KR19990046469A - Matter of dip molding for rubber goods - Google Patents
Matter of dip molding for rubber goods Download PDFInfo
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- KR19990046469A KR19990046469A KR1019990008988A KR19990008988A KR19990046469A KR 19990046469 A KR19990046469 A KR 19990046469A KR 1019990008988 A KR1019990008988 A KR 1019990008988A KR 19990008988 A KR19990008988 A KR 19990008988A KR 19990046469 A KR19990046469 A KR 19990046469A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/02—Direct processing of dispersions, e.g. latex, to articles
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
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Abstract
본 발명은 원적외선방사물질분말이 가지는 항균, 제습, 탈취기능과 원적외선 및 음이온의 방출로 생체조직의 활성황로 인한 피부손상과 노화를 방지하고 혈액순환의 촉진으로 사용자의 피로도를 격감시킬 수 있는 등의 효과를 가지도록 한 디핑형성 고무제품 성형용 조성물에 관한 것으로서;The present invention can prevent skin damage and aging caused by active sulfur of biological tissues by antibacterial, dehumidifying, deodorizing function and release of far infrared rays and anions which far infrared radiation substance powder has, and can reduce the fatigue of the user by promoting blood circulation. It relates to a composition for molding a dipping forming rubber product to have an effect of;
가류되지 않은 천연고무를 용제로 용해시켜 형성되며 고형분을 50∼60％ 함유한 액체고무 90∼95중량％에;To 90-95 weight% of liquid rubber which is formed by dissolving unvulcanized natural rubber with a solvent and containing 50 to 60% of solid content;
항균, 제습, 탈취기능과 원적외선 및 음이온의 방출되는 원적외선방사물질분말 5∼10중량％와;5 to 10% by weight of anti-infrared radiation substance powder which releases antibacterial, dehumidifying, deodorizing function and far infrared rays and anions;
상기 고무와 조성물질 분말의 총중량에 대하여 기 설정된 중량비율로 첨가되는 다른 디핑형성 고무제품 성형용 첨가물로 조성하는 것을 특징으로 한다.It is characterized in that it is composed of an additive for molding another dipping-forming rubber product is added at a predetermined weight ratio with respect to the total weight of the rubber and the composition powder.
Description
본 발명은 디핑형성 고무제품 성형용 조성물과 그 제조방법에 관한 것으로서 더욱 상세하게는 조성물을 이용하여 고무장갑이나 신발류 및 콘돔과 같은 고무제품으로 사용시 사용자들의 인체에 유익하도록 한 조성물의 제공에 관한 것이다.The present invention relates to a composition for molding a dipping-forming rubber product and a method of manufacturing the same. More particularly, the present invention relates to the provision of a composition that is beneficial to the human body of a user when used as a rubber product such as rubber gloves, footwear, and condom. .
일반적으로 가정용이나 산업용 및 의료용으로 사용되는 고무장갑이나 고무장화와 고무신과 같은 신발류 및 콘돔과 같은 피임보조기구 또는 생고무에 사용되는 조성물에는 결합성을 좋게하기 위하여 가황제나 각종의 안정제를 사용하기 때문에 이를 사용하는 사용자들의 인체에 상당한 악영향을 미치게 된다.Generally, vulcanizing agents or various stabilizers are used to improve binding properties in rubber gloves or shoes used for household, industrial and medical purposes, footwear such as rubber boots and rubber shoes, and contraceptive aids such as condoms or raw rubber. The user's body will have a significant adverse effect.
이는 고무제품의 특성상 통기가 원활하지 못하기 때문에 고무제품을 착용한 부위에서 발생하는 땀과 상기 땀으로 인하여 누적되는 오염물질로 인하여 심한 악취가 발생하게 되고, 곰팡이와 같은 유해균의 발생으로 습진, 피부각질과 같은 피부병을 불러와 피부의 손상과 노화를 촉진시키는 문제점을 가졌었다.This is due to the nature of the rubber product is not well ventilated due to the sweat generated in the area wearing the rubber product and the contaminants accumulated by the sweat causes a bad odor, eczema, skin caused by the generation of harmful bacteria such as mold It has a problem of causing skin diseases such as keratin and promoting skin damage and aging.
특히 상기와 같은 고무제품을 고온 다습한 지역에서 장시간(장기간)동안 연속적인 작업이 이루어질 경우에는 이러한 현상이 더욱더 심화되는 등의 문제점들이 있었다.In particular, when a continuous operation is performed for a long time (long term) in a high temperature and high humidity region, such a phenomenon has been further intensified.
이에 본 발명에서는 상기와 같은 문제점들을 해결하기 위하여 발명된 것으로서 통상적인 고무제품 조성물에 상온에서 원적외선이 방사되는 원적외선방사물질분말을 첨가함으로서;In the present invention, by adding a far-infrared radiation substance powder that is far-infrared at room temperature to a conventional rubber product composition as invented to solve the above problems;
상기 조성물로 제조한 각종의 고무제품에서 원적외선의 방사와 항균, 제습 밑 탈취등의 기능으로 인한 사용자들의 인체에 유익함을 줄 수 있도록 함을 목적으로 한다.The purpose of the present invention is to provide benefits to the human body due to functions such as radiation and antibacterial, dehumidification and deodorization under far infrared rays in various rubber products prepared by the composition.
이하 본 발명의 기술이 적용되는 디핑형성 고무제품 성형용 조성물과 그 제조방법에 대한 바람직한 실시예를 상세하게 설명하면 다음과 같다.Hereinafter will be described in detail a preferred embodiment of the composition for forming a dipping-forming rubber product to which the technique of the present invention is applied and a method for producing the same.
본 발명에서는 통상적인 고무제품을 생산하기 위한 공지된 조성물에 상온에서 다량의 원적외선과 음이온이 방사되도록 원적외선 및 음이온 방사물질분말(이하 원적외선방사물질분말이라 한다.)을 상온에서 충분히 혼합하여 교질상의 조성물을 얻도록 함을 특징으로 한다.In the present invention, the far-infrared and anion emitting material powder (hereinafter referred to as far-infrared radioactive material powder) is sufficiently mixed at room temperature so that a large amount of far infrared rays and anions are radiated to a known composition for producing a conventional rubber product at room temperature. It characterized in that to obtain.
상기한 공지의 조성물에 혼합하는 원적외선방사물질분말은 정제된 숯분말과 맥반석분말중 하나의 분말만을 선택하거나 두종류의 분말을 동시에 선택하여 일정한 중량비율로 혼합하여 사용한다.The far-infrared radiation substance powder to be mixed in the above known composition may be used by selecting only one powder of purified charcoal powder and elvan stone powder or by simultaneously selecting two kinds of powders and mixing them at a constant weight ratio.
상기 원적외선방사물질분말로 사용되는 숯분말과 맥반석분말은 하기와 같은 특성을 지니고 있다.The charcoal powder and elvan stone powder used as the far-infrared radiation substance powder have the following characteristics.
숯분말의 경우에는 주성분을 이루는 탄소와 칼슘, 칼륨등을 함유하고 있는 미네랄로 구성되어 항균과 제습 및 탈취기능이 뛰어나다.In the case of charcoal powder, it is composed of minerals containing carbon, calcium, potassium, etc., which are main components, and has excellent antibacterial, dehumidifying, and deodorizing functions.
맥반석분말의 경우에는 장석, 무수규산, 산화알미늄과 미네랄로 구성되어 수분을 만나면 강한 흡락력을 가지고 있어 수은, 카드뮴, 시안, 염소 및 각종세균과 같은 유해물질을 흡착하고;Elvanite powder is composed of feldspar, silicic anhydride, aluminum oxide and minerals, and has strong absorption power when it meets moisture to adsorb harmful substances such as mercury, cadmium, cyanide, chlorine and various bacteria;
미네랄을 용출하며 수질조성의 특성으로 경도가 높은 수질을 연수화시키는 특성과 용존산소량이 증대하게 되는 특성을 가진다.Minerals are eluted and the water quality is softened and the dissolved oxygen content is increased.
상기와 같은 특성을 가지는 숯분말과 맥반석분말로 구성되는 원적외선방사물질분말은;Far-infrared radiation substance powder composed of charcoal powder and elvan stone powder having the above characteristics;
고무와 원적외선방사물질분말의 총중량 기준으로 가류되지 않은 천연고무를 용제로 용해시켜 형성된 고형분 50∼60중량％를 함유한 교질상의 액체이며 고무 90∼95％ 중량에 5∼10％ 중량으로 첨가한다.It is a colloidal liquid containing 50 to 60% by weight of solids formed by dissolving natural rubber which is not vulcanized based on the total weight of rubber and far-infrared radioactive material powder with a solvent, and is added in an amount of 5 to 10% by weight to 90 to 95% by weight of rubber.
상기 원적외선방사물질분말을 고무 90∼95％중량에 첨가할 시 각각의 바람직한 중량비는 고무와 원적외선방사물질분말의 총질량 기준으로 숯분말1∼3％중량, 맥반석분말 4∼7％중량을 적절한 상태로 가변하면서 첨가한다.When the far-infrared radiation substance powder is added to 90 to 95% by weight of rubber, each preferable weight ratio is 1 to 3% by weight of charcoal powder and 4 to 7% by weight of elvan powder based on the total mass of rubber and far-infrared radiation substance powder. Add while varying.
상기와 같은 숯분말과 맥반석분말로 구성되는 원적외선방사물질분말은 약 5∼1㎛크기의 입자로 섭시 1000℃이상의 온도로 소결하여 형성한다.The far-infrared radiation substance powder composed of charcoal powder and elvan rock powder is formed by sintering at a temperature of 1000 ° C. or more with particles of about 5 to 1 μm in size.
상기와 같은 조성물을 이용하여 각종의 고무제품을 성형하는 실시예를 설명하면 다음과 같다.An embodiment of molding various rubber products using the composition as described above is as follows.
(실시예 1)(Example 1)
고형분이 60％ 포함된 생고무 또는 합성고무 90∼95중량％와 숯분말 1∼3중량％와 맥반석분말 4∼7중량％로 혼합 조성된 조성물에 상기 조성물의 총질량에 대하여 기 설정된 일정비율로 가황제 및 안정제를 포함한 다른 조성물을 혼합하여 디핑조에 담는다.90 to 95% by weight of raw or synthetic rubber containing 60% of solid content, 1 to 3% by weight of charcoal powder and 4 to 7% by weight of ganban stone powder are vulcanized at a predetermined ratio with respect to the total mass of the composition. Other compositions, including agents and stabilizers, are mixed and placed in a dipping bath.
상기와 같은 조성물을 이용하여 가정용고무장갑을 얻고자 할 경우에는;If you want to obtain household rubber gloves using the composition as described above;
고무장갑 형태의 몰드를 디핑조에 침지시켜 기 설정된 소정시간 만큼 건조시킨 후 2차 침지시켜 0.5㎜ 두께범위의 고무장갑을 얻는다.A rubber glove-type mold is immersed in a dipping tank, dried for a predetermined time, and then immersed in a second to obtain a rubber glove having a thickness range of 0.5 mm.
상기와 같이 성형된 고무장갑은 상온에서 88％의 원적외선 방사율을 나타내고 대장균은 24시간 후 85.8％가 소멸되고 녹농균은 84.6％가 소멸 되었으며, 방사에너지는 3.54 × 10²(W/㎡.㎛.40℃)가 된다.The rubber gloves formed as described above exhibited 88% far-infrared emissivity at room temperature, E. coli was extinguished after 85.8%, Pseudomonas aeruginosa was extinct 84.6%, and radiation energy was 3.54 × 10² (W / ㎡.㎛.40 ℃). )
상기와 같은 고무장갑을 사용할 경우에는, 탈색, 악취가 발생하지 않고 숯분말 및 맥반석분말로 구성된 원적외선방사물질분말로부터 방사되는 원적외선 및 음이온에 의하여 피부질환의 심화현상이 현저하게 줄어들고, 방사되는 원적외선에 의하여 신진대사의 활성화로 피로감이 격감되는 등의 효과를 얻게 된다.In the case of using the rubber gloves as described above, the deepening of skin diseases is significantly reduced by far infrared rays and anions emitted from the far-infrared radiation substance powder composed of charcoal powder and elvan rock powder without discoloration and odor. By this, the activation of metabolism, such as fatigue is reduced.
(실시예 2)(Example 2)
상기와 같은 조성물로 고무장화를 얻기 위해서는 고무장화 몰드를 상기 조성물에 침지시켜 고무장갑을 얻을 때의 침시시간과 건조시간을 조절하여 두께가 1㎜가 되도록 하면 된다.In order to obtain rubber boots with the composition as described above, the rubber boot mold may be immersed in the composition to adjust the immersion time and the drying time when the rubber gloves are obtained to have a thickness of 1 mm.
상기와 같이 얻어진 고무장화는 고무장갑과 동일한 효과를 얻을 수 있게된다.The rubber boots obtained as described above can achieve the same effects as the rubber gloves.
(실시예 3)(Example 3)
고형분이 50％ 포함된 생고무 또는 합성고무 90∼95중량％와 숯분말 1∼3중량％와 맥반석 분말 4∼7중량％로 혼합된 조성물에 상기 조성물의 총중량에 대하여 기 설정된 일정비율로 가황제 및 안정제를 포함한 다른 조성물을 혼합하여 디핑조에 담는다.Vulcanizing agent in a predetermined ratio with respect to the total weight of the composition in a composition mixed with 90 to 95% by weight of raw or synthetic rubber containing 50% of solid content, 1 to 3% by weight of charcoal powder and 4 to 7% by weight of ganban stone powder Other compositions, including stabilizers, are mixed and placed in the dipping bath.
상기 디핑조에 의료용 고무장갑 또는 콘돔의 몰드를 침지시킨 후 건조과정을 반복하여 0.2㎜두깨범위의 의료용 고무장갑이나 콘돔을 얻는다.After immersing the mold of medical rubber gloves or condoms in the dipping tank, the drying process is repeated to obtain medical rubber gloves or condoms in the 0.2 mm thickness range.
상기와 같이 얻어진 의료용 고무장갑 및 콘돔을 사용할 경우에는 1실시예의 효과와 동일한 효과를 얻을 수 있으며, 의료용 고무장갑 및 콘돔 사용과정에서 발생할 수 있는 병원균의 전염이 방지되고 사용자의 위생건강에 기여할 수 있게된다.When using the medical rubber gloves and condoms obtained as described above can achieve the same effect as in the first embodiment, to prevent the transmission of pathogens that can occur in the process of using medical rubber gloves and condoms to contribute to the user's hygiene health do.
상기와 같은 본 발명은 원적외선방사물질분말이 가지는 항균, 제습, 탈취기능과 원적외선 및 음이온의 방출로 생체조직의 활성황로 인한 피부손상과 노화를 방지하고 혈액순환의 촉진으로 사용자의 피로도를 격감시킬 수 있는 등의 효과를 가진다.The present invention as described above is to prevent skin damage and aging caused by active sulfur of biological tissues by antibacterial, dehumidifying, deodorizing function and the release of far infrared rays and anions of the far-infrared radioactive material powder to reduce the fatigue of the user by promoting blood circulation It can have such effects.
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| KR1019990008988A KR19990046469A (en) | 1999-03-17 | 1999-03-17 | Matter of dip molding for rubber goods |
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| KR1019990008988A KR19990046469A (en) | 1999-03-17 | 1999-03-17 | Matter of dip molding for rubber goods |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100357912B1 (en) * | 2000-07-11 | 2002-10-25 | 조홍주 | Method for materials of soft precious stone mattress with restitutive force |
| KR20030045448A (en) * | 2001-12-04 | 2003-06-11 | 이경회 | Condom |
| KR100789402B1 (en) * | 2005-11-25 | 2007-12-28 | 민영혜 | Negative ion or ultrared foamy rubber |
-
1999
- 1999-03-17 KR KR1019990008988A patent/KR19990046469A/en not_active Application Discontinuation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100357912B1 (en) * | 2000-07-11 | 2002-10-25 | 조홍주 | Method for materials of soft precious stone mattress with restitutive force |
| KR20030045448A (en) * | 2001-12-04 | 2003-06-11 | 이경회 | Condom |
| KR100789402B1 (en) * | 2005-11-25 | 2007-12-28 | 민영혜 | Negative ion or ultrared foamy rubber |
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| A201 | Request for examination | ||
| E902 | Notification of reason for refusal | ||
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