KR20020005829A - Method of manufacturing a Metal-Sheet-Film - Google Patents
Method of manufacturing a Metal-Sheet-Film Download PDFInfo
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- KR20020005829A KR20020005829A KR1020000039271A KR20000039271A KR20020005829A KR 20020005829 A KR20020005829 A KR 20020005829A KR 1020000039271 A KR1020000039271 A KR 1020000039271A KR 20000039271 A KR20000039271 A KR 20000039271A KR 20020005829 A KR20020005829 A KR 20020005829A
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- metal
- metal layer
- film
- metal sheet
- gold
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
- C23C14/205—Metallic material, boron or silicon on organic substrates by cathodic sputtering
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/58—After-treatment
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
- C23C14/34—Sputtering
- C23C14/35—Sputtering by application of a magnetic field, e.g. magnetron sputtering
Abstract
Description
본 발명은 금속 시트 필름의 제조방법에 관한 것으로서, 특히 액세서리 및 인테리어의 기본 자재로 사용되는 금속 시트 필름의 제조방법에 관한 것이다.The present invention relates to a method for producing a metal sheet film, and more particularly, to a method for producing a metal sheet film used as a basic material for accessories and interiors.
액세서리 및 인테리어에 금속 광택을 가지는 자재들이 많이 사용되고 있다. 특히, 금은 각종 귀중품 및 부적의 재료로 이용되어 왔다. 근래에 들어서는 베이스 필름에 금박을 증착하고 그 금박 위에 코팅 처리를 하여 금속 시트 필름을 제조하고, 금속 시트 필름에 중요한 사항을 인쇄하여 기념품으로 시판되고 있다.Metallic luster is widely used in accessories and interiors. In particular, gold has been used as a material for various valuables and amulets. In recent years, gold foil is deposited on a base film and coated on the gold foil to produce a metal sheet film, and important matters are printed on the metal sheet film and sold as souvenirs.
종래에는 기계적으로 압연된 금박을 로울러 등의 기계를 사용하여 라미네이팅 필름에 압착시키고 있다. 이와 같이, 로울러 등을 이용하여 기계적으로 압착된 금박은 두께가 균일하지 못하며 핀홀등이 많이 존재하게 되고, 매우 가벼운 금박을기계적으로 압착하게되므로 그 공정이 까다롭다. 또한, 금박의 두께를 보다 균일하게 하고, 핀홀 등의 발생을 억제하기 위해서는 작은 면적의 금속 시트 필름을 제조할 수 밖에 없으므로 생산성이 떨어지게 된다.Conventionally, mechanically rolled gold foil is crimped to a laminating film using a machine such as a roller. As described above, the gold foil mechanically compressed using a roller or the like is not uniform in thickness, there are many pinholes, and the like, and the process is difficult because the gold foil is mechanically compressed. In addition, in order to make the thickness of the gold foil more uniform and to suppress the occurrence of pinholes, the production of a metal sheet film having a small area is inevitably reduced.
따라서, 본 발명이 이루고자 하는 기술적 과제는 금속층의 두께가 균일하고, 넓은 면적을 제조할 수 있으며 생산성이 향상될 수 있는 금속 시트 필름의 제조 방법을 제공하는 데 있다.Therefore, the technical problem to be achieved by the present invention is to provide a method for producing a metal sheet film, the thickness of the metal layer is uniform, can produce a large area and the productivity can be improved.
도 1은 본 발명의 실시예에 따른 금속 시트 필름의 단면도이다.1 is a cross-sectional view of a metal sheet film according to an embodiment of the present invention.
상기 기술적 과제들을 달성하기 위한 본 발명의 금속 시트 필름의 제조 방법은, 액세서리 및 인테리어용 기본 자재를 제조하기 위한 베이스 필름을 준비하는 단계와; 상기 베이스 필름 상에 스퍼터링(Sputtering) 증착법, 이온빔(Ion Beam) 증착법, 전자빔(Electron Beam) 증착법, 및 증발(Evaporation) 증착법으로 구성된 군으로부터 선택된 어느 하나의 방법을 사용하여 금속층을 증착하는 단계와; 상기 금속층 상에 상기 금속층의 손상을 방지하거나 내용을 인쇄하기 위한 초경질 수지층을 형성하는 단계를 포함하는 것을 특징으로 한다.Method for producing a metal sheet film of the present invention for achieving the above technical problem, the method comprising the steps of preparing a base film for manufacturing accessories and basic materials for interior; Depositing a metal layer on the base film using any one method selected from the group consisting of sputtering deposition, ion beam deposition, electron beam deposition, and evaporation deposition; And forming an ultrahard resin layer on the metal layer to prevent damage to the metal layer or to print the contents.
이 때, 상기 베이스 필름은 폴리 염화 비닐(Poly Vinyl Chloride, PVC)과 에이비에스(Acrylo Butadiene Styrene, ABS) 수지를 혼합한 합성 수지 또는 폴리에스터(Polyester)로 이루어져도 좋다.In this case, the base film may be made of a synthetic resin or polyester (Polyester) mixed with poly vinyl chloride (PVC) and ABS (Acrylo Butadiene Styrene, ABS) resin.
나아가, 상기 금속층은 금, 은, 및 백금으로 구성된 군으로부터 선택된 어느 하나로 이루어져도 좋다.Further, the metal layer may be made of any one selected from the group consisting of gold, silver, and platinum.
더 나아가, 상기 금속층은 상기 금, 은, 및 백금의 광택을 가지는 합금으로 이루어져도 좋다.Furthermore, the metal layer may be made of an alloy having gloss of the gold, silver, and platinum.
이하, 첨부한 도면을 참조하여 본 발명의 바람직한 실시예들을 상세히 설명한다.Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings.
도 1은 본 발명의 실시예들에 따른 금속 시트 필름의 단면도이다.1 is a cross-sectional view of a metal sheet film according to embodiments of the present invention.
도 1을 참조하여 본 발명의 제1 실시예를 설명하면, 먼저, 액세서리 및 인테리어용 기본 자재를 제조하기 위한 폴리에스터 필름(100)을 준비한다. 폴리에스터 필름은 탄성강도가 높으므로 본 발명에 의한 금속 시트 필름을 얇게 제조할 수 있는 장점이 있다. 그리고, 초음파 세정 장치를 사용하여 폴리에스터 필름(100) 표면에 붙어 있는 사람의 지문 및 이물질을 제거한다. 초음파 세정 장치는 세정액이 들어있는 용기에 초음파 진동기로 구성된다. 그 초음파 진동기가 작동하게 되면, 용기 내의 세정액이 진동을 하게 되고 그 진동으로 인하여 폴리에스터 필름(100)으로부터 지문 및 이물질을 효율적으로 제거할 수 있게 된다.Referring to FIG. 1, a first embodiment of the present invention will be described. First, a polyester film 100 for preparing accessories and basic materials for interiors is prepared. Since the polyester film has a high elastic strength, there is an advantage in that the metal sheet film according to the present invention can be manufactured thinly. Then, the fingerprint and foreign matter of the person stuck to the surface of the polyester film 100 is removed using an ultrasonic cleaning device. The ultrasonic cleaning device is constituted by an ultrasonic vibrator in a container containing a cleaning liquid. When the ultrasonic vibrator is operated, the cleaning liquid in the container vibrates and the fingerprint and foreign matter can be efficiently removed from the polyester film 100 due to the vibration.
이어서, 폴리에스터 필름(100)의 내마모성 및 내후성이 향상되도록 폴리에스터 필름(100) 상에 접촉재를 사용하여 아크릴 코팅층(200)을 형성한다. 그리고, 아크릴 코팅층(200)에 플라즈마 에칭을 실시한다. 이것은, 아크릴 코팅층(200)의 표면을 개질하여 아크릴 코팅층(200)과 금속층(300)의 접착성을 향상시키고 아크릴코팅층(200) 표면에 존재하는 오염 물질을 제거하기 위해서이다.Subsequently, the acrylic coating layer 200 is formed on the polyester film 100 by using a contact material to improve wear resistance and weather resistance of the polyester film 100. Then, plasma etching is performed on the acrylic coating layer 200. This is to modify the surface of the acrylic coating layer 200 to improve adhesion between the acrylic coating layer 200 and the metal layer 300 and to remove contaminants present on the surface of the acrylic coating layer 200.
다음에, 아크릴 코팅층(200)의 일면에 마그네트론 스퍼터링(Magnetron Sputtering) 증착법으로 금속층(300) 예컨대, 금박을 증착한다. 마그네트론 스퍼터링 증착법으로 금속층(300)을 형성하는 과정은 다음과 같다. 먼저, 기판과 타겟 금속이 마련된 반응실에 기체를 유입한 후에 진공 상태로 유지한다. 그리고 타겟 금속에 고전압을 인가하여 반응실내의 가스를 플라즈마화시키면, 그 플라즈마가 타겟 금속에 충돌하여 타겟 금속으로부터 원자 단위를 떼어내게 되고, 그 원자 단위가 반응실내에 마련된 기판에 증착되게 된다. 이 때, 타겟 금속에 자계를 더 인가하면 타겟 금속 근처에서 고밀도의 플라즈마가 생성되게 된다. 따라서, 마그네트론 스퍼터링 증착법을 이용하면 기판 상에 박막이 고속으로 증착된다.Next, a metal layer 300, for example, gold foil is deposited on one surface of the acrylic coating layer 200 by a magnetron sputtering deposition method. The process of forming the metal layer 300 by the magnetron sputtering deposition method is as follows. First, gas is introduced into a reaction chamber provided with a substrate and a target metal, and then maintained in a vacuum state. When a high voltage is applied to the target metal to plasma the gas in the reaction chamber, the plasma collides with the target metal to remove atomic units from the target metal, and the atomic units are deposited on a substrate provided in the reaction chamber. At this time, if a magnetic field is further applied to the target metal, a high density plasma is generated near the target metal. Therefore, using the magnetron sputtering deposition method, a thin film is deposited on the substrate at high speed.
본 실시예에서는 반응실에 유입되는 기체는 불활성 기체를 사용하였고, 타겟 금속으로 금을 사용하여 아크릴 코팅층(200)의 일면에 두께가 10∼2,000Å인 금박(300)을 형성하였다. 이와 같이, 금박(300)이 원자 단위로 증착되므로 균일한 박막을 형성할 수 있다. 한편, 금속 시트 필름의 용도에 따라서 아크릴 코팅층(200)의 다른 일면들에도 금박(300)을 증착할 수 있다. 그리고, 반응실에 유입되는 기체의 종류를 다르게 함으로써 증착되는 박막의 색상을 변화시킬 수 있다.In this embodiment, an inert gas was used as the gas flowing into the reaction chamber, and gold was used to form a gold foil 300 having a thickness of 10 to 2,000 mm 3 on one surface of the acrylic coating layer 200 using gold as a target metal. As such, since the gold foil 300 is deposited in atomic units, a uniform thin film may be formed. Meanwhile, the gold foil 300 may be deposited on other surfaces of the acrylic coating layer 200 according to the use of the metal sheet film. The color of the deposited thin film may be changed by changing the kind of gas introduced into the reaction chamber.
그 다음에, 금박(300)을 사람의 지문이나 이물질로부터 보호하고, 금박(300)의 손상을 방지하며, 원하는 내용을 인쇄할 수 있도록 금박(300) 위에 초경질수지 코팅층(400)을 형성한다.Next, the ultra-hard resin coating layer 400 is formed on the gold foil 300 to protect the gold foil 300 from human fingerprints or foreign substances, to prevent damage to the gold foil 300, and to print desired contents. .
도 1을 참조하여 본 발명의 제2 실시예를 설명하면, 먼저, 폴리 염화 비닐과에이비에스 수지를 혼합한 합성수지를 사용하여 두께 조정용 필름(100)를 준비한다. 그리고, 초음파 세정 장치를 사용하여 두께 조정용 필름(100) 표면에 붙어 있는 사람의 지문 및 이물질들 제거한다. 이어서, 두께 조정용 필름(100)과 동일한 재질의 금박 증착용 팔름(200)를 마련하고, 그 위에 금박(300)을 증착한다. 그리고, 금박이 증착된 금박 증착용 필름(200)을 두께 조정용 필름(100)에 접착시킨다.Referring to FIG. 1, a second embodiment of the present invention will be described. First, a film 100 for thickness adjustment is prepared using a synthetic resin obtained by mixing polyvinyl chloride and ABS resin. Then, the ultrasonic cleaning device is used to remove fingerprints and foreign substances of the person on the surface of the thickness adjustment film 100. Subsequently, a gold foil deposition flange 200 of the same material as the film 100 for thickness adjustment is provided, and the gold foil 300 is deposited thereon. Then, the gold foil deposition film 200 in which gold foil is deposited is bonded to the film 100 for thickness adjustment.
폴리 염화 비닐과 에이비에스 수지를 혼합한 합성 수지는 제1 실시예의 폴리에스터 필름의 경우보다 용이하게 금박(300)을 증착할 수 있다. 그 반면에 탄성 강도가 약하여 상기한 제1 실시예의 폴리에스터 필름의 경우보다 두께를 두껍게 형성해야 하는데, 두께가 두껍게 되면 원활한 제조가 어렵게 된다. 따라서, 폴리 염화 비닐과 에이비에스 수지를 혼합한 합성 수지를 사용하여 금속 시트 필름을 제조하는 경우에는 두께 조정용 필름(100) 및 금박 증착용 필름(200)으로 구성하게 된다. 이때, 두께 조정용 필름(100) 및 금박 증착용 필름(200)은 동일한 재질로 이루어지므로 접착제를 사용하지 않고 열과 압력을 이용하여 접착시키게 된다.The synthetic resin in which the polyvinyl chloride and the ABS resin are mixed can deposit the gold foil 300 more easily than in the case of the polyester film of the first embodiment. On the other hand, the elastic strength is weak to form a thicker than the case of the polyester film of the first embodiment described above, if the thickness is thick, it is difficult to manufacture smoothly. Therefore, when manufacturing a metal sheet film using the synthetic resin which mixed polyvinyl chloride and ABS resin, it consists of the film 100 for thickness adjustment and the film 200 for gold foil deposition. At this time, since the thickness adjusting film 100 and the gold foil deposition film 200 are made of the same material, they are bonded using heat and pressure without using an adhesive.
그 다음에, 금박(300)을 사람의 지문이나 이물질로부터 보호하고, 금박(300)의 손상을 방지하며, 원하는 내용을 인쇄할 수 있도록 금박(300) 위에 초경질수지 코팅층(400)을 형성한다.Next, the ultra-hard resin coating layer 400 is formed on the gold foil 300 to protect the gold foil 300 from human fingerprints or foreign substances, to prevent damage to the gold foil 300, and to print desired contents. .
상술한 바와 같이 본 발명의 금속 시트 필름의 제조 방법에 의하면, 금속이 원자 단위로 증착되어 형성되므로 핀홀이 없고 균일한 두께를 가지는 양질의 금속층을 증착할 수 있다.As described above, according to the method of manufacturing the metal sheet film of the present invention, since the metal is formed by being deposited in atomic units, it is possible to deposit a high quality metal layer having no pinhole and having a uniform thickness.
또한, 생산 속도를 향상시킬 수 있고, 면적이 넓은 금속 시트 필름을 제조할 수 있다.In addition, the production speed can be improved, and a metal sheet film having a large area can be produced.
나아가, 금속층을 증착함에 있어서 기계적인 마찰이 없으므로 금속이 가지는 고유한 광택을 유지할 수 있다.Furthermore, there is no mechanical friction in depositing the metal layer, thereby maintaining the inherent gloss of the metal.
더 나아가, 금속층을 증착하는 단계에서 귀금속과 반응하는 기체들을 유입하여 증착되는 금속층의 색상을 변화시킬 수 있다.Furthermore, in the depositing of the metal layer, gases reacting with the noble metal may be introduced to change the color of the deposited metal layer.
본 발명은 상기 실시예들에만 한정되지 않으며, 본 발명의 기술적 사상 내에서 당 분야의 통상의 지식을 가진 자에 의해 많은 변형이 가능함은 명백하다.The present invention is not limited to the above embodiments, and it is apparent that many modifications are possible by those skilled in the art within the technical spirit of the present invention.
Claims (5)
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KR1020000039271A KR20020005829A (en) | 2000-07-10 | 2000-07-10 | Method of manufacturing a Metal-Sheet-Film |
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KR20200042361A (en) | 2018-10-15 | 2020-04-23 | 이영범 | Precious metal sheet and manufacturing method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS649733A (en) * | 1987-07-03 | 1989-01-13 | Oike Kogyo Kk | Film for silver vapor-deposited tinsel |
JPH01283138A (en) * | 1988-05-11 | 1989-11-14 | Dainippon Printing Co Ltd | Metallic decoration sheet for sheathing sash |
KR970069327A (en) * | 1996-04-24 | 1997-11-07 | 이서봉 | Insulation material using metal deposition film |
-
2000
- 2000-07-10 KR KR1020000039271A patent/KR20020005829A/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS649733A (en) * | 1987-07-03 | 1989-01-13 | Oike Kogyo Kk | Film for silver vapor-deposited tinsel |
JPH01283138A (en) * | 1988-05-11 | 1989-11-14 | Dainippon Printing Co Ltd | Metallic decoration sheet for sheathing sash |
KR970069327A (en) * | 1996-04-24 | 1997-11-07 | 이서봉 | Insulation material using metal deposition film |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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KR20200042361A (en) | 2018-10-15 | 2020-04-23 | 이영범 | Precious metal sheet and manufacturing method thereof |
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