KR20040013682A - Cleanser for liquefied dry cleaning - Google Patents
Cleanser for liquefied dry cleaning Download PDFInfo
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- KR20040013682A KR20040013682A KR1020020046713A KR20020046713A KR20040013682A KR 20040013682 A KR20040013682 A KR 20040013682A KR 1020020046713 A KR1020020046713 A KR 1020020046713A KR 20020046713 A KR20020046713 A KR 20020046713A KR 20040013682 A KR20040013682 A KR 20040013682A
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- weight
- parts
- surfactant
- dry cleaning
- viscosity
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- 238000005108 dry cleaning Methods 0.000 title abstract description 8
- 239000003599 detergent Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims abstract description 8
- 239000004359 castor oil Substances 0.000 claims abstract description 7
- 235000019438 castor oil Nutrition 0.000 claims abstract description 7
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 5
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims abstract description 4
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 claims abstract description 4
- 229960003237 betaine Drugs 0.000 claims abstract description 4
- 239000003352 sequestering agent Substances 0.000 claims abstract description 4
- 239000011780 sodium chloride Substances 0.000 claims abstract description 4
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims abstract description 3
- 239000002562 thickening agent Substances 0.000 claims abstract description 3
- 239000000835 fiber Substances 0.000 claims description 12
- 238000005406 washing Methods 0.000 claims description 6
- 239000002216 antistatic agent Substances 0.000 claims description 3
- 239000002537 cosmetic Substances 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 239000003205 fragrance Substances 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- OVSQVDMCBVZWGM-QSOFNFLRSA-N quercetin 3-O-beta-D-glucopyranoside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC1=C(C=2C=C(O)C(O)=CC=2)OC2=CC(O)=CC(O)=C2C1=O OVSQVDMCBVZWGM-QSOFNFLRSA-N 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000013543 active substance Substances 0.000 claims 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 7
- 239000002736 nonionic surfactant Substances 0.000 abstract description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 2
- 239000011707 mineral Substances 0.000 abstract description 2
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 abstract 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 abstract 1
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 abstract 1
- 239000002304 perfume Substances 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
- 230000021148 sequestering of metal ion Effects 0.000 abstract 1
- 230000003068 static effect Effects 0.000 abstract 1
- 239000000463 material Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 208000017520 skin disease Diseases 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 241000195628 Chlorophyta Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Description
본 발명은 환경친화적 액상 드라이크리닝용 세재에 관한 것으로, 종래의 드라이크리닝용 세재에 비하여 세척력은 향상되면서 환경친화적임은 물론 다수의 이로운 특징을 가진다.The present invention relates to an environmentally friendly liquid dry cleaning detergent, while the cleaning power is improved compared to the conventional dry cleaning detergent, as well as environmentally friendly and has a number of beneficial features.
주로 세탁용으로 사용되는 통상의 드라이크리닝용 세재는 비천연성 재료를 사용하여 인체에 이롭지 못하여 피부질환을 유발시키기도 하며 섬유 손상률이 높고 섬유에 결합되어 있는 오염물질의 입자를 섬유로부터 분리만 시킬 뿐 분해를 하여 제거하지 못하기 때문에 세척력은 우수하지 못하며 수질생분해성이 우수하지 못한 등의 단점과 함께 환경친화적이지 못한 문제를 안고 있다.Conventional dry cleaning cleaners, which are mainly used for washing, use non-natural materials, which are not beneficial to the human body, causing skin diseases, and have high fiber damage rate and only separate particles of contaminants bound to the fiber from the fiber. Because it cannot be decomposed and removed, the washing power is not excellent, and there is a problem that is not environmentally friendly with disadvantages such as poor water biodegradability.
따라서 본 발명은, 종래 드라이크리닝용 세재가 가지는 단점을 해결하면서 섬유에 탄성이 부여되고 특히 환경친화적인 액상 드라이크리닝용 세재를 제공코저한다.Therefore, the present invention, while solving the disadvantages of the conventional dry cleaning detergents to provide an elastic and particularly environmentally friendly liquid dry cleaning detergents to the fibers.
이를 위하여 본 발명은, 피마자기름 10중량부와, 세재의 점도를 상승시키기 위한 점증제인 히드록실프로필메틸셀룰로오스 0.5중량부와, 고급 섬유용 또는 미용용으로 사용되는 비누인 포타슘하이드로사이드(K.O.H) 5중량부와, 비이온계 계면활성제 5중량부와, 양이온계 계면활성제 5중량부와, 음이온계 계면활성제 7중량부와, 세재의 점도를 상승시키면서 기포의 발생량을 줄여주는 염화나트륨 3중량부와, 정전기 방지제인 양이온계 계면활성제인 베타인 1중량부와, 향료 0.1중량부와, 물 속의 무기질을 침전시켜 세척효과를 우수하도록 하는 금속이온 봉쇄제(E.D.T.A.-4a) 2중량부와, 물 61.4중량부로 구성된 것을 특징으로 한다.To this end, the present invention, 10 parts by weight of castor oil, 0.5 parts by weight of hydroxylpropyl methyl cellulose, a thickener for increasing the viscosity of the detergent, potassium hydroxide (KOH) 5 which is a soap used for high-quality fibers or cosmetics Parts by weight, 5 parts by weight of nonionic surfactant, 5 parts by weight of cationic surfactant, 7 parts by weight of anionic surfactant, 3 parts by weight of sodium chloride which reduces the amount of foaming while increasing the viscosity of the detergent, 1 part by weight of betaine, a cationic surfactant that is an antistatic agent, 0.1 parts by weight of fragrance, 2 parts by weight of a metal ion sequestrant (EDTA-4a) that precipitates inorganic matters in water, and excellent water, 61.4 weight of water It is characterized by consisting of wealth.
이하 본 발명에 따른 바람직한 실시예를 제시한다.Hereinafter, a preferred embodiment according to the present invention is presented.
상기의 피마자기름 10중량부와 물 61.4중량부 및 고급 섬유용 또는 미용용으로 사용되는 비누인 포타슘하이드로사이드(K.O.H) 5중량부를 검화솥 안으로 투입시켜 95∼100℃의 열을 가하면서 약 120분 동안 서서히 교반시켜 상기 재료들의 치환반응을 유도시킴과 아울러 이어서 천연성의 비이온계 계면활성제 5중량부와, 천연성의 양이온계 계면활성제 5중량부 및 천연서의 음이온계 계면활성제 7중량부와, 세재의 점도를 상승시키면서 기포의 발생량을 줄여주는 염화나트륨 3중량부와, 정전기 방지제인 양이온계 계면활성제인 베타인 1중량부와, 향료 0.1중량부와, 물 속의 무기질을 침전시켜 세척효과를 우수하도록 하는 금속이온 봉쇄제(E.D.T.A.-4a)2중량부를 검화솥 안으로 투입시켜 다시 약 120분 동안 서서히 교반시켜 고점도의 점성을 가지는 액상의 본 발명이 완성이 된다.10 parts by weight of castor oil and 61.4 parts by weight of water and 5 parts by weight of potassium hydroside (KOH), a soap used for high-quality fibers or cosmetics, were put into a saponification pot and heated at 95-100 ° C. for about 120 minutes. While slowly stirring to induce substitution of the above materials, followed by 5 parts by weight of natural nonionic surfactant, 5 parts by weight of natural cationic surfactant and 7 parts by weight of anionic surfactant, 3 parts by weight of sodium chloride to reduce the amount of bubbles while increasing the viscosity of the beta, 1 part by weight of betaine, a cationic surfactant that is an antistatic agent, 0.1 parts by weight of fragrance, and minerals in water to precipitate excellent washing effect 2 parts by weight of a metal ion sequestrant (EDTA-4a) was added to the saponification pot and slowly stirred for about 120 minutes to give a liquid of high viscosity to the present invention. It is completed.
이상과 같이 제조된 본 발명을 실험한 결과 다음과 같은 품질검사 성적을 얻을 수 있었다.Experimental results of the present invention manufactured as described above were able to obtain the following quality test results.
본 발명의 액상 드라이크리닝용 세재는, 피마자기름과 천연음이온 및 천연양이온, 천연비이온의 계면활성제를 사용함으로서 섬유에 결합되어 있는 오염물질의 입자를 섬유로부터 분해시키기 때문에 세척력이 종래의 세재에 비하여 30% 이상 상승되며, 또한 피마자기름 등의 천연성 재료를 사용함으로서 약알칼리성으로서 세탁물의 손상을 방지하는 중성 세재로서 문제가 없고, 세척력은 우수하게 하지만 강이나 바다의 플랑크톤의 영양의 균형을 파괴시켜 적조 또는 녹조현상을 유발시키는 전인산염이 전혀 검출되지 않았으며, 거품발생률이 종래 분말 세재에 비하여 40% 이상 감소되고 생분해도가 96% 이상으로서 수질오염을 유발시키지 않는 우수한 세재라는 결론을 얻었다. 그리고 본 발명은, 천연성 재료를 사용함으로서 피부질환을 유발시키지 않으며 상기의 천연성 비이온과 양이온, 음이온계의 계면활성제를 사용함으로서 옷감을 손상시키지 않으면서 내구력이 상승됨은 물론 세탁후의 옷감이 풀을 먹인 것처럼 빳빳하고 탄성감이 좋은 등의 결과를 얻었다.The detergent for liquid dry cleaning of the present invention uses a surfactant of castor oil, a natural anion, a natural cation and a natural nonion to decompose particles of contaminants bound to the fiber from the fiber, so that the cleaning power is higher than that of conventional detergents. It is increased by more than 30%, and it is a weak alkaline, using natural materials such as castor oil, and it is no problem as a neutral detergent that prevents damage to laundry.It has excellent washing power but breaks the balance of nutrition of river and sea plankton. The total phosphate causing red tide or green algae was not detected at all, and it was concluded that foaming rate was reduced by more than 40% and biodegradability of more than 96% compared to the conventional powder cleaning agent, which is an excellent detergent that does not cause water pollution. In addition, the present invention, by using a natural material does not cause skin diseases and by using the above-mentioned natural non-ionic, cationic, anionic surfactants, the durability is increased without damaging the cloth, as well as the cloth after washing It was as if it was fed with a good feeling of elasticity.
이상과 같은 본 발명은, 종래와 달리 천연성의 음이온 및 비이온, 양이온계 계면활성제를 사용하고 피마자기름 및 기타 천연성의 재료를 사용함으로서 생분해성이 탁월하고 수질을 오염시키지 않아 환경친화적인 것이 특징으로 대두됨과 아울러 섬유입자에 결합된 때를 단순히 분리시켜 오수와 함께 배출시키는 것이 아니고 오염입자를 섬유로부터 분해시키기 때문에 세척력이 우수하면서 거품의 발생량은 적고, 섬유를 손상시키지 않으면서 내구력을 상승시키며 피부질환을 유발시키지 않는 등의 다수 유용한 효과가 있다.As described above, the present invention, unlike conventional, uses natural anions, nonionics and cationic surfactants, and castor oil and other natural materials, which are excellent in biodegradability and do not contaminate water quality, and are environmentally friendly. In addition to being soybean, it is not easy to separate when it is bound to fiber particles and discharge it with sewage, but to decompose contaminants from fiber, so it has excellent cleaning power, less foaming, increased durability without damaging fiber, and skin diseases. There are many useful effects, such as not causing them.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020020046713A KR20040013682A (en) | 2002-08-08 | 2002-08-08 | Cleanser for liquefied dry cleaning |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020020046713A KR20040013682A (en) | 2002-08-08 | 2002-08-08 | Cleanser for liquefied dry cleaning |
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| Publication Number | Publication Date |
|---|---|
| KR20040013682A true KR20040013682A (en) | 2004-02-14 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020020046713A KR20040013682A (en) | 2002-08-08 | 2002-08-08 | Cleanser for liquefied dry cleaning |
Country Status (1)
| Country | Link |
|---|---|
| KR (1) | KR20040013682A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980067230A (en) * | 1997-01-31 | 1998-10-15 | 이병모 | Composition and preparation method of laundry detergent for emulsifying |
| JPH11302686A (en) * | 1998-04-17 | 1999-11-02 | Lion Corp | Granular nonionic detergent composition and production thereof |
| KR20000006397A (en) * | 1998-06-24 | 2000-01-25 | 조지안느 플로 | Conditioning and detergent composition and use |
| KR100352934B1 (en) * | 1997-12-18 | 2002-09-16 | 우노 쇼오유 가부시끼 가이샤 | Transparent Liquid Detergent Containing Alkylbenzenesulfonate Anionic Surfactant and Sodium Silicate |
| KR20030003956A (en) * | 2001-07-04 | 2003-01-14 | 주식회사 엘지생활건강 | Tablet detergent composition and method for preparing the same |
-
2002
- 2002-08-08 KR KR1020020046713A patent/KR20040013682A/en not_active Application Discontinuation
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980067230A (en) * | 1997-01-31 | 1998-10-15 | 이병모 | Composition and preparation method of laundry detergent for emulsifying |
| KR100352934B1 (en) * | 1997-12-18 | 2002-09-16 | 우노 쇼오유 가부시끼 가이샤 | Transparent Liquid Detergent Containing Alkylbenzenesulfonate Anionic Surfactant and Sodium Silicate |
| JPH11302686A (en) * | 1998-04-17 | 1999-11-02 | Lion Corp | Granular nonionic detergent composition and production thereof |
| KR20000006397A (en) * | 1998-06-24 | 2000-01-25 | 조지안느 플로 | Conditioning and detergent composition and use |
| KR20030003956A (en) * | 2001-07-04 | 2003-01-14 | 주식회사 엘지생활건강 | Tablet detergent composition and method for preparing the same |
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