KR100385445B1 - A manufacture method of innocuousness film using pasture liquid - Google Patents
A manufacture method of innocuousness film using pasture liquid Download PDFInfo
- Publication number
- KR100385445B1 KR100385445B1 KR10-2000-0085204A KR20000085204A KR100385445B1 KR 100385445 B1 KR100385445 B1 KR 100385445B1 KR 20000085204 A KR20000085204 A KR 20000085204A KR 100385445 B1 KR100385445 B1 KR 100385445B1
- Authority
- KR
- South Korea
- Prior art keywords
- film
- weight
- wood vinegar
- food
- raw material
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/02—Wrappers or flexible covers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D197/00—Coating compositions based on lignin-containing materials
- C09D197/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
본 발명은 목초액을 주재로 한 무독성 필름의 제조방법에 관한 것으로, 좀더 상세하게는 가정이나 업소에서 각종 반찬이나 음식물 및 가공식품을 일정 용기에 담고 변질되지 않토록 보관 및 유통시키기 위하여 사용되는 랩 필름을 비롯하여 김장용 비닐봉투를 위한 필름과, 빵등의 식품포장용 비닐 필름(봉투) 및 각종 비닐빽, 비닐지퍼빽, 위생용 비닐장갑과, 종이컵, 컵라면등의 식품포장용기의 내면에 라미네이팅 형태로 코팅되는 코팅용 필름(이하 필름이라 약칭함)을 제조함에 있어, 각 필름의 제조시 필름지를 이루는 비닐 원재료가 용융된 상태로 이송되는 공정중에 목초액이 주재로 된 혼합물을 일정량 주입시켜 완성된 필름지 내에 목초액 성분이 함유되게 하여 줌으로서 각 필름의 고유 기능인 투명성, 방운성, 수축성 및 차폐성, 강도보강 뿐만 아니라 인체에 무해하면서 식품의 선도유지 향상과 그로인한 유통기간의 연장 및 직, 간접적인 살균, 소독, 생선등의 냄새 제거와 식품의 고유 풍미를 장기간 유지 시킬수 있게 한 목초액을 주재로 한 무독성 필름의 제조 방법을 제공하는데 그 특징이 있다.The present invention relates to a method for producing a non-toxic film based on wood vinegar, and more particularly, wrap film used to store and distribute various side dishes, foods and processed foods in a certain container at home or business so as not to be altered Laminating on the inner surface of food packaging containers such as film for plastic bags for kimchi, food packaging vinyl films (bags) such as bread, and various plastic bags, vinyl zipper mills, sanitary vinyl gloves, paper cups, cup noodles, etc. In manufacturing the coating film (hereinafter abbreviated as film), a certain amount of wood-based liquor is injected into the finished film paper during the process of transporting the raw material of the film to the molten state during the manufacture of each film. In addition to transparency, weather resistance, shrinkage and shielding, strength enhancement, which is a unique function of each film In addition, it is harmless to human body, and it is a non-toxic film based on wood vinegar which can improve the freshness of food and extend its shelf life, and thus direct, indirect sterilization, disinfection, odor removal of fish, etc. It is characterized by providing a manufacturing method.
Description
본 발명은 목초액을 주재로 한 무독성 필름의 제조방법에 관한 것이다.The present invention relates to a method for producing a non-toxic film based on wood vinegar.
좀더 상세하게는 가정이나 업소에서 각종 반찬이나 음식물 및 가공식품을 일정 용기에 담고 변질되지 않토록 보관 및 유통시키기 위하여 사용되는 랩 필름을 비롯하여 김장용 비닐봉투를 위한 필름과, 빵등의 식품포장용 비닐 필름(봉투) 및 각종 비닐빽, 비닐지퍼빽, 위생용 비닐장갑과, 종이컵, 컵라면등의 식품포장용기의 내면에 라미네이팅 형태로 코팅되는 코팅용 필름(이하 필름이라 약칭함)을 제조함에 있어, 각 필름의 제조시 필름지를 이루는 비닐 원재료가 용융된 상태로 이송되는 공정중에 목초액이 주재로 된 첨가물을 일정량 주입시켜 완성된 필름지 내에 목초액 성분이 함유되게 하여 줌으로서 각 필름의 고유 기능인 투명성, 방운성, 수축성 및 차폐성, 강도보강 뿐만 아니라 인체에 무해하면서 식품의 선도유지 향상과 그로인한 유통기간의 연장 및 직, 간접적인 살균, 소독, 생선등의 냄새 제거와 식품의 고유 풍미를 장기간 유지 시킬수 있게 한 목초액을 주재로 한 무독성 필름의 제조 방법에 관한 것이다.More specifically, a wrap film used to store various side dishes, foods and processed foods in a certain container in a home or a business, and store and distribute them so as not to be deteriorated, a film for plastic bags for kimchi, and a plastic film for food packaging such as bread ( Bags) and various plastic bags, vinyl zipper bags, sanitary vinyl gloves, and coating films (hereinafter abbreviated as "films") coated on the inner surface of food packaging containers such as paper cups and cup noodles. During the manufacture of the film, a certain amount of wood-based liquor is injected into the finished film paper during the process of transferring the raw material of the film paper in the molten state, so that the wood-based solution is contained in the finished film paper. Not only shrinkage, shielding, and strength enhancement, but also harmless to human body It relates to the extension and the direct and indirect sterilization, disinfection and preparation of non-toxic film the unique flavor of foods such as fish odor and was able to preside over the vinegar sikilsu maintained for long periods of time.
일반적으로 비닐이라 불리는 필름지는 석유화학제품의 산물로서 그 응용분야가 매우 다양하다.Film paper, commonly called vinyl, is the product of petrochemicals and has a wide variety of applications.
이러한 비닐제품은 농업용 비닐필름을 비롯하여 각종 식품 또는 식료품의 포장용기로 사용되고 있는데, 각종 식품과 관련한 비닐필름지는 각 제품의 특성에 따라 원재료의 선택이 매우 중요하다.Such vinyl products are used as packaging containers for various foods or foodstuffs, including agricultural vinyl films, and the selection of raw materials is very important according to the characteristics of each product.
이는 각 필름의 고유 기능인 투명성, 방운성, 수축성 및 차폐성, 강도보강등을 위한 것이다.This is for transparency, weather resistance, shrinkage and shielding, strength reinforcement, etc. which are inherent functions of each film.
한편, 본 발명에서는 식품과 관련 한 비닐필름의 제조방법을 제시하고 있는데, 각종 식품과 관련한 비닐필름의 원재료에 대한 부분은 언급하지 않기로 하겠다.On the other hand, the present invention proposes a method for producing a vinyl film associated with food, but will not be mentioned for the raw material of the vinyl film associated with various foods.
다만, 상기 비닐필름을 제조하는 과정중에 목초액을 주재로 한 첨가물을 혼입함으로서 목초액이 갖는 유효작용을 식품과 관련한 포장 및 처리하는 용도의 제품이 더욱 위생적이고 포장식품의 선도가 더욱 장기간 유지될수 있게 하기위한 것이므로 식품포장용 랩을 예로들어 설명하고, 다른용도의 제품, 즉 필름에 대해서는 제조시 첨가량을 밝히는 정도의 실시예로 설명하기로 하겠다.However, by incorporating additives based on wood vinegar during the manufacturing process of the vinyl film, the products for packaging and processing the effective action of wood vinegar for food are more hygienic and the freshness of packaged food can be maintained for a longer time. Since it is intended for the food packaging wrap as an example, and for other uses, that is, the film will be described in the embodiment of the degree to reveal the addition amount during manufacture.
그러므로 본원발명이 식품포장용 랩에 한정, 해석되어서는 아니되고 또한 후술될 본원발명의 특정 실시예에 국한되는 것이 아님을 미리 밝혀둔다.Therefore, it should be noted that the present invention should not be limited to, or construed as, a food packaging wrap, and is not limited to the specific embodiments of the present invention described below.
상기에서의 랩(Wrap)은 신선한 식료품 및 가공식품을 포장하기위한 8 ~ 20㎛ 정도의 극히 얇은 필름을 말한다.Wrap in the above refers to an extremely thin film of about 8 to 20 ㎛ for packaging fresh foods and processed foods.
이러한 랩은 다음과 같은 성질을 필수적으로 보유해야만 한다.These wraps must possess the following properties:
1) 식품보호성1) Food Protection
0. 물리적 성질(적당한 강도, 인열강도, 팽창성, 수축성보유)0. Physical properties (appropriate strength, tear strength, expandability, shrinkage)
0. 차폐성(방습, 방수, 방시(air resistance), 통기성)0. Shielding (moistureproof, waterproof, air resistance, breathable)
0. 안정성(내수, 내산, 내유, 내열, 내한성)0. Stability (Water, Acid, Oil, Heat, Cold Resistance)
0. 위생성(절대로 무독성 이어야 한다)0. Hygiene (should be absolutely nontoxic)
2) 작업성2) Workability
0. 포장작업에 적합하여야 하고(적절한 점착성)0. Should be suitable for packing work (adequate adhesion)
0. 절단이 용이해야 하며,0. Should be easy to cut,
0. 잘 풀려나와야 한다.0. Should be released well.
3) 상품성3) Merchandise
0. 투명성(필름자체 및 결로 분산에 의한 투명성 유지)0. Transparency (transparency maintained by the film itself and condensation dispersion)
0. 결로분산성,0. Condensation Dispersibility,
0. 광택평활성(깨끗하게 보일것)0. Glossy smoothness (looks clean)
4) 경제성4) Economics
0. 소모품이므로 저렴하여야 한다.0. It is a consumable item.
5) 안전성 및 기능성5) Safety and functionality
0. 음식물의 부패방지기능0. Food corruption prevention function
0. 탈취성(생선 및 육류의 비린내제거기능)0. Deodorant (fishy and meaty fishy removal function)
0. 직간접적인 살균기능 향상으로 이를 섭취 또는 음용 하는자의 위생 및 안전성확보.0. Ensure the hygiene and safety of those who eat or drink by improving direct or indirect sterilization function.
0. 랩 자체에서 발생 할 수 있는 환경호르몬의 중화 제거로 발암가능성 극소화.등0. Minimize carcinogenic potential by neutralizing environmental hormones that may occur in the lab itself.
이와같이 랩은 상술한 바와같은 성질을 보유해야만 우수한 포장 효과를 얻을수 있고, 특히, 위 5 번에 기술한 안전성 및 기능성의 향상효과로 인해 이를 사용하는 사람들의 위생 및 안전성을 얻을수 있으며, 또한 환경 또는 자연친화적 상품으로서의 기능을 확보할수 있다 하겠다.As such, the wrap must have the properties described above to obtain excellent packaging effects, and in particular, the hygiene and safety of people using it can be obtained due to the improvement of safety and functionality described above. It can secure the function as a friendly product.
종래의 랩은 그 원료로서 폴리염화비닐(PVC), 폴리염화비닐덴, 폴리부타디엔, EVA, LD-PE(저밀도 폴리에텔렌)등을 사용하여 제조하였는바, 이중에서도 가격, 특성, 안정성등으로 가정용은 LD-PE, PVC, 폴리염화 비닐덴, 폴리부타디엔등을 원료로하고,영업용은 PVC만 을 원료로 구분하여 사용하였다.Conventional wraps were manufactured using polyvinyl chloride (PVC), polyvinylidene chloride, polybutadiene, EVA, LD-PE (low density polyetherene) as raw materials. LD-PE, PVC, polyvinylidene chloride and polybutadiene are used as raw materials for home use, and only PVC is used as a raw material for commercial use.
그러나, 영업용으로 많이 사용하는 PVC 원료로 만든 랩은 고온에서 염산, 염소가스가 발생하고, 발암성이 있을 뿐만 아니라, 안정성등이 문제가 되어 투명도등은 좋으나, 인체에 유해한 폐단이 있었고, LD-PE는 강도가 약하고 투명성이 저하되는등 작업성과 상품성이 결여된 문제가 있었다.However, wraps made of PVC raw materials, which are frequently used for commercial use, generate hydrochloric acid and chlorine gas at high temperatures, are not only carcinogenic, but also have stability problems, such as transparency, but they have harmful wastes. PE had a problem of lack of workability and commerciality, such as low strength and poor transparency.
한편, 본 발명에서는 상기한 종래의 식품 포장용랩이 갖는 제반문제의 해결과 동시에 랩에 탈취 작용과 직,간접적인 살균, 소독작용을 겸 할 수 있는 기능을 부가하여 음식물의 부패를 더욱 방지하고, 음식물 고유풍미의 보존 및 환경 친화적인 랩을 제공하려 하는데,On the other hand, the present invention is to solve the problems of the conventional food packaging wraps as described above and at the same time add a function that can act as a deodorizing action, direct and indirect sterilization, disinfection to the wrap to further prevent food corruption, To preserve food flavors and provide environmentally friendly wraps,
이때 랩의 제조에 사용되는 조성물에 참숯 추출물인 목초액을 일정비율로 혼합하여 얻을수 있게 하였다.At this time, it was possible to obtain a mixture of wood vinegar solution, which is a charcoal extract in a proportion to the composition used in the preparation of the wrap.
상기에서의 목초액은 주지 하는바와 같이, 숯을 구을때 가마의 굴뚝에서 나오는 연기를 냉각시켜 만들어진 나무의 혈액이라 불리우는 액체이다.Wood liquor in the above is, as is known, is a liquid called wood blood made by cooling the smoke from the chimney of the kiln when burning charcoal.
이 목초액은 숯가마의 온도 80 ~ 130℃ 사이에서 채취된다.This wood vinegar is collected between the charcoal kiln temperature 80 ~ 130 ℃.
이 액체는 수용성과 유용성으로 나뉘어 지는데, 수용성의 액체는 목초액으로서 사람이 음용 할 수 있고, 유용성의 액체는 목타르로 음용 할수 없으며, 공업용으로 사용된다.This liquid is divided into water solubility and oil solubility. The water solubility is wood vinegar, which can be drunk by humans.
목초액은 초산을 주 성분으로하는 PH3 전후의 산성 액체이다.Wood vinegar is an acidic liquid before and after PH3, which has acetic acid as its main ingredient.
그 밖에도 의산(개미산), 프로피온산, 등의 지방산, 메탄올, 프로페놀등의 알콜아세톤, 포름알데히드(Formaldehyde), 페놀성분등 약 200종류 이상의 유효성분이 함유되어 있다.In addition, it contains about 200 kinds of active ingredients such as fatty acids such as formic acid (formic acid), propionic acid, alcohol acetone such as methanol and propphenol, formaldehyde and phenol components.
주성분인 초산이 50% 정도이나 목초액은 90% 정도가 수분이기때문에 전체 용액중의 초산 성분은 약 3% 정도이다.Acetic acid in the total solution is about 3% because the main component is acetic acid is about 50% but wood vinegar is about 90% water.
상기의 목초액은 많은 약효성분도 들어있지만 극소량의 유해성분도 들어있어 이 유해 물질은 증유 정제하여 제거한다.The wood vinegar contains a lot of active ingredients, but also contains a very small amount of harmful components, these harmful substances are removed by milk purification.
목초액은 무색 또는 약간의 차색을 띤 투명액체이며, 식물, 동물등의 체내로 침투성, 흡수성이 강한것이 특징이다.Wood vinegar is a colorless or slightly colored transparent liquid, characterized by strong permeability and absorption into the body of plants and animals.
원액은 냄새가 꽤 강해서 코를 자극하는데, 특유의 타는 냄새가 나지만 초산, 메타놀, 포름알데히드,등이 있어 햄, 소세지등의 훈제제품은 이 냄새를 이용해서 만들어진다고 알려져 있다.The undiluted liquor is quite strong and irritates the nose. It has a characteristic burning smell, but acetic acid, methanol, formaldehyde, etc., and it is known that smoked products such as ham and sausage are made using this smell.
고기나 생선등의 비린내를 목초액의 냄새로 중화하여 없애버리는 유효작용을하는 것이다.Neutralizes fishy fish and other fishy smells of wood vinegar.
본 발명은 상기한 바와 같은 목초액을 랩등의 필름 제조에 사용되는 원료를 용융, 이송시키는 공정에서 일정비율로 함께 투입, 혼합하여 종래의 랩 필름등이 갖는 제반 문제를 해소함과 동시에 식품의 선도 및 탈취작용을 향상시키고, 살균효과를 함께 얻을수 있게 함으로서 이 랩에 의해 포장, 보관된 식품을 섭취 또는 음용하는 사용자들의 건강과 안전성을 더욱 향상 시킬수 있게 하려는데 그 주된 목적이 있다.The present invention solves the problems of the conventional wrap film by adding and mixing together the wood vinegar solution at a predetermined ratio in the process of melting and transporting the raw material used in the film production, such as wrap, to solve the problems of the conventional wrap film, etc. Its main purpose is to further improve the health and safety of users who consume or consume the food packaged and stored by the lab by improving its function and by obtaining a bactericidal effect.
본 발명의 다른 목적은 상기의 목초액이 필름에 함유되어 있으므로 인해 뜨거운 식품의 보관시 발생될 우려가 있는 환경호르몬과 같은 발암물질등을 중화시킴으로서 제품 및 사용자의 안전성을 더욱 향상 시키려는데 있다.Another object of the present invention is to improve the safety of the product and the user by neutralizing carcinogens, such as environmental hormones that may be generated when the hot food is stored because the wood vinegar is contained in the film.
본 발명의 다른 또 하나의 목적은 식품의 포장 또는 처리와 관련한 비닐필름지의 제조시 목초액이 주재로된 혼합물을 적정량 투입하여 줌으로서 그 응용범위를 대폭 확대 하려는데 있다.Another object of the present invention is to significantly expand the scope of application by introducing a suitable amount of the mixture consisting of wood vinegar solution in the production of vinyl film paper related to the packaging or processing of food.
상기한 목적을 달성하기 위하여 본 발명에서는 다음과 같은 목초액을 주재로 한 무독성 필름의 제조방법을 제시한다.In order to achieve the above object, the present invention provides a method for producing a non-toxic film based on the following wood vinegar.
통상의 필름 제조방법에 있어서,In the usual film production method,
선형 저밀도 폴리에틸렌(LLD-PE)과, 저밀도 폴리에틸렌(LD-PE) 및 타르마, 접착제, 계면활성제 등이 일정비율로 혼합된 통상의 랩 필름제조를 위한 원료를 피더기(공급장치)를 통해 고온을 유지하고 있는 통상의 압출성형기에 투입하여 용융, 이송시키는 공정과,The raw material for the production of a typical wrap film, in which linear low density polyethylene (LLD-PE), low density polyethylene (LD-PE) and tarma, adhesive, and surfactant are mixed at a constant ratio, is fed through a feeder (feeder). A process of melting and conveying by inserting into a conventional extrusion molding machine which maintains
원료가 용융되어 액상의 상태로 이송되고 있는 상기 압출 성형기내에 대두유 30 중량%, 식물성접착제 32중량%, 식물성 계면활성제 23중량%, 식물성 대전방지제 10 중량%, 목초액 5중량% 가 혼합된 첨가물을 원료대비 6% 의 비율로 일정하게 예열, 주입시켜 원료와 혼합시키는 공정과,In the extrusion machine in which the raw material is melted and conveyed in a liquid state, an additive containing 30% by weight of soybean oil, 32% by weight of vegetable adhesive, 23% by weight of vegetable surfactant, 10% by weight of vegetable antistatic agent, and 5% by weight of vinegar solution Preheating and injecting at a rate of 6% compared to the mixing with the raw material,
상기 혼합물이 압출기 종단의 압출금형을 통해 두께 8 ~ 20㎛ 를 유지하는 필름을 압출 성형하는 일련의 성형공정이 연속적으로 이루어지는 목초액을 주재로한 무독성 필름의 제조방법을 제공한다.The mixture provides a method for producing a non-toxic film based on wood vinegar, which is a series of molding process in which a series of extrusion process for extruding a film having a thickness of 8 ~ 20㎛ through an extrusion mold at the end of the extruder.
이와같은 제조방법에 의해 성형되는 본 발명은 가정용 및 업소용으로 적합한 랩, 즉 식품의 포장용으로 적합한 랩을 얻을수 있었는바, 즉 무공해성, 절단성 및 점착성이 우수하였고, 투명성과 방운성이 좋고 적당한 강도의 랩을 얻을수 있었다.The present invention molded by such a manufacturing method was able to obtain a wrap suitable for homes and businesses, that is, a wrap suitable for packaging food, that is, excellent in pollution-free, cutability and tackiness, good transparency, weather resistance and moderate strength Could get a rap.
이때 상기 목초액이 혼합된 첨가물은 통상의 필름 압출성형기를 이루고 있는 히터가 구비된 철관 내에 외부의 동력을 받아 회전하고 있는 이송스크류에 의해 용융된 원료가 일측을 향해 지속적으로 이송되고 있고, 또한 고온을 유지하고 있으므로 별도의 예열장치는 불필요하며,At this time, the additives mixed with the wood vinegar is continuously conveyed to one side by a feed screw that is rotated by a rotating screw driven by an external power in an iron pipe equipped with a heater forming a conventional film extrusion machine, and also maintains a high temperature. No extra preheating device is required
회전하는 이송스크류의 축봉에 노즐형태의 분사공을적어도 하나이상 형성하고, 이송스크류를 이루고 있는 축봉의 일측과 연통된 미세유도로를 형성하여 첨가물에 압을 가해 주입시킴으로서 일정 압력으로 주입되는 첨가물의 주입압력과 이송스크류의 회전이 일정하게 지속적으로 이루어져 용융상태의 원료와 상기 첨가물이고루 혼합됨을 알수 있었다.At least one nozzle-shaped injection hole is formed on the shaft of the rotating screw, and a micro-induction path communicating with one side of the shaft forming the screw is formed to apply pressure to the additive, thereby injecting the additive at a predetermined pressure. It was found that the injection pressure and the rotation of the feed screw were continuously and constantly mixed with the raw materials in the molten state and the additives.
다음은 본 발명이 응용 실시될수있는 실시예로서 고밀도 폴리 에틸렌(HDPE)이 주원료인 포장용 빽과;The following is an embodiment in which the present invention can be applied to the packing mil and the high density polyethylene (HDPE) is the main raw material;
저밀도 폴리에틸렌(LDPE)이 주원료인 포장용 지퍼빽, 위생장갑, 김장봉투, 쓰레기봉투등을 제조하는 경우;When manufacturing low-density polyethylene (LDPE) packaging bags with main ingredients, sanitary gloves, gimjang bags, garbage bags, etc .;
고밀도 또는 저밀도 폴리에틸렌으로 구성된 주 원료 95 중량% 에 목초액 5 중량% 를 다른 혼합물 없이 첨가한 경우에도 전술한 본 발명과 동일한 효과를 얻을수 있었다.The same effect as the above-described invention was obtained even when 5 wt% of wood vinegar was added to 95 wt% of the main raw material composed of high density or low density polyethylene without any other mixture.
또한 빵봉지등의 식품포장용 비닐필름을 제조하는 경우에는 주원료 92 중량% 에 목초액 3 중량% 와, 식물성 계면활성제 5 중량% 를 혼합한 첨가물을 투입하였더니 이 또한 전술한 본 발명과 동일한 효과를 얻을수 있었다.In addition, in the case of manufacturing a food packaging vinyl film such as bread bags, an additive containing a mixture of 3% by weight of wood vinegar and 5% by weight of a vegetable surfactant was added to 92% by weight of the main raw material. there was.
또한 종이컵, 컵라면등의 식품 포장용기의 내면에 라미네이팅 형태로 코팅되는 코팅용 비닐필름을 제조하는 경우에는 전술한 제 1 실시예에서와 같이 주 원료 95 중량% 에 목초액 5 중량%를 다른 첨가물 없이 주입하였더니 식품보호성 또는 작업성에 전혀 문제되지 않고, 포장식품의 풍미를 장기간 유지시킬수 있는등의 전술한 본발명과 동일한 효과를 얻을수 있었다.In addition, when manufacturing a coating vinyl film coated in a laminating form on the inner surface of the food packaging containers such as paper cups, cup noodles, etc., as in the first embodiment described above 95% by weight of the main raw material 5% by weight of the wood herb solution without other additives When injected, it was possible to obtain the same effect as the above-described invention, such as maintaining the flavor of the packaged food for a long time without any problem in food protection or workability.
이와같은 본 발명에 의하면 목초액을 랩등의 필름 제조에 사용되는 원료를 용융시키는 공정에서 직접 주입, 혼합하여 줌으로서 제조시 문제됨 없이 그 사용을 용이하게 함과 동시에 종래의 랩을 비롯한 비닐필름 제품이 갖는 여러 제반 문제를해소하였고, 이를 사용할 경우에는 필름에 함유되어 있는 상기의 목초액 성분이 식품에 직, 간접적으로 작용하여 식품의 선도 및 탈취작용을 향상시키고, 살균효과를 함께 얻을수 있게 함으로서 이 랩에 의해 포장, 보관된 식품을 섭취 또는 음용하는 사용자들의 건강과 안전성을 더욱 향상 시킬수 있게 되었을뿐 아니라 뜨거운 식품의 보관시 다른 조성물과 혼합되어 성형 완료된 필름으로부터 발생될 우려가 있는 환경호르몬과 같은 발암물질등을 자체에서 중화시킴으로서 제품 및 사용자의 안전성을 더욱 향상 시키는등의 유용한 효과를 함께 얻을수 있는 매우 유익한 발명임이 명백하다.According to the present invention, by directly injecting and mixing wood vinegar in the process of melting the raw materials used in the manufacture of films such as wraps, and easy to use without problems during the production, and the conventional vinyl film products including wraps To solve this problem, the wood vinegar component contained in the film acts directly or indirectly on the food to improve the freshness and deodorization of the food, and to obtain a bactericidal effect. This can improve the health and safety of users who consume or drink the food packaged and stored, as well as carcinogens, such as environmental hormones, which may be generated from the finished film by mixing with other compositions when storing hot food. Improves the safety of products and users by neutralizing To be a very useful invention that obtained with the useful effect, such that it is clear.
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2000-0085204A KR100385445B1 (en) | 2000-12-29 | 2000-12-29 | A manufacture method of innocuousness film using pasture liquid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2000-0085204A KR100385445B1 (en) | 2000-12-29 | 2000-12-29 | A manufacture method of innocuousness film using pasture liquid |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020055944A KR20020055944A (en) | 2002-07-10 |
KR100385445B1 true KR100385445B1 (en) | 2003-05-27 |
Family
ID=27688458
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR10-2000-0085204A KR100385445B1 (en) | 2000-12-29 | 2000-12-29 | A manufacture method of innocuousness film using pasture liquid |
Country Status (1)
Country | Link |
---|---|
KR (1) | KR100385445B1 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57170175A (en) * | 1981-04-15 | 1982-10-20 | Furointo Sangyo Kk | Material for food preservation device |
JPS58111668A (en) * | 1981-12-24 | 1983-07-02 | Nippon Kayaku Co Ltd | Antiseptic and fungicidal agent for food |
JPH0297348A (en) * | 1988-10-04 | 1990-04-09 | Takamasa Iritani | Freshness-keeping agent for food |
KR19980064987A (en) * | 1998-06-12 | 1998-10-07 | 조건식 | Antibacterial. Insect repellent sacks and antibacterial compositions |
KR20020014852A (en) * | 2000-08-19 | 2002-02-27 | 이상현 | A manufacturing method of atoxic wrap film uswg pyroligneous liquor |
-
2000
- 2000-12-29 KR KR10-2000-0085204A patent/KR100385445B1/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS57170175A (en) * | 1981-04-15 | 1982-10-20 | Furointo Sangyo Kk | Material for food preservation device |
JPS58111668A (en) * | 1981-12-24 | 1983-07-02 | Nippon Kayaku Co Ltd | Antiseptic and fungicidal agent for food |
JPH0297348A (en) * | 1988-10-04 | 1990-04-09 | Takamasa Iritani | Freshness-keeping agent for food |
KR19980064987A (en) * | 1998-06-12 | 1998-10-07 | 조건식 | Antibacterial. Insect repellent sacks and antibacterial compositions |
KR20020014852A (en) * | 2000-08-19 | 2002-02-27 | 이상현 | A manufacturing method of atoxic wrap film uswg pyroligneous liquor |
Also Published As
Publication number | Publication date |
---|---|
KR20020055944A (en) | 2002-07-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1951056B1 (en) | Composition for use in edible biodegradable articles and method of use | |
EP1359190B1 (en) | Compositions for photodegradable and biodegradable plastic product and use thereof | |
WO1997019988A9 (en) | Biodegradable, grain protein-based solid articles and forming methods | |
DE2552126A1 (en) | WATER-SOLUBLE AND EDIBLE THERMOPLASTIC MOLDING COMPOUNDS, PROCESS FOR THEIR PRODUCTION AND USE OF THE SAME FOR THE PRODUCTION OF MOLDINGS | |
CN104558750A (en) | High-performance nano preservative film | |
CN104086777A (en) | PLA (poly lactic acid) modified material and preparation method thereof | |
CN110577753A (en) | Method for manufacturing degradable disposable tableware by using jasmine | |
KR101796074B1 (en) | Bioplastic with improved insect-proof and antimicrobial and a method there of | |
KR100378875B1 (en) | Synthetic resin product containing shellfish powder and its manufacturing method | |
KR100385445B1 (en) | A manufacture method of innocuousness film using pasture liquid | |
KR100391779B1 (en) | A manufacturing method of atoxic wrap film uswg pyroligneous liquor | |
CN103665510A (en) | Antibacterial fresh-keeping film | |
CN107298785A (en) | A kind of environment friendly bacteriostatic polyethylene film and preparation method thereof | |
KR100656984B1 (en) | Food Packaging Film having Anti-Oxidative and Antimicrobial Properties, and Preparation Method thereof | |
KR20150010109A (en) | Polymer product for food packaging having bread roasting flavour and the manufacturing method thereof | |
US20230189861A1 (en) | Granulate of only natural constitutions; granulate for the manufacture of composable products and method for manufacturing the granulate and the products obtained therefrom | |
KR101545288B1 (en) | Eco friendly material pellet having good maintenance effect of freshness, and manufacturing method thereof | |
KR102443077B1 (en) | Antibacterial film and manufacturing method thereof | |
CN106616206A (en) | Natural food preservative | |
KR100310994B1 (en) | A method for manufacturing plasticity keeping freshness and having antibiosis | |
WO2020106261A2 (en) | A novel egg protective coating material and production method thereof | |
KR800000025B1 (en) | Method of manufacturing a protein-starch binary molding compositon | |
JP2869666B2 (en) | Method for producing scented resin composition | |
JP2001288697A (en) | Antimicrobial-treated paper | |
JP2002101860A (en) | Film or sheet, and method for keeping freshness of fresh food with the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A201 | Request for examination | ||
E701 | Decision to grant or registration of patent right | ||
GRNT | Written decision to grant | ||
FPAY | Annual fee payment |
Payment date: 20100513 Year of fee payment: 8 |
|
LAPS | Lapse due to unpaid annual fee |