CN110078414A - A kind of diatom ooze coating - Google Patents
A kind of diatom ooze coating Download PDFInfo
- Publication number
- CN110078414A CN110078414A CN201910235961.3A CN201910235961A CN110078414A CN 110078414 A CN110078414 A CN 110078414A CN 201910235961 A CN201910235961 A CN 201910235961A CN 110078414 A CN110078414 A CN 110078414A
- Authority
- CN
- China
- Prior art keywords
- parts
- mass ratio
- diatom ooze
- mixed
- ooze coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F112/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F112/02—Monomers containing only one unsaturated aliphatic radical
- C08F112/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F112/06—Hydrocarbons
- C08F112/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
Abstract
The present invention relates to a kind of diatom ooze coatings, belong to technical field of finishing materials.The present invention can be very good to improve damping and the clean-up effect of coating by modified particles, by utilizing granular absorption performance therein, it is adsorbed, promote and increase the clean-up effect of diatomite using oxygen hollow body therein, secondly increased using wherein copper sulphate and enhancing damping effect is absorbed and released to moisture, and improve anti-microbial property, the present invention is by utilizing volcanic ash, zeolite is as basic raw material, improve the active group such as amido of particle surface, there is good affinity with wall, increase bond strength, the combination water of zeolite interior is utilized simultaneously, the property discharged at high operating temperatures, avoid the drying of air, and clean-up effect can be enhanced using volcanic ash；The present invention can be very good to improve bond effect and water retention property by the way that mixed polymer is added, and enhance the water absorbing properties under the film forming and tidal environment under caking property and dry tack free environment therein.
Description
Technical field
The present invention relates to a kind of diatom ooze coatings, belong to technical field of finishing materials.
Background technique
Diatom ooze is a kind of emerging functional interior decoration wall material, using certain technology, can will be dissociated in air
Formaldehyde, benzene gas, radiogen etc. are decomposed by absorbing, and are converted to innocuous substance.Diatom ooze coating is then that one kind contains silicon
The interiro wall latex paint coating of algal gel, by formula using the approach such as the diatom material with super adsorption capacity, realization pair
The absorption and degradation of indoor formaldehyde, thus can satisfy simultaneously using the decorative, feature of environmental protection.
Diatomite is a kind of siliceous rock, is by being referred to as the dead later silicate remains shape of the unicellular alga of diatom
At main component is silica, is shown as micron-sized porous material under electron microscope, and porosity is up to 90%, unit plane
Fine hole number in product is thousands of times out more than charcoal.Just because of this kind of performance of diatomite, has diatom ooze good
Formaldehyde adsorption, purification air, adjust humidity, releasing negative oxygen ion, fire protection flame retarding, the functions such as the self-cleaning, deodorization and sterilization of metope.No
Only in this way, diatom ooze coating also has the characteristics that aesthetic feeling is outstanding, easy construction, therefore, diatom ooze becomes more and more consumers
Selection.In recent years, influence of the house decorative material to air quality is increasingly taken seriously, and people are beautiful, real in addition to selection
Outside decorative effect, health environment-friendly function also become selection ornament materials an important reference indicator, therefore ecological, environmental protective,
Healthy comfortable house decorative material becomes the Main Trends of The Development of domestic and international building material industry.
Currently, diatomite is core component in the market in various diatom ooze coating formulas.Porous, fluffy, the change of diatomite
It learns property and stablizes feature, make it have the performances such as absorption, heat-insulated, sound insulation, cooperate other bonding components, color and particle adjusting group
Point, the New Wall Material for being different from traditional coating is obtained, although preparation-obtained diatom ooze coating environmental-protecting performance is preferable at present,
Cohesive force is poor, not scrubbing resistance, is mainly manifested in poor water resistance, is not suitable for moist environment and uses, and usual damping effect is not
Obviously, purification ability of air is limited.
Summary of the invention
The technical problems to be solved by the invention: it is unobvious for current diatom ooze coating damping effect, purify air energy
The limited problem of power, the present invention provides a kind of diatom ooze coatings.
In order to solve the above technical problems, the present invention is using technical solution as described below:
A kind of diatom ooze coating, according to parts by weight, including 50~60 parts of diatomite of following component, 10~15 parts of water, 1.3~
1.9 parts of additives, 16~18 parts of modified particles, 12~15 parts of active particles, 7~13 parts of polymer, 1~3 part of auxiliary agent.
The additive is sodium cellulose glycolate, sodium carboxymethyl starch and odium stearate 5:2~5:1 in mass ratio mixing
It forms.
The modified particles the preparation method comprises the following steps:
(1) according to parts by weight, 70~75 parts of ethanol solutions, 60~70 parts of water, 40~50 parts of mixed metal salts, 40~45 parts are taken
Mix monomer, 29~38 parts of ethyl orthosilicates, 2~8 parts of cetyl trimethylammonium bromides, 3~7 parts of initiators, 1~1.5 part
Polyethylene glycol；
(2) water, mixed metal salt, polyethylene glycol are put into container and are stirred evenly first, using ammonium hydroxide adjust pH to 7.5~
8.0, it stirs evenly, stands, filter, dry, calcining collects calcined material, calcined material, water and mix monomer are uniformly mixed, put
Enter in reaction kettle, nitrogen protection, preheat, add ethyl orthosilicate, cetyl trimethylammonium bromide and initiator, heating is anti-
It answers；
(3) after the completion of reaction, cooling, it discharges, freeze-drying object is collected in freeze-drying, by freeze-drying object and tetrahydrofuran
1:8 in mass ratio~14 is mixed, and stands, filtering, using ethanol washing, collects washings, dry, collects dried object；
(4) by dried object, 0.1mol/L sulfuric acid solution and the copper sulphate agitating and heating of 7~9:16:3 in mass ratio, 4~6 are being placed in
DEG C, it stands, filtering, collects filter residue to get modified particles.
The mix monomer is styrene, polyvinylpyrrolidone 4:2~4 in mass ratio mix.
The mixed metal salt is that manganese sulfate, iron chloride and magnesium nitrate 3:4~6:2 in mass ratio are mixed.
The initiator is azo-bis-isobutyl cyanide, potassium peroxydisulfate 7:1~3 in mass ratio mix.
The active particle is that volcanic ash, zeolite 7~9:4 in mass ratio mill, and collects mill admixture, will grind
It grinds mixture, modifying agent and ethanol solution 9:2~4:18 in mass ratio to be uniformly mixed, heat, filtrate is collected in filtering, and it is dry,
It crushes to get active particle.
The modifying agent is that sodium hydroxide solution is mixed with fatty alkyl dimethyl tertiary amine 5:2~3 in mass ratio.
The polymer is polyglutamic acid, polyallylamine 8:3~5 in mass ratio mix.
The auxiliary agent is calcium carbonate.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention is by using mixed metal salt as base stock, by carrying out well under the action of polyethylene glycol
Dispersion obtains manganese magnesium iron oxygen hollow body by being precipitated using ammonium hydroxide, then again with ethyl orthosilicate, mix monomer
It is mixed, reacts to form polymer by mix monomer, as supporter, ethyl orthosilicate is hydrolyzed, and it is heavy to generate particle
Drop, by dissolving polymer therein using solvent, increases the hole inside particle inside manganese magnesium iron oxygen hollow body
Gap improves absorption property, then recycles and is mixed with copper sulphate, is deposited in hole by forming copper sulfate crystal,
To obtain modified particles, the damping and the clean-up effect that improve coating can be very good by modified particles, by using wherein
Granular absorption performance, adsorbed, use oxygen hollow body therein promote and increase diatomite clean-up effect, secondly utilize
Wherein copper sulphate, which increases, absorbs and releases enhancing damping effect to moisture, and improves anti-microbial property；
(2) present invention is by improving particle by the modification using modifying agent using volcanic ash, zeolite as basic raw material
The active group on surface such as amido has good affinity with wall, increases bond strength, while utilizing the knot of zeolite interior
Heshui, the property discharged at high operating temperatures avoid the drying of air, and clean-up effect can be enhanced using volcanic ash；
(3) present invention can be very good to improve bond effect and water retention property by the way that mixed polymer is added, and enhance therein viscous
Knot property and the film forming under dry tack free environment and the water absorbing properties under tidal environment.
Specific embodiment
Additive be sodium cellulose glycolate, sodium carboxymethyl starch and odium stearate 5:2~5:1 in mass ratio mix and
At.
Modified particles the preparation method comprises the following steps:
(1) according to parts by weight, take 70~75 parts of 1.2mol/L ethanol solutions, 60~70 parts of water, 40~50 parts of mixed metal salts,
40~45 parts of mix monomers, 29~38 parts of ethyl orthosilicates, 2~8 parts of cetyl trimethylammonium bromides, 3~7 parts of initiators, 1
~1.5 parts of polyethylene glycol；
(2) water, mixed metal salt, polyethylene glycol are put into container and are stirred evenly first, using ammonium hydroxide adjust pH to 7.5~
8.0 stirring evenly, 6h is stood, is filtered, it is dry, in 700 DEG C of calcining 2h, calcined material is collected, by calcined material, water and mix monomer
It is uniformly mixed, is put into reaction kettle, nitrogen protection, in 45 DEG C of preheating 30min, adds ethyl orthosilicate, cetyl front three
Base ammonium bromide and initiator are warming up to 80 DEG C, react 9h；
(3) after the completion of reaction, cooling, it discharges, freeze-drying object is collected in freeze-drying, by freeze-drying object and tetrahydrofuran
30min is mixed with 900r/min in 1:8~14 in mass ratio, stands 1h, and filtering is collected washings using ethanol washing, done
It is dry, collect dried object；
(4) dried object, 0.1mol/L sulfuric acid solution and copper sulphate 7~9:16:3 in mass ratio are heated with stirring to 90 DEG C, heating
3h is being placed in 4~6 DEG C, is standing overnight, filtering, collects filter residue to get modified particles.
Mix monomer is styrene, polyvinylpyrrolidone 4:2~4 in mass ratio mix.
Mixed metal salt is that manganese sulfate, iron chloride and magnesium nitrate 3:4~6:2 in mass ratio are mixed.
Initiator is azo-bis-isobutyl cyanide, potassium peroxydisulfate 7:1~3 in mass ratio mix.
Active particle is that volcanic ash, zeolite 7~9:4 in mass ratio mill, and collects mill admixture, mixed by milling
It closes object, modifying agent and 1.0mol/L ethanol solution 9:2~4:18 in mass ratio to be uniformly mixed, is heated to 80 DEG C, heat 2h, mistake
Filtrate is collected in filter, dry, crushes 10min with 800r/min to get active particle.
Modifying agent for 0.6mol/L sodium hydroxide solution is mixed with fatty alkyl dimethyl tertiary amine 5:2~3 in mass ratio and
At.
Polymer is polyglutamic acid, polyallylamine 8:3~5 in mass ratio mix.
Auxiliary agent is calcium carbonate.
A kind of diatom ooze coating, according to parts by weight, including 50~60 parts of diatomite of following component, 10~15 parts of water, 1.3
~1.9 parts of additives, 16~18 parts of modified particles, 12~15 parts of active particles, 7~13 parts of polymer, 1~3 part of auxiliary agent.
Additive is that sodium cellulose glycolate, sodium carboxymethyl starch and odium stearate 5:5:1 in mass ratio are mixed.
Modified particles the preparation method comprises the following steps:
(1) according to parts by weight, take 75 parts of 1.2mol/L ethanol solutions, 70 parts of water, 50 parts of mixed metal salts, 45 parts of mixing single
Body, 38 parts of ethyl orthosilicates, 8 parts of cetyl trimethylammonium bromides, 7 parts of initiators, 1.5 parts of polyethylene glycol；
(2) water, mixed metal salt, polyethylene glycol are put into container and are stirred evenly first, using ammonium hydroxide adjust pH to 7.5~
8.0, it stirs evenly, stands 6h, filter, it is dry, in 700 DEG C of calcining 2h, calcined material is collected, by calcined material, water and mix monomer
It is uniformly mixed, is put into reaction kettle, nitrogen protection, in 45 DEG C of preheating 30min, adds ethyl orthosilicate, cetyl front three
Base ammonium bromide and initiator are warming up to 80 DEG C, react 9h；
(3) after the completion of reaction, cooling, it discharges, freeze-drying object is collected in freeze-drying, by freeze-drying object and tetrahydrofuran
30min is mixed with 900r/min in 1:14 in mass ratio, stands 1h, and filtering collects washings using ethanol washing, dry,
Collect dried object；
(4) dried object, 0.1mol/L sulfuric acid solution and copper sulphate 9:16:3 in mass ratio are heated with stirring to 90 DEG C, heat 3h,
6 DEG C are being placed in, is being stood overnight, is being filtered, is collecting filter residue to get modified particles.
Mix monomer is styrene, polyvinylpyrrolidone 4:4 in mass ratio is mixed.
Mixed metal salt is that manganese sulfate, iron chloride and magnesium nitrate 3:6:2 in mass ratio are mixed.
Initiator is azo-bis-isobutyl cyanide, potassium peroxydisulfate 7:3 in mass ratio is mixed.
Active particle is that volcanic ash, zeolite 9:4 in mass ratio mill, and collects mill admixture, will mill mixing
Object, modifying agent and 1.0mol/L ethanol solution 9:4:18 in mass ratio are uniformly mixed, and are heated to 80 DEG C, heat 2h, are filtered, and are collected
Filtrate, it is dry, 10min is crushed to get active particle with 800r/min.
Modifying agent is that 0.6mol/L sodium hydroxide solution is mixed with fatty alkyl dimethyl tertiary amine 5:3 in mass ratio.
Polymer is polyglutamic acid, polyallylamine 8:5 in mass ratio is mixed.
Auxiliary agent is calcium carbonate.
A kind of diatom ooze coating, according to parts by weight, including 60 parts of diatomite of following component, 15 parts of water, 1.9 parts of additions
Agent, 18 parts of modified particles, 15 parts of active particles, 13 parts of polymer, 3 parts of auxiliary agents.
Additive is that sodium cellulose glycolate, sodium carboxymethyl starch and odium stearate 5:4:1 in mass ratio are mixed.
Modified particles the preparation method comprises the following steps:
(1) according to parts by weight, take 73 parts of 1.2mol/L ethanol solutions, 65 parts of water, 45 parts of mixed metal salts, 43 parts of mixing single
Body, 32 parts of ethyl orthosilicates, 6 parts of cetyl trimethylammonium bromides, 5 parts of initiators, 1.3 parts of polyethylene glycol；
(2) water, mixed metal salt, polyethylene glycol are put into container and are stirred evenly first, using ammonium hydroxide adjust pH to 7.5~
8.0, it stirs evenly, stands 6h, filter, it is dry, in 700 DEG C of calcining 2h, calcined material is collected, by calcined material, water and mix monomer
It is uniformly mixed, is put into reaction kettle, nitrogen protection, in 45 DEG C of preheating 30min, adds ethyl orthosilicate, cetyl front three
Base ammonium bromide and initiator are warming up to 80 DEG C, react 9h；
(3) after the completion of reaction, cooling, it discharges, freeze-drying object is collected in freeze-drying, by freeze-drying object and tetrahydrofuran
30min is mixed with 900r/min in 1:11 in mass ratio, stands 1h, and filtering collects washings using ethanol washing, dry,
Collect dried object；
(4) dried object, 0.1mol/L sulfuric acid solution and copper sulphate 8:16:3 in mass ratio are heated with stirring to 90 DEG C, heat 3h,
5 DEG C are being placed in, is being stood overnight, is being filtered, is collecting filter residue to get modified particles.
Mix monomer is styrene, polyvinylpyrrolidone 4:3 in mass ratio is mixed.
Mixed metal salt is that manganese sulfate, iron chloride and magnesium nitrate 3:5:2 in mass ratio are mixed.
Initiator is azo-bis-isobutyl cyanide, potassium peroxydisulfate 7:2 in mass ratio is mixed.
Active particle is that volcanic ash, zeolite 8:4 in mass ratio mill, and collects mill admixture, will mill mixing
Object, modifying agent and 1.0mol/L ethanol solution 9:3:18 in mass ratio are uniformly mixed, and are heated to 80 DEG C, heat 2h, are filtered, and are collected
Filtrate, it is dry, 10min is crushed to get active particle with 800r/min.
Modifying agent for 0.6mol/L sodium hydroxide solution is mixed with fatty alkyl dimethyl tertiary amine 5:2.5 in mass ratio and
At.
Polymer is polyglutamic acid, polyallylamine 8:4 in mass ratio is mixed.
Auxiliary agent is calcium carbonate.
A kind of diatom ooze coating, according to parts by weight, including 55 parts of diatomite of following component, 13 parts of water, 1.6 parts of additions
Agent, 17 parts of modified particles, 13 parts of active particles, 11 parts of polymer, 2 parts of auxiliary agents.
Additive is that sodium cellulose glycolate, sodium carboxymethyl starch and odium stearate 5:2:1 in mass ratio are mixed.
Modified particles the preparation method comprises the following steps:
(1) according to parts by weight, take 70 parts of 1.2mol/L ethanol solutions, 60 parts of water, 40 parts of mixed metal salts, 40 parts of mixing single
Body, 29 parts of ethyl orthosilicates, 2 parts of cetyl trimethylammonium bromides, 3 parts of initiators, 1 part of polyethylene glycol；
(2) water, mixed metal salt, polyethylene glycol are put into container and are stirred evenly first, adjusted pH to 7.5 using ammonium hydroxide, stir
It mixes uniformly, stands 6h, filter, it is dry, in 700 DEG C of calcining 2h, calcined material is collected, calcined material, water and mix monomer are mixed equal
It is even, it is put into reaction kettle, nitrogen protection, in 45 DEG C of preheating 30min, adds ethyl orthosilicate, cetyl trimethyl bromination
Ammonium and initiator are warming up to 80 DEG C, react 9h；
(3) after the completion of reaction, cooling, it discharges, freeze-drying object is collected in freeze-drying, by freeze-drying object and tetrahydrofuran
30min is mixed with 900r/min in 1:8 in mass ratio, stands 1h, and filtering collects washings using ethanol washing, dry,
Collect dried object；
(4) dried object, 0.1mol/L sulfuric acid solution and copper sulphate 7:16:3 in mass ratio are heated with stirring to 90 DEG C, heat 3h,
4 DEG C are being placed in, is being stood overnight, is being filtered, is collecting filter residue to get modified particles.
Mix monomer is styrene, polyvinylpyrrolidone 4:2 in mass ratio is mixed.
Mixed metal salt is that manganese sulfate, iron chloride and magnesium nitrate 3:4:2 in mass ratio are mixed.
Initiator is azo-bis-isobutyl cyanide, potassium peroxydisulfate 7:1 in mass ratio is mixed.
Active particle is that volcanic ash, zeolite 7:4 in mass ratio mill, and collects mill admixture, will mill mixing
Object, modifying agent and 1.0mol/L ethanol solution 9:2:18 in mass ratio are uniformly mixed, and are heated to 80 DEG C, heat 2h, are filtered, and are collected
Filtrate, it is dry, 10min is crushed to get active particle with 800r/min.
Modifying agent is that 0.6mol/L sodium hydroxide solution is mixed with fatty alkyl dimethyl tertiary amine 5:2 in mass ratio.
Polymer is polyglutamic acid, polyallylamine 8:3~5 in mass ratio mix.
Auxiliary agent is calcium carbonate.
A kind of diatom ooze coating, according to parts by weight, including 50 parts of diatomite of following component, 10 parts of water, 1.3 parts of additions
Agent, 16 parts of modified particles, 12 parts of active particles, 7 parts of polymer, 1 part of auxiliary agent.
Comparative example 1 is substantially the same manner as Example 2 only the difference is that lacking modified particles.
Comparative example 2 is substantially the same manner as Example 2 only the difference is that lacking active particle.
Comparative example 3 is substantially the same manner as Example 2 only the difference is that lacking polymer.
The commercially available diatom ooze coating of comparative example 4.
Raw material in Examples 1 to 3 and comparative example 1~3 is mixed to get diatom ooze coating, then by diatom mash
Material and the diatom ooze coating of comparative example 4 carry out index of correlation detection, detect foundation and judgment basis is that GB/T9756-2009 " is closed
At resin emulsion interior wall coating " and JC/T2177-2013 " diatom ooze decorative wall material ", detecting environment is 20 ± 2 DEG C of room temperature, phase
To humidity 50 ± 5%.Testing result is shown in Table 1.
Table 1:
| Test item | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Comparative example 4 |
| Abrasion resistance (secondary) | 612 | 642 | 626 | 563 | 583 | 463 | 500 |
| Dry cracking resistance 6h | Flawless | Flawless | Flawless | Micro-crack at 3 | Micro-crack at 1 | Flawless | Slight crackle at 1 ~ 2 |
| Surface drying time (h) | 0.93 | 0.95 | 0.92 | 1.3 | 1.4 | 1.2 | 1.9 |
| Adhesion strength (MPa) | 0.74 | 0.78 | 0.75 | 0.62 | 0.65 | 0.51 | 0.51 |
| Hygroscopic capacity for 24 hours, Wa(g/m2) | 76 | 89 | 83 | 52 | 62 | 72 | 41 |
In summary, diatom ooze coating of the invention is excellent in compared to commercial product properties, is worth promoting.
Claims (10)
1. a kind of diatom ooze coating, according to parts by weight, including 50~60 parts of diatomite of following component, 10~15 parts of water, 1.3~
1.9 parts of additives, which is characterized in that further include 16~18 parts of modified particles, 12~15 parts of active particles, 7~13 parts of polymer,
1~3 part of auxiliary agent.
2. diatom ooze coating according to claim 1, which is characterized in that the additive is sodium cellulose glycolate, carboxylic first
Base sodium starch and odium stearate 5:2~5:1 in mass ratio are mixed.
3. diatom ooze coating according to claim 1, which is characterized in that the modified particles the preparation method comprises the following steps:
(1) according to parts by weight, 70~75 parts of ethanol solutions, 60~70 parts of water, 40~50 parts of mixed metal salts, 40~45 parts are taken
Mix monomer, 29~38 parts of ethyl orthosilicates, 2~8 parts of cetyl trimethylammonium bromides, 3~7 parts of initiators, 1~1.5 part
Polyethylene glycol；
(2) water, mixed metal salt, polyethylene glycol are put into container and are stirred evenly first, using ammonium hydroxide adjust pH to 7.5~
8.0, it stirs evenly, stands, filter, dry, calcining collects calcined material, calcined material, water and mix monomer are uniformly mixed, put
Enter in reaction kettle, nitrogen protection, preheat, add ethyl orthosilicate, cetyl trimethylammonium bromide and initiator, heating is anti-
It answers；
(3) after the completion of reaction, cooling, it discharges, freeze-drying object is collected in freeze-drying, by freeze-drying object and tetrahydrofuran
1:8 in mass ratio~14 is mixed, and stands, filtering, using ethanol washing, collects washings, dry, collects dried object；
(4) by dried object, 0.1mol/L sulfuric acid solution and the copper sulphate agitating and heating of 7~9:16:3 in mass ratio, 4~6 are being placed in
DEG C, it stands, filtering, collects filter residue to get modified particles.
4. diatom ooze coating according to claim 3, which is characterized in that the mix monomer is styrene, polyvinyl pyrrole
Alkanone 4:2~4 in mass ratio mix.
5. diatom ooze coating according to claim 1, which is characterized in that the mixed metal salt be manganese sulfate, iron chloride and
Magnesium nitrate 3:4~6:2 in mass ratio is mixed.
6. diatom ooze coating according to claim 1, which is characterized in that the initiator is azo-bis-isobutyl cyanide, persulfuric acid
Potassium 7:1~3 in mass ratio mix.
7. diatom ooze coating according to claim 1, which is characterized in that the active particle is that volcanic ash, zeolite are pressed matter
Amount mill than 7~9:4, collection mill admixture, by mill admixture, modifying agent and ethanol solution 9:2 in mass ratio~
4:18 is uniformly mixed, and is heated, and filtering is collected filtrate, be dry, pulverize to get active particle.
8. diatom ooze coating according to claim 7, which is characterized in that the modifying agent is sodium hydroxide solution and fatty alkane
Base dimethyl tertiary amine 5:2~3 in mass ratio mix.
9. diatom ooze coating according to claim 1, which is characterized in that the polymer is polyglutamic acid, polyallylamine
8:3~5 mix in mass ratio.
10. diatom ooze coating according to claim 1, which is characterized in that the auxiliary agent is calcium carbonate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910235961.3A CN110078414A (en) | 2019-03-27 | 2019-03-27 | A kind of diatom ooze coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910235961.3A CN110078414A (en) | 2019-03-27 | 2019-03-27 | A kind of diatom ooze coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN110078414A true CN110078414A (en) | 2019-08-02 |
Family
ID=67413589
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910235961.3A Withdrawn CN110078414A (en) | 2019-03-27 | 2019-03-27 | A kind of diatom ooze coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110078414A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112625476A (en) * | 2020-12-29 | 2021-04-09 | 成都芙涵麟涂料科技有限公司 | Preparation method of diatom ooze coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980018145A (en) * | 1997-06-17 | 1998-06-05 | 최종태 | Construction Interior Material Using Paper Sludge and Manufacturing Method Thereof |
| CN102850835A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Putty powder capable of adsorbing foreign gas |
| CN104046229A (en) * | 2014-05-14 | 2014-09-17 | 阜阳市明强家具有限公司 | Self-cleaning heat dissipation coating |
| CN104353420A (en) * | 2014-09-29 | 2015-02-18 | 安徽博硕科技有限公司 | Composite powder with efficient adsorption effect |
-
2019
- 2019-03-27 CN CN201910235961.3A patent/CN110078414A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR19980018145A (en) * | 1997-06-17 | 1998-06-05 | 최종태 | Construction Interior Material Using Paper Sludge and Manufacturing Method Thereof |
| CN102850835A (en) * | 2012-08-30 | 2013-01-02 | 苏州市德莱尔建材科技有限公司 | Putty powder capable of adsorbing foreign gas |
| CN104046229A (en) * | 2014-05-14 | 2014-09-17 | 阜阳市明强家具有限公司 | Self-cleaning heat dissipation coating |
| CN104353420A (en) * | 2014-09-29 | 2015-02-18 | 安徽博硕科技有限公司 | Composite powder with efficient adsorption effect |
Non-Patent Citations (1)
| Title |
|---|
| 董丽红: "《两亲分子在纳米技术领域中的应用》", 31 October 2013, 吉林大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112625476A (en) * | 2020-12-29 | 2021-04-09 | 成都芙涵麟涂料科技有限公司 | Preparation method of diatom ooze coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105602383B (en) | A kind of Environment-friendlyexterior exterior wall paint containing oyster shell whiting | |
| CN106082759A (en) | A kind of high-thin arch dam polycarboxylate composite water reducing agent and preparation method thereof | |
| CN103102869A (en) | Manufacturing method of phase change material | |
| CN104109444B (en) | Biomass interior wall coating and preparation method thereof | |
| WO2014090105A1 (en) | Water-based expandable fireproof coating for steel structure and preparation method therefor | |
| CN103740188A (en) | Heat insulating and preserving coating for exterior wall of building | |
| CN110078414A (en) | A kind of diatom ooze coating | |
| CN109503076A (en) | A kind of preparation method of ornament materials and its dalle with releasing negative oxygen ion environmental protection health-preserving function | |
| CN102277030A (en) | Efficient environment-friendly flame retardant for flame retardance of coating and preparation method thereof | |
| CN107434943B (en) | A kind of preparation method of fire resistant coating | |
| CN109336512A (en) | A kind of nano metal organic frame wall material and preparation method thereof | |
| CN103254696B (en) | A kind of have inhale ripple, the environmental friendly indoor dry powder paint and preparation method thereof of anti-flaming function and constructional method | |
| CN106045444B (en) | A kind of flexible ecological environmental protection diatom ooze coating and preparation method thereof | |
| CN107777917A (en) | A kind of preparation method of the special diatom ooze of wall | |
| CN105524232A (en) | Preparation method of humidity-adjusting adsorption composite porous chelating resin | |
| CN108774025A (en) | A kind of silica-filled modified concrete material and preparation method thereof | |
| CN102827366A (en) | Polymeric adsorbent for removing formaldehyde and preparation method thereof | |
| CN107382250A (en) | A kind of plasterboard for inducing anion and preparation method thereof | |
| CN104530890A (en) | Water-based acrylate fireproof coating and preparation method thereof | |
| CN110105827A (en) | A kind of ornament materials and preparation method thereof of inorganic fire releasing negative oxygen ion | |
| CN105086518A (en) | Black iron oxide pigment containing bamboo charcoal powder and preparation method thereof | |
| CN108484106A (en) | A kind of adjustable wet diatomite ecotecture decorative brick and preparation method | |
| CN109206960A (en) | A kind of conch meal interior wall air cleaning sealing wax | |
| CN104672965A (en) | Waterproof paint with high adhesive force and crack resistance and preparation method of waterproof paint | |
| CN108218297A (en) | A kind of preparation method of diatom ooze coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190802 |
|
| WW01 | Invention patent application withdrawn after publication |