KR20030009983A - Composite of Antibacterial and Clean Soap by using Germanium and Titanium Dioxide - Google Patents

Composite of Antibacterial and Clean Soap by using Germanium and Titanium Dioxide Download PDF

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KR20030009983A
KR20030009983A KR1020010044682A KR20010044682A KR20030009983A KR 20030009983 A KR20030009983 A KR 20030009983A KR 1020010044682 A KR1020010044682 A KR 1020010044682A KR 20010044682 A KR20010044682 A KR 20010044682A KR 20030009983 A KR20030009983 A KR 20030009983A
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soap
germanium
titanium dioxide
antibacterial
skin
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KR1020010044682A
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Korean (ko)
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김홍재
손방의
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김홍재
손방의
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D9/00Compositions of detergents based essentially on soap
    • C11D9/04Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
    • C11D9/06Inorganic compounds
    • C11D9/18Water-insoluble compounds

Abstract

PURPOSE: Provided is an antimicrobial beauty soap composition containing germanium and sol-state titanium dioxide, which is excellent in antimicrobial effect, aging protection, and skin protecting effect. CONSTITUTION: The beauty soap composition comprises 87-89wt% of refined soap base, 0.5-0.8wt% of jojoba oil, 0.5-0.7wt% of tocopherol, 0.6-0.75wt% of alkoxy glycerol, 0.6-0.95wt% of aloe vera, 1-1.3wt% of grapeseed oil, 0.8-1.1wt% of herb extract, 1.0-1.4wt% of perfume, 0.5-2.5wt% of sol-state titanium dioxide(TiO2), and 1.5-3.5wt% of germanium.

Description

게르마늄과 이산화티탄을 함유한 항균 미용비누 조성물 {Composite of Antibacterial and Clean Soap by using Germanium and Titanium Dioxide}Composition of Antibacterial and Clean Soap by using Germanium and Titanium Dioxide}

본 발명은 이산화티탄과 게르마늄을 함유하고 하는 비누조성물에 관한 것이다.The present invention relates to a soap composition containing titanium dioxide and germanium.

좀더 상세하게는, 일반적인 비누조성물에 약 40,000ppm 정도의 농도를 갖는 게르마늄 수용액 1.5∼3.5중량%, 와 이산화티탄(TiO2, Sol) 0.5∼2.5중량%을 첨가하여 항균 및 우수한 피부 미용효과를 갖는 새로운 비누 조성물에 관한 것이다.More specifically, 1.5 to 3.5% by weight of a germanium aqueous solution having a concentration of about 40,000 ppm and 0.5 to 2.5% by weight of titanium dioxide (TiO2, Sol) are added to a general soap composition to have an antibacterial and excellent skin beauty effect. It relates to a soap composition.

비누조성물 및 제조방법에 대한 종래의 기술을 살펴보면 황과 싸바염을 첨가하여 개발한 저자극성 항균비누의 제조기술(한국 특허 공개번호 제 96-10847 호), 마늘 엑기스를 이용한 항균 및 살충성 비누조성물과 제조법(한국 특허 공개번호 제 20010010118 호), 세피 오라이트, 탈크 및 나무타르를 함유하는 비누조성물(한국 특허 공개번호 제 2001-0016083 호)등의 기술들이 공개 되어진 바 있다. 외국의 경우 피부의 냄새를 억제하기 위해 USP4,32 2,308호가 공지된바 있으며, 미국 USP3,723,326호에는 소취효과를 증대시키기 위해 3,4',4'-트리클로로 카바닐라이트등의 여러 화학물질들을 혼합하여 제조된 비누 조성법을 공시한 바 있다. 그러나 상기 특허 중 USP3,723,326호에 공시된 합성 화학물질을 이용한 비누의 제조 방법의 경우 소취 효과는 우수하나 자외선에 의해 쉽게 파게되고, 안정성이 없을 뿐만 아니라 피부에 자극이 있어 그 사용량의 제한을 두고 있는 실정이다.Looking at the conventional techniques for soap composition and manufacturing method, the manufacturing technology of hypoallergenic antibacterial soap developed by adding sulfur and saba salt (Korean Patent Publication No. 96-10847), antibacterial and insecticidal soap composition using garlic extract And manufacturing methods (Korean Patent Publication No. 20010010118), soap compositions containing Sepiolite, talc and wood tar (Korean Patent Publication No. 2001-0016083) have been disclosed. In foreign countries, USP 4,32 2,308 has been known to suppress the odor of the skin. US US 3,723,326 has various chemicals such as 3,4 ', 4'-trichlorocarbanilite to increase the deodorizing effect. The soap composition method prepared by mixing them has been disclosed. However, the manufacturing method of the soap using the synthetic chemical disclosed in the USP3,723,326 of the patent is excellent deodorizing effect, but easily digs by ultraviolet light, there is no stability and irritation to the skin, limiting its usage There is a situation.

본 발명에서 항균의 기능을 목적으로 첨가된 이산화티탄은 한때 20년 동안 실용화 되지 않았으나 1989년 후지시마에 의한 개발 및 연구로 꿈의 에너지라는 극찬을 받게 되었으며, 지금은 반도체, 도료, 생활환경 정화 등의 많은 응용분야에 적용하고 있다.Titanium dioxide added for the purpose of antibacterial function in the present invention has not been put to practical use for 20 years, but it was praised as a dream energy by development and research by Fujishima in 1989, and now, semiconductor, paint, purification of living environment, etc. It is applied to many applications.

상기의 이산화티탄은 태양광에 의한 촉매활성이 매우 뛰어나고, 화학적으로 안정할 뿐만 아니라 백색도와 착색력이 뛰어나 현재 고품질의 페인트, 잉크, 고무의 광택도 조절과 제품의 내구성 향상을 위해 이용되고 있으며 화장품의 자외선 차단제로도 사용되고 있다. 또한 태양광을 받아 촉매의 기능을 발휘하며 각종 박테리아 및 유해한 균들의 산화 막을 산화시켜 사멸 할 수 있는 기능을 가지고 있어 항균 기능에 뛰어난 효과를 가지고 있 기도 하다.Titanium dioxide has excellent catalytic activity by sunlight, is not only chemically stable, but also excellent in whiteness and coloring power, and is currently used to control the glossiness of high quality paints, inks and rubbers and to improve the durability of products. It is also used as a sunscreen. In addition, it has the function of activating the catalyst by receiving sunlight and oxidizing and killing the oxide film of various bacteria and harmful bacteria.

이와 더불어 "21세기의 구세주"로 클로즈업 되어가고 있는 게르마늄은 피부조직에 산소를 공급함으로써 불순물을 제거하여 청결한 피부와 항균기능, 원적외선 방출에 따른 노 화방지, 잔주름, 여드름, 모공수축, 각질 및 노폐물제거를 목적으로 조성화합물에 첨부되었 으며 또한 인체 피부조직에 독소성분이 전혀 없어 적용처의 범위를 넓게할 수 있다는 장점 을 가지고 있다 . 게르마늄은 질량수 76의 규산염 중에 일부의 규소가 치환되어 존재하기도 하고 황화광 혹은 석탄중에도 존재하는 회백색의 입방정계, 다이몬드구조를 갖는 물질이기 도 하며, 현재 게르마늄을 사용하여 응용화된 기술들은 항암제, 화상치료제, 질 세정제, 각 종 피부질환자, 안질환자 등의 치료제로 적용되고 있으며, 반도체와 원적외선 방사체의 합 첩용으로도 널리 이용되고 있다.In addition, germanium, which is getting close to the “savior of the 21st century”, removes impurities by supplying oxygen to skin tissue to remove impurities, clean skin and antibacterial function, prevent aging due to far-infrared radiation, fine wrinkles, acne, pore shrinkage, dead skin and waste products. It is attached to the compound for the purpose of removal and has the advantage of widening the range of application because there is no toxin component in human skin tissue. Germanium is a substance having a gray-white cubic system and a diamond structure, which are partially substituted by silicon in a silicate having a mass number of 76, and also in sulfide or coal, and currently applied technologies using germanium are anticancer agents and burns. It is used as a therapeutic agent, vaginal cleanser, various skin diseases, eye diseases, etc., and is also widely used for bonding semiconductors and far-infrared radiators.

이에 본 발명은 상기에서 언급한 바와 같이 이산화티탄과 게르마늄의 특성 및 물 성을 이용한 새로운 비누조성물을 제시함으로써 피부의 피지성분이 제거되고, 피부세포가 각질화 되어 모공이 막혀 혐기성 여드름균등이 침투하여 발생하는 염증 등을 방지할 뿐만 아니라 포도상구균 (Staphylococcus aureus ATCC 6538)과 폐렴쌍구균(Klebaiella pneumo -niae ATCC 4352)과 같은 유해균들에 대해서도 항균 기능을 발휘할 수 있는 조성물에 관한 것이다. 또한 인체 피부조직에 독소성분이 전혀 없는 게르마늄을 첨가하므로써 노화방지, 잔주름, 여드름, 모공 수축, 각질 및 노폐물을 제거함으로써 피부 미용에 뛰어난 비누 조 성물을 제시하고자 한다.Accordingly, the present invention, as mentioned above, by presenting a new soap composition using the properties and properties of titanium dioxide and germanium, the sebum component of the skin is removed, the skin cells are keratinized, the pores are clogged, the anaerobic acne is infiltrated The present invention relates to compositions that can exert antimicrobial functions against harmful bacteria such as staphylococcus aureus ATCC 6538 and pneumococcal bacteria (Klebaiella pneumo-niae ATCC 4352). In addition, by adding germanium which has no toxin content in human skin tissues, we propose an excellent soap composition for skin beauty by removing anti-aging, fine lines, acne, pore shrinkage, dead skin cells and wastes.

본 발명의 주된 기술적 과제는 태양열로부터 뛰어난 광촉매 성질을 가진 이산화티탄(TiO2, Sol)과 생명의 원소라 불리우는 게르마늄을 혼합 제조한 비누 조성법을 고안함으 로써 항균 및 우수한 피부 미용효과를 갖는 새로운 비누의 제조기술을 제공 하고자 한다.The main technical problem of the present invention is to devise a soap composition method in which a mixture of titanium dioxide (TiO2, Sol) having excellent photocatalytic properties from solar heat and germanium called an element of life is invented, thereby providing a new soap having an antibacterial and excellent skin beauty effect. To provide manufacturing technology.

본 발명에서 고안된 항균 및 미용비누의 기술적 과제를 수행하기 위해 그 대상물질로 이산화티탄과 게르마늄을 첨가한 새로운 비누 조성물을 고안 하였으며 수회의 테스트와 실험을 통해 그 효능을 입증하는데 주력 하였다.In order to carry out the technical task of the antibacterial and beauty soap designed in the present invention, a new soap composition was added to the titanium dioxide and germanium as the target material and focused on proving its efficacy through several tests and experiments.

실시예1.Example 1

1. 식물성 소지(Refined soap base): 87∼89중량%1.Refined soap base: 87-89% by weight

2. 호호바 오일(Jojoba oil, 0.5∼0.8중량%): 피부친화력, 건성피부에 효과적.2. Jojoba oil (0.5 ~ 0.8 wt%): Skin-friendly, effective for dry skin.

3. 토코페롤(Tocopherol, 0.5∼0.7중량%): 비타민 E제공, 노화방지, 여드름과 기미방지, 피부밖으로 젖산물질 배출, 피부탄력기능 등3. Tocopherol (0.5 ~ 0.7% by weight): Providing vitamin E, preventing aging, preventing acne and blemishes, discharging lactic acid substance out of skin, skin elasticity, etc.

4. 알콕시 를리세롤(Alkoxy glycerol, 0.6∼0.75중량%): 신체면역 방어기능 활성화, 항체생성 자극제, 백혈구 및 혈소판수 증가효과.4. Alkoxy glycerol (0.6 ~ 0.75% by weight): activate body immune defense, stimulating antibody production, leukocyte and platelet count.

5. Aloe vera (0.6∼0.95중량%): 피부보습제, 수렴작용, 피부종화작용, 미백작용, 자외선흡수능력, 화상치료, 화장품원료, 피부질환치료효과 등5. Aloe vera (0.6∼0.95% by weight): skin moisturizer, astringent effect, skin emollient effect, whitening effect, UV absorption ability, burn treatment, cosmetic raw material, skin disease treatment effect, etc.

6. 그래이프시드오일(Grapeseed oil, 1∼1.3중량%): 항산화력 작용.6. Grapeseed oil (1-1.3% by weight): antioxidant activity.

7. 한방 추출액(24성분, 0.8∼1.1중량%): 백렴, 백급, 백편두, 행인, 은행, 감초, 고삼, 죽염 등7. Herbal extract (24 ingredients, 0.8 ~ 1.1% by weight): white worm, white gram, white migraine, almond, ginkgo, licorice, ginseng, bamboo salt, etc.

8. Perfume: 1.0∼1.4중량%8.Perfume: 1.0-1.4 wt%

본 고안의 특징으로는 상기의 영양제, 피부보습제, 한방추출액 등의 비누조성물에 이산화티탄(TiO2, Sol) 0.5∼2.5중량%와 게르마늄수용액 1.5∼3.5중량%를 첨가하여 항균 및 인간의 피부보호 효과를 증대시킬 수 있는 비누 조성물을 갖고 있다는 것이며, 이는 일반적인 비누제조 공정을 통하여 제조할 수 있다.Characteristic of the present invention is the antimicrobial and human skin protection effect by adding 0.5 to 2.5% by weight of titanium dioxide (TiO2, Sol) and 1.5 to 3.5% by weight of germanium aqueous solution to soap compositions such as nutrients, skin moisturizers and herbal extracts. It has a soap composition that can increase the, it can be prepared through a general soap manufacturing process.

[항균 효과 시험][Antibacterial Effect Test]

본 발명에서 고안된 조성물로 제조된 항균 미용비누의 항균효과를 측정하기 위해 포도상구균(Staphylococcus aureus ATCC 6538)과 폐렴쌍구균(Candida albicans ATCC 14053)의 접종균농도를 각각 1.5±0.1×105/ml와 2.3±0.1×105/ml를 취하여 측정한 결과 표1에 서 보여준 것처럼 각각의 균주에 대하여 99.9%의 정균율을 나타내었다.In order to measure the antimicrobial effect of the antibacterial cosmetic soap prepared with the composition designed in the present invention, the concentrations of inoculation bacteria of Staphylococcus aureus ATCC 6538 and P. pneumoniae (Candida albicans ATCC 14053) were respectively 1.5 ± 0.1 × 10 5 / ml and As a result of taking 2.3 ± 0.1 × 10 5 / ml, the bacteriostatic rate was 99.9% for each strain.

항균실험Antimicrobial Experiment 사용공시균주Used strain 접종균농도(세균수/㎖)Inoculation bacteria concentration (bacterial number / ml) 24시간후24 hours later 정균율(%)Bacteriostatic rate (%) BlankBlank 포도상구균Staphylococcus 1.5 ×105 1.5 × 10 5 6.3 ×106 6.3 × 10 6 -- 폐렴상구균Pneumococcal 2.3 ×105 2.3 × 10 5 8.3 ×106 8.3 × 10 6 -- SampleSample 포도상구균Staphylococcus 1.5 ×105 1.5 × 10 5 <10<10 99.999.9 폐렴상구균Pneumococcal 2.3 ×105 2.3 × 10 5 <10<10 99.999.9

표 1. 포도상구균과 폐렴쌍구균에 대한 항균축광사의 항균테스트 결과Table 1. Antimicrobial Test Results of Antimicrobial Photoluminescent Incidents against Staphylococcus and Pneumococci

주) ⊙ 항균미용비누의 시료농도: 1%Note) Sample concentration of antibacterial soap: 1%

⊙ 사용공시균주: Staphylococcus aureus ATCC 6538⊙ Test strain used: Staphylococcus aureus ATCC 6538

Candida albicans ATCC 14053Candida albicans ATCC 14053

⊙ 비이온 계면활성제 종류: TWEEN 80 (0.05%)Nonionic surfactant type: TWEEN 80 (0.05%)

⊙ 시험조건⊙ Test condition

-시험균액을 35±1℃에서 24시간 진탕 배양후 균수 측정(진탕횟수150회/분)-Bacterial count measured after shaking culture at 35 ± 1 ℃ for 24 hours (150 shakes / min)

⊙ 중화용액: 인산완충용액(pH 7.0± 0.2)⊙ Neutralizing solution: Phosphate buffer solution (pH 7.0 ± 0.2)

상기에서 살펴본 바와 같이 이산화티탄과 게르마늄을 혼합한 항균미용비누의 경우 인간에게 유해한 균주들에 대해 매우 뛰어난 항균 및 멸균 효과를 제공할 수 있고, 피부에 자극성이 없고 미용 효과가 뛰어난 조성물로 유용한 발명기술이라 할 수 있다.As described above, in the case of antibacterial beauty soap mixed with titanium dioxide and germanium, it is possible to provide very excellent antimicrobial and sterilizing effect against strains harmful to humans, and it is not irritating to the skin and has excellent cosmetic effect. This can be called.

Claims (2)

소지, 보습제, 한방추출액 등의 통상 비누 조성물에 이산화티탄(TiO2, Sol) 0.5∼2.5중량%와 게르마늄 1.5∼3.5중량%를 첨가하여 항균 및 인간의 피부보호 효과를 증대시킬 수 있는 비누 조성물.A soap composition capable of increasing antibacterial and human skin protection effects by adding 0.5 to 2.5% by weight of titanium dioxide (TiO 2, Sol) and 1.5 to 3.5% by weight of germanium to ordinary soap compositions such as bases, moisturizers and herbal extracts. 청구항 1.에서 제시한 조성물을 특징으로 하는 미용비누, 크림비누, 세안비누, 목욕비누의 비누조성물.Soap composition of cosmetic soap, cream soap, facial soap, bath soap, characterized in that the composition shown in claim 1.
KR1020010044682A 2001-07-25 2001-07-25 Composite of Antibacterial and Clean Soap by using Germanium and Titanium Dioxide KR20030009983A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100507901B1 (en) * 2002-06-28 2005-08-11 황만선 Manufacture method of aminoacid germanium soap
KR100962534B1 (en) * 2008-06-20 2010-06-14 주식회사 리솝 Soap composition comprising herb extracts
KR101125893B1 (en) * 2005-04-13 2012-03-21 (주)아모레퍼시픽 Medicinal herb cosmetic soap composition
WO2017192110A1 (en) * 2016-05-03 2017-11-09 Bioarge Bitiksel Kozmetik Arastirma Gelistirme Muhendislik Ltd. Sti. Herbal extraction and manufacturing process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100507901B1 (en) * 2002-06-28 2005-08-11 황만선 Manufacture method of aminoacid germanium soap
KR101125893B1 (en) * 2005-04-13 2012-03-21 (주)아모레퍼시픽 Medicinal herb cosmetic soap composition
KR100962534B1 (en) * 2008-06-20 2010-06-14 주식회사 리솝 Soap composition comprising herb extracts
WO2017192110A1 (en) * 2016-05-03 2017-11-09 Bioarge Bitiksel Kozmetik Arastirma Gelistirme Muhendislik Ltd. Sti. Herbal extraction and manufacturing process

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