KR20010064299A - Matter of dip molding for rubber goods - Google Patents

Matter of dip molding for rubber goods Download PDF

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KR20010064299A
KR20010064299A KR1019990064466A KR19990064466A KR20010064299A KR 20010064299 A KR20010064299 A KR 20010064299A KR 1019990064466 A KR1019990064466 A KR 1019990064466A KR 19990064466 A KR19990064466 A KR 19990064466A KR 20010064299 A KR20010064299 A KR 20010064299A
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rubber
composition
jade powder
molding
weight
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Korean (ko)
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이재윤
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이재윤
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • C08L7/02Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds

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  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
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Abstract

PURPOSE: Provided is a moulding composition of dipping type rubber products such as house hold gloves, shoes and condoms wherein jade powder is added to improve wetting resistance and anti-bacterial property. The jade powder is used a mixture of pyroxene and amphibole in a ratio of 50:50, which are known to eliminate moisture and have bactericide property respectively. Thereby uncomfortable situation and skin irritation and disease due to perspiration are reduced during their use. CONSTITUTION: The moulding composition is prepared by dissolving in an unvulcanized rubber as solvent. Also, the composition is characterized by composing an additive for moulding another dipping type rubber products added 90-95wt.% this rubber solution containing 50-60wt.% of solids with 5-10wt.% of the jade powder with 1-5 micrometer in size, consisting the mixture of pyroxene and amphibole in a ratio of 50:50. This rubber compound is again mixed with vulcanizing agent, stabilizer and other additives to make the final compositions for various purposes.

Description

디핑형성 고무제품 성형용 조성물{Matter of dip molding for rubber goods}Composition for molding dipping molding rubber product {Matter of dip molding for rubber goods}

본 발명은 디핑형성 고무제품 성형용 조성물과 그 제조방법에 관한 것으로서 더욱 상세하게는 조성물을 이용하여 고무장갑이나 신발류 및 콘돔과 같은 고무제품으로 사용시 사용자들의 인체에 유익함을 줄 수 있도록 한 조성물의 제공에 관한 것이다.The present invention relates to a composition for molding a dipping-forming rubber product and a method of manufacturing the same. More particularly, the present invention relates to a composition for providing benefits to a human body when used as a rubber product such as rubber gloves, footwear, and condom. It is about giving.

일반적으로 가정용이나 산업용 및 의료용으로 사용되는 고무장갑이나 고무장화와 고무신과 같은 신발류 및 콘돔과 같은 피임보조기구 또는 생고무에 사용되는 조성물에는 결합성을 좋게하기 위하여 가황제나 각종의 안정제를 사용하게 된다.Generally, vulcanizing agents or various stabilizers are used to improve binding properties in rubber gloves, rubber boots and rubber shoes used for home, industrial and medical purposes, and contraceptive aids such as condoms or raw rubber.

뿐만 아니라, 착색을 위하여 아연화 등의 중금속이 든 부제를 소량이나마 사용하고 아울러 유기 항균제를 사용하게 된다.In addition, a small amount of a subsidiary containing heavy metals such as zinc for the coloring and use an organic antimicrobial agent.

상기와 같이 유기 항균제를 사용할 경우에는 사용과정에서 이러한 성분들이 용출되는 문제가 발생하고, 유기용제의 특성상 그 효과가 제품의 수명만큼 지속적인 효과를 가지지 못하게 됨으로서 이를 사용하는 사용자들의 인체에 상당한 악영향을 미치게 된다.In the case of using the organic antimicrobial agent as described above, such components are eluted in the use process, and due to the nature of the organic solvent, the effect does not have a lasting effect as long as the life of the product, which has a significant adverse effect on the human body of the user using the same. do.

특히 고무제품의 특성상 통기가 원활하지 못하기 때문에 고무제품을 착용한 부위에서 발생하는 땀과 상기 땀으로 인하여 누적되는 오염물질로 인하여 심한 악취가 발생하게 되고, 곰팡이와 같은 유해균의 발생으로 습진, 피부각질과 같은 피부병을 불러와 피부의 손상과 노화를 촉진시키는 문제점을 가졌었다.In particular, due to the nature of the rubber product is not well ventilated due to the sweat generated in the area wearing the rubber product and the contaminants accumulated by the sweat occurs a bad odor, eczema, skin caused by the generation of harmful bacteria such as mold It has a problem of causing skin diseases such as keratin and promoting skin damage and aging.

특히 상기와 같은 고무제품을 고온 다습한 지역에서 장시간 또는 장기간동안 연속적인 작업이 이루어질 경우에는 이러한 현상이 더욱더 가중되는 등의 문제점들이 있었다.In particular, when the continuous operation is performed for a long time or a long time in a high temperature and high humidity region, such a phenomenon has a problem that is further aggravated.

이에 본 발명에서는 상기와 같은 문제점들을 해결하기 위하여 발명된 것으로서 통상적인 고무제품 조성물에 상온에서 곰팡이균 또는 대장균과 같은 일반적인 세균뿐만 아니라 주부습진등을 야기시키는 여러가지 원인균에 대한 항균력을 높일 수 있고, 근본적으로 각종 피부질환을 야기시키는 원인을 제공하는 땀을 제거할 수 있는 옥분말을 첨가하는 것을 특징으로 하고;Accordingly, the present invention can increase the antimicrobial activity against various causative bacteria causing not only common bacteria such as fungus or E. coli but also housewife eczema at room temperature in a conventional rubber product composition as invented to solve the above problems, and It is characterized in that the addition of jade powder to remove the sweat to provide a cause causing various skin diseases;

상기 조성물로 제조한 각종의 고무제품에서 항균 및 습기제거기능으로 사용자들의 인체에 유익함을 줄 수 있도록 함을 목적으로 한다.The purpose of the present invention is to provide benefits to the human body with antibacterial and moisture removal functions in various rubber products prepared with the composition.

도 1은 본 발명에 사용되는 옥분말의 성분을 나타낸 도표.1 is a table showing the components of the jade powder used in the present invention.

도 2는 본 발명에 사용되는 옥분말의 성분분포를 도시한 그래프도.Figure 2 is a graph showing the component distribution of the jade powder used in the present invention.

도 3은 본 발명의 디핑형성 고무제품 성형용 조성물로 항균심험한 결과 도표.Figure 3 is a result of antimicrobial test results with the composition for molding a dipping-forming rubber product of the present invention.

이하 본 발명의 기술이 적용되는 디핑형성 고무제품 성형용 조성물과 그 제조방법에 대한 바람직한 실시예를 상세하게 설명하면 다음과 같다.Hereinafter will be described in detail a preferred embodiment of the composition for forming a dipping-forming rubber product to which the technique of the present invention is applied and a method for producing the same.

도 1은 본 발명에 사용되는 옥분말의 성분을 나타낸 도표, 도 2는 본 발명에 사용되는 옥분말의 성분분포를 도시한 그래프도, 도 3은 본 발명의 디핑형성 고무제품 성형용 조성물로 항균심험한 결과 도표로서 함께 설명한다.1 is a diagram showing the components of the jade powder used in the present invention, Figure 2 is a graph showing the component distribution of the jade powder used in the present invention, Figure 3 is a composition for molding a dipping forming rubber product of the present invention antibacterial Explain the results together as a chart.

본 발명에서는 통상적인 고무제품을 생산하기 위한 공지된 조성물에 상온에서 곰팡이균 또는 대장균과 같은 일반적인 세균뿐만 아니라 주부습진등을 야기시키는 여러가지 원인균에 대한 항균력을 높일 수 있고;In the present invention, it is possible to increase the antimicrobial activity against a variety of causative agents causing not only common bacteria such as fungus or E. coli but also housewife eczema at room temperature in a known composition for producing a conventional rubber product;

근본적으로 각종 피부질환을 야기시키는 원인을 제공하는 땀을 제거할 수 있는 옥분말을 첨가하여 상온에서 충분히 혼합하여 교질상의 조성물을 얻도록 함을 특징으로 한다.It is characterized in that the addition of jade powder to remove the sweat that provides a cause for causing various skin diseases by mixing sufficiently at room temperature to obtain a gelatinous composition.

상기한 공지의 조성물에 혼합하는 옥분말은;The jade powder mixed with the above known composition is;

습기제거능력이 뛰어난 특성을 가지는 휘석과 항균력이 유수한 각섬석을 1∼5㎛이하로 분쇄한 분말을 50;50%의 비율로 충분히 혼합하여 교질상의 조성물로 얻어진 것을 사용한다.A powder obtained by pulverizing a mixture of fluorite having excellent moisture removal ability and hornblende having excellent antimicrobial activity to 1 to 5 μm or less at a ratio of 50: 50% is obtained as a colloidal composition.

상기 옥분말은 소결로에 1000℃ 이상에서 24시간 이상 소결시켜 분자의 구조상 가지고 있는 산소를 이탈시켜 양이온화 되도록 유도하고;The jade powder is sintered in a sintering furnace at 1000 ° C. for at least 24 hours to induce oxygen to be catalyzed by leaving oxygen contained in the structure of the molecule;

부가적으로 고온하에서 불순물을 태워 순수의 재료를 얻으며 비중을 낮추어 공정상 침지되는 양을 줄이는 공정을 거치도록 하는 것이 바람직 하다.In addition, it is desirable to go through the process of burning the impurities under high temperature to obtain the material of pure water and to reduce the specific immersion by lowering the specific gravity.

상기와 같은 옥분말이 함유하고 있는 성분은 도 1,2에 도시된 바와 같이 제습, 녹농균과 대장균에 대한 항균력을 가지는 항균성분이 풍부한 K2O, MgO, MnO, NaO, P2O5, SiO2, Tio2, Al2O3, CaO, Fe2o3와 같은 성분으로 구성된다.As the components contained in the above jade powder are dehumidified, K2O, MgO, MnO, NaO, P2O5, SiO2, Tio2, Al2O3, CaO, which are rich in antibacterial components having antibacterial activity against P. aeruginosa and E. coli. Consists of components such as Fe2o3.

상기와 같은 특성을 가지는 옥분말을 총중량 기준으로 가류되지 않은 천연고무를 용제로 용해시켜 형성된 고형분 50∼60중량%를 함유한 교질상의 액체이며 고무 90∼95%중량에 5∼10%중량으로 첨가한다.It is a colloidal liquid containing 50 to 60% by weight of solids formed by dissolving jade powder having the above characteristics as a solvent by dissolving natural rubber which is not vulcanized based on the total weight, and is added in an amount of 5 to 10% by weight to 90 to 95% by weight of rubber. do.

상기 옥분말을 고무 90∼95%중량에 첨가할 시 바람직한 중량비는 고무와 옥분말의 총질량 기준으로 옥분말 5∼10%중량을 적절한 상태로 가변하면서 첨가한다.When the jade powder is added to the rubber 90 to 95% by weight, the preferred weight ratio is added while varying the jade powder 5 to 10% by weight in an appropriate state based on the total mass of the rubber and jade powder.

상기와 같은 옥분말은 약 5∼1㎛크기의 입자로 형성하는 것이 좋으며, 상기와 같은 조성물을 이용하여 각종의 고무제품을 성형하는 실시예를 설명하면 다음과 같다.The jade powder as described above may be formed into particles having a size of about 5 to 1 μm, and an embodiment of molding various rubber products using the composition as described above is as follows.

실시예1;Example 1;

고형분이 60% 포함된 천연고무 또는 합성고무 90∼95중량%와 옥분말 5∼10중량%로 혼합 조성된 조성물에 상기 조성물의 총 질량에 대하여 기 설정된 일정비율로 가황제 및 안정제를 포함한 다른 조성물을 혼합하여 디핑조에 담는다.Other compositions including a vulcanizing agent and a stabilizer in a predetermined ratio with respect to the total mass of the composition in a composition composed of 90 to 95% by weight of natural or synthetic rubber containing 60% of solids and 5 to 10% by weight of jade powder. Mix and place in dipping bath.

상기와 같은 조성물을 이용하여 가정용 고무장갑을 얻고자 할 경우에는 고무장갑 형태의 몰드를 디핑조에 침지시켜 기 설정된 소정시간만큼 건조시킨 후 2차침지시켜 0.5mm 두께범위의 고무장갑을 얻는다.In order to obtain household rubber gloves using the composition as described above, a rubber glove-shaped mold is immersed in a dipping tank, dried for a predetermined time, and then immersed in a second to obtain a rubber glove having a thickness range of 0.5 mm.

상기와 같이 성형된 고무장갑은 도 3에 도시된 바와같이 대장균은 24시간 후 97.2%가 소멸되고 녹농균은 95,9%가 소멸되었다.As shown in FIG. 3, the rubber gloves molded as described above were 97.2% disappeared after 24 hours and 95.9% were eliminated for Pseudomonas aeruginosa.

상기와 같은 고무장갑을 사용할 경우에는 탈색, 악취가 발생하지않고 피부질환의 심화현상이 줄어들고 고무장갑을 사용하는 도중 땀이 잘차지 않는 효과를 얻게된다.In the case of using such rubber gloves, the discoloration, odor does not occur, and the severity of skin diseases is reduced, and sweating is not performed well while using rubber gloves.

실시예2;Example 2;

상기와 같은 조성물로 고무장화를 얻기 위해서는 고무장화 몰드를 상기 조성물에 침지시켜 고무장갑을 얻을 때의 침지시간과 건조시간을 조절하여 두께가 2mm가 되도록 하면 된다.In order to obtain rubber boots with the composition as described above, the rubber boots mold may be immersed in the composition to adjust the immersion time and drying time when the rubber gloves are obtained to have a thickness of 2 mm.

상기와 같이 얻어진 고무장화는 실시예1의 고무장갑과 동일한 효과를 얻을 수 있게된다.The rubber boots obtained as described above can obtain the same effects as the rubber gloves of Example 1.

실시예3;Example 3;

상기 디핑조에 의료용 고무장갑 또는 콘돔의 몰드를 침지시킨 후 건조과정을 반복하여 0.2mm 두께범위의 의료용 장갑이나 콘돔을 얻는다.After dipping the mold of medical rubber gloves or condoms in the dipping tank and repeating the drying process, a medical gloves or condoms having a thickness range of 0.2 mm are obtained.

상기와 같이 얻어진 의료용 고무장갑이나 콘돔을 사용할 경우에는 실시예1에서의 효과와 동일한 효과를 얻을 수 있으며;When the medical rubber gloves or condoms obtained as described above are used, the same effects as in Example 1 can be obtained;

의료용 고무장갑이나 콘돔의 사용과정에서 발생할 수 있는 병원균의 전염예방에 도움이 되고 사용자의 위생건강에 기여할 수 있게된다.It can help to prevent the transmission of pathogens that may occur during the use of medical rubber gloves or condoms, and contribute to the hygiene and health of users.

이상과 같은 본 발명은 옥분말이 가지는 습기제거능력과 강한 항균력에 의하여 각종 피부질환의 방지와 사용중 땀의 누적으로 야기될 수 있는 불쾌감을 제거할 수 있으며;The present invention as described above can eliminate the discomfort caused by the prevention of various skin diseases and the accumulation of sweat during use by the moisture removal ability and strong antibacterial ability of jade powder;

물리적으로 연속적인 고리구조를 가지는 고무의 특성에 암석의 조각을 첨가함으로서 케익형태의 재질을 쪼개어 공극을 인위적으로 키우므로 피부접촉성의 향상과 더불어 유연성을 향상시키는데 일조하는 등의 효과를 가진다.By adding a piece of rock to the characteristics of the rubber having a physically continuous ring structure, the cake-like material is split to artificially increase the voids, thereby improving skin contact and improving flexibility.

Claims (2)

디핑성형용 고무제품의 성형용 조성물에 있어서;A composition for molding a rubber product for dipping molding; 가류되지 않은 천연고무를 용제로 용해시켜 형성되며 고형분을 50∼60%함유한 액체고무 90∼95중량%에 옥분말 5∼10중량%를 상기 고무와 조성물질 분말의 총중량에 대하여 기 설정된 중량비율로 첨가되는 다른 디핑형성 고무제품 성형용 첨가물로 조성되는 것을 특징으로 하는 디핑형성 고무제품 성형용 조성물.It is formed by dissolving unvulcanized natural rubber with a solvent and 5 to 10% by weight of jade powder to 90 to 95% by weight of liquid rubber containing 50 to 60% of solid content. A composition for molding a dipping forming rubber product, characterized in that it is composed of an additive for molding another dipping forming rubber product. 제 1 항에 있어서;The method of claim 1; 상기 가류되지 않은 천연고무를 용제로 용해시켜 형성되며 고형분을 50∼60%함유한 액체고무 90∼95중량%에 옥분말과 기타 항균제분말 5∼10중량%를 상기 고무와 조성물질 분말의 총중량에 대하여 기 설정된 중량비율로 첨가되는 다른 디핑형성 고무제품 성형용 첨가물로 조성되는 것을 특징으로 하는 디핑형성 고무제품 성형용 조성물.It is formed by dissolving the unvulcanized natural rubber with a solvent, and 90 to 95% by weight of liquid rubber containing 50 to 60% of solid content, and 5 to 10% by weight of jade powder and other antimicrobial powders to the total weight of the rubber and the composition powder. A composition for molding a dipping forming rubber product, characterized in that the composition is formed of an additive for forming another dipping forming rubber product added at a predetermined weight ratio.
KR1019990064466A 1999-12-29 1999-12-29 Matter of dip molding for rubber goods KR20010064299A (en)

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