KR19990078895A - Manufacturing method of polystyrene film for food packing appendant anti-microbial - Google Patents
Manufacturing method of polystyrene film for food packing appendant anti-microbial Download PDFInfo
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- KR19990078895A KR19990078895A KR1019990034071A KR19990034071A KR19990078895A KR 19990078895 A KR19990078895 A KR 19990078895A KR 1019990034071 A KR1019990034071 A KR 1019990034071A KR 19990034071 A KR19990034071 A KR 19990034071A KR 19990078895 A KR19990078895 A KR 19990078895A
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- polystyrene film
- polystyrene
- powder
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- 239000004793 Polystyrene Substances 0.000 title claims abstract description 90
- 229920002223 polystyrene Polymers 0.000 title claims abstract description 90
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 48
- 235000013305 food Nutrition 0.000 title claims abstract description 31
- 239000004599 antimicrobial Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- 238000012856 packing Methods 0.000 title claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 35
- 241000894006 Bacteria Species 0.000 claims abstract description 20
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 19
- 238000002844 melting Methods 0.000 claims abstract description 13
- 230000008018 melting Effects 0.000 claims abstract description 13
- 238000004806 packaging method and process Methods 0.000 claims abstract description 12
- 241000700605 Viruses Species 0.000 claims abstract description 10
- 241000233866 Fungi Species 0.000 claims abstract description 7
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 6
- 241001070947 Fagus Species 0.000 claims description 4
- 235000010099 Fagus sylvatica Nutrition 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims 3
- 230000002401 inhibitory effect Effects 0.000 abstract description 2
- 238000009826 distribution Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920005669 high impact polystyrene Polymers 0.000 description 4
- 239000004797 high-impact polystyrene Substances 0.000 description 4
- 235000019645 odor Nutrition 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- 235000016068 Berberis vulgaris Nutrition 0.000 description 2
- 241000335053 Beta vulgaris Species 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229940117958 vinyl acetate Drugs 0.000 description 2
- 238000009395 breeding Methods 0.000 description 1
- 230000001488 breeding effect Effects 0.000 description 1
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000005038 ethylene vinyl acetate Substances 0.000 description 1
- 235000021485 packed food Nutrition 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/10—Copolymers of styrene with conjugated dienes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Laminated Bodies (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
- Packages (AREA)
Abstract
본발명은 식품을 포장할 수 있는 폴리스틸렌 필름 및 식품을 담을 수 있는 용기의 표면으로 접착되는 폴리스틸렌 필름에 관한 것으로 특히, 폴리스틸렌 분말에 항균성을 가진 항균성 마스터벳치 분말을 첨가 혼합하여 폴리스틸렌 필름을 성형함으로서, 폴리스틸렌 필름과 접촉하는 세균들의 증식을 억제시켜 세균,곰팡이 ,기타 바이러스에 대한 항균력을 얻을 수 있는 동시에 우수한 탈취성능을 얻을 수 있도록 안출된 것으로,The present invention relates to a polystyrene film capable of packaging food and a polystyrene film adhered to the surface of a container capable of containing food, and in particular, by adding and mixing an antimicrobial antimicrobial masterbatch powder to the polystyrene powder to form a polystyrene film, By inhibiting the growth of bacteria in contact with the polystyrene film to obtain antibacterial activity against bacteria, fungi, and other viruses, it is designed to obtain excellent deodorizing performance,
식품을 포장할 수 있는 폴리스틸렌 필름 및 식품을 담을 수 있는 용기의 표면으로 접착되는 폴리스틸렌 필름과 접촉하는 세균들의 증식을 억제시켜 세균,곰팡이,기타 바이러스에 대한 항균력을 얻을 수 있는 동시에 우수한 탈취성능을 얻기 위해 폴리스틸렌 분말에 항균성을 가진 항균 마스터벳치 분말을 첨가 혼합한뒤 용융,압출방사하여 폴리스틸렌 필름을 성형한 것을 특징으로 하는 항균제가 첨가된 식품 포장용 폴리스틸렌 필름의 제조 방법을 제공한다.Inhibits the growth of bacteria that come in contact with the polystyrene film for packing food and the polystyrene film adhered to the surface of a container for food, thereby obtaining antibacterial activity against bacteria, fungi, and other viruses, and at the same time obtaining excellent deodorizing performance. The present invention provides a method for producing a polystyrene film for food packaging, wherein the antimicrobial agent is added to the polystyrene powder by mixing and mixing the antimicrobial master bezel powder having antimicrobial properties, followed by melting and extruding the polystyrene film.
Description
본발명은 식품을 포장할 수 있는 폴리스틸렌 필름 및 식품을 담을 수 있는 용기의 표면으로 접착되는 폴리스틸렌 필름에 관한 것으로 특히, 폴리스틸렌 분말에 항균성을 가진 항균 마스터벳치 분말을 첨가 혼합하여 폴리스틸렌 필름을 성형함으로서, 폴리스틸렌 필름과 접촉하는 세균들의 증식을 억제시켜 세균,곰팡이 ,기타 바이러스에 대한 항균력을 얻을 수 있는 동시에 우수한 탈취성능을 얻을 수 있는 항균제가 적층된 식품 포장용 폴리스틸렌 필름의 제조 방법에 관한 것이다.The present invention relates to a polystyrene film for packing food and a polystyrene film adhered to the surface of a container for food, and in particular, by adding and mixing an antimicrobial masterbatch powder having antimicrobial properties to the polystyrene powder to form a polystyrene film, The present invention relates to a method for producing a polystyrene film for food packaging in which an antimicrobial agent capable of obtaining antibacterial activity against bacteria, fungi and other viruses by inhibiting the growth of bacteria in contact with the polystyrene film and attaining excellent deodorizing performance.
종래의 식품을 포장할 수 있는 폴리스틸렌 필름 및 식품을 담을 수 있는 용기에 부착되는 폴리스틸렌 필름 표면 또는 이면에는 제조과정이나 유통과정에서 세균,곰팡이,기타 바이러스등이 접촉되면서 증식을 하게 된다.The polystyrene film that can wrap a conventional food and the polystyrene film that is attached to the container or the container for food can be proliferated by contact with bacteria, mold, other viruses, etc. in the manufacturing or distribution process.
상기와 같이 세균,곰팡이,기타 바이러스등이 폴리스틸렌 필름에 증식을 하게 되면 식품을 변질시키게 하고 많은 악취가 발생하게 되므로 매우 비위생적인 문제점을 가지고 있었으며 그만큼 식품의 유통기간이 단축되어지는 문제점을 가지고 있었다.As described above, when bacteria, fungi, and other viruses proliferate on the polystyrene film, the food is deteriorated and many odors are generated, thus having a very unsanitary problem and shortening the distribution period of the food.
이러한 종래의 문제점등을 해결 보완하기 위한 본발명의 목적은,The purpose of the present invention for solving and solving these conventional problems,
폴리스틸렌 필름의 표면 및 이면으로 세균,곰팡이,기타 바이러스 등이 증식되는 것을 방지하여 폴리스틸렌 필름으로 포장된 식품이 변질되는 것을 막는 동시에 악취의 발생을 막아 위생적인 유통이 가능하도록 하고 식품의 유통기간을 늘릴 수 있도록 하는 목적을 제공한다.Prevents the growth of bacteria, mold, and other viruses on the front and back of the polystyrene film to prevent the food from being packaged with the polystyrene film from being deteriorated and to prevent the occurrence of odors and to allow for hygienic distribution and to increase the shelf life of the food. Serve the purpose of making it possible.
상기의 목적을 달성하기 위하여 본발명은,In order to achieve the above object, the present invention,
폴리스틸렌의 용융액에 향균성을 가진 항균 마스터벳치 분말을 첨가 혼합하여 폴리스틸렌 필름을 성형하면 본발명의 목적을 달성할 수 있게된다.Forming a polystyrene film by adding and mixing antimicrobial masterbatch powder having antimicrobial to the melt of polystyrene can achieve the object of the present invention.
본발명의 제조 방법을 상세히 설명하기로 한다.The manufacturing method of the present invention will be described in detail.
식품을 포장할 수 있는 폴리스틸렌 필름 및 식품을 담을 수 있는 용기의 표면으로 접착되는 폴리스틸렌 필름과 접촉하는 세균들의 증식을 억제시켜 세균,곰팡이,기타 바이러스에 대한 항균력을 얻을 수 있는 동시에 우수한 탈취성능을 얻기 위해 폴리스틸렌 분말에 항균성을 가진 항균 마스터벳치 분말을 첨가 혼합한뒤 용융,압출방사하여 폴리스틸렌 필름을 성형하였다.Inhibits the growth of bacteria that come in contact with the polystyrene film for packing food and the polystyrene film adhered to the surface of a container for food, thereby obtaining antibacterial activity against bacteria, fungi, and other viruses, and at the same time obtaining excellent deodorizing performance. In order to add and mix the antimicrobial masterbatch powder having antimicrobial properties to the polystyrene powder, and melted and extruded to form a polystyrene film.
그리고, 상기 폴리스틸렌 필름을 외층과 중층 그리고 내층으로 적층하여 3중 구조의 필름으로 성형시 외층의 폴리스틸렌 분말에 항균성 마스터 벳치 분말을 첨가 혼합한뒤 용융,압출방사하여 성형하였다.In addition, the polystyrene film was laminated to the outer layer, the middle layer and the inner layer to form a triple structure film, and then mixed with the antimicrobial master bezel powder to the polystyrene powder of the outer layer, followed by melting and extruding.
또한, 상기 폴리스틸렌 필름을 외층과 중층 그리고 내층으로 적층하여 3중 구조의 필름으로 성형시 중층의 초산비닐 분말에 항균성 마스터 벳치 분말을 첨가 혼합한뒤 용융,압출방사하여 성형하였다.In addition, the polystyrene film was laminated in an outer layer, a middle layer and an inner layer to form a triple structure film, and then mixed with an antimicrobial master bezel powder in an intermediate vinyl acetate powder, followed by melting and extruding.
그리고, 상기 폴리스틸렌 필름을 외층과 중층 그리고 내층으로 적층하여 3중 구조의 필름으로 성형시 내층의 폴리스틸렌 분말에 항균성 마스터 벳치 분말을 첨가 혼합한뒤 용융,압출방사하여 성형하였다.In addition, the polystyrene film was laminated to an outer layer, a middle layer and an inner layer to form a triple structure film, and then mixed with an antimicrobial master bezel powder to the polystyrene powder of the inner layer, followed by melting and extruding.
또한, 상기 폴리스틸렌 필름을 외층과 내층으로 적층하여 2중 구조의 필름으로 성형시 외층 및 내층의 폴리스틸렌 분말에 항균성 마스터 벳치 분말을 첨가 혼합한뒤 용융,압출방사하여 성형하였다.In addition, the polystyrene film was laminated in an outer layer and an inner layer to be molded into a double structured film, and then mixed with an antimicrobial master bezel powder to the polystyrene powder of the outer layer and the inner layer, followed by melting and extruding.
이와같이된 본발명의 작용을 설명하면 다음과 같다.Referring to the operation of the present invention as described above is as follows.
먼저, 본발명 폴리스틸렌(Polystyrene)분말과 향균성을 가진 항균성 마스터벳치(Anti-Bacteria Master Batch) 분말의 혼합비는 85-95중량% : 5-15중량%가 적정의 혼합비이다.First, the mixing ratio of the present invention polystyrene powder and the antimicrobial anti-bacterial Master Batch (Anti-Bacteria Master Batch) powder is 85-95% by weight: 5-15% by weight is the appropriate mixing ratio.
상기와 같이 폴리스텔렌 분말과 항균성 마스터벳치의 혼합이 완료되면 이들을 용융시켜 압출방사함으로서 항균성 폴리스틸렌 필름을 성형 제조할수 있게 된다.As described above, when the mixing of the polystyrene powder and the antimicrobial masterbatch is completed, the antimicrobial polystyrene film may be molded and manufactured by melting and extruding them.
상기와 같이 제조된 폴리스틸렌 필름은 식품과 직접 접촉하면서 식품을 포장하게 되는바, 상기의 제조과정이나 유통과정중 세균,곰팡이,기타 바이러스등이 폴리스틸렌 필름에 접촉되더라도 폴리스틸렌 필름에 포함되어 있는 항균성 마스터벳치의 항균성에 의해 이들의 증식을 막을수 있게 된다.Polystyrene film prepared as described above is to package the food while in direct contact with the food bar, even if the bacteria, fungi, other viruses, etc. in contact with the polystyrene film during the manufacturing or distribution process, the antimicrobial masterbetes contained in the polystyrene film The antimicrobial properties of teeth can prevent their growth.
따라서, 상기 항균성 마스터벳치의 항균작용에 의해 포장된 내용물의 변질을 막을수 있고 아울러 세균들이 죽으면서 발생했던 악취의 발생도 막을수 있기 때문에 매우 위생적인 폴리스틸렌 필름 포장지를 얻을수 있고 식품의 유통기간을 연장시킬수 있게 된다.Therefore, it is possible to prevent the deterioration of the packaged contents by the antimicrobial action of the antimicrobial master beet, and also to prevent the occurrence of odor generated when the bacteria die, thereby obtaining a very hygienic polystyrene film wrapping paper and to extend the shelf life of food. do.
한편, 상기 폴리스틸렌 필름을 외층과 중층 그리고 내층으로 적층하여 3중 구조의 필름으로 성형시 외층에 항균성 마스터 벳치 분말을 첨가 혼합하여 외층에서만 항균작용이 유발되도록 할수 있다.On the other hand, by stacking the polystyrene film in the outer layer, the middle layer and the inner layer to add the antimicrobial master beech powder to the outer layer when mixing to form a three-layered film to the antimicrobial action can be induced only in the outer layer.
즉, 상기 폴리스틸렌 필름의 외층은 폴리스틸렌(Polystyrene) 70-85중량%와, 스틸렌-부타디엔 공중합체(Styrene-Butadiene Copolymer) 10-20중량%와, 고강도 폴리스틸렌(High Impact Polystyrene) 1-5중량%와, 항균성 마스터벳치(Anti-Bacteria Master Batch)5-15중량%의 비율로 혼합시킨다.That is, the outer layer of the polystyrene film is 70-85% by weight of polystyrene, 10-20% by weight of styrene-butadiene copolymer, 1-5% by weight of high impact polystyrene, , Anti-Bacteria Master Batch (Anti-Bacteria Master Batch) 5-15% by weight of the mixture is mixed.
그리고, 상기의 비율로 혼합된 외층을 통상적인 중층 및 내층과 함께 용융, 압출방사시키면 항균성을 가진 3중구조의 폴리스틸렌 필름을 얻을 수 있게 된다.Then, when the outer layer mixed at the above ratio is melted and extruded together with the conventional middle and inner layers, a polystyrene film having a triple structure having antimicrobial properties can be obtained.
상기와 같이 외층에서만 항균 작용을 하는 폴리스틸렌 필름은 식품포장 용기의 바닥면에 접착하여 사용을 하게 된다.As described above, the polystyrene film which acts only on the outer layer is bonded to the bottom surface of the food packaging container.
즉, 상기 3중구조의 폴리스틸렌 필름의 내층은 용기의 바닥면과 접촉하면서 접착되도록 하고 항균성이 있는 외층을 포장되는 내용물과 접촉하도록 함으로서 세균들의 번식을 막을 수 있게 된다.That is, the inner layer of the polystyrene film of the triple structure is allowed to adhere while contacting the bottom surface of the container and to prevent the breeding of bacteria by bringing the outer layer with antimicrobial contact with the package contents.
또한, 상기 외층과 중층 그리고 내층으로 적층하여 3중 구조로된 폴리스틸렌 필름을 성형시 중층에 항균성 마스터 벳치 분말을 첨가 혼합하여 중층에서만 항균작용이 유발되도록 할수 있다In addition, when the polystyrene film having a triple structure is formed by stacking the outer layer, the middle layer and the inner layer, the antimicrobial master beech powder may be added and mixed in the middle layer so that the antimicrobial action may be induced only in the middle layer.
즉, 상기 폴리스틸렌 필름의 중층은 초산비닐(Ethylene-Vinyl-Acetate)85-95중량%, 항균성 마스터벳치(Anti-Bacteria Master Batch)5-15중량%의 비율로 혼합시킨다.That is, the middle layer of the polystyrene film is mixed at a ratio of 85 to 95% by weight of vinyl acetate (Ethylene-Vinyl-Acetate) and 5 to 15% by weight of an anti-Bacteria Master Batch.
그리고, 상기의 비율로 혼합된 중층을 통상적인 외층 및 내층 사이에 위치되도록 용융, 압출방사시키면 항균성을 가진 3중구조의 폴리스틸렌 필름을 얻을 수 있게 된다.Then, by melting and extruding the mixed middle layer so as to be positioned between the conventional outer layer and the inner layer, it is possible to obtain a polystyrene film having a triple structure having antibacterial properties.
상기와 같이 중층에서만 항균 작용을 하는 폴리스틸렌 필름은 항균성이 외층과 내층 모두로 영향이 미치기 때문에 식품을 직접 감싸 포장하는 포장지 및 식품포장 용기의 바닥면에 접착하여 사용을 하게 된다.As described above, the polystyrene film having an antimicrobial effect only in the middle layer has an antimicrobial effect on both the outer layer and the inner layer, so that the polystyrene film is adhered to the bottom surface of the wrapping paper and the food packaging container for wrapping the food directly.
따라서, 상기 폴리스틸렌 필름의 중층에 본발명의 항균성 마스터벳치를 혼합하여 성형하여도 세균들의 번식을 막을 수 있게 된다.Therefore, even if the antimicrobial master beets of the present invention are mixed and molded into the middle layer of the polystyrene film, it is possible to prevent the growth of bacteria.
한편, 상기 폴리스틸렌 필름을 외층과 중층 그리고 내층으로 적층하여 3중 구조의 필름으로 성형시 외층에 항균성 마스터 벳치 분말을 첨가 혼합하여 내층에서만 항균작용이 유발되도록 할수도 있다.Meanwhile, the polystyrene film may be laminated in an outer layer, a middle layer and an inner layer to add and mix an antimicrobial master batch powder to the outer layer when forming a triple-structured film so that the antimicrobial action may be induced only in the inner layer.
즉, 상기 폴리스틸렌 필름의 내층은 폴리스틸렌(Polystyrene) 70-85중량%와, 스틸렌-부타디엔 공중합체(Styrene-Butadiene Copolymer) 10-20중량%와, 고강도 폴리스틸렌(High Impact Polystyrene) 1-5중량%와, 항균성 마스터벳치(Anti-Bacteria Master Batch)5-15중량%의 비율로 혼합시킨다.That is, the inner layer of the polystyrene film is 70-85% by weight of polystyrene, 10-20% by weight of styrene-butadiene copolymer, 1-5% by weight of high impact polystyrene, , Anti-Bacteria Master Batch (Anti-Bacteria Master Batch) 5-15% by weight of the mixture is mixed.
그리고, 상기의 비율로 혼합된 내층을 통상적인 중층 및 내층과 함께 용융, 압출방사시키면 항균성을 가진 3중구조의 폴리스틸렌 필름을 얻을 수 있게 된다.In addition, when the inner layer mixed at the above ratio is melted and extruded together with the conventional middle layer and the inner layer, it is possible to obtain a polystyrene film having a triple structure having antimicrobial properties.
상기와 같이 내층에서만 항균작용을 하는 폴리스틸렌 필름은 식품포장 용기의 바닥면에 접착하여 사용을 하게 된다.As described above, the polystyrene film having an antibacterial effect only on the inner layer is used by bonding to the bottom surface of the food packaging container.
즉, 상기 3중구조의 폴리스틸렌 필름의 외층은 용기의 바닥면과 접촉하면서 접착되도록 하고 항균성이 있는 내층을 포장되는 내용물과 접촉하도록 함으로서 세균들의 번식을 막을 수 있게 된다.That is, the outer layer of the triple structure of the polystyrene film is in contact with the bottom surface of the container to be adhered, and the antimicrobial inner layer to be in contact with the packaged contents to prevent the growth of bacteria.
또한, 상기 폴리스틸렌 필름을 외층과 내층으로 적층하여 2중 구조의 필름으로 성형시 외층 및 내층에 항균성 마스터 벳치 분말을 첨가 혼합하여 내,외층에서모두에서 항균작용이 유발되도록 할수도 있다.In addition, the polystyrene film may be laminated in an outer layer and an inner layer to add and mix an antimicrobial master bezel powder in the outer layer and the inner layer when forming a double-structured film, so that the antimicrobial action may be induced in both the inner and outer layers.
즉, 상기 2중 구조의 폴리스틸렌 필름의 외층은 폴리스틸렌(Polystyrene) 70-85중량%와, 스틸렌-부타디엔 공중합체(Styrene-Butadiene Copolymer) 10-20중량%와, 고강도 폴리스틸렌(High Impact Polystyrene) 1-5중량%와, 항균성 마스터벳치(Anti-Bacteria Master Batch)3-15중량%의 비율로 혼합시킨다.That is, the outer layer of the polystyrene film of the double structure is 70-85% by weight of polystyrene, 10-20% by weight of styrene-butadiene copolymer, and high-strength polystyrene (High Impact Polystyrene) 1- 5% by weight and 3-15% by weight of Anti-Bacteria Master Batch (Anti-Bacteria Master Batch) is mixed.
그리고, 상기 2중 구조의 폴리스틸렌 필름의 내층도 폴리스틸렌(Polystyrene) 70-85중량%와, 스틸렌-부타디엔 공중합체(Styrene-Butadiene Copolymer) 10-20중량%와, 고강도 폴리스틸렌(High Impact Polystyrene) 1-5중량%와, 항균성 마스터벳치(Anti-Bacteria Master Batch)3-15중량%의 비율로 혼합시킨다.In addition, the inner layer of the double structured polystyrene film is also 70-85% by weight of polystyrene, 10-20% by weight of styrene-butadiene copolymer, and high-strength polystyrene (High Impact Polystyrene) 1- 5% by weight and 3-15% by weight of Anti-Bacteria Master Batch (Anti-Bacteria Master Batch) is mixed.
그리고, 상기의 비율로 혼합된 외층 및 내층을 용융, 압출방사시키면 항균성을 가진 2중구조의 폴리스틸렌 필름을 얻을 수 있게 된다.Then, by melting and extruding the outer layer and the inner layer mixed at the above ratio, it is possible to obtain a polystyrene film having a double structure having antimicrobial properties.
상기와 같이 내,외층에서 모두에서 항균작용을 하는 폴리스틸렌 필름은 항균성이 외층과 내층 모두에서 발생하기 때문에 식품을 직접 감싸 포장하는 포장지 및 식품포장 용기의 바닥면에 접착하여 사용을 하게 된다.As described above, the polystyrene film having an antimicrobial action in both the inner and outer layers is used to adhere to the bottom surface of a wrapping paper and a food packaging container that directly wraps the food because the antimicrobial activity occurs in both the outer and inner layers.
따라서, 상기 2중으로된 폴리스틸렌 필름에 본발명의 항균성 마스터 벳치를 혼합하여 성형하여도 세균들의 번식을 막을 수 있게 된다.Therefore, even when molded by mixing the antimicrobial master batch of the present invention to the double polystyrene film it is possible to prevent the growth of bacteria.
이와같이된 본발명은 폴리스틸렌의 용융액에 향균성을 가진 항균 마스터벳치 분말을 첨가 혼합하여 폴리스틸렌 필름을 성형함으로서, 폴리스틸렌 필름의 표면 및 이면으로 세균,곰팡이,기타 바이러스 등이 증식되는 것을 방지하여 폴리스틸렌 필름으로 포장된 식품이 변질되는 것을 막는 동시에 악취의 발생을 막아 위생적인 유통이 가능하도록 하고 식품의 유통기간을 늘릴 수 있는 유용한 효과를 갖는다.Thus, the present invention forms a polystyrene film by adding and mixing an antimicrobial masterbatch powder having antimicrobial effect to the melt of the polystyrene, thereby preventing the growth of bacteria, mold, and other viruses on the surface and the back of the polystyrene film to form a polystyrene film. It prevents the packaged foods from being deteriorated and at the same time prevents the occurrence of odors, thus enabling hygienic distribution and extending the shelf life of the foods.
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KR100508065B1 (en) * | 2002-05-06 | 2005-08-17 | 임종섭 | Method for preparing antimicrobial resin composition for food treating product |
KR100769060B1 (en) * | 2006-06-15 | 2007-10-22 | 주식회사 이테크 | Absorbent and biodegradable psp sheet, method for producing thereof and tray using thereof |
KR101673463B1 (en) | 2015-11-18 | 2016-11-16 | 윤영욱 | Film structure and a method of manufacturing the PET tray having the sealing structure |
KR101686606B1 (en) | 2015-11-18 | 2016-12-15 | 윤영욱 | The structure and manufacturing method of a film with a polypropylene fusion sealing structure |
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JPH07126432A (en) * | 1993-11-05 | 1995-05-16 | Toyo Ink Mfg Co Ltd | Antimicrobial and antifungal resin composition and masterbatch |
KR0149195B1 (en) * | 1994-09-24 | 1998-10-15 | 이덕림 | Composition of polystyreme foam |
JP3789573B2 (en) * | 1996-11-19 | 2006-06-28 | 大日本印刷株式会社 | Laminated material and laminar tube container using the same |
KR100222420B1 (en) * | 1997-01-22 | 1999-10-01 | 고충준 | Method and apparatus for antibiosis packing material |
JPH1143567A (en) * | 1997-05-29 | 1999-02-16 | Sumitomo Chem Co Ltd | Polystyrene-based resin composition and molded product |
KR19990047920A (en) * | 1997-12-06 | 1999-07-05 | 박건규 | Styrene resin-based heat-shrinkable film composition and method for producing same |
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KR100508065B1 (en) * | 2002-05-06 | 2005-08-17 | 임종섭 | Method for preparing antimicrobial resin composition for food treating product |
KR100769060B1 (en) * | 2006-06-15 | 2007-10-22 | 주식회사 이테크 | Absorbent and biodegradable psp sheet, method for producing thereof and tray using thereof |
KR101673463B1 (en) | 2015-11-18 | 2016-11-16 | 윤영욱 | Film structure and a method of manufacturing the PET tray having the sealing structure |
KR101686606B1 (en) | 2015-11-18 | 2016-12-15 | 윤영욱 | The structure and manufacturing method of a film with a polypropylene fusion sealing structure |
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