KR20040045505A - Week acidic liquid soap and method for preparation thereof - Google Patents

Week acidic liquid soap and method for preparation thereof Download PDF

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Publication number
KR20040045505A
KR20040045505A KR1020020073306A KR20020073306A KR20040045505A KR 20040045505 A KR20040045505 A KR 20040045505A KR 1020020073306 A KR1020020073306 A KR 1020020073306A KR 20020073306 A KR20020073306 A KR 20020073306A KR 20040045505 A KR20040045505 A KR 20040045505A
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metallic salt
weight
liquid soap
amine
ammonium lauryl
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KR1020020073306A
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Korean (ko)
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임호
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임호
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/30Organic compounds, e.g. vitamins containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D13/00Making of soap or soap solutions in general; Apparatus therefor
    • C11D13/12Cooling
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/08Liquid soap, e.g. for dispensers; capsuled
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/02Compositions of detergents based essentially on soap on alkali or ammonium soaps
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/18Water-insoluble compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/26Organic compounds, e.g. vitamins containing oxygen
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/22Organic compounds, e.g. vitamins
    • C11D9/32Organic compounds, e.g. vitamins containing sulfur
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/44Perfumes; Colouring materials; Brightening agents ; Bleaching agents
    • C11D9/442Perfumes

Abstract

PURPOSE: A weakly acidic liquid soap composition and its preparation method are provided, to obtain a soap with a pH of 5.2-5.8 having excellent moisturizing and cleansing effects and reduced stimulus to the skin. CONSTITUTION: The weakly acidic liquid soap composition comprises 50 wt% or more of amino acid-series fatty acid condensate; 3.0 wt% of ceramic powder; and 0.05 wt% of an antibacterial agent. Preferably the antibacterial agent is isothiazoline, and the ceramic powder is germanium powder having an average diameter of 1.5-1.7 micrometers. Preferably the composition comprises 5.0-15.0 wt% of fatty alkyl glutamate metallic salt; 15.0-20.0 wt% of ammonium lauryl sulfate; 3.0-7.0 wt% of cocoamidopropyl betaine; 2.0-3.0 wt% of glycerine monostearate; 2.0-3.0 wt% of glycerine; 1.0-2.0 wt% of citric acid; 2.0 wt% of dimethiocone; 1.0-2.0 wt% of coconut oil fatty acid; 3.0 wt% of ceramic powder; 0.5 wt% of an antibacterial agent; 0.05 wt% of a perfume; three to five element selected from 5.0-10.0 wt% of fatty alkyl isethionate metallic salt, 3.0-7.0 wt% of ammonium lauryl ether sulfate, 0.5-2.0 wt% of cocomonoethanol amine and 0.5-1.0 wt% of cocodiethanol amine; and the balance of ionized water.

Description

약산성 액상 비누 및 그 제조방법{WEEK ACIDIC LIQUID SOAP AND METHOD FOR PREPARATION THEREOF}Weak acid liquid soap and its manufacturing method {WEEK ACIDIC LIQUID SOAP AND METHOD FOR PREPARATION THEREOF}

본 발명은 pH 5.2-5.8 의 범위를 갖는 약산성 액상 비누 및 그 제조방법에 관한 것으로 , 좀더 상세하게는 아미노산 계열의 지방산 축합물을 50 중량% 이상 함유하고, 세라믹 파우더 3.0 중량% 및 항균제를 0.05 중량% 함유한 것을 특징으로 하는 약산성 액상 비누 및 그 제조방법에 관한 것이다.The present invention relates to a weakly acidic liquid soap having a pH in the range of 5.2-5.8 and a method for producing the same, more specifically, containing at least 50% by weight of fatty acid condensates of amino acid series, 3.0% by weight of ceramic powder and 0.05% by weight of antibacterial agent. The present invention relates to a weakly acidic liquid soap and a method for producing the same.

종래의 일반적인 화장비누는 우지, 야자, 팜, 팜핵유 등의 동, 식물 유지나 그 지방산을 가성소다(NaOH)나 가성칼륨(KOH)등으로 직접 검화 또는 중화시켜 알칼리성을 갖는 지방산염을 만들고 여기에 적당한 향료와 색소가 첨가된 것으로서, 이들의 pH 는 통상 7-12의 범위로서 지속적으로 사용시 피부 손상을 초래할 뿐 만 아니라, 알칼리성으로 인하여 피부 각질 등을 발생시키고 세정성 외에 피부에 특별히 우수한 효과를 내는 것은 없었다.Conventional cosmetic soaps are made of fatty acid having alkalinity by directly saponifying or neutralizing copper, plant oils and fatty acids such as tallow, palm, palm, palm kernel oil, and fatty acids with caustic soda (NaOH) or caustic potassium (KOH). With the addition of suitable fragrances and pigments, their pH is usually in the range of 7-12, which not only causes skin damage when used continuously, but also causes skin keratin, etc. due to alkalinity, and has a particularly good effect on skin besides cleansing properties. There was nothing.

이에, 알칼리에 의한 자극을 줄이기 위해서는 합성 계면활성제를 주원료로 사용하여 중성 내지 약산성 pH를 갖는 비누가 나오기는 하나, 제조공정이 까다롭고사용시 물성이 나쁘기 때문에 널리 사용되지 못하고 있다.Thus, in order to reduce the irritation caused by alkali, soaps having a neutral to weakly acidic pH are produced by using a synthetic surfactant as a main raw material, but they are not widely used because of the difficult manufacturing process and poor physical properties.

따라서, 본 발명은 이러한 종래의 문제점을 개선하고자 발명된 것으로서, 아미노산 계열의 지방산 축합물을 50% 이상 함유하고, 세라믹파우더 및 항균제를 함유함으로서 노폐물 제거는 물론, 원적외선 방출로 피로회복 효과를 갖는 약산성 액상 비누를 제공하고자 한다.Therefore, the present invention has been invented to improve such a conventional problem, by containing more than 50% of the amino acid-based fatty acid condensate, and containing a ceramic powder and an antimicrobial agent to remove the waste, as well as weak acidity having a fatigue recovery effect by far-infrared emission To provide a liquid soap.

본 발명의 또 다른 목적은 이러한 약산성 액상 비누의 제조방법을 제공하고자 한다.Another object of the present invention is to provide a method for preparing such weakly acidic liquid soap.

상기한 발명의 목적을 달성하기위하여, 본 발명의 약산성 액상 비누는 아미노산 계열의 지방산 축합물을 50 중량% 이상 함유하고, 원적외선 방사율이 높은 세라믹 파우더 3.0 중량% 및 항균제 0.05 중량%를 포함함으로서 원적외선 방사 뿐 만 아니라, 피부에 기생하는 독성 세균을 살균함으로서, 피부 자극 없이 피부 세정력이 증진 될 뿐 만 아니라, 피부 보습력이 뛰어난 효과를 갖는다.In order to achieve the object of the present invention, the weakly acidic liquid soap of the present invention contains more than 50% by weight of fatty acid condensates of the amino acid series, 3.0% by weight of far-infrared emissivity ceramic powder and 0.05% by weight of antimicrobial agent to far-infrared radiation In addition, by sterilizing the toxic bacteria parasitic on the skin, not only skin irritation is enhanced without skin irritation, but also has excellent skin moisturizing power.

세라믹 파우더는 원적외선 방사율이 높은 게르마늄이 바람직하고, 평균 입자의 직경은 1.5-1.7㎛가 가장 적당하다. 항균제는 일반적인 항균제로 알려진 이소티아졸린(isothiazoline) 등이 바람직하다.The ceramic powder is preferably germanium having a high far-infrared emissivity, and an average particle diameter of 1.5-1.7 mu m is most suitable. The antimicrobial agent is preferably isothiazoline (isothiazoline) known as a general antimicrobial agent.

좀더 상세하게는, 본 발명은 액상 비누 조성물 중량 기준 5.0-15.0 중량%의 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt), 15.0-20.0중량%의 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 3.0-7.0 중량%의 코코아미도프로필 베탄(cocoamidopropyl betane), 2.0-3.0 중량%의 글리세린 모노스테아레이트(glycerine monostearate), 2.0-3.0 중량%의 글리세린, 1.0-2.0 중량%의 시트르산, 2.0 중량%의 디메치콘, 1.0-2.0 중량%의 야자유 지방산, 3.0 중량%의 세라믹파우더, 0.5 중량%의 항균제, 0.05 중량%의 향료 및 3.0-10.0 중량%의 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 2.0-10.0 중량%의 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 3.0-7.0 중량%의 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 1-2.0 중량%의 코코모노에탄올 아민(cocomonoethanol amine), 0.5-2.0 중량%의 코코다이에탄올 아민(cocodiethanol amine)으로 구성된 군에서 선택되는 세개 내지 다섯개의 구성 성분을 포함하고, 나머지는 이온수로 구성되는 것을 특징으로 한다.More specifically, the present invention is 5.0-15.0% by weight of fatty alkyl glutamate metallic salt, 15.0-20.0% by weight of ammonium lauryl sulfate, 3.0 by weight of the liquid soap composition -7.0 wt% cocoamidopropyl betane, 2.0-3.0 wt% glycerin monostearate, 2.0-3.0 wt% glycerin, 1.0-2.0 wt% citric acid, 2.0 wt% dimeth Chicon, 1.0-2.0 wt% palm oil fatty acid, 3.0 wt% ceramic powder, 0.5 wt% antibacterial agent, 0.05 wt% fragrance, and 3.0-10.0 wt% fatty alkyl isethionate metallic salt , 2.0-10.0% by weight of fatty alkyl taurate metallic salt, 3.0-7.0% by weight of ammonium lauryl ether sulfate, 1-2.0% by weight of cocomonoethanol amine (cocomonoethanol amine), 0 .5-2.0% by weight of cocodiethanol amine (cocodiethanol amine) comprises three to five components selected from the group consisting of, the remainder is characterized by consisting of ionic water.

이러한 본 발명의 조성물은 하기의 제조방법을 통하여 제조된다. :Such a composition of the present invention is prepared through the following manufacturing method. :

액상 비누 조성물 중량 기준으로 2-3 중량%의 글리세린모노스테아레이트, 3.0 중량%의 세라믹 파우더, 3.0-10.0 중량%의 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 2.0-10.0 중량%의 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 5.0-15.0 중량%의 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt), 15.0-20.0 중량%의 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 3.0-7.0 중량%의 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 3.0-7.0 중량%의 코코아미도프로필 베탄(cocoamidopropyl betane), 1.0-2.0 중량%의 코코모노에탄올아민(cocomonoethanol amine), 0.5-2.0 중량%의 코코다이에탄올 아민(cocodiethanol amine), 2.0-3.0 중량%의 글리세린, 1.0-2.0 중량%의 시트르산, 2.0 중량%의 디메치콘, 1.0-2.0 중량%의 야자유 지방산, 0.5 중량%의 항균제, 0.05 중량%의 향료를 준비하고, 나머지 중량의 이온수를 준비하는 단계;2-3 weight percent glycerin monostearate, 3.0 weight percent ceramic powder, 3.0-10.0 weight percent fat alkyl isethionate metallic salt, 2.0-10.0 weight percent based on the weight of the liquid soap composition Fatty alkyl taurate metallic salt, 5.0-15.0 wt% fatty alkyl glutamate metallic salt, 15.0-20.0 wt% ammonium lauryl sulfate, 3.0-7.0% by weight of ammonium lauryl ether sulfate, 3.0-7.0% by weight of cocoamidopropyl betane, 1.0-2.0% by weight of cocomonoethanol amine, 0.5-2.0 wt% cocodiethanol amine, 2.0-3.0 wt% glycerin, 1.0-2.0 wt% citric acid, 2.0 wt% dimethicone, 1.0-2.0 wt% palm oil fatty acid, 0.5 wt% Antibacterial, 0.05% by weight Preparing a perfume and preparing remaining weight of ionized water;

이온수를 70-80℃로 승온시킨 후 글리세린 모노스테아레이트(glycerine monostearate) 및 게르마늄파우더를 첨가하여 녹이는 단계;Warming the ionized water to 70-80 ° C. and then dissolving by adding glycerine monostearate and germanium powder;

50-60℃를 유지하면서 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)을 첨가하는 단계;Adding fatty alkyl isethionate metallic salt, fatty alkyl taurate metallic salt, and fatty alkyl glutamate metallic salt at 50-60 ° C. ;

암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 코코아미도프로필 베탄(cocoamidopropyl betane), 코코모노에탄올 아민(cocomonoethanol amine), 글리세린, 시트르산, 디메치콘, 야자유 지방산, 항균제, 향료를 첨가하는 단계; 및Ammonium lauryl sulfate, ammonium lauryl ether sulfate, cocoamidopropyl betane, cocomonoethanol amine, glycerin, citric acid, dimethicone Adding palm oil fatty acid, antibacterial and flavoring; And

40-50℃로 냉각시키는 단계.Cooling to 40-50 ° C.

하기의 실시예를 통하여 본 발명을 상세히 설명하나, 본 발명이 이에 제한되지는 않는다.The present invention will be described in detail through the following examples, but the present invention is not limited thereto.

[실시예 1]Example 1

액상 비누 조성물 중량 기준으로 3.0 중량%의 글리세린모노스테아레이트,3.0 중량%의 세라믹 파우더, 5.0 중량%의 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 5.0 중량%의 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 10.0 중량%의 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt), 15.0 중량%의 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 7.0 중량%의 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 3.0 중량%의 코코아미도프로필 베탄(cocoamidopropyl betane), 2.0 중량%의 코코모노에탄올 아민(cocomonoethanol amine), 2.0 중량%의 글리세린, 1.0 중량%의 시트르산, 2.0 중량%의 디메치콘, 2.0 중량%의 야자유 지방산, 0.5 중량%의 항균제, 0.05 중량%의 향료를 준비하고, 나머지 중량의 이온수를 준비한다.3.0 weight percent glycerin monostearate, 3.0 weight percent ceramic powder, 5.0 weight percent fat alkyl isethionate metallic salt, 5.0 weight percent pattyalkyl taurate metal salt by weight of the liquid soap composition (fatty alkyl taurate metallic salt), 10.0% by weight of fatty alkyl glutamate metallic salt, 15.0% by weight of ammonium lauryl sulfate, 7.0% by weight of ammonium lauryl ether sulfate Ammonium lauryl ether sulfate, 3.0 wt% cocoamidopropyl betane, 2.0 wt% cococomonoethanol amine, 2.0 wt% glycerin, 1.0 wt% citric acid, 2.0 wt% Dimethicone, 2.0% by weight palm oil fatty acid, 0.5% by weight antimicrobial agent, 0.05% by weight fragrance is prepared, and the remaining weight of deionized water is prepared.

이온수를 제조기에 투입한 후 이온수의 온도를 70-80℃로 승온시킨 후 고온의 물에 녹는 성질을 갖는 원료인 글리세린 모노스테아레이트(glycerine monostearate) 및 게르마늄 파우더를 투입하여 녹인다. 그 후 분말인 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)을 첨가 교반하여 물에 분산시킨다. 이때, 제조기의 온도는 50-60℃를 유지시킨다. 그 후 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 코코아미도프로필 베탄(cocoamidopropyl betane), 코코모노에탄올 아민(cocomonoethanol amine), 글리세린, 시트르산, 디메치콘, 야자유 지방산, 항균제인 헬스가드, 향료를 교반하면서 순차적으로 투입한다.After the ionized water is introduced into the manufacturing machine, the temperature of the ionized water is raised to 70-80 ° C, and then dissolved by adding glycerine monostearate and germanium powder, which are raw materials having a property of dissolving in high temperature water. Then, the powder is added to the mixture by stirring the fatty alkyl isethionate metallic salt, the fatty alkyl taurate metallic salt and the fatty alkyl glutamate metallic salt. Let's do it. At this time, the temperature of the manufacturer is maintained at 50-60 ℃. Ammonium lauryl sulfate, ammonium lauryl ether sulfate, cocoamidopropyl betane, cocomonoethanol amine, glycerin, citric acid, Dimethicone, palm oil fatty acid, health guard (antibacterial agent), and fragrance are sequentially added while stirring.

제조기의 온도를 40-50℃로 냉각시킴으로서 물비누 조성물을 완성하였다.The water soap composition was completed by cooling the temperature of the maker to 40-50 ° C.

헬스가드는 이소티아졸린, 다이에틸 글리콜 모노부틸에테르, 및 계면활성제 및 유화제를 포함하는 조성물로서 Australian Textile Chemicals P/L 에서 구입한 것으로 항균력이 높은 조성물이다.Hellguard is a high antimicrobial composition purchased from Australian Textile Chemicals P / L as a composition comprising isothiazoline, diethyl glycol monobutylether, and a surfactant and an emulsifier.

연대 의대 부설 알레르기 연구소에서 헬스가드를 처리한 천으로서 집먼지 진드기를 치사율 및 기피율을 실험한 결과는 하기와 같다.The results of testing the house dust mite mortality and evasion rate as a cloth treated with health guard at the Allergy Research Institute affiliated with Yantai University of Medicine are as follows.

0.5% 헬스가드로 처리한 천에서 집먼지진드기를 3일간 사육할 경우 전체 집 먼지진드기 중 36%가 기피하였으며, 33.3%가 죽었다.When house dust mites were bred for three days in a cloth treated with 0.5% health guard, 36% of all house dust mites avoided and 33.3% died.

0.3% 헬스가드로 처리한 천에서도 유사한 결과가 관찰되었다. (기피율 21.3%, 치사율 66.1%). 0.1% 헬스가드로 처리한 천에서는 기피율과 치사율이 12.0%, 27.3%로 비교적 낮았다. 이를 종합하여 판단 시 헬스가드로 처리한 천이 모두 대조천에 비하여 기피율 및 치사율이 높았다.Similar results were observed with fabrics treated with 0.3% Hellguard. (21.3% evasion, 66.1% mortality). In the fabric treated with 0.1% health guard, the evasion rate and lethality were 12.0% and 27.3%, respectively. In conclusion, all the fabrics treated with health guard had higher evasion rate and mortality rate than the control cloth.

[실시예 2]Example 2

실시예 1의 방법으로 본 발명의 조성물을 제조하되, 각 조성물의 중량비는 하기 표 1과 같다.To prepare a composition of the present invention by the method of Example 1, the weight ratio of each composition is shown in Table 1.

표 1Table 1

조성Furtherance 함량(중량%)Content (% by weight) 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt)Fatty alkyl isethionate metallic salt 7.07.0 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt)Fatty alkyl taurate metallic salt 5.05.0 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)Fatty alkyl glutamate metallic salt 8.08.0 암모늄 라우릴 설패이트 (ammonium lauryl sulfate)Ammonium lauryl sulfate 15.015.0 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate)Ammonium lauryl ether sulfate 5.05.0 코코아미도프로필 베탄(cocoamidopropyl betane)Cocoamidopropyl betane 3.03.0 코코모노에탄올아민(cocomonoethanol amine)Cocomonoethanol amine 1.51.5 코코다이에탄올 아민(cocodiethanol amine)Cocodiethanol amine 0.50.5 글리세린 모노스테아레이트(glycerine monostearate)Glycerine monostearate 3.03.0 글리세린glycerin 2.02.0 시트르산Citric acid 1.01.0 디메치콘Dimethicone 2.02.0 야자유 지방산Palm oil fatty acid 2.02.0 게르마늄 분말Germanium powder 3.03.0 항균제인 헬스가드Health Guard Antibacterial 0.50.5 향료Spices 0.050.05

[실시예 3]Example 3

실시예 1의 방법으로 본 발명의 조성물을 제조하되, 각 조성물의 중량비는 하기표 2와 같다.To prepare a composition of the present invention by the method of Example 1, the weight ratio of each composition is shown in Table 2.

표 2TABLE 2

조성Furtherance 함량(중량%)Content (% by weight) 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt)Fatty alkyl isethionate metallic salt 3.03.0 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt)Fatty alkyl taurate metallic salt 2.02.0 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)Fatty alkyl glutamate metallic salt 15.015.0 암모늄 라우릴 설패이트 (ammonium lauryl sulfate)Ammonium lauryl sulfate 20.020.0 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate)Ammonium lauryl ether sulfate 3.03.0 코코아미도프로필 베탄(cocoamidopropyl betane)Cocoamidopropyl betane 5.05.0 코코모노에탄올아민(cocomonoethanol amine)Cocomonoethanol amine 1.01.0 코코다이에탄올 아민(cocodiethanol amine)Cocodiethanol amine 1.01.0 글리세린 모노스테아레이트(glycerine monostearate)Glycerine monostearate 2.02.0 글리세린glycerin 3.03.0 시트르산Citric acid 1.01.0 디메치콘Dimethicone 2.02.0 야자유 지방산Palm oil fatty acid 2.02.0 게르마늄 분말Germanium powder 3.03.0 항균제인 헬스가드Health Guard Antibacterial 0.50.5 향료Spices 0.050.05

[실시예 4]Example 4

실시예 1의 방법으로 본 발명의 조성물을 제조하되, 각 조성물의 중량비는 하기 표 3과 같다.To prepare a composition of the present invention by the method of Example 1, the weight ratio of each composition is shown in Table 3.

표 3TABLE 3

조성Furtherance 함량(중량%)Content (% by weight) 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt)Fatty alkyl isethionate metallic salt 10.010.0 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt)Fatty alkyl taurate metallic salt 5.05.0 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)Fatty alkyl glutamate metallic salt 5.05.0 암모늄 라우릴 설패이트 (ammonium lauryl sulfate)Ammonium lauryl sulfate 20.020.0 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate)Ammonium lauryl ether sulfate 코코아미도프로필 베탄(cocoamidopropyl betane)Cocoamidopropyl betane 5.05.0 코코모노에탄올아민(cocomonoethanol amine)Cocomonoethanol amine 코코다이에탄올 아민(cocodiethanol amine)Cocodiethanol amine 2.02.0 글리세린 모노스테아레이트(glycerine monostearate)Glycerine monostearate 3.03.0 글리세린glycerin 2.02.0 시트르산Citric acid 1.01.0 디메치콘Dimethicone 2.02.0 야자유 지방산Palm oil fatty acid 1.01.0 게르마늄 분말Germanium powder 3.03.0 항균제인 헬스가드Health Guard Antibacterial 0.50.5 향료Spices 0.050.05

[실시예 5]Example 5

실시예 1의 방법으로 본 발명의 조성물을 제조하되, 각 조성물의 중량비는 하기 표 4와 같다.To prepare a composition of the present invention by the method of Example 1, the weight ratio of each composition is shown in Table 4.

표 4Table 4

조성Furtherance 함량(중량%)Content (% by weight) 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt)Fatty alkyl isethionate metallic salt 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt)Fatty alkyl taurate metallic salt 10.010.0 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)Fatty alkyl glutamate metallic salt 10.010.0 암모늄 라우릴 설패이트 (ammonium lauryl sulfate)Ammonium lauryl sulfate 15.015.0 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate)Ammonium lauryl ether sulfate 5.05.0 코코아미도프로필 베탄(cocoamidopropyl betane)Cocoamidopropyl betane 5.05.0 코코모노에탄올아민(cocomonoethanol amine)Cocomonoethanol amine 2.02.0 코코다이에탄올 아민(cocodiethanol amine)Cocodiethanol amine 1.01.0 글리세린 모노스테아레이트(glycerine monostearate)Glycerine monostearate 2.02.0 글리세린glycerin 2.02.0 시트르산Citric acid 1.01.0 디메치콘Dimethicone 2.02.0 야자유 지방산Palm oil fatty acid 1.01.0 게르마늄 분말Germanium powder 3.03.0 항균제인 헬스가드Health Guard Antibacterial 0.50.5 향료Spices 0.050.05

[실시예 6]Example 6

실시예 1의 방법으로 본 발명의 조성물을 제조하되, 각 조성물의 중량비는 하기 표 5와 같다.To prepare a composition of the present invention by the method of Example 1, the weight ratio of each composition is shown in Table 5.

표 5Table 5

조성Furtherance 함량(중량%)Content (% by weight) 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt)Fatty alkyl isethionate metallic salt 5.05.0 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt)Fatty alkyl taurate metallic salt 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)Fatty alkyl glutamate metallic salt 15.015.0 암모늄 라우릴 설패이트 (ammonium lauryl sulfate)Ammonium lauryl sulfate 15.015.0 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate)Ammonium lauryl ether sulfate 5.05.0 코코아미도프로필 베탄(cocoamidopropyl betane)Cocoamidopropyl betane 7.07.0 코코모노에탄올아민(cocomonoethanol amine)Cocomonoethanol amine 2.02.0 코코다이에탄올 아민(cocodiethanol amine)Cocodiethanol amine 글리세린 모노스테아레이트(glycerine monostearate)Glycerine monostearate 2.02.0 글리세린glycerin 2.02.0 시트르산Citric acid 2.02.0 디메치콘Dimethicone 2.02.0 야자유 지방산Palm oil fatty acid 2.02.0 게르마늄 분말Germanium powder 3.03.0 항균제인 헬스가드Health Guard Antibacterial 0.50.5 향료Spices 0.050.05

각각의 실시예에 의하여 제조된 조성물은 원적외선 방사효과가 입증된 게르마늄 및 항균효과가 뛰어난 항균제의 일종인 헬스가드를 사용함으로서 종래의 비누에 비하여 피부세정력 등을 높이는 효과를 갖는 것을 확인하였다.The composition prepared by each example was confirmed to have an effect of increasing skin cleansing power and the like compared to conventional soap by using a health guard which is a kind of antimicrobial excellent germanium and antimicrobial effect is proved far infrared radiation effect.

이상에서 살펴본 바와 같이, 본 발명의 조성물은 아미노산 계열의 지방산 축합물을 50% 이상 함유하고, 게르마늄 파우더 3.0% 및 항균제 0.05% 함유함으로서, 약산성의 pH를 가짐으로서 피부 친화적이며, 피부노화를 방지시켜 주고, 피부자극이 없을 뿐 만 아니라, 보습성, 세정성, 생분해성이 우수한 효과를 갖는다.As described above, the composition of the present invention contains more than 50% of the amino acid-based fatty acid condensate, 3.0% germanium powder and 0.05% antimicrobial agent, having a slightly acidic pH, skin-friendly, prevent skin aging Not only has no skin irritation, but also has excellent moisturizing properties, cleansing properties and biodegradability.

즉, 게르마늄 파우더는 피부모공내의 노폐물을 제거하여 피부표면에 지방 및 노폐물의 축적을 방지할 뿐 만 아니라, 지속적인 원적외선 방출로 혈액순환 및 피로회복에 우수한 효과를 발휘한다.In other words, germanium powder not only removes wastes in the skin pores, but also prevents accumulation of fats and wastes on the surface of the skin, and has an excellent effect on blood circulation and fatigue recovery through continuous far infrared emission.

또한, 항균제의 함유로 피부표면 및 모공 내에 존재하는 독성 균류를 제거함으로써 감기 및 질병의 예방에 탁월한 효과를 발휘한다.In addition, it contains an antimicrobial agent to remove toxic fungi present in the skin surface and pores, thereby exerting an excellent effect on the prevention of colds and diseases.

Claims (7)

액상 비누 조성물 중량 기준으로 50 중량% 이상의 아미노산 계열의 지방산축합물, 3.0 중량%의 세라믹 파우더 및 0.05%의 항균제를 포함 하는 것을 특징으로 약산성 액상비누 조성물.A weakly acidic liquid soap composition, characterized in that it comprises at least 50% by weight of amino acid-based fatty acid condensate, 3.0% by weight of ceramic powder, and 0.05% of antibacterial agent by weight of the liquid soap composition. 제 1항에 있어서,The method of claim 1, 항균제는 이소티아졸린인 것을 특징으로 하는 약산성 액상 비누 조성물.A weakly acidic liquid soap composition, wherein the antimicrobial agent is isothiazoline. 제 1항 또는 제 2항에 있어서,The method according to claim 1 or 2, 세라믹 파우더는 게르마늄인 것을 특징으로 하는 약산성 액상 비누 조성물.The weakly acidic liquid soap composition, wherein the ceramic powder is germanium. 제 3항에 있어서,The method of claim 3, 게르마늄파우더의 입자의 평균입경은 1.5-1.7㎛ 인 것을 특징으로 하는 약산성 액상 비누조성물.A weakly acidic liquid soap composition, wherein the average particle diameter of the particles of the germanium powder is 1.5-1.7 μm. 액상 비누 조성물 중량 기준으로 5.0-15.0 중량%의 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt), 15.0-20.0 중량%의 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 3.0-7.0 중량%의 코코아미도프로필 베탄(cocoamidopropyl betane), 2.0-3.0 중량%의 글리세린 모노스테아레이트(glycerine monostearate), 2.0-3.0 중량%의 글리세린, 1.0-2.0 중량%의 시트르산, 2.0 중량%의 디메치콘, 1.0-2.0 중량%의 야자유 지방산, 3.0 중량%의 세라믹파우더, 0.5 중량%의 항균제, 0.05 중량%의 향료 및 5.0-10.0 중량%의 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 2.0-10.0 중량%의 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 3.0-7.0 중량%의 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 0.5-2.0 중량%의 코코모노에탄올 아민(cocomonoethanol amine), 0.5-1.0 중량%의 코코다이에탄올 아민(cocodiethanol amine)으로 구성된 군에서 선택되는 세개 내지 다섯 개의 구성 성분을 포함하고, 나머지는 이온수로 구성되는 것을 특징으로 하는 약산성 액상 비누 조성물.5.0-15.0 weight percent fat alkyl glutamate metallic salt, 15.0-20.0 weight percent ammonium lauryl sulfate, 3.0-7.0 weight percent cocoamido, by weight of the liquid soap composition Propyl betane, 2.0-3.0 wt% glycerin monostearate, 2.0-3.0 wt% glycerin, 1.0-2.0 wt% citric acid, 2.0 wt% dimethicone, 1.0-2.0 wt% Palm oil fatty acid, 3.0 wt% ceramic powder, 0.5 wt% antimicrobial agent, 0.05 wt% fragrance and 5.0-10.0 wt% fat alkyl isethionate metallic salt, 2.0-10.0 wt% Fatty alkyl taurate metallic salt, 3.0-7.0 wt% ammonium lauryl ether sulfate, 0.5-2.0 wt% cocoomonoethanol amine, 0.5- 1.0 wt% cocoa Ethanolamine (cocodiethanol amine) as it included in the three to five ingredients selected from the group consisting of the rest weakly acidic liquid soap composition, characterized in that consisting of water. 하기의 단계를 포함하는 것을 특징으로 하는 약산성 액상 비누 조성물의 제조방법:Method for producing a weakly acidic liquid soap composition comprising the following steps: 액상 비누 조성물 중량 기준으로 2-3 중량%의 글리세린모노스테아레이트, 3.0 중량%의 세라믹 파우더, 3.0-10.0 중량%의 패티알킬이세티오네이트금속염(fatty alkyl isethionate metallic salt), 2.0-10.0 중량%의 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 5.0-15.0 중량%의 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt), 15.0-20.0 중량%의 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 3.0-7.0 중량%의 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 3.0-7.0 중량%의 코코아미도프로필 베탄(cocoamidopropyl betane), 1.0-2.0 중량%의 코코모노에탄올 아민(cocomonoethanol amine), 0.5-2.0 중량%의 코코다이에탄올 아민(cocodiethanol amine), 2.0-3.0 중량%의 글리세린, 1.0-2.0 중량%의 시트르산, 2.0 중량%의 디메치콘, 1.0-2.0 중량%의 야자유 지방산, 0.5 중량%의 항균제, 0.05 중량%의 향료를 준비하고, 나머지 중량의 이온수를 준비하는 단계;2-3 weight percent glycerin monostearate, 3.0 weight percent ceramic powder, 3.0-10.0 weight percent fat alkyl isethionate metallic salt, 2.0-10.0 weight percent based on the weight of the liquid soap composition Fatty alkyl taurate metallic salt, 5.0-15.0 wt% fatty alkyl glutamate metallic salt, 15.0-20.0 wt% ammonium lauryl sulfate, 3.0-7.0 wt% ammonium lauryl ether sulfate, 3.0-7.0 wt% cocoamidopropyl betane, 1.0-2.0 wt% cocoomonoethanol amine, 0.5-2.0 wt% cocodiethanol amine, 2.0-3.0 wt% glycerin, 1.0-2.0 wt% citric acid, 2.0 wt% dimethicone, 1.0-2.0 wt% palm oil fatty acid, 0.5 wt% Antibacterial, 0.05% by weight Preparing a perfume and preparing remaining weight of ionized water; 이온수를 70-80℃로 승온시킨 후 글리세린 모노스테아레이트(glycerine monostearate) 및 게르마늄파우더를 첨가하여 녹이는 단계;Warming the ionized water to 70-80 ° C. and then dissolving by adding glycerine monostearate and germanium powder; 50-60℃를 유지하면서 패티알킬이세티오네이트 금속염(fatty alkyl isethionate metallic salt), 패티알킬타우레이트 금속염(fatty alkyl taurate metallic salt), 패티알킬글루타메이트 금속염(fatty alkyl glutamate metallic salt)을 첨가하는 단계;Adding fatty alkyl isethionate metallic salt, fatty alkyl taurate metallic salt, and fatty alkyl glutamate metallic salt at 50-60 ° C. ; 암모늄 라우릴 설패이트 (ammonium lauryl sulfate), 암모늄 라우릴 에테르 설패이트 (ammonium lauryl ether sulfate), 코코아미도프로필 베탄(cocoamidopropyl betane), 코코모노에탄올 아민(cocomonoethanol amine), 글리세린, 시트르산, 디메치콘, 야자유 지방산, 항균제, 향료를 첨가하는 단계; 및Ammonium lauryl sulfate, ammonium lauryl ether sulfate, cocoamidopropyl betane, cocomonoethanol amine, glycerin, citric acid, dimethicone Adding palm oil fatty acid, antibacterial and flavoring; And 40-50℃로 냉각시키는 단계.Cooling to 40-50 ° C. 제 6항에 있어서,The method of claim 6, 세라믹 파우더는 게르마늄 파우더이고, 항균제는 이소티아졸린인 것을 특징으로 하는 약산성 액상 비누 조성물의 제조방법.The ceramic powder is germanium powder, and the antimicrobial agent is isothiazoline.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200488020Y1 (en) 2018-03-27 2018-12-04 현경미 Supporting device for fishing

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JPS57126408A (en) * 1981-01-28 1982-08-06 Kiyo Kondo Cosmetic containing germanium
JPS63275698A (en) * 1987-05-06 1988-11-14 Giyuuniyuu Setsuken Kiyoushinshiya Kk Liquid detergent composition
JPH01238521A (en) * 1988-03-17 1989-09-22 Lion Corp Liquid skin detergent composition
JPH0860190A (en) * 1994-08-16 1996-03-05 Lion Corp Liquid detergent composition for cleansing hard surface
JPH1045563A (en) * 1996-08-08 1998-02-17 Noevir Co Ltd Antimicrobial and low-irritant cosmetic
KR19980082074A (en) * 1998-08-20 1998-11-25 김석태 Polyester resin composition and its manufacturing method
KR20010013376A (en) * 1997-06-04 2001-02-26 데이비드 엠 모이어 Leave-on antimicrobial compositions

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Publication number Priority date Publication date Assignee Title
JPS57126408A (en) * 1981-01-28 1982-08-06 Kiyo Kondo Cosmetic containing germanium
JPS63275698A (en) * 1987-05-06 1988-11-14 Giyuuniyuu Setsuken Kiyoushinshiya Kk Liquid detergent composition
JPH01238521A (en) * 1988-03-17 1989-09-22 Lion Corp Liquid skin detergent composition
JPH0860190A (en) * 1994-08-16 1996-03-05 Lion Corp Liquid detergent composition for cleansing hard surface
JPH1045563A (en) * 1996-08-08 1998-02-17 Noevir Co Ltd Antimicrobial and low-irritant cosmetic
KR20010013376A (en) * 1997-06-04 2001-02-26 데이비드 엠 모이어 Leave-on antimicrobial compositions
KR19980082074A (en) * 1998-08-20 1998-11-25 김석태 Polyester resin composition and its manufacturing method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR200488020Y1 (en) 2018-03-27 2018-12-04 현경미 Supporting device for fishing

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