KR20020042546A - A glass plate with a color pattern and the manufacturing method - Google Patents

A glass plate with a color pattern and the manufacturing method Download PDF

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KR20020042546A
KR20020042546A KR1020020016031A KR20020016031A KR20020042546A KR 20020042546 A KR20020042546 A KR 20020042546A KR 1020020016031 A KR1020020016031 A KR 1020020016031A KR 20020016031 A KR20020016031 A KR 20020016031A KR 20020042546 A KR20020042546 A KR 20020042546A
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plate glass
glass
etching
layer
pattern
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KR1020020016031A
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Korean (ko)
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온재민
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온재민
정재석
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Priority to KR1020020016031A priority Critical patent/KR20020042546A/en
Publication of KR20020042546A publication Critical patent/KR20020042546A/en

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K13/00Etching, surface-brightening or pickling compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/40Coatings comprising at least one inhomogeneous layer
    • C03C2217/43Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
    • C03C2217/46Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
    • C03C2217/48Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase having a specific function
    • C03C2217/485Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/70Properties of coatings
    • C03C2217/72Decorative coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/10Deposition methods
    • C03C2218/11Deposition methods from solutions or suspensions
    • C03C2218/118Deposition methods from solutions or suspensions by roller-coating

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

PURPOSE: A manufacturing method of color patterned plate glass through etching is provided, which is characterized by using aqueous natural mixture(flour, glue, potatoes, etc.) instead of conventional chemicals. Accordingly, the method forms various patterns on glass easily and gives no peeling-off pattern. CONSTITUTION: The manufacturing method comprises the steps of: preparing aqueous naturals(S10) by mixing 50-60wt.% of flour, 28-35wt.% of glue, 8-12wt.% of potato juice, and 8-12wt.% of sweet potato; forming a natural mixture layer(S20) by screen printing natural mixture on the surface of a plate glass in a certain pattern; thermal drying(S30) the plate glass at 70-100deg.C, firstly; forming an etched face(S40) on the surface of the plate glass with no natural mixture layer by etching the dried glass with an automatic sanding machine; washing the glass(S50) to remove natural mixture; forming a paint layer(S60) on the upper part of the etched face by spreading a paint over the surface of the plate glass with a roller; thermal drying(S70) the plate glass at 50-70deg.C, secondly; washing the glass(S80).

Description

칼라 무늬가 형성된 판유리 및 그 제조방법{A glass plate with a color pattern and the manufacturing method}A glass plate with a color pattern and the manufacturing method

본 발명은 칼라 무늬가 형성된 판유리 및 그 제조방법에 관한 것으로, 더욱상세하게는 각종 인테리어용으로 사용되는 판유리의 표면에, 밀가루, 아교, 감자, 고구마 등의 천연재를 혼합한 수성약품을 이용하여 특정문양의 에칭(etching)면을 형성시키고, 에칭면 상부에 다양한 색상의 안료를 도포하여 안료층을 형성시킴으로써, 다양한 도안의 무늬를 용이하게 형성시킬 수 있어 창작성 및 장식성이 우수하도록 함과 동시에, 수분이나 대기에 접촉되어도 칼라 무늬가 박리되지 않는 등 외부환경에 대한 내구성이 우수하도록 할 뿐만 아니라, 화학약품을 이용하지 않음으로써 환경 오염을 방지할 수 있도록 한 것이다.The present invention relates to a plate glass with a color pattern and a method of manufacturing the same, and more particularly, by using an aqueous chemical agent mixed with natural materials, such as flour, glue, potatoes, sweet potatoes, on the surface of the plate glass used for various interiors By forming an etching surface of a specific pattern and applying a pigment of various colors to the upper surface of the etching surface to form a pigment layer, it is possible to easily form a pattern of a variety of patterns, while creating excellent creativity and decoration, Not only does the color pattern do not peel off when it comes into contact with moisture or the atmosphere, but also provides excellent durability to the external environment, and also prevents environmental pollution by not using chemicals.

판유리는 중세시대부터 제조되었고, 예전에는 사원 건축용재로서 특별히 이용되었으나 19세기 중반 이후 탱크가마에 의해 대량 생산이 가능해지면서부터 널리 사용되었다. 초기의 판유리는 용융(鎔融) 도가니에서 철봉 끝에 유리덩어리를 말아올려 회전시키면서 원판상으로 하여 판유리을 잘라낸다든가 틀에 대고 불어서 원통으로 만들어 사용하였으며, 그 후 철판 위에서 롤(roll)로 압연하는 방법, 또는 탱크가마에서 넘쳐흐르는 유리용액을 서로 반대로 회전하는 롤로 압연하면서 연속적으로 판유리를 제조하는 방법 등이 개발되었다.Plate glass has been manufactured since the Middle Ages, and was formerly used as a temple building material, but has been widely used since the mid-19th century when mass production was possible by tank kilns. Initially, the plate glass was rolled up from the melting crucible to the end of the iron rod and rolled to form a plate, cut into a plate, or blown into a frame to make a cylinder. Or a method of continuously producing a plate glass while rolling the glass solution overflowing from the tank kiln by rotating rolls opposite to each other has been developed.

근래의 판유리는 원료조합, 용해, 청징, 성형, 서랭 및 가공의 공정을 거쳐 제조되며, 필요에 따라 표면을 가공처리함으로써 표면을 거칠게 하여 불투명하게 하거나, 착색제를 이용하여 착색하여 제조한다.In recent years, plate glass is manufactured through a process of raw material combination, melting, clarification, molding, slow cooling, and processing. If necessary, the surface glass is roughened to make the surface opaque or colored by using a colorant.

투명유리는 외부의 시선이나 빛으로부터 보호받을 수 없어 욕실 및 화장실의 칸막이로 이용하거나, 사무실의 칸막이 또는 창으로 이용할 시에 결점을 가지고 있어, 투명유리의 표면을 거칠게 하거나 무늬를 형성시킴으로써, 판유리의 반대편으로부터 투시를 차단하여 판유리 안쪽의 프라이버시를 보호할 수 있도록 하였다.Transparent glass cannot be protected from external eyes and light, and it has defects when used as partitions in bathrooms and toilets, or as partitions or windows in offices. Perspectives were blocked from the other side to protect the privacy inside the panes.

상기 판유리의 표면을 거칠게 하는 방법에는 물리적 방법과 화학적 방법이 있으며, 그 물리적 방법으로는 판유리의 무늬를 성형할 부분을 고압으로 분사되는 모래로 타격하여 미세한 요철면을 형성함으로써 필요한 무늬를 성형하는 샌드블라스팅(sandblasting)방법이 사용되고 있으며, 화학적 방법으로는 용제 중에 플루오르화수소산(hydrofluoric acid)을 함유하는 잉크로써 유리면에 필요한 무늬를 실크 스크린 인쇄하여 플루오르화수소산(hydrofluoric acid)이 판유리의 표면을 부식시켜 무늬를 형성시키는 에칭방법이 사용되고 있다.There are physical and chemical methods for roughening the surface of the plate glass, and the physical method includes sand for forming a pattern required by forming a fine uneven surface by striking a portion to form a pattern of the plate glass with sand injected at high pressure. The blasting method is used, and the chemical method is an ink containing hydrofluoric acid in a solvent, and silk-screen printing a pattern required on the glass surface so that hydrofluoric acid corrodes the surface of the plate glass. An etching method for forming a pattern is used.

상기 샌드블라스팅방법은 유리면의 무늬가 성형되지 아니하는 부분을 보호필름으로 가리고 원하는 무늬 부분만이 모래의 타격에 노출되도록 하는 과정을 거치는 것이므로, 보호필름에서 무늬부에 해당하는 부분을 수작업 등으로 오려내는 작업이 선행되어야 함에 따라 무늬 성형 공정이 복잡하고 정교한 무늬의 형성이 불가능하여 제품생산성이 크게 떨어지며, 성형된 무늬에 있어서도 요철면이 비교적 거칠어 무늬면이 매끄럽지 못하고 먼지 등의 이물질이 부착되기 쉬우므로 상품가치가 떨어지는 문제점이 있었다.The sand blasting method is to cover the portion of the glass surface is not molded with a protective film, and only the desired pattern portion is exposed to the impact of sand, so the portion corresponding to the pattern portion in the protective film is cut out by hand or the like. As the work must be done in advance, the pattern forming process is complicated and the formation of elaborate patterns is impossible, and the product productivity is greatly reduced. There was a problem of falling commodity value.

화학에칭방법은 실크스크린 인쇄방법을 사용함에 따라 정교한 무늬의 형성이 가능하고 생산성을 크게 향상시킬 수 있으며 무늬부를 비교적 매끄럽게 형성할 수 있어 상품가치를 제고시킬 수 있으나, 인쇄 부식 완료 후 유리면에는 강산으로서 환경 오염물질인 플루오르화수소산이 그대로 남아있어 세척공정을 반드시 거쳐야함에 따라 플루오르화수소산이 포함된 산업폐수가 대량으로 발생함으로써 폐수처리비용의 과중한 부담으로 인하여 그대로 방류시켜 환경오염을 발생시키는 등의 문제점이 있었다.As the chemical etching method is used for silk screen printing, it is possible to form elaborate patterns, greatly improve productivity, and to form product parts relatively smoothly, thereby increasing the value of products. Since hydrofluoric acid, an environmental pollutant, remains as it is, it must go through a washing process, resulting in a large amount of industrial wastewater containing hydrofluoric acid, which is discharged as it is due to the heavy burden of wastewater treatment costs. .

상기와 같은 문제점의 해결을 위해 선출원 된 특허공보 제 1992-2632호의 '다색도 부분 칼라경을 갖는 장식용 판유리의 가공방법'은, 폴리비닐알코올과 메틸알코올 및 염료를 이용하여 칼라층을 형성시킴으로써 다색도 부분 칼라경을 갖도록 하였으나, 화학약품의 사용으로 인하여 환경 오염을 유발시키는 문제점을 해결할 수 없었으며, 또 다른 선출원 된 특허공보 제 224080호는 '판유리의 칼라에칭방법'에 관한 것으로, 판유리에 보호필름을 부착하고 문양대로 커팅한 후 고무층을 적층형성시킴으로써 무늬를 형성시켰으나, 제조공정이 복잡하고 비용이 고가이므로 실용화하기에는 어려움이 있었다.Patent Document No. 1992-2632, 'Processing method of decorative plate glass having a multi-color partial color diameter', for solving the above problems, is formed by forming a color layer using polyvinyl alcohol, methyl alcohol and dyes Although it has a partial collar diameter, the problem of causing environmental pollution due to the use of chemicals could not be solved, and another prior patent publication No. 224080 relates to a 'color etching method of plate glass' and protects the plate glass. After attaching the film and cutting it to a pattern, a rubber layer was laminated to form a pattern. However, since the manufacturing process was complicated and expensive, it was difficult to put it to practical use.

따라서, 본 발명의 목적은 단순히 표면을 불투명하게 에칭한 종래의 판유리가 지닌 제반 문제점을 해결하기 위하여, 판유리의 표면에 밀가루, 아교, 감자, 고구마 등의 천연재를 혼합한 수성약품을 이용하여 특정문양의 에칭(etching)면을 형성시키고, 에칭면 상부에 다양한 색상의 안료를 도포하여 안료층을 형성시킴으로써, 다양한 도안의 무늬를 용이하게 형성시킬 수 있어 장식성이 우수하도록 함과 동시에, 수분이나 대기에 접촉되어도 칼라 무늬가 박리되지 않는 등 외부환경에 대한 내구성이 우수하도록 할 뿐만 아니라, 화학약품을 이용하지 않음으로써 환경 오염을 방지할 수 있도록 하는 칼라 무늬가 형성된 판유리 및 그 제조방법을 제공함에 있다.Accordingly, an object of the present invention is to simply solve the problems of the conventional glass plate by etching the surface opaquely, using a water-based chemicals mixed with natural materials such as flour, glue, potato, sweet potato on the surface of the glass plate By forming an etching surface of the pattern and applying a pigment of various colors to the upper surface of the etching surface to form a pigment layer, it is possible to easily form a pattern of a variety of patterns to improve the decoration and at the same time moisture or air The present invention provides a plate-shaped plate glass and a method of manufacturing the same, which not only exfoliate the color pattern even when it is in contact with the external environment, but also prevent the environmental pollution by not using chemicals. .

도 1은 본 발명에 의한 칼라 무늬가 형성된 판유리의 제조공정도.1 is a manufacturing process diagram of the plate glass formed with a color pattern according to the present invention.

도 2 a, b, c, d는 본 발명에 의한 칼라 무늬가 형성된 판유리의 공정상태를 나타낸 단면도.Figure 2 a, b, c, d is a cross-sectional view showing a process state of the plate glass with a colored pattern according to the present invention.

도 2 a는 수성약품이 스크린인쇄된 상태의 단면도.Figure 2 a is a cross-sectional view of the aqueous drug screen printing.

도 2 b는 에칭된 상태의 단면도.2B is a sectional view of the etched state.

도 2 c는 세척되어 수성약품이 제거된 상태의 단면도.Figure 2 c is a cross-sectional view of the state in which the aqueous drug is removed by washing.

도 2 d는 안료가 도포된 상태의 단면도.Figure 2d is a cross-sectional view of the pigment applied state.

도 3은 본 발명에 의한 칼라 무늬가 형성된 판유리의 사시도.Figure 3 is a perspective view of a plate glass with a color pattern according to the present invention.

* 도면의 주요부분에 대한 부호의 설명 *Explanation of symbols on the main parts of the drawings

1: 판유리2: 수성약품층1: plate glass 2: aqueous chemical layer

3: 안료층 11: 에칭면3: pigment layer 11: etching surface

상기한 목적을 달성하기 위하여 본 발명의 칼라 무늬가 형성된 판유리(A) 및 그 제조방법은, 밀가루 50∼60중량%, 아교 28∼35중량%, 감자즙 8∼12중량% 및 고구마즙 8∼12중량%의 배합비율로 혼합하여 수성약품을 제조하는 단계(S10):와 혼합한 수성약품을 판유리(1)의 표면에 특정문양으로 스크린인쇄하여 수성약품층(2)을 형성시키는 단계(S20):와 수성약품층(2)이 형성된 판유리(1)를 70∼100℃의 온도범위에서 1차 열건조하는 단계(S30):와 건조된 판유리(1)를 자동샌딩기계로 에칭함으로써 수성약품층이(2)이 형성되지 아니한 판유리(1)의 표면에 에칭면(11)을 형성시키는 단계(S40)와: 에칭면(11)이 형성된 판유리(1)를 세척하여 수성약품층(2)을 제거하는 단계(S50):와 수성약품층(2)이 제거된 판유리(1)의 표면에, 롤을 이용하여 안료를 도포함으로써 에칭면(11)의 상부에 안료층(3)을 형성시키는 단계(S60):와 안료층(3)이 형성된 판유리(1)를 50∼70℃의 온도범위로 2차 열건조하는 단계(S70): 및 2차 열건조된 판유리(1)를 세척하는 단계(S80)로 제조되는 것을 특징으로 한다.In order to achieve the above object, the plate glass (A) formed with the color pattern of the present invention and its manufacturing method are 50 to 60% by weight of flour, 28 to 35% by weight of glue, 8 to 12% by weight of potato juice and 8 to sweet potato juice. Step 12 to prepare an aqueous drug by mixing at a blending ratio of 12% by weight (S10): the step of forming a water-based drug layer (2) by screen printing the mixed aqueous drug with a specific pattern on the surface of the glass (1) (S20) ): And primary heat-drying of the plate glass (1) formed with the aqueous chemical layer (2) at a temperature range of 70 ~ 100 ℃ (S30): and the aqueous plate chemicals by etching the dried plate glass (1) with an automatic sanding machine Forming an etching surface 11 on the surface of the plate glass 1 on which the layer 2 is not formed (S40) and: washing the plate glass 1 on which the etching surface 11 is formed, thereby removing the aqueous chemical layer 2 Removing step (S50): and the surface of the plate glass (1) from which the aqueous chemical layer (2) has been removed, by applying a pigment using a roll on the upper surface of the etching surface (11) Step (S60) of forming the pigment layer (3): and secondary heat drying step (S70) of the plate glass (1) on which the pigment layer (3) is formed in a temperature range of 50 to 70 ℃: and secondary heat-drying Characterized in that it is manufactured in the step (S80) of washing the plate glass (1).

이하 본 발명이 속하는 기술분야에서 통상의 지식을 가진자가 본 발명을 용이하게 실시할 수 있을 정도로 본 발명의 바람직한 실시예를 첨부된 도면을 참조하여 상세하게 설명하면 다음과 같다.Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the accompanying drawings such that those skilled in the art can easily implement the present invention.

첨부도면 중 도 1은 본 발명에 의한 칼라 무늬가 형성된 판유리의 제조공정도이고, 도 2 a, b, c, d는 본 발명에 의한 칼라 무늬가 형성된 판유리의 공정상태를 나타낸 단면도로서, 도 2 a는 수성약품이 스크린인쇄된 상태의 단면도이고, 도2 b는 에칭된 상태의 단면도이며, 도 2 c는 세척되어 약품이 제거한 상태의 단면도이고, 도 2 d는 안료가 도포된 상태의 단면도이며, 도 3은 본 발명에 의한 칼라 무늬가 형성된 판유리의 사시도이다.Figure 1 of the accompanying drawings is a manufacturing process diagram of a plate glass with a colored pattern according to the present invention, Figure 2 a, b, c, d is a cross-sectional view showing a process state of the plate glass with a colored pattern according to the present invention, Figure 2 a 2 is a cross-sectional view of the water-based drug screen printing state, Figure 2b is a cross-sectional view of the etched state, Figure 2c is a cross-sectional view of the drug is removed, Figure 2d is a cross-sectional view of the pigment applied state, 3 is a perspective view of a plate glass with a color pattern according to the present invention.

밀가루 50∼60중량%, 아교 28∼35중량%, 감자즙 8∼12중량% 및 고구마즙 8∼12중량%의 배합비율로 혼합하여 수성약품을 제조하는 단계(S10)에서, 상기 밀가루는 글루텐 성분을 포함하므로 점착성을 가지므로 수성약품의 응고를 용이하게 하고, 감자와 고구마는 삼베헝겊이나 거즈를 이용하여 즙을 내어 사용하는 것으로 그 방법을 제한하는 것은 아니며 이 또한 수성약품의 응고를 용이하게 하는 것이며, 아교는 동물의 가죽, 힘줄, 연골 등을 구성하는 천연 단백질인 콜라겐을 뜨거운 물로 처리하면 얻어지는 유도 단백질의 일종으로, 2∼3% 이상의 농도에서는 실온(室溫)에서 탄성이 있는 겔(gel)이 되는 성질을 가져 수성약품의 응고를 돕는다.50 to 60% by weight of flour, 28 to 35% by weight of glue, 8 to 12% by weight of potato juice and 8 to 12% by weight of sweet potato juice in the step of preparing an aqueous drug (S10), the flour is gluten Because it contains ingredients, it has a stickiness to facilitate coagulation of water-based medicines. Potatoes and sweet potatoes are juiced using burlap cloth or gauze, and the method is not limited thereto. Glue is a kind of derived protein obtained by treating collagen, a natural protein constituting animal skins, tendons, cartilage, etc. with hot water. A gel that is elastic at room temperature at a concentration of 2-3% or more. It has the property of becoming gel) to help the coagulation of aqueous drugs.

혼합한 수성약품을 판유리(1)의 표면에 특정문양으로 스크린인쇄하여 수성약품층(2)을 형성시키는 단계(S20)는, 수성약품층(2)을 형성시킴으로써 에칭시 수성약품층(2)은 에칭되지 않도록 하고 수성약품층(2)이 형성되지 아니한 판유리(1)의 표면은 에칭되도록 한 것이다.Forming the aqueous chemical layer (2) by screen-printing the mixed aqueous chemicals on the surface of the plate glass (1) in a specific pattern (S20), the aqueous chemical layer (2) during etching by forming the aqueous chemical layer (2) Silver is not etched and the surface of the plate glass 1 in which the aqueous chemical layer 2 is not formed is etched.

상기 인쇄방법으로는 스크린인쇄 방법을 이용하여 다양하면서도 정교한 무늬의 형성이 가능하게 하는 것이 바람직하나 반드시 이를 제한하는 것은 아니다.As the printing method, it is preferable to use a screen printing method to enable various and sophisticated pattern formation, but is not necessarily limited thereto.

수성약품층(2)이 형성된 판유리(1)를 70∼100℃의 온도범위에서 1차 열건조하는 단계(S30)는, 판유리(1)의 표면에 인쇄된 수성약품층(2)을 열건조하여 에칭시에 샌딩되지 않도록 하는 단계로서, 건조 공정상 시간과 비용을 고려할 때 70∼100℃의 온도범위에서 짧은 시간내에 열건조하는 것이 바람직하나, 이를 반드시 제한하는 것은 아닌 것으로 자연건조도 가능함은 물론이다.The primary heat drying step (S30) of the plate glass 1 on which the aqueous chemical layer 2 is formed at a temperature range of 70 to 100 ° C., heat-drying the aqueous chemical layer 2 printed on the surface of the plate glass 1. As a step to prevent sanding during etching, it is preferable to heat dry within a short time in the temperature range of 70 ~ 100 ℃ considering the time and cost in the drying process, but it is not necessarily limited to this, it is possible to naturally dry Of course.

건조된 판유리(1)를 자동샌딩기계로 에칭함으로써 수성약품층이(2)이 형성되지 아니한 판유리(1)의 표면에 에칭면(11)을 형성시키는 단계(S40)는 수성약품층(2)이 형성되지 아니한 부분의 판유리(1)를 자동샌딩기계를 이용하여 에칭함으로써 에칭면(11)을 형성시키는 단계로, 자동샌딩기계로 에칭함에 따라 에칭시간 및 비용이 단축되도록 하고, 정교한 무늬를 형성시킬 수 있도록 한다.The step of forming the etching surface 11 on the surface of the plate glass 1 on which the aqueous chemical layer 2 is not formed by etching the dried plate glass 1 with an automatic sanding machine (S40) is the aqueous chemical layer 2 The step of forming the etching surface 11 by etching the plate glass (1) of the unformed portion by using an automatic sanding machine, to reduce the etching time and cost by etching with the automatic sanding machine, to form a fine pattern Make it work.

에칭면(11)이 형성된 판유리(1)를 세척하여 수성약품층(2)을 제거하는 단계(S50)는, 판유리(1)의 표면에 형성된 수성약품층(2)을 판유리(1)로부터 제거하기 위한 단계로서, 물을 이용하여 세척기로 세척한다.The step S50 of washing the plate glass 1 on which the etching surface 11 is formed to remove the aqueous chemical layer 2 removes the aqueous chemical layer 2 formed on the surface of the plate glass 1 from the plate glass 1. As a step to do this, it is washed with water using a washing machine.

수성약품층(2)이 제거된 판유리(1)의 표면에, 롤을 이용하여 안료를 도포함으로써 에칭면(11)의 상부에 안료층(3)을 형성시키는 단계(S60)는 판유리(1)의 표면에 안료를 도포함으로써 판유리(1)의 에칭면(11) 상부에는 안료가 도포되어 안료층(3)이 형성되도록 하는 것으로, 다양한 색상의 안료를 여러번 도포하여 여러 색상을 표현할 수 있도록 하며, 또한 에칭면(11)에 안료층(3)이 형성됨으로써 안료층(3)의 내구성이 강화될 수 있는 것이다.Step S60 of forming the pigment layer 3 on the etching surface 11 by applying the pigment to the surface of the plate glass 1 from which the aqueous chemical layer 2 has been removed is performed by using the roll (S60). By applying a pigment on the surface of the glass 1 to the upper surface of the etching surface 11, the pigment is applied to form a pigment layer (3), by applying a pigment of various colors several times to express a variety of colors, In addition, since the pigment layer 3 is formed on the etching surface 11, the durability of the pigment layer 3 can be enhanced.

안료층(3)이 형성된 판유리(1)를 50∼70℃의 온도범위로 2차 열건조하는 단계(S70)는 안료층(3)의 건조를 위한 단계로서, 그 건조방법 및 건조온도는 제한하지 않는다.The secondary heat drying step (S70) of the plate glass (1) on which the pigment layer (3) is formed in a temperature range of 50 ~ 70 ℃ (S70) is a step for drying the pigment layer (3), the drying method and drying temperature is limited I never do that.

2차 열건조된 판유리(1)를 세척하는 단계(S80)는, 안료의 도포 및 건조를 통하여 판유리(1)의 표면에 생성된 이물질을 제거하는 단계로서, 그 세척방법에는 제한을 두지 않는다.The step S80 of washing the secondary heat-dried plate glass 1 is a step of removing foreign substances generated on the surface of the plate glass 1 through the application and drying of the pigment, and the cleaning method is not limited.

따라서, 본 발명의 판유리(A)의 제조방법에 의하면 상기의 공정에 따른 연속무늬에칭방법을 이용하여 다양한 무늬가 형성된 판유리(A)를 규격화할 수 있는 것이다.Therefore, according to the manufacturing method of the plate glass A of this invention, it can standardize the plate glass A in which the various patterns were formed using the continuous pattern etching method which concerns on the said process.

상기 본 발명을 판유리(1)의 일측에만 칼라 무늬가 형성되게 한 것을 예로 하여 설명하였으나 반드시 이를 특정하는 것은 아니며, 예를 들면 판유리(1)의 양측 모두에 칼라 무늬가 형성되도록 할 수 있는 것으로, 본 발명의 범주와 사상을 벗어나지 않는 범위 내에서 다양한 변형실시가 가능함은 물론이다.Although the present invention has been described with an example in which a collar pattern is formed only on one side of the plate glass 1, it is not necessarily specified, and for example, the collar pattern may be formed on both sides of the plate glass 1. Various modifications may be made without departing from the scope and spirit of the invention.

이상의 설명에서 분명히 알 수 있듯이 본 발명의 칼라 무늬가 형성된 판유리 및 그 제조방법에 의하면, 판유리의 표면에 밀가루, 감자, 고구마 등의 천연재를 혼합한 수성약품을 이용하여 특정문양의 에칭(etching)면을 형성시키고 에칭면 상부에 다양한 색상의 안료를 도포하여 안료층을 형성시킴으로써, 다양한 도안의 무늬를 용이하게 형성시킬 수 있어 장식성이 우수함과 동시에 수분이나 대기에 접촉되어도 칼라 무늬가 박리되지 않는 등 외부환경에 대한 내구성 또한 우수하여 저렴한 비용으로 상품가치가 우수한 제품을 제조할 수 있을 뿐만 아니라, 연속무늬에칭을 이용하여 다양한 칼라 무늬의 판유리를 규격화 시킬수 있으며, 또한 제조시 화학약품을 이용하지 않음으로써 환경 오염을 방지할 수 있도록 하는 등의 유용한 효과를 제공한다.As is apparent from the above description, according to the present invention, the plate-shaped plate glass and a method of manufacturing the same include etching a specific pattern using an aqueous chemical agent mixed with natural materials such as flour, potato, and sweet potato on the surface of the plate glass. By forming a surface and applying a pigment of various colors on the etching surface to form a pigment layer, it is possible to easily form a pattern of a variety of patterns, excellent decoration, and does not peel off the color pattern even when contacted with moisture or air With excellent durability against external environment, it is possible not only to manufacture products with excellent product value at low cost, but also to standardize various colored glass plates using continuous pattern etching, and also by not using chemicals in manufacturing It provides useful effects such as preventing environmental pollution.

Claims (2)

칼라 무늬가 형성된 판유리(A)의 제조방법에 있어서,In the manufacturing method of the plate glass A in which the collar pattern was formed, 밀가루 50∼60중량%, 아교 28∼35중량%, 감자즙 8∼12중량% 및 고구마즙 8∼12중량%의 배합비율로 혼합하여 수성약품을 제조하는 단계(S10):와 혼합한 수성약품을 판유리(1)의 표면에 특정문양으로 스크린인쇄하여 수성약품층(2)을 형성시키는 단계(S20):와 수성약품층(2)이 형성된 판유리(1)를 70∼100℃의 온도범위에서 1차 열건조하는 단계(S30):와 건조된 판유리(1)를 자동샌딩기계로 에칭함으로써 수성약품층이(2)이 형성되지 아니한 판유리(1)의 표면에 에칭면(11)을 형성시키는 단계(S40)와: 에칭면(11)이 형성된 판유리(1)를 세척하여 수성약품층(2)을 제거하는 단계(S50):와 수성약품층(2)이 제거된 판유리(1)의 표면에, 롤을 이용하여 안료를 도포함으로써 에칭면(11)의 상부에 안료층(3)을 형성시키는 단계(S60):와 안료층(3)이 형성된 판유리(1)를 50∼70℃의 온도범위로 2차 열건조하는 단계(S70): 및 2차 열건조된 판유리(1)를 세척하는 단계(S80)로 이루어지는 것을 특징으로 하는 칼라 무늬가 형성된 판유리의 제조방법.50-60% by weight of flour, 28-35% by weight of glue, 8-12% by weight of potato juice and 8-12% by weight of sweet potato juice to prepare an aqueous drug (S10): mixed with the aqueous drug The screen printing on the surface of the plate glass 1 in a specific pattern to form an aqueous drug layer (S20): and the plate glass (1) on which the water-based chemical layer (2) is formed in a temperature range of 70 ~ 100 ℃ Primary thermal drying step (S30): and etching the dried plate glass 1 with an automatic sanding machine to form an etching surface 11 on the surface of the plate glass 1 on which the aqueous chemical layer 2 is not formed. Step S40 and: Cleaning the plate glass 1 on which the etching surface 11 is formed to remove the aqueous chemical layer 2 (S50): and the surface of the plate glass 1 from which the aqueous chemical layer 2 has been removed. Step (S60) of forming the pigment layer 3 on the etching surface 11 by applying the pigment using a roll, and the plate glass (1) on which the pigment layer 3 is formed at a temperature of 50 to 70 ℃ 2 as a range Primary heat-drying step (S70): and the second heat-drying plate glass (1) washing step (S80) of the manufacturing method of the plate-shaped plate glass, characterized in that consisting of. 제 1항의 제조방법으로 제조된 것을 특징으로 하는 칼라 무늬가 형성된 판유리.A plate glass with a collar pattern, characterized in that produced by the manufacturing method of claim 1.
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KR100889229B1 (en) * 2007-10-04 2009-03-16 김영임 Method for manufacturing coloring flat glass

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KR950002234A (en) * 1993-06-30 1995-01-04 세끼모또 타다히로 Voltage generator circuit for generating stable negative potential
KR960010586A (en) * 1994-09-27 1996-04-20 김은영 High Frequency Dielectric Self Composition and Manufacturing Method Thereof
KR19990033053A (en) * 1997-10-22 1999-05-15 김영환 Color etching method of glass plate
KR20010069260A (en) * 2000-12-08 2001-07-25 상 철 이 glass manufacturing method for decoration

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Publication number Priority date Publication date Assignee Title
KR850005992A (en) * 1984-02-08 1985-09-28 김중형 How to form frost on the surface of glass
KR950002234A (en) * 1993-06-30 1995-01-04 세끼모또 타다히로 Voltage generator circuit for generating stable negative potential
KR960010586A (en) * 1994-09-27 1996-04-20 김은영 High Frequency Dielectric Self Composition and Manufacturing Method Thereof
KR19990033053A (en) * 1997-10-22 1999-05-15 김영환 Color etching method of glass plate
KR20010069260A (en) * 2000-12-08 2001-07-25 상 철 이 glass manufacturing method for decoration

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