KR20060020450A - Composition of transparent and color paint and glass product for structural interior and facing produced by using the same - Google Patents

Composition of transparent and color paint and glass product for structural interior and facing produced by using the same Download PDF

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KR20060020450A
KR20060020450A KR1020040069294A KR20040069294A KR20060020450A KR 20060020450 A KR20060020450 A KR 20060020450A KR 1020040069294 A KR1020040069294 A KR 1020040069294A KR 20040069294 A KR20040069294 A KR 20040069294A KR 20060020450 A KR20060020450 A KR 20060020450A
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weight
parts
yellow
lake
pigment
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KR1020040069294A
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Korean (ko)
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윤동언
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윤동언
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/28—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material
    • C03C17/32—Surface treatment of glass, not in the form of fibres or filaments, by coating with organic material with synthetic or natural resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/01—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/541—Silicon-containing compounds containing oxygen
    • C08K5/5415—Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419—Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Paints Or Removers (AREA)

Abstract

본 발명은 투명칼라 도료 조성물 및 이를 이용하여 제조된 건축물 내외장용 유리제품에 관한 것으로, 자일렌 및 아크릴수지를 주원료로 하는 아크릴 수지 조성물(Acryl Varnish)를 제조하고 이를 기본 원료로 하여 안료를 첨가혼합함으로써 유리판을 기재로 하여 그 일면에 코팅하였을 때 투명한 색감과 윤기를 더할뿐만 아니라 오랜동안 태양광선에 노출되어도 색감과 질감이 변질되지 않고 가공 및 절단시 도포면이 일어나지 않는 건축물 내외장용 유리에 코팅하기 위한 투명칼라 도료 조성물과 이를 이용한 유리제품을 제공하는 매우 뛰어난 효과가 있다.The present invention relates to a transparent color coating composition and a glass product for building interior and exterior manufactured using the same, to prepare an acrylic resin composition (Acryl Varnish) containing xylene and acrylic resin as a main raw material, and to add and mix pigments as a basic raw material. By applying the glass plate as a base, it not only adds a transparent color and luster, but also coats the building interior and exterior glass where the color and texture do not change even when exposed to sunlight for a long time and the coated surface does not occur during processing and cutting. There is a very excellent effect of providing a transparent color coating composition and a glass product using the same.

도료, 투명도료, 건축용 유리제품, 내외장용 유리제품, 아크릴 수지 Paint, Transparent Paint, Glass Products for Building, Glass Products for Interior and Exterior, Acrylic Resin

Description

투명칼라 도료 조성물 및 이를 이용하여 제조된 건축물 내외장용 유리제품{Composition of transparent and color paint and glass product for structural interior and facing produced by using the same}Composition of transparent and color paint and glass product for structural interior and facing produced by using the same}

본 발명은 투명칼라 도료 조성물 및 이를 이용하여 제조된 건축용 내외장재 유리제품에 관한 것으로, 보다 상세하게는 유리판을 기재로 하여 그 일면에 코팅되어 투명한 색감과 윤기를 표현하는 건축물 내외장용 유리제품을 제조하기 위한 투명칼라 도료 조성물과 이를 이용한 유리제품에 관한 것이다.The present invention relates to a transparent color coating composition and a building interior and exterior glass articles manufactured using the same, and more particularly, to manufacture a building interior and exterior glass articles that are coated on one surface thereof based on a glass plate to express a transparent color and gloss. It relates to a transparent color coating composition and a glass product using the same.

칼라유리는 생산과정에서 색상을 첨가해 만들어지는 유리(미러.브론즈.그린등등), 도료(에폭시.우레탄)를 이용하여 제작되는 유리 및 600∼700℃ 정도의 온도에서 구워 만들어지는 세라믹 코팅유리로 구분할 수 있다.Colored glass is glass made by adding color in the production process (mirror, bronze, green, etc.), glass made using paint (epoxy and urethane), and ceramic coated glass made by baking at the temperature of 600 ~ 700 ℃. Can be distinguished.

생산과정에서 색상을 첨가한 유리는 용도가 한정되어 있고(외벽.샤시등) 도료를 이용하여 제작한 유리는 강한 빛에 노출시 갈라짐 현상과 색상변화가 있으며 습기에 약하고 가공 및 절단시 도포면이 일어나는 단점이 있다. 또한, 세라믹 코팅유리는 고온에서의 색상파손과 (채도가 떨어짐) 다양하지 못한 색상과 조색이 어렵고 투명성이 좋아 뒷면의 접착제가 비치는 단점이 있다.Glass that has added color in the production process is limited in its use (outer wall, chassis, etc.). Glass made with paint has cracking and color change when exposed to strong light. There are disadvantages. In addition, the ceramic coated glass has a disadvantage in that color breakage at high temperature (deterioration of saturation) and various color and toning are difficult and good transparency is reflected.

본 발명자는 상기 종래의 칼라유리가 가지는 단점을 극복하기 위해 자일렌 및 아크릴수지를 주원료로 하는 아크릴 수지 조성물(Acryl Varnish)를 제조하고 이를 기본 원료로 하여 안료를 첨가혼합함으로써 유리판을 기재로 하여 그 일면에 코팅하였을 때 다양한 색감과 질감을 표현할뿐만 아니라 오랜동안 태양광선에 노출되어도 색감과 질감이 변질되지 않고 가공 및 절단시 도포면이 일어나지 않는 건축물 내외장용 유리에 코팅하기 위한 투명칼라 도료 조성물과 이를 이용한 유리제품을 제조함으로써 본 발명을 완성하였다.MEANS TO SOLVE THE PROBLEM This inventor manufactures the acrylic resin composition (Acryl Varnish) which has xylene and an acrylic resin as a main raw material, and adds and mixes pigment as a basic raw material in order to overcome the disadvantage which the said conventional color glass has, When coated on one surface, not only expresses various colors and textures, but also color and texture do not change even when exposed to sunlight for a long time and the transparent color coating composition for coating on the interior and exterior glass of the building does not occur during processing and cutting and using the same The present invention has been completed by manufacturing glass articles.

따라서, 본 발명의 목적은 유리판을 기재로 하여 그 일면에 코팅되어 다양한 색감과 윤기를 더하는 건축물 내외장용 유리제품을 제조하기 위한 투명칼라 도료 조성물을 제공하는 데 있다.Accordingly, it is an object of the present invention to provide a transparent color coating composition for manufacturing glass products for interior and exterior building, which is coated on one surface of a glass plate to add various colors and shine.

본 발명의 또 다른 목적은 투명칼라 도료 조성물을 유리판 일면에 코팅함으로써 다양한 색감과 윤기를 더하는 유리제품을 제공하는 데 있다.Still another object of the present invention is to provide a glass product that adds a variety of colors and gloss by coating a transparent color coating composition on one surface of a glass plate.

본 발명의 상기 목적은 자일렌, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate), N-부틸아크릴레이트(N-Butylacrylate), 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate), 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 및 벤질퍼옥사이드(BO; Benzylperoxide)를 중합반응시킨 후 자일렌 및 벤질퍼옥사이드를 다시 일정량 첨가하여 중합반응시켜 아크릴 수지 조성물을 제조한 후 상기 아크릴 수지 조성물에 감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane), 블록 이소시아네이트(Block isocyanate; 상품명 D-660), 부틸아세테이트(Butyl acetate), 자일렌, 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 및 안료를 첨가혼합함으로써 투명칼라 도료 조성물을 제조하고 제조된 투명칼라 도료 조성물을 건축용 투명 판유리의 일면에 코팅함으로써 건축물 내외장용 유리제품을 제조하고 제조된 유리제품의 물성을 조사함으로써 달성하였다.The object of the present invention is xylene, methyl methacrylate (MMA; MethylMetaAcrylate), N- butyl acrylate (N-Butylacrylate), cyclohexyl methacrylate (CHMA; Cyclohexyl methacrylate), 2-hydroxyethyl acrylate (2-HEA; 2-Hydroxyethylacrylate) and benzyl peroxide (BO; Benzylperoxide) are polymerized to add an amount of xylene and benzyl peroxide again to polymerize to prepare an acrylic resin composition, and then gamma to the acrylic resin composition. Γ-methacryloxytriethoxy silane, Block isocyanate (tradename D-660), Butyl acetate, Xylene, Propylene glycol mono methyl ether A transparent color paint composition was prepared by adding and mixing acetate (PMA) and a pigment, and the prepared transparent color paint composition was used for building a transparent plate. By coating on the Li surface it was achieved by preparing the buildings within the exterior of glass and investigating the properties of a manufactured glass product.

이하 본 발명의 구성을 설명한다.Hereinafter, the configuration of the present invention.

본 발명은 자일렌, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate), N-부틸아크릴레이트(N-Butylacrylate), 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate), 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 및 벤질퍼옥사이드(BO; Benzylperoxide)를 중합반응시킨 후 자일렌 및 벤질퍼옥사이드를 다시 일정량 첨가하여 중합반응시켜 아크릴 수지 조성물을 제조하는 단계; 상기 단계에서 제조한 아크릴 수지 조성물에 감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane), 블록 이소시아네이트(Block isocyanate; 상품명 D-660), 부틸아세테이트(Butyl acetate), 자일렌, 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 및 안료를 첨가혼합함으로써 투명칼라 도료 조성물을 제조하는 단계; 상기 단계에서 제조한 투명칼라 도료 조성물을 건축용 투명 판유리의 일면에 코팅함으로써 건축물 내외장용 유리제품을 제조하는 단계; 및 상기 단계의 유리제품의 물성을 조사하는 단계로 구성된다.The present invention is xylene, methyl methacrylate (MMA; MethylMetaAcrylate), N- butyl acrylate (N-Butylacrylate), cyclohexyl methacrylate (CHMA; Cyclohexyl methacrylate), 2-hydroxyethyl acrylate (2- Preparing a acrylic resin composition by polymerizing HEA; 2-Hydroxyethylacrylate) and benzylperoxide (BO; Benzylperoxide), and then adding a predetermined amount of xylene and benzylperoxide again to polymerize; In the acrylic resin composition prepared in the above step, gamma-methacryloxytriethoxy silane, γ-methacryloxytriethoxy silane, Block isocyanate (trade name D-660), butyl acetate, xylene, propylene glycol Preparing a transparent color coating composition by adding and mixing monomethyl ether acetate (PMA) and a pigment; Manufacturing a glass product for building interior and exterior by coating the transparent color coating composition prepared in the step on one surface of a transparent glass plate for building; And investigating the physical properties of the glass article of the step.

본 발명은 자일렌 36.4중량부, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate) 17.3중량부, N-부틸아크릴레이트(N-Butylacrylate) 22중량부, 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate) 11중량부, 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 4.6중량부 및 벤질퍼옥사이드(BO; Benzylperoxide) 0.1중량부를 110℃에서 7시간 동안 중합반응시킨 후 자일렌 8.2중량부 및 벤질퍼옥사이드 0.4중량부를 첨가하여 다시 2시간 동안 중합반응시켜 얻은 아크릴 수지 조성물 55중량부에In the present invention, 36.4 parts by weight of xylene, 17.3 parts by weight of methyl methacrylate (MMA), 22 parts by weight of N-butyl acrylate (N-Butylacrylate), 11 parts by weight of cyclohexyl methacrylate (CHMA; Cyclohexyl methacrylate) Part, 4.6 parts by weight of 2-hydroxyethyl acrylate (2-HEA; 2-Hydroxyethylacrylate) and 0.1 parts by weight of benzylperoxide (BO; Benzylperoxide) were polymerized at 110 ° C. for 7 hours, and then 8.2 parts by weight of xylene and benzyl 55 parts by weight of an acrylic resin composition obtained by adding 0.4 parts by weight of peroxide and polymerizing again for 2 hours.

감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane) 1중량부, 블록 이소시아네이트(Block isocyanate; 상품명 D-660) 24.8중량부, 부틸아세테이트(Butyl acetate) 10중량부, 자일렌 7.2중량부 및 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 2중량부를 첨가혼합함으로써 얻은 투명도료조성물을 제공한다.1 part by weight of gamma-methacryloxytriethoxy silane, 24.8 parts by weight of block isocyanate (tradename D-660), 10 parts by weight of butyl acetate, 7.2 parts by weight of xylene And it provides a transparent coating composition obtained by adding and mixing 2 parts by weight of propylene glycol mono methyl ether acetate (PMA).

상기 투명도료조성물에 안료를 0.1중량부 추가 혼합함으로써 투명칼라 도료 조성물을 제공할 수 있다.By adding 0.1 parts by weight of a pigment to the transparent coating composition can be provided with a transparent color coating composition.

본 발명은 또한 자일렌 36.4중량부, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate) 17.3중량부, N-부틸아크릴레이트(N-Butylacrylate) 22중량부, 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate) 11중량부, 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 4.6중량부 및 벤질퍼옥사이드(BO; Benzylperoxide) 0.1중량부를 110℃에서 7시간 동안 중합반응시킨 후 자일렌 8.2중량부 및 벤질퍼옥사이드 0.4중량부를 첨가하여 다시 2시간 동안 중합반응 시켜 얻은 아크릴 수지 조성물 55중량부에The present invention also provides 36.4 parts by weight of xylene, 17.3 parts by weight of methyl methacrylate (MMA), 22 parts by weight of N-butyl acrylate (N-Butylacrylate), cyclohexyl methacrylate (CHMA; Cyclohexyl methacrylate) 11 Parts by weight, 4.6 parts by weight of 2-hydroxyethyl acrylate (2-HEA; 2-Hydroxyethylacrylate) and 0.1 parts by weight of benzylperoxide (BO; Benzylperoxide) after polymerization at 110 ℃ for 7 hours, 8.2 parts by weight of xylene and 55 parts by weight of an acrylic resin composition obtained by adding 0.4 parts by weight of benzyl peroxide and polymerizing again for 2 hours.

감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane) 1중량부, 블록 이소시아네이트(Block isocyanate; 상품명 D-660) 24.8중량부, 부틸아세테이트(Butyl acetate) 10중량부, 자일렌 7.2중량부 및 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 2중량부를 첨가혼합함으로써 얻은 투명도료조성물을 투명 판유리의 일면에 코팅하여 얻은 건축물 내외장용 유리제품을 제공한다. 더 나아가, 상기 투명도료조성물에 안료 0.1중량부를 추가 혼합하여 얻은 투명칼라 도료 조성물을 판유리의 일면에 코팅하여 투명칼라의 건축물 내외장용 유리제품을 제공할 수 있다. 1 part by weight of gamma-methacryloxytriethoxy silane, 24.8 parts by weight of block isocyanate (tradename D-660), 10 parts by weight of butyl acetate, 7.2 parts by weight of xylene And a transparent paint composition obtained by adding and mixing 2 parts by weight of propylene glycol mono methyl ether acetate (PMA) on one surface of a transparent plate glass to provide a building interior and exterior glassware. Furthermore, the transparent color coating composition obtained by additionally mixing 0.1 part by weight of the pigment in the transparent coating composition may be coated on one surface of the plate glass to provide a glass product for building interior and exterior of the transparent color.

본 발명에서 사용하는 안료로는 당업계에 알려진 일반적인 유기안료를 사용할 수 있으며 예를 들면 염료계 안료로서 로더민레이크, 메틸바이올렛레이크, 키놀린옐로우레이크, 말라카이트그린레이크 및 알리자린레이크; 아조계 안료로서 카민6B, 레이크레드C, 디스아조옐로우, 레이크레드4R, 크로모프탈 예로우3G, 크로모프탈 스카레드RN, 니켈아조옐로우 및 퍼머넌트오렌지 HL; 프탈로시아닌안료로서 프탈로시아닌블루 및 프탈로시아닌그린; 축합다환안료로서 플라반스론옐로우, 지오인디고볼드, 페리논오렌지, 페릴렌레드, 디옥사딘바이올렛, 키나크리든레드 및 이소인돌린옐로우; 니트로계안료로서 내프톨옐로우S; 니트로소계안료로서 퍼그먼트그린B, 주야형광안료로서 루모겐 옐로우 및 시그널레드; 알칼리블루; 그리고 아닐라블랙 등이 있다.As the pigments used in the present invention, general organic pigments known in the art may be used. Examples of the pigments include dyes of pigments such as Laudermin Lake, Methyl Violet Lake, Chinoline Yellow Lake, Malachite Green Lake, and Alizarin Lake; Carmine 6B, lake red C, disazo yellow, lake red 4R, chromophthal yellow 3G, chromophthal scarred RN, nickel azo yellow and permanent orange HL as azo pigments; Phthalocyanine blue and phthalocyanine green as phthalocyanine pigments; As condensed polycyclic pigments, flavans ron yellow, geoindigobold, perinone orange, perylene red, dioxadine violet, quinacridin red and isoindolin yellow; Naphthol yellow S as a nitro pigment; Pigment green B as a nitroso pigment, lumogen yellow and signal red as day and night fluorescent pigments; Alkali blue; And Anila Black.

무기안료의 경우 색감을 탁하게 하여 투명한 효과를 주기 어려우므로 유기안 료를 사용하는 것이 바람직하다.In the case of inorganic pigments, it is preferable to use organic pigments because it is difficult to give a transparent effect by turbid color.

본 발명의 투명도료조성물의 코팅 방법은 당업계에 알려진 일반적인 코팅 방법으로써 스프레이법, 정전코팅법, 딥코팅법, 롤코팅법, 플로우코팅법, 붓칠 등 모두를 사용할 수 있다.The coating method of the transparent coating composition of the present invention can be used as a general coating method known in the art, spray method, electrostatic coating method, dip coating method, roll coating method, flow coating method, brushing and the like.

본 발명의 투명도료조성물은 유리의 일면에 코팅된 후 경화되어질 수 있다. 이때 경화방법으로는 컨베어식 또는 벨트타입의 LPG, 석유, 전기 방식의 연속오븐, 배치타입의 박스오븐, 메카니컬 콘벡션 오븐, 항온항습조 등 최고 180℃까지 승온 가능한 가열 방식이면 모두 가능하다.The transparent coating composition of the present invention may be cured after coating on one side of the glass. At this time, as the curing method, any heating method capable of heating up to 180 ° C., such as a conveyor type or belt type LPG, petroleum, electric continuous oven, batch type box oven, mechanical convection oven, and a constant temperature / humidity bath, is possible.

이하, 본 발명을 실시예에 의해 상세히 설명하나, 본 발명의 단순한 변형 또는 변경이 이 분야의 통상의 지식을 가진 자에 의하여 용이하게 실시될 수 있으며 이러한 변형이나 변경은 모두 본 발명의 영역에 포함되는 것으로 볼 수 있다.Hereinafter, the present invention will be described in detail by way of examples, but simple modifications or changes of the present invention can be easily carried out by those skilled in the art, and all such modifications or changes are included in the scope of the present invention. It can be seen as.

실시예 1: 아크릴 수지 조성물의 제조Example 1: Preparation of Acrylic Resin Composition

자일렌 36.4중량부, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate) 17.3중량부, 노말-부틸아크릴레이트(N-Butylacrylate) 22중량부, 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate) 11중량부, 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 4.6중량부 및 벤질퍼옥사이드(BO; Benzylperoxide) 0.1중량부를 110℃에서 7시간 동안 중합반응시킨 후 자일렌 8.2중량 및 벤질퍼옥사이드 0.4중량부를 첨가하여 다시 2시간 동안 중합반응시켜 아크릴 수지 조성물을 제조하였다. 아크릴 수지 조성물은 안료를 포함하고 있지 않아 실질적으로 투명한 수지의 형태이었으며 점도는 81Ku이었다. 아크릴 수지 조성물의 배합예를 하기 표 1에 나타내었다.Xylene 36.4 parts, MMA (MethylMetaAcrylate) 17.3 parts by weight, 22 parts by weight of normal butyl acrylate (N-Butylacrylate), 11 parts by weight of cyclohexyl methacrylate (CHMA; 4.6 parts by weight of hydroxyethyl acrylate (2-HEA; 2-Hydroxyethylacrylate) and 0.1 parts by weight of benzylperoxide (BO; Benzylperoxide) were polymerized at 110 ° C. for 7 hours, and 8.2 weights of xylene and 0.4 weight of benzylperoxide. The addition was carried out and further polymerized for 2 hours to prepare an acrylic resin composition. The acrylic resin composition was free of pigments and was in the form of a substantially transparent resin with a viscosity of 81Ku. A blending example of the acrylic resin composition is shown in Table 1 below.

구성성분Ingredient 배합비(중량부)Compounding ratio (part by weight) 자일렌Xylene 44.644.6 메틸메타아크릴레이트Methyl methacrylate 17.317.3 노말-부틸아크릴레이트Normal-Butylacrylate 2222 시클로헥실메타아클릴레이트Cyclohexyl methacrylate 1111 2-하이드록시에틸아크릴레이트2-hydroxyethyl acrylate 4.64.6 벤질퍼옥사이드Benzyl peroxide 0.50.5

실시예 2: 본 발명 투명도료조성물의 제조Example 2 Preparation of the Invention Transparent Coating Composition

상기 실시예 1에서 제조한 아크릴 수지 조성물 55중량부에 감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane; 상품명 KBM 503) 1중량부, 블록 이소시아네이트(Block isocyanate; 상품명 D-660) 24.8중량부, 부틸아세테이트(Butyl acetate) 10중량부, 자일렌 7.2중량부 및 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 2중량부를 순서대로 첨가한 후 교반하여 혼합함으로써 투명도료조성물을 제조하였다. 제조된 도료조성물은 무색을 띠는 수지의 형태이었으며 점도는 85Ku이었다. 본 발명 투명도료조성물의 구체적인 배합예를 하기 표 2에 나타내었다.55 parts by weight of the acrylic resin composition prepared in Example 1, 1 part by weight of gamma-methacryloxytriethoxy silane (γ-methacryloxytriethoxy silane; trade name KBM 503), Block isocyanate (trade name D-660) 24.8 Part by weight, 10 parts by weight of butyl acetate, 7.2 parts by weight of xylene, and 2 parts by weight of propylene glycol mono methyl ether acetate (PMA) were added in this order, followed by stirring and mixing to form a transparent coating composition. Was prepared. The paint composition prepared was in the form of a colorless resin with a viscosity of 85Ku. Specific blending examples of the transparent coating composition of the present invention are shown in Table 2 below.

구성성분Ingredient 배합비(중량부)Compounding ratio (part by weight) 아크릴 수지 조성물Acrylic resin composition 55.055.0 감마-메타아크록시프로필트리에톡시 실란Gamma-Metaoxypropyltriethoxy silane 1.01.0 블록 이소시아네이트Block isocyanate 24.824.8 부틸아세테이트Butyl acetate 10.010.0 자일렌Xylene 7.27.2 프로필렌 글리콜 모노 메틸 에테르 아세테이트Propylene Glycol Monomethyl Ether Acetate 2.02.0

실시예 3: 본 발명 투명칼라 도료 조성물의 제조Example 3 Preparation of the Invention Transparent Color Coating Composition

상기 실시예 2에서 제조한 투명도료조성물에 시아닌블루를 추가혼합하여 탁하지 않고 투명한 청색의 도료조성물을 제조하였다. 제조된 도료조성물은 청색을 띠는 수지의 형태이었으며 점도는 84Ku이었다. 본 발명 투명칼라도료조성물의 구체적인 배합예를 하기 표 3에 나타내었다.Cyanine blue was further mixed with the transparent paint composition prepared in Example 2 to prepare a transparent blue paint composition. The prepared paint composition was in the form of a blue resin, and the viscosity was 84Ku. Specific blending examples of the transparent color paint composition of the present invention are shown in Table 3 below.

구성성분Ingredient 배합비(중량부)Compounding ratio (part by weight) 아크릴 수지 조성물Acrylic resin composition 55.055.0 감마-메타아크록시프로필트리에톡시 실란Gamma-Metaoxypropyltriethoxy silane 1.01.0 블록 이소시아네이트Block isocyanate 24.824.8 부틸아세테이트Butyl acetate 10.010.0 자일렌Xylene 7.27.2 프로필렌 글리콜 모노 메틸 에테르 아세테이트Propylene Glycol Monomethyl Ether Acetate 2.02.0 프탈로시아닌블루Phthalocyanine Blue 0.10.1

실시예 4: 본 발명 투명도료조성물을 이용한 유리제품 제조Example 4 Glass Product Preparation Using the Invention Transparent Coating Composition

상기 실시예 2에서 제조한 본 발명 투명도료조성물을 건축용 투명 판유리의 일면에 스프레이법으로 코팅한 후 배치타입의 박스오븐을 이용하여 경화시킴으로써 건축물 내외장용 유리제품을 제조하였다.The transparent coating composition of the present invention prepared in Example 2 was coated on one surface of a transparent glass plate for building by spraying, and then cured using a batch type box oven to manufacture a glass product for building interior and exterior.

실시예 5: 본 발명 투명칼라 도료 조성물을 이용한 유리제품 제조Example 5 Glass Production Using the Invention Transparent Color Coating Composition

상기 실시예 3에서 제조한 본 발명 투명칼라 도료 조성물을 건축용 투명 판유리의 일면에 스프레이법으로 코팅한 후 배치타입의 박스오븐을 이용하여 경화시킴으로써 건축물 내외장용 유리제품을 제조하였다.The transparent color coating composition of the present invention prepared in Example 3 was coated on one surface of a transparent glass plate for building by spraying, and then cured using a batch-type box oven to manufacture a building interior and exterior glassware.

실험예 1: 본 발명 투명도료조성물을 이용한 유리제품의 물성 조사Experimental Example 1 Investigation of Physical Properties of Glass Product Using Inventive Transparent Coating Composition

상기 실시예 4에서 제조한 유리제품의 물성을 하기 표 4에 기재된 방법에 따라 조사한 후 그 결과를 표 4에 함께 기재하였다.The physical properties of the glassware prepared in Example 4 were investigated according to the method described in Table 4 below, and the results are shown in Table 4 together.

본 발명 투명도료조성물을 이용한 유리제품의 물성조사 방법 및 결과Physical properties investigation method and result of glass product using transparent coating composition of the present invention 항목Item 조사 방법Survey method 조사 결과result 공업 규격Industrial standard 촉진내후성Weathering resistance 선샤인 카복 아크(sunshine carbon arc)/5000시간후 색차(ΔE) 및 광택 감소율(ΔG) 측정Determination of color difference (ΔE) and gloss reduction (ΔG) after 5000 hours of sunshine carbon arc ΔE: 0.3 ΔG: 2.9ΔE: 0.3 ΔG: 2.9 KS M 5982, JIS K 5400 9.8.2, JIS B 7753, ASTM D 4587KS M 5982, JIS K 5400 9.8.2, JIS B 7753, ASTM D 4587 연필경도Pencil hardness 시험기로 1kgf힘으로 1cm/sec의 속도로 10mm 그어 5회 반복 후 상처 1회 이하10 mm at a speed of 1 cm / sec with 1 kg f force with a tester 9H 이상9H or more KS D 6711, JIS K 5400 8.4.1(5)(b)KS D 6711, JIS K 5400 8.4.1 (5) (b) 부착성Adhesion 크로스 컷 가이드(Cross Cut Guide)로 1mm 간격으로 가로, 세로 11개선을 그어 셀로판 테이프로 박리Draw 11 horizontal and vertical lines at 1mm interval with Cross Cut Guide and peel off with cellophane tape 100/100100/100 KS D 6711, JIS K 5400 8.5.2, JIS B 7753KS D 6711, JIS K 5400 8.5.2, JIS B 7753 내충격성Impact resistance 500g 스틸 볼(steel ball)을 50cm에서 낙하/시험편양면500g steel ball dropped from 50 cm ○○ KS D 6711, JIS K 5400 8.3.2KS D 6711, JIS K 5400 8.3.2 내산성Acid resistance 5% 황산 침적/120시간5% sulfuric acid deposition / 120 hours ○○ KS D 6711, JIS K 5400 8.22KS D 6711, JIS K 5400 8.22 내알카리성Alkali resistance 5% 탄산나트륨 침적/120시간5% Sodium Carbonate Deposition / 120 Hours ○○ KS M 5000, JIS K 5400KS M 5000, JIS K 5400 난연성Flame retardant 주열원: 전열 1.5kw + 부열원:프로판가스 350cc/min, 10분 발열계수Main heat source: Electric heat 1.5kw + Sub-heat source: Propane gas 350cc / min, 10 minutes heating coefficient 난연 1급Flame retardant class 1 KS F 2271KS F 2271 내열성Heat resistance 300℃/ 720시간300 ℃ / 720 hours ○○ JIS K 5400 8.13JIS K 5400 8.13 내한열성Cold resistance -20℃ 2시간 ↔ 60℃ 2시간/ 500회-20 ℃ 2 hours ↔ 60 ℃ 2 hours / 500 times ○○ KS M 5000, JIS A 6910KS M 5000, JIS A 6910 내자외선성UV-resistant 자외선 램프(일본 도시바(주) 제품, 블랙라이트 4W FL4BL-B)를 수직 5cm 거리에 놓고 128시간 조사Place UV lamp (Toshiba, Japan, black light 4W FL4BL-B) at a distance of 5 cm vertical for 128 hours ○○ 변색촉진시험Discoloration promotion test 60℃ 10% 질산용액에 10일간 침적 변색 유무 확인Check for 10 days of deposition discoloration in 10% nitric acid solution at 60 ℃ ○○ 절단면 조사Cut surface probe 절단 후 도포면이 일어나는 지 조사Investigate whether the coating surface occurs after cutting 절단시 도포면 일어나지 않음No coating surface occurs during cutting [주] 1. KS: 한국 공업 규격, JIS: 일본 공업 규격, ASTM: 미국 공업 규격 2. 물성 결과 중 '○'는 이상없음 또는 변색없음을 나타낸다.1. KS: Korean Industrial Standards, JIS: Japanese Industrial Standards, ASTM: American Industrial Standards 2. In the physical properties, '○' indicates no abnormality or no discoloration.

상기 표 4의 결과를 통하여 확인할 수 있듯이 본 발명 투명도료조성물로 코팅된 유리제품은 물리화학적 물성에 있어서 이상이 없이 공업 규격에 적합하며 자외선 등의 광선을 조사한 후에도 광택 저하 등이 발생하지 않으며 질감이 유지됨을 알 수 있었다. 또한, 절단시 도포면이 일어나는 현상이 없었다.As can be seen from the results of Table 4, the glass article coated with the transparent coating composition of the present invention is suitable for industrial standards without abnormalities in physical and chemical properties. It was found to be maintained. In addition, there was no phenomenon that the coated surface during cutting.

실험예 2: 본 발명 투명칼라 도료 조성물을 이용한 유리제품의 물성 조사Experimental Example 2: Investigation of the physical properties of the glass product using the present invention transparent color coating composition

상기 실시예 5에서 제조한 유리제품의 물성을 하기 표 5에 기재된 방법에 따 라 조사한 후 그 결과를 표 5에 함께 기재하였다.The physical properties of the glassware prepared in Example 5 were investigated according to the method described in Table 5 below, and the results are shown in Table 5 together.

본 발명 투명칼라 도료 조성물을 이용한 유리제품의 물성조사 방법 및 결과Physical properties investigation method and result of glass product using transparent color coating composition of the present invention 항목Item 조사 방법Survey method 조사 결과result 공업 규격Industrial standard 촉진내후성Weathering resistance 선샤인 카복 아크(sunshine carbon arc)/5000시간후 색차(ΔE) 및 광택 감소율(ΔG) 측정Determination of color difference (ΔE) and gloss reduction (ΔG) after 5000 hours of sunshine carbon arc ΔE: 0.2 ΔG: 2.7ΔE: 0.2 ΔG: 2.7 KS M 5982, JIS K 5400 9.8.2, JIS B 7753, ASTM D 4587KS M 5982, JIS K 5400 9.8.2, JIS B 7753, ASTM D 4587 연필경도Pencil hardness 시험기로 1kgf힘으로 1cm/sec의 속도로 10mm 그어 5회 반복 후 상처 1회 이하10 mm at a speed of 1 cm / sec with 1 kg f force with a tester 9H 이상9H or more KS D 6711, JIS K 5400 8.4.1(5)(b)KS D 6711, JIS K 5400 8.4.1 (5) (b) 부착성Adhesion 크로스 컷 가이드(Cross Cut Guide)로 1mm 간격으로 가로, 세로 11개선을 그어 셀로판 테이프로 박리Draw 11 horizontal and vertical lines at 1mm interval with Cross Cut Guide and peel off with cellophane tape 100/100100/100 KS D 6711, JIS K 5400 8.5.2, JIS B 7753KS D 6711, JIS K 5400 8.5.2, JIS B 7753 내충격성Impact resistance 500g 스틸 볼(steel ball)을 50cm에서 낙하/시험편양면500g steel ball dropped from 50 cm ○○ KS D 6711, JIS K 5400 8.3.2KS D 6711, JIS K 5400 8.3.2 내산성Acid resistance 5% 황산 침적/120시간5% sulfuric acid deposition / 120 hours ○○ KS D 6711, JIS K 5400 8.22KS D 6711, JIS K 5400 8.22 내알카리성Alkali resistance 5% 탄산나트륨 침적/120시간5% Sodium Carbonate Deposition / 120 Hours ○○ KS M 5000, JIS K 5400KS M 5000, JIS K 5400 난연성Flame retardant 주열원: 전열 1.5kw + 부열원:프로판가스 350cc/min, 10분 발열계수Main heat source: Electric heat 1.5kw + Sub-heat source: Propane gas 350cc / min, 10 minutes heating coefficient 난연 1급Flame retardant class 1 KS F 2271KS F 2271 내열성Heat resistance 300℃/ 720시간300 ℃ / 720 hours ○○ JIS K 5400 8.13JIS K 5400 8.13 내한열성Cold resistance -20℃ 2시간 ↔ 60℃ 2시간/ 500회-20 ℃ 2 hours ↔ 60 ℃ 2 hours / 500 times ○○ KS M 5000, JIS A 6910KS M 5000, JIS A 6910 내자외선성UV-resistant 자외선 램프(일본 도시바(주) 제품, 블랙라이트 4W FL4BL-B)를 수직 5cm 거리에 놓고 128시간 조사Place UV lamp (Toshiba, Japan, black light 4W FL4BL-B) at a distance of 5 cm vertical for 128 hours ○○ 변색촉진시험Discoloration promotion test 60℃ 10% 질산용액에 10일간 침적 변색 유무 확인Check for 10 days of deposition discoloration in 10% nitric acid solution at 60 ℃ ○○ 절단면 조사Cut surface probe 절단 후 도포면이 일어나는 지 조사Investigate whether the coating surface occurs after cutting 절단시 도포면 일어나지 않음No coating surface occurs during cutting [주] 1. KS: 한국 공업 규격, JIS: 일본 공업 규격, ASTM: 미국 공업 규격 2. 물성 결과 중 '○'는 이상없음 또는 변색없음을 나타낸다.1. KS: Korean Industrial Standards, JIS: Japanese Industrial Standards, ASTM: American Industrial Standards 2. In the physical properties, '○' indicates no abnormality or no discoloration.

상기 표 5의 결과를 통하여 확인할 수 있듯이 본 발명 투명칼라 도료 조성물로 코팅된 유리제품은 물리화학적 물성에 있어서 이상이 없이 공업 규격에 적합하며 자외선 등의 광선을 조사한 후에도 변색이나 광택 저하 등이 발생하지 않으며 색감과 질감이 유지됨을 알 수 있었다. 또한, 절단시 도포면이 일어나는 현상이 없 었다.As can be seen from the results of Table 5, the glass article coated with the present invention transparent color coating composition is suitable for industrial standards without abnormalities in physical and chemical properties, and does not cause discoloration or gloss reduction even after irradiation with ultraviolet rays or the like. Color and texture were maintained. In addition, there was no phenomenon that the coated surface during cutting.

이상 상기에서 살펴본 바와 같이 본 발명 투명도료조성물은 자일렌 및 아크릴수지를 주원료로 하는 아크릴 수지 조성물(Acryl Varnish)를 제조하고 이를 기본 원료로 하여 안료를 첨가혼합함으로써 유리판을 기재로 하여 그 일면에 코팅하였을 때 다양한 색감과 질감을 표현할뿐만 아니라 오랜동안 태양광선에 노출되어도 색감과 질감이 변질되지 않고 가공 및 절단시 도포면이 일어나지 않는 건축물 내외장용 유리에 코팅하기 위한 투명칼라 도료 조성물과 이를 이용한 유리제품을 제공하는 매우 뛰어난 효과가 있으므로 도료산업 및 건축산업상 매우 유용한 것이다.As described above, the transparent coating composition of the present invention prepares an acrylic resin composition (Acryl Varnish) containing xylene and an acrylic resin as a main raw material, and adds and mixes a pigment based on the base material to coat the surface on a glass plate. In addition to expressing various colors and textures, the transparent color coating composition and glass products using the same for coating on interior and exterior glass of buildings where color and texture do not deteriorate even when exposed to sunlight for a long time and coating surface does not occur during processing and cutting It is very useful for the paint industry and construction industry because it has a very good effect.

Claims (4)

자일렌 36.4중량부, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate) 17.3중량부, 노말-부틸아크릴레이트(N-Butylacrylate) 22중량부, 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate) 11중량부, 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 4.6중량부 및 벤질퍼옥사이드(BO; Benzylperoxide) 0.1중량부를 110℃에서 7시간 동안 중합반응시킨 후 자일렌 8.2중량부 및 벤질퍼옥사이드 0.4중량부를 첨가하여 다시 2시간 동안 중합반응시켜 얻은 아크릴 수지 조성물 55중량부에Xylene 36.4 parts, MMA (MethylMetaAcrylate) 17.3 parts by weight, 22 parts by weight of normal butyl acrylate (N-Butylacrylate), 11 parts by weight of cyclohexyl methacrylate (CHMA; 4.6 parts by weight of hydroxyethyl acrylate (2-HEA; 2-Hydroxyethylacrylate) and 0.1 parts by weight of benzylperoxide (BO; Benzylperoxide) were polymerized at 110 ° C. for 7 hours, and 8.2 parts by weight of xylene and benzyl peroxide 0.4 To 55 parts by weight of the acrylic resin composition obtained by adding a part by weight and polymerizing again for 2 hours 감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane) 1중량부, 블록 이소시아네이트(Block isocyanate) 24.8중량부, 부틸아세테이트(Butyl acetate) 10중량부, 자일렌 7.2중량부, 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 2중량부 및 안료 0.1중량부를 첨가혼합함으로써 얻은 투명칼라 도료 조성물.1 part by weight of gamma-methacryloxytriethoxy silane, 24.8 parts by weight of block isocyanate, 10 parts by weight of butyl acetate, 7.2 parts by weight of xylene, propylene glycol monomethyl A transparent color coating composition obtained by adding and mixing 2 parts by weight of ether glycol monomethyl ether acetate (PMA) and 0.1 part by weight of a pigment. 제 1항에 있어서, 상기 안료는 염료계 안료로서 로더민레이크, 메틸바이올렛레이크, 키놀린옐로우레이크, 말라카이트그린레이크 및 알리자린레이크; 아조계 안료로서 카민6B, 레이크레드C, 디스아조옐로우, 레이크레드4R, 크로모프탈 예로우3G, 크로모프탈 스카레드RN, 니켈아조옐로우 및 퍼머넌트오렌지 HL; 프탈로시아닌안료로서 프탈로시아닌블루 및 프탈로시아닌그린; 축합다환안료로서 플라반스론옐 로우, 지오인디고볼드, 페리논오렌지, 페릴렌레드, 디옥사딘바이올렛, 키나크리든레드 및 이소인돌린옐로우; 니트로계안료로서 내프톨옐로우S; 니트로소계안료로서 퍼그먼트그린B, 주야형광안료로서 루모겐 옐로우 및 시그널레드; 알칼리블루; 그리고 아닐라블랙으로 이루어진 그룹 중에서 선택되는 어느 하나 이상임을 특징으로 하는 투명칼라 도료 조성물.The method of claim 1, wherein the pigment is a dye-based pigments such as Laudermin Lake, Methyl Violet Lake, Kyolin Yellow Lake, Malachite Green Lake and Alizarin Lake; Carmine 6B, lake red C, disazo yellow, lake red 4R, chromophthal yellow 3G, chromophthal scarred RN, nickel azo yellow and permanent orange HL as azo pigments; Phthalocyanine blue and phthalocyanine green as phthalocyanine pigments; As condensed polycyclic pigments, flavansron yellow, geoindigobold, perinone orange, perylene red, dioxadine violet, kinacreden red and isoindolin yellow; Naphthol yellow S as a nitro pigment; Pigment green B as a nitroso pigment, lumogen yellow and signal red as day and night fluorescent pigments; Alkali blue; And transparent color coating composition, characterized in that any one or more selected from the group consisting of anila black. 자일렌 36.4중량부, 메틸메타아크릴레이트(MMA; MethylMetaAcrylate) 17.3중량부, 노말-부틸아크릴레이트(N-Butylacrylate) 22중량부, 시클로헥실메타아클릴레이트(CHMA; Cyclohexyl methacrylate) 11중량부, 2-하이드록시에틸아크릴레이트(2-HEA; 2-Hydroxyethylacrylate) 4.6중량부 및 벤질퍼옥사이드(BO; Benzylperoxide) 0.1중량부를 110℃에서 7시간 동안 중합반응시킨 후 자일렌 8.2중량부 및 벤질퍼옥사이드 0.4중량부를 첨가하여 다시 2시간 동안 중합반응시켜 얻은 아크릴 수지 조성물 55중량부에Xylene 36.4 parts, MMA (MethylMetaAcrylate) 17.3 parts by weight, 22 parts by weight of normal butyl acrylate (N-Butylacrylate), 11 parts by weight of cyclohexyl methacrylate (CHMA; 4.6 parts by weight of hydroxyethyl acrylate (2-HEA; 2-Hydroxyethylacrylate) and 0.1 parts by weight of benzylperoxide (BO; Benzylperoxide) were polymerized at 110 ° C. for 7 hours, and 8.2 parts by weight of xylene and benzyl peroxide 0.4 To 55 parts by weight of the acrylic resin composition obtained by adding a part by weight and polymerizing again for 2 hours 감마-메타아크록시프로필트리에톡시 실란(γ-methacryloxytriethoxy silane) 1중량부, 블록 이소시아네이트(Block isocyanate) 24.8중량부, 부틸아세테이트(Butyl acetate) 10중량부, 자일렌 7.2중량부, 프로필렌 글리콜 모노 메틸 에테르 아세테이트(Propylene glycol mono methyl ether acetate; P.M.A.) 2중량부 및 안료 0.1중량부를 첨가혼합함으로써 얻은 투명칼라 도료 조성물을 투명 유리의 일면에 코팅하여 얻은 건축물 내외장용 투명칼라 유리제품.1 part by weight of gamma-methacryloxytriethoxy silane, 24.8 parts by weight of block isocyanate, 10 parts by weight of butyl acetate, 7.2 parts by weight of xylene, propylene glycol monomethyl A transparent color glass product for building interior and exterior obtained by coating a transparent color coating composition obtained by adding and mixing 2 parts by weight of ether glycol monomethyl ether acetate (PMA) and 0.1 part by weight of a pigment. 제 3항에 있어서, 상기 안료는 염료계 안료로서 로더민레이크, 메틸바이올렛레이크, 키놀린옐로우레이크, 말라카이트그린레이크 및 알리자린레이크; 아조계 안료로서 카민6B, 레이크레드C, 디스아조옐로우, 레이크레드4R, 크로모프탈 예로우3G, 크로모프탈 스카레드RN, 니켈아조옐로우 및 퍼머넌트오렌지 HL; 프탈로시아닌안료로서 프탈로시아닌블루 및 프탈로시아닌그린; 축합다환안료로서 플라반스론옐로우, 지오인디고볼드, 페리논오렌지, 페릴렌레드, 디옥사딘바이올렛, 키나크리든레드 및 이소인돌린옐로우; 니트로계안료로서 내프톨옐로우S; 니트로소계안료로서 퍼그먼트그린B, 주야형광안료로서 루모겐 옐로우 및 시그널레드; 알칼리블루; 그리고 아닐라블랙으로 이루어진 그룹 중에서 선택되는 어느 하나 이상임을 특징으로 하는 건축물 내외장용 투명칼라 유리제품.4. The pigment of claim 3, wherein the pigment is a dye-based pigment such as Laudermin Lake, Methyl Violet Lake, Chinoline Yellow Lake, Malachite Green Lake and Alizarin Lake; Carmine 6B, lake red C, disazo yellow, lake red 4R, chromophthal yellow 3G, chromophthal scarred RN, nickel azo yellow and permanent orange HL as azo pigments; Phthalocyanine blue and phthalocyanine green as phthalocyanine pigments; As condensed polycyclic pigments, flavans ron yellow, geoindigobold, perinone orange, perylene red, dioxadine violet, quinacridin red and isoindolin yellow; Naphthol yellow S as a nitro pigment; Pigment green B as a nitroso pigment, lumogen yellow and signal red as day and night fluorescent pigments; Alkali blue; And transparent color glass products for building interior and exterior, characterized in that any one or more selected from the group consisting of anila black.
KR1020040069294A 2004-08-31 2004-08-31 Composition of transparent and color paint and glass product for structural interior and facing produced by using the same KR20060020450A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100800417B1 (en) * 2006-05-10 2008-02-01 김인열 A light and insect proof composition for being coated on glass, a coated layer using the same and a preparation method thereof
KR101315318B1 (en) * 2011-06-22 2013-10-08 케이에스케미칼 주식회사 Coating composition for vehicle

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100800417B1 (en) * 2006-05-10 2008-02-01 김인열 A light and insect proof composition for being coated on glass, a coated layer using the same and a preparation method thereof
KR101315318B1 (en) * 2011-06-22 2013-10-08 케이에스케미칼 주식회사 Coating composition for vehicle

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