KR20030018038A - Method of inoganic Fireproof Paint and Fireproof Bond - Google Patents
Method of inoganic Fireproof Paint and Fireproof Bond Download PDFInfo
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- KR20030018038A KR20030018038A KR1020030008372A KR20030008372A KR20030018038A KR 20030018038 A KR20030018038 A KR 20030018038A KR 1020030008372 A KR1020030008372 A KR 1020030008372A KR 20030008372 A KR20030008372 A KR 20030008372A KR 20030018038 A KR20030018038 A KR 20030018038A
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- South Korea
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- fire
- adhesive
- retardant
- layer
- paint
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- 239000003973 paint Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract 3
- 239000000853 adhesive Substances 0.000 claims abstract description 50
- 230000001070 adhesive effect Effects 0.000 claims abstract description 50
- 239000000463 material Substances 0.000 claims abstract description 43
- 239000003063 flame retardant Substances 0.000 claims abstract description 40
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000002023 wood Substances 0.000 claims abstract description 11
- 239000000123 paper Substances 0.000 claims abstract description 9
- 238000009413 insulation Methods 0.000 claims abstract description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 5
- 239000011120 plywood Substances 0.000 claims abstract description 5
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 5
- 239000002689 soil Substances 0.000 claims abstract description 5
- 239000007864 aqueous solution Substances 0.000 claims abstract description 4
- 239000011230 binding agent Substances 0.000 claims abstract description 4
- 239000004568 cement Substances 0.000 claims abstract description 3
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 239000004575 stone Substances 0.000 claims abstract description 3
- 229910021538 borax Inorganic materials 0.000 claims abstract 2
- 239000004328 sodium tetraborate Substances 0.000 claims abstract 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract 2
- 238000003756 stirring Methods 0.000 claims abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 17
- 239000000049 pigment Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 claims 1
- 239000010959 steel Substances 0.000 claims 1
- 239000010410 layer Substances 0.000 abstract description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 9
- 229910052760 oxygen Inorganic materials 0.000 abstract description 9
- 239000001301 oxygen Substances 0.000 abstract description 9
- 239000000843 powder Substances 0.000 abstract description 9
- 239000012790 adhesive layer Substances 0.000 abstract description 8
- 230000009970 fire resistant effect Effects 0.000 abstract description 7
- 239000011521 glass Substances 0.000 abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 6
- 230000000903 blocking effect Effects 0.000 abstract description 5
- 230000002265 prevention Effects 0.000 abstract description 5
- 239000004327 boric acid Substances 0.000 abstract description 4
- 239000011247 coating layer Substances 0.000 abstract description 4
- 239000004576 sand Substances 0.000 abstract description 4
- 239000007921 spray Substances 0.000 abstract description 4
- 229910010272 inorganic material Inorganic materials 0.000 abstract description 3
- 239000011147 inorganic material Substances 0.000 abstract description 3
- 239000002344 surface layer Substances 0.000 abstract description 3
- XDVOLDOITVSJGL-UHFFFAOYSA-N 3,7-dihydroxy-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound O1B(O)OB2OB(O)OB1O2 XDVOLDOITVSJGL-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000919 ceramic Substances 0.000 abstract description 2
- 230000001934 delay Effects 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 239000002253 acid Substances 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 239000011850 water-based material Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 230000009545 invasion Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 2
- 239000002250 absorbent Substances 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- -1 crushed Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000012796 inorganic flame retardant Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
- C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J9/00—Adhesives characterised by their physical nature or the effects produced, e.g. glue sticks
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Fireproofing Substances (AREA)
Abstract
본 발명은 규산소다를 주제로한 세라믹 바인더에 붕산 혹은 붕사, 색상이 필요시 임의의 색소를 첨가 혼합 교반하여 수용액으로 만들어, 방화페인트의 기능은 가연성 소재인 종이류, 합판류, 목재류 등의 표면에 도포하면 표면층 내부로 흡수되며 잔여물은 표면층 상부에 도막층을 형성하며, 자연 건조하면 미려한 외관과 내산성을 갖으면서 방염 처리가 되는 무기물 수성 방화 페인트가 된다.The present invention is made by mixing and stirring boric acid or borax in the ceramic binder based on sodium silicate, color, if needed, to make an aqueous solution, the function of the fire-retardant paint is on the surface of combustible materials such as paper, plywood, wood When applied, it is absorbed into the surface layer and the residue forms a coating layer on top of the surface layer. When dried naturally, it becomes an inorganic water-based fire-retardant paint which has a beautiful appearance and acid resistance and is flameproofed.
방화 접착제의 기능은 가연성 및 불연성 소재 즉, 종이류, 합판류, 목재류, 석재류, 시멘트 류, 철판류 등의 소재에 방화 접착제를 도포하여 동종간 혹은 이종간 접착시켜 자연건조나 100도씨 이하 저온 건조시키면 완벽한 접착력을 갖는 방화 접착제가 된다.Fire retardant adhesives function by applying fire retardant adhesives to combustible and non-combustible materials, such as paper, plywood, wood, stone, cement, and iron plates, and then bonding them in the same or different types to dry them naturally or at low temperature below 100 degrees Celsius. This results in a fire resistant adhesive with perfect adhesion.
방화접착제로 분쇄된 종이, 목분류, 흙, 모래등 유무기 재료를 방화 접착제로 접착시에는 소정량의 접착제를 소재에 첨가 배합압축 성형하여 자연건조나 100도씨 이하 저온건조하면 견고한 고형체가 된다.When bonding organic and inorganic materials such as paper, wood, soil, and sand crushed with a fireproof adhesive with a fireproof adhesive, a predetermined amount of adhesive is added to the material. do.
본 발명의 무기방화페인트로 형성된 도막층과 방화접착제로 접착된 접착층은 150도씨 정도부터 온도가 상승함에 따라 붕산은 피로붕산(H2B4O7)과 유리상태로 변형하면서 거품상태로 부풀어 오른 단열 방화층을 형성하여 가연성 소재의 인화착화점을 지연시키면서 온도 상승에 따라 착화점이 지나도 산소 공급의 차단으로 발화가 되지 않고 탄화가 됨으로 소방기준에 부합되며,The coating layer formed of the inorganic fireproof paint of the present invention and the adhesive layer bonded with the fire prevention adhesive have a temperature of about 150 ° C. As the temperature rises, boric acid swells in a bubble state while being transformed into pyroboric acid (H 2 B 4 O 7 ) and a glass state. By forming the right insulation fireproof layer, it delays the ignition point of the combustible material and meets the firefighting standards as it does not ignite due to the blocking of oxygen supply even after the ignition point passes by the temperature rise.
방화접착제의 작용은 화재 발생시 접착층이 거품상태로 부풀어 올라 단열 방화층이 형성되고 접착면은 접착시 침적된 층과 유리상태로 고착되 산소를 차단시켜 불꽃 없이 탄화되 화염의 전이를 저지시킨다.The action of the fire retardant adhesive is that when the fire occurs, the adhesive layer swells into a foam state to form a heat insulation fireproof layer, and the adhesive surface is fixed to the deposited layer and the glass state upon bonding, and blocks oxygen to carbonize without flame to prevent the transfer of flame.
방화접착제로 유무기 분말을 접착고형 시킬 경우는 고온에 노출되어도 망상형태로 혼합결합 압축되어 있어서 견고한 형태를 유지한 상태로 탄화됨으로 화염의 전이를 막는다.When the organic-inorganic powder is solidified with a fire-retardant adhesive, it is mixed and compressed into a reticular form even when exposed to high temperature, so that it is carbonized while maintaining a solid form to prevent the transfer of flame.
본 발명의 무기 방화 페인트 겸 방화접착제는 사용방법도 위치나 장소에 구애받지 않고 붓이나 스프레이로 특수기술 없이 간편히 사용할 수 있고 자연 건조되며 수성 제재이며 용재는 물(H2O)이므로 작업 시 화재의 위험이 없고 냄새가 없어 친환경적이며 발색이 필요시 기존 색상페인트의 기능도 동시에 할 수 있는 다기능, 다용도로 이용된다.Inorganic fire-retardant paint and fire-retardant adhesive of the present invention can be used simply and without any special technique by using a brush or spray regardless of the location or location, it is naturally dried, water-based material and the material is water (H 2 O), so It is eco-friendly because there is no risk, no smell, and it is used for multi-functional and versatile, which can also function as existing color paint at the same time.
Description
본 발명의 방화페인트 기능은 가연성 소재로된 건축 내외장재, 가구 및 집기류 등의 노출된 표면에 스프레이나 붓으로 도포하여 자연 건조 시키면 방염처리가 되고 색상이 필요시에는 임의의 색소를 첨가시키면 도색 역할까지 할 수 있다. 화재 발생시 방염처리층은 열침해를 받어 부풀어 올라 단열 방화층을 형성하여 인화 발화접을 지연시키고 접착된 표면층은 가연성 소재에 함침 고착되어 있으므로 산소를 차단하여 가연성 소재가 불꽃 없이 탄화되어 소방기준치를 충분히 만족시킨다. 방화접착제의 기능중 면 접찹 경우는 가연성소재나 비가연성 소재의 동일 종류나 이질 종류 관계없이 접착면에 스프레이나 붓으로 도포하여 접착시켜 자연건조나 시간단축을 요할 시에는 방염, 반응온도 이하인 100도씨 이하 저온으로 건조시키면 완벽한 접착면을 갖고 화재 발생시 열 침해를 받으면 도포된 접착층이 부풀어 올라 단열 방화층을 형성하여 인화발화점을 지연시키고 양 접착면을 접착제와 함침 고착되어 소재에 산소를 차단시켜 불꽃없이 탄화된다.Fire-retardant paint function of the present invention is applied to the exposed surface, such as building interior and exterior materials, furniture, and household appliances made of combustible materials by spraying or brushing it to be dried naturally, it is flame-retardant treatment, if the color is required to add any pigment to the paint role can do. In the event of a fire, the flame-retardant layer undergoes thermal invasion and swells to form an insulating fire-proof layer, delaying ignition ignition, and the bonded surface layer is impregnated with a flammable material. Let's do it. In the case of the function of fire-retardant adhesive, if it is a cotton glue, it is applied to the adhesive surface by spray or brush regardless of the same kind or heterogeneous type of flammable material or non-flammable material. When dried at a low temperature below the seed, it has a perfect adhesive surface, and if it is invaded by heat in case of fire, the applied adhesive layer swells to form a thermal insulation fireproof layer, delays the flash point, and impregnates both adhesive surfaces with an adhesive to block oxygen to the material Without carbonization.
방화접착제의 기능중 가연성 비가연성 분말형의 소재(목재분, 종이분, 흙, 모래등)을 접착 고형화 시킬 경우 소정의 접착제를 임의의 소재와 배합 압축성형하여 자연건조나 100도씨 이하 저온으로 건조시키면 소재의 고유 물성을 유지하면서 견고한 고형체가 이루어진다.In case of flammable non-flammable powder type materials (wood flour, paper powder, soil, sand, etc.) among the functions of the fire retardant adhesive, certain adhesives are mixed with any material and compressed to form natural dry or low temperature below 100 degrees. Drying results in a solid solid that retains the material's inherent properties.
화제 발생시 고온으로 상승하여 인화발화점을 지나도 망상형태로 혼합결합되어 있어 단열방화층으로 되며 산소의 차단으로 고형체를 유지하면서 탄화되어 화염 차단 효과를 얻는다.When the fire is generated, it rises to a high temperature and is mixed in a mesh form even after passing through the flash point, so that it becomes a heat-insulating fireproof layer and is carbonized while maintaining a solid body by blocking oxygen to obtain a flame blocking effect.
상기와 같이 본 발명품은 무기소재로 이루어져 그 자체만으로도 방염 역활을 할 수 있고 용재가 물(H2O) 이므로 화재의 위험이 없고 냄새가 없어 친 환경적이다.As described above, the present invention is made of an inorganic material and can act as a flame retardant by itself, and since the solvent is water (H 2 O), there is no risk of fire and no smell, which is environmentally friendly.
표면도포나 접착작업이 간편하고 방염기능, 접착기능, 도색기능등 다기능을 갖는 장점이 있고 소재 자체가 저가이므로 대중적으로 사용될 수 있는 개발품이다.It is a development product that can be widely used because it has the advantages of simple surface coating and adhesive work, multi-function such as flame retardant function, adhesive function, and painting function.
종래 제품은 많이 개발되어 있으나 제품소재가 대다수 유무기 혼합형이고 용제가 가연성 신너이므로 사용상 화재의 위험이 있고 유해성 냄새가 나기 때문에 비환경적이고 고가이다.Conventional products have been developed a lot, but since most of the product materials are organic-inorganic mixed type and the solvent is a flammable thinner, there is a risk of fire in use and it is non-environmental and expensive because of the harmful smell.
본 발명은 무기물 수성 바인더를 기조로 하고 무기물인 방염제 및 필요시 임의 색소를 혼합교반하여 수용액 상태로 제조되어 물(H2O)로 희석할 수 있고 스프레이나 붓으로 가연성 소재에 도포하고 자연건조하면 소방기준에 적합한 방염기능을 수행할 수 있고 방염접착제의 기능중 면접착의 경우는 가연성 소재나 비가연성 소재의 동일 종류나 이질 종류 관계없이 접착면에 스프레이나 붓으로 도포하여 접착시켜 자연건조나 100도씨 이하 저온으로 건조시키면 완벽한 접착면을 갖고 화재 발생시 열침해를 받으면 도포된 접착층이 부풀어 올라 단열방화층을 형성하고 양접착면을 접착제와 함침 고착되어 소재에 산소를 차단시켜 불꽃 없이 탄화되어 방염작용을 한다.The present invention is based on an inorganic aqueous binder, and mixed with an inorganic flame retardant and optional pigment if necessary, prepared in the form of an aqueous solution can be diluted with water (H 2 O) and applied to a combustible material with a spray or a brush and dried naturally It is possible to perform fire-resistance function that meets the standard of fire-fighting, and in case of surface adhesion among the functions of flame-retardant adhesive, it is applied by spraying or brushing on the adhesive surface irrespective of the same kind or heterogeneous type of flammable material or non-flammable material. If the temperature is lower than the seed, it has a perfect adhesive surface, and if it is thermally invaded in the event of a fire, the applied adhesive layer swells to form a heat insulation fireproof layer, and both adhesive surfaces are impregnated with an adhesive to block oxygen in the material to be carbonized without flame to be flame-retarded. Do it.
방화 접착제의 기능 중 가연성, 비가연성 분말형의 소재(목재분, 종이분, 흙, 모래 등)을 소정의 형태로 접착고형화 시킬 경우 소정의 접착제와 임의의 소재를 배합하여 압축성형하고 건조시키면 견고한 고형체가 형성되며 열 침해시 단열 및 산소 차단 효과가 있어 강도 있는 고형체를 유지하면서 탄화된다.In case of flammable and non-flammable powder material (wood powder, paper powder, soil, sand, etc.) in the form of adhesive, solidified by compression molding and drying by mixing the specific adhesive and any material. Solids are formed, and they have a thermal insulation and oxygen blocking effect during heat invasion and are carbonized while maintaining a solid solid.
도색이 필요시에는 색소를 첨가 사용하면 방염, 발색 기능을 동시에 수행한다.When painting is required, the addition of pigments can be used for flame retardant and color development functions.
상기와 같이 소방기준에 적합하고 사용이 간편하고 안정성이 있고 환경친화적이며 복합기능을 수행한다.As above, it meets the firefighting standards, is simple to use, stable, environmentally friendly, and performs a combination of functions.
도1은 본 발명의 무기방화 페인트 겸 방화접착제 중 방화페인트를 가연성소재의 노출된 표면에 도포된 도막층과 가연성 소재 상층부에 흡수된 흡수층의 단면도1 is a cross-sectional view of an absorbing layer absorbed by a coating layer coated on the exposed surface of a combustible material and an upper portion of the combustible material in the inorganic fire-retardant paint and fire-retardant adhesive of the present invention;
도2는 도1에서 방화페인트 도막층이 열을 받어 부풀어 오른 변형된 방화벽층과 가연성소재 표면에 흡수된 흡수층의 탄화된 부위의 단면도.FIG. 2 is a cross-sectional view of the carbonized portion of the deformed firewall layer and the absorbent layer absorbed on the flammable material surface in FIG.
도3은 본 발명의 무기방화페인트겸 방화 접착제중 방화 접착제로 접착한 단면도.Figure 3 is a cross-sectional view of the inorganic fire-retardant paint and fire-retardant adhesive of the present invention bonded with a fire-retardant adhesive.
도4는 도3의 접착층이 열 침해로 부풀어 올라 변형된 방화벽 층.FIG. 4 is a firewall layer in which the adhesive layer of FIG. 3 is inflated due to heat intrusion. FIG.
도5는 방화 접착제중 분쇄된 유무기 분말 재료를 방화접착제와 배합하여 접착 고형화 시킨 제품의 단면도.5 is a cross-sectional view of a product in which the solidified organic-inorganic powder material in the fire prevention adhesive is combined with the fire prevention adhesive to solidify the adhesive.
도6은 도5의 고형화된 제품이 열 침해를 받아 탄화되어도 견고한 형태를 유지한 상태의 단면도.FIG. 6 is a cross-sectional view of the solidified product of FIG. 5 in a state in which a solid form is maintained even when carbonized under heat intrusion; FIG.
[도면의 주요부분에 대한 부호의 설명][Explanation of symbols on the main parts of the drawings]
1. 가연성 소재 2. 가연성소재 표면에 도포 된 방화페인트 층 3. 가연성 소재 표면에 방화 페인트가 흡수된 층 4. (2)의 방화 페인트층이 열 침해를 받어부풀어 오른 변형된 상태의 층 5. (3)의 흡수층이 열 침해를 받어 탄화된 층1. Flammable material 2. Fire-retardant paint layer applied on the surface of flammable material 3. Layer where fire-resistant paint is absorbed on the surface of flammable material 4. Deformed layer in which the fire-resistant paint layer of (2) is swollen by heat invasion 5. Absorbent layer of (3) is heat invaded and carbonized layer
6. 접착소재(가연성 미 비가연성) 7. 무기방화 접착제로 접착된 단면층6. Adhesive material (non-flammable, non-flammable) 7. Single layer bonded with inorganic fireproof adhesive
8. (7)이 열 침해를 받어 부풀어 오른 변형된 상태의 층 9. 유무기 분말형태의 소재를 무기방화 접착제로 접착된 고형체의 단면도 10. (9)의 고형체가 열 침해를 받어 탄화된 상태의 탄화된 고형체.8. Deformed layer swelled due to heat invasion (7) 9. Cross-sectional view of solid body in which inorganic-inorganic powder-like material is bonded with an inorganic fireproof adhesive 10. Solids in (9) are thermally invaded and carbonized Carbonized solids in the sealed state.
본 발명의 구성은 접착 기능을 하는 규산소다(NaO·nSiO2·xH2O)를 기조로한 세라믹 바인더에 방염기능을 하는 붕산(H3BO3)이나 유사기능을 하는 붕사(Na2B4O7·10H2O)를 규산소다 대비 10% 내외, 발색이 필요시 임의의 색소를 첨가 혼합교반하여 수용액으로 제조한 무기 방화페인트 겸 방화 접착제를 필요시 용제인 물(H2O)로 적절히 희석하여 방염을 필요로 하는 경우에는 가연성 소재(벽지, 합판,목재, 가구류 등)에 스프레이 혹은 붓으로 도포하여 자연 건조시키면 도1에서와 같이 가연성 소재(1) 표면에 유리상의 도표면(2)이 형성되고 가연성소재(1) 상단층에 접착제가 흡수된 층(3)이 형성된다.The composition of the present invention is boric acid (H 3 BO 3 ) or flame retardant boric acid (Na 2 B 4 ) to the flame retardant function in a ceramic binder based on sodium silicate (NaO · nSiO 2 · xH 2 O) to the adhesive function O 7 · 10H 2 O) is about 10% compared to sodium silicate, and any color is mixed and stirred if necessary to develop an inorganic fire-retardant paint and fire-retardant adhesive prepared as an aqueous solution with water (H 2 O) as needed. If dilution is required for flame retardant, spray or brush on flammable material (wall paper, plywood, wood, furniture, etc.) and dry it naturally. Is formed and a layer 3 on which the adhesive is absorbed is formed on the upper layer of the combustible material 1.
방화 접착제 기능 중 면 접착을 할 경우에는 가연성 소재, 불연성 소재 도 3의(6) 즉 종이류, 목재류, 석재류, 시멘트 류, 철판류 등의 소재에 방화 접착제를 도포하여 동종류나 이종류 간에 접착시키면 접착층(7)이 형성되며 자연건조나 속건을 요할 시에는 열 반응 이하 온도인 100도씨 이하 저온으로 건조하면 완벽한 접착력을 갖는다.In case of surface bonding among the fire retardant adhesives, flammable and non-flammable materials are applied to the same or different types by applying a fire retardant to a material such as paper, wood, stone, cement, iron plate, etc. of FIG. 3 (6). When the adhesive layer 7 is formed, when it is required to dry naturally or fast-drying, the adhesive layer 7 has a perfect adhesive strength when dried at a low temperature below 100 ° C, which is a temperature below the thermal reaction.
방화접착제 기능 중 분말형을 고형화 시에는 소재 도5(목재류 분쇄분, 종이류분, 흙, 모래 등) 중 소정의 방화 접착제를 첨가 배합하여 압축 성형하고 자연건조나 저온 건조시키면 물성의 변화 없이 견고한 고형체가 제조된다.When solidifying the powder form among the fire-resistant adhesives, a certain fire-resistant adhesive is added and blended in the material Figure 5 (wood, crushed, paper, soil, sand, etc.), and it is compressed and formed by natural drying or low temperature drying. Shapes are made.
발색 기능이 필요시 색소를 첨가한 방화 페인트를 소재에 도포하면 방염기능과 색상도료의 기능을 동시에 얻는다.When color development is needed, the fire prevention paints with pigments are applied to the material to obtain the functions of flame retardant and color paint.
본 발명의 방염작용은 무기방화페인트로 형성된 도포층 (2)은 화재 발생시 150도씨 내외에서부터 온도가 상승함에 따라 붕산은 피로붕산(H2B4O7)과 유리상태로 변형하면서 거품상태로 부풀어 오른 단열 방화층 도2의 (4)이 만들어저 가연성소재 (1)에 인화 착화점을 지연시키며 온도 상승에 따라 발화되지 않은 것은 가연성소재 표면과 가연성소재 상단부(3)에 방화페인트 흡수층(5)이 유리(glass)상태로 고착되어 산소를 차단시켜 발화하지 않고 탄화가 이루어지므로 소방기능을 충분히 만족시킨다.Flame-retardant action of the present invention is the coating layer (2) formed of an inorganic fire-resistant paint as the temperature rises from about 150 degrees when the fire occurs boric acid is transformed into a pyroboric acid (H 2 B 4 O 7 ) and a glass state in a foam state Puffed Insulation Fire Protection Layer FIG. 2 (4) is made to delay the ignition point of the combustible material (1) and not ignite as the temperature rises, the fire resistant paint absorbing layer (5) on the surface of the combustible material and the upper part of the combustible material It is fixed in this glass (glass) state and blocks oxygen so that carbonization is performed without ignition so that the fire fighting function is sufficiently satisfied.
방화접착제 중 면접착의 효과는 화재 발생시 도3의 (7) 접착층이 화재로 인해 과열이 되면 상기 기술한 바와 같이 거품상태로 부풀어 오른 단열방화층 도4의 (8)이 형성되고 소재(6)의 접착면은 유리상태로 고착되어 산소 차단으로 발화되지 않고 탄화가되어 방염 작용을 하고 방화 접착제로 접착하고 접착한 소재 표면에 방화 페인트로 도포하면 방화효과는 배가되며 극대화된다.The effect of surface adhesion among the fireproof adhesives is that when the fire occurs, the adhesive layer of FIG. 3 (7) is overheated due to the fire. The adhesive surface is fixed in the glass state and is not fired by the oxygen barrier, but is carbonized to act as a flame retardant. The fire protection effect is doubled and maximized when it is applied with fire protection paint on the surface of the bonded material.
방화 접착제 기능 중 분말 고형화시의 효과는 압축성형된 고형체도5가 열침해를 받으면 단열 및 산소 차단효과가 있어 강도 있는 탄화 고형체가 되므로 방화 효과가 있다.The effect of powder solidification during the fire prevention adhesive function is the fire protection effect because the compressed molded solid figure 5 is thermally infiltrated and has an oxygen blocking effect, resulting in a strong carbonized solid.
이와 같은 구성으로 된 무기 방화 페인트 겸 방화 접착제는 무기물로 구성되어 방염효과가 탁월하고 용제는 물(H2O)로 사용하므로 사용 시 화제 위험이 없고 냄새가 없어 환경친화적이고, 방화접착제로 소재를 필요 용도에 붙이고 붙인 소재 전면에 방염처리를 하면 방염효과가 배가되어 탁월하다.Inorganic fire retardant paint and fire retardant adhesive composed of such a composition is composed of inorganic material and has excellent flame retardant effect and solvent is used as water (H 2 O). The flame retardant effect is doubled and excellent when the flame retardant treatment is applied to the entire surface of the material attached to the required use.
필요시 발색도료 역할을 겸하여 2중의 효과를 얻는, 다기능 제품이고 특히 구성소재가 저렴하여 사용함에 비용이 절감된다.If necessary, it is a multifunctional product that doubles the role of coloring paint, and in particular, the material is cheaper, and the cost is reduced.
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Cited By (3)
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KR100696874B1 (en) * | 2003-11-28 | 2007-03-20 | 윤욱열 | Flame retardant and fire extinguishing pharmaceutical composition |
US7560041B2 (en) | 2003-11-28 | 2009-07-14 | Wook Yeal Yoon | Composition for action of resist-fire and fire-extinguishing |
CN112830748A (en) * | 2021-01-19 | 2021-05-25 | 北京慕成防火绝热特种材料有限公司 | Preparation method of intrinsic hydrophobic non-intumescent steel structure fireproof coating |
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KR100696874B1 (en) * | 2003-11-28 | 2007-03-20 | 윤욱열 | Flame retardant and fire extinguishing pharmaceutical composition |
US7560041B2 (en) | 2003-11-28 | 2009-07-14 | Wook Yeal Yoon | Composition for action of resist-fire and fire-extinguishing |
CN112830748A (en) * | 2021-01-19 | 2021-05-25 | 北京慕成防火绝热特种材料有限公司 | Preparation method of intrinsic hydrophobic non-intumescent steel structure fireproof coating |
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