KR20030092376A - Good dry and wet stop distance PCR Tread compound - Google Patents

Good dry and wet stop distance PCR Tread compound Download PDF

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KR20030092376A
KR20030092376A KR1020020030016A KR20020030016A KR20030092376A KR 20030092376 A KR20030092376 A KR 20030092376A KR 1020020030016 A KR1020020030016 A KR 1020020030016A KR 20020030016 A KR20020030016 A KR 20020030016A KR 20030092376 A KR20030092376 A KR 20030092376A
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weight
parts
rubber
carbon black
dry
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김현수
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금호타이어 주식회사
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    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47F—SPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
    • A47F3/00—Show cases or show cabinets
    • A47F3/04—Show cases or show cabinets air-conditioned, refrigerated
    • A47F3/0482—Details common to both closed and open types
    • A47F3/0495—Spraying, trickling or humidifying means
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47F—SPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
    • A47F3/00—Show cases or show cabinets
    • A47F3/001—Devices for lighting, humidifying, heating, ventilation
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47F—SPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
    • A47F3/00—Show cases or show cabinets
    • A47F3/04—Show cases or show cabinets air-conditioned, refrigerated
    • A47F3/0404—Cases or cabinets of the closed type
    • A47F3/0408—Cases or cabinets of the closed type with forced air circulation
    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47F—SPECIAL FURNITURE, FITTINGS, OR ACCESSORIES FOR SHOPS, STOREHOUSES, BARS, RESTAURANTS OR THE LIKE; PAYING COUNTERS
    • A47F3/00—Show cases or show cabinets
    • A47F3/04—Show cases or show cabinets air-conditioned, refrigerated
    • A47F3/0478—Control or safety arrangements
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
    • A61L2/02—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using physical phenomena
    • A61L2/08—Radiation
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24F—AIR-CONDITIONING; AIR-HUMIDIFICATION; VENTILATION; USE OF AIR CURRENTS FOR SCREENING
    • F24F6/00—Air-humidification, e.g. cooling by humidification
    • F24F6/12—Air-humidification, e.g. cooling by humidification by forming water dispersions in the air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D23/00—General constructional features
    • F25D23/003—General constructional features for cooling refrigerating machinery
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D29/00—Arrangement or mounting of control or safety devices
    • F25D29/005—Mounting of control devices
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F23/00—Advertising on or in specific articles, e.g. ashtrays, letter-boxes
    • G09F23/06—Advertising on or in specific articles, e.g. ashtrays, letter-boxes the advertising matter being combined with articles for restaurants, shops or offices
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2700/00—Means for sensing or measuring; Sensors therefor
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D2700/00—Means for sensing or measuring; Sensors therefor
    • F25D2700/12—Sensors measuring the inside temperature

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
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  • Dispersion Chemistry (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

PURPOSE: A tread rubber composition is provided, to improve the dry and wet traction without deterioration of the abrasion resistance and the gasoline mileage. CONSTITUTION: The rubber composition comprises 100 parts by weight of a source rubber comprising 35-40 parts by weight of an emulsion polymerization styrene-butadiene rubber whose styrene content is 35-45 wt%, 35-40 parts by weight of a solution polymerization styrene-butadiene rubber whose styrene content is 40-45 wt%, and 20-30 parts by weight of a butadiene rubber; and 25-45 parts by weight of carbon black as reinforcing filler. Preferably the carbon black has an iodine adsorption value of 90-100 mg/g, a DBP adsorption value of 114-124 cc/100 g, and ASTM tint of 115-120.

Description

마른 노면과 젖은 노면에서의 제동거리 특성이 우수한 트레드 고무조성물{Good dry and wet stop distance PCR Tread compound}Tread rubber composition with excellent braking distance characteristics on dry and wet roads {Good dry and wet stop distance PCR Tread compound}

본 발명은 트레드 고무조성물에 관한것으로, 보다 상세하게는 마른 노면과 젖은 노면에서 저연비 성능 및 제동성이 우수한 승용차(Passenger car, PCR)용 트레드 고무조성물에 관한 것이다.The present invention relates to a tread rubber composition, and more particularly to a tread rubber composition for a passenger car (Passenger car, PCR) having excellent fuel efficiency and braking properties on dry and wet road surface.

PCR 타이어에서 요구되는 성능은 매우 다양하다. 예를들어, 웨트 트랙션(wet traction)이나 저연비 성능과 밀접한 관계가 있는 저회전 저항, 그리고 소음, 내마모성, 그리고 제동성능 등을 들 수 있다.The performance required for PCR tires varies widely. For example, low traction resistance, which is closely related to wet traction and low fuel consumption, and noise, abrasion resistance, and braking performance.

그러나 이들 성능은 서로 이율배반적인 것으로서, 타성능의 희생없이 원하는 특정의 성능을 향상시키는 것이 매우 어려우며, 더군다나 이들 성능을 동시에 향상시키는 것은 더욱 어려운 문제이다.However, these performances are mutually exclusive, and it is very difficult to improve the specific performance desired without sacrificing other performance, and even more difficult to improve these performances simultaneously.

일예로, 웨트 트랙션의 향상은 저연비 성능의 저하를 수반하게 된다. 따라서, 저연비 성능의 저하없이 웨트 트랙션 성능의 개선시키기는 매우 어렵다.In one example, the improvement in wet traction is accompanied by a decrease in low fuel consumption performance. Therefore, it is very difficult to improve the wet traction performance without lowering the low fuel consumption performance.

이에, 본 발명은 저연비 성능을 확보한 고무 조성물의 제동성능을 개선하기 위하여 고 스티렌(high styrene) 함량을 갖는 고무 및 유리전이 온도가 낮은 고무의 조성비를 적절히 조절하고 표면적이 큰 카본블랙을 적용하여 기존의 연비 및 마모 성능을 동등 수준 이상을 유지하면서 마른 노면 및 젖은 노면에서의 제동력(Dry & Wet Traction) 성능 등 주행안전성을 향상시키는 PCR 트레드용 고무조성물을 제공하는 것을 목적으로 한다.Therefore, in order to improve the braking performance of a rubber composition having low fuel efficiency, the present invention properly adjusts the composition ratio of rubber having a high styrene content and rubber having a low glass transition temperature, and applies carbon black having a large surface area. It is an object of the present invention to provide a rubber tread composition for PCR tread that improves driving safety such as braking force on dry and wet roads while maintaining the same fuel economy and wear performance.

본 발명의 따른 마른 노면 및 젖은 노면의 제동성능이 우수한 트레드 고무조성물은 스티렌 함량이 35 ~ 45%인 유화중합 스티렌 부타디엔 고무(E-SBR) 35~40 중량부, 스티렌 함량이 40 ~ 45%인 용액중합 스티렌 부타디엔 고무(S-SBR) 35~40 중량부 및 부타디엔 고무(BR) 20~30 중량부 포함하는 원료고무 100 중량부에 대하여 카본블랙이 25 ~ 45 중량부 포함함을 특징으로 한다.The tread rubber composition having excellent braking performance of dry and wet roads according to the present invention is 35 to 40 parts by weight of emulsion-polymerized styrene butadiene rubber (E-SBR) having a styrene content of 35 to 45%, and a styrene content of 40 to 45%. The solution black styrene butadiene rubber (S-SBR) 35 to 40 parts by weight and butadiene rubber (BR) is characterized in that 25 to 45 parts by weight of carbon black based on 100 parts by weight of the raw material rubber.

본 발명에서 보강충진제로서 상기 카본블랙 이외에도 원료고무 100 중량부에 대하여 실리카를 40 중량부를 사용할 수 있다.As the reinforcing filler in the present invention, 40 parts by weight of silica may be used based on 100 parts by weight of the raw material rubber in addition to the carbon black.

본 발명에서 카본블랙은 다양한 특성을 가진 것을 사용한바 요오드 흡착가가 90∼100 mg/g, DBP 흡착가가 114∼125 cc/100g, ASTM Tint가 115∼120인 특성을 가진 카본블랙을 적용시 본 발명의 목적에 가장 부합하는 트레드 고무조성물을 얻을 수 있었다.In the present invention, the carbon black has various properties. The iodine adsorption value of 90 to 100 mg / g, the DBP adsorption value of 114 to 125 cc / 100 g, and the ASTM Tint of 115 to 120 are applied to the carbon black having the properties of the present invention. A tread rubber composition best suited to the purpose was obtained.

이하 본 발명을 다음의 비교예, 실시예 및 시험예에 의하여 설명하고자 한다. 그러나 이들은 본 발명의 일예로서 이들이 본 발명의 권리범위를 한정하는 것은 아니다.Hereinafter, the present invention will be described by the following comparative examples, examples and test examples. However, these are examples of the present invention and they do not limit the scope of the present invention.

<비교예>Comparative Example

다음 표 2에 제시된 배합비와 같이 본 발명에 따른 유화중합 SBR 40 중량부, 용액중합 SBR-1 40 중량부 및 부탄디엔 고무(BR) 20 중량부로 구성된 원료고무 100 중량부에 대하여 활성제(ZnO#S) 3 중량부, 실리카(Z-175) 40 중량부, 카본블랙으로(N-375) 31.2 중량부, 커플링제인 설파이드 실란(Sulfidsilane, Si-69)과 카본블랙 N-330이 1:1로 혼합된 X-50S(DEGUSSA, GERMANY) 6.4 중량부, 노화방지제(RD) 2 중량부, 노화방지제(K-13) 2 중량부, 노화방지제(WAX) 2 중량부, 활성제(S/A) 2 중량부, 가류제(S) 1.9 중량부, 촉진제(CZ) 1.8 중량부, 촉진제(DPG) 0.5 중량부를 혼합한 후 밴버리믹서(banbury mixer)를 이용하여 160℃에서 15~20분간 가류하여 트레드 고무를 제조하였다.The active agent (ZnO # S) based on 100 parts by weight of the raw material rubber consisting of 40 parts by weight of emulsion polymerization SBR, 40 parts by weight of solution polymerization SBR-1 and 20 parts by weight of butanediene rubber (BR) according to the compounding ratio shown in Table 2 below. ) 3 parts by weight, 40 parts by weight of silica (Z-175), carbon black (N-375) 31.2 parts by weight, sulfide silane (Sulfidsilane, Si-69) and carbon black N-330 in a 1: 1 ratio 6.4 parts by weight of mixed X-50S (DEGUSSA, GERMANY), 2 parts by weight of anti-aging agent (RD), 2 parts by weight of anti-aging agent (K-13), 2 parts by weight of anti-aging agent (WAX), active agent (S / A) 2 By weight, 1.9 parts by weight of vulcanizing agent (S), 1.8 parts by weight of accelerator (CZ), 0.5 parts by weight of accelerator (DPG), followed by vulcanization at 160 ° C. for 15-20 minutes using a banbury mixer. Was prepared.

본 발명에 사용되는 고무조성물은 표 1에 도시된 바와 같다. 유화중합 SBR은 유리전이온도(Tg)가 -25℃이며 스티렌(Styrene) 함량이 40.5% 이고, 용액중합 SBR-1은 비닐함량 33%의 미세구조를 가지며 유리전이 온도가 -33℃, 스티렌 함량이 35% 이고, 부탄디엔 고무는 시스 98%의 미세구조를 가지며 유리전이온도가 -109℃인 고무이다.The rubber composition used in the present invention is as shown in Table 1. The emulsion polymerization SBR has a glass transition temperature (Tg) of -25 ° C and a styrene content of 40.5%, and the solution polymerization SBR-1 has a microstructure of 33% vinyl content and a glass transition temperature of -33 ° C and styrene content. This is 35%, butanediene rubber is a rubber having a microstructure of the sheath 98% and a glass transition temperature of -109 ℃.

한편 보강충진제중 카본블랙(N-375)은 요오드 흡착가가 140 mg/g, DBP 흡착가가 130 cc/100g, ASTM Tint가 127인 특성을 가진다.Carbon black (N-375) among the reinforcing fillers has a characteristic of 140 mg / g of iodine adsorption, 130 cc / 100g of adsorption of DBP, and 127 of ASTM Tint.

<실시예 1><Example 1>

유화중합 SBR 40 중량부, 용액중합 SBR-2 40 중량부 및 부탄디엔 고무(BR) 20 중량부로 구성된 원료고무 100 중량부에 대하여 활성제(ZnO#S) 3 중량부, 실리카(Z-175) 40 중량부, 카본블랙으로(N-103) 31.2 중량부, 커플링제인 설파이드 실란(Sulfidsilane, Si-69)과 카본블랙 N-330이 1:1로 혼합된 X-50S(DEGUSSA, GERMANY) 6.4 중량부, 노화방지제(RD) 2 중량부, 노화방지제(K-13) 2 중량부, 노화방지제(WAX) 2 중량부, 활성제(S/A) 2 중량부, 가류제(S) 1.9 중량부, 촉진제(CZ) 1.8 중량부, 촉진제(DPG) 0.5 중량부를 혼합한 후 밴버리믹서(banbury mixer)를 이용하여 160℃에서 15~20분간 가류하여 트레드 고무를 제조하였다.3 parts by weight of activator (ZnO # S), silica (Z-175) 40 with respect to 100 parts by weight of the raw material rubber composed of 40 parts by weight of emulsion polymerization SBR, 40 parts by weight of solution polymerization SBR-2 and 20 parts by weight of butanediene rubber (BR). Parts by weight, carbon black (N-103) 31.2 parts by weight, X-50S (DEGUSSA, GERMANY) in which 1: 1 coupling of sulfide silane (Sulfidsilane, Si-69) and carbon black N-330 in a 1: 1 weight Part, 2 parts by weight of anti-aging agent (RD), 2 parts by weight of anti-aging agent (K-13), 2 parts by weight of anti-aging agent (WAX), 2 parts by weight of activator (S / A), 1.9 parts by weight of vulcanizing agent (S), Tread rubber was prepared by mixing 1.8 parts by weight of accelerator (CZ) and 0.5 parts by weight of accelerator (DPG), followed by vulcanization at 160 ° C. for 15-20 minutes using a banbury mixer.

본 발명에 사용되는 고무조성물은 표 1에 도시된 바와 같다. 유화중합 SBR은 유리전이온도가 -25℃이며 스티렌(Styrene) 함량이 40.5% 이고, 용액중합 SBR-2는 유리전이온도가 -33℃이며, 스티렌 함량이 40.5% 이고, 부탄디엔 고무는 시스 98%의 미세구조를 가지며 유리전이온도가 -109℃인 고무이다.The rubber composition used in the present invention is as shown in Table 1. The emulsion polymerization SBR has a glass transition temperature of -25 ° C and a styrene content of 40.5%. The solution polymerization SBR-2 has a glass transition temperature of -33 ° C, a styrene content of 40.5%. It is a rubber with a microstructure of% and a glass transition temperature of -109 ° C.

한편 보강충진제중 카본블랙(N-103)은 요오드 흡착가가 90 mg/g, DBP 흡착가가 114 cc/100g, ASTM Tint가 115인 특성을 가진다.Carbon black (N-103) among the reinforcing fillers has a characteristic of 90 mg / g of iodine adsorption, 114 cc / 100g of adsorption of DBP, and 115 of ASTM Tint.

<실시예 2><Example 2>

유화중합 SBR 35 중량부, 용액중합 SBR-2 35 중량부 및 부탄디엔 고무 30 중량부로 구성된 원료고무 100 중량부에 대하여 카본블랙(N-103) 26.2 중량부를 사용하는 것 이외에는 상기 실시예 1과 동일한 방법으로 트레드 고무를 제조하였다.Except for using 26.2 parts by weight of carbon black (N-103) based on 100 parts by weight of the raw material rubber consisting of 35 parts by weight of emulsion polymerization SBR, 35 parts by weight of solution polymerization SBR-2 and 30 parts by weight of butanediene rubber. The tread rubber was manufactured by the method.

표 1. 본 발명에 사용한 고무조성물Table 1. Rubber Compositions Used in the Present Invention

형태shape 스티렌(%)Styrene (%) 비닐(%)vinyl(%) 시스(%)Sheath (%) 유리전이온도(℃)Glass transition temperature (℃) 유화중합 SBREmulsification Polymerization SBR 40.540.5 -- -- -25-25 용액중합 SBR-1Solution Polymerization SBR-1 35.035.0 33.033.0 -- -33-33 용액중합 SBR-2Solution Polymerization SBR-2 45.045.0 -- -- -33-33 BRBR -- -- 98.098.0 -109-109

표 2. 고무조성물 배합비(단위 : 중량부)Table 2. Mixing ratio of rubber composition

구분division 비교예Comparative example 실시예1Example 1 실시예2Example 2 고무Rubber 유화 중합 SBREmulsion Polymerization SBR 40.040.0 40.040.0 35.535.5 용액 중합 SBR-1Solution Polymerization SBR-1 40.040.0 -- -- 용액 중합 SBR-2Solution Polymerization SBR-2 -- 40.040.0 35.535.5 BRBR 20.020.0 20.020.0 30.030.0 활성제Active agent ZnO#SZnO # S 3.03.0 좌동Left 좌동Left 충진제Filler Z-175Z-175 40.040.0 좌동Left 좌동Left X50SX50S 6.46.4 좌동Left 좌동Left N-375N-375 31.231.2 -- -- N-103N-103 -- 31.231.2 26.226.2 노방제Labor RDRD 2.02.0 좌동Left 좌동Left K-13K-13 2.02.0 좌동Left 좌동Left WAXWAX 2.02.0 좌동Left 좌동Left 활성제Active agent S/AS / A 2.02.0 좌동Left 좌동Left 가류제Vulcanizing agent SS 1.91.9 좌동Left 좌동Left 촉진제accelerant CZCZ 1.81.8 좌동Left 좌동Left DPGDPG 0.50.5 좌동Left 좌동Left

< 시험예 ><Test Example>

상기 비교예, 실시예 1 및 실시예 2에서 제조한 트레드 고무배합물을 ASTM 관련 규정에 의하여 물성시험을 측정하고 그 결과를 다음 표 3에 나타내었다.The physical properties of the tread rubber compounds prepared in Comparative Examples, Examples 1 and 2 were measured by ASTM-related regulations, and the results are shown in Table 3 below.

표3. 물성시험 측정결과구분Table 3. Physical property test result

구분division 비교예Comparative example 실시예 1Example 1 실시예 2Example 2 인장물성Tensile Properties 경도Hardness 6767 6868 6969 300% 모듈러스(kgf/cm2)300% modulus (kgf / cm 2 ) 108108 110110 115115 인장강도The tensile strength 190190 228228 238238 신장율(g)Elongation (g) 475475 534534 537537 동적점탄성Dynamic viscoelasticity 유리전이온도(Tg, ℃)Glass transition temperature (Tg, ℃) -19.7-19.7 -14.9-14.9 -14.3-14.3 Tanδ@0℃Tanδ @ 0 ℃ 0.3680.368 0.4030.403 0.3970.397 Tanδ@70℃Tanδ @ 70 ℃ 0.1280.128 0.1310.131 0.1250.125 Dry TractionDry traction tanδ(0℃)/E'(-1/3) tanδ (0 ° C) / E ' (-1/3) 244244 287287 302302 마모(Abrasion)Abrasion gg 0.0340.034 0.0320.032 0.0280.028

상기 표 3에 나타난 바와 같이, 실시예에 의한 본 발명의 트레드 고무가 종래의 트레드 고무에 비하여 인장물성 중 경도, 300% 모듈러스, 인장강도, 신장율 모두가 향상되었으며 또한 마모성능이 향상되었다. 특히 건조 노면 및 젖은 노면에서의 제동력이 좋아졌음을 알수 있다.As shown in Table 3, the tread rubber of the present invention according to the embodiment has improved the hardness, 300% modulus, tensile strength, and elongation of the tensile properties compared to the conventional tread rubber, and also improved wear performance. In particular, it can be seen that the braking force on dry and wet roads is improved.

상기와 같이, 실시예에서는 비교예보다 높은 스티렌 함량을 가진 용액중합 SBR-2를 사용하였으며 또한, 카본블랙을 N-103으로 함으로써 저연비성능 향상 및 마모성, 인장물성 그리고 건조 노면 및 젖은 노면에서의 제동력이 향상되는 효과가 있다.As described above, in Example, solution polymerization SBR-2 having a higher styrene content than that of Comparative Example was used, and the carbon black was N-103 to improve low fuel efficiency and abrasion, tensile properties, and braking power on dry and wet roads. This has the effect of being improved.

Claims (2)

스티렌 함량이 35∼45%인 유화중합 SBR 35∼40 중량부, 스티렌 함량이 40∼45%인 용액중합 SBR 35∼40 중량부 및 부타디엔 고무 20∼30 중량부로 구성된 원료고무 100 중량부에 대하여 보강충진제로 카본블랙 25∼45 중량부 포함하는 것을 특징으로 하는 마른노면 및 젖은노면의 제동성능이 우수한 트레드 고무조성물.Reinforcement with respect to 100 parts by weight of raw material rubber consisting of 35 to 40 parts by weight of emulsion polymerization SBR with 35 to 45% styrene content, 35 to 40 parts by weight of solution polymerization SBR with 40 to 45% styrene content and 20 to 30 parts by weight of butadiene rubber A tread rubber composition having excellent braking performance on dry and wet road surfaces, comprising 25 to 45 parts by weight of carbon black as a filler. 제 1 항에 있어서, 카본블랙은 요오드 흡착가가 90∼100 mg/g, DBP 흡착가가 114∼125 cc/100g, ASTM Tint가 115∼120 임을 특징으로 하는 마른노면 및 젖은노면의 제동성능이 우수한 트레드 고무조성물.The tread with excellent braking performance of dry and wet surfaces of claim 1, wherein the carbon black has an iodine adsorption value of 90 to 100 mg / g, a DBP adsorption value of 114 to 125 cc / 100 g, and an ASTM Tint of 115 to 120. Rubber composition.
KR1020020030016A 2002-05-29 2002-05-29 Good dry and wet stop distance PCR Tread compound KR20030092376A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100827321B1 (en) 2007-03-27 2008-05-07 금호타이어 주식회사 Tire tread rubber composition
KR101132780B1 (en) * 2009-12-22 2012-04-09 한국타이어 주식회사 Rubber composition for tire tread and tire manufactured by using the same
CN107383493A (en) * 2017-08-21 2017-11-24 万力轮胎股份有限公司 A kind of rubber composition of tire tread and its application
KR102261767B1 (en) * 2020-04-09 2021-06-07 넥센타이어 주식회사 Winter rubber composition with improved fuel efficiency and winter tire manufactured from it

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56163908A (en) * 1980-05-23 1981-12-16 Bridgestone Corp Pneumatic tyre
JPS62143947A (en) * 1985-12-19 1987-06-27 Yokohama Rubber Co Ltd:The Rubber composition for tire tread
JPS62273104A (en) * 1986-05-21 1987-11-27 Sumitomo Rubber Ind Ltd Radial tire for passenger car
KR19990040404A (en) * 1997-11-18 1999-06-05 홍건희 Low fuel consumption tire tread rubber composition with improved braking and wear resistance
KR20010106747A (en) * 2000-05-23 2001-12-07 조충환 Tire tread composition
KR20030015932A (en) * 2001-08-18 2003-02-26 금호산업 주식회사 Tread rubber composition improved wet traction

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS56163908A (en) * 1980-05-23 1981-12-16 Bridgestone Corp Pneumatic tyre
JPS62143947A (en) * 1985-12-19 1987-06-27 Yokohama Rubber Co Ltd:The Rubber composition for tire tread
JPS62273104A (en) * 1986-05-21 1987-11-27 Sumitomo Rubber Ind Ltd Radial tire for passenger car
KR19990040404A (en) * 1997-11-18 1999-06-05 홍건희 Low fuel consumption tire tread rubber composition with improved braking and wear resistance
KR20010106747A (en) * 2000-05-23 2001-12-07 조충환 Tire tread composition
KR20030015932A (en) * 2001-08-18 2003-02-26 금호산업 주식회사 Tread rubber composition improved wet traction

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100827321B1 (en) 2007-03-27 2008-05-07 금호타이어 주식회사 Tire tread rubber composition
KR101132780B1 (en) * 2009-12-22 2012-04-09 한국타이어 주식회사 Rubber composition for tire tread and tire manufactured by using the same
CN107383493A (en) * 2017-08-21 2017-11-24 万力轮胎股份有限公司 A kind of rubber composition of tire tread and its application
CN107383493B (en) * 2017-08-21 2019-06-18 万力轮胎股份有限公司 A kind of rubber composition of tire tread and its application
KR102261767B1 (en) * 2020-04-09 2021-06-07 넥센타이어 주식회사 Winter rubber composition with improved fuel efficiency and winter tire manufactured from it

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