KR20040029344A - Ink for heat insulating antibacterial ceramic print and preparation method thereof - Google Patents

Ink for heat insulating antibacterial ceramic print and preparation method thereof Download PDF

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KR20040029344A
KR20040029344A KR1020040017798A KR20040017798A KR20040029344A KR 20040029344 A KR20040029344 A KR 20040029344A KR 1020040017798 A KR1020040017798 A KR 1020040017798A KR 20040017798 A KR20040017798 A KR 20040017798A KR 20040029344 A KR20040029344 A KR 20040029344A
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ceramic
ink
antibacterial
printing ink
solvent
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KR1020040017798A
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Korean (ko)
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김상현
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김상현
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/033—Printing inks characterised by features other than the chemical nature of the binder characterised by the solvent
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
    • C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00—Inks
    • C09D11/02—Printing inks
    • C09D11/10—Printing inks based on artificial resins
    • C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Nanotechnology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

PURPOSE: An ink for heat insulating antibacterial ceramic print and its preparation method are provided, to improve heat insulation, antibacterial effect and far infrared ray emitting effect. CONSTITUTION: The ink is obtained by mixing and dispersing a ceramic mixture which comprises alumina, vermiculite, elvan and silver and has a particle size of 20-200 nm, a fluid vehicle, a solvent and an auxiliary.

Description

단열 항균세라믹 인쇄용 잉크와 그의 제조방법.{omitted}Insulating antibacterial ceramic printing ink and manufacturing method thereof.

알루미나, 질석은 단열의 특성을 지닌과 고강도 구조용재료, 내화학, 내열 재료 또는 치과용 소재, 단열재로 사용되고 있으며, 유해물질 제거 및 중금속 분해 작용과 미네랄 용출 작용, 수질조절 및 정수작용 방부작용, 원적외선 방출 등의 기능으로 건강 및 의학, 건축자재로 널리 응용되고 있는 맥반석, 강한 살균력을 특징으로 하는 은은 항균 응용 분야에 사용되고 있으나, 포장분야에 있어서는 단열,항균, 신선도 유지 등의 문제점은 과제로 남아있다.Alumina and vermiculite are used as insulation materials, high strength structural materials, chemicals, heat-resistant materials or dental materials, and insulation materials.It removes harmful substances, decomposes heavy metals, dissolves minerals, regulates water quality, antiseptic action, and far-infrared rays. Elvan, which is widely used in health, medicine, and building materials for its functions such as release, and silver, which is characterized by strong sterilizing power, is used in antibacterial applications, but problems such as insulation, antibacterial, and freshness remain in the packaging field. .

본 발명의 알루미나, 질석, 맥반석, 은이 잉크로서의 기능을 갖기 인쇄기상 적합한 단열 세라믹 인쇄용 잉크 만들어지기 위해서는 상기한 알루미나, 질석, 맥반석, 은이 20∼200 나노미터 크기로 미세분말 되어야하며, 이러한 미세 분말 세라믹을 비히클과 보조제와 혼합 분산시켜 인쇄용 잉크를 만드는 것이 본발명의 기술적 과제이다.In order to make the alumina, vermiculite, elvan, and silver of the present invention having a function as an ink, the alumina, vermiculite, elvan, and silver should be finely powdered in a size of 20 to 200 nanometers. It is a technical problem of the present invention to produce a printing ink by mixing and dispersing the mixture with a vehicle and an auxiliary agent.

도1 은단열 항균 세라믹 인쇄용 잉크 공정도1 is a process diagram of ink for thermal insulation antibacterial ceramic printing

＜도면의 주요부분에 대한 부호 설명＞<Description of Signs of Main Parts in Drawings>

(1)단열 항균 세라믹 미세분말 (2)용 해 (3)혼 합 (4)분 산 (5)조 정(1) insulating antibacterial ceramic fine powder (2) dissolution (3) mixture (4) dispersion (5) conditioning

(6)검 사(6) Inspection

본 발명의 단열 항균 세라믹 인쇄용 잉크의 구성은 안료로서의 알루미나, 질석, 맥반석, 은의 혼합된 미세분말 세라믹과 인쇄면까지 전달 시키기 위한 유동성을 지닌 유채상의 물질인 비히클과 유지, 용제, 보조제로 구성되어 있다.The composition of the heat-insulating antimicrobial ceramic printing ink of the present invention is composed of a mixed fine powder ceramic of alumina, vermiculite, elvan, silver as a pigment, and a vehicle, oil, solvent, and auxiliaries which have fluidity for transferring to the printing surface. .

상기한 알루미나, 질석, 맥반석, 은의 미세분말 세라믹은 20∼200 나노미터 크기로 미세분말 되어야 한다.The fine powder ceramics of alumina, vermiculite, elvan, and silver should be fine powder with a size of 20 to 200 nanometers.

상기한 비히클(Vanish)은 인쇄기상에서 전이하여 피인쇄체에 상을 형성하는데 사용되며, 수지는 로진계 수지로 로진변성 페놀수지가 쓰이며, 로진계수지 중에는 경화로진, 로진 에스테르, 로진변성로진변성 말레인산 수지도 포함한다. 로진변성 페놀수지를 구성하는 주요 원재료는 로진, 다가알콜, 페놀류 및 알데히그류가 있다. 로진 페놀수지는 로진과 다가알콜의 에스테르화 반응에서 로진에스테르를, 페놀류와 포름알데히드의 메틸롤화 및 축합반응에서 페놀수지(레졸수지)를 각각 합성하고, 로진에스테르와 페놀수지의 부가반응에서 로진변성 페놀수지를 합성한 수지로 바니스를 제조한다.The above-mentioned vehicle (Vanish) is used to form a phase on the printed object by transferring on a printing machine, the resin is a rosin-based resin is used as a rosin-modified phenol resin, among the rosin resins, cured rosin, rosin ester, rosin-modified rosin It also contains modified maleic acid resins. The main raw materials for rosin-modified phenolic resins are rosin, polyhydric alcohol, phenols and aldehydes. Rosin phenolic resin synthesizes rosin ester in the esterification reaction of rosin and polyhydric alcohol, phenolic resin (resol resin) in methylolation and condensation reaction of phenol and formaldehyde, and rosin modification in addition reaction of rosin ester and phenolic resin. A varnish is manufactured by resin which synthesize | combined phenol resin.

상기한 유지는 아마인유(Linseed oil), Tung oil(China wood oil), 페릴라유(Perilla oil)의 건성유를 사용하며, 잉크의 건조에 영향을 주는 이중결합의 수는 140∼200사이의 것을 사용한다.The above-mentioned fats and oils use linseed oil, Tung oil (China wood oil) and dry oil of Perilla oil, and the number of double bonds affecting the drying of the ink is between 140 and 200. use.

상기한 용제는 탄화수소계 용제를 사용하며, 석유계 탄화수소의 구성 성분은 Paraffine 60％, Aromatic 15∼18％, Napthene 30％ 내외로 240∼330의 비점 범위의 용제를 사용한다.The above solvent is a hydrocarbon solvent, and the petroleum hydrocarbon component is a solvent having a boiling point of 240 to 330 with 60% of Paraffine, 15 to 18% of Aromatic, and 30% of Napthene.

상기한 보조제는 용제콤바운드 및 드라이어를 사용한다.Said adjuvant uses a solvent combound and a dryer.

단열 항균 세라믹 인쇄용 잉크의 제조 공정은, 1단계 용해, 2단계 혼합, 3단계 분산, 4단계 조정, 5단계 검사의 순으로 이루어진다.The manufacturing process of the heat-insulating antibacterial ceramic printing ink consists of one step dissolution, two steps mixing, three steps dispersion, four steps adjustment, and five steps inspection.

상기한 1단계 용해는 천연수지, 합성수지 등을 식물성 건성유와 광물유를 가열 반응시켜 만들어지는 비히클 제조공정이다.The one-step dissolution is a vehicle manufacturing process made by heating and reacting a vegetable dry oil and a mineral oil with a natural resin, a synthetic resin, and the like.

상기한 2단계 혼합은 분말형태인 단열 항균 세라믹과 페이스트 상태인 비히클을 분산공정 전에 충분한 예비 훈련을 시켜 분산물이 균일하게 복사열 단열 안료에 비히클이 잘 습윤 잘 될 수 있도록 하는 공정이다.The two-stage mixing is a process in which a sufficient amount of preliminary training is performed before the dispersing process of the powder-insulating antibacterial ceramic and the vehicle in the paste state so that the dispersion can be well wetted to the radiant heat insulating pigment.

상기한 3단계 분산은 단열 항균 세라믹의 입자를 최소화하여 완전히 코딩을 시키는 공정이다.The three-step dispersion is a process of completely coding by minimizing the particles of the insulating antibacterial ceramic.

상기한 4단계 조정은 단열 항균 세라믹 인쇄용 잉크의 사용 용도에 따라 택 또는 점도를 보완 해야 할 경우 조정하는 공정이다.The four-step adjustment described above is a process for adjusting the tack or viscosity depending on the intended use of the heat-insulating antibacterial ceramic printing ink.

상기한 5단계 검사는 조정이 끝난 후 규정된 규격에 맞추어졌는지를 판정, 표준화, 기본 제품과 비교 시험하는 공정을 거쳐 단열 항균 세라믹 인쇄용 잉크가 만들어진다.After the five-step inspection, after the adjustment is completed, the process for determining whether to meet the prescribed standard, standardization, and comparative test with the basic product is made ink for heat-insulating antibacterial ceramic printing.

단열 항균 세라믹 인쇄용 잉크는 분말 세라믹의 배합 성분에 따라 알루미나와 질석을 혼합한 단열 세라믹 인쇄용 잉크, 맥반석과 은을 혼합한 항균 세라믹 인쇄용 잉크 및 알루미나, 질석, 맥반석, 은을 혼합한 단열 항균 세라믹 인쇄용 잉크로 구분되어진다.Insulating antibacterial ceramic printing inks are insulated ceramic printing inks mixed with alumina and vermiculite according to the composition of powder ceramics, insulated antibacterial ceramic printing inks mixed with alumina and vermiculite and insulated antibacterial ceramic printing inks mixed with alumina, vermiculite, elvan, and silver It is divided into

단열 항균 세라믹 인쇄용 잉크는 인쇄기 또는 피인쇄체에 따라 단열 항균 윤전 인쇄용 잉크, 단열 항균 그라비아 인쇄용 잉크, 단열 항균 플랙소 인쇄용 잉크로 구분되어진다.Insulating antibacterial ceramic printing inks are classified into insulated antibacterial roto printing inks, insulating antibacterial gravure printing inks, and insulating antibacterial flexo printing inks according to a printing press or a printed object.

상기한 단열 항균 윤전 인쇄용 잉크의 배합은 ＜표 1＞과 같다.The mixing | blending of said ink for thermal insulation antibacterial rotation printing is shown in <Table 1>.

상기한 단열 항균 그라비아 인쇄용 잉크의 배합은 ＜표 2＞과 같다.The mixing | blending of the said heat insulation antibacterial gravure printing ink is as Table <Table 2>.

상기한 단열 항균 플랙소 인쇄용 잉크의 배합은 ＜표 3＞과 같다.The mixing | blending of said ink for heat insulation antimicrobial flexo printing is shown in <Table 3>.

본 발명의 단열 항균 인쇄용 잉크는 알루미나 및 질석의 단열특성, 맥반석의유해물질 제거 및 중금속 분해 작용과 미네랄 용출 작용, 수질조절 및 정수작용 방부작용, 원적외선 방출 등의 기능 및 은의 강력한 항균력을 부각시켜 단열 항균 세라믹 인쇄용 잉크를 발명함으로써 포장산업에 신선도 유지 및 제품 유통기한의 연장으로 생산성과 유통 및 그 응용분야에 큰 기대 효과를 기대할 수 있다.Insulation antibacterial printing ink of the present invention is characterized by the heat insulating properties of alumina and vermiculite, removal of harmful substances of elvanite and heavy metal decomposition and mineral elution action, water quality control and water purification antiseptic action, far infrared radiation release and the strong antibacterial power of silver By inventing antimicrobial ceramic printing inks, it is possible to expect great effects on productivity, distribution and its applications by maintaining freshness in the packaging industry and extending product shelf life.

Claims (4)

알루미나, 질석, 맥반석, 은을 20∼200나노마터의 크기로 미세 분말한 세라믹의 혼합물과 인쇄면 까지 전달 시키기 위한 유동성을 지닌 유채상의 물질인 비히클과 유지, 용제, 보조제와 혼합분산시켜 만들어진 것을 특징으로하는 단열 항균 세라믹 인쇄용 잉크.It is made by mixing and dispersing alumina, vermiculite, elvan, and silver with a mixture of fine powdered ceramics with a size of 20-200 nanometers and a velvety material having a fluidity to transfer to the printing surface and a fat, a solvent, a solvent and an auxiliary agent. Insulated antibacterial ceramic printing ink. 제1항에 있어서, 알루미나, 질석 분말 세라믹과 인쇄면 까지 전달 시키기 위한 유동성을 지닌 유채상의 물질인 비히클과 유지, 용제, 보조제와 혼합 분산시켜 만들어진 것으로 단열을 특징으로 하는 단열 항균 세라믹 인쇄용 잉크.The heat-insulating antimicrobial ceramic printing ink according to claim 1, which is made by mixing and dispersing alumina, vermiculite powder ceramic, and a vehicle which is a rapeseed material having a fluidity for transferring to a printing surface, and a fat, a solvent, and an auxiliary agent. 제1항에 있어서, 맥반석, 은 분말 세라믹과 인쇄면 까지 전달시키기 위한 유동성을 지닌 유채상의 물질인 비히클과 유지, 용제, 보조제와 혼합 분산시켜 만들어진 것으로 항균을 특징으로 하는 단열 항균 세라믹 인쇄용 잉크.The heat-insulating antimicrobial ceramic printing ink according to claim 1, wherein the ink is made by mixing and dispersing it with a vehicle, oil, a solvent, and an auxiliary agent, which is a rapeseed material having fluidity for transferring to elvan, silver powder ceramic, and printing surface. 제1항에 있어서, 인쇄기 또는 피인쇄체에 따라 단열 항균 윤전 인쇄용 잉크, 단열 항균 그라비아 인쇄용 잉크, 단열 항균 플랙소 인쇄용 잉크로 구분되어지는 것을 특징으로하는 단열 항균 세라믹 인쇄용 잉크.The insulated antibacterial ceramic printing ink according to claim 1, which is classified into an insulated antibacterial roto printing ink, an insulated antibacterial gravure printing ink, and an insulated antibacterial flexo printing ink according to a printing machine or a printed object.
KR1020040017798A 2004-03-16 2004-03-16 Ink for heat insulating antibacterial ceramic print and preparation method thereof KR20040029344A (en)

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