KR20030062601A - The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver - Google Patents
The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver Download PDFInfo
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- KR20030062601A KR20030062601A KR1020020002869A KR20020002869A KR20030062601A KR 20030062601 A KR20030062601 A KR 20030062601A KR 1020020002869 A KR1020020002869 A KR 1020020002869A KR 20020002869 A KR20020002869 A KR 20020002869A KR 20030062601 A KR20030062601 A KR 20030062601A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic System
- D06M11/42—Oxides or hydroxides of copper, silver or gold
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/13—Physical properties anti-allergenic or anti-bacterial
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- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2501/00—Wearing apparel
- D10B2501/02—Underwear
- D10B2501/021—Hosiery; Panti-hose
Abstract
Description
본 발명은 아연과 은(銀)을 이용한 항균양말염색 제조에 관한 것으로 산화아연 100g과 은(銀)을 소립 분쇄한 은(銀)분말 100g을 용해조에 넣고 열을 주면서 염한 50ml와 질산 150ml를 합성하여 상기 용해조에 서서히 첨가 하면서 은을 용해시킨다. 상기 은용액을 중화시키기 위하여 가성소오다 용액을 첨가시키면서 아질산까스를 날려보내고 ph7.5가 되게 하여 물 1000ml에 염화주석 100g을 용해하여 은염과 혼합하여 은염 용액을 만든다. 또한 망초 100g을 물1000ml에 용해하고 가성소오다 ph12가 되게하여 가칭 알카리 촉매제를 만든다. 물 1000ml에 유화소다 50g을 넣고 용해하여 환원제를 만든다. 상기와 같이 은염용액과 또한 촉매제와 환원제를 만들어 항균염색제를 제조한다. 그리고 상기 항균염색제 사용을 살펴보면 다음과 같다. 항균하고자 하는 양말을 은염용액에 10분 침지시켜 탈수한 후 가교제에 10분 침지시키는 순간 브라운 색상이 착염된다. 상기 착염된 양말을 환원제에 10분간 침지시키면 브라운색이 회색으로 된다. 상기 양말을 세척 건조하여 본 발명의 항균 양말염색을 완성시키는 방법이다.The present invention relates to the production of antimicrobial powder dyeing using zinc and silver. 100g of zinc oxide and 100g of silver powder obtained by pulverizing silver particles are put into a dissolution tank and synthesized 50ml of salt and 150ml of nitric acid while being heated. To dissolve the silver while slowly adding to the dissolution tank. To neutralize the silver solution, add caustic soda solution and blow the nitrous acid cutlet to pH 7.5 to dissolve 100 g of tin chloride in 1000 ml of water and mix with silver salt to make a silver salt solution. In addition, 100 g of forget-me-not is dissolved in 1000 ml of water, and caustic soda ph12 is used to make a tentative alkali catalyst. 50 g of sodium sulfate is added to 1000 ml of water to dissolve to form a reducing agent. As described above, an antimicrobial dye is prepared by making a silver salt solution and also a catalyst and a reducing agent. And look at the use of the antimicrobial dyes are as follows. Socks to be antibacterial dehydrated by immersion in silver salt solution for 10 minutes, and then immersed in a crosslinking agent for 10 minutes. When the complexed socks are immersed in a reducing agent for 10 minutes, the brown color becomes gray. Washing and drying the socks is a method of completing the antibacterial socks dyeing of the present invention.
상기 항균염색 제조 방법을 구체적으로 살펴보면 다음과 같다.Looking at the antimicrobial dye production method in detail.
본 발명에서 먼저 은(銀)과 아연을 항균 염색제의 주안점으로 사용한 것은 아연과 은(銀)은 항균 금속으로 항균력이 우수하다. 이중 은(銀)은 항균 금속으로 높이 평가하고 있을 뿐 아니라 지상의 모든 병균이나 마이러스가 은에 접촉되어 6분간 살아남는 균이 없다고 보고되었다. 또한 산화아연은 안전성이 높고 인자에 무독이므로 어린아이 땀띠, 화장품 등에 널리 사용하고 있어 이들을 항균 담체로 사용하면서 용해시키면서 질산과 염산을 사용한 것은 은(銀)과 아연은 질산에 잘 녹을 뿐 아니라 질산이 은과 결합되어 용해되었을 경우 침투력이 아주 우수할 뿐 아니라 또한 산화아연은 산과 알카리에 잘 녹는다. 상기은염에는 염화주석, 질산염, 산화아연, 알카리염으로 합성되어 물에 잘 녹아 있으므로 상기 은염은 침투력이 매우 우수하다. 또한 촉매제로 망초와 알카리용액(PH12)1,000ml를 만들어 촉매제로 사용한 것은 항균하고자하는 흰양말을 은염 용액에 침지시키면 은염이 양말에 침주된다. 상기 양말을 은염에 10분간 침지시켜 탈수하여 촉매제인 알카리용액에 침지시키는 순간 짙은 부라운에 침지되는 순간 브라운색상이 착염된다. 이것은 은이 알카리와 결합하면서 은이 Ag+로 이온화되면서 양말에 침지되면서 알카리용액의 독성에 의하여 색상이 변하게 된다. 상기 착염된 양말을 탈수하여 그대로 두면 색상이 변화되는 것이 발견된다. 이것은 은염이 햇볕 염소, 불소화합물 등에 흑변 또는 항변되는 것이 특징이다. 본 발명은 가성소오다에 침지된 색상이 변화를 막고 고착시키기 위해 물1000ml에 유화소오다 50g을 넣고 용해한 용액인 환원제를 만들어 상기 양말을 침지시키는 순간 회색으로 화원되어 색상이 염착되어 변화되지 않는 것이발견되었다. 이것은 은염의 고형분의 량과 촉매제의 가성소오다 PH와 망초 등의 염소량에 따라 색상이 다르게 나타나는 것이 확인되었고 또한 양말을 침지시키는 시간에 따라 색상의 변화가 있고 촉매제 및 환원제 종류에 따라 색상이 다르게 나타날 뿐 아니라 자연섬유와 화학섬유로 만들어진 양말 등을 같은 조건에서 항균 염색 할 경우 대상이 다른 것이 확인되고 있다. 본 발명의 은항균염색은 온수와 냉수에 관게없이 착염이 되는 것이 확인되고 세척결려도가 시험테스터 결과 2도가 되었다. 또한 인디고 염료와 같이 자연적이고 부드러운 색상이고 세척을 하면 눈에 보이지 않게 물이 빠져 항상 새로운 양말을 착용하는 것 같은 권퇴롭지 않을 뿐 아니라 발에 냄새 등이 전혀 나지 않고 항균효과가 반영구적이다.In the present invention, the first use of silver (아연) and zinc as an antimicrobial dye, zinc and silver (항균) is an antibacterial metal is excellent antibacterial activity. Among them, silver is highly regarded as an antibacterial metal, and it has been reported that all germs or myruses on the ground survive for 6 minutes by contact with silver. In addition, zinc oxide is highly safe and non-toxic, and it is widely used in children's sweat bands and cosmetics, and the use of nitric acid and hydrochloric acid while dissolving them as an antimicrobial carrier makes silver and zinc not only soluble in nitric acid but also nitric acid. When dissolved in combination with silver, the penetration is very good, and zinc oxide is also soluble in acids and alkalis. The silver salt is synthesized with tin chloride, nitrate, zinc oxide, and alkali salts, so that it is well dissolved in water. In addition, 1,000 ml of forget-me-not and alkaline solution (PH12) were used as a catalyst and the catalyst was used as a catalyst to immerse silver salt in socks. The sock is immersed in silver salt for 10 minutes, dehydrated and immersed in an alkaline solution as a catalyst. This is because silver binds with alkali and silver is ionized with Ag +, soaked in socks, and the color is changed by the toxicity of alkaline solution. It is found that the color changes when the complexed socks are dehydrated and left as is. This is characterized in that silver salt is blackened or denatured in sunlight chlorine, fluorine compound and the like. In the present invention, the color immersed in caustic soda is made of a reducing agent which is a solution dissolved by adding 50 g of sodium sulphate in 1000 ml of water in order to prevent change and fixation. Found. It was confirmed that the color was different depending on the amount of solids of silver salt and the amount of chlorine, such as caustic soda PH and forget-me-not of the catalyst, and also the color was changed depending on the time of soaking the socks and the color was different depending on the type of catalyst and reducing agent. In addition, when antibacterial dyeing of socks made of natural fibers and chemical fibers under the same conditions, it is confirmed that the target is different. Silver antibacterial staining of the present invention was confirmed to be complex salt irrespective of hot water and cold water and the degree of washing was 2 degrees as a result of the test tester. In addition, it is natural and soft color like indigo dye and washes invisibly and water is not repulsed like wearing new socks at all times, and foot does not smell at all and antibacterial effect is semipermanent.
기존 양말 항균을 살펴보면 은을 소립 분해한 분말을 섬유원료에 합성하여 실을 뽑아 양말을 제조한 항균양말이 있고 키토산이나 은을 수지에 혼합하여 양말에 접착시킨 항균 양말 등이 있고 본 발명자가 은을 파라듐 등과 합성하여 양말에 침지시켜 항균제로 시판하고 있다. 본 발명과 같이 은염을 이용하여 양말에 항균염색하는 기술과는 많은 차이가 있다.Looking at the existing antibacterial socks, there is an antibacterial socks made of synthetically pulverized silver powder into a fiber material to make socks, and antibacterial socks, which are made by mixing chitosan or silver with a resin and adhering to the socks. It is synthesized with palladium and soaked in socks and marketed as an antibacterial agent. There are many differences from the technique of antibacterial dyeing on socks using silver salt as in the present invention.
상기에 밝힌 바와 같이 본 발명은 산화아연과 은을 이용하여 은염을 만들어 항균매체로 하면서 상기 항균매체를 수지를 전혀 사용하지 않고 양말에 항균 효과를 고착 착염시키는 기술이다.As described above, the present invention is a technique for fixing silver and salt of antibacterial effect on socks without using any resin while making silver salt using zinc oxide and silver as an antimicrobial medium.
본 기술은 염료를 전혀 사용하지 않고 은염이 햇볕 또는 하로겐 화합물과 결합하거나 할 때 흑변 또는 항변되는 성질을 이용하여 알카리로 은을 양말에 이온화시키면서 은염이 독성인 가성소오다용액과 결합할 때 브라운 색상이 되면서 햇볕에 산화되는 것이 본 발명자가 발견하여 간단한 양말을 상기 은염용액에 착염시켜 항균염색을 하면서 햇볕 등에 산화되고 항변되는 성질을 막기 위하여 환원제로 유화소오다를 사용하여 색상의 변화가 없게 고착시키는 기술을 발명하였다. 상기 항균 염착된 양말을 염색 결여도가 3도 정도이고 또한 세척 등에 의하여 눈에 잘 보이지 않게 탈색되는 것이 기존 염료에서 찾아볼 수 없는 자연적이고 부드러운 색상을 양말에 항균과 동시에 염색하는 방법이다.This technique uses the properties of blacking or anti-singing when silver salts are combined with sunlight or halogen compounds without the use of dyes at all, and when silver salts are combined with poisonous caustic soda solution while ionizing silver into socks. The inventors found that the color becomes oxidized in the sun as it becomes a color, so that the simple socks are soaked in the silver salt solution for antimicrobial dyeing to prevent oxidized and resisted properties in the sun. Invented the technology. The antimicrobial dyed socks are dyed at a degree of about 3 degrees and are not easily visible by washing, etc., which is a method of simultaneously dyeing socks with antibacterial natural and soft colors not found in conventional dyes.
상기와 같은 본 발명의 양말 항균염색 방법은 은염용액에 항균 금속의 고형분과 촉매제의 량과 ph에 따라 색상과 항균력이 다르다. 또한 환원제의 고형분량과도 색상에 밀접한 관계가 있어 촉매제와 환원제 종류를 개발하면 수가지의 색상을 현재 양말 색상에서 찾아볼 수 없는 항균 염색 디자인을 찾을 수 있다.Socks antimicrobial dyeing method of the present invention as described above is different in color and antimicrobial power depending on the amount and ph of the solid content of the antimicrobial metal and the catalyst in the silver salt solution. In addition, there is a close relationship between the solid content of the reducing agent and the color, so developing a kind of catalyst and reducing agent can find an antimicrobial dyeing design in which several colors are not currently found in the socks color.
본 발명의 구성을 살펴 보면 다음과 같다. 먼저 은염 용액인 항균 및 염색매체를 제조하기 위하여 산화아연 100g과 은을 소립 분쇄한 분말 100g을 용해조에 넣고 열을 주면서 염산 50ml와 질산 150ml를 혼합하여 서서히 용해조에 넣고 아연과 은을 녹인다. 또한 상기 은용액을 중화시키기 위하여 가성소오다 용액을 첨가하면서 아질산까스를 날려 보내면서 PH7.5가 되게 한다. 물 1000ml 에 염화주석 100g을 용해하여 상기 중화된 은염에 첨가하여 은염용액을 만든다. 또한 망초 50g을 물 1000ml에 용해하여 촉매제를 만든다. 그리고 환원제를 만들기 위하여 물1000ml에 유화소오다 50g을 넣고 용해하여 항균양말 염색제를 제조한다. 상기 항균염색제에양말을 항균착염하기 위하여 정연된 양말 1켤레를 은염 용액에 10분 침지시켰다가 탈수하여 촉매제인 알카리염에 10분 담갔다가 탈수하여 환원제에 10분 담갔다가 탈수 건조하여 본 발명의 항균양말 염색제조를 완성하는데 상기 본 발명의 항균양말 염색제조를 보다 더 상세한 설명은 실시예에서 설명하기로 한다.Looking at the configuration of the present invention. First, 100g of zinc oxide and 100g of finely pulverized powder of silver are pulverized in a dissolution tank, and 50ml of hydrochloric acid and 150ml of nitric acid are mixed in a dissolution tank to slowly dissolve zinc and silver. Also, to neutralize the silver solution, the caustic nitrite is blown off while adding caustic soda solution to PH7.5. 100 g of tin chloride is dissolved in 1000 ml of water and added to the neutralized silver salt to prepare a silver salt solution. Also, 50 g of forget-me-not is dissolved in 1000 ml of water to make a catalyst. Then, to make a reducing agent, 50 g of sodium sulfate is dissolved in 1000 ml of water to prepare an antimicrobial socks dye. In order to antibacterial dyeing of the socks on the antimicrobial dye, a pair of square socks were immersed in silver salt solution for 10 minutes and then dehydrated. To complete the socks dyeing production of the antimicrobial socks dyeing of the present invention will be described in more detail in the Examples.
[실시예1]Example 1
은염 항균제 및 양말 염색 촉매제 제조 Manufacture of silver salt antibacterial agent and sock dyeing catalyst
제1공정1st process
산화아연 100g과 은을 분쇄 소립한 분말 100g을 정량한다.100 g of zinc oxide and 100 g of powder obtained by grinding and pulverizing silver are quantified.
제2공정2nd process
염산 50ml와 질산 150ml를 혼합하여 정량한다.50 ml of hydrochloric acid and 150 ml of nitric acid are mixed and quantified.
제3공정3rd process
용해조 1000ml 용량을 준비하여 열을 줄 수 있도록 준비하면서 용해조 위에 가스를 빨아낼 수 있는 간단한 장치를 한다.Prepare a 1000 ml capacity of the dissolution tank and prepare a simple device that can draw gas over the dissolution tank while preparing it for heat.
제4공정4th process
가성소오다 용액(ph12) 1000ml에 염화주석 100g을 용해하여 정량한다.Dissolve 100 g of tin chloride in 1000 ml of caustic soda solution (ph12) and quantify it.
제5공정5th process
가성소오다 용액(ph12) 1000ml에 망초 50g을 용해하여 가칭 알카리 촉매제를 만든다.50 g of forget-me-not is dissolved in 1000 ml of caustic soda solution (ph12) to form a tentative alkali catalyst.
제6공정6th process
물 1000ml에 유화소오다 50g을 용해하여 환원제를 만들어 정량한다.Dissolve 50 g of sodium sulfate in 1000 ml of water to make a reducing agent.
제7공정7th process
제1공정의 약품을 제3공정의 용해조에 넣고 열을 주면서 제2공정의 약품을 서서히 첨가 시키면서 은을 용해한다.The chemicals in the first process are added to the dissolution tank in the third process and the silver is dissolved while gradually adding the chemicals in the second process.
제8공정8th process
제7공정에 제8공정의 알카리 용액을 서서히 첨가시키면서 제7공정의 약품을 중화시키면 아질산까스가 발생하는데 상기 가스를 날려 보내면서 PH7.5가 되게 물 3000ml를 용해하여 본 발명의 항균 염색제를 만든다.Neutralizing the chemicals of the seventh step while gradually adding the alkaline solution of the eighth step to the seventh step, nitrous acid cutlet is generated, dissolving 3000 ml of water to PH7.5 while blowing the gas to make the antimicrobial dye of the present invention. .
[실시예 2]Example 2
항균 양말 염색 방법 Antibacterial Sock Dyeing Method
제1공정1st process
양말 1켤레를 준비한다.Get a pair of socks ready.
제2공정2nd process
[실시예 1] 제8공정의 은염 용액 1000ml를 정량한다.Example 1 1000 ml of the silver salt solution of the eighth step was quantified.
제3공정3rd process
[실시예 1] 의 제5공정 촉매제 1000ml를 준비한다.1000 ml of the 5th process catalysts of Example 1 were prepared.
제4공정4th process
[실시예 1] 의 제6공정 환원제 1000ml를 정량 준비한다.1000 ml of 6th process reducing agents of Example 1 is prepared quantitatively.
제5공정5th process
제1공정의 양말을 제2공정의 용액에 10분간 침지시켜 탈수한다.The socks of the first step are immersed in the solution of the second step for 10 minutes and dehydrated.
제6공정6th process
제2공정의 촉매제에 제4공정의 양말을 10분간 침지시켜 탈수한다.The socks of the fourth step are immersed in the catalyst of the second step for 10 minutes to be dehydrated.
제7공정7th process
제3공정의 환원제에 제5공정의 양말을 10분간 침지시켜 탈수 세척하여 본 발명의 산화아연을 이용한 항균양말 염색 제조를 완성한다.The socks of the fifth step were immersed in the reducing agent of the third step for 10 minutes to be dehydrated and washed to complete the antimicrobial socks dyeing production using the zinc oxide of the present invention.
본 발명에서 은염을 이용한 항균양말 염색은 항균효과가 우수하여 착용할 경우 탈취효과는 물론 무좀, 습진 등이 예방되고 기존 양말 염색에게 찾아볼 수 없는 부드럽고 자연스러운 양말 색상을 얻을 수 있다.Antimicrobial socks dyeing using silver salt in the present invention has excellent antibacterial effect when worn, as well as deodorant effect, athlete's foot, eczema is prevented and can be obtained a soft natural socks color not found in conventional socks dyeing.
Claims (1)
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020020002869A KR20030062601A (en) | 2002-01-17 | 2002-01-17 | The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver |
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| Application Number | Priority Date | Filing Date | Title |
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| KR1020020002869A KR20030062601A (en) | 2002-01-17 | 2002-01-17 | The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver |
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| KR20030062601A true KR20030062601A (en) | 2003-07-28 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190001047A (en) * | 2017-06-26 | 2019-01-04 | (주)바이오소재 | Bio-vinyl composition for antimicrobial roll bags, sanitary bags and sanitary gloves using biodegradable catalyst |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5458906A (en) * | 1993-09-13 | 1995-10-17 | Liang; Paul M. S. | Method of producing antibacterial fibers |
| KR19980087632A (en) * | 1998-09-04 | 1998-12-05 | 강남석 | Silver Gun Product Manufacturing Method |
| KR19990014311U (en) * | 1998-12-31 | 1999-04-26 | 임병윤 | Silver Antibacterial Structure of Cloth |
| WO2000075415A1 (en) * | 1999-06-07 | 2000-12-14 | The Cupron Corporation | An article of clothing having antibacterial, antifungal, and antiyeast properties |
| KR20020062535A (en) * | 2001-01-22 | 2002-07-26 | 정태은 | Manufacture Method of Silver Coating Cloths |
| KR20030052226A (en) * | 2001-12-20 | 2003-06-26 | 박서현 | The manufacture metal to shide socks |
-
2002
- 2002-01-17 KR KR1020020002869A patent/KR20030062601A/en not_active Application Discontinuation
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5458906A (en) * | 1993-09-13 | 1995-10-17 | Liang; Paul M. S. | Method of producing antibacterial fibers |
| KR19980087632A (en) * | 1998-09-04 | 1998-12-05 | 강남석 | Silver Gun Product Manufacturing Method |
| KR19990014311U (en) * | 1998-12-31 | 1999-04-26 | 임병윤 | Silver Antibacterial Structure of Cloth |
| WO2000075415A1 (en) * | 1999-06-07 | 2000-12-14 | The Cupron Corporation | An article of clothing having antibacterial, antifungal, and antiyeast properties |
| KR20020062535A (en) * | 2001-01-22 | 2002-07-26 | 정태은 | Manufacture Method of Silver Coating Cloths |
| KR20030052226A (en) * | 2001-12-20 | 2003-06-26 | 박서현 | The manufacture metal to shide socks |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20190001047A (en) * | 2017-06-26 | 2019-01-04 | (주)바이오소재 | Bio-vinyl composition for antimicrobial roll bags, sanitary bags and sanitary gloves using biodegradable catalyst |
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