KR20030005483A - The organic liquid manure with agricultural by-products for pepper in fertigated cultivation and manufacturing method thereof - Google Patents

The organic liquid manure with agricultural by-products for pepper in fertigated cultivation and manufacturing method thereof Download PDF

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KR20030005483A
KR20030005483A KR1020010040788A KR20010040788A KR20030005483A KR 20030005483 A KR20030005483 A KR 20030005483A KR 1020010040788 A KR1020010040788 A KR 1020010040788A KR 20010040788 A KR20010040788 A KR 20010040788A KR 20030005483 A KR20030005483 A KR 20030005483A
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liquid fertilizer
pepper
weight
fertilizer
agricultural
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KR100431121B1 (en
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주선종
홍성택
정재현
이경희
노창우
김태수
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충청북도 농업기술원
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F3/00Fertilisers from human or animal excrements, e.g. manure
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F5/00Fertilisers from distillery wastes, molasses, vinasses, sugar plant or similar wastes or residues, e.g. from waste originating from industrial processing of raw material of agricultural origin or derived products thereof
    • C05F5/002Solid waste from mechanical processing of material, e.g. seed coats, olive pits, almond shells, fruit residue, rice hulls
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G5/00Fertilisers characterised by their form
    • C05G5/20Liquid fertilisers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Mechanical Engineering (AREA)
  • Botany (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fertilizers (AREA)

Abstract

PURPOSE: An organic liquid fertilizer comprising agriculture byproduct(fowl waste, bean and rice hull) is provided for use in fertigation of pepper under greenhouse. Accordingly, the greenhouse grown pepper has sweetness and high quality. CONSTITUTION: The organic liquid fertilizer is produced by mixing 45-55wt.% of fowl waste, 22.5-27.5wt.% of rice hull, and 22.5-27.5wt.% of bean, diluting the mixture with water in a ratio of 1:4; anaerobic fermenting for 40-60days under shade. The resultant liquid fertilizer diluted with 7-15times water is applied to greenhouse pepper.

Description

농산부산물을 이용한 시설고추 관비재배용 유기질 액체비료 및 그 제조방법{The organic liquid manure with agricultural by-products for pepper in fertigated cultivation and manufacturing method thereof}The organic liquid manure with agricultural by-products for pepper in fertigated cultivation and manufacturing method

본 발명은 농산부산물을 이용한 액체비료에 관한 것이다.The present invention relates to a liquid fertilizer using agricultural by-products.

더욱 상세하게는 농산부산물인 계분과 대두박 및 쌀겨를 일정비율로 배합하여 환경친화적 유기질 액체비료로 시설고추재배에 사용함으로써 안전하고 당도높은 고품질의 고추를 생산하기 위한 시설고추 관비재배용 유기질 액체비료와 그 제조방법에 관한 것이다.More specifically, organic liquid fertilizer for planting red pepper and fertilizer for producing red peppers of high quality and high quality by mixing the agricultural by-products, soybean meal, soybean meal and rice bran in a certain ratio and using it for facility pepper cultivation as an environmentally friendly organic liquid fertilizer. It relates to a manufacturing method.

우리나라 농산부산물 발생량은 매년 900만톤 정도이며 유기성폐기물의 발생량은 약 3억톤으로서 그 양은 증가추세에 있어 환경오염의 요인이 되고 있다. 특히 시설채소 재배지는 강우가 차단된 상태에서 연중 다기작으로 장기간 재배하게 되며 화학비료와 농약을 과도하게 사용하여 지력이 약화되고 염류가 집적되어 생육이 저해되며 안전성이 낮아지는 문제가 발생되고 있다.The amount of agricultural by-products generated in Korea is about 9 million tons per year, and the amount of organic waste generated is about 300 million tons, which is a factor of environmental pollution. In particular, plant vegetable cultivation is cultivated for a long period of time by a multi-productive operation in a state in which the rainfall is blocked, and excessive use of chemical fertilizers and pesticides weakens the intellect, salts accumulate, inhibits growth, and the safety is low.

본 발명은 이러한 문제점을 개선하기 위한 것으로서 농산부산물로 유기 액체비료를 만들어 사용함으로써 시설재배에서 많이 사용하게 되는 화학비료와 농약 사용량을 줄이면서 안전하고 당도가 높은 고품질의 고추를 생산하는데 목적이 있다.The present invention is to improve the above problems by using an organic liquid fertilizer made by agricultural by-products to reduce the amount of chemical fertilizers and pesticides used in facility cultivation, while producing a safe and high sugar high quality pepper.

이와같은 목적을 달성하기 위하여 계분 45∼55중량%, 쌀겨 22.5∼27.5중량%, 대두박 22.5∼27.5중량%를 배합하고 이 배합물을 물로 4배 희석한 후 혐기성발효시켜 관비재배용 유기질 액체비료를 만들어 시설재배하는 고추에 시비함을 특징으로 한다.To achieve this purpose, 45 to 55% by weight of flour, 22.5 to 27.5% by weight of rice bran, 22.5 to 27.5% by weight of soybean meal are mixed and diluted 4 times with water and then anaerobic fermentation to make organic liquid fertilizer for fertilization. It is characterized by fertilization of peppers grown.

농산부산물중 액비로 사용할 수 있는 자재는 계분, 어분, 골분, 쌀겨, 대두박 등이 있으며 이들 농산부산물 자재의 이화학성은 <표 1>과 같으며 각각의 자재를 발효하여 제조한 액체비료의 이화학성은 <표 2>와 같이 어분, 골분과 대두박에는 질소가 많고 계분, 쌀겨 및 대두박에는 인산, 칼리, 석회 및 고토성분이 많으나 이들 각각의 액체비료는 영양분이 과다하거나 부족하지만 이들을 선택적으로 적당량 배합한 본 발명의 액체비료는 영양분이 균형을 이루고 있음을 알수 있다.Among the agricultural by-products, materials that can be used as liquid fertilizer include gye flour, fish meal, bone meal, rice bran, soybean meal, etc. The physicochemical properties of these agricultural by-products are shown in <Table 1>. As shown in <Table 2>, fish meal, bone meal and soybean meal are high in nitrogen, and chicken flour, rice bran and soybean meal are high in phosphoric acid, kali, lime and goto. However, each of these liquid fertilizers is nutrient-rich or lacking in nutrients. Liquid fertilizer of the present invention can be seen that the nutrient balance.

본 발명은 건조한 계분 45∼55중량%, 쌀겨 22.5∼27.5중량%, 대두박 22.5∼27.5중량%를 배합하고 이 배합물을 4배의 물로 희석한 후 직사광선을 피한 곳에 발효조(Tank)를 안치하고 40∼60일 동안 혐기성발효시켜 관비재배용 유기질 액체비료를 제조하며 제조한 액체비료를 사용할 때는 물로 7∼15배 희석하여 고추에 시비한다.The present invention is formulated with 45 to 55% by weight of dry flour, 22.5 to 27.5% by weight of rice bran, 22.5 to 27.5% by weight of soybean meal, and the compound is diluted with 4 times of water and placed in a fermentation tank (Tank) where it is avoided in direct sunlight. Anaerobic fermentation for 60 days to produce organic liquid fertilizer for fertilization cultivation. When using the prepared liquid fertilizer, dilute 7-15 times with water and fertilize it with red pepper.

<실시예><Example>

수분 10.9%로 건조시킨 계분 25㎏, 수분 9.3%의 쌀겨 12.5㎏, 수분 12.7%의 대두박 12.5㎏을 배합하고 이 배합물을 물 200ℓ로 희석한 후 400ℓ 발효조 탱크에 넣고 50일동안 직사광선을 피한 상온에서 혐기성발효시켜 액체비료를 제조하며 고추에 시비할 때는 제조한 액체비료를 물로 10배 희석하여 고추를 심은 후 14일부터 7일간격으로 시비한다.25 kg of dried flour with 10.9% moisture, 12.5 kg of rice bran with 9.3% moisture, and 12.5 kg of soybean meal with 12.7% moisture are diluted with 200 L of water and put into a 400 L fermenter tank at room temperature for 50 days. Anaerobic fermentation produces liquid fertilizer. When fertilizing red pepper, dilute the prepared liquid fertilizer with water 10 times and fertilize every 14 days after planting red pepper.

다음 <표 3>∼<표 6>은 화학비료(요소, 용성인비, 염화카리), 시판액체비료, 실시예에서 보인 방법으로 제조한 액체비료를 각각 고추에 시비하여 재배한 실험결과를 나타낸 것이다.<Table 3> to <Table 6> show the experimental results of fertilizing each fertilizer fertilized with chemical fertilizers (urea, soluble phosphorus fertilizer, carry chloride), commercial liquid fertilizer, and liquid fertilizer prepared by the method shown in the examples.

본 발명에서와 같이 계분 50중량%, 쌀겨 25중량%, 대두박 25중량%의 배합물로 제조한 액체비료로 고추에 시비하여 재배하였을 경우 화학비료와 시판액체비료를 고추에 시비하여 재배하였을 경우보다 고추의 주경경, 분지수, 건물율 등이 높았으며(<표 3>), 고추의 매운맛 성분인 캡사이신(Capsaicin) 함량이 26.4㎎/100g으로 화학비료와 시판액체비료를 고추에 시비하여 재배하였을 경우보다 낮았고 당도에 있어서는 10°Brix로 높아(<표 4>) 감칠 맛이 나는 고추를 생산할 수 있었으며 또 <표 5>에서와 같이 고추 수량 지수는 화학비료를 시비하여 재배한 경우를 100%로 보았을 때 본 발명의 액체비료를 시비하여 재배한 경우가 101.4%로 시판 액체비료를 시비하여 재배하였을 경우보다 높았다. 또한 각각의 비료를 시비한 후의 토양 이화학성을 살펴보면 본 발명의 액체비료를 고추에 시비하여 재배하였을 경우가 화학비료와 시판액체비료를 고추에 시비하여 재배하였을 경우보다 전기전도도 (EC(Electric Conductivity)가 낮았으며 양이온치환용량(CEC)은 높아 토양이화학성을 개선시킴을 알 수 있었다.(<표 6>)As in the present invention, when fertilized with red pepper as a liquid fertilizer prepared from a blend of 50% by weight, 25% by weight of rice bran, and 25% by weight of soybean meal, pepper and chemical liquid fertilizer were fertilized with red pepper than when fertilized with red pepper. The main diameter, the number of branches, and the dry matter ratio were high (<Table 3>). The capsaicin content of hot pepper was 26.4mg / 100g, which was higher than that of fertilizers fertilized with chemical fertilizer and commercial liquid fertilizer. Low sugar content and high sugar content of 10 ° Brix (<Table 4>) were able to produce flavorful peppers, and as shown in <Table 5>, the pepper yield index was 100% when fertilized with chemical fertilizers. The fertilizer of the liquid fertilizer of the present invention was cultivated at 101.4%, which was higher than the fertilizer of commercial liquid fertilizer. In addition, when looking at the soil physicochemical properties of each fertilizer, the liquid fertilizer of the present invention was fertilized in red peppers and cultivated more than the chemical fertilizer and commercial liquid fertilizers in red peppers. Was low and the cation exchange capacity (CEC) was high, improving soil chemistry (Table 6).

따라서, 계분 45∼55중량%와 쌀겨 22.5∼27.5중량%와 대두박 22.5∼27.5 중량% 배합한 것을 1로 하고 이에 대하여 물 4배로 희석하여 혐기성발효시킨 본 발명의 액체비료가 고추의 수량과 품질에서 가장 우수함을 알 수 있었다.Therefore, the liquid fertilizer of the present invention, anaerobic fermented by fermenting 45 to 55% by weight, 22.5 to 27.5% by weight of rice bran and 22.5 to 27.5% by weight of soybean meal, and diluting it with water four times, yielded in the quantity and quality of red pepper. It was found to be the best.

<표1> 농산부산물 자재의 이화학성<Table 1> Physicochemical Properties of Agricultural By-Products

액비자재Liquid material 수분moisture OMOM T-CT-C T-NT-N P2O5 P 2 O 5 K2OK 2 O CaOCaO MgOMgO Na2ONa 2 O %% 계 분Total minutes 10.910.9 53.253.2 30.930.9 2.532.53 4.804.80 2.942.94 13.8513.85 1.001.00 0.580.58 어 분Fish 9.809.80 79.379.3 46.046.0 9.859.85 6.396.39 0.810.81 7.387.38 0.390.39 1.001.00 골 분Bone marrow 6.806.80 81.181.1 47.047.0 7.057.05 10.6410.64 0.370.37 13.6413.64 0.370.37 0.740.74 쌀 겨Rice bran 9.309.30 90.190.1 52.252.2 1.801.80 4.574.57 2.062.06 0.110.11 1.441.44 0.020.02 대두박Soybean meal 12.7012.70 91.291.2 52.952.9 6.836.83 1.391.39 2.452.45 0.500.50 0.470.47 0.040.04

<표2>농산부산물 액체비료의 이화학성(발효기간 : 50일)<Table 2> Physicochemical Properties of A by-product Liquid Fertilizer (Effective Period: 50 days)

액비자재Liquid material 수분moisture OMOM T-CT-C T-NT-N P2O5 P 2 O 5 K2OK 2 O CaOCaO MgOMgO Na2ONa 2 O %% 계 분Total minutes 97.597.5 1.01.0 0.60.6 0.300.30 0.020.02 0.530.53 0.0040.004 0.0010.001 0.100.10 어 분Fish 95.195.1 4.44.4 2.62.6 1.481.48 0.100.10 0.170.17 0.0020.002 0.0020.002 0.180.18 골 분Bone marrow 97.597.5 2.02.0 1.11.1 0.910.91 0.050.05 0.250.25 0.0040.004 0.0000.000 0.100.10 쌀 겨Rice bran 93.593.5 4.64.6 2.72.7 0.320.32 0.800.80 0.420.42 0.0120.012 0.2300.230 0.020.02 대두박Soybean meal 84.584.5 14.114.1 8.28.2 1.151.15 0.160.16 0.500.50 0.0480.048 0.0250.025 0.010.01 본 발명의액체비료Liquid fertilizer of the present invention 95.095.0 3.43.4 2.02.0 0.510.51 0.170.17 0.510.51 0.080.08 0.090.09 0.050.05

<표3> 화학비료, 시판액체비료, 본 발명의 액체비료를 각각<Table 3> Chemical fertilizer, commercial liquid fertilizer, and liquid fertilizer of the present invention, respectively

고추에 시비하였을 경우 고추의 생육특성Growth Characteristics of Red Pepper when Fertilized with Red Pepper

처리process 초장(㎝)Extra long (cm) 주경장(㎝)Main length (cm) 주경경(㎜)Major diameter (mm) 분지수(개/주)Quarterly indexes 생체중(g/주)Live weight (g / week) 건물중(g/주)Among buildings (g / week) 건물율(%)% Building 화학비료Chemical fertilizer 240.3240.3 22.622.6 14.714.7 21.021.0 636.0636.0 162.2162.2 25.525.5 시판액체비료Commercial liquid fertilizer 228.7228.7 22.422.4 13.613.6 23.323.3 593.3593.3 167.9167.9 28.328.3 본 발명의액체비료Liquid fertilizer of the present invention 209.7209.7 21.221.2 16.516.5 24.024.0 630.0630.0 195.3195.3 31.031.0

<표4> 화학비료, 시판액체비료, 본 발명의 액체비료를 각각<Table 4> Chemical fertilizer, commercial liquid fertilizer, and liquid fertilizer of the present invention, respectively

고추에 시비하였을 경우 생산고추과실의 주요성분 함량Main Components of Red Pepper Fruits Produced in Red Pepper

처리process Capsaicin(mg/100g)Capsaicin (mg / 100g) 당도(°Brix)Sugar (° Brix) 당함량(%)Sugar content (%) capsaicincapsaicin dihydro-capsaicindihydro-capsaicin TotalCapsaicinTotalCapsaicin GalactoseGalactose FructoseFructose GlucoseGlucose TotalTotal 화학비료Chemical fertilizer 41.941.9 24.324.3 66.266.2 8.68.6 0.030.03 2.692.69 1.911.91 4.634.63 시판액체비료Commercial liquid fertilizer 27.627.6 12.512.5 40.140.1 8.58.5 0.320.32 2.542.54 1.691.69 4.554.55 본발명의액체비료Liquid fertilizer of the present invention 26.426.4 15.415.4 41.841.8 10.010.0 0.080.08 2.632.63 2.482.48 5.195.19

<표 5> 화학비료, 시판액체비료, 본 발명의 액체비료를 각각<Table 5> Chemical fertilizer, commercial liquid fertilizer, liquid fertilizer of the present invention, respectively

고추에 시비하였을 경우 생산고추의 수량구성요소 및 수량Quantity Components and Quantity of Red Peppers Fertilized with Red Pepper

처리process 과수(개/주)Fruit Trees 과장(㎝)Exaggeration (cm) 과경(㎜)Over diameter (mm) 상품화율(%)Merchandising Rate (%) 수량(㎏/10a)Quantity (kg / 10a) 지수(%)Indices(%) 풋고추Green pepper 적색물고추Red Water Pepper system 화학비료Chemical fertilizer 107.2107.2 13.213.2 19.319.3 9898 2,0972,097 3,0243,024 5,1215,121 100100 시판액체비료Commercial liquid fertilizer 113.8113.8 12.612.6 19.019.0 9797 2,2972,297 2,4772,477 4,7744,774 93.293.2 본발명의액체비료Liquid fertilizer of the present invention 133.0133.0 12.112.1 18.718.7 9898 2,4842,484 2,7062,706 5,1905,190 101.4101.4

<표 6> 화학비료, 시판 액체비료, 본 발명의 액체비료를 고추에 시비전과 시비후 토양 이화학성Table 6 Chemical fertilizers, commercial liquid fertilizers, liquid fertilizers of the present invention in red pepper fertilization before and after fertilization soil

처리process pHpH EC(ds/m)EC (ds / m) OM(%)OM (%) NH4-NNH 4 -N NO3-NNO 3 -N AV1P2O5 AV 1 P 2 O 5 KK CaCa MgMg CECCEC (mg/kg)(mg / kg) (cmol(+)/kg)(cmol (+) / kg) 시험전Before the test 7.407.40 0.900.90 0.600.60 2.102.10 41.3041.30 74.0074.00 0.190.19 7.707.70 1.101.10 9.009.00 시험후After the test 화학비료Chemical fertilizer 7.207.20 2.202.20 1.001.00 2.102.10 1.401.40 103.00103.00 0.120.12 12.6012.60 0.800.80 10.5010.50 시판액체비료Commercial liquid fertilizer 7.107.10 2.302.30 1.101.10 2.102.10 2.402.40 81.0081.00 0.110.11 19.1019.10 0.800.80 14.0014.00 본 발명의 액체비료Liquid fertilizer of the present invention 7.007.00 1.401.40 1.101.10 2.002.00 3.503.50 84.0084.00 0.150.15 9.709.70 0.700.70 20.0020.00

농가에서 버려지는 농산부산물을 재활용하여 유기질 액체비료로 이용함으로써 환경오염의 원인을 제거하고 화학비료 시용량을 줄일 수 있어 비용을 절감하며 고추를 재배할 때 본 발명의 유기질 액제비료를 시용하면 수확량이 많고 고추의 매운맛이 적은 반면 당도가 높고 안전성이 있어 품질이 좋을 뿐 아니라 특히 시설재배에서 문제점으로 되고 있는 토양중의 전기전도도(Electric Conductivity)가 화학비료 2.20dS/m, 시판액체비료 2.3dS/m 에 비하여 본 발명의 액체비료는 1.4dS/m 로 약 40% 낮아지고, 양이온치환용량(CEC)은 화학비료 10.50cmol(+)/kg, 시판 액체비료 14.00cmol(+)/kg에 비하여 본 발명의 액체비료는 20.00cmol(+)/kg 으로 약 39% 높아져 토양이화학성 개선에 효과적이다.By recycling agricultural by-products discarded in farmhouses and using them as organic liquid fertilizers, it is possible to eliminate the causes of environmental pollution and reduce the amount of chemical fertilizers, thereby reducing costs, and when the organic liquid fertilizers of the present invention are used when growing red pepper, The pepper's spicy taste is high but its sugar content and safety are not only good quality but also the electrical conductivity of soil which is a problem in plant cultivation is 2.20dS / m for chemical fertilizer and 2.3dS / m for commercial liquid fertilizer. In comparison, the liquid fertilizer of the present invention is about 40% lowered to 1.4dS / m, and the cation substitution capacity (CEC) is 10.50cmol (+) / kg of chemical fertilizer and 14.00cmol (+) / kg of commercial liquid fertilizer. Liquid fertilizer is 20.00cmol (+) / kg, about 39% higher, which is effective for improving soil chemistry.

Claims (2)

액체비료 제조방법에 있어서, 계분 45∼55중량%, 쌀겨 22.5∼27.5중량%, 대두박 22.5∼27.5중량%를 배합하고 이 배합물을 물로 4배 희석한 후 40∼60일 동안 직사광선을 피한 곳에서 혐기성발효시켜 액체비료를 만들어 물로 7∼15배 희석하여 시설재배하는 고추에 시비함을 특징으로 하는 농산부산물을 이용한 시설고추 관비재배용 유기질 액체비료 제조방법.In the liquid fertilizer manufacturing method, 45 to 55% by weight, 22.5 to 27.5% by weight of rice bran, 22.5 to 27.5% by weight of soybean meal are mixed, and the mixture is diluted four times with water, and then anaerobic at 40 to 60 days in direct sunlight. A method for producing organic liquid fertilizer for fertilization of red pepper facilities using agricultural by-products, which is fermented to make liquid fertilizer and diluted 7-15 times with water to fertilize red pepper grown in the facility. 액체비료에 있어서, 계분 45∼55중량%, 쌀겨 22.5∼27.5중량%, 대두박 22.5∼27.5중량%를 배합하고 이 배합물을 물로 4배 희석한 후 40∼60일 동안 직사광선을 피한 곳에서 혐기성발효시킨 것을 특징으로 하는 농산부산물을 이용한 시설고추 관비재배용 유기질 액체비료.In liquid fertilizer, 45 to 55% by weight of flour, 22.5 to 27.5% by weight of rice bran, 22.5 to 27.5% by weight of soybean meal were mixed, diluted 4 times with water, and anaerobic fermentation in direct sunlight for 40 to 60 days. Organic liquid fertilizer for fertilization of red pepper facility facilities using agricultural by-products.
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KR101297426B1 (en) * 2010-12-28 2013-08-19 충청북도 (관리부서:충청북도 농업기술원) The organic liquid manure with agricultural by―products for watermelon in fertigated cultivation and manufacturing method of the same
KR101172424B1 (en) 2010-12-28 2012-08-08 충청북도 (관리부서:충청북도 농업기술원) The organic liquid manure with agricultural by-products for tomato in fertigated cultivation and manufacturing method of the same
CN103159530A (en) * 2013-04-16 2013-06-19 重庆港宸农资有限公司 Special slow-release compound fertilizer for hot peppers and preparation method of special slow-release compound fertilizer
KR102099253B1 (en) 2019-04-09 2020-04-09 이중근 manufacturing method of liquid fertilizer using natural pozzolan

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