KR20020062535A - Manufacture Method of Silver Coating Cloths - Google Patents

Manufacture Method of Silver Coating Cloths Download PDF

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Publication number
KR20020062535A
KR20020062535A KR1020010003655A KR20010003655A KR20020062535A KR 20020062535 A KR20020062535 A KR 20020062535A KR 1020010003655 A KR1020010003655 A KR 1020010003655A KR 20010003655 A KR20010003655 A KR 20010003655A KR 20020062535 A KR20020062535 A KR 20020062535A
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South Korea
Prior art keywords
silver
deposited
silver coating
aluminum
weight
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KR1020010003655A
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Korean (ko)
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KR100403331B1 (en
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정태은
김철
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정태은
김철
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/02Underwear
    • D10B2501/021Hosiery; Panti-hose
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2503/00Domestic or personal
    • D10B2503/06Bed linen

Abstract

PURPOSE: Provided is a manufacturing method of silver coating clothes which is characterized by removing reproductive ability of a virus by electrical load of silver ion(Ag+), removing harmful bacteria, having antibiosis and deodorizing ability on a body and being useful for pants, brassieres and socks. CONSTITUTION: The silver coating clothes is obtained by: using sulfone fatty acid amide as pre-treating washing agent to increase softness and adhesive property of silver on textile; and using metal alloyed with 90.2-92.5wt.% of silver and 7.5-9.8wt.% of aluminum as vacuum metalizing agent to give corrosion resistance.

Description

은(銀:Ag)피복 의류의 제조방법{Manufacture Method of Silver Coating Cloths}Manufacture Method of Silver Coating Cloths

본 발명은 금속 은(銀:Ag)을 원사(原絲) 및 직물(Textiles)에 진공 증착한 것을 의류로 사용하는 방법에 관한 것으로 특히 팬티(Pants)또는 여성용 브레지어(Brassieres), 남녀 양말(Socks)등에 이용 제조함으로서 그 은(銀)의 특성인 살균성, 내 항균성과 세포 속의 바이러스, 박테리아와 같은 곰팡이균류들이 산소대사를 할 때 필요한 효소의 기능을 정지시키는 촉매역할을 하는 것으로 알려져 있다.BACKGROUND OF THE INVENTION 1. Field of the Invention [0001] The present invention relates to a method of using vacuum deposition of metallic silver on yarns and textiles as garments, in particular panties or women's brassieres, men's and women's socks. It is known that it is used as a catalyst to stop the function of enzymes required for oxygen metabolism by fungi such as bactericidal, antimicrobial resistance and virus in cells and bacteria.

본 발명은 이러한 점을 감안하여 새로운 코팅(Coating)방식을 발명하여 은(銀)성분의 탈락을 방지하고 은(銀)성분의 표면부착 상태를 누구나 육안으로 확인할 수 있도록 휘황찬란한 은색 광택 의류를 제공하는데 있다.The present invention invented a new coating (Coating) in view of this point to prevent the fall of the silver component and provide a brilliant silver glossy clothing so that anyone can visually check the surface adhesion state of the silver component It is.

종래 기술은 기지의 방법인 은(銀)을 전기분해한 물로 의류에 흡수시켜 건조한 것으로 은(銀)의 성분이 미미할 뿐 아니라 세탁과 동시에 전량 탈락하여 아무런 효과도 전무한 실정이었다. 또한 그 탈락을 방지하기 위한 수단으로 접착제인 초산비닐 또는 아크릴 접착제류로 코팅하여 탈락을 방지하는 방법 등이 이용되어 왔으나 그것은 은(銀)성분 위에 덮어버리는 결과이기 때문에 아무런 가치가 없는 방법이며 그 은(銀)의 효과를 발휘하기에는 턱없이 부족한 설정이었다.In the prior art, silver, which is a known method, is absorbed into clothes by electrolyzing water and dried. Not only the components of silver are insignificant, but also all of them fall off at the same time as washing. Also, as a means of preventing the dropping, coating with vinyl acetate or an acrylic adhesive, which is an adhesive, has been used to prevent the dropping, but it has no value because it is the result of covering it on the silver component. (銀) effect was not good enough to show.

본 발명의 또 다른 목적은 동의보감에서 은(銀)은 여자의 냉을 다스린다는 기록이 있으며 본초강목에는 은(銀)을 지니면 오장이 편안하고 심신이 안정되며 명(命)을 길게 한다는 기록도 있다.Another object of the present invention has a record that the silver (보) reigns in women's cold in the sense of agreement, and the herbaceous wood has a record (5) is comfortable to the five intestines, stable mind and body, and long life (도) have.

그것 말고도 항공기 기내 정수시스템 뿐만 아니라 NASA 우주선의 식수도 은(銀)필터 정수기를 사용한 것 모두가 은(銀)이 인체에 유해한 잡균을 살균하는 은(銀)의 놀라운 작용이 있어서이며 의학적으로 은(銀)솜, 은붕대를 사용함은 이미 과학적으로 은(銀)의 효험을 입증한 것이다. 또 미국 F·D·A는 콜로이드 실버(Colloidal Silver)의 항생제로서의 판매를 인정하고 있는 실정이다. 본 발명은 팬티(Pants)의 국부에다 은(銀)코팅 직물로 제조함으로서 여성의 냉을 예방하고 잡균번식을 억제하며 불쾌한 냄새를 제거할 수 있다. 남성용으로는 살균, 방취외에도 남성의 기(氣)를 돋구어 주는 쾌적한 국부 분위기를 형성하는데 그 목적이 있다.Apart from that, not only the aircraft's in-flight water system but also the NASA spacecraft's drinking water use silver filter water purifiers, all of which have the amazing effect of silver killing germs that are harmful to the human body. 솜) The use of cotton and silver bandage has already scientifically proved the efficacy of silver. In addition, the US F, D, and A recognize the sale of colloidal silver as an antibiotic. The present invention is made of silver coated fabrics in the parts of the pants (Pants) to prevent the cold of women, to suppress the breeding of bacteria and to remove the unpleasant odor. In addition to sterilization and deodorization for men, the purpose is to create a pleasant local atmosphere that enhances the spirit of men.

본 발명의 또 다른 목적은 지금까지 은(銀)물로 처리된 직물을 이용하여 팬티등을 제조코자 한 바 있으나 은(銀)물의 은(銀)함량이 극히 미미한 몇 ppm에 그칠 수밖에 없으며 은(銀)은 산화하기 쉬운 물질이라서 밝은 색의 직물에는 흑갈색으로 변하여 외관상 상품가치가 전무할 뿐 아니라 효용가치도 기대할 수 없었다.Another object of the present invention has been to produce panties and the like using a fabric treated with silver water, but the silver content of silver water is limited to only a few ppm. ) Is a material that is easy to oxidize, so it turns to blackish brown on brightly colored fabrics.

본 발명이 개선코자 하는 것은 은(銀)광택을 발현하고 그 금속이 산화되지 아니하며 은(銀)피복된 직물이 오랫동안 변색되지 않고 은(銀)이 탈락되지 않는 제품을 제공하는데 있다.An object of the present invention is to provide a product in which silver gloss is expressed, the metal is not oxidized, and the silver-coated fabric does not discolor for a long time and silver does not fall off.

이를 위하여, 본 발명에 있어서 원사(原絲)라 함은 면섬유, 포리에스텔섬유, 또는 합사를 말하며 이것으로서 직조된 직물을 피증착물로 증착전처리 단계와 증착단계로 구분되어 있다.To this end, in the present invention, yarn refers to cotton fiber, polyester fiber, or plywood, and the woven fabric is divided into a pre-deposition step and a deposition step as a deposit.

피증착물은 완전히 건조되어야하며 어떠한 유해가스나 수분이 진공 Chamber를 오염시켜서는 안 된다.The deposits must be completely dry and no harmful gases or moisture can contaminate the vacuum chamber.

또한 Chamber내의 진공도에 대하여 다른 피증착물과는 달리 원사 또는 직물에다 금속 광택의 표면을 얻고자 하려면 진공도가 10-5mmHG ∼ 10-7mmHG의 고진동도가 필요로 하며 특히 Chamber내 기류를 반사경이나 전자제품을 피복할 때 종전에 흔히 사용하던 수소 분위기 대신 반드시 소량의 알곤기류중에 열을 가하여 은(銀) 합금을 용해 증발토록 해야만 하는 것이다.In addition, unlike other deposits, to obtain the surface of metallic luster on yarn or fabric, the degree of vacuum in the chamber requires a high vibration of 10 -5 mmHG to 10 -7 mmHG. When coating the product, it is necessary to apply heat in a small amount of argon to dissolve and evaporate the silver alloy instead of the hydrogen atmosphere commonly used in the past.

본 발명에 있어서 은(銀)에다 알미늄을 합금하는 중요한 이유는 은(銀) 단독으로 증착 가공하였을 경우 은(銀)은 내식성이 없는 금속으로 쉽게 흑갈색으로 변색하며 상품가치를 기대할 수 없다.In the present invention, an important reason for alloying aluminum with silver is that when silver is deposited by silver alone, silver is a metal with no corrosion resistance and is easily discolored to black brown, and product value cannot be expected.

이러한 점을 시정하기 위하여 인체에 유해하지 않는 알미늄을 7.5∼9.8 중량%를 용융합금하여 그 세선을 전열 Heater선에 걸어서 증발케 함으로서 광택성 증착은 물론 내식성이 우수한 표면을 가진 의류를 제조함을 특징으로 하는 제조 방법을 제공한다.In order to correct this problem, 7.5 to 9.8 wt% of aluminum, which is not harmful to the human body, is melted and the fine wire is evaporated by hanging on an electric heater wire to produce a garment having a surface with excellent corrosion resistance and corrosion resistance. It provides a production method.

본 발명은 직물 또는 원사의 전 처리 세탁세제로 Sulfone Fatty Acid Amide를 사용하여 직물섬유에 유연성과 은(銀)의 부착성을 향상시켜주는 효과를 제공한다.The present invention uses Sulfone Fatty Acid Amide as a pretreatment laundry detergent for fabrics or yarns to provide the effect of improving the flexibility and adhesion of silver to fabric fibers.

본 발명은 순도 99.9%의 은(銀) 90.2∼92.5중량%, 순도 99.9%의 알미늄 7.5%∼9.8중량%로 합금된 금속을 진공 증착제로 사용하여 내식성을 부여한 은(銀)증착 의류를 제공하는데 있다.The present invention provides a silver-deposited garment provided with corrosion resistance using a metal alloyed from 90.2 to 92.5% by weight of silver having a purity of 99.9% and 7.5% to 9.8% by weight of aluminum having a purity of 99.9% as a vacuum evaporation agent. have.

본 발명을 실시예에 따라 실시한다.The invention is practiced according to the examples.

본 발명은 은(銀)증착 직물 및 원사의 전처리과정은 다음과 같다.In the present invention, the pretreatment process of silver-deposited fabric and yarn is as follows.

실시예 1Example 1

성 분 비율Percentage

Sulfone Fatty Acid Amide(세제) 0.3 중량%Sulfone Fatty Acid Amide 0.3% by weight

溫 水 45℃ 99.7 중량%Water 45 ℃ 99.7% by weight

이와 같이 계면활성제 0.3중량%의 溫水에다 은(銀)피복에 사용될 직물 또는 원사류를 한시간 정도 담그었다가 청수에 완전히 헹구어 탈수, 완전 건조 후에 사용한다. 이것은 섬유의 유연성을 부가하고 증착 금속의 밀착성을 강하게 하여준다.Thus, the fabric or yarn to be used for silver coating in 0.3% by weight of surfactant is immersed for about an hour, rinsed thoroughly in fresh water, and used after dehydration and complete drying. This adds fiber flexibility and strengthens the adhesion of the deposited metal.

본 발명은 은(銀)알미늄 합금 과정The present invention is a silver aluminum alloy process

실시예 2Example 2

성 분 비율Percentage

은(銀) 90.2∼92.5 중량%Silver 90.2-92.5 wt%

알미늄 7.5∼9.8 중량%Aluminum 7.5-9.8 wt%

이 실시 예에서 증발금속인 은(銀)과 알미늄을 합금 함은 은 단독으로서는 내식성이 없는 고로 쉽게 변색하며 미관상 상품가치가 없으므로 해서 그 은(銀)의 효용성에 지장이 없을 정도의 증착 표면을 얻게 되었다.In this embodiment, the alloying of silver and aluminum, which are evaporated metals, is easily discolored due to the absence of corrosion resistance as silver alone, and thus has no aesthetic value, thereby obtaining a deposition surface that does not interfere with the effectiveness of the silver. It became.

진공 증착 과정Vacuum deposition process

실시예 3Example 3

진공도 10-5mmHG∼10-7mmHGVacuum degree 10 -5 mmHG to 10 -7 mmHG

은 합금사 0.3mmSilver Alloy Yarn 0.3mm

분위기 Algon 기류Atmosphere Algon Airflow

본 박막 진공 증착 성형 방법에 있어서 거울이나 반사경 또는 잡화물과 같은 것과는 전혀 다른 작업 방식이며 또한 고분자 Film에다 연속 식으로 증착하는 방법도 아니다. 직물류는 일 회분을 거치대에 현수하여 밀폐 진공 가열 증착하는 것으로서 증착물에 유해증기가 발생하여도 안되며 진공도가 본 실시 예와 같이 고 진동도 분위기가 형성되어야 하며, 섬유 조직에 증착된 금속은 은(銀)은 피부에 자극을 주지 않도록 미세한 입자 즉 0.05㎛이하로 포집부착되어 있는 상태이다.In this thin film vacuum deposition molding method, it is a completely different working method from that of mirrors, reflectors or sundries, and it is not a method of continuously depositing a polymer film. The textiles are suspended in a stand and sealed vacuum heating, and no harmful vapors are generated in the deposits, and a high vibration atmosphere must be formed in the vacuum as in this embodiment. ) Is a state in which fine particles are collected and attached to 0.05 μm or less so as not to irritate the skin.

이와 같은 본 발명의 은(銀)피복의류 제조방법에 있어서 금속은(Metalic Silver)이 방출하는 은이온(Ag+)의 전기적 부하가 병균의 생식기능을 제거하고 박테이라 곰팡이 등에 산소대사에 필요한 효소기능을 중지시키는 작용을 한다.In the method of manufacturing silver coated clothing of the present invention, the electrical load of silver ions (Ag +) released by metal silver removes germ function of bacteria and enzyme function required for oxygen metabolism such as bacterium fungus. It acts to stop.

이러한 물질을 이용한 의류를 특히 팬티, 브레지어, 양말 등에 적용함으로서 인체에 유해 잡균을 박멸하고 항균과 탈취 작용은 물론 은이온(Ag+)방출에 의한 기(氣)의 활성화와 감성에 쾌적도를 상승시켜 원활한 생활에 활력을 제공하는데 있다.By applying clothing using such materials, especially panties, bras, socks, etc., it eliminates harmful germs to the human body, increases anti-bacterial and deodorizing effects, and improves the comfort and sensitivity of the group by releasing silver ions (Ag +). It is to provide vitality to a smooth life.

Claims (3)

본 발명의 은(銀)증착 직물 및 원사의 전처리 과정에서 사용하는 Sulfone Fatty Acid Amide 0.3중량%를 이용한 은금속 부착력 강화제 역할 및 유연제 조성물.A silver metal adhesion enhancing agent and softener composition using 0.3 wt% of Sulfone Fatty Acid Amide used in the pretreatment process of silver-deposited fabric and yarn of the present invention. 은(銀)90.2∼92.5중량%와 알미늄 7.5~9.8중량%로 합금된 내식성, 내광택성을 발휘하는 진공증착 은(銀)의류의 증발원료의 합금 제조방법Method for producing alloy of evaporation raw material of vacuum evaporation silver garment which exhibits corrosion resistance and gloss resistance alloyed with 90.2 to 92.5% by weight of silver and 7.5 to 9.8% by weight of aluminum 은(銀)증착 섬유 또는 원사로 제조된 의복류, 그리고 모자, 목도리, 브라우스, 콜셋트, 베개, 이불, 방석 등을 은(銀)증착 직물류로 제조된 제품.Apparel made of silver-deposited fibers or yarns, and products made of silver-deposited fabrics of hats, shawls, blouse, corsets, pillows, duvets, cushions, and the like.
KR10-2001-0003655A 2001-01-22 2001-01-22 Manufacture Method of Silver Coating Cloths KR100403331B1 (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030062601A (en) * 2002-01-17 2003-07-28 최명부 The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver
KR100723460B1 (en) * 2005-07-05 2007-05-31 손만호 A manufacturing method of silver nano coating hypodermis for car interior

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20030062601A (en) * 2002-01-17 2003-07-28 최명부 The Dyeing of Antiviotic Socks Using Zinc Oxice and Silver
KR100723460B1 (en) * 2005-07-05 2007-05-31 손만호 A manufacturing method of silver nano coating hypodermis for car interior

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