KR20050111443A - Indoor finishing material for a building - Google Patents

Indoor finishing material for a building Download PDF

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KR20050111443A
KR20050111443A KR1020040036151A KR20040036151A KR20050111443A KR 20050111443 A KR20050111443 A KR 20050111443A KR 1020040036151 A KR1020040036151 A KR 1020040036151A KR 20040036151 A KR20040036151 A KR 20040036151A KR 20050111443 A KR20050111443 A KR 20050111443A
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South Korea
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powder
finishing material
building
activated carbon
effect
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KR1020040036151A
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Korean (ko)
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서정윤
서명포
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서정윤
서명포
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/02Coverings or linings, e.g. for walls or ceilings of plastic materials hardening after applying, e.g. plaster
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0076Deodorizing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0097Anion- and far-infrared-emitting materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Building Environments (AREA)

Abstract

본 발명은 건축용 기능성 마감재에 관한 것으로, 천연 옥 분말 40-70%, 활성탄 및 황토분말 중 적어도 어느 하나 이상이 20-35%에 기타 무기질 세라믹 및 혼합재 10-20% 점증제 0.1-0.2%, 소포제 0.1-0.5%, 에멀젼 15%, 부동액 0.1-1.5% 등의 결합제를 혼합한 마감재를, 시멘트 내장재의 내외벽에 마감 시공하여 시멘트의 독성 중화 작용, 원적외선 효과, 항균, 항 곰팡이, 탈취 및 악취 제거 작용뿐만 아니라 공기 정화 및 건강유지, 에너지 절감 등을 기대할 수 있으며 건강하고 쾌적한 주거 환경을 제공하는 것이다.The present invention relates to a building functional finishing material, 40-70% natural jade powder, at least one or more of activated carbon and ocher powder 20-35% other inorganic ceramics and mixtures 10-20% thickener 0.1-0.2%, defoamer Finishing materials mixed with binders such as 0.1-0.5%, 15% emulsion, and 0.1-1.5% antifreeze are finished on the inner and outer walls of the cement lining to remove the toxic neutralization, far infrared effect, antibacterial, anti-fungal, deodorant and odor of cement. In addition to the operation, air purification and health maintenance, energy savings can be expected and provide a healthy and pleasant living environment.

Description

건축용 실내 기능성 마감재{Indoor Finishing Material for a Building}Interior Finishing Material for a Building

본 발명은 건축용 기능성 마감재에 관한 것으로, 더 상세하게는 액상의 무기 고화제 성분으로 된 마감재를 붓, 롤 및 스프레이 방법 등으로 시멘트 건축물의 내, 외벽에 마감 시공하는 것에 의해 시멘트의 독성 중화 작용, 원적외선 효과, 항균, 항 곰팡이, 탈취 및 악취 제거 작용뿐만 아니라, 공기 정화 및 건강유지, 에너지 절감 등을 기대할 수 있으며, 건강하고 쾌적한 주거 환경을 제공할 수 있도록 발명된 것이다.The present invention relates to a functional finishing material for construction, and more particularly, to the toxic neutralization of cement by finishing the finishing material of the liquid inorganic solidifying agent component on the inner and outer walls of the cement building by a brush, roll and spray method, Far-infrared effect, antibacterial, anti-fungal, deodorant and odor removal action, as well as air purification and health maintenance, can be expected to save energy, and is invented to provide a healthy and comfortable living environment.

일반적으로 새로 신축되는 건축 구조물 내지 내장재 등과 같은 각종 건축자재에는 유해물질이 포함되어 있다.In general, various building materials such as newly constructed building structures or interior materials include harmful substances.

즉, 종래 콘크리트와 같은 골격구조물은 물론 벽지, 장판지 등과 같은 각종 내장재를 부착하기 위한 접착제에서 포름알데히드 및 휘발성 유기화합물(VOC) 등과 같은 유해물질이 장시간에 걸쳐 서서히 방출되어 질병유발과 같이 인체에 심각한 피해를 주는 것으로 알려져 있다.In other words, the harmful substances such as formaldehyde and volatile organic compounds (VOC) are gradually released over a long period of time from the adhesive for attaching various interior materials such as wallpaper and floorboards as well as concrete such as concrete, which is serious for human body such as disease. It is known to cause damage.

본 발명의 목적은 시멘트 건축물의 내, 외벽에 마감 시공하는 것에 의해 시멘트의 독성을 중화시켜 건강하고 쾌적한 주거 환경을 만들어 주는 마감재를 제공하는데 있다.It is an object of the present invention to provide a finishing material that neutralizes the toxicity of cement by finishing the interior and exterior walls of a cement building to create a healthy and comfortable living environment.

본 발명의 다른 목적은 원적외선 방출에 의한 건강 증대효과와 항균, 항 곰팡이, 탈취 및 악취 제거 작용뿐만 아니라, 공기 정화 및 에너지 절감효과를 갖도록 한 마감재를 제공하는데 있다.It is another object of the present invention to provide a finishing material having an effect of increasing the health and antibacterial, anti-fungal, deodorant and odor removal effect as well as air purification and energy saving effect by far-infrared emission.

이러한 본 발명의 목적은, 천연 옥 분말 40-70%(중량%)과, 활성탄 및 황토분말 중 적어도 어느 하나 이상이 20-35%(중량%)로 혼합된 분말 조성물을 얻고, 물이나 결합제가 소정의 비율로 혼합되어서 구성된다.The object of the present invention is to obtain a powder composition in which 40-70% (wt%) of natural jade powder and at least one of activated carbon and ocher powder are mixed in 20-35% (wt%), and water or binder It is comprised by mixing in a predetermined ratio.

한편 액상으로 시공하기 위하여는 상기 옥, 황토, 활성탄으로 된 소재에 결합제로 에멀젼, 소포제 및 점중제가 더 혼합되어서 액상 마감재로 완성되는 것이다.Meanwhile, in order to construct a liquid phase, an emulsion, an antifoaming agent, and a thickening agent are further mixed as a binder to a material of jade, loess, and activated carbon, thereby completing a liquid finish.

일반적으로 옥은 상온에서 원적외선을 방사하는 광석으로 이미 알려져 있다.In general, jade is already known as an ore that emits far infrared rays at room temperature.

따라서 인간에게 건강을 위한 보석으로도 널리 이용되고 있는데, 이원적외선은 5-20㎛ 범위대에서 몸속의 생체에너지를 증가시켜 근육의 피로를 회복시켜 주며 혈액순환, 내분비 계통의 순환을 촉진하고 피부 깊숙이 침투하여 노폐물 등의 불필요한 축적물들을 수분과 함께 배출시켜 신진 대사는 물론 혈액순환을 촉진하는 것으로 알려져 있다.Therefore, it is widely used as a jewel for human health, and dual infrared rays increase the body's bioenergy in the range of 5-20㎛ to restore muscle fatigue, promote blood circulation, endocrine system circulation and deep skin It is known to promote metabolism and blood circulation by infiltrating and discharging unnecessary accumulations such as waste products together with water.

또한 독성의 중화 작용, 항균, 항 곰팡이 등에 효과가 입증되고 있다.In addition, it has been proven effective in neutralizing toxic effects, antibacterial and antifungal.

그리고 이러한 옥의 기능에서 항균, 항 곰팡이 등의 효과 및 원적외선 발생효과와 현재 실내 공기 질 관리 수준에서 탈취효과, 이온성 물질 제거 및 흡착효과를 더하여 얻을 수 있도록 하는 것이다.In addition, the effect of jade and anti-fungal and far-infrared rays and deodorization, ionic substances removal and adsorption at the current indoor air quality management level.

즉 일정량의 황토와 기능성 소재로 활성탄 등을 옥 분말에 첨가하여 기존의 옥 단독 사용시에서 보다 개선된 독성 중화, 탈취율 개선, 실내 공기 및 분진 흡착등의 효과로 친 환경적인 주거 환경을 제공할 수 있는 건축용 마감 미장재료를 얻고자 하는 것이다.In other words, activated carbon is added to jade powder with a certain amount of loess and functional material to provide eco-friendly living environment by toxic neutralization, deodorization improvement, indoor air and dust absorption, etc. It is to obtain finishing plastering materials for construction.

옥으로는 천연옥을 사용하여 미세한 분말로 300 mesh 이상이 되도록 한다.For jade, use natural jade to make fine powder over 300 mesh.

미분말 일수록 마감재로 사용 후 표면이 균일하며, 단위 비표면적이 커지게 되므로, 타 성분과의 혼화성 및 각종 세라믹 성분과의 결합성이 우수해진다.The finer the powder, the more uniform the surface after use as a finishing material and the larger the unit specific surface area, the better the compatibility with other components and bonding with various ceramic components.

따라서 마감재로 옥, 황토, 활성탄이 소정의 비율로 혼합되어 분말상태로 제조, 판매되고, 시공될 때는 상기 분말 혼합물에 물을 적당한 비율로 섞어서 붓이나 롤 및 노즐에 의한 스프레이 방법으로 시공하는 것이다.Therefore, as a finishing material, jade, loess, and activated carbon are mixed in a predetermined ratio, and manufactured and sold in a powder state, and when they are constructed, the powder mixture is mixed with water at an appropriate ratio and applied by a spray method using a brush, a roll, and a nozzle.

한편 페인트와 같은 액상의 마감재 상태로 제공되는 경우에는 상기 옥, 황토, 제올라이트, 활성탄 분말에 에멀젼과 소포제 친환경적인 점중제가 각각 소정 비율로 혼합되어 완성된다.On the other hand, when provided in the form of a liquid finish, such as paint, the jade, ocher, zeolite, activated carbon powder is completed by mixing an emulsion and an antifoaming agent eco-friendly concentrate in a predetermined ratio, respectively.

에멀젼은 접착용 수지로써 수용성 분말 혹은 액체형으로 사용하며 일반적으로 상품화되어 있는 제품을 사용해도 무방하다.Emulsions are adhesive resins that can be used in water-soluble powders or in liquid form, and may be used as a commercially available product.

소포제는 마감재 제조 및 혼화시에 발생하는 기포를 제어하기 위해 약 0.1-0.5의 양으로 사용되며 일반적인 시중의 소포제를 사용하면 된다.Antifoaming agents are used in amounts of about 0.1-0.5 to control the air bubbles generated during the manufacture and blending of finishing materials. Common antifoaming agents can be used.

혼합액의 특성상으로 본 발명품의 조성액일 경우 소포제를 사용하지 않아도 혼화 및 취급관리에는 별 문제가 발생하지 않았다.Due to the characteristics of the mixed solution, even if the composition solution of the present invention did not use a defoamer, there was no problem in mixing and handling management.

활성탄은 3-10% 범위에서 주입시켜 흡착 효과 및 탈취율의 증가 효과 그리고 음이온 방출 효과를 갖도록 하였다.Activated carbon was injected in the range of 3-10% to have an adsorption effect, an increase in deodorization rate and an anion release effect.

세라믹 결합재 및 혼합재는 다공정인 물질로 5-20% 범위에서 주입하여 탈취 효과를 극대화할수 있다.Ceramic binders and mixtures are multi-process materials and can be injected in the range of 5-20% to maximize the deodorizing effect.

그러나 이 활성탄 및 세라믹 결합재 등 을 상기 범위를 벗어난 과량 혼합하는 경우, 본 기능성 재료의 점착이나 흡수율, 그리고 결합성 등에 문제가 되므로 적정량 범위에서 혼합사용 하여야 한다.However, when the activated carbon and the ceramic binder are mixed in excess of the above ranges, they should be mixed and used in an appropriate amount range because of problems in adhesion, water absorption, and bondability of the functional material.

아래 비교표에서 살펴보면 탈취율만 비교했을 경우 기존의 옥 분말을 사용하였을 경우보다 탈취율면에서 약 40-50%가 개선되는 결과를 볼 수가 있었다.Looking at the comparison table below, when compared to the deodorization rate only compared to the case of using the conventional jade powder it can be seen that about 40-50% in terms of deodorization rate is improved.

이러한 기능성 마감재는 일반적인 도포방법으로 시멘트 미장 마감 후 그 상부에 붓이나, 롤 또는 노즐을 이용한 스프레이 분사 방법 등으로 건축물의 내, 외벽에 코팅을 실시하게 된다.The functional finishing material is a general coating method and after coating the cement plastering is applied to the inner and outer walls of the building by a spray spraying method using a brush, a roll or a nozzle on the top.

이하 본 발명의 바람직한 실시예를 설명하기로 한다.Hereinafter, a preferred embodiment of the present invention will be described.

실시예 1.( 기능성 마감재의 제조)Example 1 (Preparation of Functional Finishes)

약 300-500 mesh의 천연옥 분말 7kg 및 기능성 보조제로 황토, 활성탄 등을 2-3.5kg, 세라믹 결합재 및 혼합재 1-2kg 에멀젼으로 일반적인 아크릴 또는 우레탄수지 1-1.5kg, 소포제로 범용의 일반적인 소포제, 점증제로는 친환경적인 셀루로스(cellulose)로 0.2-0.9kg 정도를 혼합하였다.7kg natural jade powder of 300-500 mesh and 2-3.5kg of ocher and activated carbon as functional aids, 1-2kg emulsion of ceramic binder and mixture, 1-1.5kg of general acrylic or urethane resin, general defoamer as general defoaming agent, thickening Zero is an eco-friendly cellulose (0.2-0.9kg) was mixed.

기타 무기 세라믹 결합제 및 혼합재 등 1-2kg를 사용하여 제조하였으며 이와 같이 제조된 기능서 마감재는 탈취 및 원적외선 효과, 항균, 항 곰팡이, 습도 조절 및 에너지 절약 효과를 얻을 수가 있었다.Other inorganic ceramic binders and mixtures were prepared using 1-2kg, and the functional finishes thus obtained were able to obtain deodorizing and far-infrared effects, antibacterial, anti-mildew, humidity control and energy saving effects.

실시예 2. (탈취효과)Example 2. (Deodorization effect)

일반적으로 옥으로 사용하였을 때 탈취율이 30-37% 범위(KICM-FIR 1085 방법에 따른 암모니아 가스의 제거효과)였으나 본 기능성 마감재의 경우 첨가물을 추가 제조하였을 때 탈취효과(KICM-FIR 1085 방법에 다른 암모니아 가스의 제거 효과)는 60~70%로 배 이상의 효과를 거둘 수가 있었으며 그 결과는 하기 표 1과 2에 나타내었다.In general, when used as jade, the deodorization rate was in the range of 30-37% (the effect of removing ammonia gas according to KICM-FIR 1085 method). Removal effect of ammonia gas) was 60-70% more than twice the effect was shown in Tables 1 and 2 below.

상기 표 1, 표 2에서 알 수 있듯이 본 발명의 기능성 분말 첨가시 탈취효과가 옥 분말 단독 사용시보다 월등히 우수함을 알 수가 있다.As can be seen from Table 1 and Table 2, it can be seen that the deodorizing effect of the addition of the functional powder of the present invention is much better than that of jade powder alone.

실시예 3. (항균, 항곰팡이 효과)Example 3. (Antibacterial, antifungal effect)

상기 실시예 1에서 제조된 기능성 마감재 분말의 경우 항균, 항 곰팡이 효과를 ASTM G-21 방법에 따라 평가하였으며, 그 결과를 하기 표 3,4에 나타내었다.For the functional finish powder prepared in Example 1, the antimicrobial and antifungal effects were evaluated according to ASTM G-21 method, the results are shown in Tables 3 and 4 below.

시험에 사용된 곰팡이 균주로는 Aspergillus niger ATCC 9642, Penicillium pinophilum ATCC 11797 및 Chaetomium globosum ATCC 6205의 혼합 균주를 사용 하였다.As a fungal strain used in the test, a mixed strain of Aspergillus niger ATCC 9642, Penicillium pinophilum ATCC 11797 and Chaetomium globosum ATCC 6205 was used.

* 곰팡이 균주 (혼합균주)Fungal strains (mixed strains)

Aspergillus niger ATCC 9642Aspergillus niger ATCC 9642

Penicillium pinophilum ATCC 11797Penicillium pinophilum ATCC 11797

Chaetomium golbosum ATCC 6205Chaetomium golbosum ATCC 6205

Gliosiadium virens ATCC 9645Gliosiadium virens ATCC 9645

Aureobasidium pullulans ATCC 15233Aureobasidium pullulans ATCC 15233

* 사용균주* Use strain

Escherichia coli ATCC 25922Escherichia coli ATCC 25922

Pseudomonas aeruginosa ATCC 15442Pseudomonas aeruginosa ATCC 15442

실시예 4. (적외선 열화상 시험)Example 4 (Infrared Thermal Imager Test)

본 실시예는 실시예 1의 경우 기능성 분말 사용시 방출되는 적외선을 측정하여 열전도율을 평가 시험한 값이다.This Example is a value obtained by evaluating the thermal conductivity by measuring the infrared rays emitted when using the functional powder in the case of Example 1.

시험은 적외선 열화상 장치를 사용하여 실내온도(room temperature) 25℃ 습도 54% 조건에서 시험하였으며 방사되는 적외선 방사에너지 영과 온도 데이터로 처리하여, 그 결과를 도 1에 나타내었다.The test was conducted at room temperature 25 ° C humidity 54% using an infrared thermal imager and treated with radiated infrared radiation energy and temperature data, the results are shown in FIG. 1.

실시예 5. (원적외선 방사 효과)Example 5 (far infrared radiation effect)

상기 실시예 1의 기능성 마감재로 FT-RI Spectrometer를 이용하여 온도 40℃에서 흑체(Black Body)에 대비하여 본 발명의 기능성 마감 재료가 방사하는 적외선을 측정하여 본 결과 원적외선 파장인 5-20㎛ 에서의 방사율이 0.925이었으며 방사에너지는 3.73×102(w/㎡)으로 원적외선을 방사하는 것으로 나타냈다.Using the FT-RI Spectrometer as a functional finish material of Example 1, the infrared rays emitted by the functional finish material of the present invention were measured in comparison with a black body at a temperature of 40 ° C., and as a result, the wavelength was 5-20 μm. The emissivity of was 0.925 and the radiant energy was 3.73 × 10 2 (w / ㎡).

상기와 같은 본 발명의 마감재는, 조성분말 또는 조성액으로 각각 원하는 용도에 맞추어 제공되는데, 시멘트 독성 중화 작용, 탈취 및 항균, 항 곰팡이 효과 및 원적외선 효과 등을 보여주는 친환경 건축 마감재를 얻을 수가 있는 것이다.The finishing materials of the present invention as described above, provided as a composition powder or a composition liquid, respectively, according to the desired use, it is possible to obtain an environmentally friendly building finish showing a cement toxicity neutralizing effect, deodorizing and antibacterial, anti-mildew effect and far-infrared effect.

이들 재료를 건물 내부의 벽 마감재 또는 바닥재로 적용함으로써 인체의 유익한 건강과, 쾌적한 주거 환경 및 습도 조절 등에 좋은 효과를 보여주며, 특히 원적외선 방사율이 높아서 인체에 필요한 혈액 운동 촉진, 신진 대사 활동 촉진 등과 같은 생체리듬을 활성화하는 것으로, 천연 재료를 사용함으로써 자연 친화적이며 건강한 주택문화 공간 조성을 꾀할 수가 있다.By applying these materials as wall finishing or flooring materials in buildings, they show good effects on the human body's beneficial health, pleasant living environment and humidity control. By activating biorhythms, natural materials can be used to create a space that is both natural and healthy.

특히, 탈취율이 높고 열효율 증대, 습도 조절 등의 추가 효과로 실내 건강 및 난방효과를 동시에 얻을 수 있는 등의 매우 유용한 발명인 것이다.In particular, it is a very useful invention, such as high deodorization rate, thermal efficiency increase, humidity control, and at the same time obtain the indoor health and heating effect.

도 1은 본 발명에 의해 방사되는 적외선 방사에너지 영과 온도 데이터를 보인 사진.1 is a photograph showing the infrared radiation energy zero and temperature data emitted by the present invention.

Claims (2)

천연 옥 분말 40-70%(중량%)과, 활성탄, 제올라이트 및 황토분말 중 적어도 어느 하나 이상이 20-35%(중량%), 기타 무기질 세라믹 및 혼합재 10-20%, 점증제 0.1-2%, 소포제 0.1-0.5%, 에멀젼 5-20%, 부동액 0.1-1.5%를 혼합하여서 된 것을 특징으로 하는 건축용 기능성 마감재.40-70% (wt%) of natural jade powder, 20-35% (wt%) of at least one of activated carbon, zeolite and ocher powder, 10-20% of other inorganic ceramics and mixtures, 0.1-2% thickener Building functional finishing material, characterized in that by mixing 0.1-0.5% antifoam, 5-20% emulsion, 0.1-1.5% antifreeze. 제 1항에 있어서 상기 옥, 활성탄 및 황토 외의 모든 분말 입도는 300-500mesh 이상인 것을 특징으로 하는 건축용 기능성 마감재.The building functional finishing material according to claim 1, wherein all powders other than jade, activated carbon and loess are 300-500mesh or more.
KR1020040036151A 2004-05-20 2004-05-20 Indoor finishing material for a building KR20050111443A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100613877B1 (en) * 2005-10-31 2006-08-17 소순형 Manufacturing method of painting material comprising precious stone component
KR100796729B1 (en) * 2007-01-11 2008-01-21 한국호진공업 주식회사 Manufacturing method the functional coating liquid of building interior materials
KR100802421B1 (en) * 2007-03-08 2008-02-13 (주)큐엔솔루션 Conclusion panel for construction materials
KR101239491B1 (en) * 2007-10-16 2013-03-05 (주)엘지하우시스 Functional loess tile having improved adsorption rate
WO2014104498A1 (en) 2012-12-26 2014-07-03 김혁중 Eco-friendly water-soluble paint composition for interior finishing material of building

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100613877B1 (en) * 2005-10-31 2006-08-17 소순형 Manufacturing method of painting material comprising precious stone component
KR100796729B1 (en) * 2007-01-11 2008-01-21 한국호진공업 주식회사 Manufacturing method the functional coating liquid of building interior materials
KR100802421B1 (en) * 2007-03-08 2008-02-13 (주)큐엔솔루션 Conclusion panel for construction materials
KR101239491B1 (en) * 2007-10-16 2013-03-05 (주)엘지하우시스 Functional loess tile having improved adsorption rate
WO2014104498A1 (en) 2012-12-26 2014-07-03 김혁중 Eco-friendly water-soluble paint composition for interior finishing material of building
US9249312B2 (en) 2012-12-26 2016-02-02 Hyeok Jung Kim Eco-friendly water-based paint composition for interior finishing materials of buildings

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