KR20060031791A - Production method of drinking water from the deep sea water - Google Patents

Abstract

An object of the present invention is to provide a method for producing a beverage using deep sea water of 200 m or less.

To this end, the present invention, the present invention is to take the deep sea water of less than 200m depth, warming at 20 ~ 30 ℃ and small grouping treatment of water molecules, and then sand filtration (micro filter), Sulfate (CaSO), which removes suspended solids (SS) from water by ultra filtration and nano-filtration, is a problem in scale generation in reverse osmosis filter. ₄ ) and remove the divalent or more mineral salt and send it to the first reverse osmosis filtration process, and the brine is sent to the salt and mineral salt manufacturing process, and the desalted demineralized water is sent to the pH adjustment process to adjust the pH to 9-11. The deborated water, from which the boron compound has been removed and sent to the second reverse osmosis filtration process, is sent to the mineral mixing and neutralization process.

Mineral modifier sends sulfuric acid ion-containing mineral water removed from nanofiltration process to evaporative concentration process, evaporation concentration of bomedo specific gravity (° Be) is 24 ~ 26 ° Be, and concentrated mineral water is sent to salt and mineral manufacturing process, and precipitation Calcium sulfate (CaSO ₄ ), which is mixed and dissolved in the pre-filtered deep seawater by the mineral composition adjusting process so that the Ca / Mg weight composition ratio is in the range of 2.0 to 6.0, is mixed with the monovalent anion selective exchange membrane and monovalent cation selective exchange. After desalination of monovalent salts (NaCl, KCl) by electrodialysis desalting process with alternating diaphragms arranged in multiple rows, the monovalent anion selective exchange diaphragm and the cation selective exchange diaphragm are alternately arranged. trehalose (trehalose, α-D-glucopyranosyl α-D-glucopyanoside) and lactic acid (lactic acid) to send to the removal of sulfate ions by electrodialysis apparatus installed in the multi-stage process to remove sulfate ions (SO ₄ ^2-), Electric conductivity indicating switch by mineral mixing and neutralization process by converting single or two or more kinds of additives from ascorbic acid and gluconic acid into organic mineral salts Send the required amount by adjusting.

In the mineral mixing and neutralization process, the minerals are mixed and neutralized and sent to the sterilization process to be sterilized, and then the beverage is produced by the process of packing, inspecting and packing the container.

The beverage produced in the present invention is suitable for mineral balance while treating boron, which has been a problem in the production of beverages from deep sea water, to 0.3 mg / l or less, suitable for mineral balance, and agglomerates of water molecules; It is expected that it will be widely used in the production method of beverages because clusters are small grouped, so that the surface tension decreases and the refreshing feeling is improved and the water taste is good.

Deep sea water, beverages, subpopulations, nanofiltration, reverse osmosis, sulfate ions, saline, minerals, boron

Description

Production method of drinking water from the deep sea water}

1 is a process chart for producing a beverage from deep sea water

2 is a small grouping process chart of water molecules

3 is a process for precipitation of calcium sulfate by evaporative concentration of mineral water containing sulfate ion

4 is a mineral composition adjustment and desalination process chart

5 is a process for removing sulfate ion of demineralized mineral water

6 is a model diagram of a water molecular aggregate

<Description of Symbols for Main Parts of Drawings>

One; Electronic treatment tank 2; electrode

 3; Insulator 4; Stainless steel sheet

 5; Foundation concrete structure 6; grounding

 7; Constant voltage generator (Electron charger)

 7a; Variable resistor 7b; grounding

 7c; Primary winding 7d; Iron core

 7e; Secondary winding 8; Intermediate Treatment Tank

 9; Magnetizer feed pump 10; Constant Voltage Conduit Magnetizer

11; Small group reservoir 12; Small group transfer pump

13; Sulfate ion-containing mineral water storage tank 14; Sulfuric acid ion-containing mineral water transfer pump

15; Precipitation tank 16; Precipitation Tank Rake

17; Evaporation tower 18; Spray nozzle

19; Exhaust Fan

20; Precipitated calcium sulphate conveying conveyor

21; Dehydrator 22; Dehydration Filtration & Pond Water Storage Tank

23; Dewatered and feed water feed pumps 24; Mineral composition adjustment tank

25; Mineral composition adjusting tank stirrer 26; Mineral Composition Adjustment Water Transfer Pump

27; Desalination electrodialysis apparatus 28; anode

29; Cathode 30; Anode chamber

31; Cathode chamber 32; Monovalent anion selective exchange diaphragm

33; Monovalent cation selective exchange membrane 34; Desalination Room

35; Salt concentration room 36; Brine Storage Tank

37; Brine transfer pump 38; rectifier

39; Mineral water storage tank 40; Mineral Water Transfer Pump

41; Sulfate ion electrodialysis apparatus 42; anode

43; Cathode 44; Anode chamber

45; Cathode chamber 46; Monovalent anion selective exchange diaphragm

47; Cation selective exchange diaphragm 48; Demineral Room

49; Mineral concentration chamber 50; Desulfurization ion mineral water storage tank

51; Desulfurized ion mineral water transfer pump 52; rectifier

Ⓢ; Solenoid valve M; Motor

FI; Flow indicator

pHI; Hydrogen ion concentration indicator (pH indicator)

pHIS; PH indicating switch

ORPI; Oxidation reduction potential indicator

LS; Level switch

PCV; Pressure control valve

BI; Baumedo Stopwatch

BIS; Baumedo Indicating Switch

ECIS; Electric conductivity indicating switch

In the present invention, the deep sea water having a depth of 200 m or less is collected, warmed at 20 to 30 ° C., and subjected to a small grouping of water molecules, followed by sand filtration, micro filtration, ultra filtration. Suspended solids (SS) are removed from the water, and the salts are removed by nanofiltration and first reverse osmosis (RO filter), and then the pH is adjusted to 9-11. After removing the boron compound to neutralize the pH in the range of 6 to 8 while adjusting the mineral balance relates to a method for producing a beverage by sterilization.

Deep seawater and surface seawater with a depth of 200 m or less have similar concentrations of salinity (NaCl) and most minerals, as shown in Table 1, "Analysis of Compositions of Deep Sea Water and Surface Water," but nutrients (nitrogen nitrogen, Phosphoric acid, silicon), viable cell number, and water temperature are significantly different.

Table 1 Component Analysis of Deep Sea Water and Surface Sea Water

            Item   Deep ocean water     Surface seawater General item Water temperature (℃) 9 16.5-24.0 pH 7.59 7.85 DO dissolved oxygen (mg / L) 7.80 8.91 TOC Organic Carbon (mg / L) 0.962 1.780 Soluble evaporation residue (mg / L) 40750 37590 M-alkalido (mg / L) 114.7 110.5 Major element Cℓ chloride ion (wt%) 2.237 2.192 Na sodium (wt%) 1.080 1.030 Mg magnesium (wt%) 0.130 0.131 Ca Calcium (mg / L) 456 441 K potassium (mg / L) 414 399 Br cancel (mg / L) 68.8 68.1 Sr Strontium (mg / L) 7.77 7.61 B boron (mg / L) 4.44 4.48 Ba barium (mg / L) 0.044 0.025 F Fluorine (mg / L) 0.53 0.56 SO₄ (mg / L) 2833 2627 Nutrients NH₄ ammonia nitrogen (mg / L) 0.05 0.03 NO₃Nitrate Nitrate (mg / L) 1.158 0.081 PO₄ Phosphate (mg / L) 0.177 0.028 Si silicon (mg / L) 1.89 0.32 Trace elements Pb lead (μg / L) 0.102 0.087 Cd Cadmium (μg / L) 0.028 0.008 Cu copper (μg / L) 0.153 0.272 Fe iron (μg / L) 0.217 0.355 Mn Manganese (μg / L) 0.265 0.313 Ni nickel (μg / L) 0.387 0.496 Zn Zinc (μg / L) 0.624 0.452 As Arsenic (μg / L) 1.051 0.440 Mo molybdenum (μg / L) 5.095 5.555  Number of bacteria Viable count (pcs / ml) 10² 10³ to 10⁴

※ The above analysis data are obtained by analyzing deep seawater and surface seawater of 374m below the east of Murodo Lighthouse in Kochi Prefecture, Japan.

The water temperature of deep sea water is almost constant throughout the year, and the surface water temperature of sea level is 16 ~ 28 ℃, but the water temperature of 374m deep water is 9 ℃, showing low temperature stability and low cleanness of plankton, microorganisms, especially pathogenic bacteria. There is (淸 淨 性).

Deep seawater was not detected in the test of 10 kinds of bacteria such as Escherichia coli and virus except general bacteria, and the total viable count is hygienically safe water from about one tenth to one hundredth of surface water.

In addition, deep sea water contains about 5 to 10 times more inorganic nutrients than surface water and contains more than 70 kinds of minerals, which are necessary for humans. Deep mineral water, which contains only a small amount, has a deep relationship with human health, such as copper, arsenic, and chromium.

In addition, deep sea water is matured for a long period of time at low temperature and high pressure in the deep sea, and the organic content is low and pH is lower than surface water (around pH 7.8), and it is a cluster of water molecules compared to terrestrial or mineral water. ) Has a small characteristic.

Therefore, deep sea water can be a high-quality drink by removing salt and some harmful substances (boron) and adjusting the mineral balance appropriately.

Examining the conditions for the production of beverages are as follows.

1. It should not contain harmful substances.

Unhealthy organic chlorine compounds, pesticides, heavy metal ions (arsenic, lead, cadmium, mercury, chromium…), bacteria, viruses… It should not contain harmful substances such as

2. Mineral balance necessary for human body should be suitable.

(1) Water having a hardness of 10 to 300 mg / L, which represents the concentration of calcium (Ca) and magnesium (Mg), is preferable.

② Water with a ratio of (Ca + K + SiO ₂ ) / (Mg + SiO ₄ ), which is an index of good water taste (OI) of 2.0 or more, tastes good.

③ Ca-0.87Na, which is the index of health (KI), is more than 5.2.

④ The concentration of evaporation residue should be 30 ～ 300㎎ / ℓ.

3. The pH is 7.2 ~ 7.4 weak alkaline water is good for your health.

The pH of human blood is 7.3 ~ 7.45, which is weakly alkaline. The concentration of hydrogen ions in the body is always weakly alkaline and physiologically controlled, so weakly alkaline water is easily absorbed by the body. Acidic water with a pH of less than 7 is not good because of the easy growth of bacteria and viruses.

4. Water of microclustered water is preferred where the cluster of water molecules is subpopulated.

When the group of water molecules are small grouped, surface tension decreases, and the penetration force is improved in the cell, thereby promoting metabolism. Also, the water with good penetration power has a refreshing feeling and the taste of water is good. NMR) Water treated with a value of ¹⁷ O-NMR half width of 60 Hz or less is preferable.

5. Oxidation Reduction Potential (ORP) value of + 100 ~ -200㎷ is good for health.

Higher redox potential means higher oxidative power, while lower redox potential means stronger reducing power.

Water is a compound of hydrogen and oxygen, hydrogen has a strong reducing power at a potential of -420 mV, oxygen shows a strong oxidation power at a potential of +820 mV, from which water shows a potential of -420 to +820 mV, and reduction of oxidation degree The potential of water in the state not shown is +200 kPa which is halfway between the potential of hydrogen and oxygen.

Although the potential of the biological water varies slightly from person to person, depending on the part of the human body and the state of health, it usually shows a minus potential of less than or equal to 0 μs. Dislocation increases, and as a result, the dislocation of urine immediately after excretion in vitro is about 0 to +100 kPa in a healthy person.

The quality of living water is a major factor in determining the health of the human body, and drinking water also turns into living water after a few seconds.

Normally, the potential of tap water is high in the range of +300 to +600 mV, and the tongue of a healthy person is -100 mV around the potential, so water in the range of -100 to +100 mV feels delicious, and intake of reduced water of -100 mV or less When the diuretic effect increases, blood is purified, and the osmotic pressure of water increases, solubility of minerals is significantly increased, and mineral absorption efficiency is improved. When drinking a large amount, it acts on the oxidized part of the body to improve the constitution.

Reducible water with a low redox potential (ORP) is good for health because it has the ability to oxidize cells in the body and eliminate active oxygen that promotes aging, and in particular, the redox potential value is from +100 to Water in the range of -200㎷ is good.

6. High wave water is good, especially water with high immune waves (免疫 波動) is good for health.

7. Water taste is good if free carbonate dissolves 3-30mg / l and dissolved oxygen 5-6mg / l.

8. The concentration of COD _Mn , which indicates the organic content, is 3 mg / l or less, the concentration of free chlorine is 0.4 mg / l or less, the odor is 3 or less, and the chromaticity is Is less than or equal to 5 degrees, turbidity is less than or equal to 2 degrees, iron is less than 0.05 mg / l, and manganese (Mn) is less than 0.01 mg / l.

9. Water temperature is 20 ℃ or less, the taste is good.

The water temperature is correlated with the water taste, the water temperature of 10 ~ 14 ℃ is the best water taste.

Generally, the characteristics of deep sea water refer to low temperature safety, cleanliness, eutrophicity, mineral properties, and maturation. The characteristics are as follows.

1. It is very clean and contains various minerals necessary for the human body.

The deep sea contains various minerals necessary for the human body, and it is a clean state without contaminants such as domestic wastewater and environmental hormones, with little or no pathogenic microorganisms at low temperature and high pressure without sunlight being transmitted. It's water.

2. Deep sea water has an infinite amount of mineral water and river water on land, and it can produce high quality sanitary drinks.

3. It has been shown to activate the proliferation of macrophage.

4. Nuclear magnetic resonance (NMR) ¹⁷ O-NMR half-width of 75 ~ 80Hz, aged under mineral and low temperature and high pressure for a long time, water compared to 130-150Hz of ¹⁷ O-NMR half-width of tap water The population of molecules is subgrouped.

5. Oxidation Reduction Potential (ORP) is somewhat lower than that of regular tap water.

The redox potential of ordinary tap water has a value of +165 to + 175㎷, which is somewhat lower than that of +500 to + 700㎷.

6. Compared with surface water, deep water has a large amount of divalent trivalent iron while repeating the oxidation-reduction reaction. Therefore, when the magnetization treatment is performed with high wave water, small grouping efficiency of water molecules is increased. Can be treated with high water.

The human body consists of four elements, carbon (C), hydrogen (H), oxygen (O), and nitrogen (N), about 96% of the total and 4% of the minerals. Minerals are proteins, fats, carbohydrates, vitamins and one of the five major nutrients, and are part of the body. Minerals are indispensable for the adjustment of fluid volume, acid and alkalinity, and muscle and nerve function. In addition, it is deeply involved in the metabolism of carbohydrates, proteins, fats, etc., and the amount of minerals is very small, but it is indispensable for the maintenance of life. Deficiency can lead to osteoporosis, delayed intelligence development, tooth decay, back or joint pain, muscle spasms, seizures, insomnia, emotional anxiety, and high blood pressure.

In other words, minerals play an important role, which can be referred to as `` body's lubricant '' as an indispensable nutrient for the smooth movement of the body's functions, such as metabolism, hormone production, and osteoporosis. The body cannot function smoothly, and minerals can not be made in the body, so it has no choice but to supplement it with food, drinking water, salt, etc.Insufficient intake can cause deficiency and cause various diseases. To do this, you need to consume the minerals that are balanced and appropriate.

The constituent elements of the human body are 65% oxygen, 18% carbon, 10% hydrogen, 3% nitrogen, and important minerals: 1.5-2.1% calcium, 0.8-1.2% phosphorus, 0.3-0.4% potassium, 0.25-0.3% sulfur Trace minerals other than 0.15 to 0.2% sodium, 0.15 to 0.2% chlorine and 0.05 to 0.1% magnesium, 0.006% iron, 0.002% zinc, selenium 0.0003%, manganese 0.0003%, copper 0.00015%, urethra 0.00004%, other molybdenum, Cobalt, chromium, etc. are in extremely small amounts.

The daily requirement of minerals is calcium 600-700 mg, phosphorus 700 mg, potassium 2000 mg, sodium 1.5 g, magnesium 250-320 mg and trace mineral iron 10-12 mg, zinc 10-12 mg, copper 1.6- 1.8 mg, manganese 3.0-4.0 mg, urethra 150 µg, selenium 45-60 µg, molybdenum 25-30 µg, and chromium 30-35 µg.

In particular, lack of calcium among minerals may cause osteoporosis, lack of calcium (Ca) is the most problematic problem, the required calcium intake is 600 ~ 700 ㎎ / day, magnesium is 250 ~ 320 ㎎ / day It is important to consume magnesium at a ratio of 2 to 2.4: 1 by weight.

In the case of beverages, water with a ratio of (Ca + K + SiO ₂ ) / (Mg + SO ₄ ^2- ), which is a good water index (OI) of 2.0 or more, tastes good, and Ca- 0.87Na, which is an index of health (KI) Water with a value of 5.2 or more is known to be good for health.

However, in the case of deep sea water, there is a problem that the concentration of magnesium (MgCl ₂ and MgSO ₄ ) is about 3 times higher than that of calcium (Ca) salt while the NaCl concentration is high.

In other words, in order to mix the minerals in food, or used as a mineral-adjusting liquid to the drinking water while at least a weight ratio of Ca / Mg 2.0 sulfuric acid ion (SO ₄ ^{2 -),} as is preferred that the low concentrations of, but in Table 1 ocean In the deep water, the Ca / Mg weight ratio is 0.35 and the concentration of sulfate ion is about 2,800mg / ℓ. Therefore, the mineral balance of Ca / Mg and the mineral salt that has been removed as much as possible can be used as food or beverage regulator. There is a problem.

NaCl in drinking water shall remind the salty taste, magnesium (MgCl _2, MgSO ₄₎ has a bitter taste, sour calcium (KCl) is a sulfate ion (SO ₄ ^{2 -)} to remind of the acidity (酸味) to tteurige dropped mulmat On the other hand, the calcium component is characterized by softening the taste of water to improve the taste of water.

The following are the considerations to be taken into consideration when producing deep-water withdrawals.

1, yet at least a weight ratio of Ca / Mg 2.0, sulfate ion (SO ₄ ^{2 -)} and the concentration should be low.

2. Reverse osmosis filtration process causes membrane clogging due to scale generation during operation, which leads to an increase in pressure loss coefficient, drift of feed water, and deterioration of reverse osmosis membrane. Should be done.

3. A method of reducing the membrane resistance in reverse osmosis by reducing surface tension and viscosity should be taken.

4. Heat-resistant amino acids, such as trehalose, should not be heat-treated to prevent thermal degradation of heat-sensitive materials.

5. Inorganic mineral salts are poor in absorption efficiency, so organic complex salts are preferred.

And in addition to the above-mentioned problems of mineral balance of Ca / Mg when producing a beverage from deep sea water, there are the following problems.

1. Boric acid, known as a substance that causes disorders in the digestive or nervous system of the human body when ingested in large quantities, is a small molecule particle and cannot be completely removed by simple nanofiltration, reverse osmosis filtration, and electrodialysis.

Since boron has a small particle size of 0.23Å, it is difficult to process water below the standard of 0.3 mg / l by simple nanofiltration and reverse osmosis filtration. Boron compounds (H ₃ BO ₃₎ ), And the dissociation constant pKa value is about 9, which is almost undissolved in seawater and rarely exists in the ionic state. There is a problem that the treatment is difficult to mg / L or less.

2. The redox potential value is somewhat lower as +165 to +175 ㎷ compared to +500 to +700 ㎷ in general beverages such as tap water, but higher than the appropriate value at +100 to -200 ㎷.

3. Nuclear Magnetic Resonance (NMR) ^{17 The} O-NMR half-width ranges from 75 to 80 Hz, indicating that the small grouping rate of water molecules is not very high.

In Japanese Patent Laid-Open No. 2005-52130 and Japanese Patent Laid-Open No. 2002-369671, in order to solve the problem of boron contained in the above-described deep sea water, fresh water and fresh water collected from the deep water of the deep sea water and streams are used. ), A method of mixing water such as mineral water, tap water, and the like has been proposed, but such a beverage has a problem in that it can not fully exhibit the characteristics of deep sea water.

In Japanese Patent Application Laid-Open No. 2004-65196g, the treatment was performed while adjusting the conductivity to less than 10 mW / cm in an electrodialysis apparatus using a membrane that selectively permeates only monovalent ions. Boron was not treated at 0.2 mg / l or less, and there was a problem that the concentration of Mg ions was higher than that of Ca ions, and in the case of JP-A-238515, seawater was treated by adjusting the electrical conductivity by electrodialysis. However, this method also did not solve the above problems.

The method of reverse osmosis filtration treatment with Amberlite resin of Japanese Patent Publication No. 2002-361246 and Japanese Patent Publication No. 2001-300264 for removing boron compound is carried out in the final stage of reverse osmosis process by three stage reverse osmosis filtration. Although a method of adjusting the pH has been proposed, these also have problems such as mineral balance, small grouping of water molecules and redox potential values have not been properly solved.

In the present invention, the Bomedo (° Be) of the Baume's hydrometer representing the specific gravity of seawater is expressed as a numerical value of the scale when the Bomedo hydrometer is floated in the liquid to measure the specific gravity of the liquid, Heavy bomedoes for heavy liquids and light bomedoes for light liquids that are lighter than the specific gravity of water. Among them, pure liquids are pure water. 0 ° Be, 15% saline solution to 15 ° Be, with 15 divisions between them. For liquid solution, 10% saline solution to 0 ° Be and pure water to 10 ° Be. The scale is divided into 15 equal parts between them, and BOME (° Be) is widely used as a measure of concentration because seawater approximates salt concentration (wt%).

The relationship between the Bume (° Be) and the specific gravity (d) of the liquid is

For heavy media that has a specific gravity of liquid greater than that of water

d = 144.3 / (144.3- ° Be). … … … … … … … … … … … … … … … … … ①

In the case of an alarm field where the specific gravity of the liquid is lower than the specific gravity of the water

d = 144.3 / (134.3 + ° Be). … … … … … … … … … … … … … … … … … ②

The electrical conductivity measured by the electric conductivity indicating switch (ECIS) is an indicator of the degree of conduction of an aqueous solution by conducting electricity. The unit represents the salt concentration in water. The unit is the inverse of the electrical resistivity of the aqueous solution. Corresponding Siemens / meter, and the relationship between the electrical conductivity (EC) and the total soluble salt (TSS) in water is as follows.

TSS (ppm) = 640 X EC (mm / cm). … … … … … … … … … … … … … … … ③

The double salinity concentration (NaCl ppm) can be estimated simply by the following equation (4).

Salinity concentration (NaCl ppm) = 552 x EC (cc / cm) -200. … … … … … … … … … ④

The conductivity value is expressed in millimenss / meter, or microsiemens / centimeter, which is an international system of units, and ㎳ / m = 10 μs / cm (or 10 μmhos / cm).

In order to solve the above problems, the present invention treats the concentration of the boron compound from the deep sea water to the drinking water standard value of 0.3 mg / l or less while adjusting the mineral balance and treating the population of water molecules with 5 to 6 small groups. It is an object of the present invention to provide a method for producing a beverage that is good and excellent in taste of water.

In order to achieve the above object, the present invention is to collect the deep sea water of 200m or less, warming to 20 ~ 30 ℃, small grouping of water molecules and sand filtration-microfiltration-ultrafiltration pretreatment step, nanofiltration ( Nano filtration) and pH adjustment to 9-11 and salt and mineral removal in the second reverse osmosis process, after adjusting the mineral balance to the weight ratio of Ca / Mg is 2 to 4 after removing the salt and sulfate ions Injecting the step of preparing a mineral balance regulator, mineral mixing and neutralization treatment, sterilization treatment. It is characterized by consisting of the steps of producing a beverage by filling, packaging and inspecting the container.

First of all, the characteristics of deep ocean water are 200 meters below sea level, and since the deep sea water does not reach the plankton because it does not reach the sun, unlike the sea water at the surface, high nutrients do not exist in the surface water. It is characterized by cleanliness, low temperature stability and mineral balance characteristics.

1. High nutrition

In the deep sea where sunlight does not reach, the photosynthesis by plankton is hardly performed, unlike seawater in the surface layer, so there is no consumption of inorganic nutrients (nitrogen, nitrate, phosphate, silicon) consumed by photosynthesis in the surface seawater. Due to the lack of activity, large amounts of nutrients are decomposed and eluted from organic matter, such as dead bodies of organisms that have settled from the surface, and high concentrations of nutrients exist because there is no plankton to use. .

2. Cleanliness

In the deep sea where sunlight does not reach, there is little plankton, so there are few organisms such as fish, there are few pathogenic microorganisms, and the possibility of contamination by pollutants from land and the atmosphere is very small compared to surface water, and it is very clean. .

3. Low Temperature Stability

Deep sea water is characterized by extremely stable changes in water temperature at low and high pressures without mixing with surface water from the difference in temperature and salt concentration.

4. Mineral Properties

Deep sea water contains more than 70 different essential trace elements.

Since mineral salts dissolved in deep sea water have the above characteristics, they can produce high-quality mineral salts because they contain various mineral components that are hygienic and safe and useful to the human body.

The following are the considerations for the preparation of high quality deep-sealed populations using deep ocean water.

1. The boron compound should be treated with the drinking water standard below 0.3mg / l.

Deep sea water contains boron in the range of 4-5 mg / l and is present in the form of boric acid (H ₃ BO ₃ ). Since the particle size is small, with an ion radius of 0.23 음료, nanofiltration and reverse osmosis Because the treatment is difficult to be treated with the treatment standard value of 0.3 mg / l or less, resin adsorption method, flocculation sedimentation method, and alkali treatment with pH of 9-11 are used to convert boric acid to gel boric acid to polyboric acid. There is a method of treatment by reverse osmosis filtration. In the present invention, a method of removing boric acid converted to polyboric acid by alkali treatment by reverse osmosis is selected.

When boric acid in water is subjected to alkali treatment, it is converted into polyboric acid in gel state by the reaction of ⑤ as follows.

B (OH) ₃ + OH ^_ → [B (OH) ₄ ] ^- → [B ₃ O ₃ (OH) ₄ ] ^- → [B ₄ O ₅ (OH) ₄ ] ^2- → [B ₅ O ₆ (OH ) ₄ ] ^- … ⑤

2. Mineral balance should be suitable.

Lack of calcium among minerals may cause osteoporosis, lack of intake of calcium (Ca) is the most important problem, calcium intake required in adults is 600 ~ 700mg / day, magnesium is 250 ~ 320mg / day The weight ratio of calcium (Ca) / magnesium (Mg) is preferably ingested at a ratio of two or more.

In order to use a mineral adjustment minerals to beverages Ca / Mg ion sulfuric acid while the weight ratio is 2.0 or more of (SO ₄ ^{2 -)} preferably is of low level, however, the deep sea water, as shown in Table 1, the weight of the Ca / Mg Since the ratio of magnesium is much higher than calcium and the concentration of sulfate ions is about 2,800 mg / l, the ratio is 0.35. Therefore, it is recommended to adjust the balance of Ca / Mg and to make mineral salts with the least amount of sulfate ions and to use them as beverage adjusters. desirable.

In water, calcium gives a mild and mellow taste, while magnesium makes bitter, potassium sour, and salt salty.

In the present invention, the mineral balance in the hardness range of 10 ~ 300mg / ℓ, the concentration of evaporation residue (蒸發 殘留 物) in the range of 30 ~ 200mg / ℓ while good water index (OI) is 2.0 or more The mineral balance is adjusted so that the health index (KI) is above 5.2.

Index of good taste (OI) = (Ca + K + SiO ₂ ) / (Mg + SiO ₄ ). … … … ⑥

Index of health (KI) = Ca- 0.87 Na... … … … … … … … … … … … … … … … ⑦

3. Adjust the Oxidation Reduction Potential (ORP) value within the range of +100 to -200 mA.

Water with a redox potential of less than + 200㎷ is called reducing water, and reducing water has good ability to eliminate free radicals in the body, which is good for health.If the redox potential is below -200㎷, it tastes like water. In the present invention, the redox potential value is adjusted to be in the range of +100 to -200 mA.

The redox potential of deep sea water is slightly lower (+165 to +175 kPa) compared to +500 to +700 kPa of general beverages such as tap water, but higher than the appropriate value of +100 to -200 kPa.

4. Nuclear Magnetic Resonance (NMR) ¹⁷ O-The NMR half-value width is treated with microclustered water in the range of 48 to 60 Hz.

When the cluster of water molecules is small grouped, the surface tension is decreased and the penetration is improved, so that the absorption of the cell is increased and the metabolic activity is activated.

Nuclear Magnetic Resonance (NMR) ¹⁷ O-NMR half-width value 1/10 is equal to the number of water molecules, and ¹⁷ O-NMR half-width value is 60Hz water molecule The number of groups is 6 microclustered water (小集團 水).

For tap water, the nuclear magnetic resonance ¹⁷ O-NMR half-width ranges from 130 to 150 Hz, and the mineral waters of Lourdes and Evian in France, and the Nordenau in Germany , Nadana of India, Tracote of Mexico, and Lee Myung-soo of Mt. Baekdu have the values of nuclear magnetic resonance ¹⁷ O-NMR half-width of 60 ~ 70Hz, which is less than that of general tap water. In the case of deep ocean water, the small grouping rate is not so high at 75 to 80 Hz.

In general, nuclear magnetic resonance, such as tap water ¹⁷ O-NMR half-width value of the 130~150Hz while the number of water molecules group this group of dogs 13 to 15 water molecules may flood the Grand Mass (Bound water) and la, while the ¹⁷ O- The value of NMR half-width is less than six groups of water molecules of 60 Hz or less, and water having a small number of water molecules is called microclustered water.

In the present invention, the population of water molecules is treated with a small population of nuclear magnetic resonance ¹⁷ O-NMR half-widths in the range of 48 to 60 Hz.

Hereinafter, described in detail by the accompanying drawings as follows.

I. Pretreatment stage

1. Intake and heating process

In the pretreatment process, the deep sea water with a depth of 200m or less is taken out and warmed, the small groups of water molecules are treated so that the subsequent treatments such as nanofiltration, reverse osmosis filtration, desalination of NaCl, concentration, and removal of sulfate ion Pretreatment filtration.

In FIG. 1, the deep sea water is taken from the deep seabed of 200 m or less, and the intake method is to take the pipe down to 200 m or less from the ship's bottom, or install the pipe to the sea level 200 m or less, and then take it with a pump. Or, pipes are installed up to 200m below sea level, and the intake wells are installed below sea level to take water according to siphon principle.

Deep sea water collected in the sump is warmed to 20 ~ 30 ℃ because of its low viscosity and high filtration efficiency.

In reverse osmosis, when the water temperature rises by 1 ° C, the membrane permeability increases by about 3%.

The heating method may be supplied with heat from a boiler, or may use surface water in the summer.

2. Small grouping process of water molecule population

The warmed deep ocean water is a group of water molecules by magnetizing the group of water molecules with a high pressure constant voltage treatment of a small grouping process and a constant voltage conductive tube magnetizer or a permanent magnet. (Cluster) is divided into small groups and treated with microclustered water to reduce surface tension and viscosity, and then sent to pretreatment filtration process.

In the treatment step of small grouping of water molecules by a process combining a high-voltage constant voltage treatment and a magnetization treatment in the constant voltage conductive tube magnetizer 10, the electrons of the small grouping of water molecules are removed from the deep sea water subjected to heating treatment. It is injected into the treatment tank 1, and the high voltage AC constant voltage is applied from the constant voltage generator 7 to the electrode 2 with a voltage of 3,000 to 5,000 Volt (field strength of 0.3 to 15 KV / m) and a current of 0.4 to 1.6 µA. When the electrostatic fields of + and-are alternately applied to the water molecules for 4 to 10 hours alternately, the water molecules themselves vibrate and rotate repeatedly. When the hydrogen bonds of the molecules are partially broken, they are sent to the intermediate treatment water storage tank (8) and to the magnetizer supply pump (9) to the constant voltage conductor tube magnetizer (10) to the conductive tube. Low voltage of alternating current or direct current in the range of 0.5-5V After applied to the magnetic treatment, while some are conveyed to electronic processing tank 1 NMR; of the half-width range 48~60㎐ (半値幅) for ¹⁷ O-NMR of (核磁氣共鳴Nuclear magnetic resonance, NMR) When microclustered water is produced, the remainder is sent to the small group storage tank 11 and then sent to the pretreatment filtration process by the small group transfer pump 12.

The flow rate sent from the intermediate treatment water storage tank 8 to the magnetizer supply pump 9 to the constant voltage conductive tube magnetizer 10 and returned to the electronic treatment water tank 1 is 1 to 4 times the inflow water flow rate.

The small grouped water thus produced is treated with reduced water having a high alkaline oxidation frequency of +100 to -200 kW with high energy oxidation reduction potential (ORP).

The voltage applied to the electrode 2 of the electronic treatment tank 1 in the constant voltage generator 7 is adjusted in accordance with the values of pHI (7.4-7.8) and ORPI (+100 Hz or less) provided in the intermediate treatment water storage tank 8. do.

The material of the electrolytic treatment tank 1 is made of stainless steel, and the stainless steel electrode 2 filled with charcoal having high conductivity is inside. To the bottom of the insulator (3) of polyethylene (polyethylene), polyvinyl chloride (PVC), Styrofoam (Styrofoam) is selected and installed, the lower part of the insulator (3) is a conductor and corrosion-resistant material A steel sheet 4 is installed between the foundation concrete structures 5, and the stainless steel sheet 4 is grounded 6 to the ground.

The constant voltage conductor magnetizer (10) is a coil wound around a cylindrical conductive tube of insulating material such as synthetic resin (PVC, PE, styrene resin, etc.), ebonite, FRP, and Bakelite. ) When a low voltage of AC or DC in the range of 0.5 to 5 V is applied, a magnetic field is formed inside the coil, and when water is passed through it, the water is treated as a small group of water. .

Instead of the constant voltage conductive tube magnetizer 10, a permanent magnet magnetized in the range of 12,000 to 15,000 G (Gauss) may be provided.

When the capacity of the treated water is large, the electronic treatment water tank 1 in which the net of the electrode 2 of stainless steel filled with charcoal is embedded is treated by installing multiple stages.

As in the present invention, when the group of the water molecules by the high-voltage constant voltage treatment and the magnetizer is small grouped and treated with the small group water, the surface tension and the viscosity of the water are reduced and the penetration force is reduced. ), As the filtration efficiency is improved in the filtration process, various mineral components are activated while being magnetized, and when ingested, activated minerals having an excellent absorption rate are generated.

3. Pretreatment Filtration Process

Pretreatment filtration process is performed by sand filtration, micro filtration, ultra filtration alone or a combination of two or more of them, followed by nanofiltration and reverse osmosis filtration. Reverse osmosis filtration (SS) removes suspended solids (SS) that can cause fouling.

At this time, the filtration pressure is determined in consideration of the pressure loss of the filter and the pressure loss of the pipe according to the operating conditions.The filtration speed of sand filtration is 6-10 m / hour, and the effective diameter of the filter sand is 0.3-0.45 mm, the uniformity coefficient shall be 2.0 or less, and the thickness of the filtrate layer shall be 0.5-1.0 m.

At this time, if the turbidity of the deep ocean water taken is 2 mg / ℓ or less, it is not necessary to sand filtration.

Micro-filter and ultra-filter are not limited to the type of filtration membrane, and the supply pressure of the pump is decided by considering the filtration speed and the pressure loss according to the vendor's specifications. do.

In microfiltration or ultrafiltration, the filtration (Fouling index) of the water supplied to the nanofiltration and reverse osmosis filtration process is treated in the range of 2 to 4.

The FI value is a numerical value representing the fine turbidity concentration in the target water, and is expressed by the following equation (8).

FI = (1-T ₀ / T ₁₅ ) x 100/15... … … … … … … … … … ⑧

Where T ₀ is the time required for filtration of the first 500 ml of sample water when the sample water was filtered under pressure of 0.2 MPa using a 0.45 μm microfiltration membrane, and T ₁₅ was filtered for 15 minutes in the same state as T _0. It is time required for filtration of 500 ml of sample water afterwards.

II. Salt and Mineral Removal Steps

The shape of the membrane module of nanofiltration and reverse osmosis is tubular, hollow fiber, spiral wound, and flat plate and frame. It may be used in any form such as), and the material of the film is not particularly limited.

As the material of the nanofiltration membrane, polyamide-based, polypiperazineamide-based, polyesteramide-based, or cross-linked water-soluble vinyl polymer can be used. Is a dense layer on one side of the membrane, and has an asymmetric membrane with micropores of large pore diameter gradually from the dense layer toward the membrane or on one side of the membrane, or on the dense layer of such asymmetric membrane. A composite membrane having a very thin separation functional layer formed of another material can be used, and a piperazine polyamide composite membrane is preferable, but the material and structure of the membrane are not particularly limited in the present invention.

1. Nanofiltration Process

The deep seawater from which the suspended solids are removed from the pretreatment filtration process is sent to the nanofiltration process, the unfiltered sulfate ions are sent to the evaporation concentration process, and the desulfurization ion brine is filtered to the first reverse osmosis filtration process.

For the transmission order of the ion in the nano-filtration membrane is a cation is ^{Ca 2 + ≥Mg 2 +> Li} +> Na +> K +> is a NH ₄ ^+, if the anion is _{^{SO 4 2 - »HCO 3 ->}} F -> _{^{Cl -> Br -> NO 3}} -> and SiO _2, in the case of sulfate ions (SO ₄ ^2-) is hard to permeate than Mg ^{+ 2} and Ca ^{+ 2.}

In the first nanofiltration process, the solubility is small such as CaCO ₃ , CaSO ₄ , and SrSO ₄ dissolved in the first deep ocean water, and the scale is formed in the membrane during the concentration of salt in the reverse osmosis filtration process. In order to minimize fouling phenomenon, desulfurized ions brine (SO ₄ ^2- ) is removed by reverse osmosis filtration, and sulphate-containing mineral water is sent to evaporative concentration process to remove mineral regulator. Used for manufacturing.

In the first nanofiltration process, the supply pressure is 15 to 20 atm below 25 atm of deep ocean water osmotic pressure (atm) with a salt concentration of 3.5 wt%, and in the case of spiral, the membrane permeate is 0.7 to If it is 1.4m 3 / m 2 · day, the membrane permeate amount is 70-80% of the inflow rate.

Example 1

After warming the deep sea water of Table 1 to 25 ° C, a group of water molecules is injected into the electronic treatment tank 1 of the small group treatment step, and a high-pressure AC constant voltage is applied to the electrode 2 from the constant voltage generator 7. The voltage of Volt (electric strength 1.2KV / m) and the current of 0.5μA are applied for 4-10 hours to the intermediate treatment water storage tank (8) and to the magnetizer supply pump (9) to the constant voltage conductor tube magnetizer (10). After the magnetization treatment was applied to a coil wound around the conductive tube with a direct current of 0.6 V, a small number of small groups having a half width of ¹⁷ O-NMR of 52 N of magnetic resonance of nuclear magnetic resonance was returned to the electron treatment tank (1). The pre-treated filtrate with a FI value of 3.2 was filtered using ultra-filtration helical nanofiltration membrane of model No. SU-610 made of cross-linked polyamide of Toray Corporation of Japan. Is supplied to the membrane at 20㎏ / ㎠G and the membrane permeation amount is 1.2㎥ / ㎡ · day Membrane permeate flow was when she was 80% of the intake quantity, at this time the filtered result sulfate ion-containing mineral acid and filtration desulfurization equal to the contents of Table 2 value analysis of the main components of the hot water.

           Table 2 Analysis of Major Components of Water Quality Before and After Nanofiltration

 Item Pre-treated deep sea water (raw water) Desulphurized Water Salt (filtration)   % Removal      pH        7.80         7.24      - Na ⁺ (mg / L)   10,800    9,650     10.65 Cl ^- (㎎ / ℓ)   22,370   17,300     22.66 Ca ^{2 +} (㎎ / ℓ)      456      338     25.88 Mg ^{2 +} (㎎ / ℓ)    1,300    1,060     18.46 K ⁺ (mg / L)      414      355     14.25 _{^{SO 4 2 - (㎎ / ℓ}} )    2,833      608     78.54  B (mg / L)        4.44        4.43       0.23

As shown in Table 2, nano-filtration treatment of deep sea water resulted in almost no removal of boron compounds, and low removal rates of salts, calcium, and magnesium, as low as 10-26%, but 78.54% of sulfate ions. This was quite high.

2. First Reverse Osmosis Filtration Process

When the desulfurized ions brine filtered in the first nanofiltration process is supplied to the first reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 50 to 60 atmospheres (atm), and the membrane permeability is 0.5 to 0.8 for the spiral filtration membrane. When operating at ㎥ / ㎡ · day, salinity is removed in the range of 99.0 ~ 99.85wt%, brine is sent to salt and mineral manufacturing process, some is sent to manufacture calcium sulfate in evaporative concentration process, and demineralized water with desalted salt Send to pH adjustment process.

Example 2

The pressure of 60 kg / cm 2 was determined using a spiral reverse osmosis membrane of high-pressure reverse osmosis membrane model No. SU-810 of Toray Co., Ltd., Japan, which was filtered filtration water in the nanofiltration of Example 1. The membrane permeation amount was 52% of the inflow rate when the membrane permeate water was supplied to G membrane at 0.72㎥ / ㎡ · day, and the result of filtration showed that the analysis of the main components of the water quality of the filtered demineralized water was shown in Table 3 below. Same as

       Table 3 Analysis of Major Components of Demineralized Water as Filtrate in First Reverse Osmosis

 Item    Influent Water (Desulphurized Salt Water)    Filtrate (Demineralized Water)   % Removal      pH        7.24         7.20      - Na ⁺ (mg / L)    9,650       38.7     99.60 Cl ^- (㎎ / ℓ)   17,300       71.6     99.59 Ca ^{2 +} (㎎ / ℓ)      338        0.6     99.82 Mg ^{2 +} (㎎ / ℓ)    1,060        1.9     99.82 K ⁺ (mg / L)      355        1.7     99.52 _{^{SO 4 2 - (㎎ / ℓ}} )      608        4.7     99.23  B (mg / L)        4.43        1.8     59.37

As shown in Table 3, most of the substances were removed highly by 99% or more in the deep osmosis, but the boron compound was 1.8 mg / ℓ and the removal rate was less than 60%, and the drinking water quality standard was 0.3 mg / ℓ. It was not possible to use it for beverage production because it exceeded 6 times.

3. pH adjustment process

In the pH adjustment process, one of NaOH, NaHCO ₃ and Na ₂ CO ₃ is supplied as an alkali agent to adjust the pH to a range of 9 to 11, and the boric acid component in the water is treated with polyboric acid for the second reverse osmosis filtration process. send.

The operating condition of the pH adjustment step is that the pH adjustment method is performed by injecting alkali into the demineralized water of the first reverse osmosis step while stirring with a propeller stirrer of 180 to 360 RPM (rotational speed) for 15 to 30 minutes. Adjust to 9-11.

4. Second Reverse Osmosis Filtration Process

When the pH is adjusted to 9 ~ 11 in the pH adjustment process and supplied to the secondary reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 10-20 atm, and in the case of the spiral filtration membrane, the amount of membrane permeate is 0.6∼0.8㎥ Boron-containing water that has not been filtered and operated at / m² / day is discharged to the original position below 200m after the neutralization treatment, and the deboron water filtered with the boron concentration below 0.3 mg / l, which is the drinking water standard, is mixed and neutralized. Send to fair

In the second reverse osmosis process, even when the pH is supplied in an alkaline state of 9 to ₁₁ , scale generation is not a problem since the materials such as CaCO ₃ and CaSO _{4 which} generate scale are removed in the nanofiltration process.

Example 3

In the second reverse osmosis of Example 2, demineralized water, which was filtered water, was adjusted to pH 9.5 in a pH adjustment step to convert the boron compound in the water into the form of polyboric acid, followed by Toray Corporation of Japan. Low pressure reverse osmosis membrane model number SU-710 using a spiral reverse osmosis membrane to supply pressure to the membrane at 25㎏ / ㎠G and the membrane permeation rate was 0.72㎥ / ㎡ · day and the membrane permeation rate was 82% of the inflow rate. When the concentration of boron (B) in the filtered water (deboron water) was measured, 0.12 mg / L of boron in the drinking water was treated at 0.3 mg / L or less, which could be used for drinking water production.

III. Mineral modifier manufacturing stage

1. Evaporative Concentration Process of Mineral Water Containing Sulfate Ion

Sulfate ion-containing mineral water that has not been filtered in the nanofiltration process and part of the brine that has not been filtered in the first reverse osmosis filtration process enters the sulfuric acid ion-containing mineral water storage tank of the evaporative concentration process (13). Dry air in the atmosphere by the exhaust fan (19) while spraying through the spray nozzle (18) above the evaporation tower (17) together with the concentrated mineral water conveyed by the dehydration filtrate and the feed water feed pump (23). The water is sucked from the lower part of the evaporation tower 17 and countercurrently contacted with the sulfuric acid ion-containing mineral water while the water in the sulfuric acid ion-containing mineral water is evaporated, and then dropped into the precipitation tank 15 and flows into the upper part of the water, which is dehydrated. And it is sent to the water storage tank 22, the precipitated calcium sulfate (CaSO ₄ ) is precipitated to the bottom of the precipitation tank 15 by the precipitation tank lake 16 to the cone portion (Cone) of the lower center of the precipitation tank (15) Precipitation Sulphate Knife Transfer switch to supply to the dehydrator 21 by the Kurume conveyor 20 dewatered filtrate is then sent to the dehydration filtrate and ripening ryusu reservoir 22. The dehydration liquid and the poultry water transfer pump 23 are returned to the upper part of the evaporation tower 17, and the dehydrated calcium sulfate is sent to the mineral adjustment tank 24 of the mineral adjustment process.

As described above, the sulfuric acid ion-containing mineral water is sent to the upper part of the evaporation tower 17, and the water is evaporated after dropping into the precipitation tank 15 to convey the dehydration filtrate and the water feed pump 23 to the evaporation tower 17. Calcium sulfate (CaSO ₄ ) begins to precipitate after the evaporation continues to be 11.5 ° Be of the liquid, and NaCl is precipitated when the Bomedo specific gravity is ₂₄ to 26 ° Be. Calcium sulfate (CaSO ₄ ), which is precipitated by concentrating the specific gravity of Bomedo to ₂₄ ~ 26 ° Be, is sent to the mineral adjustment process, and the concentrated mineral water, which is dehydrated, is sent to the salt and mineral salt manufacturing process.

And if the processing capacity is large, the water of the precipitation tank 15 is dewatered and the water storage tank 22, the dewatered filtrate and the storage tank of the water is separately installed and sent to the water storage tank to the evaporation tower by the water feed pump (17) It is easy to adjust the concentration of concentrated mineral water which is returned to the upper part as a dehydration filtrate.

The structure of the evaporation tower 17 is the same as that of the cooling tower of an industrial plant, and the material is preservative wood, fiber glass reinforced plastic (FRP), slate, and the like.

The material of the precipitation tank 15, the dewatering liquid and the water storage tank 22 may be epoxy coated on reinforced concrete, or lining or coating FRP resin or epoxy resin on titanium or SUS-316L or steel sheet. Use it.

The diameter of the precipitation tank 15 ranges from 60 to 90 kg / m 2 · day of solid salt loading of the precipitation salt, with a depth of 2 to 4 m, and a slope of the bottom of the bottom in the range of 1.5 / 10 to 2.5 / 10. To be designed).

The material of the precipitation tank rake 16 also uses the above-described flame-retardant material, or is coated with an epoxy resin on a steel sheet, the rotation speed is 0.02 ~ 0.05rpm, the power of the reducer and the diameter of the precipitation tank 15 The torque is determined by taking into account the state of the precipitated salt.

The material of the dehydration and poultry water transfer pump (23), the precipitated calcium sulfate transfer screw conveyor (20), the dehydration filtrate and the pore water transfer pump (23) and the dehydrator (21) are made of titanium or SUS-316L. Pipes are made of titanium, SUS-316L, PE (polyethylene) or PVC (poly vinyl chlorde) resin.

And in case of small capacity, the angle of inclination of the bottom of the precipitation tank 15 is 60 °. The precipitation tank rake 16 may be omitted.

2. Mineral composition adjustment process

As shown in Table 1, the mineral component contained in the deep sea water is about 0.35 by weight ratio of Ca / Mg, whereas a good beverage is (Ca + K + SiO ₂ ) / which is the good water taste index (OI) (Mg + SO ₄ ^{2 -)} a good water ratio of 2.0 or greater taste, but also the water more than the value of the Ca- 0.87Na Health index (KI) of the formula ⑦ 5.2 is known to be good for your health.

However, since the concentration of NaCl in the deep sea water is high and the concentration of magnesium (MgCl ₂ and MgSO ₄ ) is higher than that of calcium (Ca) salt, the weight ratio of Ca / Mg in order to use mineral as a mineral adjustment liquid in beverages Is a mineral salt having a low concentration of sulfate ion (SO ₄ ^{2 −} ) at 2.0 or higher, but as shown in Table 1, the concentration of Ca / Mg in the deep sea water is 0.35 and the concentration of sulfate ion is about 2,800 mg / Because it exists as high as ℓ, it can be used as a beverage adjuster only when adjusting mineral balance of Ca / Mg and making mineral salt that removed sulfate ion as much as possible.

Therefore, in the present invention, CaSO ₄ discharged from the salt production process is injected into the deep seawater pre-filtered so as to have a balance of Ca / Mg in the range of 2 to 6, thereby preparing a mineral regulator having a suitable mineral balance.

In the mineral composition adjusting process, the pre-filtered deep seawater is injected into the mineral composition adjusting tank 24 in the required amount, and calcium sulfate (CaSO ₄ ) is injected into the Ca / Mg weight ratio in the range of 2 to 6 to propeller type. The mineral balance was adjusted by stirring the mineral composition adjusting tank stirrer 25 at a rotational speed of 180 to 360 RPM for 30 to 40 minutes to dissolve calcium sulfate, and then adjusting the mineral balance by the mineral composition adjusting water transfer pump 26. 34).

The material of the mineral composition adjustment tank agitator 25 also uses SUS-316L, titanium, and bronze alloys, which are flame resistant materials.

3. Desalination Process

The desalination electrodialysis apparatus of the NaCl desalination process separates ionic solutes by membrane permeation using the potential difference of the direct current power applied from the rectifier 38 as a driving force. The monovalent cation selective exchange diaphragm 21 selectively transmits a monovalent cation having a fixed negative charge, and the monovalent anion selective exchange diaphragm 20 has a fixed electrostatic charge. An ion exchange diaphragm that selectively transmits monovalent anions with

As shown in FIG. 4, the desalination electrodialysis apparatus 27 suppresses scale troubles and improves salt concentration efficiency while increasing the limit current density to increase treatment efficiency so that monovalent cation selective exchange is possible. The diaphragm 33 and the monovalent anion selective exchange diaphragm 32 are alternately installed between the positive electrode 28 and the negative electrode 29 in a row in a multistage manner, and the positive electrode chambers 30 at both ends are provided. The deep seawater in which the mineral balance is adjusted in the mineral composition adjustment process is applied with a direct current from the rectifier 38 to the anode 28 of the anode 28 and the cathode 29 of the cathode chamber 31. 26) to the desalting chamber 34 to desalting the concentration of salts (monovalent salts of NaCl and KCl) in the range of 400 to 800 mg / l, while some were returned to the mineral composition adjusting tank 24 and desalting. Mineral water (demineralized water) is used in the electrical conductivity indicating switch (ECIS). Electric conductivity is sent to the mineral water storage tank (39) by operating a solenoid valve (Solenoid valve; 로) in the range of 6 ~ 12㎳ / ㎝, and salt water in the brine storage tank 36 to the salt concentration chamber (35) to the brine transfer pump ( 37), monovalent cations such as Na ⁺ and K ⁺ in mineral water pass through the monovalent cation selective exchange diaphragm 33 by electrical attraction to the salt concentration chamber 35 on the negative electrode 28 side. The Cl ⁻ ions pass through the monovalent anion selective exchange diaphragm 32 and move to the salt concentration chamber 35 toward the anode 28 to remove salts (NaCl, KCl), thereby removing the salt from the brine reservoir 36. Concentrated brine concentrated in the range of 10-22 ° Be is sent to the salt and mineral salt manufacturing process by the operation of the solenoid valve (ⓢ) by the BOME (Baume indicating switch).

When the water level of the brine storage tank 36 drops, the desalted water of the drinking water production process is operated by supplying a solenoid valve ⓢ to a level controller LS installed in the brine storage tank 36 as a water.

The desalination electrodialysis apparatus 27 preferably increases the current density as much as possible within the range of the limit current density in order to increase the processing performance, but the limit current density is proportional to the salt concentration in the diffusion layer. Since it is inversely proportional to the thickness of (iii), when the thickness of the diffusion layer is constant, it depends on the concentration of salt in the mineral water to be drained and the concentration of brine, and according to the present invention, the monovalent cation selective exchange membrane 33 and Mineral balance in the desalination electrodialysis apparatus 27 which forms the desalination chamber 34 and the salt concentration chamber 35 which alternately arrange the monovalent anion selective exchange diaphragm 32 between the anode 28 and the cathode 29. Is sent to the desalination chamber (34) by the mineral composition adjustment water transfer pump (26), which is partially circulated after desalination, and the brine is concentrated by the brine transfer pump (37). Desalination and salt concentration by circulation By supplying a large amount of brine passing through the salt concentration chamber 35 so that the scale component is not produced in the salt concentration chamber 35 while improving the rate, scale trouble can be prevented, and the salt concentration in the salt concentration chamber 35 is increased. By supplying high salt water, the current resistance decreases, so that the limit current density can be increased, so that the processing performance of the desalination electrodialysis apparatus 27 can be improved.

In order to improve electrodialysis efficiency and to suppress scale trouble by increasing the limit current density in the desalination electrodialysis apparatus 27 and increasing the amount of energization, the flow rate supplied to the desalination chamber 34 is the membrane surface velocity (膜). The demineralized mineral water is returned to the mineral composition adjusting tank 24 so that the surface water is in the range of 10 to 30 cm / sec, and the flow rate of the brine supplied to the salt concentration chamber 35 is 1 to 3 The brine is returned to the brine reservoir 36 to maintain the cm / sec range.

The monovalent cation selective exchange diaphragm 33 used in the present invention is an exchange membrane that selectively permeates only monovalent cations while suppressing divalent or more multivalent cation permeation, and is a polystyrene-divinylbenzene. Side chains and polyethyleneimine in the negatively charged membrane, which holds the negatively charged R-SO ₃ ⁻ in the main chain of the Or an ion exchange membrane synthesized with a graft polymer such as polyvinylpyridine or a graft polymer whose main chain is polystyrene or a polystyrene pyridine side chain, wherein the main chain of the graft polymer is the main cation exchange membrane. Any structure having the same molecular structure as the chain or the side chain can be used without limitation. Preferably, polyethylene, polypropylene, polychloride The main chain or the side chain (側鎖) 1 is only cation permeable to the function (透過能) with the same molecular structure and a polymer consisting of a cation exchange membrane is fixed ^a-carbonyl (Polyvinylchlorde), polystyrene (polystyrene) or the like negatively charged R-SO ₃ It is possible to use a cation selective exchange membrane such as polyvinylpyridine, polyvinylamine or polyethyleneimine membrane having a molecular structure, and in particular, polystyrene-graft-ethylene imine of polystyrene-divinylbenzene Most preferably.

And 1 is selected, the anion exchange membrane 32 is a monovalent cation selected exchange membrane 33, as opposed to one that a film with an anion only be selectively exchanged by the electrostatic charge (正電荷) R-NH ₃ ⁺ of the polymer chain ( It is also fixed to the polymer chain and fixed to the membrane, so it is also called static charge membrane, and the ion exchange group is crosslinked by aliphatic hydrocarbon, An anion exchange diaphragm in which a thin layer of a polymer material having a cation exchange group is formed on the surface, and it is preferable to perform cross-linking and quaternization simultaneously with aliphatic hydrocarbon to the monomer introduced into the exchange group. Examples of the polymer material having a cation exchange group include a polymer electrolyte having a cation exchange group, a linear polymer electrolyte, an insoluble polymer having a cation exchange group, and the like. Polyelectrolytes having a cation exchange group having a molecular weight of 500 or more in sulfonates such as linginsulfonate, phosphate ester salts such as higher alcohol phosphate esters, methacrylic acid, styrene sulfonic acid Linear polymer electrolyte containing a large number of monomer units having a carboxylic acid group (-COOH) or a sulfonic acid group (-SO ₃ H), such as phenols and aldehydes including a cation exchange group. The membrane which selectively exchanges monovalent anions, such as an insoluble polymer which has a cation exchange group which condensed, is used.

The anode 28 of the anode chamber 30 of the desalination electrodialysis apparatus 27 is made of a corrosion-resistant material and uses a DSA (Dimensionally stable anode) electrode or a platinum plated electrode having high hydrogen and oxygen generation overvoltage. Injecting the solution through the cathode chamber 31 to suppress the generation of chlorine and oxygen on the surface of the anode 28, the cathode 29 has a high hydrogen generation overvoltage (Ranney nickel) ) Or a stainless steel sheet, and the cation exchange membrane closest to the cathode chamber 19 is formed by using a hydrogen ion impermeable permeable membrane or a monovalent anion selective permeable membrane 32. (29) It is advisable to reduce the amount of hydrogen ions generated on the surface, thereby improving power efficiency and reducing odor.

In addition, in the salt concentration chamber 35, a polarity switching device is installed in the rectifier 38 to switch the power of the positive electrode 28 and the negative electrode 29 in case the treatment efficiency is lowered. So that the attached scale is detached.

The electrolyte solution of the electrode chamber is supplied to the cathode chamber 31 to supply the electrolyte solution discharged to the cathode chamber 30, the electrolyte solution (cathode chamber solution) supplied to the cathode chamber 31 is sea water (deep sea water) It is also possible to use, but 3 to 10wt% Na ₂ SO ₄ Using an aqueous solution can suppress corrosion of the electrode and generation of chlorine (Cl ₂ ) gas at the anode 28.

4. Sulfate Ion Removal Process

In the above-described desalination electrodialysis apparatus 27, when the monovalent ion salts (NaCl and KCl) are demineralized and the mineral water is transferred to the mineral water storage tank 39, the cation exchange membrane is more than monovalent and bivalent to the mineral water transfer pump 40. A cation selective exchange diaphragm 47 is used, which permeates all of the polyvalent cations, and the anion exchange membrane is a monovalent anion selective exchange diaphragm that selectively permeates only monovalent anions as in the desalination electrodialysis apparatus 27 ( 46 is supplied to the demineralization chamber 48 of the sulfate-ion removing electrodialysis apparatus 41 in which a plurality of stages are alternately installed between the anode 42 and the cathode 43, and the desulfurized ion mineral water storage tank ( The desulfurization ion mineral water of 50) is supplied to the mineral concentration chamber 49 by the desulfurization ion mineral water transfer pump 51 and circulated to the desulfurization ion mineral water storage tank 50, thereby direct current is supplied from the rectifier 52. When applied, cations such as Ca ²⁺ and residual Na ⁺ , K ^{+ in} mineral water All moves to the negative electrode 43 of mineral concentration chamber 49 on the side through the cation selected exchange membranes 47 and anion ion sulfuric acid because it first uses the selected anion exchange membrane _{^{(32) (SO 4 2 -}} ) The divalent or higher polyvalent ions such as do not pass through the monovalent anion selective exchange diaphragm 46, and only the monovalent anion (Cl ⁻ ) passes through the monovalent anion selective exchange diaphragm 46 to concentrate the mineral on the anode 42 side. Moving to (49), the mineral salts are concentrated and the sulfate ions are removed from the mineral water.

In NaCl-desalted mineral water, sulfates such as MgSO ₄ and CaSO ₄ combined with sulfate ions are present, but the cation exchange membrane 47 uses a cation exchange membrane that permeates all cations, and the anion exchange membrane selectively contains only monovalent anions. In the ion exchange membrane electrodialysis apparatus in which the monovalent anion selective exchange membrane 46 that is permeate is alternately arranged in a row between the anode 42 and the cathode 43, sulfate ion is difficult to penetrate the anion exchange membrane. Since it remains in the chamber 48, since there are few sulfate ions in the mineral concentration chamber 49, calcium ions (Ca ²⁺ ) are combined with extra chlorine ions (Cl ⁻ ) to form calcium chloride (CaCl ₂ ).

The reason why the composition of the water is changed is that the concentration of mineral water by ion exchange membrane electrodialysis is difficult for SO ₄ ^{2 -} ions to pass through the monovalent anion selective exchange membrane 46. It is called selective permeability.

After the mineral balance is adjusted, the demineralized mineral water in the desulfurized ion mineral water storage tank 50 is supplied while the demineralized mineral water is supplied to the demineral chamber 48 by the mineral water transfer pump 40 and returned to the mineral water storage tank 39. The ion mineral water is supplied to the mineral concentration chamber 49 by the desulfurized ion mineral water transfer pump 51, and circulated to the desulfurized ion mineral water storage tank 50, and a direct current is applied from the rectifier 52. All cations in the mineral water of 48) penetrate through the cation selective exchange diaphragm 47 by electrical attractive force and move to the mineral concentration chamber 49 on the cathode 43 side. Only the monovalent anions excluding the above ions are selectively moved to the mineral concentration chamber 49, and only the mineral components and the monovalent anions in the mineral water are moved, so that the electrical conductivity drops to 8 to 20 kW / cm. Electric conductivity indi The solenoid valve (ⓢ) is operated by a cating switch to send sulfate-containing water to the salt and mineral salt manufacturing process, and minerals are separated and concentrated in the mineral concentration chamber (49) to store the desulfurized ion mineral water storage tank (50). When the selling weight is concentrated in the range of 10 to 24 ° Be, the solenoid valve (ⓢ) is operated by a Baume indicating switch (BIS) and sent to the additive mixing process.

And when the water level of the desulfurization ion mineral water storage tank 50 falls, demineralized water is supplied to the water level controller LS installed in the desulfurization ion mineral water storage tank 50 by the operation of the solenoid valve ⓢ.

In the case of the above-described sulfate ion removing ion exchange membrane electrodialysis apparatus 41, all cations such as Na ⁺ , K ⁺ , Ca ^{2 +} , Mg ^{2 + in water} pass through the cation exchange membrane, and Cl ⁻ , Br ⁻ , SO ₄ ^{2 -} is on the negative sulfate ion (SO ₄ ^2-), except the monovalent anion-selective ion but a large amount of sulfate ions by using the base film, such as exchange (SO ₄ ^2-) ion is sulfate because it is difficult to pass through concentration is low, the remaining Ca ^{2 +} ion is a chloride ion (Cl ^-) and the following formula ⑨ metathesis like; wake up the (複分解double decomposition) reaction of calcium chloride (CaCl ₂₎ is generated.

CaSO ₄ + MgCl ₂ → CaCl ₂ + MgSO ₄ ... … … … … … … … … … … … ⑨

The anode 42 of the electrodialysis device 41 of the sulfate ion removing process also uses a corrosion-resistant material and a DSA (Dimensionally stable anode) or platinum-plated electrode having high hydrogen and oxygen generation overvoltage. The anode chamber solution injects the solution that has passed through the cathode chamber 45 to suppress the generation of chlorine and oxygen on the surface of the anode 42, and the cathode 43 has a high nickel production high-nickel nickel. (Cannery nickel) or stainless steel (Stainless steel) steel plate, and the cation exchange diaphragm closest to the cathode chamber 45 is a cathode (by using a hydrogen ion impermeable membrane or a monovalent anion permeable membrane). 43) Reduce the generation of hydrogen ions (H ⁺ ) on the surface to improve power efficiency and reduce odor.

In addition, in the mineral concentration chamber 49, a polarity switching device is installed in the rectifier 52 in order to reduce the processing efficiency by generating scale so that the attached scale is detached.

The electrolyte solution of the electrode chamber supplies the electrolyte solution discharged from the cathode chamber 45 to the cathode chamber 44, and the electrolyte solution (cathode chamber solution) supplied to the cathode chamber 45 may use deep sea water. 3-10 wt% Na ₂ SO ₄ Using an aqueous solution can suppress corrosion of the electrode and generation of chlorine (Cl ₂ ) gas at the anode 42.

Sulfate ion removal electrodialysis device (41) is also preferred to increase the current density as high as possible within the range of the limit current density to increase the processing performance, but the limit current density is proportional to the salt concentration. Since the thickness of the diffusion layer is inversely proportional to the thickness of the diffusion layer, the concentration of the diffusion layer depends on the salt concentration in the sulfate-containing water to be drained and the salt concentration of the desulfurized concentrated mineral water. The number of minerals in the electrodialysis apparatus 41 which forms the demineralization chamber 48 and the mineral concentration chamber 49 which arranged the anion selective exchange diaphragm 46 alternately between the anode 42 and the cathode 43 Partial circulation after demineralization is sent to the demineralization chamber 48 by the mineral water transfer pump 40, and desulfurization ion concentrated mineral water is transferred to the mineral concentration chamber 49 by the desulfurization ion mineral water transfer pump 51. By sending By supplying a large amount of desulfurized ion concentrated mineral water passing through the mineral concentration chamber 49 to prevent the scale component from being generated in the mineral concentration chamber 49 while improving the mineral concentration efficiency, it is possible to prevent scale troubles. By supplying the desulfurized ion mineral water with high mineral salt concentration to the chamber 49, the liquid resistance of the current is reduced, so that the limit current density can be increased, thereby improving the processing performance of the electrosulfate removing electrolysis device 41. You can.

In order to improve electrodialysis efficiency and to suppress scale trouble by increasing the limit current density in the sulfate elimination electrodialysis apparatus 41, the flow rate supplied to the demineralization chamber 48 is increased. The mineral water is returned to the mineral water storage tank 39 at a plane linear velocity in the range of 10 to 30 cm / sec, and the flow rate of the desulfurized ion mineral water supplied to the mineral concentration chamber 49 is the membrane surface velocity. It is returned to the desulfurized ion mineral water storage tank 50 so that 1 to 3 cm / sec range is maintained.

The cation selective exchange diaphragm 47 used in the present invention fixes the negatively charged R-SO ₃ ⁻ to the main chain of the polystyrene-divinylbenzene system. A monovalent anion selective exchange diaphragm 46 is used, and the monovalent anion selective exchange diaphragm 46 is a monovalent anion selective exchange diaphragm 20 of the desalination electrodialysis apparatus 27 of the above-described desalination step. Use the same as).

The liquid desulfurized ion mineral water produced here is also used as a mineral additive in food, animal and fish feed, and the liquid desulfurized ion mineral water is produced by evaporating and concentrating the liquid desulfurized ion mineral water in the solid state of food, animal and fish. It can also be used as a mineral additive in feed.

5. Additive Mixing Process

Mineral salts in the inorganic state have low absorption efficiency when ingested, and can produce organic complex compounds, which are harmless to trehalose (α-D-glucopyranosyl α-D-glucopyanoside), ascorbic acid, Organic mineral additives, such as lactic acid, are supplied to prepare mineral mineral regulators.

Mineral water from which sulfate ions (SO ₄ ^2- ) have been removed from mineral water is injected into the additive mixing tank of the additive mixing process, and trehalose is injected into the total mineral content in the mineral water in the range of 0.3 to 5 wt%, and lactic acid (Lactic) acid), ascorbic acid, gluconic acid (gluconic acid) in the pH range of 4.5 to 5.5 while stirring alone or mixed two or more types of 5 to 20wt% aqueous solution with an additive mixing stirrer for 0.5 to 2 hours It is added to prepare a mineral regulator which is an organic mineral salt.

For example, in the case of calcium mineral, the reaction with lactic acid reacts as shown in the following reaction formula to produce calcium lactate, an organic mineral salt.

_{^{Ca 2 + + 2CH 2 CHOHCOOH →}} Ca (CH 3 CHOHCOO) 2 + 2H + ... … … … … … … … ⑩

 In the stirring method, the stirring time (retention time) is 0.5-2 hours and the rotation speed is 180-360 RPM with a propeller stirrer, and the material is one of flame resistant materials SUS-316L, titanium, and bronze alloys. .

The liquid organic mineral salts prepared here are also used as mineral additives in food, animal and fish feeds, or the liquid organic mineral salts are evaporated and concentrated to produce solids as mineral additives in food, animal and fish feeds. Can also be used.

Ⅳ. Final beverage production stage

1. Mineral mixing and neutralization process

In the mineral mixing and neutralization process, when deboron water from which the boron compound has been removed is introduced in the second reverse osmosis process, acid (HCl, neutralizing agent) is added to neutralize the pH to a range of 6-8, a calcium sulfate (CaSO ₄₎ to adjust the mineral balance in the range 2 to 6. the weight ratio of Ca / Mg and then, salt (NaCl) and sulfate ions (SO ₄ ^{2 -)} the removal of trehalose and ascorbic acid, lactic acid in the mineral, Supplying a mineral regulator prepared in the form of an organic mineral salt by supplying an aqueous solution of 5-20 wt% of an organic additive, alone or mixed in two or more kinds of gluconic acid, to supply electricity to an electric conductivity indicating switch. The hardness is adjusted in the range of 50 to 300 mg / L by the conductivity adjustment.

In the sulfuric acid ion removal process, desulfurized ionized mineral water is directly mixed with minerals in desulfurized mineral water from which sulfate is removed, and mineral additives such as trehalose, ascorbic acid, lactic acid, and gluconic acid are added. You can also use zero.

In other words, desulfurized mineral water can be used as a mineral modifier in the mineral mixing and neutralization process without adding organic additives such as trehalose, ascorbic acid and lactic acid to desulfurized mineral water.

The reaction tank capacity of the mineral mixing and neutralization process is set to have a residence time of 20 to 30 minutes, and is stirred with a propeller stirrer of 180 to 360 RPM (rotational speed).

Example 4

In the second reverse osmosis filtration process of Example 3, Ca / Mg was neutralized by adding 10wt% aqueous hydrochloric acid (HCl) solution to the filtered water (deboronized water) in which the boron compound was finally treated to the beverage water quality level or lower. The water quality analysis results of the mineral modifier prepared at the ratio of 3 to 3 were adjusted with the conductivity indicator controller (ECIS) in the range of 250∼260㎲ / ㎝.

Table 4 Result of mineral regulator injected into the filtered water (deboron water) of the second reverse osmosis filtration

                      Water quality analysis value

    Item  Second Reverse Osmosis Membrane Filtrate   Mineral mixed and neutralized water     Remarks (water consumption standard)          pH       8.2       7.3    5.8 to 8.5    Conductivity (㎲ / ㎝)          210         255 ¹⁷ O-NMR (㎐)          53         53  Redox potential value (㎷)           62          60  Hardness (mg / ℓ)          14.8        210.7   300 or less Na ^{+ (mg / l)}          28.96         32.62  200 or less (according to WHO) Cl- ^{(mg / L)}          50.82         57.24   250 or less Ca ^{2 + (㎎ / ℓ)}           0.86         42.30 Mg ^{2 + (㎎ / ℓ)}           3.08         16.90 K ^{+ (mg / l)}           0.98         1.10 SiO _{2 (mg / L)}           0.25         2.26 SO ₄ ^{2- (mg / L)}           3.32         5.20   Less than 200  B (mg / l)           0.12         0.13   0.3 or less

Reviewing the results of processing of the information in Table 4 Index of good mulmat of the aforementioned formula ⑥ (OI) = (Ca + K + SiO ₂₎ / (Mg + SO ₄ ^{2 -),} the value of is (42.30 + 1.10 + 2.26) /(16.90 + 5.20) = 2.04, which is greater than or equal to 2.0 the standard of good water index, and the index of health (KI) = Ca- 0.87Na = 42.30 -0.87 × 32.62 = 13.92, which is greater than the standard 5.2. Has been properly adjusted, the redox potential has been properly treated to 60㎐, and the ¹⁷ O-NMR value of the half width of the nuclear magnetic resonance is 53㎐, so that the water molecules are small grouped to produce high quality beverages. It turned out to be.

In addition, the concentration of boron (B) was also treated to 0.13 mg / L, which is 0.3 mg / L or less of drinking water standard value.

2. Sterilization, container filling, packaging and inspection process

The above-mentioned mineral mixture and neutralization treatment are sent to the sterilization process, and the beverage sterilized by high temperature sterilization or UV sterilization at 120-135 ° C. for 0.5 to 10 minutes is sent to the container filling process to fill the container (can or plastic bottle). Next, it is packaged after inspection and shipped as a beverage.

As described above, according to the present invention, since the deep ocean water has an infinite amount and contains various minerals useful for cleanliness and human body, the salt and boron are matured by high water pressure for many years. Drinking water mixed with a mineral balance modifier with the Ca / Mg weight ratio adjusted to a range of 2 to 4 after treatment within the drinking water standard value is expected to have a wide spreading effect.

Claims (5)

Deep ocean water below 200m I. Pretreatment stage 1. Intake and heating process Piping down the pipe below 200m from the ship's bottom, or installing the pipe up to 200m below the seabed, or using a pump, or installing the pipe up to 200m below the seabed to install the water well below the sea level. The deep sea water taken in accordance with the siphon principle is heated to 20 to 30 ° C. 2. Small grouping process of water molecule population The warmed deep sea water is injected into the electronic treatment tank 1 of the group of water molecules in a small grouping process, and a high-voltage AC constant voltage is applied to the electrode 2 from the constant voltage generator 7 to 3,000 to 5,000 Volts (field strength). A voltage of 0.3-15 KV / m and a current of 0.4-1.6 μA are applied to the water molecules alternately and repeatedly applied to the water molecules for 4-10 hours (+/-). AC in the range of 0.5-5V to the coil wound on the conductive tube of the constant voltage conductive tube magnetizer 10 by sending it to the intermediate treatment water storage tank 8 while printing. Alternatively, after the magnetization treatment is applied by applying a low voltage of DC, a half width of ¹⁷ O-NMR of Nuclear Magnetic Resonance (NMR) is returned to the electronic treatment tank 1. Iv) when microclustered water is produced in the range of 48 to 60㎐, it is sent to the small group reservoir (11). The small group feed pump 12 is sent to a pretreatment filtration process. 3. Pretreatment Filtration Process The pretreatment filtration process uses sand filter, micro filter, ultra filtration alone or a combination of two or more to filter the FI (Fouling index). Treat it as a range. II. Salt and Mineral Removal Steps 1. Nanofiltration Process The deep sea water from which suspended solids are removed from the pre-filtration process is sent to the nano-filtration process, and the operating pressure is 15 to 20 atm, and a portion of the divalent or higher mineral component and sulfate ion (SO ₄ ^2-) The desulfurized ions brine having been removed) is sent to the reverse osmosis filtration process, and the sulfuric acid ion-containing mineral water is sent to the evaporation concentration process for use in the preparation of mineral regulators. 2. First Reverse Osmosis Filtration Process When desulfurized ions brine filtered in the first nanofiltration process is supplied to the first reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 50 to 60 atmospheres (atm), and the brine is evaporated and concentrated in the salt and mineral manufacturing process. The desalted water in which the salt is desalted is sent to the pH adjusting process. 3. pH adjustment process In the pH adjustment process, one of NaOH, NaHCO ₃ and Na ₂ CO ₃ is supplied as an alkali agent to adjust the pH to a range of 9 to 11, and the boric acid component in the water is treated with polyboric acid for the second reverse osmosis filtration process. send. 4. Second Reverse Osmosis Filtration Process When the pH is adjusted to 9-11 in the pH adjustment process and supplied to the second reverse osmosis filtration process, the operating pressure is supplied to the filtration membrane at 10-20 atm, and the boron concentration is filtered below the drinking water standard of 0.3 mg / l. Deboron water is sent to the mineral mixing and neutralization process. III. Mineral modifier manufacturing stage 1. Evaporative Concentration Process of Mineral Water Containing Sulfate Ion In the nanofiltration process, unfiltered sulfuric acid-containing mineral water and part of the brine of the first reverse osmosis filtration process are introduced into the sulfate-ion-containing mineral water storage tank (13) of the evaporative concentration process by the sulfate-ion-containing mineral water transfer pump (14). Dry air in the air is discharged from the air by the exhaust fan 19 while spraying through the spray nozzle 18 on the top of the evaporation tower 17 together with the concentrated mineral water conveyed by the dehydration filtrate and the feed water transfer pump 23. 17) The water which is sucked from the lower part and flows in countercurrent contact with the sulfuric acid ion-containing mineral water and evaporates the water in the sulfuric acid ion-containing mineral water. Calcium sulfate (CaSO ₄ ), which is concentrated and deposited to 24 to 26 ° Be, while being sent to the storage tank 22 and returned to the upper part of the evaporation tower 17, precipitates under the precipitation tank 15, and precipitates the lake 16 Precipitation tank () 15) When the bottom portion of the condensate (Cone) is collected, the precipitated calcium sulfate is transferred to the dehydrator 21 by the transport conveyor conveyor 20, and the dehydration filtrate is sent to the dehydration filtrate and the poultry water storage tank 22, and the dehydration treatment is performed. Calcium sulfate is sent to the mineral adjustment tank 24 of the mineral adjustment process. 2. Mineral composition adjustment process The deep sea water is injected into the mineral composition adjusting tank 24, and calcium sulfate (CaSO ₄ ) is injected into the weight ratio of Ca / Mg in the range of 2 to 4, and the rotational speed of the mineral composition adjusting tank stirrer 25 of the propeller type is supplied. Is stirred at 180 to 360 RPM for 30 to 40 minutes to dissolve the calcium sulfate to adjust the mineral balance, and then sent to the desalination chamber 34 of the desalination process by the mineral composition adjusting water transfer pump 26. 3. Desalination Process The desalination electrodialysis apparatus 27 multi-stages the monovalent cation selective exchange diaphragm 33 and the monovalent anion selective exchange diaphragm 32 alternately between the positive electrode 28 and the negative electrode 29. The minerals in the mineral composition adjustment process while installing a plurality of currents and applying a direct current from the rectifier 38 to the anode 28 of the anode chamber 30 and the cathode 29 of the cathode chamber 31 at both ends. The balanced deep sea water is supplied to the desalination chamber 34 by the mineral composition adjustment water transfer pump 26 to desalination in the range of 400 to 800 mg / L of salt (monovalent salts of NaCl and KCl). Some are returned to the mineral composition adjusting tank 24, and the desalted mineral water (demineralized water) has a conductivity of the electric conductivity indicating switch (ECIS) in the range of 6 to 12 kV / cm, for example, a solenoid valve; Ⓢ) to send to the mineral water storage tank (39), the salt concentration chamber 35 to the brine of the brine storage tank (36) When circulated by the brine transfer pump 37, monovalent cations such as Na ⁺ and K ⁺ in the mineral water pass through the monovalent cation selective exchange diaphragm 33 by electrical attraction, and the salt concentration chamber on the cathode 28 side. And the Cl ⁻ ions pass through the monovalent anion selective exchange diaphragm 32 to the salt concentration chamber 35 toward the anode 28 to remove the salts (NaCl, KCl) while the salt water reservoir ( The brine concentrated in the range of 10-22 ° Be in the range of bomedo is sent to the salt and mineral salt manufacturing process by the solenoid valve (ⓢ) by the bomedo hydrometer BIS (Baume indicating switch). When the water level of 36) drops, the solenoid valve ⓢ is operated by a level switch LS installed in the brine reservoir 36 using demineralized water. 4. Sulfate Ion Removal Process After adjusting the mineral balance, the desulfated ions of the desulfurized ions mineral water storage tank 50 are supplied while the demineralized mineral water is supplied to the demineralization chamber 48 by the mineral water transfer pump 40 and returned to the mineral water storage tank 39. When mineral water is supplied to the mineral concentration chamber 49 by the desulfurized ion mineral water transfer pump 51 and circulated to the desulfurized ion mineral water storage tank 50, a direct current is applied from the rectifier 52 to demineralized ion chamber 48. All cations in the mineral water of c) pass through the cation selective exchange diaphragm 47 by electric attraction and move to the mineral concentration chamber 49 on the cathode 43 side, and the anion is divalent, such as sulfate ion. Only monovalent anions excluding the above ions are selectively moved to the mineral concentrating chamber 49. When only the mineral component and the monovalent anions in the mineral water are moved and the conductivity drops to 8 to 20 kW / cm, the conductivity indicator controller (ECIS; Electric conductivity indica The solenoid valve (ⓢ) is operated by a ting switch to send the sulfuric acid ion-containing water to the salt and mineral salt manufacturing process, and the minerals are separated and concentrated in the mineral concentration chamber 49 so as to supply the desulfurized ion mineral water storage tank 50. When the specific gravity is concentrated in the range of 10 to 24 ° Be, the solenoid valve (ⓢ) is operated by a Baume indicating switch (BIS) and sent to the additive mixing process, and the desulfurized ion mineral water storage tank 50 When the water level drops, demineralized water is supplied to the water level controller LS installed in the desulfurized ion mineral water storage tank 50 as water by the operation of the solenoid valve ⓢ. 5. Additive Mixing Process Mineral water from which sulfate ions (SO ₄ ^2- ) have been removed from the mineral water is introduced into the additive mixing tank of the additive mixing process, and trehalose (α-D-glucopyranosyl α-D-glucopyanoside) is added to the total mineral content of the mineral water at 0.3. It is injected into the range of -5wt%, and is supplied with an additive mixing agitator while supplying an aqueous solution in the range of 5-20wt%, which is mixed alone or in combination of two or more types of lactic acid, ascorbic acid and gluconic acid. The pH is added in the range of 4.5-5.5 with stirring for 0.5-2 hours. Ⅳ. Final beverage production stage 1. Mineral mixing and neutralization process In the mineral mixing and neutralization process, when deboron water from which the boron compound has been removed is introduced in the second reverse osmosis process, acid (HCl, neutralizing agent) is added to neutralize the pH to a range of 6-8, Adjust the mineral balance between calcium sulfate (CaSO ₄ ) and the weight ratio of Ca / Mg in the range of 2 to 6, and then remove trehalose, ascorbic acid, lactic acid, minerals from mineral water without salt (NaCl) and sulfate ion (SO ₄ ^2- ). Supplying a mineral regulator prepared in the form of an organic mineral salt by supplying an organic additive additive alone or mixed in two or more kinds of gluconic acid and adjusting the hardness by adjusting the electrical conductivity of an electrical conductivity indicating switch. Adjust to 50-300 mg / L range. 2. Sterilization, container filling, packaging and inspection process After adjusting hardness, sterilization process and high temperature sterilization at 120 ~ 135 ℃ for 0.5-10 minutes or UV sterilization can be sent to container filling process and filled into containers (cans or plastic bottles). To drink water. A method for producing a beverage from deep sea water by the above treatment process. The method according to claim 1, wherein the permanent magnet is magnetized in the range of 12,000 to 15,000 G (Gauss) instead of the voltage conductor tube magnetizer 10 of the water molecular treatment process. Method of producing a drink from deep water. The desulfuric acid according to claim 1, wherein in the mineral mixing and neutralization step, the desulfuric acid is removed without the use of a mineral modifier in which trehalose, ascorbic acid, lactic acid, and gluconic acid are added to desulfurized mineral water from which sulfate ions are removed. A method for producing beverages from deep sea water by using ion mineral water as a mineral modifier in mineral mixing and neutralization processes. The liquid desulfurized ion mineral water produced in the desulfurization ion removing process of claim 1 may also be used as a mineral additive in food, animal and fish feed, or the liquid desulfurized ion mineral water is evaporated and concentrated to produce a solid phase. Used as a mineral additive in food, animal and fish feed. The organic mineral salt in the liquid phase prepared in the additive mixing process of claim 1 may also be used as a mineral additive in the food, animal or fish feed, or the organic mineral salt in the liquid phase may be evaporated and concentrated to produce a solid food, animal or fish. To use as mineral additives in feed.

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