KR100321820B1 - Processing method of concrete sludge - Google Patents

Processing method of concrete sludge Download PDF

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Publication number
KR100321820B1
KR100321820B1 KR1019980035048A KR19980035048A KR100321820B1 KR 100321820 B1 KR100321820 B1 KR 100321820B1 KR 1019980035048 A KR1019980035048 A KR 1019980035048A KR 19980035048 A KR19980035048 A KR 19980035048A KR 100321820 B1 KR100321820 B1 KR 100321820B1
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concrete
sludge
concrete sludge
molded
dried
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KR1019980035048A
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Korean (ko)
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KR19980082135A (en
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권 허
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(주)아텍스
허권
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/26Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
    • B28B1/265Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor pressure being applied on the slip in the filled mould or on the moulded article in the mould, e.g. pneumatically, by compressing slip in a closed mould
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/16Waste materials; Refuse from building or ceramic industry
    • C04B18/167Recycled materials, i.e. waste materials reused in the production of the same materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02Macromolecular compounds
    • C04B26/04Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/0072Heat treatment
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

PURPOSE: A method for processing the concrete sludge is provided, to recycle the concrete sludge wasted from the industrial field and to prepare an exterior material for construction from the concrete sludge. CONSTITUTION: The method comprises the steps of preparing a neutral or strong alkali concrete sludge paste; drying the concrete sludge paste; pulverizing the concrete sludge, mixing the concrete sludge with a concrete adhesive, a mixing material and a copolymer, injecting the mixture into a mold, and press molding the mixture at a pressure of 100-1,000 kg/cm2 for 1-10 hours; drying the molded concrete sludge; and heating the dried one in a furnace at a temperature of 1,000-1,200 deg.C. Preferably the concrete adhesive is poly(vinyl acetate), and the mixing material is the pulverized pulp or rice-straw, polyethylene or polystyrene.

Description

콘크리트 슬러지의 가공방법Processing method of concrete sludge

본 발명은 콘크리트 슬러지의 가공방법에 관한 것으로, 더욱 상세하게는 산업현장에서 폐기되어 수질이나 토양을 오염시키는 콘크리트 슬러지를 재활용이 가능하도록 가공처리함으로써, 환경의 오염을 방지하고 콘크리트 폐기물을 자원화할 수 있는 콘크리트 슬러지의 가공방법에 관한 것이다.The present invention relates to a method for processing concrete sludge, and more particularly, by processing the concrete sludge that can be disposed of in an industrial site to contaminate water quality or soil to be recycled, thereby preventing environmental pollution and recycling concrete waste. The present invention relates to a method of processing concrete sludge.

콘크리트 슬러지는 레미콘 공장이나 흄관 공장 등, 콘크리트 2차 제품을 생산하거나 콘크리트를 사용하여 구조물 등을 제조하는 업체에서 폐기물로서 발생되는 처리 곤란한 물질이다. 왜냐하면, 콘크리트 슬러지는 일반적으로 pH가 11이상이 되며, 일반 시멘트와 혼합하여도 그 강도가 매우 낮을 뿐만 아니라 성형성도 없어서 사용하기에 곤란하기 때문이다. 그러므로, 슬러지가 생산되는 업체에서는 슬러지의 처리를 위하여 막대한 비용을 들여서 매립하거나 산업 폐기물로 처리하고 있다. 따라서, 슬러지 처리에 있어서 경제적으로 큰 어려움을 겪고 있으며, 최근에는 환경 보호를 위한 법적인 제한으로 인하여 그 처리에 있어서 어려움이 가중되고 있다.Concrete sludge is a material that is difficult to process as waste in companies that produce secondary concrete products, such as ready-mix concrete plants or fume pipe plants, or manufacture structures using concrete. This is because concrete sludge generally has a pH of 11 or more, and even when mixed with general cement, its strength is very low and it is difficult to use because it is not formable. Therefore, companies that produce sludge have a huge cost for disposal of the sludge, which is landfilled or disposed of as industrial waste. Therefore, there is a great economic difficulty in the sludge treatment, and in recent years, due to legal restrictions for environmental protection, the difficulty in the treatment is increased.

국내의 많은 연구 기관에서는 콘크리트 슬러지의 처리방법을 다각도로 연구하고 있으나, 현실적으로 적용하기 어려운 방법만이 제시되어 왔다. 또한, 해외의 선진국에서도 일부학자들이 콘크리트 슬러지의 재활용 방법에 대하여 많은 시간과 정렬을 바치고 있으나, 해외에서 수행되는 연구는 국책 과제로 수행되고 연구 결과가 해당국의 산업 기밀로 보호되고 있으므로, 그 결과의 국내 활용은 불가능한 실정이다.Many research institutes in Korea are studying the treatment method of concrete sludge from various angles, but only methods that are difficult to apply in reality have been proposed. In addition, even in advanced countries, some scholars devote a lot of time and alignment to the recycling method of concrete sludge, but the research conducted abroad is carried out as a national project and the results of the research are protected by the industrial secrets of the country. Domestic use is not possible.

본 발명은 상기와 같은 종래의 문제점을 해결하기 위해 안출된 것으로, 본 발명의 목적은, 산업 현장에서 쏟아져 나오는 콘크리트 슬러지를 재활용이 가능하도록 가공처리함으로써, 높은 pH를 갖는 콘크리트 슬러지를 매립할 때 발생하는 지하수의 오염 및 토양의 오염을 미연에 방지할 수 있고, 콘크리트 폐기물의 자원화를 가능하게 하는 콘크리트 슬러지의 가공방법을 제공하려는 것이다.The present invention has been made to solve the conventional problems as described above, the object of the present invention, by processing the concrete sludge pouring from the industrial site to be recycled, it occurs when the concrete sludge having a high pH landfill To prevent the contamination of groundwater and soil pollution in advance, and to provide a concrete sludge processing method that enables the recycling of concrete waste.

상기와 같은 목적을 달성하기 위해서, 본 발명은,In order to achieve the above object, the present invention,

출발물질로서 반죽상태의 콘크리트 슬러지를 준비하는 단계(S1);Preparing a concrete sludge of dough state as a starting material (S1);

상기 콘크리트 슬러지를 건조시키는 단계(S2);Drying the concrete sludge (S2);

건조된 콘크리트 슬러지를 분쇄 및 성형하는 단계(S3); 그리고Grinding and molding the dried concrete sludge (S3); And

성형된 콘크리트 슬러지를 건조시키는 단계(S4)를 포함하는 콘크리트 슬러지의 가공방법을 제공한다.It provides a method of processing the concrete sludge comprising the step of drying the molded concrete sludge (S4).

상기 콘크리트 슬러지의 가공방법은, 상기 단계(S4) 후에, 건조된 성형 콘크리트 슬러지를 로내에서 1,000∼1,200℃의 온도로 열처리하는 단계(S5)를 더 포함한다.The method of processing the concrete sludge, after the step (S4), further comprises a step (S5) of heat-treating the dried molded concrete sludge at a temperature of 1,000 ~ 1,200 ℃ in the furnace.

또한, 상기와 같은 목적을 달성하기 위해서, 본 발명은,In addition, in order to achieve the above object, the present invention,

출발물질로서 반죽상태의 콘크리트 슬러지를 준비하는 단계(SS1);Preparing a concrete sludge of dough state as a starting material (SS1);

상기 콘크리트 슬러지를 건조시키는 단계(SS2);Drying the concrete sludge (SS2);

건조된 콘크리트 슬러지를 분쇄 및 성형하는 단계(SS3);Grinding and molding the dried concrete sludge (SS3);

성형된 콘크리트 슬러지를 건조시키는 단계(SS4); 그리고Drying the molded concrete sludge (SS4); And

건조된 성형 콘크리트 슬러지의 표면을 처리하는 단계(SS5)를 포함하는 콘크리트 슬러지의 가공방법을 제공한다.It provides a method of processing the concrete sludge comprising the step (SS5) of treating the surface of the dried molded concrete sludge.

이상에서 언급한 바와 같이, 본 발명에서는, 국내 콘크리트 산업 현장에서 쏟아져 나오는 콘크리트 슬러지를 재활용이 가능하도록 가공처리함으로써, 지하수의 수질 환경 뿐만 아니라, 토양의 오염을 방지할수 있게한다.As mentioned above, in the present invention, by processing the concrete sludge pouring from the domestic concrete industrial site to be recycled, it is possible to prevent contamination of the soil as well as the water quality environment of groundwater.

이하, 본 발명의 바람직한 실시 예에 따른 콘크리트 슬러지의 가공방법을 보다 상세하게 설명한다.Hereinafter, a method of processing concrete sludge according to a preferred embodiment of the present invention will be described in more detail.

일반적으로, 콘크리트 슬러지는 발생 당시에 많은 양의 물을 함유하며, 발생된 슬러지는 물과 함께 집수조에 집수되어 침전과정을 거친다. 침전된 슬러지는 페로다 등의 장비를 이용하여 대형 운송장치에 실려서 일반 쓰레기로 매립되거나 산업 폐기물로 처리된다.In general, concrete sludge contains a large amount of water at the time of occurrence, and the sludge generated is collected in a sump together with water and subjected to precipitation. Precipitated sludge is loaded into large-scale transportation equipment using equipment such as ferodas and landfilled as general waste or industrial waste.

이때, 침전 과정에서 침전의 속도와 용액의 중화를 위하여 황산을 사용하는 경우도 있다. 황산을 첨가하면 용액의 액성은 중성화된다. 따라서, 얻어진 폐슬러지 침전물의 액성은 중성이거나 강한 알칼리성이며, 다양한 입도의 분말 형태 슬러지를 물에 반죽시켜 놓은 상태로 얻어진다.In this case, sulfuric acid may be used for the rate of precipitation and neutralization of the solution during the precipitation process. The addition of sulfuric acid neutralizes the liquidity of the solution. Therefore, the liquidity of the waste sludge obtained is neutral or strong alkaline, and is obtained in a state in which powdered sludge of various particle sizes is kneaded in water.

본 발명은 이를 건조시켜서 사용하는 것으로, 먼저 이들 반죽상태 물질을 원심분리기 또는 건조로를 이용하여 완전히 건조시킨다. 건조된 슬러지는 덩어리 형태를 유지하지만 강도는 매우 낮다. 건조된 슬러지는 분쇄기를 이용하여 곱게 분쇄한다. 슬러지를 분쇄하는 동안에 폴리비닐아세테이트(에틸렌 비닐 아세테이트)와 같은 콘크리트 접착제, 종이 펄프나 볏짚을 잘게 분쇄시킨 혼화재료, 또는 폴리에틸렌이나 폴리스티렌과 같은 고분자를 혼합하여 높은 압력에서 성형한다. 압축 성형 강도가 클수록 고강도의 제품을 얻을 수 있고 성형성도 우수하다.The present invention is to use it by drying, first, these dough-like material is completely dried using a centrifuge or drying furnace. Dried sludge retains lump form but has a very low strength. The dried sludge is finely ground using a grinder. During sludge milling, a concrete adhesive such as polyvinylacetate (ethylene vinyl acetate), a blend of finely pulverized paper pulp or rice straw, or a polymer such as polyethylene or polystyrene is mixed and molded at high pressure. The greater the compression molding strength, the higher strength the product can be obtained and the better the moldability.

이때, 종이 펄프나 볏짚과 같은 다공성 물질을 혼합하여 압축 성형하면, 단열성이 크고 압축강도 뿐만아니라 인장 강도가 우수한 제품을 얻을 수 있다. 또한, 슬러지와 함께 폴리에틸렌이나 폴리스티렌과 같은 고분자를 혼합하여 압축 성형하면, 물에 강한 물질이 얻어진다. 이와는 달리, 순수한 슬러지만을 이용하여 압축 성형하면, 열전도성이 우수한 제품이 얻어진다. 그러므로, 용도에 따라서 이들 제품을 다양하게 성형하여 사용할 수 있다.In this case, when a compression molded by mixing a porous material such as paper pulp or rice straw, it is possible to obtain a product having excellent thermal insulation properties and excellent tensile strength as well as tensile strength. In addition, by mixing a sludge with a polymer such as polyethylene or polystyrene and compression molding, a substance resistant to water is obtained. On the other hand, by compression molding using only pure sludge, a product having excellent thermal conductivity is obtained. Therefore, these products can be molded and used in various ways depending on the application.

이렇게 성형되어 얻어진 제품을 건조시키면 건축용 자재로 사용할 수 있다.When the product obtained by molding is dried, it can be used as a building material.

이상에서 얻어진 제품의 표면에 혐수성 물질 등을 분무하거나 표면 처리함으로써, 건축물의 외장재로도 사용이 가능하다.By spraying or surface-treating a hydrophobic substance etc. on the surface of the product obtained above, it can be used also as a exterior material of a building.

이상에서 살펴본 바와 같이 본 발명에 따라서 처리된 제품은 화기에 강한 콘크리트 슬러지를 활용하여 성형하므로, 내화성이 대단히 우수하다.As described above, the product treated according to the present invention is molded using a strong concrete sludge for fire, so it is very excellent in fire resistance.

하기에서는 본 발명에서 사용되는 콘크리트 슬러지의 압축 성형 방법을 간략하게 설명한다.The following briefly describes the compression molding method of concrete sludge used in the present invention.

먼저, 콘크리트 슬러지를 만들고자하는 형태의 거푸집(몰드)을 만들어 여기에 전술한 바와 같은 슬러지와 다른 혼화재료를 잘 혼합하여 채우고, 약 100 ∼ 1,000kg/cm2의 높은 압력으로 1∼10분 정도 가압함으로써 거푸집내에 압력이 골고루 전달될 수 있게 한다. 필요에 따라서 고급 제품을 만들기 위하여 여기서 성형된 제품을 유압 압축기를 이용하여 기름과 같은 유체내에서 재성형하는 경우도 있다.First, form the mold (mold) to form the concrete sludge, and then mix and fill the sludge and other miscible materials as described above, and pressurized for about 1 to 10 minutes at a high pressure of about 100 ~ 1,000kg / cm 2 This allows pressure to be evenly distributed within the formwork. If necessary, the molded product may be remolded in a fluid such as oil using a hydraulic compressor to make a high quality product.

압축성형시 콘크리트 접착제로 사용되는 폴리비닐아세테이트(EVA류)와 같은 물질은 슬러지 질량의 약 0.1∼20% 범위를 사용하는 것이 바람직하며, 종이 펄프나 볏짚과 같은 물질은 슬러지 질량에 어떤 비율로도 혼합이 가능하다. 이와같은 물질의 혼합비율은 성형되어 얻어지는 제품의 용도에 따라 변화될 수 있으며, 압축성형 강도 등이 정하여진다. 또한, 혼합되는 혼화재료의 입도 등도 용도에 따라 결정될 수 있다. 일반적으로, 압축 성형성은 혼화재료의 입도가 작을수록 좋으며, 섬유가 가늘면서 길고 질길수록 성형된 제품의 인장 강도가 크게 얻어진다.Materials such as polyvinylacetate (EVA), which are used as concrete adhesives for compression molding, should be used in the range of about 0.1 to 20% of the mass of sludge. Mixing is possible. The mixing ratio of such materials may vary depending on the use of the product obtained by molding, and the compression molding strength is determined. In addition, the particle size and the like of the mixed materials to be mixed may be determined according to the use. In general, the compression moldability is better the smaller the particle size of the mixed material, the longer the fibers are thin and long, the greater the tensile strength of the molded product.

한편, 압축 성형되어 얻어진 제품은 표면이 높은 압력으로 성형되었으나, 건조된 상태에서 표면의 분말이 일부 묻어나올 수 있다. 따라서, 제품의 상품성을 증진시키고 취급이 편리하도록 표면을 처리하는 방법이 강구되어야한다.On the other hand, the product obtained by compression molding is molded at a high pressure, the surface of the powder may be partially buried in the dried state. Therefore, a method of treating the surface should be devised to enhance the commerciality of the product and to facilitate handling.

예를 들면, 고온에서 열처리함으로써 고체화학 반응을 통하여 처리할 수 있다. 이때, 로내의 처리 온도는 1,000℃∼1,200℃ 범위이며, 1,000℃부근의 저온 영역에서는 장시간의 열처리 시간이 요구된다. 1,200℃ 부근의 고온 영역에서는 비교적 짧은 시간동안에 표면 처리가 가능하고, 시간이나 온도 구배에 따라서 제품의 내부까지 열처리 조절이 가능하다.For example, it can be processed through a solid chemical reaction by heat treatment at a high temperature. At this time, the treatment temperature in the furnace is in the range of 1,000 ° C to 1,200 ° C, and a long heat treatment time is required in the low temperature region near 1,000 ° C. In the high temperature region around 1,200 ℃, surface treatment can be done for a relatively short time, and heat treatment can be controlled to the inside of the product according to time or temperature gradient.

이와는 달리, 표면에 혐수성 제품의 물질을 분무, 건조하거나 방수제 등을 분무, 건조시켜서 물과의 접촉시 직접적으로 물이 침투되지 않도록 처리하는 것도 가능하다. 또다른 방법으로는, 거푸집 내면에 접착제 또는 혐수성의 제품을 성형 압축전에 처리하여 성형 압축과 동시에 표면 처리가 이루어지도록 하는 것이다.Alternatively, it is also possible to spray or dry the material of the hydrophobic product on the surface, or to spray and dry the water repellent, etc., so that the water does not directly penetrate when contacted with water. Alternatively, an adhesive or hydrophobic product is treated on the form inner surface prior to molding compression so that surface treatment is performed simultaneously with molding compression.

이상과 같은 방법으로 압축 성형된 제품을 표면 처리하면, 건축 외장재로도 사용이 가능하다.If the product is compression-molded in the above manner, it can be used as a building exterior material.

실시 예Example

건조된 콘크리트 슬러지 500g을 분쇄하면서 폴리비닐아세테이트(에틸렌 비닐 아세테이트 공중합체) 25g을 첨가하여 슬러지와 골고루 혼합한다. 혼합된 시료 중 일부(150g)를 분취하여 실온에서 직경 70mm의 원형 몰드로 5분간 600kg/cm2의 압력으로 가압 성형하며, 이중의 일부(150g)를 종이 펄프 30g과 혼합하여 앞에서와 같이 성형하며, 또한 일부(150g)를 볏짚 30g과 혼합하여 성형한다. 이상에서 성형된 제품을 건조로를 이용하여 80℃에서 3시간 건조시킨다. 여기까지의 과정을 거쳐서 만든 제품이 표면 처리를 하지 않은 제품이며, 건축 자재나 단열재, 또는 열 전도체 등으로 사용이 가능하다.500 g of dried concrete sludge is pulverized, and 25 g of polyvinylacetate (ethylene vinyl acetate copolymer) is added and mixed with the sludge evenly. A portion of the mixed sample (150 g) was aliquoted and press-molded at a pressure of 600 kg / cm 2 for 5 minutes in a circular mold having a diameter of 70 mm at room temperature. A portion of the mixture (150 g) was mixed with 30 g of paper pulp and formed as described above. In addition, a part (150g) is mixed with 30g of rice straw and molded. The molded product is dried at 80 ° C. for 3 hours using a drying furnace. Products made through the process up to this point are products without surface treatment, and can be used as building materials, insulation materials, or thermal conductors.

여기서, 폴리비닐 아세테이트 (에틸렌 비닐 아세테이트 공중합체)를 과량(5 0∼100g)첨가하면 외장재로서도 대단히 양호하게 사용될 수 있다. 표면에서 분말이묻어나는 제품을 방수액으로 표면 처리한 후 다시 건조하였고, 또한 혐수성 페인트 (락카, 니스 등)로 표면 처리하여 건축물의 외장재를 만들었다. 또한, 초기에 혼화재료가 첨가되지 않은 제품을 1,100℃의 온도에서 2시간 열처리하여 단단한 벽돌을 만들었다.Here, when an excess (50 to 100 g) of polyvinyl acetate (ethylene vinyl acetate copolymer) is added, it can be used very well as a packaging material. The product, which had powder on the surface, was surface-treated with a waterproofing solution and dried again, and the surface of the building was made by surface-treating with a hydrophobic paint (lacka, varnish, etc.). In addition, initially, the product without the admixture was heat-treated for 2 hours at a temperature of 1,100 ℃ to make a solid brick.

이상에서 언급한 바와 같이, 본 발명에 따르면, 국내 콘크리트 산업 현장에서 쏟아져 나오는 콘크리트 슬러지를 재활용이 가능하도록 가공함으로써, 지하수의 수질 환경을 보호할 수 있을 뿐만 아니라, 토양의 오염을 방지할 수 있게된다. 또한, 콘크리트 폐기물을 양호한 방법으로 관리 및 처분할 수 있게 함으로써, 콘크리트 폐기물의 음성적인 폐기를 방지하는 효과를 얻을 수 있고, 환경 처리비용을 절감시킬 수 있다. 게다가, 본 발명에 따른 콘크리트 슬러지 처리 방법을 다른 폐기물 처리에 까지 확장시킬 수 있고, 본 발명에 의해서 제조된 제품은 내화성이 우수하므로 건축용 자재로 활용할 수 있다.As mentioned above, according to the present invention, by processing the concrete sludge pouring from the domestic concrete industry to be recycled, not only can protect the water quality environment of the groundwater, it is also possible to prevent soil contamination. . In addition, by enabling the concrete waste to be managed and disposed in a good manner, it is possible to obtain the effect of preventing the negative waste of the concrete waste, and to reduce the environmental treatment cost. In addition, the concrete sludge treatment method according to the present invention can be extended to other waste treatment, and the product produced by the present invention can be utilized as a building material because of excellent fire resistance.

상기에서는 본 발명의 바람직한 실시예를 참조하여 설명하였지만, 해당기술 분야의 숙련된 당업자는 하기의 특허청구범위에 기재된 본 발명의 사상 및 영역으로부터 벗어나지 않는 범위 내에서 본 발명을 다양하게 수정 및 변경시킬 수 있음을 이해할 수 있을 것이다.Although the above has been described with reference to the preferred embodiments of the present invention, those skilled in the art will be able to variously modify and change the present invention without departing from the spirit and scope of the invention as set forth in the claims below. It will be appreciated.

Claims (3)

출발물질로서 반죽상태의 중성 또는 강알칼리성 콘크리트 슬러지를 준비하는 단계(S1);Preparing a neutral or strongly alkaline concrete sludge as a starting material (S1); 상기 콘크리트 슬러지를 건조시키는 단계(S2);Drying the concrete sludge (S2); 상기 건조된 콘크리트 슬러지를 분쇄하면서 콘크리트 접착제, 혼화재료 또는 공중합체를 혼합한 후, 혼합물을 소정의 몰드 내에 채우고 100∼1,000kg/㎤의 압력 으로 1∼10분 동안 가압하여 성형하는 단계(S3);After mixing the concrete adhesive, admixture or copolymer while grinding the dried concrete sludge, the mixture is filled into a predetermined mold and molded by pressing for 1 to 10 minutes at a pressure of 100 to 1,000 kg / cm 3 (S3). ; 성형된 콘크리트 슬러지를 건조시키는 단계(S4); 그리고Drying the molded concrete sludge (S4); And 건조된 성형 콘크리트 슬러지를 로내에서 1,000∼1,200°C의 온도로 열처리하는 단계(S5)를 포함하는 것을 특징으로 하는 콘크리트 슬러지의 가공방법.Process for the treatment of concrete sludge, characterized in that it comprises the step (S5) of the dried molded concrete sludge in a furnace at a temperature of 1,000 ~ 1,200 ° C. 제 1 항에 있어서, 상기 콘크리트 접착제는 폴리비닐아세테이트로 이루어지고, 상기 혼화재료는 종이 펄프나 볏짚을 잘게 분쇄시킨 것이나 폴리에틸렌 또는 폴리스티렌으로 이루어진 것을 특징으로 하는 콘크리트 슬러지의 가공방법.The method of claim 1, wherein the concrete adhesive is made of polyvinylacetate, and the admixture is made of finely pulverized paper pulp or rice straw, or made of polyethylene or polystyrene. 제 2 항에 있어서, 상기 폴리비닐아세테이트는 상기 건조된 콘크리트 슬러지 질량의 0.1∼20% 범위로 첨가되는 것을 특징으로 하는 콘크리트 슬러지의 가공방법.3. The method of claim 2, wherein the polyvinyl acetate is added in the range of 0.1-20% of the mass of the dried concrete sludge.
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Publication number Priority date Publication date Assignee Title
KR101967231B1 (en) 2018-07-26 2019-04-09 주식회사 샌드네이처 Manufacturing method for recycled aggregate using sludge and concrete products thereof

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR940002191A (en) * 1992-07-14 1994-02-16 노재성 Manufacturing method of lightweight foamed concrete (ALC) using cement sludge
KR970021514A (en) * 1997-02-13 1997-05-28 최영길 Manufacturing method of concrete pavement and sidewalk block using waste concrete
KR19980033800A (en) * 1996-11-01 1998-08-05 이현구 Lightweight aggregate using fly ash and / or stone sludge and method for producing same

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR940002191A (en) * 1992-07-14 1994-02-16 노재성 Manufacturing method of lightweight foamed concrete (ALC) using cement sludge
KR19980033800A (en) * 1996-11-01 1998-08-05 이현구 Lightweight aggregate using fly ash and / or stone sludge and method for producing same
KR970021514A (en) * 1997-02-13 1997-05-28 최영길 Manufacturing method of concrete pavement and sidewalk block using waste concrete

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101967231B1 (en) 2018-07-26 2019-04-09 주식회사 샌드네이처 Manufacturing method for recycled aggregate using sludge and concrete products thereof

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