KR20030000485A - Method for forming gate electrode of semiconductor device - Google Patents
Method for forming gate electrode of semiconductor device Download PDFInfo
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- KR20030000485A KR20030000485A KR1020010036280A KR20010036280A KR20030000485A KR 20030000485 A KR20030000485 A KR 20030000485A KR 1020010036280 A KR1020010036280 A KR 1020010036280A KR 20010036280 A KR20010036280 A KR 20010036280A KR 20030000485 A KR20030000485 A KR 20030000485A
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- gate electrode
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- semiconductor device
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- 238000000034 method Methods 0.000 title claims abstract description 39
- 239000004065 semiconductor Substances 0.000 title claims abstract description 30
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 51
- 229920005591 polysilicon Polymers 0.000 claims abstract description 27
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 238000005530 etching Methods 0.000 claims abstract description 4
- 230000015572 biosynthetic process Effects 0.000 claims abstract 3
- 229910052732 germanium Inorganic materials 0.000 claims description 37
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 37
- 239000007789 gas Substances 0.000 claims description 23
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052710 silicon Inorganic materials 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
- 238000004518 low pressure chemical vapour deposition Methods 0.000 claims description 5
- 239000002019 doping agent Substances 0.000 claims description 4
- 238000011065 in-situ storage Methods 0.000 claims description 3
- 230000001590 oxidative effect Effects 0.000 claims description 3
- 238000001289 rapid thermal chemical vapour deposition Methods 0.000 claims description 3
- 238000011066 ex-situ storage Methods 0.000 claims description 2
- 238000005468 ion implantation Methods 0.000 claims description 2
- 238000000038 ultrahigh vacuum chemical vapour deposition Methods 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 238000001505 atmospheric-pressure chemical vapour deposition Methods 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052796 boron Inorganic materials 0.000 abstract description 4
- 229910000577 Silicon-germanium Inorganic materials 0.000 abstract 4
- 229910006160 GeF4 Inorganic materials 0.000 abstract 1
- -1 boron ions Chemical class 0.000 abstract 1
- QUZPNFFHZPRKJD-UHFFFAOYSA-N germane Chemical compound [GeH4] QUZPNFFHZPRKJD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052986 germanium hydride Inorganic materials 0.000 abstract 1
- 230000003647 oxidation Effects 0.000 abstract 1
- 238000007254 oxidation reaction Methods 0.000 abstract 1
- PPMWWXLUCOODDK-UHFFFAOYSA-N tetrafluorogermane Chemical compound F[Ge](F)(F)F PPMWWXLUCOODDK-UHFFFAOYSA-N 0.000 abstract 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007772 electrode material Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- ZPPUVHMHXRANPA-UHFFFAOYSA-N germanium titanium Chemical compound [Ti].[Ge] ZPPUVHMHXRANPA-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/28008—Making conductor-insulator-semiconductor electrodes
- H01L21/28017—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
- H01L21/28026—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
- H01L21/28035—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/28—Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
- H01L21/283—Deposition of conductive or insulating materials for electrodes conducting electric current
- H01L21/285—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation
- H01L21/28506—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers
- H01L21/28512—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic System
- H01L21/28525—Deposition of conductive or insulating materials for electrodes conducting electric current from a gas or vapour, e.g. condensation of conductive layers on semiconductor bodies comprising elements of Group IV of the Periodic System the conductive layers comprising semiconducting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32139—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/40—Electrodes ; Multistep manufacturing processes therefor
- H01L29/43—Electrodes ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/49—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET
- H01L29/4916—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen
Abstract
Description
본 발명은 반도체소자의 게이트전극 형성방법에 관한 것으로, 보다 상세하게 게이트절연막 상부에 게이트전극으로 폴리-실리콘저마늄(poly-SiGe)을 형성함으로써 소자의 전기적 특성을 향상시키는 반도체소자의 게이트전극 형성방법에 관한 것이다.BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a method for forming a gate electrode of a semiconductor device, and more particularly, to forming a gate electrode of a semiconductor device, by forming poly-silicon germanium (poly-SiGe) as a gate electrode on a gate insulating layer to improve electrical characteristics of the device. It is about a method.
반도체소자가 고집적화되어 감에 따라 모스 전계효과 트랜지스터(MetalOxide Semiconductor Field Effect Transistor; 이하 MOS FET라 칭함)의 게이트 전극도 폭이 줄어들고 있으나, 게이트 전극의 폭이 N배 줄어들면 게이트 전극의 전기 저항이 N배 증가되어 반도체소자의 동작 속도를 떨어뜨리는 문제점이 있다.As semiconductor devices become more integrated, the gate electrode of a metal oxide semiconductor field effect transistor (hereinafter referred to as a MOS FET) is decreasing in width, but when the width of the gate electrode is reduced by N times, the electrical resistance of the gate electrode is reduced to N. There is a problem that decreases the operation speed of the semiconductor device by doubling.
현재 반도체소자의 제조방법 중 게이트전극 재료로 사용되고 있는 폴리실리콘층은 게이트전극 재료로서 우수한 물리적 특성을 갖추고 있어서 현재까지 많이 사용되어 오고 있다.Currently, polysilicon layers used as gate electrode materials in semiconductor device manufacturing methods have been widely used to date because they have excellent physical properties as gate electrode materials.
그러나, 소자가 고집적화 되어 감에 따라 매몰채널(barried channel)에 기인한 짧은 채널효과(short channel effect)와 이로 인한 DIBL(drain induced barrier lowering)현상 증가 및 문턱 전압 불안정 현상이 나타난다. 또한, 폴리-게이트 공핍효과(poly-gate depletion effect) 및 게이트산화막을 통한 채널 영역으로의 보론 도펀트 침투 현상으로 소자의 전기적 특성이 열화된다고 알려져 있다.However, as devices become more integrated, short channel effects due to buried channels, increased drain barrier barrier (DIBL), and threshold voltage instability occur. In addition, the poly-gate depletion effect and the boron dopant penetration into the channel region through the gate oxide film are known to degrade the electrical characteristics of the device.
상기와 같이 종래기술에 따른 반도체소자의 게이트전극 형성방법은, 열산화막 상부에 형성되는 폴리-실리콘저마늄(poly-SiGe)막은 접착성(adhesion)과 핵생성(nucleation)이 좋지 않기 때문에 열산화막 상부에 사일렌가스(SiH4)를 이용하여 매우 얇은 폴리실리콘 시드(seed)층을 증착한 후 이후 이 시드층 상부에 폴리실리콘저마늄을 증착하는 것이었다. 이 경우, 열산화막 상부에 실리콘층이 증착되어 그 계면 상태가 열산화막/실리콘기판 계면보다 다소 열화될 뿐만 아니라, 후속 열공정 시 보론이 폴리실리콘 시드층을 통해 채널영역으로 더 빨리 침투한다는 문제점이 있다.As described above, in the method of forming a gate electrode of a semiconductor device according to the related art, since a poly-silicon germanium (poly-SiGe) film formed on the thermal oxide film is poor in adhesion and nucleation, the thermal oxide film is poor. A very thin polysilicon seed layer was deposited on top of xylene gas (SiH 4 ) and then polysilicon germanium was deposited on the seed layer. In this case, the silicon layer is deposited on top of the thermal oxide film so that the interface state is slightly degraded than the thermal oxide / silicon substrate interface, and in the subsequent thermal process, boron penetrates into the channel region through the polysilicon seed layer more quickly. have.
본 발명은 상기한 종래 기술의 문제점을 해결하기 위하여, 게이트절연막의 표면을 저메인가스로 환원시켜 폴리실리콘 시드층을 형성하고, 상기 폴리실리콘 시드층 상부에 폴리-실리콘저마늄층을 형성한 다음, 게이트전극 마스크를 이용하여 패터닝함으로써 상기 폴리-실리콘저마늄층을 균일하게 형성하고, 그에 따른 소자의 동작 특성 및 신뢰성을 향상시키는 반도체소자의 게이트전극 형성방법을 제공하는데 그 목적이 있다.The present invention, in order to solve the above problems of the prior art, to form a polysilicon seed layer by reducing the surface of the gate insulating film with a low main gas, a poly-silicon germanium layer formed on the polysilicon seed layer, the gate It is an object of the present invention to provide a method for forming a gate electrode of a semiconductor device by uniformly forming the poly-silicon germanium layer by patterning using an electrode mask, thereby improving operating characteristics and reliability of the device.
도 1 은 본 발명에 따른 반도체소자의 게이트전극 형성방법에 의한 공정 단면도.1 is a cross-sectional view of a process of forming a gate electrode of a semiconductor device according to the present invention;
< 도면의 주요부분에 대한 부호의 설명 ><Description of Symbols for Major Parts of Drawings>
11 : 반도체기판 13 : 게이트절연막패턴11: semiconductor substrate 13: gate insulating film pattern
15 : 폴리실리콘 시드층 패턴 17 : 폴리-실리콘저마늄층패턴15 polysilicon seed layer pattern 17 poly-silicon germanium layer pattern
19 : LDD영역 21 : 절연막 스페이서19: LDD region 21: insulating film spacer
23 : 소오스/드레인영역23: source / drain area
이상의 목적을 달성하기 위한 본 발명에 따른 반도체소자의 게이트전극 형성방법은,A method of forming a gate electrode of a semiconductor device according to the present invention for achieving the above object,
반도체기판의 표면을 열산화시켜 게이트절연막을 형성하는 공정과,Thermally oxidizing the surface of the semiconductor substrate to form a gate insulating film;
상기 게이트절연막의 표면을 저메인가스로 환원시켜 폴리실리콘 시드층을 형성하는 공정과,Reducing the surface of the gate insulating film with a low main gas to form a polysilicon seed layer;
상기 폴리실리콘 시드층 상부에 폴리-실리콘저마늄층을 형성하는 공정과,Forming a poly-silicon germanium layer on the polysilicon seed layer;
상기 폴리-실리콘저마늄층, 폴리실리콘 시드층 및 게이트절연막을 게이트전극 마스크를 식각마스크로 이용한 식각공정으로 패터닝하여 폴리-실리콘저마늄층패턴과 폴리실리콘 시드층 패턴으로 되는 게이트전극과 게이트절연막패턴의 적층구조를 형성하는 공정을 포함하는 것을 특징으로 한다.The poly-silicon germanium layer, the polysilicon seed layer, and the gate insulating layer are patterned by an etching process using a gate electrode mask as an etch mask, thereby stacking a gate electrode and a gate insulating layer pattern, the poly-silicon germanium layer pattern and the polysilicon seed layer pattern. It is characterized by including a step of forming a structure.
이하, 첨부된 도면을 참고로 하여 본 발명을 상세히 설명한다.Hereinafter, the present invention will be described in detail with reference to the accompanying drawings.
도 1 은 본 발명에 따른 반도체소자의 게이트전극 형성방법에 의한 공정 단면도이다.1 is a cross-sectional view illustrating a process of forming a gate electrode of a semiconductor device according to the present invention.
먼저, 반도체기판(11)의 표면을 열산화시켜 게이트절연막을 형성한다.First, the surface of the semiconductor substrate 11 is thermally oxidized to form a gate insulating film.
다음, 상기 게이트절연막의 표면에 저메인가스를 주입하여 1 ∼ 50Å 두께의 폴리-실리콘 시드층을 형성한다. 이때, 상기 저메인가스는 400 ∼ 600℃의 온도에서 주입되고, 상기 게이트절연막에서 저마늄이 형성되기 전까지 주입된다. 그리고, 상기 저메인가스는 GeH4또는 GeF4가스가 사용되고, 수소 가스 내에 0.1 ∼ 100%의 저마늄이 함유되어 있는 가스이다. 상기 저메인가스는 SiO2로 구성되는 게이트절연막(13)을 하기와 같은 화학식에 의한 환원작용으로 폴리실리콘 시드층을 형성한다.Next, a low main gas is injected into the surface of the gate insulating layer to form a polysilicon seed layer having a thickness of 1 to 50 kHz. At this time, the low mages is implanted at a temperature of 400 ~ 600 ℃, is injected until the germanium is formed in the gate insulating film. The low main gas is a gas in which GeH 4 or GeF 4 gas is used and 0.1-100% germanium is contained in hydrogen gas. The low mages forms a polysilicon seed layer by reducing the gate insulating film 13 composed of SiO 2 by the following chemical formula.
GeH4(g) + SiO2-> H2O(g) + GeO(g) +Si + H2(g)GeH 4 (g) + SiO 2- > H 2 O (g) + GeO (g) + Si + H 2 (g)
그 다음, 상기 폴리실리콘 시드층 상부에 폴리-실리콘저마늄층을 형성한다. 상기 폴리-실리콘저마늄층은 450 ∼ 650℃의 온도에서 SiH4또는 Si2H6의 실리콘 소오스 가스와 GeH4또는 GeF4저마늄 소오스 가스를 사용하여 형성된다. 이때, 상기 실리콘 소오스 가스는 수소 가스에 10 ∼ 100%의 실리콘이 함유되어 있고, 상기 저마늄 소오스 가스는 수소 가스에 10 ∼ 100%의 저마늄이 함유되어 있으며, 상기 폴리-실리콘저마늄층은 10 ∼ 70%의 저마늄을 함유하고 있다. 그리고, 상기 폴리-실리콘저마늄층은 LPCVD(low pressure chemical vapor deposition), VLPCVD(very low pressure chemical vapor deposition), PE-VLPCVD(plasma enhanced-very low pressure chemical vapor deposition), UHVCVD(hltrahigh vacuum chemical vapordeposition), RTCVD(rapid thermal chemical vapor deposition) 또는 APCVD(atmosphere chemical vapor deposition)방법으로 형성된다. 또한, 상기 폴리-실리콘저마늄층은 이온주입공정을 이용한 익스-시튜(ex-situ)방법으로 도핑되거나 도펀트 가스를 이용한 인-시튜(in-Situ)방법으로 도핑된다.Next, a poly-silicon germanium layer is formed on the polysilicon seed layer. The poly-silicon germanium nyumcheung is formed using SiH 4 or the silicon source gas and the GeH 4 or GeF 4 titanium germanium source gas of Si 2 H 6 at a temperature of 450 ~ 650 ℃. In this case, the silicon source gas contains 10 to 100% silicon in hydrogen gas, the germanium source gas contains 10 to 100% germanium in hydrogen gas, the poly-silicon germanium layer is 10 It contains 70% of germanium. The poly-silicon germanium layer may include low pressure chemical vapor deposition (LPCVD), very low pressure chemical vapor deposition (VLPCVD), plasma enhanced-very low pressure chemical vapor deposition (PE-VLPCVD), and high high vacuum chemical vapor deposition (UHVCVD). It is formed by rapid thermal chemical vapor deposition (RTCVD) or atmosphere chemical vapor deposition (APCVD). In addition, the poly-silicon germanium layer is doped by an ex-situ method using an ion implantation process or doped by an in-situ method using a dopant gas.
다음, 게이트전극 마스크를 식각마스크로 이용하여 상기 폴리-실리콘저마늄층, 폴리실리콘 시드층 및 게이트절연막을 패터닝하여 폴리-실리콘저마늄층패턴 (17)과 폴리실리콘 시드층패턴(15)의 적층구조로 되는 게이트전극과 게이트절연막패턴(13)을 형성한다.Next, the poly-silicon germanium layer, the polysilicon seed layer, and the gate insulating layer are patterned using a gate electrode mask as an etch mask to form a laminate structure of the poly-silicon germanium layer pattern 17 and the polysilicon seed layer pattern 15. The gate electrode and the gate insulating film pattern 13 are formed.
다음, 상기 구조를 LDD산화하여 상기 게이트전극 양측의 반도체기판(11)에 LDD 절연막(18)을 형성한다.Next, the structure is LDD-oxidized to form an LDD insulating film 18 on the semiconductor substrate 11 on both sides of the gate electrode.
그 다음, 상기 게이트전극 양측의 반도체기판(11)에 저농도의 불순물을 이온주입하여 LDD영역(19)을 형성한다.Next, a low concentration of impurities are implanted into the semiconductor substrate 11 on both sides of the gate electrode to form the LDD region 19.
다음, 상기 게이트전극 및 게이트절연막패턴(13)의 측벽에 절연막 스페이서 (21)를 형성한다.Next, an insulating film spacer 21 is formed on sidewalls of the gate electrode and the gate insulating film pattern 13.
그 다음, 상기 절연막 스페이서(21)의 양측 반도체기판(11)에 고농도의 불순물을 이온주입하여 소오스/드레인영역(23)을 형성한다. (도 1 참조)Subsequently, a high concentration of impurities are ion-implanted into both semiconductor substrates 11 of the insulating film spacer 21 to form the source / drain regions 23. (See Figure 1)
이상에서 설명한 바와 같이 본 발명에 따른 반도체소자의 게이트전극 형성방법은, 반도체기판의 표면을 열산화시켜 게이트절연막을 형성하고, 상기 게이트절연막의 표면을 저메인(GeH4)가스로 환원시켜 폴리실리콘 시드(seed)층을 형성한 다음, 폴리-실리콘저마늄층을 균일하게 형성한 후 게이트전극 마스크를 이용한 식각공정으로 게이트전극을 형성하고, LDD영역 및 소오스/드레인영역을 형성하여 트랜지스터를 형성함으로써 게이트절연막과 폴리-실리콘저마늄층 간의 계면 특성을 향상시키고, 보론 도펀트(boron dopant)의 침투 현상을 억제하여 게이트전극의 신뢰성 및 동작 특성을 향상시키는 이점이 있다.As described above, in the method of forming a gate electrode of a semiconductor device according to the present invention, a polysilicon seed is formed by thermally oxidizing a surface of a semiconductor substrate to form a gate insulating film, and reducing the surface of the gate insulating film with low main (GeH 4 ) gas. After the (seed) layer is formed, the poly-silicon germanium layer is uniformly formed, the gate electrode is formed by an etching process using a gate electrode mask, and the LDD region and the source / drain region are formed to form a transistor to form a gate insulating film. The interfacial properties between the polysilicon germanium layer and the boron dopant may be suppressed to improve the reliability and operation characteristics of the gate electrode.
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