KR20040017503A - Processing Method of Soy Sauce Having Meat-like Flavor from Acid-Hydrolyzed Vegetable Protein with Alkaline Treatment - Google Patents

Processing Method of Soy Sauce Having Meat-like Flavor from Acid-Hydrolyzed Vegetable Protein with Alkaline Treatment Download PDF

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KR20040017503A
KR20040017503A KR1020020049578A KR20020049578A KR20040017503A KR 20040017503 A KR20040017503 A KR 20040017503A KR 1020020049578 A KR1020020049578 A KR 1020020049578A KR 20020049578 A KR20020049578 A KR 20020049578A KR 20040017503 A KR20040017503 A KR 20040017503A
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soy sauce
flavor
acid
meat
vegetable protein
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KR1020020049578A
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KR100491246B1 (en
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차용준
조우진
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차용준
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/50Soya sauce
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/20Synthetic spices, flavouring agents or condiments
    • A23L27/21Synthetic spices, flavouring agents or condiments containing amino acids
    • A23L27/215Synthetic spices, flavouring agents or condiments containing amino acids heated in the presence of reducing sugars, e.g. Maillard's non-enzymatic browning
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/20Synthetic spices, flavouring agents or condiments
    • A23L27/26Meat flavours
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30Artificial sweetening agents
    • A23L27/33Artificial sweetening agents containing sugars or derivatives
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/88Taste or flavour enhancing agents

Abstract

PURPOSE: Provided is a manufacturing method of soy sauce having the meat-like flavor from acid-hydrolyzed vegetable protein with alkaline treatment by thermal reaction. Therefore, the value added of the acid-hydrolyzed vegetable protein is increased. CONSTITUTION: In a manufacturing method of soy sauce having the meat-like flavor from acid-hydrolyzed vegetable protein with alkaline treatment as a raw material, it comprises the steps of: mixing the raw material with 14.20% of fructose, 0.42% of methionine and 0.12% of cysteine; and heating the mixture in a stainless steel container at 130 deg.C for 32 minutes.

Description

저염산 알칼리처리법으로 제조한 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법{Processing Method of Soy Sauce Having Meat-like Flavor from Acid-Hydrolyzed Vegetable Protein with Alkaline Treatment}Processing Method of Soy Sauce Having Meat-like Flavor from Acid-Hydrolyzed Vegetable Protein with Alkaline Treatment}

본 발명은 저염산 알칼리처리법에 의해 제조된 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법에 관한 것으로, 좀더 상세하게 설명하면, 인체에 바람직하지 못한 식품오염물질로 규정된 3-클로로-1,2-프로판디올(3-chloro-1,2-propanediol; MCPD)의 생성량을 감소시킴과 동시에 단시간내에 제조가 가능하여 경제적 측면에서 우수하지만 알칼리처리에 의해 생성되는 독특한 불쾌치를 가진 저염산 알칼리처리법에 의해 제조한 산분해간장으로부터 부재료와 가열반응(thermal reaction)을 통해 향미를 개선한 구운 고기맛과 향을 가진 콩간장 제조방법에 관한 것이다.The present invention relates to a method for producing soy soy sauce having a roasted meat taste and aroma from acid-decomposed soy sauce prepared by a low hydrochloric acid alkali treatment method. Low hydrochloric acid with unique discomfort produced by alkali treatment, although it is economically good because it reduces the amount of 3-chloro-1,2-propanediol (MCPD) and can be manufactured in a short time. The present invention relates to a soybean soy sauce manufacturing method having a roasted meat taste and aroma, which has been improved in flavor through thermal reaction from an acid-decomposed soy sauce prepared by alkali treatment.

일반적으로 간장이라 함은 단백질 및 탄수화물이 함유된 원료로 제국(製麴)하거나 메주를 주원료로 하여 식염수 등을 섞어 발효한 것과 효소분해 또는 산분해법 등으로 가수분해 하여 얻은 여액을 가공한 것을 말한다. 간장은 조미식품류에 속하며 우리나라 식문화의 중요한 자리를 차지하고 있다.In general, soy sauce refers to raw materials containing protein and carbohydrates, such as empire (製 麴) or meju as the main raw material and fermented with saline solution and processed filtrate obtained by hydrolysis by enzymatic or acid decomposition method. Soy sauce is a seasoned food and occupies an important place in Korean food culture.

종래의 간장류를 제조하는 방법은 종류에 따라 제조방법이 달라지는데, 현재 산업적으로 많이 유통되고 있는 개량식 양조간장, 산분해간장, 혼합간장은 다음과 같다.The manufacturing method of the conventional soy sauce varies depending on the type, the improved brewed soy sauce, acid-decomposed soy sauce, mixed soy sauce that is currently widely distributed in the industry are as follows.

첫째, 개량식 양조간장의 제조방법은, 첫 단계로서 원료인 증자한 대두와 볶아 분쇄한 밀을 혼합한뒤 종균(種菌)을 제국실에 넣어 국(麴)을 만든다. 제국실에서 꺼낸 국은 식염 농도를 조절한 염수와 혼합하여 적정 온도에서 보관하여 발효시켜 숙성덧을 만든후 포대에 넣고 압착을 하여 추출한 생간장을 가열 살균처리하여 제품으로 만든다.First, the production method of the improved brewed soy sauce, as the first step is to mix the raw soybeans and roasted crushed wheat as raw materials and then put the spawn (균) in the imperial chamber to make soup. The soup taken out of the imperial chamber is mixed with brine with the adjusted salt concentration, stored at the proper temperature and fermented to make fermented soybeans. Then, the raw soy sauce extracted by compressing is heated and sterilized into a product.

둘째, 산분해간장은 단백질 원료를 염산으로 가수분해한 다음 수산화나트륨 또는 탄산나트륨으로 중화하여 얻은 액에 일정 농도의 소금물을 가한 후 탈취, 탈색 처리를 하여 제품으로 만든다.Second, acid-decomposed soy sauce is made by hydrolyzing protein raw material with hydrochloric acid and then neutralizing it with sodium hydroxide or sodium carbonate, adding a certain concentration of brine, and then deodorizing and decolorizing the product.

셋째, 혼합간장은 제조방법이 다양한데 양조간장과 산분해간장을 직접 혼합하는 방법, 또는 산분해간장에 생간장을 넣고 발효ㆍ숙성시켜 제조하는 방법 등이 있다.Third, mixed soy sauce has a variety of manufacturing methods, such as a method of directly mixing brewed soy sauce and acid-decomposed soy sauce, or a method of preparing by adding fermented soy sauce to fermented and aged.

한편, 산분해간장은 제조시간 및 공정등의 단축에 의해 단시간내에 제조가 가능하여 원가절감효과로 인해 경제적 측면에서 우수하여 양조간장에 비해 저가로 판매됨으로서 대부분의 음식점이나 가정에서 널리 보급되어져왔다. 그러나 최근에산분해에 의해 인체에 바람직하지 못한 식품오염물질로 규정된 3-클로로-1,2-프로판디올이 생성됨에 따라 근래에는 저염산 알칼리처리법으로 산분해간장을 제조하게되면서 3-클로로-1,2-프로판디올의 생성량은 감소시켰지만, 알칼리처리 특유의 불쾌치가 발생함에 따라 단일제품으로 사용되지 못하고 양조간장등과 혼합(혼합간장)된 형태로 사용되어지고 있는 실정이다.On the other hand, acid-decomposed soy sauce can be manufactured in a short time by shortening the production time and process, etc., because it is superior in terms of economics due to the cost-saving effect and sold at a lower price than brewed soy sauce, has been widely used in most restaurants and homes. However, recently, 3-chloro-1,2-propanediol, which is defined as an undesired food pollutant by humans due to acid decomposition, has recently been produced. Although the amount of 1,2-propanediol is reduced, it is not used as a single product due to the peculiar discomfort of alkali treatment and is used in the form of mixing (mixed soy sauce) with brewing soy sauce.

본 발명은 상기와 같은 문제점을 보완하기 위하여 안출한 것으로서, 저염산 알칼리처리법에 의해 제조한 산분해간장을 부재료와 가열반응을 통하여 알칼리처리 특유의 불쾌치를 제거함과 동시에 구운 고기맛과 향을 가진 콩간장으로 제조하여 그 부가가치를 높일 수 있도록 구운 고기맛과 향을 가진 콩간장 제조방법을 제공하는데 그 목적이 있다.The present invention has been made to solve the above problems, the acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment method by removing the unpleasant characteristic peculiar to the alkali treatment through the heating reaction with subsidiary materials and at the same time baked beans The purpose of the present invention is to provide a soy sauce manufacturing method with roasted meat flavor and flavor so as to increase the added value by making soy sauce.

도 1은 본 발명인 저염산 알칼리처리법으로 제조한 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법에 관한 제조 공정도이다.1 is a manufacturing process chart of a method for producing soy soy sauce with meat flavor and aroma baked from acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment of the present invention.

상기 목적은 본 발명에 따라, 저염산 알칼리처리법에 의해 제조한 산분해간장을 원료로 하는 구운 고기맛과 향을 가진 콩간장 제조방법에 있어서, 상기 원료의 관능적 향미 향상을 위해 부재료를 첨가하는 단계와 상기 결과 배합물을 가열반응하는 단계를 포함하는 것을 특징으로 하는 구운 고기맛과 향을 가진 콩간장 제조방법에 의해 달성된다.The above object is, according to the present invention, in a soybean soy sauce manufacturing method having a roasted meat taste and aroma as a raw material of acid-decomposed soy sauce prepared by a low hydrochloric acid alkali treatment method, adding a subsidiary material to improve the sensory flavor of the raw material And the resultant is achieved by a method for producing soy soy sauce having a roasted meat flavor and aroma comprising the step of heating the resultant mixture.

이하, 첨부된 도면을 참고하여 본 발명인 저염산 알칼리처리법에 의해 제조한 산분해간장으로 부터 구운 고기맛과 향을 가진 콩간장 제조방법에 대해 상세하게 알아보면 다음과 같다. 첨부한 도 1은 본 발명인 저염산 알칼리처리법으로 제조한 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법에 관한 제조 공정도이다.Hereinafter, referring to the accompanying drawings, a detailed description will be made of a method for preparing soy sauce with roasted meat flavor and aroma from acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment method of the present invention. 1 is a manufacturing process chart of a soybean soy sauce manufacturing method having meat flavor and aroma baked from acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment method of the present invention.

본 발명은 저염산 알칼리처리법에 의해 제조한 산분해 간장(M1)을 원료로 하여 상기 원료에 열반응 향미화합물 생성을 유도하기 위해 부재료를 첨가하는 단계(M2)와, 상기 배합물을 스테인레스 용기내에서 최적 온도와 시간에 의해 가열반응하는 단계(M3)와 이후 냉각 및 살균을 거쳐 제품화하는 단계(M4)로 이루어진다.The present invention comprises the step (M2) of adding a subsidiary material to induce the heat-reacting flavor compound to the raw material using acid-decomposed soy sauce (M1) prepared by the low hydrochloric acid alkali treatment method, and the blend in a stainless container The step (M3) of the heating reaction by the optimum temperature and time, and then the step of cooling and sterilizing the product (M4).

상기 원료(M1)에 부재료를 첨가하는 단계(M2)에서는 반응표면분석법에 의해 설정된 최적 첨가량을 따른다. 즉 상기 원료의 중량에 대해 과당 14.20%, 메티오닌 0.42%, 시스테인 0.12%를 첨가한다. 이때 첨가된 부재료들은 다음의 가열반응하는 단계를 거치면서 불쾌치를 제거함과 동시에 향미를 증진시키기 위한 반응물질의 전구체로 사용된다.In the step (M2) of adding the subsidiary material to the raw material M1, the optimum addition amount set by the reaction surface analysis method is followed. That is, 14.20% fructose, 0.42% methionine and 0.12% cysteine are added to the weight of the raw material. At this time, the added subsidiary materials are used as precursors of the reactants to remove the discomfort and enhance the flavor during the next heating reaction step.

가열반응하는 단계(M3)에서는 상기 배합물을 일정 압력에 안전한 스테인레스 용기내에서 가열온도 130℃에서 32분간 가열하는 단계를 포함한다. 이때 가열반응하는 동안에 상기 배합물의 풍미성분은 강해지며, 또한 상기 첨가된 부재료들의 가열반응에 의해 다수의 열반응 향미화합물(reaction flavor)이 생성된다. 열반응에 의해 상기 배합물에서 생성된 열반응 향미화합물 중 특히, 3-메틸티오프로파날(3-methylthiopropanal), 3-아세틸티오펜(3-acetylthiophene), 2-아세틸티오펜(2-acethylthiophene), 2-프로피오닐티오펜(2-propionylthiophene)등이 다량생성되며, 상기 화합물들은 배합물의 구운감자 냄새, 구운 고기향 등을 강화 시킨다.The heating reaction step (M3) includes the step of heating the blend for 32 minutes at a heating temperature of 130 ℃ in a stainless container safe to a certain pressure. At this time, the flavor component of the compound becomes strong during the heating reaction, and a plurality of thermal reaction flavor compounds are generated by the heating reaction of the added subsidiary materials. Among the thermally reactive flavor compounds produced in the blend by thermal reaction, in particular, 3-methylthiopropanal, 3-acetylthiophene, 2-acetylthiophene, 2-acylthiophene, 2-propionylthiophene is produced in large quantities, and the compounds enhance the smell of roasted potatoes, roasted meat, etc. of the formulation.

이와같이, 본 발명인 저염산 알칼리처리법에 의해 제조한 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법은 알칼리처리 특유의 불쾌치를 제거함과 동시에 단일제품으로 사용되지 못했던 산분해간장을 구운 고기맛과 향을 가진 콩간장으로 전환하여 고부가가치 상품으로 재창출함으로서, 경제적 효과 및 이용가능성을 극대화 한다.As described above, the method for preparing soy sauce with roasted meat taste and flavor from acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment of the present invention removes unpleasant characteristics peculiar to alkali treatment and at the same time roasts acid-decomposed soy sauce that has not been used as a single product. By converting into soy sauce with flavor and re-creating it as a high value-added product, it maximizes economic effect and availability.

본 발명인 저염산 알칼리처리법에 의해 제조한 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법은 제조시간 및 공정등의 단축에 의해 단시간내에 제조가 가능하여 원가절감효과로 인해 경제적 측면에서 우수하여 양조간장에 비해 저가로 판매되어왔던 저염산 알칼리처리법으로 제조한 산분해 간장의 알칼리처리 특유의 불쾌치를 제거하고, 구운 고기맛과 향을 가진 콩간장으로 전환하여 단일제품으로 사용되지 못했던 산분해간장을 고부가가치 상품으로서 재창출함으로서, 경제적 효과 및 이용가능성을 극대화 할 수 있는 발명이다.Soy soy sauce manufacturing method has a meat taste and flavor baked from acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment method can be produced in a short time by the shortening of the production time and process, etc., excellent in terms of economics due to cost reduction effect Acid-decomposed soy sauce with low hydrochloric acid treatment, which had been sold at a lower price than brewed soy sauce, and removed the discomfort specific to alkaline treatment of soy sauce, and converted to soy soy sauce with roasted meat flavor and aroma. By re-creating soy sauce as a high value-added product, it is an invention that can maximize economic effect and availability.

Claims (1)

저염산 알칼리처리법에 의해 제조한 산분해간장을 원료로 하는 구운 고기맛과 향(meat-like flavor)을 가진 콩간장 제조방법에 있어서,In the manufacturing method of soy soy sauce with roast meat taste and aroma (meat-like flavor) using the acid-decomposed soy sauce prepared by the low hydrochloric acid alkali treatment method, 상기원료에 열반응 향미화합물을 유도하기 위해 원료 중량에 대해 부재료인 과당 14.20%, 메티오닌 0.42%, 시스테인 0.12%를 첨가하여 배합하는 단계와,In order to induce the heat-reacting flavor compound to the raw material by adding a raw material of fructose 14.20%, methionine 0.42%, cysteine 0.12% to the weight of the raw material, 상기 배합물을 스테인레스 용기내에서 130℃에 32분간 가열반응하는 단계를 포함하는 것을 특징으로 하는 저염산 알칼리처리법에 의해 제조한 산분해간장으로부터 구운 고기맛과 향을 가진 콩간장 제조방법.Roasting soy sauce with a meat flavor and flavor roasted from acid-decomposed soy sauce prepared by a low hydrochloric acid alkali treatment method comprising the step of heating the mixture at 130 ° C for 32 minutes in a stainless container.
KR10-2002-0049578A 2002-08-21 2002-08-21 Processing Method of Soy Sauce Having Meat-like Flavor from Acid-Hydrolyzed Vegetable Protein with Alkaline Treatment KR100491246B1 (en)

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