KR20050025701A - A floor with marble quality using two kinds of color sols which have different color and viscosity, and method for producing the same - Google Patents

A floor with marble quality using two kinds of color sols which have different color and viscosity, and method for producing the same Download PDF

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Publication number
KR20050025701A
KR20050025701A KR1020030062507A KR20030062507A KR20050025701A KR 20050025701 A KR20050025701 A KR 20050025701A KR 1020030062507 A KR1020030062507 A KR 1020030062507A KR 20030062507 A KR20030062507 A KR 20030062507A KR 20050025701 A KR20050025701 A KR 20050025701A
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South Korea
Prior art keywords
layer
colored
sol
viscosity
color
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KR1020030062507A
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Korean (ko)
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김상호
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주식회사 금강고려화학
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Priority to KR1020030062507A priority Critical patent/KR20050025701A/en
Publication of KR20050025701A publication Critical patent/KR20050025701A/en

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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F15/00Flooring
    • E04F15/02Flooring or floor layers composed of a number of similar elements
    • E04F15/10Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
    • E04F15/107Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials composed of several layers, e.g. sandwich panels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/402Coloured
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00Buildings or parts thereof
    • B32B2419/04Tiles for floors or walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00Walls, panels

Landscapes

  • Engineering & Computer Science (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Laminated Bodies (AREA)
  • Floor Finish (AREA)

Abstract

Provided are a marble texturing floor and its production to use two kinds of colored sol with different color and viscosity, which supplies marble texture by putting the two-colored sol with a substrate while forming a colored adhesive layer on a substrate. The floor has a multi-structure consisting of a substrate(10) and a surface layer(20) on its upside. The surface layer(20) contains a colored adhesive layer(2) with marble texture caused by two kinds of colored sol(2',2") having different colors and viscosity. One colored sol has 4,000-7,000cps of a viscosity and the other has 10,000-15,000cps of a viscosity. The substrate consists of stacking a nonwoven plywood(11) or a nonexpanded underlayer on an underside of a glass wool impregnated layer(1). The surface layer(20) is made by stacking a colored adhesive(2), a transparent layer(3), and a surface-treatment layer(4) in sequence on the substrate(10).

Description

색상과 점도가 상이한 2종의 유색졸을 이용한 마블질감의 바닥재 및 이의 제조방법{A FLOOR WITH MARBLE QUALITY USING TWO KINDS OF COLOR SOLS WHICH HAVE DIFFERENT COLOR AND VISCOSITY, AND METHOD FOR PRODUCING THE SAME}Marble flooring material using two colored sol with different color and viscosity and manufacturing method thereof

본 발명은 색상과 점도가 상이한 2종의 유색졸을 이용한 마블질감의 바닥재에 관한 것으로서, 보다 상세하게는 다층구조의 바닥재에 있어서, 기재층 위에 유색접착층을 형성시, 색상과 점도가 상이한 2종의 유색졸을 동시에 투입하여 원단 진행과 동시에 2종의 유색졸의 색상이 부분적으로 혼합되므로써 마블질감이 부여된 바닥재 및 이의 제조방법에 관한 것이다.The present invention relates to a marble-based flooring material using two kinds of colored sol having different colors and viscosities. More specifically, in a flooring having a multilayer structure, two kinds of colors and viscosities are different when a colored adhesive layer is formed on a substrate layer. It relates to a flooring material and a method for producing the same by adding a colored sol at the same time as the color of the two color sol is partially mixed with the progress of the fabric.

종래의 마블질감의 바닥재의 경우, 크기와 색상이 다양한 마블칩을 일정량 산포하여 가열압착한 후 표면처리하는 방법과 카렌다 설비를 이용하여 시트 제작시 마블질감을 부여하는 방법이 통상적으로 적용되었으나, 졸코팅방법으로 마블질감을 균일하게 부여하는 데는 공법적인 한계가 있었다. In the case of the marble floor of the prior art, the method of surface treatment after spreading and compressing a certain amount of marble chips having various sizes and colors and applying the texture to the sheet using a calender facility have been commonly applied. There was a public limitation in giving the marble texture uniformly by the coating method.

본 발명은 상기와 같은 문제점을 해결하기 위한 것으로, 본 발명의 목적은 다층구조의 바닥재에 있어서, 기재층 위에 유색접착층을 형성시, 색상과 점도가 상이한 2종의 유색졸을 동시에 투입하여 원단 진행과 동시에 2종의 유색졸의 색상이 부분적으로 혼합되므로써 마블질감이 부여된 바닥재 및 이의 제조방법을 제공하는 것이다.The present invention is to solve the above problems, an object of the present invention in the multi-layered flooring, when forming a colored adhesive layer on the base layer, at the same time the two kinds of colored sol different in color and viscosity to advance the fabric Simultaneously with the color of the two color sol is partially mixed to provide a flooring material and a method of manufacturing a marble texture.

본 발명의 마블질감의 바닥재는 기재층(10)과 기재층(10) 상부의 표면층(20)으로 구성되어 있으며, 기재층(10)은 유리섬유 함침층(1)과, 유리섬유 함침층(1) 하부에 부직포 합판층(11) 또는 비발포하부층(12)이 적층된 구조로 이루어지고, 표면층(10)은 유리섬유 함침층(1) 상부에 차례로 유색접착층(2), 투명층(3) 및 표면처리층(4)(생략가능)이 적층된 구조로 이루어진다.Marble flooring material of the present invention is composed of a base layer 10 and the surface layer 20 on the base layer 10, the base layer 10 is a glass fiber impregnation layer (1), a glass fiber impregnation layer ( 1) The non-woven plywood layer 11 or the non-foaming lower layer 12 is laminated on the bottom, the surface layer 10 is a colored adhesive layer (2), transparent layer (3) in order on the glass fiber impregnation layer (1) And a structure in which the surface treatment layer 4 (optional) is laminated.

이하에서는, 본 발명의 바람직한 실시형태에 대해 도면을 참조하여 설명한다.EMBODIMENT OF THE INVENTION Hereinafter, preferred embodiment of this invention is described with reference to drawings.

본 발명에 따른 일실시예인 도 2에 도시된 마블질감의 바닥재는 크게 기재층(10)과 기재층(10) 상부의 표면층(20)으로 이루어진다. 기재층(10)은 유리섬유 함침층(1)과 유리섬유 함침층(1) 하부에 부직포 합판층(11)이 적층된 구조로 이루어지고, 표면층(10)은 유리섬유 함침층(1) 상부에 차례로 유색접착층(2), 투명층(3) 및 표면처리층(4)이 적층된 구조로 이루어진다.The marbled floor material shown in FIG. 2, which is an embodiment according to the present invention, is composed of a base layer 10 and a surface layer 20 on the base layer 10. The base layer 10 has a structure in which a nonwoven plywood layer 11 is stacked below the glass fiber impregnation layer 1 and the glass fiber impregnation layer 1, and the surface layer 10 is formed on the glass fiber impregnation layer 1. In order, the colored adhesive layer 2, the transparent layer 3, and the surface treatment layer 4 were laminated.

본 발명에 따른 마블질감의 바닥재의 제조방법에 대한 개요는 도 1에 나타낸다. 도 1의 제조방법에 따라 제조된 도 2에 도시된 본 발명의 마블질감의 바닥재의 제조방법을 설명하면, 우선 제품의 치수안정성을 부여하는 유리섬유 함침층(1)을 제조한다. An outline of a method for producing a marble-based flooring material according to the present invention is shown in FIG. 1. Referring to the manufacturing method of the flooring of the marble texture of the present invention shown in Figure 2 manufactured according to the manufacturing method of Figure 1, first to prepare a glass fiber impregnated layer (1) to impart the dimensional stability of the product.

유리섬유 함침층(1)은 유리섬유와 같은 기재 위에 함침층의 조성물을 적정 두께로 나이프 코팅하여 형성시키고, 그 하부에 부직포를 유리섬유 함침층(1)과 합판하여 130∼210℃에서 3∼10m/min의 속도로 10∼200초간 가열한 후, 합판과 동시에 겔(gel)화시키므로써 부직포 합판층(11)을 형성시킨다. 부직포 합판층(11)을 적층하지 않을 경우, 비발포하부층(12)을 적층할 수도 있다. 부직포 적층 제품의 경우, 부직포 합판층(11)의 두께는 다양할 수 있으나 유리섬유 함침층(11)에 부직포를 합판한 후의 두께가 0.5∼1.2.mm인 것이 바람직하고, 부직포를 적층하지 않고 비발포하부층(12)을 적층할 경우, 비발포하부층(12)의 두께는 다양할 수 있으나 유리섬유 함침층(11) 하부에 비발포 하부층을 겔링한 후의 두께가 0.3∼1.0mm인 것이 바람직하다.The glass fiber impregnated layer 1 is formed by knife coating a composition of the impregnated layer on a substrate such as glass fiber to an appropriate thickness, and a nonwoven fabric is laminated with the glass fiber impregnated layer 1 at the lower portion thereof at 3 to 130 ° C. After heating for 10 to 200 seconds at a rate of 10 m / min, the nonwoven plywood layer 11 is formed by gelation simultaneously with the plywood. If the nonwoven plywood layer 11 is not laminated, the non-foaming lower layer 12 may be laminated. In the case of the nonwoven laminated product, the thickness of the nonwoven plywood layer 11 may vary, but the thickness after the nonwoven fabric is laminated to the glass fiber impregnated layer 11 is preferably 0.5 to 1.2 mm, and the nonwoven fabric is not laminated. When the foamed lower layer 12 is laminated, the thickness of the non-foamed lower layer 12 may vary, but the thickness after gelling the non-foamed lower layer below the glass fiber impregnated layer 11 is preferably 0.3 to 1.0 mm.

이때 유리섬유 함침층(1)의 조성물은, 예를 들어 중합도가 1000∼2000인 염화비닐수지 100중량부에 가소제 30∼70중량부, 안정제 1∼5중량부, 충진제 50∼200중량부와 기타 첨가제를 혼합하여 졸(sol) 상태로 만든 것이 바람직하다.At this time, the composition of the glass fiber impregnated layer (1) is, for example, 30 to 70 parts by weight of plasticizer, 1 to 5 parts by weight of stabilizer, 50 to 200 parts by weight of filler and the like to 100 parts by weight of vinyl chloride resin having a polymerization degree of 1000 to 2000. It is preferable to make the sol state by mixing the additives.

상기와 같이 유리섬유 함침층(1)의 하부에 부직포 합판층(11) 또는 비발포하부층(12)이 적층되어 이루어진 기재층(10) 위에 유색접착층(2)을 형성시키는데, 이 때 마블질감을 부여하기 위해 유색졸 A(2')와 유색졸 B(2'')를 동시에 투입한 후 0.2∼1.0mm의 두께로 나이프 코팅한다.As described above, the colored adhesive layer 2 is formed on the base layer 10 formed by laminating the nonwoven plywood layer 11 or the non-foaming lower layer 12 under the glass fiber impregnated layer 1, and at this time, To give, colored sol A (2 ') and colored sol B (2' ') are added simultaneously and knife coated to a thickness of 0.2 to 1.0 mm.

유색접착층(2)을 형성하기 위해 사용하는 유색졸 A(2')와 유색졸 B(2'')의 조성물은, 예를 들어 중합도가 1000∼2000인 염화비닐수지 100중량부에 가소제 30∼100중량부, 안정제 1∼5중량부, 안료 0.01∼10중량부와 기타 첨가제를 혼합하여 졸상태로 만든 것이 바람직하다.The composition of colored sol A (2 ') and colored sol B (2' ') used for forming the colored adhesive layer 2 is, for example, 100 parts by weight of a vinyl chloride resin having a polymerization degree of 1000 to 2000, and a plasticizer of 30 to It is preferable to mix | blend 100 weight part, 1-5 weight part of stabilizers, 0.01-10 weight part of pigments, and other additives, and to make it into a sol state.

마블질감을 균일하게 부여하기 위해서는 각각의 유색접착졸의 투입 위치가 원단의 중앙을 기준으로 좌우대칭이 되도록 해야 하고, 투입되는 배관의 크기와 졸 투입방법을 효과적으로 적용하여야 한다.In order to give the marble texture uniformly, each colored adhesive sol should be symmetrical with respect to the center of the fabric, and the size of the pipe and the sol feeding method should be effectively applied.

도 4에 도시된 바와 같이, 유색졸의 투입은 각 유색졸의 투입량 및 점도에 따라 미리 정해진 서로 다른 직경을 갖는 유색졸 A, B 투입용 배관을 통해 이루어지며, 투입된 각 유색졸은 일시적으로 뱅크(졸이 코우터 앞에서 코팅되기 바로 전에 잠시 모여있는 단계)에 잠시 머물다가, 기재층(10)으로 이루어진 바닥재 원단 위에 코팅된다. 배관을 통해 졸을 투입할 때에는, 원단의 중앙, 원단의 중앙과 좌측 끝단의 중앙 및 원단의 중앙과 우측 끝단의 중앙의 총 3군데에서 졸을 투입하는 것이 바람직하고, 균일한 마블질감을 부여하기 위해서는 라인속도(line speed)를 균일하게 유지하도록 한다. 졸 투입은 코팅두께와 라인속도를 감안하여 순간적이고 불연속적인 투입이 아닌 계속적인 투입될 수 있도록 해야 한다. 투입된 졸이 뱅크에 투입되어 섞이게 되는데, 원하는 마블질감을 내기 위해서는 투입된 졸이 많이 섞이지 않은 상태로 뱅크를 빠져나와 바닥재 원단에 코팅되어야 한다. 따라서, 뱅크에 졸이 머무는 시간이 길고, 졸 뱅크량(코우터 앞에서 코팅되기 바로 전에 잠시 모여있는 졸의 양)이 많아지면 서로 다른 점도의 두가지 졸이 많이 섞이게 되어 원하는 마블질감을 얻을 수 없으므로, 졸 뱅크량은 유색졸끼리 많이 섞이지 않은 상태에서 원하는 마블질감으로 코팅될 수 있도록 일정한 양으로 유지하는 것이 바람직하다. 즉, 라인속도와 유색졸 A, B의 투입량을 각각 균일하게 유지함으로써, 유색졸이 필요 이상으로 많이 섞이기 이전에 원단에 코팅될 수 있도록 하여야 한다.As shown in Figure 4, the addition of the color sol is made through the pipes for the color sol A, B input having a different diameter predetermined according to the amount and viscosity of each color sol, each color sol is added to the bank temporarily It stays for a while (the stage where the sol is gathered just before coating in front of the coater) and is coated on the flooring fabric made of the base layer 10. When injecting the sol through the pipe, it is preferable to inject the sol in three places: the center of the fabric, the center of the fabric and the left end, and the center of the fabric and the right end, to give a uniform marble texture. To do this, keep the line speed uniform. Sol injection should take into account the coating thickness and line speed so that it can be added continuously rather than instantaneously and discontinuously. The sol is introduced into the bank and mixed, and in order to produce the desired marble texture, the sol must be exited from the bank without being mixed and coated on the flooring fabric. Therefore, if the sol stays in the bank for a long time and the amount of sol bank (the amount of sol gathered for a while before being coated in front of the coater) increases, the two sol having different viscosities are mixed, so that the desired marble texture cannot be obtained. The amount of the sol bank is preferably maintained at a constant amount so that the colored sol can be coated with a desired marble texture without mixing a lot of colored sol. That is, by maintaining the line speed and the amount of the colored sol A and B uniformly, the colored sol should be coated on the fabric before mixing the colored sol more than necessary.

투입되는 졸의 양은 마블 정도에 따라 유색졸 A(2')와 유색졸 B(2'')를 8:2∼9.5:0.5의 비율로 투입되도록 2종의 유색졸의 점도를 고려하여 배관 크기의 조정이 필요하다. 유색졸 A에 대한 유색졸 B의 비율이 상기 비율보다 높을 경우, 제조된 바닥재의 마블질감이 혼란스럽고 지저분하여 외관상 좋지 않고, 유색졸 A에 대한 유색졸 B의 비율이 상기 비율보다 낮을 경우, 2종의 유색졸의 색상의 부분적인 혼합에 의한 마블질감의 부여효과가 미미하므로 바람직하지 않다.The amount of sol added is pipe size considering the viscosity of the two colored sol so that colored sol A (2 ') and colored sol B (2' ') are added at a ratio of 8: 2 to 9.5: 0.5. Need adjustment. When the ratio of colored sol B to colored sol A is higher than the above ratio, the marble texture of the manufactured flooring material is confusing and dirty, and the appearance is not good, and when the ratio of colored sol B to colored sol A is lower than the ratio, 2 It is not preferable because the effect of imparting marble texture by the partial mixing of the color of the colored sol of the species is insignificant.

효과적인 마블질감을 부여하기 위해, 유색졸 A(2')와 유색졸 B(2'')는 상이한 점도를 갖는 것을 사용하는 것이 바람직한데, 제품 기본 색상을 유지하는 유색졸 A(2')의 경우 4,000∼7,000cps, 마블질감을 부여하는 유색졸 B(2'')의 경우 10,000∼15,000cps의 점도를 갖는 것이 바람직하다. 상이한 점도를 갖는 유색졸 A와 유색졸 B를 사용하는 것은 졸의 유동특성을 이용하여 유동성 차이를 주므로써 마블질감을 효과적으로 부여하기 위한 것인데, 기본이 되는 기본색(유색졸 A)의 경우 점도를 저점도화하여 원단 전체에서 균일하게 코팅이 되도록 유도하면서, 포인트색(유색졸 B)의 경우 점도를 고점도화하여 유색졸 A와 혼합되어 색상이 혼색되는 현상을 최소화하고자 하는 것이다.In order to give an effective marble texture, it is preferable to use colored sol A (2 ') and colored sol B (2' ') having different viscosities. In the case of colored sol B (2 ") giving 4,000 to 7,000 cps and marble texture, it is preferable to have a viscosity of 10,000 to 15,000 cps. The use of colored sol A and colored sol B having different viscosities is to effectively give a marble texture by varying the fluidity by using the flow characteristics of the sol. In the case of the basic color (colored sol A), It is intended to minimize the phenomenon of color mixing by mixing with colored sol A by increasing the viscosity in the case of point color (colored sol B) while lowering the viscosity to induce uniform coating throughout the fabric.

상기 유색접착층(2) 위에 투명층(3)을 적층한다. 투명층(3)은 유색접착층(2) 위에 0.05∼0.5mm의 두께로 나이프 코팅하여 130∼230℃에서 3∼10m/min의 속도로 60∼240초 동안 가열하여 겔화시켜 형성시킨다. The transparent layer 3 is laminated on the colored adhesive layer 2. The transparent layer 3 is formed by gel coating on the colored adhesive layer 2 with a thickness of 0.05 to 0.5 mm and gelling by heating at 130 to 230 ° C. at a rate of 3 to 10 m / min for 60 to 240 seconds.

투명층(3)의 조성물은, 예를 들어 중합도 1000∼2000의 염화비닐수지 100중량부에 가소제 20∼60중량부, 안정제 1∼5중량부 및 기타 첨가제를 혼합하여 졸상태로 만든 것이 바람직하다. The composition of the transparent layer 3 is preferably made into a sol state by mixing 20 to 60 parts by weight of a plasticizer, 1 to 5 parts by weight of a stabilizer and other additives to 100 parts by weight of a vinyl chloride resin having a polymerization degree of 1000 to 2000, for example.

이렇게 형성된 투명층(3) 위에 표면처리층(4)을 형성시킨다. 표면처리층(4)은 자외선 경화형 폴리우레탄 도료를 투명층(3) 위에 10∼25㎛ 두께로 적층하여 3∼10m/min의 속도로 60∼300watt/in 출력의 UV 램프 3∼8개를 사용하여 경화시키므로써 형성된다.The surface treatment layer 4 is formed on the transparent layer 3 thus formed. The surface treatment layer 4 is formed by laminating a UV curable polyurethane paint on the transparent layer 3 to a thickness of 10 to 25 μm and using 3 to 8 UV lamps having a power of 60 to 300 watt / in at a speed of 3 to 10 m / min. It is formed by curing.

상기 바닥재의 각 구성층에서 사용된 가소제는 디옥틸프탈레이트(DOP), 텍사놀이소부틸레이트(TXIB), 부틸벤질프탈레이트(BBP), 에폭시화 대두유(ESO) 등이 있고, 안정제로는 Ba-Zn계 내열(발포)안정제, Cd-Ba-Zn계 내열(발포)안정제, 유기 주석계 안정제 등을 사용하며, 충진제로는 탄산칼슘, 실리카 분말 등을 사용한다. 또한 기타 첨가제로 사용되는 것들에는 공지의 안료나 점도저하제 등이 있다.Plasticizers used in each constituent layer of the flooring material include dioctyl phthalate (DOP), texanoxobutyrate (TXIB), butylbenzyl phthalate (BBP), epoxidized soybean oil (ESO), and the stabilizer Ba-Zn. A system heat-resistant (foaming) stabilizer, a Cd-Ba-Zn system heat-resistant (foaming) stabilizer, an organic tin stabilizer, etc. are used, and as a filler, calcium carbonate, silica powder, etc. are used. In addition, those used as other additives include known pigments and viscosity reducing agents.

이하에서는 구체적인 실시예를 통하여 본 발명을 설명하나, 본 발명은 이에 한정되는 것은 아니다.Hereinafter, the present invention will be described through specific examples, but the present invention is not limited thereto.

실시예Example

[기재층(10)의 형성][Formation of Base Layer 10]

유리섬유 기재 위에 중합도가 1700인 염화비닐수지 100중량부, 가소제인 디옥틸프탈레이트 70중량부, 에폭시 화합물 3중량부, 내열안정제인 바륨-아연계 화합물 3중량부, 점도저하제 5중량부, 충진제인 탄산칼슘 150중량부를 혼합한 조성물을 0.7mm의 두께로 나이프 코팅한 후, 부직포를 합판시켜 160℃의 겔링드럼에서 5m/min의 속도로 50초간 가열하면서 겔화시키므로써 기재층(10)을 형성시켰다.100 parts by weight of a vinyl chloride resin having a polymerization degree of 1700 on the glass fiber substrate, 70 parts by weight of dioctylphthalate as a plasticizer, 3 parts by weight of an epoxy compound, 3 parts by weight of a barium-zinc compound as a heat stabilizer, 5 parts by weight of a viscosity reducing agent, and a filler After the composition of 150 parts by weight of calcium carbonate was knife-coated to a thickness of 0.7 mm, the nonwoven fabric was laminated and gelled while heating for 50 seconds at a rate of 5 m / min in a gelling drum at 160 ° C. to form the base layer 10. .

[유색접착층(2)의 형성][Formation of Colored Adhesive Layer 2]

상기 기재층(10) 위에 중합도 1700인 염화비닐수지 100중량부에 대하여, 가소제인 디옥틸프탈레이트 75중량부, 에폭시 화합물 3중량부, 내열안정제인 바륨-아연계 화합물 3중량부, 점도저하제 8중량부, 충진제인 탄산칼슘 150중량부, 안료 0.2중량부를 포함하는 유색졸 A(2'), 가소제인 디옥틸프탈레이트 60중량부, 에폭시 화합물 3중량부, 내열안정제인 바륨-아연계 화합물 3중량부, 점도저하제 5중량부, 충진제인 탄산칼슘 150중량부, 안료 0.4중량부를 혼합한 유색졸 B를 동시에 9:1의 비율로 투입한 후, 1.0mm 두께로 나이프 코팅하여 유색접착층(2)을 형성시켰다.75 parts by weight of dioctylphthalate as a plasticizer, 3 parts by weight of an epoxy compound, 3 parts by weight of a barium-zinc-based compound as a heat stabilizer, and 8 parts by weight of a viscosity reducing agent based on 100 parts by weight of a vinyl chloride resin having a polymerization degree of 1700 on the substrate layer 10. Parts, 150 parts by weight of calcium carbonate as a filler, colored sol A (2 ') containing 0.2 parts by weight of pigment, 60 parts by weight of dioctylphthalate as a plasticizer, 3 parts by weight of epoxy compound, 3 parts by weight of barium-zinc compound as heat stabilizer , 5 parts by weight of a viscosity reducing agent, 150 parts by weight of calcium carbonate as a filler, and 0.4 parts by weight of pigment were mixed at a ratio of 9: 1 at the same time, and then knife-coated to 1.0 mm thickness to form a colored adhesive layer 2. I was.

[투명층(3)의 형성][Formation of the transparent layer 3]

상기 유색접착층(2) 위에 중합도가 1700인 염화비닐수지 100중량부, 가소제인 디옥틸프탈레이트 30중량부, 에폭시 화합물 3중량부, 내열안정제인 바륨-아연계 화합물 3중량부, 점도저하제 5중량부를 혼합한 조성물을 0.3mm의 두께로 나이프 코팅한 후 170℃의 오븐에서 30m/min의 속도로 1분 30초간 가열하여 투명층(3)을 형성시켰다.100 parts by weight of a vinyl chloride resin having a polymerization degree of 1700, 30 parts by weight of dioctylphthalate as a plasticizer, 3 parts by weight of an epoxy compound, 3 parts by weight of a barium-zinc-based compound as a heat stabilizer, and 5 parts by weight of a viscosity reducing agent on the colored adhesive layer 2. The mixed composition was knife coated to a thickness of 0.3 mm and then heated in a oven at 170 ° C. at a rate of 30 m / min for 1 minute and 30 seconds to form a transparent layer 3.

[표면처리층(4)의 형성][Formation of Surface Treatment Layer 4]

상기 투명층(3) 위에 자외선 경화형 폴리우레탄 도료를 15㎛ 두께로 적층하고, 5m/min의 속도로 80Watt/in 출력의 UV 램프 4개를 이용하여 경화시키므로써 표면처리층(4)을 형성시켰다.The UV curable polyurethane paint was laminated on the transparent layer 3 to a thickness of 15 μm, and cured by using four UV lamps of 80 Watt / in output at a rate of 5 m / min to form the surface treatment layer 4.

본 발명에 의하면, 다층구조의 바닥재에 있어서, 기재층 위에 유색접착층을 형성시, 색상과 점도가 상이한 2종의 유색졸을 동시에 투입하여 원단 진행과 동시에 2종의 유색졸의 색상이 부분적으로 혼합되므로써 마블질감이 부여된 바닥재 및 이의 제조방법이 제공된다.According to the present invention, in forming a colored adhesive layer on a base material layer, when the colored adhesive layer is formed on a base material layer, two kinds of colored sol having different colors and viscosities are simultaneously added, and the colors of the two colored sol are mixed at the same time as the fabric proceeds. Thereby it is provided with a flooring given a marble texture and a method of manufacturing the same.

도 1은 본 발명에 따른 바닥재의 제조공정을 설명하기 위한 블록선도.1 is a block diagram illustrating a manufacturing process of a flooring according to the present invention.

도 2 및 도 3은 본 발명에 따른 바닥재의 일실시예를 나타내는 단면도.2 and 3 are cross-sectional views showing one embodiment of the flooring according to the invention.

도 4는 본 발명에 따른 바닥재의 제조공정중 유색접착층(2) 형성시, 유색졸 A와 유색졸 B가 바닥재 원단이 진행됨에 따라 투입되어 마블질감이 부여되는 과정을 설명하기 위한 도면.Figure 4 is a view for explaining a process in which colored sol A and colored sol B are added as the bottom fabric proceeds to provide a marble texture during the formation of the colored adhesive layer 2 during the manufacturing process of the flooring according to the present invention.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

1 : 유리섬유 함침층 2 : 유색접착층1: glass fiber impregnated layer 2: colored adhesive layer

2': 유색졸 A 2'': 유색졸 B 2 ': colored sol A 2' ': colored sol B

3 : 투명층 4 : 표면처리층 3: transparent layer 4: surface treatment layer

10 : 기재층 11 : 부직포 합판층 10: base material layer 11: nonwoven plywood layer

12 : 비발포하부층 20 : 표면층12: non-foaming lower layer 20: surface layer

Claims (4)

기재층과 기재층 상부의 표면층으로 이루어진 다층구조의 바닥재에 있어서, 상기 표면층에, 색상과 점도가 상이한 2종의 유색졸에 의해 마블질감이 부여된 유색접착층을 포함하는 것을 특징으로 하는 바닥재.A flooring having a multilayer structure comprising a base layer and a surface layer on top of the base layer, wherein the surface layer includes a colored adhesive layer imparted with a marbling feel by two kinds of colored sol having different colors and viscosities. 제 1항에 있어서, 상기 2종의 유색졸중 하나는 4,000∼7,000cps, 다른 하나는 10,000∼15,000cps의 점도를 갖는 것을 특징으로 하는 바닥재.The flooring material of claim 1, wherein one of the two colored sol has a viscosity of 4,000 to 7,000 cps and the other of 10,000 to 15,000 cps. 제 1항 또는 제 2항에 있어서, 상기 기재층은 유리섬유 함침층의 하부에 부직포 합판층 또는 비발포하부층이 적층되어 이루어진 것이고, 상기 기재층 상부의 표면층은 기재층 위에 유색접착층, 투명층 및 표면처리층이 차례로 적층되어 이루어진 것임을 특징으로 하는 바닥재.According to claim 1 or 2, wherein the base layer is a non-woven plywood layer or a non-foamed lower layer laminated on the lower portion of the glass fiber impregnated layer, the surface layer on the base layer is a colored adhesive layer, a transparent layer and a surface on the base layer Flooring, characterized in that the treatment layer is made by laminating in sequence. 기재층과 기재층 상부의 표면층으로 이루어진 다층구조의 바닥재의 제조방법에 있어서, 상기 표면층에, 색상과 점도가 상이한 2종의 유색졸을 8:2∼9.5:0.5의 비율로 동시에 균일한 양으로 투입하여 균일한 라인속도 하에서 동시에 2종의 유색졸의 색상이 부분적으로 혼합되게 하여 마블질감이 부여된 유색접착층을 형성하는 것을 특징으로 하는 바닥재의 제조방법.In the method for producing a flooring material having a multi-layer structure consisting of a base layer and a surface layer on top of the base layer, at the same time a uniform amount of two colored sol having different colors and viscosities is added to the surface layer at a ratio of 8: 2 to 9.5: 0.5 simultaneously. A method of manufacturing a flooring material, characterized in that the color of the two colored sol at the same time under a uniform line speed to be partially mixed to form a colored adhesive layer with a marble texture.
KR1020030062507A 2003-09-08 2003-09-08 A floor with marble quality using two kinds of color sols which have different color and viscosity, and method for producing the same KR20050025701A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100715370B1 (en) * 2005-03-28 2007-05-07 김정배 Mobile terminal having karaoke function

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100715370B1 (en) * 2005-03-28 2007-05-07 김정배 Mobile terminal having karaoke function

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