KR20000038404A - Waterproofing composition for coating wood sock panel - Google Patents

Waterproofing composition for coating wood sock panel Download PDF

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Publication number
KR20000038404A
KR20000038404A KR1019980053395A KR19980053395A KR20000038404A KR 20000038404 A KR20000038404 A KR 20000038404A KR 1019980053395 A KR1019980053395 A KR 1019980053395A KR 19980053395 A KR19980053395 A KR 19980053395A KR 20000038404 A KR20000038404 A KR 20000038404A
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South Korea
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weight
parts
desiccant
wood
waterproof
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KR1019980053395A
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Korean (ko)
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KR100294575B1 (en
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박춘근
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박춘근
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/18—Materials not provided for elsewhere for application to surfaces to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2240/00—Purpose of the treatment
    • B27K2240/70—Hydrophobation treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical

Abstract

PURPOSE: A waterproofing composition for coating wood stock panel is provided, which exhibits excellent waterproofing and dampproofing properties. CONSTITUTION: A waterproofing composition for coating wood stock panel comprises: 45-55 wt.% of acryl resin, 0.5-1.5 wt.% of urea resin incorporating 100-115 parts by weight of formalin, 60-70 parts by weight of urea 0.1-0.5 parts by weight of poly vinyl alcohol, 0.1-0.5 parts by weight of NaOH, 0.05-0.3 parts by weight of glacial acetic acid, 0.5-1.5 wt.% of crosslinking agent, 0.8-1.6 wt.% of thickening agent, 0.5-1.5 wt.% of vinyl alcohol, and 45-55 wt.% of water.

Description

압축목재 패널용 방수방습제Waterproof Desiccant for Compressed Wood Panels

본 발명은 압축목재 패널용 방수방습제에 관한 것으로서, 더욱 상세하게는 가구나 건재 등의 표면에 코팅하여 방수 효과를 발휘할 수 있는 방수·방습제에 관한 것이다.The present invention relates to a waterproof desiccant for compressed wood panels, and more particularly, to a waterproof and desiccant capable of exhibiting a waterproof effect by coating a surface of furniture or building materials.

종래 압축 목재 패널을 제조하는 데 있어서 방수방습 효과를 부여하기 위한 방법으로는 압축 패널 소재 제조시 왁스를 첨가하거나 접착제의 첨가량을 증량시키는 방법 등이 있었다.Conventional methods for imparting a waterproof and moisture proof effect in the production of compressed wood panels include a method of adding wax or increasing the amount of the adhesive when the compressed panel material is manufactured.

그러나, 왁스나 접착제를 사용하여 압축 패널에 방수 방습효과를 부여하는 방법은 그 효과가 기대치의 30% 정도에 그치고 있는 수준이다.However, the method of imparting a waterproof and moisture proof effect to the compression panel using wax or adhesive is only about 30% of the expectation.

종래 이와같은 방법으로 처리된 압축 목재 판재, 구체적으로 MDF, HDF, P, B 등은 거의 방수 방습성이 없어 가구나 건구로 제작된 후 이들 제품이 습기나 물에 접하게 되면 형태가 부풀게 된다. 결과적으로 판재 고유의 모든 기능을 잃게 되어 폐기 처분할 수 밖에 없다.Conventionally compressed wood plate treated in this way, specifically MDF, HDF, P, B, etc. is almost waterproof and moisture-proof, and after being made of furniture or dry bulbs these products are in contact with moisture or water will swell. As a result, they lose all their inherent functions and are forced to dispose of them.

이와같은 압축목재 판재의 폐기처분은 목재가 거의 수입되는 자재인 점을 감안할 때 외화낭비이며, 국가경제에 미치는 손해 또한 막대하다 할 것이다.The disposal of such compressed wood boards is a waste of foreign currency given that wood is almost imported, and the damage to the national economy will be enormous.

본 발명의 목적은 압축 목재 판재의 소재 생산시에 표면에 코팅하여 방수 방습 효과를 부여할 수 있는 우수한 방습제를 제공하는 데 있다.An object of the present invention is to provide an excellent desiccant that can be applied to the surface during the production of the material of the compressed wood plate to impart a waterproof moisture-proof effect.

이와같은 목적을 달성하기 위한 본 발명의 압축패널용 방수방습제는 아크릴계 수지 45∼55 중량%, 우레아 수지 0.5∼1.5 중량%, 가교제 0.5∼1.5 중량%, 증점제 0.8∼1.6 중량%, 비닐알콜 0.5∼1.5 중량% 및 물 45∼55 중량%로 이루어진 것임을 그 특징으로 한다.Waterproofing moisture-proofing agent for the compression panel of the present invention for achieving the above object 45-55% by weight of acrylic resin, 0.5-1.5% by weight of urea resin, 0.5-1.5% by weight of crosslinking agent, 0.8-1.6% by weight of thickener, 0.5-vinyl alcohol It is characterized by consisting of 1.5% by weight and 45 to 55% by weight of water.

이와같은 본 발명을 더욱 상세하게 설명하면 다음과 같다.The present invention will be described in more detail as follows.

본 발명의 방습제를 이루는 우레아 수지는 포르말린, 우레아, 폴리비닐알콜, 수산화나트륨 및 빙초산을 혼합하여 제조된 것이다.The urea resin constituting the desiccant of the present invention is prepared by mixing formalin, urea, polyvinyl alcohol, sodium hydroxide and glacial acetic acid.

보다 구체적으로는 포르말린 100∼115 중량부, 우레아 60∼70 중량부, 폴리비닐알콜 0.1∼0.5 중량부, 수산화나트륨 0.1∼0.5 중량부 및 빙초산 0.05∼0.3 중량부를 혼합하여 통상의 축합반응을 통해 제조된다.More specifically, 100 to 115 parts by weight of formalin, 60 to 70 parts by weight of urea, 0.1 to 0.5 parts by weight of polyvinyl alcohol, 0.1 to 0.5 parts by weight of sodium hydroxide, and 0.05 to 0.3 parts by weight of glacial acetic acid are prepared through a conventional condensation reaction. do.

우레아 수지는 접착제로 사용되며, 상온경화도 가능하고 저온접착도 가능한 것으로 알려져 있다.Urea resin is used as an adhesive, it is known that it can be cured at room temperature and can also be a low temperature adhesive.

통상의 압축패널용 방습제는 상기와 같은 우레아 수지에 방습성을 부여하기 위해 왁스 에멀젼을 혼합하였으나, 본 발명에서는 아크릴계 수지, 가교제, 증점제 및 비닐알콜을 우레아 수지 및 물과 혼합한다.Conventional compressive panel desiccant is mixed with a wax emulsion to impart moisture resistance to the urea resin as described above, in the present invention, acrylic resin, crosslinking agent, thickener and vinyl alcohol is mixed with urea resin and water.

보다 상세하게는 아크릴계 수지 45∼55 중량%, 우레아 수지 0.5∼1.5 중량%, 가교제 0.5∼1.5 중량%, 증점제 0.8∼1.6 중량%, 비닐알콜 0.5∼1.5 중량% 및 물 45∼55 중량%로 이루어진다.More specifically, it consists of 45-55% by weight of acrylic resin, 0.5-1.5% by weight of urea resin, 0.5-1.5% by weight of crosslinking agent, 0.8-1.6% by weight of thickener, 0.5-1.5% by weight of vinyl alcohol and 45-55% by weight of water. .

이를 혼합하여 판재의 표면에 롤러코팅 작업으로 150℃ 열건조하면 방수방습의 기능을 100% 얻을 수 있다.Mixing it and heat-drying 150 ℃ by roller coating on the surface of plate can get 100% waterproof and moisture proof function.

또한, 목조건축물 등 목재가 외부에 노출되는 부위 및 내부의 습기를 방지하기 위해 사용하면 종래의 도장 방법보다 몇 십배로 목재 수명을 연장시킬 수 있다.In addition, when used to prevent the interior of the wood exposed to the outside, such as wooden building construction and the humidity of the inside can extend the life of the wood several ten times than the conventional coating method.

이와같은 방습제를 사용하여 합판을 제조하는 경우 합판에 상기한 방습제를 롤러 코팅하고, 이를 40∼160℃에서 1분여 동안 열건조한다. 그 다음, 이를 냉각시킨다.When the plywood is manufactured using such a desiccant, the plywood is coated with the above desiccant and heat-dried at 40 to 160 ° C. for 1 minute. Then it is cooled.

또는 현장에서 붓 도장이나 스프레이 건으로 상기 방수제를 코팅하고 자연건조하여 목재 패널을 제조할 수도 있다.Alternatively, the waterproofing agent may be coated and air-dried with a brush paint or a spray gun in the field to manufacture wood panels.

이와같이 제조된 목재패널을 가구나 건구로 생산할 경우 종래 방습제는 목재간 접착이 불가능하였으나, 본 발명에 따른 방습제를 코팅한 목재패널의 경우는 단순히 비닐계 수성본드를 사용하여 접착될 수 있으므로 가구·건구 생산성을 향상시킬 수 있다.In the case of producing the wood panel manufactured as a furniture or dry bulb, the conventional desiccant was not possible to bond between the wood, but in the case of the wood panel coated with the desiccant according to the present invention can be simply bonded using a vinyl-based aqueous bond, so that the furniture and dry bulb productivity Can improve.

이하, 본 발명을 실시예에 의거 상세히 설명하면 다음과 같은 바, 본 발명이 실시예에 의해 한정되는 것은 아니다.Hereinafter, the present invention will be described in detail with reference to Examples, but the present invention is not limited by the Examples.

실시예 1Example 1

다음 표 1에 나타낸 바와 같은 조성 및 함량으로 방습제를 제조하고, 제조된 방수제를 코팅한 합판에 대하여 방습성 시험을 실시하여 그 결과를 다음 표 2에 나타내었다.To prepare a desiccant with a composition and content as shown in Table 1, the moisture-proof test was carried out on the plywood coated with the prepared waterproofing agent and the results are shown in Table 2 below.

이때 합판으로는 두께 3m/m이고, 규격이 1200×2400인 것을 사용하였으며, 상기 방습제를 10μ 되도록 도포하여 150℃에서 1분 동안 열건조하여 압축 목재 방수 패널을 제조하였다.At this time, as a plywood thickness of 3m / m, the specification was used 1200 × 2400, was applied to the desiccant 10μ heat-drying for 1 minute at 150 ℃ to prepare a compressed wood waterproof panel.

(단위 : 중량%)(Unit: weight%) 실시예 1Example 1 아크릴 수지Acrylic resin 100100 우레아 수지Urea resin 1515 물water -- 가교제Crosslinking agent 55 증점제Thickener 2020 비닐알콜Vinyl alcohol 2020

시험과목test subject 시험방법Test Methods 본 발명 방수액The present invention waterproofing liquid 종래Conventional 방수성Waterproof 끓는 물을 표면에 붓고 48시간 물의 증발을 막기 위해 컵을 덮어 두었음Pour boiling water over the surface and cover it to prevent evaporation of water for 48 hours 이상없슴No problem 사용불가can not be used 내수성Water resistance 표면을 코팅하여 물속에 24시간 담궈 두었음Coated surface and soaked in water for 24 hours 이상없슴No problem 사용불가can not be used 표면접착성Surface adhesiveness 표면에 UV 및 다른 페인트를 칠하고 테이프 시험했음UV and other painted and taped surfaces 이상없슴No problem 사용불가can not be used 방습성Moisture proof 습도 120%의 공간에 넣고 24시간 두었음Placed in a space of 120% humidity for 24 hours 이상없슴No problem 사용불가can not be used

상기 표 1의 결과로부터 본 발명에 따른 방습제를 코팅하여 제조한 압축목재 패널은 내수성이 우수하고 방수 및 방습도 완벽하고 표면접착성도 우수함을 알 수 있다.From the results of Table 1, it can be seen that the compressed wood panel manufactured by coating the desiccant according to the present invention is excellent in water resistance, waterproof and moistureproof, and also excellent in surface adhesiveness.

이상에서 상세히 설명한 바와 같이, 본 발명에 따라 아크릴계 수지, 우레아 수지, 가교제, 증점제, 비닐알콜 및 물을 혼합하여 제조된 방수방습제는 방수성이 뛰어나므로 압축목재 패널에 코팅하면 우수한 방수방습 효과를 나타낼 뿐만 아니라 종래 목재 방수재는 방수코팅 후에 목재 접착이 불가능했으나 본 발명에 따른 방수제를 목재에 코팅한 후에도 비닐계 수성 본드를 사용하여 목재 접착이 가능하므로 가구·건구 생산시 생산성을 향상시킬 수 있다.As described in detail above, the waterproof desiccant prepared by mixing acrylic resin, urea resin, crosslinking agent, thickener, vinyl alcohol and water according to the present invention exhibits excellent waterproof and moistureproof effect when coated on compressed wood panel because of excellent waterproofness. In addition, the conventional wood waterproofing material is impossible to bond the wood after the waterproof coating, but even after coating the waterproofing agent according to the present invention on the wood using a vinyl-based water-based bond can be used to improve the productivity of furniture, furniture production.

Claims (2)

아크릴계 수지 45∼55 중량%, 우레아 수지 0.5∼1.5 중량%, 가교제 0.5∼1.5 중량%, 증점제 0.8∼1.6 중량%, 비닐알콜 0.5∼1.5 중량% 및 물 45∼55 중량%로 이루어진 압축목재 패널용 방수방습제.For compressed wood panel consisting of 45-55 wt% acrylic resin, 0.5-1.5 wt% urea resin, 0.5-1.5 wt% crosslinking agent, 0.8-1.6 wt% thickener, 0.5-1.5 wt% vinyl alcohol, and 45-55 wt% water Waterproof desiccant. 제 1 항의 방습제를 코팅하여 제조된 압축목재 패널.A compressed wood panel manufactured by coating the desiccant of claim 1.
KR1019980053395A 1998-12-07 1998-12-07 Waterproof Desiccant for Compressed Wood Panels KR100294575B1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160139235A (en) 2015-05-27 2016-12-07 이영미 Water repellent for wood furniture
KR101710668B1 (en) * 2016-05-31 2017-02-27 김동규 Transparent coating composition for wood coating

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101150955B1 (en) * 2011-12-09 2012-05-29 주식회사휴플러스 Bamboo compressing wood and production method for preventing of transform

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20160139235A (en) 2015-05-27 2016-12-07 이영미 Water repellent for wood furniture
KR101710668B1 (en) * 2016-05-31 2017-02-27 김동규 Transparent coating composition for wood coating

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