KR20030052226A - The manufacture metal to shide socks - Google Patents

The manufacture metal to shide socks Download PDF

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Publication number
KR20030052226A
KR20030052226A KR1020010087641A KR20010087641A KR20030052226A KR 20030052226 A KR20030052226 A KR 20030052226A KR 1020010087641 A KR1020010087641 A KR 1020010087641A KR 20010087641 A KR20010087641 A KR 20010087641A KR 20030052226 A KR20030052226 A KR 20030052226A
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South Korea
Prior art keywords
silver
solution
socks
antimicrobial
water
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KR1020010087641A
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Korean (ko)
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박서현
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박서현
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Priority to KR1020010087641A priority Critical patent/KR20030052226A/en
Publication of KR20030052226A publication Critical patent/KR20030052226A/en

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    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41BSHIRTS; UNDERWEAR; BABY LINEN; HANDKERCHIEFS
    • A41B11/00Hosiery; Panti-hose
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00Medicinal preparations containing inorganic active ingredients
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K33/00Medicinal preparations containing inorganic active ingredients
    • A61K33/24Heavy metals; Compounds thereof
    • A61K33/38Silver; Compounds thereof

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

PURPOSE: A method of making functional sock is provided to give the antimicrobial effect to the sock in order to inhibit the propagation of athlete's foot together with the deodorizing effect. CONSTITUTION: An antimicrobial is prepared by mixing tin chloride, hydroxine, hydrochloric acid and soda citrate with a silver solution. A loess water is made by mixing jade, ceramic and loess with water. The loess water is added to the antimicrobial to make an antimicrobial loess solution. An alkali synthetic zeolite is made, and dissolved in water to make a zeolite solution with the pH of 10. The target sock is dipped first in the antimicrobial loess solution, and then in the zeolite solution.

Description

기능성 양말 제조{The manufacture metal to shide socks}Manufacture of functional socks {The manufacture metal to shide socks}

본 발명은 기능성 양말 제조에 관한 것이다.The present invention relates to the manufacture of functional socks.

현재 널리 사용하고 있는 양말에 기능을 살리기 위하여 먼저 양말에 각종 병원균을 이나 바이러스가 서식하여 발에 무좀이나 습진등이 생기면서 악취등이 나고 불쾌감을 준다. 본 발명은 먼저 양말에 항균하기 위하여 은(銀)콜로이드 용액에 주석, 히드록신, 구연산소오다, 염산을 합성시켜 용해한 용액에 옥분말, 황토, 세라막 분말을 생수에 용해 교반하여 옥 및 황토 지장수를 만들어 상기 은염 용액에 합성하여 은 항균제를 만든다. 또한 은(銀)을 이온화시켜 양말 등에 완전 침지시켜 세척이나 마찰에 떨어지지 않게 하기 위하여 알카리염이 용액을 만들기 위하여 가성소오다용액에 알미늄을 용해 반응시키고 상기 용액에 규산소오다를 합성시켜 반응하여 알카리형 인조제오라이트를 만들면 탈취효과가 우수한 제품이 된다. 상기 인조제오라이트를 물에 용해하여 ph10이 되게한 용액에 상기 양말을 은용액에 침지시켜 탈수 한 후 인조제오라이트용액에 침지시키면 은염과 세라믹 인조제오라이트가 양말에 은이 이온화되어 세척이나 마찰에 잘떨어지지 않고 은이 무전극 도금화 된다. 은(銀)은 현재에 와서는 지상의 모든 병균이나 바이러스가 은에 붙어 6분간살아남는 균이 없다고 보고되고 있다. 또한 은(銀)은 항균금속으로 안전성이 매우 높다고 인정하고 있다. 현재 은(銀)을 이용한 양말에 항균하는 방법으로는 은분말을 무기물에 치환하여 수지에 합성하여 양말등에 코팅처리하는 방법이 공지화되고 있다. 상기 방법으로는 수지가 마찰등에 떨어지면 항균성도 떨어지고 또한 양말 고유의 부드러운 촉감을 죽이는 점 이 있다. 또한 일반 병균 처리 방법으로는 키토산을 수지에 혼합하여 처리하는 방법이 있고 동(同)이나 구리선을 이용하여 항균처리 하지만 구리는 인자에 유전변이를 일으키므로 사용상 문제가 되고 있다. 본 발명은 은(銀)을 무전극 양말에 이온화하면서 침지시키는 기술이다. 또한 세라믹, 옥, 황토를 물에 지장수를 만들어 은과 같이 이온화시켜 사용하므로 옥, 세라믹, 황토의 기능을 살리는 기술이고 또는 기술의 핵심은 은을 알카리용액으로 이온화시키면서 탈취효과가 우수한 인조제오라이트 용액을 사용하면서 탈취 효과를 높였다.In order to make use of the socks that are currently widely used, various pathogens or viruses inhabit the socks, resulting in athlete's foot, eczema, etc., resulting in bad smell and discomfort. The present invention first synthesized by dissolving tin, hydroxyl, sodium citrate, hydrochloric acid in a silver colloidal solution in order to antibacterial to socks, jade powder, ocher, cerammak powder dissolved in bottled water and jade It is synthesized in the silver salt solution to make a silver antibacterial agent. In addition, in order to make the solution ionized by silver ionization so as to be completely immersed in socks or the like so that alkali salts can be dissolved into solution, aluminum is dissolved in caustic soda solution to synthesize soda silicate in the solution. If you make a type artificial zeolite, the product is excellent in deodorizing effect. When the artificial zeolite was dissolved in water to make ph10, the socks were immersed in silver solution and dehydrated. Then, when the artificial zeolite solution was immersed in silver solution, the silver salt and ceramic artificial zeolite were ionized to the socks, and silver was not easily washed or rubbed. Electrodeless plating. Silver has not been reported to survive any of the earth's germs or viruses that have survived for six minutes. Silver is also an antimicrobial metal and has been recognized as having very high safety. Currently, as a method of antibacterial to socks using silver (silver), a method of coating silver socks by coating them with synthetic resins by substituting silver powder with inorganic materials has been known. In the above method, when the resin falls on friction, the antibacterial property is also lowered, and the soft touch of the socks is killed. In addition, a common germ treatment method is a method in which chitosan is mixed with a resin and treated, and antibacterial treatment is performed using copper or copper wire, but copper has a problem in use because it causes dielectric variation in printing. The present invention is a technique of immersing silver while ionizing it into an electrodeless sock. In addition, since ceramic, jade, and ocher are made into water and ionized like silver, they are used to make jade, ceramic, and ocher functions. The core of the technology is to make artificial zeolite solution with excellent deodorizing effect while ionizing silver with alkaline solution. Increased deodorizing effect while using.

본 발명은 은(銀)용액에 염화주석, 히드록신, 구연산소오다, 염산을 합성하여 은을 양말에 무전극 도금화 하기 위하여 알카리용액으로 은(銀)을 (Ag+)이온화시키는 기술을 제공하면서 알카리 용액을 탈취효과가 우수한 알카리형 인조제오라이트를 만들어 물에 용해하여 사용하면서 옥, 세라믹, 황토를 지장수를 만들어 은염용액과 합성하여 상기 은염 용액에 양말을 침지시켜 탈수한 후 바로 알카리 용액인 인조제오라이트 용액에 침지시켜 은을 이온화시켜 세척이나 마찰에 떨어지지 않게 하면서 옥, 세라믹, 황토, 탈취 등의 효과를 얻을 수 있는 기능성 양말을 제조하는 기술을 제공하였다.The present invention synthesizes tin chloride, hydroxyxine, sodium citrate, and hydrochloric acid in a silver solution to provide a technique of ionizing silver (Ag +) with an alkaline solution in order to electrolessly plate silver on a sock. Alkaline solution made of alkaline type zeolite with excellent deodorizing effect is dissolved and used in water, jade, ceramic, ocher is made of Jiji water, synthesized with silver salt solution, and soaked in the silver salt solution to dehydrate and then artificial zeolite is alkaline solution. The present invention provides a technology for producing functional socks that can be obtained by immersing in a solution to ionize silver so as not to fall on washing or friction, and to obtain jade, ceramic, loess, and deodorization effects.

본 발명의 가능성양말 제조 구성을 살펴 볼 것 같으면 먼저 양말에 은을 항균시키기 위하여 현재 공지화되어 있는 은(銀)염을 콜로이드한 은용액(고형분 100g)을 은을 양말에 문전극 도금하기 위하여 염화주석, 구연산소오다, 히도록신, 염산을 소량 은용액에 합성교반 하여 은항균제를 만든다. 또한 옥, 세라믹, 황토분말을 생수에 믹스 혼합하여 30분간 교반하여 옥, 황토세라믹, 지장수를 은용액에 합성했다. 또한 본 기술에서 핵심인 은을 이온화 하기 위하여 알카리 용액을 이용하기 위하여 탈취 효과가 우수한 알칼리형 인조제오라이트를 만들기 위하여 알카리 용액(20%)1,000ml에 알미늄분말 200g을 용해 반응한 후 규산소오다 200g을 합성하여 반응시켜 건조한 인조제오라이트를 물에 용해하여 ph10의 알카리용액 1000ml를 준비한다. 그리고 본 발명의 기능성 양말을 만들기 위하여 양말을 은염에 침지시켜 탈수하여 알카리형 인조제오라이트 용액에 침지시켜 본 발명의 기능성 양말을 제조한다. 상기 기능성양말의 약품 제조 및 처리 방법을 실시예에서 보다 상세하게 설명하기로 한다.If you look at the configuration of the possibility of the present invention, first, a silver solution (solid content of 100 g) colloidal silver salts currently known for antimicrobial of silver on socks is chlorinated to plate silver on the socks. Tin and silver citric acid, hydoxycin, and hydrochloric acid are mixed and stirred in a small amount of silver solution to make silver antibacterial agent. In addition, jade, ceramic and ocher powder were mixed and mixed with bottled water and stirred for 30 minutes to synthesize jade, ocher ceramic and jijangsu in a silver solution. In addition, in order to make alkaline artificial zeolite with excellent deodorizing effect in order to use alkali solution to ionize silver which is the core of this technology, 200g of aluminum silicate is dissolved after 200g of aluminum powder is dissolved in 1,000ml of alkaline solution (20%). Synthesis and reaction were performed to dissolve the dried artificial zeolite in water to prepare 1000 ml of alkaline solution of ph10. And to make the functional socks of the present invention, the socks are immersed in silver salt and dehydrated to immerse in an alkaline artificial zeolite solution to prepare the functional socks of the present invention. The drug manufacturing and processing method of the functional socks will be described in more detail in the Examples.

[실시예1]Example 1

·약품제조Drug manufacturing

제1공정1st process

은콜로이드 용액(은고형분 10%)을 1,000ml정량한다.1,000 ml of a silver colloidal solution (silver solids 10%) is weighed.

제2공정2nd process

염화주석 100g, 히드록산 50ml, 염산 50ml, 구연산소오다 50g을 정량한다.100 g of tin chloride, 50 ml of hydroxy acid, 50 ml of hydrochloric acid, and 50 g of sodium citrate are quantified.

제3공정3rd process

옥분말 200g, 황토 100g, 세라믹 200g을 정량하여 생수 1,500ml에 용해하여 30분간 교반하여 옥, 세라믹, 황토, 지장수 1,000ml를 정량한다.200g of jade powder, 100g of ocher and 200g of ceramic are dissolved and dissolved in 1,500ml of bottled water and stirred for 30 minutes to quantify 1,000ml of jade, ceramic, ocher and jijangsu.

제4공정4th process

알카리형 인조제오라이트 인 탈취제를 만들기 위하여 가성소오다용액(20%)1,000ml에 알미늄 분말 200g을 용해 반응시켜 구산소오다 200g을 합성시켜 반응하여 건조시켜 만들어진 인조제오라이트 300g을 정량한다.In order to make an alkaline artificial zeolite phosphorus deodorant, 200 g of aluminum powder was dissolved and reacted in 1,000 ml of caustic soda solution (20%) to synthesize 200 g of sodium octanoate, and then reacted and dried to prepare 300 g of artificial zeolite.

제5공정5th process

물 1,000ml에 제4공정의 인조제오라이트 200g을 용해하여 ph10이 되게 하여 알카리 용액을 정량한다.200 g of artificial zeolite of the fourth step is dissolved in 1,000 ml of water to make ph10, and the alkali solution is quantified.

제6공정6th process

제1공정에 제2공정, 제3공정의 약품을 혼합하여 은항균제를 만들어 1,000ml를 정량한다.The first step is to mix the chemicals of the second step and the third step to make silver antibacterial agent to quantify 1,000ml.

실시예 2Example 2

·기능성양말 제조방법Functional Socks Manufacturing Method

제1공정1st process

양말 2켤레를 준비한다.Get two pairs of socks.

제2공정2nd process

실시예 1의 제6공정의 은 항균제용액에 실시예 2의 제1공정의 양말을 침지시켜 탈수한 양말을 실시예 1의 제5공정의 알카리 용액에 상기 양말을 침지시켜 세척건조하여 본 발명의 기능성 양말을 제조한다.The socks dehydrated by immersing the socks of the first step of Example 2 in the silver antimicrobial solution of the sixth step of Example 1 are washed and dried by dipping the socks in the alkaline solution of the fifth step of Example 1 Manufacture functional socks.

본 발명의 기능성 양말은 항균력이 우수하면서 옥과 세라믹황토의 기능은 물론 탈취효과가 있어 사용할 경우 무좀 냄세 세균의 번식을 억제시키는 효과가 있는 항균된 양말임.Functional socks of the present invention is an antibacterial sock that has the effect of inhibiting the growth of athlete's foot odor bacteria when used as well as the deodorizing effect of jade and ceramic ocher as well as excellent antibacterial activity.

Claims (1)

은 용액에 염화주석, 히드록신, 염산, 구연산소오다를 합성시켜 은 항균제를 만들고 또한 옥, 세라믹, 황토, 세라믹지장수를 만들어 상기 은염 용액과 합성한 은용액을 양말 침지시켜 은을 항균시키고 또한 알카리형 인조제오라이트를 만들어 물에 용해하여 ph10의 인조제오라이트 용액에 상기 은에 침지된 양말을 침지시켜 은을 이온화시켜 기능성 양말 제조Tin chloride, hydroxyxine, hydrochloric acid, and sodium citrate are synthesized in silver solution to make silver antibacterial agent. Also, jade, ceramic, ocher, and ceramic longevity make silver antimicrobial agent by soaking the silver salt solution and synthesized silver solution. Produced functional zeolite by dissolving in water and immersing the soak immersed in silver in the artificial zeolite solution of ph10 to ionize the silver
KR1020010087641A 2001-12-20 2001-12-20 The manufacture metal to shide socks KR20030052226A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030062601A (en) * 2002-01-17 2003-07-28 최명부 The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver
KR200446960Y1 (en) * 2009-04-29 2009-12-11 이상근 Heating structure provided with heating silver plate
KR20230011169A (en) * 2021-07-13 2023-01-20 충북대학교 산학협력단 Shoe type socks for barefoot walking

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04300302A (en) * 1991-03-22 1992-10-23 Toray Ind Inc Antimicrobial deodorant stocking
KR19980025210U (en) * 1998-05-11 1998-07-25 김찬웅 Health underwear (unisex underwear and socks such as underwear, running, underwear, bra, lingerie)
KR20000054491A (en) * 2000-06-05 2000-09-05 김관배 A antibiotic skilled have a socks
KR20010084918A (en) * 2001-04-11 2001-09-07 권영길 Method for manufacturing deodorizing socks

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04300302A (en) * 1991-03-22 1992-10-23 Toray Ind Inc Antimicrobial deodorant stocking
KR19980025210U (en) * 1998-05-11 1998-07-25 김찬웅 Health underwear (unisex underwear and socks such as underwear, running, underwear, bra, lingerie)
KR20000054491A (en) * 2000-06-05 2000-09-05 김관배 A antibiotic skilled have a socks
KR20010084918A (en) * 2001-04-11 2001-09-07 권영길 Method for manufacturing deodorizing socks

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030062601A (en) * 2002-01-17 2003-07-28 최명부 The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver
KR200446960Y1 (en) * 2009-04-29 2009-12-11 이상근 Heating structure provided with heating silver plate
KR20230011169A (en) * 2021-07-13 2023-01-20 충북대학교 산학협력단 Shoe type socks for barefoot walking

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