KR20020026227A - Ceramic Bonding Mechanics of yellow clay and Carbon black members. - Google Patents

Ceramic Bonding Mechanics of yellow clay and Carbon black members. Download PDF

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KR20020026227A
KR20020026227A KR1020020010695A KR20020010695A KR20020026227A KR 20020026227 A KR20020026227 A KR 20020026227A KR 1020020010695 A KR1020020010695 A KR 1020020010695A KR 20020010695 A KR20020010695 A KR 20020010695A KR 20020026227 A KR20020026227 A KR 20020026227A
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product
products
charcoal
mixed
sodium silicate
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KR1020020010695A
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Korean (ko)
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조성균
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조성균
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/022Carbon
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • C04B14/10Clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/10Coating or impregnating
    • C04B20/1055Coating or impregnating with inorganic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B20/00Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
    • C04B20/02Treatment
    • C04B20/026Comminuting, e.g. by grinding or breaking; Defibrillating fibres other than asbestos
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00793Uses not provided for elsewhere in C04B2111/00 as filters or diaphragms
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C1/00Building elements of block or other shape for the construction of parts of buildings
    • E04C1/40Building elements of block or other shape for the construction of parts of buildings built-up from parts of different materials, e.g. composed of layers of different materials or stones with filling material or with insulating inserts
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)

Abstract

PURPOSE: Provided are yellow earth and charcoal construction products(board, brick and air filter) using sodium silicate, an aqueous ceramic binder, instead of conventional binders. The resultant products produced by drying(<=130deg.C) and forming has air-permeability, dampproofing, far infrared emission and good strength. CONSTITUTION: The yellow earth and charcoal products are produced by the following steps; grinding yellow and charcoal, and screening; adding an aqueous ceramic binder, sodium silicate, which is ground and screened; drying at less than 130deg.C; pressing under the high and the low pressure for high strength products such as bricks, blocks, tiles, etc. and low strength products such as industrial filters, respectively; drying at less than 130deg.C.

Description

수성세라믹 바인더를 이용한 황토 및 숯 제품의 고강도 성형방법{Ceramic Bonding Mechanics of yellow clay and Carbon black members.}High strength molding of ocher and charcoal products using aqueous ceramic binders {Ceramic Bonding Mechanics of yellow clay and Carbon black members.}

본 발명은 황토 및 숯 자제(보드, 벽돌 및 산업용 공기 휠타)를 주제가 규산소다인 수성세라믹 바인더로 1,2차에 거처 섭씨 130도 이하 저온에서 황토 및 숯의 고유기능과 건축자재 규격에 맞는 제품을 제조하는 방법에 관한 것이다.The present invention is an aqueous ceramic binder whose main theme is sodium silicate based on ocher and charcoal materials (boards, bricks and industrial air filter), and meets the unique function of ocher and char at low temperature below 130 degrees Celsius and meets the construction materials standard. It relates to a method of manufacturing.

종래의 건축자재는 유기바인더 및 시멘트를 주 바인더로 고형화 시켰으나 황토의 물리적 특성 때문에 압축 및 인장 강도가 떨어지거나 주 재료의 고유기능이 훼손되는 결과를 가져왔고 또한 재래식 방법으로 황토와 보강재만으로 이루어진 경우에는 황토 고유 기능은 충족하나 강도가 떨어지고 수축률이 높아 균열이 가고 물에 약해 건축자재로서는 만족스럽지 못한 기술이다.Conventional building materials have solidified organic binders and cements as main binders, but the physical properties of loess have resulted in poor compressive and tensile strengths or impaired the intrinsic function of the main materials. It is an unsatisfactory technology for building materials, although it fulfills the inherent function of ocher, but it has low strength and high shrinkage rate, so it is cracked and weak in water.

0.1∼0.001 미리크론의 입도인 코로이드가 포함된 평균 0.002mm 이하의 미립자로 구성되있고 미립자간의 모공면적이 30∼90%인 점토류에 속하는 황토를 황토 본연의 특성을 살리면서 건축자재 규격에 적합한 제품을 얻기란 기존의 저온 제조방법으로는 기준에 미치지 못하였으나 본 발명은 규산소다 주재 수성세라믹 바인더를 이용하여 제품용도에 맞게 분쇄 스크린한 황토 소단위 입자군의 외부에 세라믹코팅을 하여 건조하면 견고한 피막이 형성되고, 피막 처리된 소단위 입자군을 세라믹 바인더와 소정의 비율로 혼합하여 유압성형기로 가압성형 탈착하여 섭씨 130도 이하 저온에서 건조하면, 견고한 피막과 피막이 세라믹 바인더로 가교가 형성되어 원하는 강도를 얻을 수 있으며 건조시 제품내의 수분이 외부로 증발하는 과정에서 미세한 다량의 기공들이 형성되어 통기성을 갖는다.Loess belonging to clays with an average particle size of 0.002 mm or less containing a colloid with a particle size of 0.1 to 0.001 micron, and having a pore area of 30 to 90% between the particles, Obtaining a suitable product did not meet the standard by the existing low-temperature manufacturing method, but the present invention is solid by applying ceramic coating on the outside of the ocher subunit particle group, which is pulverized and screened for product use, using an aqueous ceramic binder based on sodium silicate. When the film is formed, the subunit particle group treated with the film is mixed with the ceramic binder in a predetermined ratio, press-molded and desorbed by a hydraulic molding machine, and dried at a low temperature of 130 degrees Celsius or less. Fine pores in the process of evaporation of moisture in the product Is formed has an air-permeable.

황토의 실내 습도 조절기능은 기공을 통하여 이루어지며 흡습과 방출은 견고하게 피막 처리된 소립자군 내에서 이루어짐으로 제품의 균열을 방지하여 황토 자체의 특성을 살릴 수 있고 건축자재 규격에 맞는 제품을 생산하는 제조방법을 제공하는데 있다.The indoor humidity control function of the ocher is made through pores, and the moisture absorption and release is made in a group of small particles that are firmly coated to prevent cracking of the product, thereby making use of the characteristics of the ocher itself and producing products that meet the construction material standard. It is to provide a manufacturing method.

숯 또한 다공성이다, 숯은 재료에 따라 차이가 있지만 보통 1g당 내부 표면적이 무려 300평방 미터나 된다. 이와 같이 놀라운 구멍을 보유한 숯으로 건축 및 산업용 자재(벽돌, 보드, 휠타)를 만들려면 숯 고유의 기능을 최대한 살려야 한다. 제품에 따라 분쇄 스크린한 소립자군의 외부를 다수의 통기구를 갖는 세라믹 바인더로 견고하게 피막처리하고 소립자군의 피막과 피막을 세라믹바인더로 가교 시키면 소재의 고유기능을 살리며 표면에 비산먼지가 제거되며 공인 규격에 맞는 제품을 생산하는 제조방법을 제공하는데 있다.Charcoal is also porous. Charcoal varies from material to material, but typically has a surface area of 300 square meters per gram. To make architectural and industrial materials (bricks, boards, and wheels) out of this amazing hole of charcoal, you need to make the most of the charcoal's unique features. Depending on the product, the outside of the small particle group, which is crushed and screened, is firmly coated with a ceramic binder having a large number of vents. It is to provide a manufacturing method for producing a product conforming to the standard.

도 1은 1,2차 제조공정을 거친 완성품 구조도1 is a structural diagram of the finished product after the 1st and 2nd manufacturing process

도 2는 1차 제조공정을 거친 피막 처리된 소단위 입자군Figure 2 is a subunit particle group subjected to the film coating after the first manufacturing process

도 3은 고밀도 제품 내부구조의 단면도3 is a cross-sectional view of a high density product internal structure

도 4는 저밀도 제품 내부구조의 단면도4 is a cross-sectional view of the low density product internal structure

도 5는 제품 생산 공정도5 is a production process flow chart

본 발명의 제조방법은 공정별로 상세히 살펴보면 다음과 같다.Looking at the manufacturing method of the present invention in detail as follows.

즉, 본 발명의 제조방법은 도 5에서 예시한 바와 같이 1차, 2차 공정으로 이루어지는데 1차 공정에서 주재료인 황토 또는 숯을 제품 특성에 맞게 분쇄 스크린하고, 첨가하는 기능성 부재도 분쇄 스크린하여 혼합교반하고 혼합 교반된 주제 및 부재를 규산소다 주제인 수성세라믹 바인더와 소정의 비율로 혼합 교반 분쇄하여 섭씨 130도 이하로 건조하면 도 2에서 예시한 바와같이 세라믹 피막된 소단위 입자군을 얻을 수 있다.That is, the manufacturing method of the present invention is composed of the first and second processes, as illustrated in Figure 5 in the first step in the grinding process of the main material ocher or charcoal in accordance with the product characteristics, and the addition of the functional screen Mixing and mixing the stirred and mixed main body and the member with the aqueous ceramic binder, which is the main body of sodium silicate, by mixing and pulverizing at a predetermined ratio, and drying to 130 degrees C or less, a ceramic-coated subunit particle group can be obtained as illustrated in FIG. .

2차 공정에서 제품 사양에 따라 소정의 피막 입자군과 소정의 세라믹 바인더를 혼합 교반하고 제품사양에 따라 고압 및 저압으로 성형 탈착시켜 섭씨 130도 이하로 건조하면 고압 성형시에는 도 3에서 예시하는 바와 같이 고밀도의 고강도 제품 즉, 벽돌, 부록, 타일, 보드등을 얻을 수 있고 저압성형시에는 도 4에서 예시하는 바와 같이 저밀도 고강도 제품 즉, 통기량 가감 선택, 두께 치수의 가감 선택을 할 수 있는 기능성 산업용 휠타류를 생산할 수 있다.In the secondary process, a predetermined film particle group and a predetermined ceramic binder are mixed and agitated according to the product specification, and molded and desorbed at high pressure and low pressure according to the product specifications, and dried to 130 degrees Celsius or less. Likewise, high density high strength products, ie bricks, appendixes, tiles, boards, etc. can be obtained, and in the case of low pressure molding, low density high strength products, ie, air flow rate selection and thickness dimension selection selection, as illustrated in FIG. 4. Produce industrial wheel rudders.

본 발명은 규산소다 주제 세라믹바인더로 다기공 미세입자의 광물을 성형하는 제조방법으로The present invention is a manufacturing method of molding the mineral of the porous microparticles with a silicate-based ceramic binder

첫째, 소재 자체의 구조를 파괴하지 않음으로 자연 그대로의 기능성을 최대한 유지한다.First, it does not destroy the structure of the material itself, thereby maintaining the functionality as it is.

둘째, 저렴한 가격의 수성세라믹 바인더와 저온에서 가공처리 됨으로 경제적이고 타제품에 경쟁력이 있다.Second, it is economical and competitive in other products because it is processed at low price with aqueous ceramic binder and low temperature.

Claims (2)

도 5에서 예시한 바와 같이 1차 공정에서 주재료인 황토 또는 숯을 제품특성에 맞게 분쇄스크린하고, 첨가하는 기능성 부재도 혼합교반하고 이 혼합된 주재료 및 부재료를 규산소다 주제인 수성세라믹 바인더와 소정의 비율로 혼합교반 분쇄하여 섭씨 130도 이하로 건조하면 도 2에서 예시한 바와 같이 세라믹 피막된 소단위 입자군을 얻을 수 있는 제조방법 및 제품.As illustrated in FIG. 5, in the first process, the functional material for grinding and screening the main material ocher or charcoal in accordance with the product characteristics is mixed and stirred. The mixed main material and the subsidiary material are mixed with the aqueous ceramic binder, which is the subject of sodium silicate, and predetermined. A method and product for mixing and pulverizing and mixing at a ratio to obtain a ceramic-coated subunit particle group as illustrated in FIG. 도 5에서 예시한 바와 같이 2차 공정에서 제품 사양에 따라 소정의 황토 및 숯의 피막 입자군과 소정의 규산소다 주재인 수성세라믹 바인더를 혼합 교반하고 제품 사양에 따라 고압 및 저압으로 성형 탈착시켜 섭씨 130도 이하로 건조하면, 고압 성형시에는 도 3에서 예시하는 바와 같이 고밀도의 고강도 제품 즉 벽돌, 부럭, 타일 ,보드 등을 얻을 수 있고, 저압 성형시에는 도 4에서 예시하는 바와 같이 저밀도 고강도 제품 즉, 통기량 및 두께 치수의 가감선택 제품(산업용 휠터,가정용 휠터)을 생산할 수 있는 방법 및 그 제품.As illustrated in FIG. 5, in a secondary process, a predetermined amount of film particles of ocher and charcoal and an aqueous ceramic binder based on predetermined sodium silicate are mixed and stirred in a secondary process and molded and desorbed at high and low pressures according to product specifications. When it is dried to 130 degrees or less, high-density products such as bricks, blocks, tiles, and boards can be obtained as shown in FIG. 3 during high-pressure molding, and low-density high-strength products as illustrated in FIG. 4 during low-pressure molding. That is, the method and the product which can produce the product selection and selection (industrial filter, household filter) of the ventilation amount and thickness dimension.
KR1020020010695A 2002-02-27 2002-02-27 Ceramic Bonding Mechanics of yellow clay and Carbon black members. KR20020026227A (en)

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KR100507241B1 (en) * 2002-05-21 2005-08-11 최병태 A method for manufacturing aromatic porous yellow soil
KR100611709B1 (en) * 2005-08-29 2006-08-10 현대산업개발 주식회사 A powder composition for decorative material, method for preparing tile and covering using the same in building

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JPH0474776A (en) * 1990-07-11 1992-03-10 Teruzou Murai Production of light inorganic molded material
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100507241B1 (en) * 2002-05-21 2005-08-11 최병태 A method for manufacturing aromatic porous yellow soil
KR100484300B1 (en) * 2002-06-21 2005-04-20 남두석 Particles for insulation material, and its production method
KR100611709B1 (en) * 2005-08-29 2006-08-10 현대산업개발 주식회사 A powder composition for decorative material, method for preparing tile and covering using the same in building

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