KR20030042320A - Extraction method of persimmon juice for natural dyeing and automatic dyeing system thereof - Google Patents
Extraction method of persimmon juice for natural dyeing and automatic dyeing system thereof Download PDFInfo
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- KR20030042320A KR20030042320A KR1020010073053A KR20010073053A KR20030042320A KR 20030042320 A KR20030042320 A KR 20030042320A KR 1020010073053 A KR1020010073053 A KR 1020010073053A KR 20010073053 A KR20010073053 A KR 20010073053A KR 20030042320 A KR20030042320 A KR 20030042320A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
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Abstract
Description
본 발명은 감잎과 감열매를 주원료로 한 천연염색제 및 천연염색 자동화시스템에 관한 것으로서, 보다 상세하게는 감잎과 열매로부터 추출한 천연색소를 일단의 후처리 공정을 거쳐 천연염색의 변색 및 탈색을 방지하고 색상의 다양화와 대량생산을 위한 천연염색의 자동화시스템 및 이로인한 고가의 천연염색제의 염가대량생산에 관한 것이다.The present invention relates to a natural dyeing agent and a natural dyeing automation system mainly composed of persimmon leaves and persimmon, and more particularly, to prevent discoloration and discoloration of natural dyeing through a series of post-treatment processes of natural pigments extracted from persimmon leaves and fruits. The present invention relates to an automated system of natural dyeing for color diversification and mass production, and thus to a cheap mass production of expensive natural dyes.
일반적으로, 감(Diospyros Kaki)은 덟은맛과 단맛을 내는 낙엽교목(落葉喬木)으로 열대, 아열대 및 온대 등 세계 어느 곳이든 분포되어 있고, 식용으로 사용되는 단감과 덟은감으로 분류된다.Generally, persimmon (Diospyros Kaki) is a deciduous arborescent tree with eight tastes and sweetness, and is distributed anywhere in the world such as tropical, subtropical and temperate, and classified into sweet persimmon and eight persimmon used for food.
감은 풋감일 때 몹시 떫은데 이것을 짓찧어 짜낸 즙을 감물이라 하여 방부, 방습, 수렴 등의 효과가 있어 화상이나 동상에 바르기도 했다. 감물을 종이에 칠하여 부채를 만드는 종이로 사용하기도 하였으며 감열매는 가죽의 무두질이나 지방에 따라서는 천연의 염색제로서 이용되어 왔다.Persimmons are very green when they are green, but the juice squeezed out is called persimmon, which is effective for antiseptic, moisture-proof, and convergence. Persimmons were painted on paper and used as fan-making papers. Persimmons have been used as natural dyes, depending on the tanning and fat of leather.
또한, 감은 7, 8월에 풋감을 따서 으깨어 즙을 내며, 이 즙은 물을 혼합하지 않고 원액 그대로 보관하면서 염액으로 이용하며, 즉시 사용할 경우에는 물을 혼합하기도 하였다.In addition, persimmons were crushed to extract juice in July and August, and this juice was used as a salt solution without storing water and used as a salt solution, and when used immediately, water was mixed.
이렇게 감즙을 흡수시킨 뒤 찌꺼기를 떨어내고 펴서 직사광선 아래에서 건조시켜 발색시키는데 이때 물을 축여주거나 감물을 축여가며 직사광선 아래서만 10여회를 반복하여 건조함으로써 진한 갈색으로 염색이 이뤄지고 이 염색물은 빳빳한풀먹인 상태처럼 보이고 염색 직후에는 매우 빳빳하지만 입고 지냄에 따라 부드러워지고 점차 더욱 갈색으로 발색이 이루어지게 된다.After absorbing the juice, the dregs are dropped and spreaded and dried under direct sunlight to develop the color. At this time, the water is reduced or the persimmon is reduced and dried over 10 times under direct sunlight, and then dyed to dark brown. It appears to be fed and is very dry right after dyeing, but as you wear it, it becomes softer and becomes more brown.
그러나, 종래의 감잎과 열매를 이용한 천연염색제 및 염색방법은 수작업과 자연채광 건조에 전적으로 의존하고 있어 색소의 다양성이 결여되어 있고, 색소의 불안정성, 낮은 색소율, 염색제 추출과 염색공정의 비합리성, 낮은 생산성, 탈색 및 변색도 등의 높은 결함을 지니고 있는 문제점이 있다.However, conventional dyeing and dyeing methods using persimmon leaves and fruits are completely dependent on manual and natural light drying, resulting in a lack of pigment variety, instability of pigments, low pigmentation rate, irrationality of dyeing and dyeing processes, and low There is a problem with high defects such as productivity, discoloration and discoloration.
또한, 일반적인 감염색은 감염액에 침지한 다음 짜고 일광하에서 7 ∼ 10일간 건조하는 동안에 3 ∼ 5 회 반복염색을 통해서 원하는 색상으로 산화발색시킨다. 이 과정에 감즙액내에 탄닌의 함유량이나 부착된 감염액의 량 및 건조일수에 따라 감염색면의 농담이 결정된다. 그러나, 이러한 발색의 조건이 천연염색에서 나타나는 최대의 단점인 색상재현성을 거의 갖지 못하게 되는 문제가 있다.In addition, the general infectious color is immersed in the infectious solution, squeezed and oxidized to the desired color through 3 to 5 repeated dyeings during 7 to 10 days of drying under sunlight. In this process, the color of the infected color is determined according to the amount of tannin in the juice, the amount of the infected solution attached and the number of days of drying. However, there is a problem that the condition of the color development has almost no color reproducibility which is the biggest disadvantage of natural dyeing.
따라서, 상기한 문제점을 해결하기 위하여 본 발명은 전통 고유 염색 기술을 확립하기 위하여 셀루로즈계 및 단백질계 섬유에 대한 천연 염료의 농색염색 조건에서 견뢰도 향상을 제공하고자 하는데 그 목적이 있다.Accordingly, an object of the present invention is to provide a fastness in fastening dyeing conditions of natural dyes for cellulose-based and protein-based fibers in order to establish traditional dyeing techniques.
상기한 목적을 달성하기 위한 본 발명은 감잎과 열매로부터 많은 양의 감즙 염색제 추출과 효과적인 감즙추출을 위해 대용량의 회전식 믹서탱크에 선별된 감잎 또는 열매를 넣고 회전시킨 후 감 열매의 경우에는 매우 작은입자로 분쇄된 것을 압착탱크에 넣어 감즙액을 추출하고, 감잎의 경우에는 섬유질분해 유기제가 들어있는 감잎색소 추출탱크에서 일정시간 실온에서 추출하여 불순물 여과필터가 내장된 색소여과 농축탱크를 거쳐 추출된 감잎 농축색소를 원액 또는 일정의 물을 혼합한 감액에 색소 변화를 방지하는 색소 안정제를 첨가하여 감액의 농도와 색소안정제 첨가비율에 따라 색조의 농도가 다양하게 재현할 수 있는 성질을 갖추게 한 다음, 물 파도를 일으키는 염색탱크에 감액 염색원료와 면직물을 담궈놓고 물 파도를 일으키면 손으로 주무르는 것과 같은 효과가 있어 염색 색소가 섬유의 조직까지 침투할 수 있게 하고 염색된 면직물을 UV램프 건조암실에서 염색제의 농도에 맞게 조사(照査) 건조한 다음, 색소 고착액이 들어있는 탱크에 침전한 후 세척하여 최종 건조한 것을 특징으로 하는 시스템을 제공함에 의해 달성된다.The present invention for achieving the above object is very small particles in the case of persimmon fruit after rotating the persimmon leaf or fruit selected in a large-volume rotary mixer tank for extracting a large amount of juice dyes and effective juice extraction from persimmon leaf and fruit Persimmon leaf was extracted from the persimmon leaf by extracting the juice from the persimmon leaf in a persimmon leaf pigment extraction tank containing fibrinolytic organic agent at room temperature for a certain period of time. A pigment stabilizer that prevents color change is added to the concentrated solution of the concentrated pigment in the stock solution or a certain amount of water so that the density of the color tone can be variously reproduced according to the concentration of the reduced solution and the ratio of the color stabilizer. Dip the dye-reducing raw material and cotton fabric into the dyeing tank that causes the waves, It has the same effect as kneading, so that the dye dye can penetrate into the tissue of the fiber, and the dyed cotton fabric is irradiated in the UV lamp drying dark to the concentration of the dye, and then precipitated in the tank containing the dye fixing liquid. By providing a system which is characterized by washing and final drying.
도 1 은 본 발명에 따른 자동화공정 시스템1 is an automated process system according to the present invention
<도면의 주요부분에 대한 부호의 설명><Description of the symbols for the main parts of the drawings>
(1) : 저장탱크 (2) : 회전분쇄 믹서탱크(1): storage tank (2): rotary grinding mixer tank
(3) : 프레스 압착탱크 (4) : 감잎색소 추출탱크(3): Press Crimp Tank (4): Persimmon Leaf Extraction Tank
(5) : 색소여과 농축탱크 (6) : 원액/혼합탱크(5): Pigmentation concentration tank (6): Stock solution / mixed tank
(7) : 색소 안정제 (8) : 물파도 염색탱크(7): color stabilizer (8): water wave dyeing tank
(9) : UV램프 건조암실 (10) : 염색고착탱크(9): UV lamp drying dark room (10): Dyeing fixing tank
(11) : 색소 고착제 (12) : 세척탱크(11): pigment fixing agent (12): washing tank
(13) : 염색직물건조실 (14) : 원단 주름방지처리(13): Dyed fabric drying room (14): Fabric anti wrinkle treatment
(15) : 원단 실크가공처리 (16) : 컷팅기(15): Fabric silk processing (16): Cutting machine
(17) : 롤러 (18) : 컴퓨터 중앙제어장치(17): roller 18: computer central control unit
이하, 첨부된 도면을 참조하여 본 발명의 일실시예를 상세히 설명하면 다음과 같다.Hereinafter, an embodiment of the present invention will be described in detail with reference to the accompanying drawings.
도 1 은 본 발명에 따른 자동화공정 시스템을 도시한 것이다.Figure 1 shows an automated process system according to the present invention.
본 발명의 감즙액 추출방법은 감잎과 감열매로부터 많은 양의 감즙 염색제 추출과 효과적인 감즙추출을 위해 저장탱크(1)에 저장되어 있는 감잎 및 감열매를 대용량의 회전식 믹서탱크(2)에 선별된 감잎 또는 감열매를 넣고 회전시키게 되는데 감열매의 경우에는 매우 작은입자로 분쇄된 것을 프레스 압착탱크(3)에 넣어 감즙액을 추출하고, 감잎의 경우에는 섬유질분해 유기제가 들어있는 감잎색소 추출탱크(4)에서 일정시간 실온에서 추출하여 불순물 여과필터(도시하지 않음)가 내장된색소여과 농축탱크(5)를 거쳐 추출되게 된다.The method of extracting the juice of the present invention selects the persimmon leaf and the heat medium stored in the storage tank (1) for the extraction of a large amount of juice dye and persimmon extract from the persimmon leaf and the heat medium in a large capacity rotary mixer tank (2) The persimmon leaf or the heat-sensitive fruit is inserted and rotated. In the case of the heat-sensitive fruit, the crushed liquid is put into a press-compression tank (3) to extract the juice, and in the case of the persimmon leaf, the persimmon leaf pigment extraction tank containing the fibrinolytic organic agent ( 4) is extracted at room temperature for a certain time and is extracted through a pigment filtration concentration tank (5) with an impurity filtration filter (not shown).
또한, 상기와 같이 감즙액을 추출하여 원단을 가공하기 위한 시스템은 불순물 여과필터를 거쳐 추출된 감잎 농축색소를 추출된 감즙 원액 또는 일정의 물을 혼합한 원액/혼합탱크(6)에서 감즙액의 농도에 따라 감즙 색소의 주성분인 탄닌 고유의 색조가 자연 변색, 탈색되는 것을 방지하기 위한 일정의 색소안정제(7)를 첨가하고,In addition, the system for processing the fabric by extracting the juice solution as described above is the juice of the juice solution in the stock solution / mixed tank (6) mixed with the juice extract or concentrated water extracted persimmon leaf concentrated pigment extracted through the impurity filtration filter According to the density | concentration, the pigment | dye stabilizer 7 which is fixed in order to prevent natural discoloration and discoloration of the natural color tone of tannin which is a main component of a juicy pigment | dye is added,
감즙액의 농도와 색소안정제(7)의 첨가 비율에 따라 탄닌 고유의 색조가 다양하게 재현할 수 있는 성질을 갖게하며,Depending on the concentration of the juice and the ratio of the addition of the color stabilizer (7) has a characteristic that can reproduce a variety of tannins inherent,
염착용 물파도 탱크(8)에 넣고 감즙 염색용 면직물을 물파도 탱크(8)에 일정시간 침전하여 손으로 주무르는 것과 같은 효과가 있는 탱크내의 물파도 운동에 의해 면직물의 섬유조직 깊은 곳까지 색소가 침투하게 되고,The pigments are placed deep into the fiber tissue by the water wave movement in the tank, which is put in the dyeing water wave tank 8 and settles the juicy dyeing cotton fabric in the water wave tank 8 for a predetermined time and kneading by hand. Infiltrate,
건조암실(9)에서 일정의 광도(W:와트)를 갖는 UV램프를 염색제의 농도에 따라 일정시간 조사, 건조하여 발색하게 한 다음,In the dry dark room (9) irradiated with UV light having a constant brightness (W: watts) for a predetermined time according to the concentration of the dyeing agent, allowed to dry and color,
이를 색소고착제(11)가 일정비율 혼합된 염색고착탱크(10)에 면직물을 일정시간과 온도에 침전한 후 세척탱크(12)에서 세척하며, 일정의 온도를 유지하는 일반 건조실(13)에서 건조한 후 주름방지(링클프리)처리(14)하고 최종적으로 실크처리(15)하게 되는 것이다.This dyeing agent (11) in a dyeing fixing tank (10) mixed with a certain ratio of precipitated cotton fabric at a predetermined time and temperature and then washed in the washing tank (12), and dried in a general drying room (13) maintaining a constant temperature After the anti-wrinkle (wrinkle-free) treatment (14) and finally the silk treatment (15).
또한, 최종적으로 실크처리되어진 원단을 자동 야드컷팅기(16)에서 절단하고 절단된 원단은 롤러(17)로 감게 되는 것이다.In addition, the final silk-treated fabric is cut by the automatic yard cutting machine 16 and the cut fabric is wound with a roller 17.
상기의 모든 시스템은 컴퓨터 중앙제어장치(18)에서 자동으로 제어하고 처리하게 되는 것이다.All of the above systems are to be automatically controlled and processed by the computer central controller 18.
상기에서와 같이 천연염색 농색화 및 견뢰도 증진의 기초적 연구의 일환으로 대두되어지고 천연염재로는 다색성 천연색소인 감 및 감잎으로부터 재현성있는 방법으로 색소를 추출하여 면, 견, 모직물에 일반적인 염색조건(염색온도, 시간, ph 등)과 염재에 따른 매염제의 종류, 매염방법, 염색조제 등을 변화시켜 염색한 것이다.As mentioned above, as a part of the basic research of natural dyeing thickening and color fastness, the natural dyeing material is extracted from persimmon and persimmon leaf, which is a multicolored natural dye, in a reproducible way. It is dyed by changing the type of mordant, mordant method, dyeing aid, etc. according to temperature, time, ph, etc.) and dyeing materials.
또한, 단시간의 발색법, 매염이나 복합염색 등을 통한 한정된 색상의 다양화를 모색하면서 후처리제 및 피염물인 섬유를 개질하여 각종의 염색 견뢰도 향상과 함께 염료로서 풋감 뿐 아니라 감잎에 의한 농색염색의 조건에서 내견뢰성 염색법을 수행하게 되는 것이다.In addition, while seeking to diversify the limited color through a short time of color development, mordant or complex dyeing, the post-treatment agent and the dyeing fiber are modified to improve the color fastness of various dyes, as well as the dyeing condition as well as the deep dyeing condition by persimmon leaves. Tolerance staining will be performed in.
본 발명에서는 감열매에 의한 염색에서 재현성있는 간편화된 염색법을 제시하기 위하여 염액에 침지한 다음 100% 픽업율로 패딩한 염색면을 건조 발색하는 과정에 일광건조에 따른 발색의 정도와 단파장으로서 큰 에너지를 지닌 UV램프하에서 단시간 조사하여 건조시켰다.In the present invention, in order to suggest a reproducible simplified dyeing method by dyeing with a heat-sensitive medium, a large energy as a degree of color development and short wavelength in the process of dry coloration of the dyed cotton padded at 100% pick-up rate after immersion in salt solution Irradiated under a UV lamp with a short time to dry.
따라서, 건조방법에 따라서는 일광건조의 경우 K/S값이 UV 건조 시료보다 낮고 불균염이 큰 반면 UV램프하에서의 발색이 감염색의 균염이나 발색에 효과적인 것이다.Therefore, depending on the drying method, the K / S value is lower than that of the UV dry sample and the disproportionate is larger than that of the UV dry sample, whereas the color under UV lamp is effective for infectious color or color development.
본 발명은 상술한 특정의 바람직한 실시예에 한정되지 아니하며, 청구범위에서 청구하는 본 발명의 요지를 벗어남이 없이 당해 발명이 속하는 기술분야에서 통상의 지식을 가진 자라면 누구든지 다양한 변형실시가 가능한 것은 물론이고, 그와같은 변경은 청구범위 기재의 범위내에 있게 된다.The present invention is not limited to the above-described specific preferred embodiments, and various modifications can be made by any person having ordinary skill in the art without departing from the gist of the present invention claimed in the claims. Of course, such changes will fall within the scope of the claims.
따라서, 본 발명은 감열매와 감잎으로부터 감즙 염색제를 추출하여 자동화 공정을 통해 회전분쇄 및 압착, 추출하고 염색원료와 면직물을 물파도 염색탱크에 담궈 물파도를 일으켜 염색한 상태에서 UV램프 건조암실에서 조사한 후 색소 고착제가 첨가된 염색고착탱크에서 침전한 다음 세척하여 건조함으로써 전통 염색공정의 간편화 및 정량화에 의한 기성복 등의 소재에 응용성을 확대할 수 있으며 기존 천연염색 과정에 농색염색을 위해 다량의 색재를 사용하여야 하는 단점을 보완하여 생산 경제성을 향상시킬 수 있고 또한 다른 천연염색과의 복합염색으로 다양한 색상을 제시할 수 효과가 있다.Therefore, the present invention extracts the succulent dye from the heat persimmon and persimmon leaves by rotary milling, compression, extraction through an automated process and the dyeing raw materials and cotton fabrics in the water wave dyeing tank to cause water waves to dye in a UV lamp dry dark room After investigation, it is precipitated in dye-fixing tank with dye fixing agent, washed and dried to extend the applicability to ready-to-wear materials such as simplification and quantification of traditional dyeing process. Compensation for the disadvantage of having to use the colorant can improve the production economics, and also has the effect of presenting a variety of colors by complex dyeing with other natural dyeing.
그리고, 전통 감염색물을 레저복 등의 소재로 활용하여 다양한 디자인은 제시함으로서 관광상품화 및 고부가가치화, 세계 패션 시장에 진출할 수 있는 영역을 확대할 수 있으며 레저복 등에 어울리는 장신구류의 상품화를 꾀할 수 있는 효과가 있다.By using traditional infection colors as materials for leisure clothes, various designs can be presented to expand the scope of tourism commercialization, high value-added and entry into the world fashion market, and commercialization of jewelry suitable for leisure clothes. It has an effect.
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KR20040006080A (en) * | 2002-07-09 | 2004-01-24 | 박원진 | Manufacture method of a natural dye |
KR100479126B1 (en) * | 2002-03-13 | 2005-03-28 | 주식회사 우성염직 | Manufacturing Method of The Fabric Dyed With Powdered Persimmon Juice And Artifical Light Source For Development |
KR100932427B1 (en) * | 2009-07-24 | 2009-12-17 | 재단법인나주시천연염색문화재단 | Equipment for automatic manufacturing of fermented liquor of persimmon tannin |
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CN103013164A (en) * | 2012-12-14 | 2013-04-03 | 桂林普兰德生物科技有限公司 | Method for extracting natural pigment from persimmon peels |
CN104693834A (en) * | 2015-03-31 | 2015-06-10 | 桂林得坤生物科技股份有限公司 | Method for preparing persimmon fruit pigments |
KR20160006376A (en) | 2014-07-09 | 2016-01-19 | (재)한국섬유기계연구원 | After treatment processing method for improvement dyeability of fabrics dyed with persimmon extract |
KR20160014246A (en) | 2014-07-29 | 2016-02-11 | (재)한국섬유기계연구원 | After treatment processing device for improvement dyeability of fabrics dyed with persimmon extract |
KR102301193B1 (en) * | 2020-07-10 | 2021-09-10 | 주식회사 제우스 | Fabrication of fabric sheet with citrus flavor |
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KR100479126B1 (en) * | 2002-03-13 | 2005-03-28 | 주식회사 우성염직 | Manufacturing Method of The Fabric Dyed With Powdered Persimmon Juice And Artifical Light Source For Development |
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KR100932427B1 (en) * | 2009-07-24 | 2009-12-17 | 재단법인나주시천연염색문화재단 | Equipment for automatic manufacturing of fermented liquor of persimmon tannin |
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KR20160014246A (en) | 2014-07-29 | 2016-02-11 | (재)한국섬유기계연구원 | After treatment processing device for improvement dyeability of fabrics dyed with persimmon extract |
CN104693834A (en) * | 2015-03-31 | 2015-06-10 | 桂林得坤生物科技股份有限公司 | Method for preparing persimmon fruit pigments |
KR102301193B1 (en) * | 2020-07-10 | 2021-09-10 | 주식회사 제우스 | Fabrication of fabric sheet with citrus flavor |
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