KR19980018145A - Construction Interior Material Using Paper Sludge and Manufacturing Method Thereof - Google Patents
Construction Interior Material Using Paper Sludge and Manufacturing Method Thereof Download PDFInfo
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- KR19980018145A KR19980018145A KR1019970025206A KR19970025206A KR19980018145A KR 19980018145 A KR19980018145 A KR 19980018145A KR 1019970025206 A KR1019970025206 A KR 1019970025206A KR 19970025206 A KR19970025206 A KR 19970025206A KR 19980018145 A KR19980018145 A KR 19980018145A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/26—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
- B28B1/265—Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor pressure being applied on the slip in the filled mould or on the moulded article in the mould, e.g. pneumatically, by compressing slip in a closed mould
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/24—Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper, cork
- C04B18/241—Paper, e.g. waste paper; Paper pulp
- C04B18/243—Waste from paper processing or recycling paper, e.g. de-inking sludge
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/4501—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with preformed sheet-like elements
- C04B41/4503—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with preformed sheet-like elements having an adhesive layer
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/02—Granular materials, e.g. microballoons
- C04B14/04—Silica-rich materials; Silicates
- C04B14/10—Clay
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B14/00—Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B14/38—Fibrous materials; Whiskers
- C04B14/40—Asbestos
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Environmental & Geological Engineering (AREA)
- Civil Engineering (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Finishing Walls (AREA)
- Panels For Use In Building Construction (AREA)
- Paper (AREA)
Abstract
본 발명은 제지 공장에서 종이를 만드는 과정에서 발생되는 폐기물인 제지 슬러지를 이용하여 건축용 내장재로써 완성시 질과 강도 등이 월등히 우수한 제품을 제공할 수 있도록 한 제지 슬러지를 이용한 건축용 내장재 및 그 제조 방법에 관한 것이다.The present invention relates to a building interior material using a paper sludge and a method for manufacturing the same, which can provide a product having excellent quality and strength upon completion as a building interior material using paper sludge, which is a waste generated in the process of making paper in a paper mill. It is about.
상기 목적을 달성하기 위해 본 발명은 페이퍼 슬러지 35~39 중량부, 규조토 10~15 중량부, 석고 10~15 중량부, 석면 8~10 중량부, 탄산칼슘 4~8 중량부, 황토(점토) 9~15 중량부, 수산화 칼슘 3~8 중량부, 규산염 3~11 중량부로 조성된다.In order to achieve the above object, the present invention provides 35 to 39 parts by weight of paper sludge, 10 to 15 parts by weight of diatomaceous earth, 10 to 15 parts by weight of gypsum, 8 to 10 parts by weight of asbestos, 4 to 8 parts by weight of calcium carbonate, and yellow clay (clay). 9-15 weight part, calcium hydroxide 3-8 weight part, and silicate 3-11 weight part.
이때 상기 탄산 칼슘은 8~12 중량부의 질납석으로 대체할 수도 있다.In this case, the calcium carbonate may be replaced with 8 to 12 parts by weight of zirconia.
이상과 같이 조성되는 본 발명의 공정에 따른 제조 방법은 상기한 조성물을 스크류 콘베어식으로 이송하여 반죽기로 완전 배합후 액체 경화제인 에틸 실리케이트 26 중량부를 투입한 후 배합한다. 완전 배합후 거품 방지제로써 이소옥틸알콜 9 중량부를 투입하고, 공업용수를 35 중량부를 투입하여 빠르게 반죽하고 나서 스크류 콘베어식으로 금형에 이동시키어 일정 크기로 제조되게 한 금형을 850℃ 정도로 가열된 상태에서 상기 반죽된 재료를 금형에 투입하여 550톤의 압력으로 찍어 성형한후, 인산 이수소 암모늄으로 불연 코팅후, 에어 스프레이로 본드를 살포하고, 외장을 위한 제지를 전 후면에 흡착시킨 후 약 180℃로 가열된 기체로 약 40초 동안 급속 건조시켜서 완성한다.In the manufacturing method according to the process of the present invention as described above, the composition is transferred to a screw conveyor type, and then blended with 26 parts by weight of ethyl silicate, which is a liquid curing agent, after mixing with a kneader. After complete mixing, 9 parts by weight of isooctyl alcohol was added as an antifoaming agent, and 35 parts by weight of industrial water was kneaded quickly, and then the mold was moved to the mold by screw conveyor to be manufactured to a predetermined size. The kneaded material was put into a mold and formed by dipping at a pressure of 550 tons, then non-flammable coating with ammonium dihydrogen phosphate, spraying the bond with an air spray, and adsorbing the paper for exterior to the front and back about 180 ° C. Complete by rapid drying for about 40 seconds with a gas heated with
Description
본 발명은 제지 공장에서 종이를 만드는 과정에서 발생되는 폐기물인 제지 슬러지를 이용하여 건축용 내장재를 제조하는 기술에 관한 것으로, 특히 건축용 내장재로써 완성시 질과 강도 등이 월등히 우수한 제품을 제공할 수 있도록 한 제지 슬러지를 이용한 건축용 내장재 및 그 제조 방법에 관한 것이다.The present invention relates to a technology for manufacturing building interior materials using paper sludge, which is a waste generated in the process of making paper in a paper mill, and in particular, to provide a product having excellent quality and strength when finished as a building interior material. The present invention relates to a building interior material using paper sludge and a method of manufacturing the same.
일반적으로 산업 발달과 더불어 환경은 심각한 몸살을 앓고 있는 것이 지금에 현실에 있다.In general, with the development of the industry, it is now a reality that the environment is suffering seriously.
그 중 페이퍼 슬러지는 종이를 제조하는 그 처리 과정에서 각종 중금속으로 오염되어 처리가 힘들뿐 아니라 토양과 수질에 오염을 제공하는 문제가 있다.Among them, paper sludge is contaminated with various heavy metals in the process of manufacturing paper, which makes it difficult to treat and provides a problem of soil and water pollution.
이러한 종래의 페이퍼 슬러지는 일부 달걀 받침대를 제조하는데 사용되기는 하나 일부에 지나지 않고, 위생상의 이유로 그나마 기피하고 있는 실정에 있다.These conventional paper sludges are used to make some egg holders, but only a part of them, and are being avoided for hygienic reasons.
따라서 대부분의 발생량을 폐기 처리하는데, 매립 방법은 막대한 처리 비용과 수질 및 토양을 오염시켜 바람직하지 못하고, 소각 방법 또한 건조시켜 소각함에 따라 처리 비용의 부담과 소각시 배출되는 유해 가스는 대기 오염의 심각한 결과를 초래한다.Therefore, most of the generated amount is disposed of. However, the landfill method is undesirably contaminated with enormous treatment costs and water and soil, and the incineration method is also dried and incinerated, and the harmful gas emitted during incineration is a serious problem of air pollution. Results.
일반적으로 이러한 페이퍼 슬러지는 다량의 펄프 찌꺼기와 Cb.Hg.Pb.H2O등 일부를 제외한 유해 화학 물질로 이루어진다.In general, these paper sludges are composed of hazardous chemicals, except for a large amount of pulp waste and some of Cb.Hg.Pb.H 2 O.
종래에는 제지 회사마다 다소의 차이는 있지만 약 65%의 수분을 함유한 상태로 배출하였으나 현재는 처리 비용의 문제로 약 40% 내외로 수분을 줄여서 배출하고 있다.In the past, the paper companies discharged the water containing about 65% of water, although there are some differences, but the water is discharged by reducing the water to about 40% due to the processing cost.
한편 이 페이퍼 슬러지는 일부의 석분을 함유하고 있어 석고 보드 대용의 제품을 만들어 합판 대용품인 내장재로의 개발을 용이하게 하는 조건을 가지고 있다.On the other hand, this paper sludge contains a part of stone powder and has a condition to facilitate the development of interior materials, which is a substitute for plywood, by making products for gypsum board.
따라서 본 발명은 상기와 같은 종래의 문제점을 해결하기 위해 창안된 것으로, 본 발명의 목적은 페이퍼 슬러지의 재활용으로 건축용 내장재를 제조함으로써 폐기물의 처리와 이를 원료로 함으로써의 수입 원료의 대체 효과로, 일석이조의 비용 창출을 이루도록 함에 그 목적이 있다.Therefore, the present invention was devised to solve the above-mentioned conventional problems, and an object of the present invention is to manufacture waste materials by recycling paper sludge, thereby treating waste and replacing the imported raw materials by using them as raw materials. Its purpose is to achieve the cost creation.
상기 목적을 달성하기 위해 본 발명은 페이퍼 슬러지 35~39 중량부, 규조토 10~15 중량부, 석고 10~15 중량부, 석면 8~10 중량부, 탄산칼슘 4~8 중량부, 황토(점토) 9~15 중량부, 수산화 칼슘 3~8 중량부, 규산염 3~11 중량부로 조성된다.In order to achieve the above object, the present invention provides 35 to 39 parts by weight of paper sludge, 10 to 15 parts by weight of diatomaceous earth, 10 to 15 parts by weight of gypsum, 8 to 10 parts by weight of asbestos, 4 to 8 parts by weight of calcium carbonate, and yellow clay (clay). 9-15 weight part, calcium hydroxide 3-8 weight part, and silicate 3-11 weight part.
이때 상기 탄산 칼슘은 8~12 중량부의 질납석으로 대체 할 수도 있다.At this time, the calcium carbonate may be replaced with 8 to 12 parts by weight of zirconia.
이상과 같이 조성되는 본 발명의 공정에 따른 제조 방법을 설명하면 다음과 같다.Referring to the manufacturing method according to the process of the present invention is as described above is as follows.
상기한 조성물을 스크류 콘베어식으로 이송하여 반죽기로 완전 배합후 액체 경화제인 에틸 실리케이트 26 중량부를 투입한 후 배합한다. 완전 배합후 거품 방지제로써 이소옥틸알콜 9 중량부를 투입하고, 공업용수를 35 중량부를 투입하여 빠르게 반죽하고 나서 스크류 콘베어식으로 금형에 이동시킨다.The composition is transferred to a screw conveyor type, and completely mixed with a kneader, and then 26 parts by weight of ethyl silicate, which is a liquid curing agent, is added and then mixed. After complete mixing, 9 parts by weight of isooctyl alcohol was added as an antifoaming agent, and 35 parts by weight of industrial water was kneaded quickly, and then kneaded to a mold by screw conveyor.
일정 크기로 제조되게 한 금형을 850℃ 정도로 가열된 상태에서 상기 반죽된 재료를 금형에 투입한다. 금형에서의 압은 550톤으로 찍어 성형하고, 성형이 끝난 후 필요한 표면처리를 하기 위해 인산 이수소 암모늄으로 불연 코팅 후, 에어 스프레이로 본드를 살포하고, 외장을 위한 제지를 전 후면에 흡착시킨 후, 약 180℃로 가열된 기체로 약 40초 동안 급속 건조시켜서 완성한다.The kneaded material is introduced into the mold while the mold which is manufactured to a predetermined size is heated to about 850 ° C. The pressure in the mold is molded by dipping 550 tons, and after the molding is finished, non-flammable coating with ammonium dihydrogen phosphate for the necessary surface treatment, spraying the bond with air spray, adsorbing paper for exterior Complete by rapid drying for about 40 seconds with a gas heated to about 180 ℃.
이하에서 본 발명을 바람직한 실시예의 첨부된 도면에 의해 보다 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in more detail with reference to the accompanying drawings of preferred embodiments.
페이퍼 슬러지 35~39 중량부, 규조토 10~15 중량부, 석고 10~15 중량부, 석면 8~10 중량부, 탄산칼슘 4~8 중량부, 황토(점토) 9~15 중량부, 수산화 칼슘 3~8 중량부, 규산염 3~11 중량부로 조성된다.Paper sludge 35 to 39 parts by weight, diatomaceous earth 10 to 15 parts by weight, gypsum 10 to 15 parts by weight, asbestos 8 to 10 parts by weight, calcium carbonate 4 to 8 parts by weight, yellow clay (clay) 9 to 15 parts by weight, calcium hydroxide 3 8 parts by weight and 3 to 11 parts by weight of silicate.
이때 상기 탄산 칼슘은 8~12 중량부의 질납석으로 대체할 수도 있다.In this case, the calcium carbonate may be replaced with 8 to 12 parts by weight of zirconia.
상기에서 페이퍼 슬러지가 35 중량부 이하이면 인장력이 크게 저하하고 39 중량부를 초과하면 불연성 및 내구성이 떨어진다.If the paper sludge is 35 parts by weight or less, the tensile force is greatly reduced, and if it exceeds 39 parts by weight, non-combustibility and durability falls.
그리고 상기 다른 조성물의 범위를 초과하는 것은 인장력에 크게 좌우하며, 특히 수산화 칼슘은 8 중량부를 초과하면 시공성 및 내구성이 크게 떨어진다.And exceeding the range of the other composition greatly depends on the tensile force, in particular calcium hydroxide is significantly less workability and durability when it exceeds 8 parts by weight.
또한 질 납석의 대체 효과는 다소 가격은 상승되나 소결성이 좋고, 내화성이 향상되며, 인체에 이로운 원적외선 방사체인 이점이 있다.In addition, the substitution effect of calcite is somewhat higher in price, but the sinterability is good, the fire resistance is improved, and there is an advantage that the far-infrared radiator is beneficial to the human body.
이상과 같이 조성되는 본 발명의 공정에 따른 제조 방법을 설명하면 다음과 같다.Referring to the manufacturing method according to the process of the present invention is as described above is as follows.
상기한 조성물을 스크류 콘베어식으로 이송하여 반죽기로 완전 배합후 액체 경화제인 에틸 실리케이트 26 중량부를 투입한 후 배합한다. 완전 배합후 거품 방지제로써 이소옥틸알콜 9 중량부를 투입하고, 공업용수를 35 중량부를 투입하여 빠르게 반죽하고 나서 스크류 콘베어식으로 금형에 이동시킨다.The composition is transferred to a screw conveyor type, and completely mixed with a kneader, and then 26 parts by weight of ethyl silicate, which is a liquid curing agent, is added and then mixed. After complete mixing, 9 parts by weight of isooctyl alcohol was added as an antifoaming agent, and 35 parts by weight of industrial water was kneaded quickly, and then kneaded to a mold by screw conveyor.
일정 크기로 제조되게 한 금형을 850℃ 정도로 가열된 상태에서 상기 반죽된 재료를 금형에 투입한다. 금형에서의 압은 550톤으로 찍어 성형하고, 성형이 끝난 후 필요한 표면처리를 하기 위해 인산 이수소 암모늄으로 불연 코팅후, 에어 스프레이로 본드를 살포하고, 외장을 위한 제지를 전 후면에 흡착시킨 후, 약 180℃로 가열된 기체로 약 40초 동안 급속 건조시켜서 완성한다.The kneaded material is introduced into the mold while the mold which is manufactured to a predetermined size is heated to about 850 ° C. The pressure in the mold is formed by dipping at 550 tons, and after the molding is finished, a non-flammable coating with ammonium dihydrogen phosphate is needed for spraying, then spraying the bond with air spray, adsorbing paper for exterior Complete by rapid drying for about 40 seconds with a gas heated to about 180 ℃.
본 발명에 의한 건축용 보드와 종래의 보드의 제품 규격에 따른 무게의 비교예를 아래의 표로 설명한다.A comparative example of the weight according to the product standard of the building board and the conventional board according to the present invention will be described in the table below.
상기의 표에서와 같이 종래에 비하여 제품의 중량을 감소시킬 수 있어 경량화를 이룰 수 있다.As shown in the above table, it is possible to reduce the weight of the product as compared to the prior art can achieve a light weight.
그리고 인장 강도에 있어서도 0.9T 시편의 실험 결과 종래의 보드가 54.9 PSI 인데 반하여 본 발명은 151.0 PSI 에 달하는 것으로 강도에서도 우수하며, 또한 중요한 인화점, 발화점 융점에 있어서도 방음(흡음)에 있어서도 시편의 두께가 12T일 때 8%, 9T일 때는 17%의 데시벨 감소가 이루어짐을 확인하였다.In addition, the tensile strength of the 0.9T specimen was 54.9 PSI, whereas the present invention reached 151.0 PSI, which is excellent in strength, and the thickness of the specimen in soundproofing (absorption) in important flash point and flash point melting point. It was confirmed that the decibel reduction of 8% at 12T and 17% at 9T.
따라서 본 발명에 의한 건축용 보드는 제지 슬러지를 사용함에 따라 원료의 원가를 저렴히 할 수 있으며, 제품이 가볍고 견고하여 시공이 편리하며 금형에 의해 생산함으로써 다양한 제품을 구현할 수 있는 특징과 흡음 능력이 우수하다.Therefore, the building board according to the present invention can reduce the cost of raw materials according to the use of paper sludge, the product is light and robust, convenient construction and excellent in the characteristics and sound absorption ability to implement a variety of products by producing by a mold. .
이상과 같이 구성되고 작용되는 본 발명은 폐기물로 분류되어 환경 오염과 폐기에 따른 비용을 유발하는 제지 슬러지를 주 원료로 하여 제조 비용을 저렴히 할 수 있고, 이에 따른 제품의 성능도 우수한 건축용 내장재를 제공함으로써 시공이 간편하고, 단열 및 흡음이 우수하고, 습도에도 강한 내장재를 제공하는 효과가 있다.The present invention constituted and operated as described above can reduce the manufacturing cost by using paper sludge, which is classified as waste and induces costs due to environmental pollution and disposal, as a main raw material, thereby providing a building interior material having excellent performance. By doing so, there is an effect of providing an interior material that is easy to construct, excellent in heat insulation and sound absorption, and resistant to humidity.
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KR1019970025206A KR100226101B1 (en) | 1997-06-17 | 1997-06-17 | Construction using paper sludge and production thereof |
PCT/KR1998/000163 WO1998057904A1 (en) | 1997-06-17 | 1998-06-16 | Interior building material made from paper-mill sludge and method for manufacturing the same |
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KR1019970025206A KR100226101B1 (en) | 1997-06-17 | 1997-06-17 | Construction using paper sludge and production thereof |
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KR20010069507A (en) * | 2001-04-07 | 2001-07-25 | 오주희 | yellow soil composition |
KR20020040367A (en) * | 2000-11-24 | 2002-05-30 | 최봉석 | yellow soil to main method manufacture of board pan |
KR100484116B1 (en) * | 2001-10-16 | 2005-04-18 | 임철웅 | Afforestation mixture containing long fibers |
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KR20150142896A (en) * | 2014-06-12 | 2015-12-23 | 주식회사 에이유 | Powder from paper sludge and a method of producing the same |
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FI64129C (en) * | 1980-05-30 | 1983-10-10 | Partek Ab | FRAMSTAELLNING AV EN BYGGNADSPLATTA ENLIGT UPPRULLNINGSFOERFARANDET |
KR900007077B1 (en) * | 1988-05-04 | 1990-09-28 | 이용복 | Hardening composition and method for producing thereof |
DE4141271C1 (en) * | 1991-12-14 | 1992-11-05 | Sicowa Verfahrenstech | |
KR0162618B1 (en) * | 1995-02-28 | 1998-12-15 | 강한성 | Interior panel using soil |
-
1997
- 1997-06-17 KR KR1019970025206A patent/KR100226101B1/en not_active IP Right Cessation
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1998
- 1998-06-16 WO PCT/KR1998/000163 patent/WO1998057904A1/en active Search and Examination
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KR100814740B1 (en) * | 2006-12-07 | 2008-03-19 | 백태현 | Method for manufacturing the insulating material having sound-proofing effects |
KR20150142896A (en) * | 2014-06-12 | 2015-12-23 | 주식회사 에이유 | Powder from paper sludge and a method of producing the same |
KR101497027B1 (en) * | 2014-07-04 | 2015-03-02 | (주)영우산업 | Functional ecostone and manufacturing method of the same |
WO2016003093A1 (en) * | 2014-07-04 | 2016-01-07 | (주)영우산업 | Functional ecostone and method for manufacturing same |
CN109293332A (en) * | 2018-11-27 | 2019-02-01 | 曲靖师范学院 | A kind of diatomite light gypsum mortar |
CN109437797A (en) * | 2018-12-06 | 2019-03-08 | 曲靖师范学院 | A kind of slag micropowder modified ardealite mortar |
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Also Published As
Publication number | Publication date |
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KR100226101B1 (en) | 1999-10-15 |
WO1998057904A1 (en) | 1998-12-23 |
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