CN111560231A - Tube-packaged texture porcelain beautifying glue - Google Patents
Tube-packaged texture porcelain beautifying glue Download PDFInfo
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- CN111560231A CN111560231A CN202010488384.1A CN202010488384A CN111560231A CN 111560231 A CN111560231 A CN 111560231A CN 202010488384 A CN202010488384 A CN 202010488384A CN 111560231 A CN111560231 A CN 111560231A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a tube-packaged texture porcelain beautifying adhesive which comprises the following components in percentage by weight: the component A comprises: 78% -88% of epoxy resin; 2 to 6 percent of benzyl alcohol; 0.1 to 0.5 percent of defoaming agent; 0.3 to 1.5 percent of silane coupling agent; 2% -6% of fumed silica; 2% -6% of glass beads A; 1% -3% of glass beads B; and B component: 70-80% of curing agent; 0.1 to 0.5 percent of defoaming agent; 4% -8% of fumed silica; 5 to 10 percent of pigment and filler; 2% -6% of glass beads A; 1% -3% of glass beads B; the component A and the component B are respectively filled in different containers and are mixed according to the volume ratio of 1:1 for use. The porcelain beautifying glue disclosed by the invention has the advantages of matte and elegant texture effects, strong wear resistance and scratch resistance, convenience in construction mode and no residue.
Description
Technical Field
The scheme belongs to the field of chemical materials, and particularly relates to the field of application of architectural chemical materials.
Background
In decoration, gaps are reserved among tiles when the tiles are paved, the gaps are usually required to be filled and decorated by materials, and the pollution resistance and mildew resistance of joint fillers such as traditional white cement or cement-based joint fillers are always very troublesome for consumers due to the defects of the materials.
Double-tube beautiful porcelain cement and barreled texture epoxy joint filling materials are developed at home and abroad respectively, and the two products have own characteristics respectively. The double-tube porcelain enamel glue has high gloss or high smoothness, is constructed by using a glue gun to glue, and is simple, convenient and fast to construct. However, the double-tube porcelain beautifying adhesive has the characteristics of matte epoxy joint sealing material with barreled texture, rough surface and texture. Although the barreled color sand epoxy joint filling material has elegant and noble effect, the popularization of the barreled color sand epoxy joint filling material is greatly limited due to the adoption of a construction mode of batch scraping and multiple cleaning, the working procedure is troublesome, the construction period is long, and the time and the labor are consumed; and the mixing ratio difference of the agent A and the agent B of the product is very large (such as 10:1 or 12:1) and the viscosity is extremely not suitable for gluing construction.
The common double-tube epoxy beautiful porcelain adhesive has no matte and elegant texture effect, has weaker wear resistance and scratch resistance than barreled texture epoxy, and can be scratched after being repeatedly scrubbed by high-hardness cleaning tools such as steel wire balls and the like. The construction mode of the barreled texture color sand epoxy joint sealing material is very complicated and epoxy materials are easy to remain on the surface of the ceramic tile.
Disclosure of Invention
In order to solve the problems in the prior art, the invention discloses a tube-packaged texture porcelain adhesive which has matte and elegant texture effects, strong wear resistance and scratch resistance, and convenient construction mode without residue.
The invention provides a tube-packaged texture porcelain beautifying adhesive which comprises a component A and a component B, wherein the component A and the component B are respectively in hundred weight
The method specifically comprises the following steps:
the component A comprises:
and B component:
the component A and the component B are respectively filled in different containers and are mixed according to the matched volume ratio for use. For example, the volume ratio of the A component to the B component is 1.2:1, or 1.1:1, or 1:1.1, or 1: 1.2.
Furthermore, the glass beads comprise 2% -6% of glass beads A and 1% -3% of glass beads B.
Further, the glass beads A are solid glass beads, the particle size range is 40-120 μm, and the true density range is 2300-2600kg/m 3; the glass beads B are hollow glass beads, the particle size range is 20-100 mu m, and the true density range is 300-800kg/m 3.
Further, the glass beads A are solid glass beads, the particle size range is 50-100 μm, and the true density range is 2300-2500kg/m 3; the glass beads B are hollow glass beads, the particle size range is 30-80 mu m, and the true density range is 350-750kg/m 3.
Further, the component B also comprises the following components in percentage by weight: 0 to 5 percent of benzyl alcohol.
Further, the component B also comprises the following components in percentage by weight: 0% -2% of an accelerant; specifically, the main component of the accelerator is tris- (dimethylaminomethyl) phenol.
Further, the component B also comprises the following components in percentage by weight: 0 to 0.6 percent of thixotropic auxiliary agent; specifically, the thixotropic auxiliary agent is one or a combination of two of a polyamide solution containing amine functional groups or a highly branched amine polymer.
Further, the color filler accounts for 6-8% by weight.
Further, the curing agent accounts for 73.3-77.3 wt%.
Further, the epoxy resin is an E51 type epoxy resin; the curing agent is obtained by reacting at least one of polyetheramine, 1, 3-cyclohexanediamine and isophorone diamine with benzyl alcohol and E51 type epoxy resin, and the equivalent weight of active hydrogen of the reactant is 150-200.
Further, the silane coupling agent is one of gamma-aminopropyltriethoxysilane or gamma- (2, 3-epoxypropoxy) propyltrimethoxysilane; the fumed silica is one or the combination of two of hydrophilic fumed silica and hydrophobic fumed silica.
Further, the defoaming agent is one or the combination of two of organic silicon and polymer defoaming agent; the color filler comprises at least one of titanium dioxide, zinc oxide, barium sulfate, pearl powder and glitter powder.
Compared with the prior art, the scheme of the invention has the advantages that:
(1) as the adopted fumed silica is one or the combination of two of hydrophilic fumed silica and hydrophobic fumed silica, the silane coupling agent is one of gamma-aminopropyltriethoxysilane or gamma- (2, 3-epoxypropoxy) propyl trimethoxysilane, and the combination of hollow glass beads and solid glass beads is used, the product characteristics of double-tube beautiful porcelain cement and barreled texture color sand epoxy joint filling material are considered, the construction is convenient, and the matt and surface textures are realized, and the effect is elegant;
(2) two kinds of glass beads with different particle diameters are added and mixed to form a scratch-resistant layer, the abrasion resistance and scratch resistance of the tubular beautiful porcelain adhesive are greatly improved by utilizing the extremely high hardness and scratch resistance of glass, scratches are not easily generated after high-hardness cleaning tools such as steel wire balls and the like are repeatedly scrubbed, and the durability of the beautiful porcelain adhesive is greatly improved;
(3) by introducing the glass beads A, the surface of the product has certain roughness, diffuse reflection is formed to realize a matte effect, and a certain texture effect is brought; by introducing the glass beads B, the opaqueness is realized by innovatively utilizing the difference of the refractive indexes between the hollow glass beads and epoxy, so that the inferior light sensation of the product is enhanced, and the traditional method of adding a large amount of extinction powder for realizing the inferior light is avoided;
(4) when a new product is realized, the problem of difficulty in gluing during product construction caused by the addition of more fillers is solved by the matching of the glass beads A and the glass beads B, the gluing hand feeling of construction is not obviously enhanced, and the construction difficulty is obviously reduced compared with a barreled texture epoxy joint compound.
Detailed Description
The invention discloses a tube-packaged texture porcelain beautifying adhesive which comprises the following components in percentage by weight:
the component A comprises:
and B component:
wherein, the epoxy resin is a generic name of a polymer containing more than two epoxy groups in the molecule. It is a polycondensation product of epichlorohydrin and bisphenol A or polyhydric alcohol; because of the chemical activity of the epoxy group, a plurality of compounds containing active hydrogen can be used for ring opening, curing and crosslinking to generate a network structure, so that the epoxy group is a thermosetting resin;
silane coupling agents were developed by united states carbide corporation and are used primarily in glass fiber reinforced plastics. The silane coupling agent generally has a molecular formula of Y-R-Si (OR)3 (wherein Y is an organic functional group, SiOR is a siloxy group); the silicon alkoxy group has reactivity to inorganic matters, and the organic functional group has reactivity or compatibility to organic matters; therefore, when the silane coupling agent is between an inorganic interface and an organic interface, a bonding layer of an organic matrix, the silane coupling agent and an inorganic matrix can be formed, and when the product is applied to the product, the bonding of epoxy to glass beads in the product and the adhesion of the product to a construction base surface can be effectively improved;
the glass beads are a novel material which has wide application and special performance and is developed in recent years. The product is prepared by processing borosilicate raw materials by high technology, the granularity is 10-250 microns, and the wall thickness is 1-2 microns; the product has the advantages of light weight, low heat conduction, higher strength, good chemical stability and the like, and the surface of the product is subjected to special treatment to have oleophilic and hydrophobic properties and is very easy to disperse in an organic material system.
The glass beads A have higher folding strength and scratch resistance, and can ensure that the surface of a product has certain roughness, so that light irradiated on the surface of the product generates diffuse reflection, a certain matte effect is realized, and a certain texture effect is achieved.
The glass beads B are hollow glass beads, have light specific gravity, can migrate to the surface of a product to a certain degree just after construction (before curing), and are beneficial to forming a rough surface on the surface of the product; and the refractive index of the epoxy resin is increased, so that the light transmittance of the surface of the product is reduced, the product is further helped to form a certain degree of opacity, the glittering and translucent effect of epoxy is reduced, and a certain matte effect is realized.
The using method comprises the following steps: the component A and the component B are respectively arranged in a double-pipe rubber pipe, a mixed rubber pipe is arranged at the head of the rubber pipe, the component A and the component B are extruded out of the respective rubber pipes by a special rubber gun according to the volume ratio of 1:1, and the components enter a rubber nozzle to be fully mixed and react, and the obtained reactant can be used for construction.
Further, the glass beads A are solid glass beads, the particle size range is 40-120 μm, and the true density range is 2300-2600kg/m 3; the glass beads B are hollow glass beads, the particle size range is 20-100 mu m, and the true density range is 300-800kg/m 3.
As an improvement mode, the component B also comprises the following components in percentage by weight: 0% -5% of benzyl alcohol; preferably, the benzyl alcohol in the component B accounts for 2-3% by weight; the component B also comprises the following components in percentage by weight: 0% -2% of an accelerant; specifically, the main component of the accelerator is tris- (dimethylaminomethyl) phenol.
Further, the component B also comprises the following components in percentage by weight: 0 to 0.6 percent of thixotropic auxiliary agent; specifically, the thixotropic auxiliary agent is one or a combination of two of a polyamide solution containing amine functional groups or a highly branched amine polymer.
The epoxy resin is E51 type epoxy resin; the curing agent is a reactant obtained by reacting at least one of polyetheramine, 1, 3-cyclohexanediamine and isophorone diamine with benzyl alcohol and E51 type epoxy resin, and the equivalent weight of active hydrogen is 150-200. Preferably, the curing agent is 73.3 to 77.3 weight percent.
The silane coupling agent is one of gamma-aminopropyltriethoxysilane or gamma- (2, 3-epoxypropoxy) propyltrimethoxysilane; the fumed silica is one or the combination of two of hydrophilic fumed silica and hydrophobic fumed silica.
The defoaming agent is one or the combination of two of organic silicon and polymer defoaming agent; the pigment and filler comprises at least one of titanium dioxide, zinc oxide, barium sulfate, pearl powder and glitter powder; preferably, the color filler is 6-8% by weight.
Embodiments 1-4 of the invention relate to a tube-packaged texture porcelain beautifying adhesive
Specifically, table 1 shows the components and weight percentages of the tube-in-tube textured enamel paste of examples 1-4;
TABLE 1
In order to better detect the excellent effects of the invention compared with the products in the prior art, the common double-tube epoxy seam filler and the barreled texture epoxy seam filler in the embodiments 1 to 4 and the existing products of the invention are detected. The detection items comprise: construction mode, gluing hand feeling, surface roughness, glossiness, wear resistance and scratch resistance.
The detection mode is as follows:
1) testing the glossiness according to GB/T9754-2017, and selecting 60 degrees as a testing angle;
2) the wear resistance is tested according to the R type in JC/T1004-2017;
3) the scratch resistance is tested according to GB/T9279-2007, the thickness of the sample is 3mm, the sample is cured for 168 hours under standard experimental conditions after molding, and the test load is 10kg and 20 kg.
The detection results are shown in table 2:
TABLE 2
As can be seen from Table 2, the invention not only considers the two product characteristics of the double-tube porcelain enamel adhesive and the barreled texture color sand epoxy joint filler, but also has the construction mode of glue spraying by a glue gun and a certain texture of a matte surface; the wear resistance and scratch resistance are greatly improved compared with the common double-tube porcelain enamel adhesive; the construction mode of gluing by using a glue gun is adopted, the gluing hand feeling is relatively light, the construction is simple and convenient, the workload is relatively reduced, and the popularization of the texture porcelain glue is facilitated.
Finally, it should be noted that: the above embodiments are only used for illustrating the technical solutions of the present invention and not for limiting the same, and a person skilled in the art can make modifications or equivalent substitutions for the specific embodiments of the present invention, such as adjustment of formula parameter values, with reference to the above embodiments, and any modifications or equivalent substitutions that do not depart from the spirit and scope of the present invention are within the scope of the claims of the present invention as filed in the application.
Claims (10)
1. The utility model provides a kind of pipe-packed feel beautiful porcelain glue, includes A component and B component, its characterized in that: the compositions by weight percentage are as follows:
the component A comprises:
and B component:
and (3) the component A and the component B are respectively filled in different containers and are mixed according to a matched volume ratio for use.
2. The tube-packaged texture porcelain gel according to claim 1, which is characterized in that: the glass beads comprise 2-6% of glass beads A and 1-3% of glass beads B; wherein the glass bead A is a solid glass bead with the particle size range of 40-120 μm and the true density range of 2300-2600kg/m 3; the glass beads B are hollow glass beads, the particle size range is 20-100 mu m, and the true density range is 300-800kg/m 3.
3. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the component B also comprises the following components in percentage by weight: 0 to 5 percent of benzyl alcohol.
4. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the component B also comprises the following components in percentage by weight: 0% -2% of an accelerant; the main component of the accelerator is tri- (dimethylaminomethyl) phenol.
5. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the component B also comprises the following components in percentage by weight: 0 to 0.6 percent of thixotropic auxiliary agent; the thixotropic auxiliary agent is one or the combination of two of polyamide solution containing amine functional group or hyperbranched amine polymer.
6. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the color filler accounts for 6 to 8 weight percent.
7. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the curing agent accounts for 73.3 to 77.3 weight percent.
8. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the epoxy resin is E51 type epoxy resin; the curing agent is at least one of polyether amine, 1, 3-cyclohexanediamine and isophorone diamine, and is obtained by reacting the curing agent with benzyl alcohol and E51 type epoxy resin, and the equivalent weight of active hydrogen of reactants is 150-.
9. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the silane coupling agent is one of gamma-aminopropyltriethoxysilane or gamma- (2, 3-epoxypropoxy) propyltrimethoxysilane; the fumed silica is one or the combination of two of hydrophilic fumed silica and hydrophobic fumed silica.
10. The tube-packaged texture porcelain enamel glue according to claim 1 or 2, which is characterized in that: the defoaming agent is one or the combination of two of organic silicon and polymer defoaming agent; the color filler comprises at least one of titanium dioxide, zinc oxide, barium sulfate, pearl powder and glitter powder.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010488384.1A CN111560231A (en) | 2020-06-01 | 2020-06-01 | Tube-packaged texture porcelain beautifying glue |
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| CN202010488384.1A CN111560231A (en) | 2020-06-01 | 2020-06-01 | Tube-packaged texture porcelain beautifying glue |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113683992A (en) * | 2021-08-17 | 2021-11-23 | 湖南美吉邦建材有限公司 | Weather-resistant texture seam beautifying agent and preparation method thereof |
| CN116102811A (en) * | 2023-03-02 | 2023-05-12 | 广州傲胜人造草股份有限公司 | Matte master batch, matte artificial grass yarn, preparation method of matte master batch and matte artificial grass yarn and matte artificial lawn |
| CN116200838A (en) * | 2023-03-02 | 2023-06-02 | 广州傲胜人造草股份有限公司 | High-temperature-resistant artificial grass yarn, preparation method thereof and artificial lawn |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN113683992A (en) * | 2021-08-17 | 2021-11-23 | 湖南美吉邦建材有限公司 | Weather-resistant texture seam beautifying agent and preparation method thereof |
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| CN116200838A (en) * | 2023-03-02 | 2023-06-02 | 广州傲胜人造草股份有限公司 | High-temperature-resistant artificial grass yarn, preparation method thereof and artificial lawn |
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Application publication date: 20200821 |