invention pertains will understand that the present invention can be variously modified or modified without departing from the spirit and scope of the present invention and the scope of the patent described in the claims below.

The table below shows one example of a diagram in which Staphylococcus aureus, pneumococci, bacteria, and MRSA (Methicillin-resistant Staphylococcus aureus) bacteria were killed at 30% by 30% of silver nanoparticles. Nano 20 was found to have excellent sterilizing power.

test subject unit Number of strains  30% nano addition (after 60 minutes) Staphylococcus aureus CFU / mL 3.4 X 10 ³ 0 Pneumonia group CFU / mL 3.1 X 10 ³ 0 MRSA (Methicillin Resistant Staphylococcus Aureus) CFU / mL 1.3 X 10 ² 0 bacteria CFU / mL 3.4 X 10 ² 0

  (This test report is the analysis data of Korea Testing Institute)

Claims (12)

 In bracelets (10) or anklets to be worn on the arms and ankles made of at least one material of any one of metals, plastics, synthetic resins, minerals, gems, silicones, rubber poly-based or mixed (160). 100 to 100% by weight of the bracelet 10, the nano nano 20 material is mixed with 0.01 to 30% by weight and the natural vegetable fragrance base 30 to 0.01 to 10% by weight mixed in the bracelet (10) body (160 ) Bracelet characterized by. The bracelet (10) is characterized in that the bracelet further comprises a coating (240) of the bracelet (10) body of 0.01 to 30% by weight of the silver nano (20) material based on 100% by weight. The method according to claim 1 or 2, Silver nano (20) put into the bracelet 10 is characterized in that the bracelet has a particle diameter of 0.01 to 300nm. The method according to claim 2, The coating 240 of the silver nano (20) material is a bracelet characterized in that the coating film 240 is formed on the bracelet 10 body to a thickness of 0.0l㎛ to 50㎛ (micrometer). The method according to claim 1, The silver nano 20 is added in an amount of 0.01 to 10% by weight or 0.01 to 20% by weight to the entire material of the bracelet or anklet 10 made of metal, and other metals are 10 to 99% by weight of stainless steel and 10 to 99% by weight of iridium. Bracelets, characterized in that the body of the bracelet 10 is alloyed by 10 to 99% by weight titanium. The method of claim 5, wherein 0.01 to 10% by weight or 0.01 to 20% by weight of silver nano 20 is added to the entire material of the bracelet 10 made of metal, and other metals are 0.01 to 10% by weight of zinc or zinc nano or 0.01 to 100% zinc. To 10% by weight, platinum or platinum nano (20) Bracelet is added to 0.01 to 10% by weight, characterized in that the body of the bracelet 10 is mixed with a nano alloy (160).  The method according to claim 2, In order to coat 240 the bracelet 10 made of a metallic material, a wet coating 240 by electrolysis of the body of the bracelet 10 extruded 230 through a molding 200 process, an injection 220 process, or an extruder 230 is performed. Bracelet, characterized in that any one of the coating method of the dry coating (240) by the sputtering, plasma. The method according to claim 2   Crosslinking agent, pressure-sensitive adhesive and silver nano (100) in the process of completing the bracelet 10 made of at least one material of any one of plastics, synthetic resins, minerals, jewelry, silicone, rubber poly-based or mixed (160) 20) Bracelets, characterized in that the material is mixed (160) by spraying or depositing (260) on the bracelet 10 body to the silver nano (20) coating film 240 is formed. The method of claim 8, The bracelet (10) is coated with a surface color and then dried (280) to dry (280) step and the bracelet characterized in that the surface resistance coating 240 to lower the surface resistance from the rough bracelet (10) surface. The method according to claim 1, After removing this material in plastic or synthetic resin, it is added to the container 50 and melted 60 so as to be softened 120. The paint, crosslinking agent and hardener are added in an amount of 0.1 to 5% by weight, and the color of the bracelet 10 is reduced. Bracelet is characterized in that the pigment is added to the 0.1 to 5% by weight in order to produce agitation (140) and put into the mold module 200 is molded (180) by injection (220) or extruded through an extruder (230). The method of claim 2.  The wet coating method of the bracelet 10 is a method of attaching a metal bracelet 10 to the pole side and attaching a target silver lump to the pole side to attach the bracelet 10 and the silver lump to a solution containing silver ions. Put a +,-a bracelet, characterized in that the wet coating (240) by flowing electricity to the pole. The method of claim 2. For dry coating, stuffing or plasma coating 240, the washing process 320 and the rinsing process are followed by drying (280) and then attached to the bracelet (10) holder and then put into the chamber 300 is inserted into the bracelet (10) body Bracelet characterized in that the coating (240).

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