KR20060121784A - Mortar composition and manufacturing method - Google Patents

Mortar composition and manufacturing method Download PDF

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KR20060121784A
KR20060121784A KR1020060108720A KR20060108720A KR20060121784A KR 20060121784 A KR20060121784 A KR 20060121784A KR 1020060108720 A KR1020060108720 A KR 1020060108720A KR 20060108720 A KR20060108720 A KR 20060108720A KR 20060121784 A KR20060121784 A KR 20060121784A
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silica
silica sand
titanium oxide
mortar
mixture
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KR1020060108720A
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Korean (ko)
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KR100867146B1 (en
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김종필
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김종필
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10—Coating or impregnating
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/04—Silica-rich materials; Silicates
    • C04B14/06—Quartz; Sand
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02—Granular materials, e.g. microballoons
    • C04B14/34—Metals, e.g. ferro-silicon

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Finishing Walls (AREA)

Abstract

Provided is a color mortar composition which minimizes cost of mortar and fundamentally prevents releasing of harmful ingredients such as poisonous substance of cement by using an adhesive of synthetic resin as mortar coagulant instead of cement, a method for preparing the same. The color mortar composition is prepared by the method comprising the steps of: washing silica having particle size of 24-34 mesh; disinfecting impurities of the washed silica and the simultaneously primarily heating the silica with heat of 70-80 deg.C for about 30 minutes so as to firmly bond it with titanium oxide; adding 15-20% titanium powder to 100% the heated silica, introducing the mixture into a stirrer, and roll mixing milling the mixture with heating it with heat of 70-80 deg.C for 30 minutes; naturally curing the mixture at ambient temperature for about 5-6 hours so that titanium oxide applied on the surface of silica is firmly bonded on the surface of silica; adding pigment and synthetic resin adhesive to the cured silica, and roll mixing rolling the mixture with heat of 70-80 deg.C for about 0.5-1 hours; and naturally curing the mixture at ambient temperature for about 30-60 minutes so that pigment is firmly bonded to the surface of silica.

Description

칼라 모르타르 조성물 및 그 제조방법{Mortar composition and manufacturing method}Color mortar composition and its manufacturing method {Mortar composition and manufacturing method}

본 발명은 칼라 모르타르 조성물 및 그 제조방법에 관한 것으로, 더욱 상세하게는 다양한 칼라를 가지는 모르타르로 벽체(실내/외 벽체는 물론 구조물의 바닥, 벽면, 천정면 모두를 포함)를 마감 처리할 수 있게 하여 별도로 벽지 또는 타일 및 도장작업을 하지 않아도 되는 칼라 모르타르 조성물 및 그 제조방법에 관한 것이다. The present invention relates to a color mortar composition and a method for manufacturing the same, and more particularly, to finish a wall (including both interior and exterior walls, as well as the floor, wall, and ceiling surface) of mortar having various colors. The present invention relates to a color mortar composition and a method for producing the same, which do not require wallpaper or tile and painting work separately.

현대의 급속한 문명의 발달과 2, 3차 산업의 발달과정을 거치며 21세기는 무분별 속에 이루워진 산업 발전의 부산물로써, 생태환경의 질서파괴를 초래하였고 대기권내 공기오염과 새집 증후군(SHS : sick house Syndrome)이라는 심하면 생명까지 위협받는 상황 속에서 삶의 질에 대한 심각성이 부각되었다.Through the rapid development of modern civilization and the development of secondary and tertiary industries, the 21st century is a byproduct of industrial development indiscriminately, resulting in the destruction of the ecological environment, air pollution and sick house syndrome in the atmosphere (SHS: sick house). The seriousness of the quality of life was highlighted in a severe life threatening situation.

우리나라에서도 텔레비젼등의 언론에 의해서 웰빙(Well-being)이라는 부분에 많은 관심이 생기게 되었다. 현재 사용되고있는 건축자재중 합판 및 목재 가공품등에서 방출되는 포름알데히드(HCHO) 및 페인트 및 석유화학제품 같은 휘발성 유기화학물질(TVOCs)로 인하여 화학물질 과민증(MCS : Multiple Chemical Sensitivity)으로 호흡기(천식), 피부염(특히 아토피 피부염) 및 두통, 만성피로, 현기증, 중추신경 억제 등의 피해를 주며 심하면 정신적으로 대인기피, 정신불안, 기억력상실 등 인간에게 심각한 영향을 주고 있다.In Korea, much attention has been given to the well-being part by the media such as TV. Multiple Chemical Sensitivity (MCS) due to volatile organic chemicals (TVOCs) such as formaldehyde (HCHO) and paints and petrochemicals emitted from plywood and wood products, among the currently used building materials. Dermatitis (especially atopic dermatitis) and headache, chronic fatigue, dizziness, central nervous system, and damage, such as severe mental retardation, mental anxiety, memory loss and serious effects on humans.

특히 내성에 약한 아동 및 노약자들과 여성들에게 지속적인 영향을 주고 있으며, 미국 환경보호국(EPA : Environmental Protection Agency)에서는 공해 중 가장 심각한 것이 실내공기이며, 메사추세츠주 특별법위원회는 실내공기의 질(IAQ : Indoor Air Quality)에 대한 오염이 자국내 발생하는 모든 질병의 50%를 책임지고 있다고 하는 신문보도도 있었다.In particular, it has a lasting effect on children, the elderly, and women who are vulnerable, and the US Environmental Protection Agency (EPA) is the most serious of the pollution, and the Massachusetts Special Law Commission has stated that indoor air quality (IAQ) Some newspapers say that pollution to air quality is responsible for 50% of all diseases in the country.

통상 철골 또는 철근 콘크리트 구조 및 조적 등의 구조로 형성되는 벽체는 그 표면에 시멘트 모르타르로 미장하고, 이에 합판 및 목재 가공품 또는 벽지, 페인트 등으로 마감처리하는 것이 보통이다.Usually, walls formed of steel or reinforced concrete structures and masonry structures are plastered with cement mortar on their surfaces, and it is common to finish them with plywood and wood processed products or wallpaper and paint.

그러나 시멘트 모르타르 등의 건축자재에서는 새집증후군으로 널리 알려진 두통, 아토피성 피부염, 천식 등을 유발시키는 유해성분을 발산하고 있다. 이는 실내의 고밀폐화에 따라 더욱 더 그 피해가 크다고 할 수 있는데, 원인은 건재 등에 포함되어 있는 휘발성유기화학물(VOC)과 포름알데히드에 기인한다.However, building materials, such as cement mortar, emit harmful ingredients that cause headaches, atopic dermatitis, and asthma, which are widely known as sick house syndrome. This can be said that the damage is more and more severe due to the high density of the room, the cause is due to volatile organic chemicals (VOC) and formaldehyde contained in building materials.

상기와 같은 새집증후군을 예방하기 위하여 베이크 아웃(bake out)이나 광촉매를 건자재의 표면에 분사하는 등의 시공을 하고 있으나, 이와 같은 외부 분사 코팅 방식은 그 지속 시간이 오래가지 못하고, 시멘트 모르타르는 다시 장식용 벽지로 도배를 하여야 비로소 실내 벽면의 마감이 이루어진다.In order to prevent the sick house syndrome as described above, such as baking out (bake out) or photocatalyst is sprayed on the surface of the building material, such as the external spray coating method does not last long, cement mortar The walls of the interior are not finished until they are painted with decorative wallpaper.

이러한 문제점을 해결하기 위한 것으로, 대한민국 특허출원 제 2005-27475호(유색 석영을 이용한 기능성 모르타르)가 안출된 바 있다.In order to solve this problem, Korean Patent Application No. 2005-27475 (functional mortar using colored quartz) has been devised.

상기 선 출원 발명은 모래와 같은 입도로 파쇄되어 통상의 세골제로 사용된 유색 석영과, 시멘트와, 마그네시아(MgO)가 혼합되어 구성되는 것이다.The above-mentioned pre-applied invention is composed of colored quartz, which is crushed into a granular particle like sand, and used as a normal fine aggregate, cement, and magnesia (MgO).

이러한 선 출원 발명에 따른 모르타르는 유색을 가지는 석영을 파쇄하여 모르타르의 골재로 사용함에 따라 그 가격이 매우 높은 단점이 있으며, 석영의 자연적인 색상의 한계로 다양한 칼라를 표현할 수 없고, 응고제로서 시멘트를 사용함에 따라 시멘트의 고유색에 의해 석영의 색상이 가려져 마감재로서의 사용에 많은 제한이 있고, 시멘트로부터 발생되는 유해한 성분으로 인하여 피해를 완전하게 방지할 수 없는 단점이 있는 것이다.Mortar according to the pre-applied invention has the disadvantage that the price is very high by using the aggregate of the mortar by crushing the colored quartz, can not express various colors due to the limitation of the natural color of the quartz, cement as a coagulant In use, the color of the quartz is masked by the intrinsic color of the cement, thereby limiting its use as a finishing material, and it is a disadvantage that the damage cannot be completely prevented due to harmful components generated from the cement.

본 발명은 전술한 문제점을 해결하기 위해 안출된 것으로서, 본 발명은 상기의 문제점을 해결하기 위해 안출된 것으로서, 본 발명은 모르타르가 벽체의 최종마감재로 이용될 수 있도록 다양한 칼라를 가지게 하여 인체에 유해한 포름알데히드(HCHO) 및 휘발성 유기화학물질(TVOCs) 등을 방출하는 합판/목재가공품/페인트/벽지 등의 사용을 배제시킬 수 있게 하는 칼라 모르타르 조성물과 그의 제조방법을 제공함에 그 목적이 있다.The present invention has been made to solve the above problems, the present invention has been made to solve the above problems, the present invention is harmful to the human body to have a variety of colors to be used as a mortar is the final finishing material of the wall It is an object of the present invention to provide a color mortar composition and a method for preparing the same, which can eliminate the use of plywood / wood products / paint / wallpaper and the like that emit formaldehyde (HCHO) and volatile organic chemicals (TVOCs).

본 발명의 또 다른 목적은 통상의 모르타르 골재로 사용되는 규사에 색을 고착시켜 칼라 모르타르를 제조함으로써, 모르타르의 제조비용을 최소화시키고, 모르타르 응고제로 합성수지 접착제를 사용하여 시멘트를 배제시켜 시멘트 독과 같은 유해성분의 방출을 원천적으로 방지시킬 수 있게 하는 것에 있다.Still another object of the present invention is to produce color mortar by fixing color to silica sand used as a general mortar aggregate, thereby minimizing the cost of producing mortar, and excluding cement by using a synthetic resin adhesive as a mortar coagulant. It is to be able to prevent the release of harmful components at the source.

이에 본 발명은 상기한 바와 같은 목적을 달성하기 위하여 다음과 같이 구성된다. 즉, 본 발명은 규사의 표면에 안료의 견고한 고착을 유도하기 위하여 산화티타늄을 코팅하고, 산화티타늄이 코팅된 규사에 안료를 착색시켜 모르타르용 골재를 형성시키고, 모르타르골재에 합성수지접착제를 포함시켜 칼라 모르타르를 제조하는 것에 큰 특징을 둔 것이다. Thus, the present invention is configured as follows to achieve the object as described above. That is, the present invention is coated with titanium oxide in order to induce a firm fixation of the pigment on the surface of the silica sand, by coloring the pigment on the titanium oxide coated silica sand to form a aggregate for mortar, including a synthetic resin adhesive in the mortar aggregate It is a big feature to manufacture mortar.

이하에서는 본 발명의 바람직한 실시 예를 상세히 설명하기로 한다.Hereinafter, a preferred embodiment of the present invention will be described in detail.

본 발명은 규사의 표면에 산화티타늄을 코팅시키고, 산화티타늄이 코팅된 규사에 안료를 첨가시키고, 모르타르의 응고제로 합성수지 접착제를 포함시켜서된 칼라모르타르 조성물이다. The present invention is a color mortar composition in which titanium oxide is coated on the surface of silica sand, a pigment is added to the titanium oxide coated silica sand, and a synthetic resin adhesive is included as a mortar coagulant.

규사의 표면에 산화티타늄을 코팅시키는 이유는 안료가 규사의 표면에 견고하게 고착되도록 하기 위함이다.The reason for coating titanium oxide on the surface of the silica sand is to allow the pigment to adhere firmly to the surface of the silica sand.

이러한 칼라 모르타르 조성물의 제조방법을 설명하면 다음과 같다.Referring to the manufacturing method of such a color mortar composition is as follows.

24∼34메쉬 정도의 입자크기를 가지는 규사를 세척시키는 세척단계와; A washing step of washing the silica sand having a particle size of about 24 to 34 mesh;

세척된 규사에 포함된 불순물을 소독하는 동시에 산화티타늄과의 견고한 결합을 위하여 70∼80℃의 열로서 30여분 가열시키는 1차 가열단계와;A primary heating step of disinfecting impurities contained in the washed silica sand and heating them for about 30 minutes with heat of 70 to 80 ° C. for solid bonding with titanium oxide;

1차 가열된 규사 100%에 15∼20%의 산화티타늄 분말을 첨가시키고, 이를 교반기에 투입시켜 70∼80℃의 열로서 30여분 가열시키면서 혼련시키는 산화티타늄 코팅단계와; A titanium oxide coating step of adding 15 to 20% of titanium oxide powder to 100% of the first heated silica sand, kneading the mixture by adding it to a stirrer and heating for 30 minutes with heat of 70 to 80 ° C .;

규사의 표면에 코팅되는 산화티타늄이 규사의 표면에 견고하게 결합되도록 상온에서 5∼6시간 자연경화시키는 1차 경화단계와; A first curing step of natural curing at room temperature for 5 to 6 hours so that the titanium oxide coated on the surface of the silica sand is firmly bonded to the surface of the silica sand;

경화단계를 거친 규사에 안료과 합성수지접착제를 첨가하고 이를 70∼80℃의 열로서 30∼1시간 정도 혼련시키는 착색단계와;A coloring step of adding a pigment and a synthetic resin adhesive to the silica sand subjected to the curing step and kneading it with heat of 70 to 80 ° C. for about 30 to 1 hour;

규사의 표면에 착색되는 안료가 견고하게 결합되도록 상온에서 30∼60여분 자연경화시키는 2차 경화단계를 거쳐 칼라 모르타르용 골재를 제조하고, 이에 합성수지 접착제를 첨가시켜 칼라 모르타를 조성물을 제조하는 것이다. To prepare a color mortar aggregate by adding a synthetic resin adhesive to the aggregate through the second curing step of natural curing at room temperature for 30 to 60 minutes to solidify the pigment pigmented on the surface of the silica sand. .

이렇게 제조된 칼라 모르타르 골재를 이용한 시공방법을 설명하면 다음과 같다.Referring to the construction method using the prepared color mortar aggregate as follows.

칼라 모르타르 골재에 아크릴수지 계열의 합성수지 접착제(응고된 후 투명한 질감을 가지는 접착제)를 첨가하여 혼합시키고, 이를 통상의 미장방법으로 벽체에 부착시키는 것이다.Acrylic resin-based synthetic resin adhesive (an adhesive having a transparent texture after coagulation) is added to the colored mortar aggregate and mixed, and it is attached to a wall by a conventional plastering method.

본 발명에서 사용되는 안료는 유기질 안료가 사용되면 안료의 칼라에 따라 다양한 색상의 칼라 모르타르용 골재를 제조할 수 있는 것이다. Pigment used in the present invention is that when the organic pigment is used, it is possible to produce aggregates for color mortar of various colors according to the color of the pigment.

그리고 착색단계를 거친 칼라 모르타르 골재에 광택제를 첨가시키게 되면 모르타르가 응고된 후 칼라가 더욱 선명하게 표현된다.In addition, when a brightening agent is added to the colored mortar aggregate after the coloring step, the color is more clearly expressed after the mortar solidifies.

본 발명은 전술한 실시 예에 국한되지 않고 본 발명의 기술사상이 허용하는 범위 내에서 다양하게 변형하여 실시할 수가 있다.The present invention is not limited to the above embodiments, and various modifications can be made within the scope of the technical idea of the present invention.

이상에서와 같이 본 발명에 따르면 모르타르가 벽체의 최종마감재로 이용될 수 있도록 다양한 칼라를 가짐에 따라 인체에 유해한 포름알데히드(HCHO) 및 휘발성 유기화학물질(TVOCs) 등을 방출하는 합판/목재가공품/페인트/벽지 등의 사용을 배제시킬 수 있으며, 이러한 별도의 마감재 설치공정을 하지 않아도 되어 공사기간을 대폭적으로 단축시킬 수 있는 효과가 있는 것이다.As described above, according to the present invention, as mortar has various colors so that it can be used as a final finishing material of the wall, plywood / wood processing product / releasing formaldehyde (HCHO) and volatile organic chemicals (TVOCs), which are harmful to the human body, The use of paint / wallpaper, etc. can be excluded, and there is no need to perform such a separate finishing material installation process, which can significantly shorten the construction period.

또한 통상의 모르타르 골재로 사용되는 규사에 색을 고착시켜 칼라 모르타르를 제조함으로써, 칼라 모르타르의 제조비용을 최소화시키고, 모르타르 응고제로 합성수지 접착제를 사용함으로써, 시멘트를 배제시켜 시멘트 독과 같은 유해성분의 방출을 원천적으로 방지시킬 수 있는 효과도 있는 것이다In addition, by producing color mortar by fixing color to silica sand used as a general mortar aggregate, minimizing the manufacturing cost of color mortar, and using a synthetic resin adhesive as a mortar coagulant, by excluding the cement to release the harmful components such as cement poison There is also an effect that can be prevented at the source

Claims (3)

24∼34메쉬 정도의 입자크기를 가지는 규사를 세척시키는 세척단계와;A washing step of washing the silica sand having a particle size of about 24 to 34 mesh; 세척된 규사에 포함된 불순물을 소독하는 동시에 산화티타늄과의 견고한 결합을 위하여 70∼80℃의 열로서 30여분 가열시키는 1차 가열단계와;A primary heating step of disinfecting impurities contained in the washed silica sand and heating them for about 30 minutes with heat of 70 to 80 ° C. for solid bonding with titanium oxide; 1차 가열된 규사 100%에 15∼20%의 산화티타늄 분말을 첨가시키고, 이를 교반기에 투입시켜 70∼80℃의 열로서 30여분 가열시키면서 혼련시키는 산화티타늄 코팅단계와; A titanium oxide coating step of adding 15 to 20% of titanium oxide powder to 100% of the first heated silica sand, kneading the mixture by adding it to a stirrer and heating for 30 minutes with heat of 70 to 80 ° C .; 규사의 표면에 코팅되는 산화티타늄이 규사의 표면에 견고하게 결합되도록 상온에서 5∼6시간 자연경화시키는 1차 경화단계와; A first curing step of natural curing at room temperature for 5 to 6 hours so that the titanium oxide coated on the surface of the silica sand is firmly bonded to the surface of the silica sand; 경화단계를 거친 규사에 안료과 합성수지접착제를 첨가하고 이를 70∼80℃의 열로서 30∼1시간 정도 혼련시키는 착색단계와;A coloring step of adding a pigment and a synthetic resin adhesive to the silica sand subjected to the curing step and kneading it with heat of 70 to 80 ° C. for about 30 to 1 hour; 규사의 표면에 착색되는 안료가 견고하게 결합되도록 상온에서 30∼60여분 자연경화시키는 2차 경화단계를 거쳐 제조됨을 특징으로 하는 칼라 모르타르의 제조방법. Method for producing a color mortar, characterized in that it is prepared through a secondary curing step of natural curing at room temperature for 30 to 60 minutes so that the pigment pigmented on the surface of the silica sand firmly bonded. 규사의 표면에 산화티타늄을 코팅시키고, 산화티타늄이 코팅된 규사에 안료를 첨가시키고, 모르타르의 응고제로 합성수지 접착제를 포함시켜서된 것을 특징으로 하는 칼라모르타르 조성물.A color mortar composition characterized by coating titanium oxide on the surface of silica sand, adding a pigment to the silica sand coated with titanium oxide, and including a synthetic resin adhesive as a mortar coagulant. 제 2 항에 있어서, 상기 조성물에 광택제를 첨가시켜 된 것을 특징으로 하는 칼라 모르타르 조성물. The color mortar composition according to claim 2, wherein a brightening agent is added to the composition.
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