CN109897737A - Biological enzyme cleaner in environmental protection and its application - Google Patents

Biological enzyme cleaner in environmental protection and its application Download PDF

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Publication number
CN109897737A
CN109897737A CN201910141110.2A CN201910141110A CN109897737A CN 109897737 A CN109897737 A CN 109897737A CN 201910141110 A CN201910141110 A CN 201910141110A CN 109897737 A CN109897737 A CN 109897737A
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CN
China
Prior art keywords
interfacial agent
biological enzyme
environmental protection
agent
cleaner
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910141110.2A
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Chinese (zh)
Inventor
张皓凯
华楠
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hangzhou Yueyang Biotechnology Co Ltd
Original Assignee
Hangzhou Yueyang Biotechnology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hangzhou Yueyang Biotechnology Co Ltd filed Critical Hangzhou Yueyang Biotechnology Co Ltd
Priority to CN201910141110.2A priority Critical patent/CN109897737A/en
Publication of CN109897737A publication Critical patent/CN109897737A/en
Pending legal-status Critical Current

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Abstract

It include: sodium carbonate peroxide, interfacial agent and biological enzyme the present invention provides a kind of biological enzyme cleaner in environmental protection, the interfacial agent includes teepol and/or non-ionic surfactant.Organic dirt is resolved into small molecule using biological enzyme by the technical program, sodium carbonate peroxide decontamination, bleaching, sterilization, disinfection are used simultaneously, again with interfacial agent, non-ionic surfactant individually or mixing reduce water surface can, enable the accumulation of dirt that floats in water simultaneously be easily removed.

Description

Biological enzyme cleaner in environmental protection and its application
Technical field
The invention belongs to detergent composition technical fields.
Background technique
There are many kinds of the dirt types that clothing may be infected in daily life, wherein the dirt of more difficult cleaning mainly wraps Include the organic dirt for being difficult to be decomposed, such as bloodstain, milk stain, bad smell of perspiration.General chemical detergent is to thoroughly removing these dirts It requires largely to add and extend the clothes washing time.But it is both easy to cause wear of clothes in this way, while it is easy to residual In in clothes fiber, causing sensitive constitution crowd to generate Contact hyper sensitization.
Summary of the invention
For existing chemical detergent be easy to cause residual and lead to sensitive constitution crowd allergy, the present invention by it is nontoxic, Odorless, free of contamination sodium carbonate peroxide is with that can combine the biological enzyme that organic dirt resolves into small molecule, so that life be made Object enzyme cleaner in environmental protection.
Technical solution is as follows:
The biological enzyme cleaner in environmental protection includes: sodium carbonate peroxide, interfacial agent and biological enzyme, the interfacial agent packet Include teepol and/or non-ionic surfactant.
Wherein, the teepol includes sulfonate interfacial agent, sulfuric acid interfacial agent or ammonia Base acid type interfacial agent.The biological enzyme includes but is not limited to protease, cellulase, amylase and/or lipase.
Further, the sulfonate interfacial agent is selected from oleoyl N-methyl taurate interfacial agent and/or rouge Fatty acid methyl esters sulfonate interfacial agent.
Further, the sulfuric acid interfacial agent is selected from fatty acid glyceride sulfate interfacial agent or alkyl sulfide Hydrochlorate interfacial agent.
Further, the amino acid pattern interfacial agent is selected from N- alkylaminoacid salts interfacial agent or N- acyl amino Hydrochlorate interfacial agent.
Further, the non-ionic surfactant be selected from monoethanolamine interfacial agent, diethanol amine interfacial agent, Beta-hydroxyethyl ethylenediamine interfacial agent, diethylentriamine interfacial agent or combinations thereof.
Further, the protease includes keratinase, subtilopeptidase A, pepsin or combinations thereof.
Further, the interfacial agent is 10wt%~25wt%, and biological enzyme is 3wt%~8wt%, and surplus was Oxygen sodium carbonate.
The biological enzyme cleaner in environmental protection of said components can be applied to fabric softening agent, optical white, brightening agent, bleaching agent Or in fabric color rendition.
The technical program is good fit using sodium carbonate peroxide and biological enzyme, decomposes organic dirt on fabric rapidly, can It is decomposed rapidly with deep limit: bloodstain, milk stain, bad smell of perspiration, laundry soil etc..The small molecule dirt being decomposed easily rinses disengaging, Not the problem of puzzlement that lotion residual clothing is learned in generalization is not had after washing, skin allergy will not be caused.Time saving, water-saving, thoroughly Cleaning does not remain.Without the phosphorus to human body or environmental injury.Clothing washes that rear sense of touch is submissive not to hurt fiber, and not upper hand does not need yet In addition softener and other bleaching agents, clothing can remain gorgeous as new.The efficiently obstinate outmoded spot of removal, can be used for yellowing, Dimmed, the clothing that hardens Hui Xin and color rendition.
Specific embodiment
It is clearly and completely described below with reference to technical effect of the embodiment to design and generation of the invention, with It is completely understood by the purpose of the present invention, feature and effect.Obviously, described embodiment is that a part of the invention is implemented Example, rather than whole embodiments, based on the embodiment of the present invention, those skilled in the art is not before making the creative labor Other embodiments obtained are put, the scope of protection of the invention is belonged to.
Embodiment 1, a kind of biological enzyme cleaner in environmental protection, comprising: the sodium carbonate peroxide of 82wt%, the interface of 10wt% are living The biological enzyme of property agent and 8wt%;Wherein, interfacial agent is oleoyl N-methyl taurate interfacial agent and fatty acid Methyl ester sulfonate interfacial agent is by 1:(1~1.5) it mixes;The biological enzyme is by keratinase and bacillus subtilis protein Enzyme composition, the active unit of two kinds of enzymes are each about 50000u/g~12000u/g.
Embodiment 2, a kind of biological enzyme cleaner in environmental protection, comprising: the sodium carbonate peroxide of 70wt%, the interface of 25wt% are living The biological enzyme of property agent and 5wt%;Wherein, interfacial agent is fatty acid glyceride sulfate interfacial agent, monoethanolamine circle Face activating agent and diethylentriamine interfacial agent are by 1:(2~2.4): (1~1.5) mixes;The biological enzyme is stomach egg White enzyme, active unit are each about 80000u/g~10000u/g.
Embodiment 3, a kind of biological enzyme cleaner in environmental protection, comprising: the sodium carbonate peroxide of 77wt%, the interface of 20wt% are living The biological enzyme of property agent and 3wt%;Wherein, interfacial agent is N- acyl amino hydrochlorate interfacial agent and alkyl sulfate interface Activating agent case 1:1.3 is mixed;The biological enzyme is amylase, and active unit is each about 60000u/g~10000u/g.
Comparative example 1, a kind of liquid clothes-washing precleaning agent of the aqua type containing polyenzyme, it includes dodecyl alcohol polyoxyethylenes (9) mixture or protease and compound stabilizer, the alkaline assistant of ether, protease and cellulase.
Comparative example 2
Commercially available infants' wear cleaning agent, stock chart mark composition are as follows: plant surface activating agent, EDTA, coconut oil fat Acid, micro-perfume material.
Examples 1 to 3 and comparative example 1,2 diluted each reality has been modulated into using ion exchange water and defined hardness water Apply the sample detergent of example or comparative example.Following cleaning force is carried out using the composition of acquisition to evaluate.The results are shown in tables 1 In.PH at 25 DEG C of sample cleaning solution is 10~11.In addition, the numerical value of the composition in table is use level (quality %).To It is put into 4 pieces of collar sample artificial contamination cloth (total 20g) in 600mL cleaning solution, impregnates the stipulated time at 20 DEG C.It uses later Terg-O-Tometer spotter is cleaned 10 minutes at 20 DEG C with the condition of 100rpm/min.Tap water rinse is used after cleaning After be dehydrated, spontaneously dry at room temperature, measure cleaning force.Cleaning force be using from note formula colorimeter measurement pollution before original cloth and Reflectivity of the pollution cloth of front and back under the light of 550nm is cleaned, and clean rate (%) is acquired by following formula, with 4 pieces of average value Determined.
Table 1
As shown in Table 1, due to being free of teepol in comparative example 1, clean rate is significantly lower than each embodiment; Be added to EDTA in comparative example 2, can and the stable water soluble complex of formation such as alkali metal, rare earth element and transition metal, but It does not contain teepol equally, and without adding biological enzyme, so its clean rate is also slightly below each implementation Example;Biological enzyme cleaner in environmental protection provided by Examples 1 to 3 shows more preferably clean rate.

Claims (10)

1. biological enzyme cleaner in environmental protection characterized by comprising sodium carbonate peroxide, interfacial agent and biological enzyme;The interface Activating agent includes teepol and/or non-ionic surfactant.
2. biological enzyme cleaner in environmental protection according to claim 1, which is characterized in that the teepol includes Sulfonate interfacial agent, sulfuric acid interfacial agent or amino acid pattern interfacial agent.
3. biological enzyme cleaner in environmental protection according to claim 2, which is characterized in that the sulfonate interfacial agent is selected from Oleoyl N-methyl taurate interfacial agent and/or fatty acid methyl ester sulfonate interfacial agent.
4. biological enzyme cleaner in environmental protection according to claim 2, which is characterized in that the sulfuric acid interfacial agent choosing From fatty acid glyceride sulfate interfacial agent or alkyl sulfate interfacial agent.
5. biological enzyme cleaner in environmental protection according to claim 2, which is characterized in that the amino acid pattern interfacial agent choosing From N- alkylaminoacid salts interfacial agent or N- acyl amino hydrochlorate interfacial agent.
6. biological enzyme cleaner in environmental protection according to claim 1, which is characterized in that the non-ionic surfactant is selected from Monoethanolamine interfacial agent, diethanol amine interfacial agent, beta-hydroxyethyl ethylenediamine interfacial agent, diethylentriamine interface Activating agent or combinations thereof.
7. biological enzyme cleaner in environmental protection according to claim 1, which is characterized in that the biological enzyme is selected from protease, fibre Tie up plain enzyme, amylase, lipase or combinations thereof.
8. biological enzyme cleaner in environmental protection according to claim 7, which is characterized in that the protease be selected from keratinase, Subtilopeptidase A, pepsin or combinations thereof.
9. described in any item biological enzyme cleaner in environmental protection according to claim 1~8, which is characterized in that the interfacial agent For 10wt%~25wt%, biological enzyme is 3wt%~8wt%, and surplus is sodium carbonate peroxide.
10. biological enzyme cleaner in environmental protection as described in any one of claims 1 to 9 in fabric softening agent, optical white, brighten Application in agent, bleaching agent or fabric color rendition.
CN201910141110.2A 2019-02-26 2019-02-26 Biological enzyme cleaner in environmental protection and its application Pending CN109897737A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910141110.2A CN109897737A (en) 2019-02-26 2019-02-26 Biological enzyme cleaner in environmental protection and its application

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910141110.2A CN109897737A (en) 2019-02-26 2019-02-26 Biological enzyme cleaner in environmental protection and its application

Publications (1)

Publication Number Publication Date
CN109897737A true CN109897737A (en) 2019-06-18

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CN201910141110.2A Pending CN109897737A (en) 2019-02-26 2019-02-26 Biological enzyme cleaner in environmental protection and its application

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112314640A (en) * 2020-08-03 2021-02-05 吴丹 Compound disinfectant with high adsorption performance
CN113841685A (en) * 2021-09-17 2021-12-28 濮阳圣恺环保新材料科技股份有限公司 Skeleton anticorrosion bleaching agent and application thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709246A (en) * 2009-11-24 2010-05-19 刘洪川 Formula of high-efficiency compound environment-protection detergent powder
CN103131542A (en) * 2013-03-20 2013-06-05 广州立白企业集团有限公司 Active oxygen washing machine tank cleaning agent and preparation method thereof
CN103756803A (en) * 2014-01-28 2014-04-30 湖南洁宇日化新技术股份有限公司 Laundry detergent composition for inhibiting ash deposition
CN106947625A (en) * 2017-03-29 2017-07-14 广东感恩生物科技有限公司 A kind of new concentrated detergent powder and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101709246A (en) * 2009-11-24 2010-05-19 刘洪川 Formula of high-efficiency compound environment-protection detergent powder
CN103131542A (en) * 2013-03-20 2013-06-05 广州立白企业集团有限公司 Active oxygen washing machine tank cleaning agent and preparation method thereof
CN103756803A (en) * 2014-01-28 2014-04-30 湖南洁宇日化新技术股份有限公司 Laundry detergent composition for inhibiting ash deposition
CN106947625A (en) * 2017-03-29 2017-07-14 广东感恩生物科技有限公司 A kind of new concentrated detergent powder and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112314640A (en) * 2020-08-03 2021-02-05 吴丹 Compound disinfectant with high adsorption performance
CN113841685A (en) * 2021-09-17 2021-12-28 濮阳圣恺环保新材料科技股份有限公司 Skeleton anticorrosion bleaching agent and application thereof

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Application publication date: 20190618

RJ01 Rejection of invention patent application after publication