KR102918628B1 - 폴리올 블록 공중합체, 이의 조성물 및 방법 - Google Patents
폴리올 블록 공중합체, 이의 조성물 및 방법Info
- Publication number
- KR102918628B1 KR102918628B1 KR1020217039575A KR20217039575A KR102918628B1 KR 102918628 B1 KR102918628 B1 KR 102918628B1 KR 1020217039575 A KR1020217039575 A KR 1020217039575A KR 20217039575 A KR20217039575 A KR 20217039575A KR 102918628 B1 KR102918628 B1 KR 102918628B1
- Authority
- KR
- South Korea
- Prior art keywords
- reaction
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- group
- polyol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/18—Block or graft polymers
- C08G64/183—Block or graft polymers containing polyether sequences
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0006—Controlling or regulating processes
- B01J19/0013—Controlling the temperature of the process
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/44—Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
- C08G64/32—General preparatory processes using carbon dioxide
- C08G64/34—General preparatory processes using carbon dioxide and cyclic ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2606—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups
- C08G65/2609—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen containing hydroxyl groups containing aliphatic hydroxyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00029—Batch processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00031—Semi-batch or fed-batch processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/00033—Continuous processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00002—Chemical plants
- B01J2219/00027—Process aspects
- B01J2219/0004—Processes in series
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00051—Controlling the temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2101/00—Manufacture of cellular products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2650/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G2650/28—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule characterised by the polymer type
- C08G2650/36—Pre-polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/02—Aliphatic polycarbonates
- C08G64/0208—Aliphatic polycarbonates saturated
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Toxicology (AREA)
- Polyesters Or Polycarbonates (AREA)
- Polyethers (AREA)
- Polyurethanes Or Polyureas (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB1906214.0A GB201906214D0 (en) | 2019-05-02 | 2019-05-02 | A polyol block copolymer, compositions and processes therefor |
| GB1906214.0 | 2019-05-02 | ||
| PCT/GB2020/051083 WO2020222019A1 (en) | 2019-05-02 | 2020-05-01 | A polyol block copolymer, compositions and processes therefor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20220004182A KR20220004182A (ko) | 2022-01-11 |
| KR102918628B1 true KR102918628B1 (ko) | 2026-01-26 |
Family
ID=67384851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020217039575A Active KR102918628B1 (ko) | 2019-05-02 | 2020-05-01 | 폴리올 블록 공중합체, 이의 조성물 및 방법 |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US12384880B2 (https=) |
| EP (1) | EP3983472A1 (https=) |
| JP (1) | JP7588091B2 (https=) |
| KR (1) | KR102918628B1 (https=) |
| CN (2) | CN114174377A (https=) |
| GB (1) | GB201906214D0 (https=) |
| WO (1) | WO2020222019A1 (https=) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7845040B2 (ja) * | 2021-05-27 | 2026-04-14 | Agc株式会社 | ポリオキシアルキレンポリカーボネートジオール及びその製造方法、ポリウレタン樹脂前駆体、ポリウレタン樹脂、ポリウレタン樹脂組成物、並びに物品 |
| GB202115335D0 (en) * | 2021-10-25 | 2021-12-08 | Econic Tech Ltd | Surface-active agent |
| GB2626546A (en) | 2023-01-25 | 2024-07-31 | Econic Tech Ltd | Surface-active agent |
| GB2626989A (en) | 2023-02-10 | 2024-08-14 | Econic Tech Ltd | Surface-active agent |
| CN119219905B (zh) * | 2024-12-04 | 2025-03-14 | 安徽普碳新材料科技有限公司 | 一种双酚a型高分子量聚碳酸酯聚醚多元醇及其生产工艺 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20130035407A1 (en) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Use of polysiloxanes comprising branched polyether moieties for the production of polyurethane foams |
| US20160362518A1 (en) | 2014-02-26 | 2016-12-15 | Covestro Deutschland Ag | Method for producing polyether ester carbonate polyols |
| WO2018158389A1 (en) | 2017-03-01 | 2018-09-07 | Econic Technologies | Method for preparing polycarbonate ether polyols |
| WO2018158366A1 (en) | 2017-03-01 | 2018-09-07 | Econic Technologies Limited | Method for preparing polyether carbonates |
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| US3427256A (en) | 1963-02-14 | 1969-02-11 | Gen Tire & Rubber Co | Double metal cyanide complex compounds |
| US4500704A (en) | 1983-08-15 | 1985-02-19 | The Dow Chemical Company | Carbon dioxide oxirane copolymers prepared using double metal cyanide complexes |
| GB8528071D0 (en) | 1985-11-14 | 1985-12-18 | Shell Int Research | Polycarbonates |
| US4866143A (en) * | 1988-04-21 | 1989-09-12 | Basf Corporation | Novel surfactants based on poly(alkylene carbonate)s |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5482908A (en) | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5627122A (en) | 1995-07-24 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5693584A (en) | 1996-08-09 | 1997-12-02 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5783513A (en) | 1997-03-13 | 1998-07-21 | Arco Chemical Technology, L.P. | Process for making double metal cyanide catalysts |
| DE19810269A1 (de) | 1998-03-10 | 2000-05-11 | Bayer Ag | Verbesserte Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| US6133402A (en) | 1998-08-04 | 2000-10-17 | Cornell Research Foundation, Inc. | Polycarbonates made using high activity catalysts |
| DE19842383A1 (de) | 1998-09-16 | 2000-03-23 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19905611A1 (de) | 1999-02-11 | 2000-08-17 | Bayer Ag | Doppelmetallcyanid-Katalysatoren für die Herstellung von Polyetherpolyolen |
| DE19937114C2 (de) | 1999-08-06 | 2003-06-18 | Bayer Ag | Verfahren zur Herstellung von Polyetherpolyolen |
| EP1276562B1 (en) | 2000-03-30 | 2003-09-17 | Shell Internationale Researchmaatschappij B.V. | Dmc complex catalyst and process for its preparation |
| AU2001260217A1 (en) | 2000-04-20 | 2001-11-07 | Bayer Aktiengesellschaft | Method for producing double metal cyanide (dmc) catalysts |
| DE10219028A1 (de) | 2002-04-29 | 2003-11-06 | Bayer Ag | Herstellung und Verwendung von hochmolekularen aliphatischen Polycarbonaten |
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| US7977501B2 (en) | 2006-07-24 | 2011-07-12 | Bayer Materialscience Llc | Polyether carbonate polyols made via double metal cyanide (DMC) catalysis |
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| EP2703426A1 (de) | 2012-08-27 | 2014-03-05 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| EP2730602A1 (de) | 2012-11-09 | 2014-05-14 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| WO2014072336A1 (de) * | 2012-11-09 | 2014-05-15 | Bayer Materialscience Ag | Verfahren zur herstellung von polyethercarbonatpolyolen |
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| EP2837648A1 (en) | 2013-08-12 | 2015-02-18 | Repsol, S.A. | Process for preparing polyether carbonate polyols |
| EP2865700A1 (de) | 2013-10-23 | 2015-04-29 | Bayer MaterialScience AG | Verfahren zur Herstellung von Polyethercarbonatpolyolen |
| KR102377243B1 (ko) * | 2014-07-03 | 2022-03-22 | 코베스트로 도이칠란트 아게 | 폴리에테르 카르보네이트 폴리올의 제조 방법 및 그 장치 |
| AU2015293702B2 (en) | 2014-07-22 | 2018-11-01 | Econic Technologies Ltd | Catalysts |
| GB201515350D0 (en) | 2015-08-28 | 2015-10-14 | Econic Technologies Ltd | Method for preparing polyols |
| EP3538588B1 (en) | 2016-11-11 | 2023-01-25 | Dow Global Technologies LLC | Polycarbonate based polyols |
| GB201703323D0 (en) | 2017-03-01 | 2017-04-12 | Econic Tech Ltd | Method for preparing polyols |
| GB201714436D0 (en) | 2017-09-07 | 2017-10-25 | Econic Tech Ltd | A polymerisation process |
| CN107868239B (zh) | 2017-11-28 | 2019-11-15 | 中国科学院长春应用化学研究所 | 一种具有高伯羟基含量的聚(碳酸酯-醚)多元醇组合物及其制备方法 |
| WO2019126221A1 (en) | 2017-12-22 | 2019-06-27 | Saudi Aramco Technologies Company | Catalysts for polycarbonate production |
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2019
- 2019-05-02 GB GBGB1906214.0A patent/GB201906214D0/en not_active Ceased
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2020
- 2020-05-01 EP EP20724557.2A patent/EP3983472A1/en active Pending
- 2020-05-01 WO PCT/GB2020/051083 patent/WO2020222019A1/en not_active Ceased
- 2020-05-01 KR KR1020217039575A patent/KR102918628B1/ko active Active
- 2020-05-01 CN CN202080047661.3A patent/CN114174377A/zh active Pending
- 2020-05-01 US US17/608,251 patent/US12384880B2/en active Active
- 2020-05-01 JP JP2021564877A patent/JP7588091B2/ja active Active
- 2020-05-01 CN CN202511213718.3A patent/CN121064458A/zh active Pending
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2025
- 2025-07-02 US US19/258,311 patent/US20260008886A1/en active Pending
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| US20130035407A1 (en) | 2011-08-03 | 2013-02-07 | Evonik Goldschmidt Gmbh | Use of polysiloxanes comprising branched polyether moieties for the production of polyurethane foams |
| US20160362518A1 (en) | 2014-02-26 | 2016-12-15 | Covestro Deutschland Ag | Method for producing polyether ester carbonate polyols |
| WO2018158389A1 (en) | 2017-03-01 | 2018-09-07 | Econic Technologies | Method for preparing polycarbonate ether polyols |
| WO2018158366A1 (en) | 2017-03-01 | 2018-09-07 | Econic Technologies Limited | Method for preparing polyether carbonates |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2020222019A1 (en) | 2020-11-05 |
| GB201906214D0 (en) | 2019-06-19 |
| JP2022531364A (ja) | 2022-07-06 |
| US20260008886A1 (en) | 2026-01-08 |
| CN114174377A (zh) | 2022-03-11 |
| KR20220004182A (ko) | 2022-01-11 |
| US12384880B2 (en) | 2025-08-12 |
| CN121064458A (zh) | 2025-12-05 |
| JP7588091B2 (ja) | 2024-11-21 |
| EP3983472A1 (en) | 2022-04-20 |
| US20220227926A1 (en) | 2022-07-21 |
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