KR20000013781A - Anti-bacterial surface coating composition for sanitary rubber glove - Google Patents
Anti-bacterial surface coating composition for sanitary rubber glove Download PDFInfo
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- KR20000013781A KR20000013781A KR1019980032846A KR19980032846A KR20000013781A KR 20000013781 A KR20000013781 A KR 20000013781A KR 1019980032846 A KR1019980032846 A KR 1019980032846A KR 19980032846 A KR19980032846 A KR 19980032846A KR 20000013781 A KR20000013781 A KR 20000013781A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
Abstract
Description
본 발명은 위생용 고무장갑의 항균성 표면 코팅제 조성물에 관한 것이다.The present invention relates to an antimicrobial surface coating composition of hygienic rubber gloves.
일반적인 위생용 고무장갑은 천연고무 라텍스, 충진제, 노화방지제, 소포제 등을 배합하여 전가류 공정을 거쳐 2회의 디핑공정을 통하여 제조하며, 장갑 표면의 점착성을 없애주고 착용이 편리하게 하기 위하여 후처리 공정으로, 염소화 공정을 실시하거나 또는 활석분말과 옥수수 전분가루 등을 장갑의 표면에 처리한다.General hygienic rubber gloves are manufactured through two dipping processes after mixing with natural rubber latex, filler, anti-aging agent, antifoaming agent, and after finishing process to remove adhesiveness of glove surface and to be convenient to wear. The chlorination process is carried out or talc powder and corn starch powder are treated on the surface of the gloves.
그러나, 상기의 공정으로 제조된 위생용 고무장갑을 착용할 경우, 일반적으로 삽입과정에서 손가락과 손에 점착을 느끼며, 장시간 착용할 경우 땀이 나면서 습기가 차고, 습진이 발생하여 피부가 짓무르게 되는 현상이 나타난다.However, when wearing the hygienic rubber gloves manufactured by the above process, generally feel the adhesion to the fingers and hands during the insertion process, if worn for a long time sweating and moisture, eczema occurs and the skin becomes crushed The phenomenon appears.
미국특허 제3,411,982호에서는 염소화 공정을 도입하여 장갑의 외부면을 개질시켜 원하는 정도의 슬립성을 갖는 공정개발에 관해 해결책을 발표하였고, 미국특허 제3,740,262호는 외과 수술용 장갑에서 파우더에 의한 환경오염문제를 최소화하는 제조방법을 발표하여 주목을 받았다. 이들 염소화 공정 기술은 다음과 같이 행해진다.U.S. Patent No. 3,411,982 proposes a solution for the development of a process having the desired degree of slipping by modifying the outer surface of the glove by introducing a chlorination process, and U.S. Patent No. 3,740,262 by environmental pollution caused by powder in surgical gloves Attention has been paid to the announcement of a manufacturing method that minimizes problems. These chlorination process techniques are performed as follows.
즉, 1 내지 5%의 염소를 포함하고 있는 차아염소산나트륨 용액에 장갑을 약 8 내지 10초간 담그고, 즉시 장갑을 옮겨 세척하여 건조한 후, 12% 염산 용액에 8 내지 10초간 담근다. 이러한 공정을 장갑 내부면에 대하여 여러번 반복한다.That is, the gloves are immersed in a sodium hypochlorite solution containing 1 to 5% chlorine for about 8 to 10 seconds, immediately moved to wash the gloves, dried, and then soaked in 12% hydrochloric acid solution for 8 to 10 seconds. This process is repeated several times for the inner surface of the glove.
또한, 미국특허 제3,326,742호와 제3,585,103호 및 영국특허공개 제1,028,446호는 히드로겔 고분자 용액을 고무장갑의 외부면과 내부면에 코팅하여 슬립성을 증가시켜 착용시 점착으로 발생하는 문제들을 해결하는 방법을 제시하였다. 여기서, 히드로겔 고분자 용액은 폴리비닐피롤리돈, 폴리히드록시에틸메타크릴레이트, 폴리메틸메타크릴레이트, 폴리히드록시프로필아크릴레이트 등의 단일 중합체 및 이들의 공중합체를 사용하고 있다.In addition, U.S. Patent Nos. 3,326,742 and 3,585,103 and U.S. Patent Publication No. 1,028,446 coat hydrogel polymer solutions on the outer and inner surfaces of rubber gloves to increase slip properties to solve problems caused by sticking when worn. The method is presented. Here, the hydrogel polymer solution uses homopolymers and copolymers thereof such as polyvinylpyrrolidone, polyhydroxyethyl methacrylate, polymethyl methacrylate and polyhydroxypropyl acrylate.
그러나, 상기의 종래 기술들로 제조된 장갑들은 항균성이 없으며, 장시간 착용할 경우 냄새가 나는 문제가 있으며, 피부에 생기는 습진, 짓무름 현상 등의 부작용 문제를 해결하지 못하였다.However, the gloves prepared by the prior art are not antibacterial, there is a problem that smells when worn for a long time, did not solve the side effects such as eczema, sores on the skin.
본 발명자는 상기와 같은 종래기술의 문제점을 해결하기 위하여 연구한 결과, 항균성 표면 코팅제 조성물을 제조하고, 이를 이용하여 위생용 고무장갑을 제조함으로써 슬립성과 착용 감각이 우수하고, 항균성이 부여된 신 기능성 위생용 고무장갑을 제조할 수 있음을 알게되어 본 발명에 이르게 되었다.The present inventors have studied in order to solve the problems of the prior art as a result, by producing an antimicrobial surface coating composition, by using it to produce hygienic rubber gloves excellent slip and wear feeling, new functionality given antibacterial It has been found that the hygienic rubber gloves can be produced, which leads to the present invention.
이에 본 발명은 위생용 고무장갑의 항균성 표면 코팅제 조성물을 제공하는 것을 목적으로 한다.Accordingly, an object of the present invention is to provide an antimicrobial surface coating composition of the hygienic rubber gloves.
또한, 본 발명은 위생용 고무장갑의 항균성 표면 코팅제 조성물을 이용하여 항균성을 가지며, 착용이 편리하고, 착용감이 우수하며, 피부 부작용의 문제점이 상당히 개선되고, 기존의 제조공정에서 후처리공정을 개선하여 공정이 훨씬 단축된 위생용 고무장갑을 제공하는 것을 목적으로 한다.In addition, the present invention has antimicrobial properties using the antimicrobial surface coating composition of the hygienic rubber gloves, easy to wear, excellent wearing comfort, significantly improve the problem of skin side effects, and improve the post-treatment process in the existing manufacturing process It is an object of the present invention to provide hygienic rubber gloves with a much shorter process.
본 발명은 위생용 고무장갑의 항균성 표면 코팅제 조성물에 관한 것이다.The present invention relates to an antimicrobial surface coating composition of hygienic rubber gloves.
본 발명의 위생용 고무장갑의 항균성 표면 코팅제 조성물은 수분산성 폴리우레탄 수지 100 중량부에 대하여, 유기산 아연 0.01 내지 30 중량부로 이루어진다.The antimicrobial surface coating composition of the hygienic rubber gloves of the present invention comprises 0.01 to 30 parts by weight of an organic acid zinc based on 100 parts by weight of a water dispersible polyurethane resin.
또다른 본 발명의 위생용 고무장갑의 항균성 표면 코팅제 조성물은 수분산성 폴리우레탄 수지 100 중량부에 대하여, 무기계 항균제 0.01 내지 30 중량부로 이루어진다.Another antimicrobial surface coating composition of the hygienic rubber gloves of the present invention is composed of 0.01 to 30 parts by weight of the inorganic antibacterial agent based on 100 parts by weight of the water dispersible polyurethane resin.
또다른 본 발명의 위생용 고무장갑의 항균성 표면 코팅제 조성물은 수분산성 폴리우레탄 수지 100 중량부에 대하여, 수용성 키토산 0.01 내지 30 중량부로 이루어진다.Another antimicrobial surface coating composition of the hygienic rubber gloves of the present invention comprises 0.01 to 30 parts by weight of water-soluble chitosan, based on 100 parts by weight of the water dispersible polyurethane resin.
또다른 본 발명의 위생용 고무장갑의 항균성 표면 코팅제 조성물은 수분산성 폴리우레탄 수지 100 중량부에 대하여, 유기산 아연, 무기계 항균제, 및 수용성 키토산 각각 0.01 내지 30 중량부로 이루어진다.Another antimicrobial surface coating composition of the hygienic rubber gloves of the present invention comprises 0.01 to 30 parts by weight of zinc organic acid, inorganic antibacterial agent, and water-soluble chitosan, respectively, based on 100 parts by weight of the water dispersible polyurethane resin.
본 발명에서 수분산성 폴리우레탄 수지는 천연고무 장갑의 표면과 항균제를 서로 결합시켜주는 표면 개질제의 기능을 하며, 황 및 설폰산기와 카르복실기를 함유하고 있다.In the present invention, the water-dispersible polyurethane resin functions as a surface modifier that binds the surface of the natural rubber gloves and the antimicrobial agent to each other, and contains sulfur and sulfonic acid groups and carboxyl groups.
본 발명에서 사용하는 수분산성 폴리우레탄 수지로는 에스테르폴리올, 에테르폴리올, 디올, 히드록시에틸메타크릴레이트와 아크릴산의 공중합체, 지방족 디이소시아네이트, 또는 방향족 디이소시아네이트로 이루어진, 산성 또는 염기성 수분산성 폴리우레탄계 수지를 사용할 수 있다.The water-dispersible polyurethane resin used in the present invention includes an ester polyol, an ether polyol, a diol, a copolymer of hydroxyethyl methacrylate and acrylic acid, an aliphatic diisocyanate, or an aromatic diisocyanate. Resin can be used.
상기와 같은 위생용 고무장갑의 항균성 표면 코팅제 조성물을 제조함으로써 항균성을 가지면서 착용이 편리하고, 착용감이 좋으며 피부 부작용의 문제점이 개선된 위생용 고무장갑을 제조할 수 있다.By preparing the antimicrobial surface coating composition of the hygienic rubber gloves as described above, it is possible to manufacture a hygienic rubber gloves having antimicrobial properties and being comfortable to wear, having a good fit, and improving the problem of skin side effects.
본 발명에 따라 항균성 표면 코팅제 조성물을 이용한 위생용 고무장갑은 다음과 같은 방법으로 제조할 수 있다.Hygienic rubber gloves using the antimicrobial surface coating composition according to the present invention can be prepared by the following method.
본 발명에 따라서, 위생용 고무장갑의 제조방법에 있어서, 장갑을 통상의 위생용 고무장갑용 배합라텍스에 1회 디핑한 후, 이어서 본 발명의 항균성 표면 코팅제 조성물에 디핑하고, 가황을 실시하여 장갑의 내부면에 항균성을 갖도록 할 수 있다.According to the present invention, in the method for producing hygienic rubber gloves, the gloves are dipped once in the compounded latex for ordinary hygienic rubber gloves, and then dipped into the antimicrobial surface coating composition of the present invention, followed by vulcanization. It can be made to have an antibacterial property on the inner surface.
또다른 구현예에 의하면, 위생용 고무장갑의 제조방법에 있어서, 통상의 위생용 고무장갑의 배합라텍스에 제 5항에 따른 무기계 항균제를 배합하고, 이어서 응고제가 묻어 있는 형틀을 배합 탱크에 디핑한 후에, 본 발명의 항균성 표면 코팅제 조성물에 디핑하고, 가황을 실시하여 장갑의 내부면에 항균성을 갖도록 할 수 있다.According to another embodiment, in the manufacturing method of the hygienic rubber gloves, the inorganic antibacterial agent according to claim 5 is blended with the compounding latex of the conventional hygienic rubber gloves, and then the mold containing the coagulant is dipped into the mixing tank. Thereafter, the antimicrobial surface coating composition of the present invention can be dipped and vulcanized to have antimicrobial properties on the inner surface of the glove.
본 발명에 따른 위생용 고무장갑의 제조방법을 더욱 상세히 설명하면 다음과 같다.When explaining the manufacturing method of the hygienic rubber gloves according to the present invention in more detail.
먼저, 공지의 배합라텍스를 숙성시킨 라텍스에 응고제가 묻은 형틀을 1회 디핑하여 건조한 후, 이어서 항균성을 갖는 표면 코팅제 용액을 1회 디핑하여 라텍스 표면을 개질시킨다. 이어서 150℃로 20분 동안 가황공정을 거쳐 두께가 0.5㎜인 항균성 위생용 고무장갑을 제조한다.First, a mold containing a coagulant is dipped into a latex, in which a known compound latex is aged, and dried, and then a surface coating solution having antibacterial properties is dipped once to modify the latex surface. Subsequently, an antimicrobial hygiene rubber glove having a thickness of 0.5 mm was prepared through a vulcanization process at 150 ° C. for 20 minutes.
상기에서, 숙성라텍스는 다음과 같이 제조한다.In the above, the aged latex is prepared as follows.
60% 천연고무 라텍스 100 중량부, 50% 황 0.5 내지 2 중량부, ZnO 0 내지 2 중량부, TiO20 내지 2 중량부, 디티오카르밤산 디에틸 아연(이하, 'Ez'이라 함) 0.1 내지 2 중량부, KOH 0.1 중량부, 노화방지제 0.2 중량부, 디티오카르밤산 디부틸 나트륨(이하, 'TP'라 함) 0.1 내지 2 중량부, 소포제 0.16 중량부의 성분을 배합탱크에서 일정하게 혼합 분쇄하여 25℃ 내지 70℃의 온도범위에서 0 내지 100시간 동안 숙성하여 숙성라텍스를 제조한다.100 parts by weight of 60% natural rubber latex, 0.5 to 2 parts by weight of 50% sulfur, 0 to 2 parts by weight of ZnO, 0 to 2 parts by weight of TiO 2 , diethyl zinc dithiocarbamate (hereinafter referred to as 'Ez') 0.1 To 2 parts by weight, KOH 0.1 parts by weight, antioxidants 0.2 parts by weight, dithiocarbamate dibutyl sodium (hereinafter referred to as 'TP') 0.1 to 2 parts by weight, antifoaming agent 0.16 parts by weight of the ingredients in the mixing tank Grinding and aging for 0 to 100 hours in the temperature range of 25 ℃ to 70 ℃ to produce a mature latex.
상기에서, 항균성을 갖는 표면 코팅제는 다음과 같이 제조한다.In the above, the surface coating agent having antimicrobial properties is prepared as follows.
즉, 또다른 배합탱크에서, 폴리아크릴산, 폴리메틸메타크릴레이트, 폴리비닐아세테이트 또는 폴리메타크릴산의 아크릴계 중합체 90 내지 10 중량부, 유기산 아연화합물 30 중량부, 수용성 키토산 10 중량부, 실리카 또는 제올라이트의 충진제 1 내지 70 중량부를 혼합하여 항균성 표면 코팅제를 제조한다.That is, in another blending tank, 90 to 10 parts by weight of an acrylic polymer of polyacrylic acid, polymethyl methacrylate, polyvinylacetate or polymethacrylic acid, 30 parts by weight of an organic acid zinc compound, 10 parts by weight of water-soluble chitosan, silica or zeolite 1 to 70 parts by weight of the filler is mixed to prepare an antimicrobial surface coating.
이렇게 제조된, 숙성라텍스와 항균성 표면 코팅제를 이용한 위생용 고무장갑의 제조방법을 상세히 설명하면 다음과 같다.Thus, the manufacturing method of the hygienic rubber gloves using the aged latex and antimicrobial surface coating agent will be described in detail.
응고제가 묻은 손모양의 형틀을 숙성된 배합라텍스에 1회 디핑하고, 형틀에 일정하게 묻어 있는 배합라텍스를 항균성 표면 코팅제에 1회 디핑한 후, 이어서 150℃로 20분 동안 가황공정을 실시한 후, 이어서 인위적으로 형틀의 가황된 위생용 고무 장갑을 벗겨 후처리 공정을 하지 않고 곧바로 표면이 개질된 위생용 고무장갑을 제조한다.After dipping the hand-shaped mold with the coagulant into the aged compound latex, and dipping the compounded latex with the mold uniformly into the antimicrobial surface coating once, followed by a vulcanization process at 150 ° C. for 20 minutes. Subsequently, the vulcanized sanitary rubber gloves of the mold are peeled off to prepare the sanitary rubber gloves with the surface modified immediately without the post-treatment process.
이하, 실시예에 의거하여 본 발명을 더욱 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to Examples.
실시예1Example 1
교반기가 부착된 500㎖ 플라스크에 60% 천연고무 라텍스 100g, 50% 황 1g, ZnO 2g, TiO22g, Ez 2g, KOH 0.1g, 노화방지제 0.2g, TP 0.1g, 소포제 0.16g의 성분을 배합탱크에서 일정하게 혼합 분쇄하여 28℃의 온도에서 56시간 동안 숙성하여 숙성라텍스를 제조하였다. 이어서 숙성된 라텍스에 응고제 용액(Ca(NO3)2·4H2O + 에탄올 + 계면활성제)이 묻어 있는 형틀을 디핑한 다음, 이어서 150℃로 20분 동안 가황공정을 거쳐 두께가 0.5㎜인 위생용 고무 장갑을 제조하였다.In a 500 ml flask equipped with a stirrer, 60% natural rubber latex 100g, 50% sulfur 1g, ZnO 2g, TiO 2 2g, Ez 2g, KOH 0.1g, antioxidant 0.2g, TP 0.1g, antifoam 0.16g The mixture was mixed and ground in a tank and aged at a temperature of 28 ° C. for 56 hours to prepare a mature latex. Subsequently, the mold was dipped in a coagulation solution (Ca (NO 3 ) 2 .4H 2 O + ethanol + surfactant) on the aged latex, followed by a vulcanization process at 150 ° C. for 20 minutes to a thickness of 0.5 mm. Rubber gloves were prepared.
실시예 2Example 2
항균성 표면 코팅제의 성분비 배합을 다음 표 1과 같이 제조한 것을 실시예 1의 손모양의 형틀에 묻어있는 숙성 라텍스 표면에 디핑하고, 이어서 실시예 1과 같은 방법으로 가황공정을 실시한 후, 항균성을 갖는 위생용 고무장갑을 제조하였다.The ingredient ratio of the antimicrobial surface coating agent was prepared as shown in the following Table 1 on the aged latex surface buried in the hand-shaped mold of Example 1, and then subjected to a vulcanization process in the same manner as in Example 1, and then having antibacterial properties. Hygienic rubber gloves were prepared.
실시예 3Example 3
항균성 표면 코팅제의 성분비 배합을 다음 표 2와 같이 제조한 것을 실시예 1의 손모양의 형틀에 묻어있는 숙성 라텍스 표면에 디핑하고, 이어서 실시예 1과 같은 방법으로 가황공정을 실시한 후, 항균성을 갖는 위생용 고무장갑을 제조하였다.The ingredient ratio of the antimicrobial surface coating agent was prepared as shown in the following Table 2 on the surface of the mature latex buried in the hand-shaped mold of Example 1, and then subjected to a vulcanization process in the same manner as in Example 1, and then having antibacterial properties. Hygienic rubber gloves were prepared.
실시예 4Example 4
항균성 표면 코팅제의 성분비 배합을 실시예 2의 표 1의 배합에서 수용성 키토산 대신에 은계 제올라이트를 10 중량부를 첨가하여 제조한 것을 실시예 2와 동일한 방법으로 실시하였다.The ingredient ratio of the antimicrobial surface coating agent was prepared by adding 10 parts by weight of silver zeolite in place of the water-soluble chitosan in the formulation of Table 1 of Example 2 in the same manner as in Example 2.
실시예 5Example 5
항균성 표면 코팅제의 성분비 배합을 실시예 3의 표 2의 배합에 은계 제올라이트를 10 중량부를 첨가하여 제조한 것을 실시예 2와 동일한 방법으로 실시하였다.A component ratio of the antimicrobial surface coating agent was prepared by adding 10 parts by weight of a silver zeolite to the formulation of Table 2 of Example 3 in the same manner as in Example 2.
실시예 6Example 6
실시예 1에서 숙성시킨 배합 라텍스 화합물에 은계 제올라이트 10 중량부를 혼합하고, 이어서 응고제가 묻어 있는 형틀을 배합탱크에 디핑한 다음, 실시예 2 내지 5에서 제조한 항균성 표면 코팅제를 실시예 1의 손모양의 형틀에 묻어 있는 숙성라텍스 표면에 디핑하고, 이어서 실시예 1과 같은 방법으로 가황공정을 실시한 후, 항균성을 갖는 위생용 고무장갑을 제조하였다.10 parts by weight of silver zeolite was mixed with the compounded latex compound aged in Example 1, and then the mold containing the coagulant was dipped into the compounding tank, and then the antimicrobial surface coating agent prepared in Examples 2 to 5 was hand-shaped. After dipping on the surface of the aged latex buried in the mold, and then subjected to the vulcanization process in the same manner as in Example 1, hygienic rubber gloves having antibacterial properties were prepared.
* 시험방법 : 가압밀착법* Test method: Pressurization
* 시험조건 : 시험균액을 25℃, 24시간 정치배양 후 균수 측정(시료 표면적 : 60㎠)* Test condition: Test bacteria after 25 ℃, standing culture for 24 hours, the number of bacteria (sample surface area: 60㎠)
본 발명의 항균성 표면 코팅제 조성물을 이용하여 항균성을 가지며, 착용이 편리하고, 착용감이 우수하며, 피부 부작용의 문제점이 상당히 개선되고, 기존의 제조공정에서 후처리공정을 개선하여 공정이 훨씬 단축된 위생용 고무장갑을 제공할 수 있다.Using antimicrobial surface coating composition of the present invention has antimicrobial properties, easy to wear, excellent wearing comfort, significantly improved problems of skin side effects, improved post-treatment process in the existing manufacturing process much shorter sanitation Rubber gloves can be provided.
Claims (6)
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| Application Number | Priority Date | Filing Date | Title |
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| KR1019980032846A KR20000013781A (en) | 1998-08-13 | 1998-08-13 | Anti-bacterial surface coating composition for sanitary rubber glove |
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| KR1019980032846A KR20000013781A (en) | 1998-08-13 | 1998-08-13 | Anti-bacterial surface coating composition for sanitary rubber glove |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20010044366A (en) * | 2001-02-13 | 2001-06-05 | 임정기 | Method for producing a water-soluble coating to suppress the generation of moss in the net. |
| KR20020001896A (en) * | 2000-03-24 | 2002-01-09 | 김희정 | Method for Manufacturing Antibacterial Sanitary Goods Using Natural Rubber Latex |
| KR20020063462A (en) * | 2001-01-29 | 2002-08-03 | 원인호 | Manufacture of work safety gloves |
| KR100530940B1 (en) * | 2002-07-26 | 2005-12-07 | 구창모 | binder paste having moisture-absorbing, antibiotic and deodorizing function and socks comprising the binder paste |
| KR100665719B1 (en) * | 2005-03-19 | 2007-01-09 | 이기율 | Method for produce of Rubber gloves contain Nano silver |
| KR100750604B1 (en) * | 2006-04-06 | 2007-08-20 | 한국조폐공사 | The formation of water soluble antibiosis intaglio ink |
| KR102007434B1 (en) * | 2018-10-24 | 2019-08-06 | 이태희 | Waterproof painting membrane composition for water treatment system |
| CN112778814A (en) * | 2020-12-29 | 2021-05-11 | 南京凯创协同纳米技术有限公司 | Preparation method of long-acting antibacterial mildew remover capable of spraying to form film |
| KR20210074041A (en) * | 2019-12-11 | 2021-06-21 | (주)도꼬마리 | Composition for glove coating containing zeolite, water-soluble urea coated glove coated with composition and method |
| CN115466435A (en) * | 2022-09-27 | 2022-12-13 | 常州市五洲化工有限公司 | Special vulcanization system composition for carboxylated nitrile rubber and preparation method thereof |
| KR20230141064A (en) | 2022-03-31 | 2023-10-10 | 남가휘 | Anti-bacterial resin omposition |
-
1998
- 1998-08-13 KR KR1019980032846A patent/KR20000013781A/en not_active Application Discontinuation
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020001896A (en) * | 2000-03-24 | 2002-01-09 | 김희정 | Method for Manufacturing Antibacterial Sanitary Goods Using Natural Rubber Latex |
| KR20020063462A (en) * | 2001-01-29 | 2002-08-03 | 원인호 | Manufacture of work safety gloves |
| KR20010044366A (en) * | 2001-02-13 | 2001-06-05 | 임정기 | Method for producing a water-soluble coating to suppress the generation of moss in the net. |
| KR100530940B1 (en) * | 2002-07-26 | 2005-12-07 | 구창모 | binder paste having moisture-absorbing, antibiotic and deodorizing function and socks comprising the binder paste |
| KR100665719B1 (en) * | 2005-03-19 | 2007-01-09 | 이기율 | Method for produce of Rubber gloves contain Nano silver |
| KR100750604B1 (en) * | 2006-04-06 | 2007-08-20 | 한국조폐공사 | The formation of water soluble antibiosis intaglio ink |
| KR102007434B1 (en) * | 2018-10-24 | 2019-08-06 | 이태희 | Waterproof painting membrane composition for water treatment system |
| KR20210074041A (en) * | 2019-12-11 | 2021-06-21 | (주)도꼬마리 | Composition for glove coating containing zeolite, water-soluble urea coated glove coated with composition and method |
| CN112778814A (en) * | 2020-12-29 | 2021-05-11 | 南京凯创协同纳米技术有限公司 | Preparation method of long-acting antibacterial mildew remover capable of spraying to form film |
| KR20230141064A (en) | 2022-03-31 | 2023-10-10 | 남가휘 | Anti-bacterial resin omposition |
| CN115466435A (en) * | 2022-09-27 | 2022-12-13 | 常州市五洲化工有限公司 | Special vulcanization system composition for carboxylated nitrile rubber and preparation method thereof |
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