KR102607031B1 - Disinfectant composition with improved fabric adsorption rate of benzalkonium chloride - Google Patents
Disinfectant composition with improved fabric adsorption rate of benzalkonium chloride Download PDFInfo
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- KR102607031B1 KR102607031B1 KR1020230054866A KR20230054866A KR102607031B1 KR 102607031 B1 KR102607031 B1 KR 102607031B1 KR 1020230054866 A KR1020230054866 A KR 1020230054866A KR 20230054866 A KR20230054866 A KR 20230054866A KR 102607031 B1 KR102607031 B1 KR 102607031B1
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- benzalkonium chloride
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- adsorption rate
- disinfectant composition
- disinfectant
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- 239000000645 desinfectant Substances 0.000 title claims abstract description 54
- 229960000686 benzalkonium chloride Drugs 0.000 title claims abstract description 52
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 title claims abstract description 52
- 239000000203 mixture Substances 0.000 title claims abstract description 41
- 238000001179 sorption measurement Methods 0.000 title claims abstract description 34
- 239000004744 fabric Substances 0.000 title claims abstract description 28
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 18
- 239000003463 adsorbent Substances 0.000 claims abstract description 17
- 150000001450 anions Chemical class 0.000 claims abstract description 17
- 102000004190 Enzymes Human genes 0.000 claims abstract description 13
- 108090000790 Enzymes Proteins 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 13
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000008213 purified water Substances 0.000 claims abstract description 7
- 239000004745 nonwoven fabric Substances 0.000 claims description 24
- 239000003599 detergent Substances 0.000 claims description 14
- 229920001661 Chitosan Polymers 0.000 claims description 13
- 229940088598 enzyme Drugs 0.000 claims description 12
- 229920000728 polyester Polymers 0.000 claims description 11
- 239000002280 amphoteric surfactant Substances 0.000 claims description 9
- 230000000249 desinfective effect Effects 0.000 claims description 9
- 229920000297 Rayon Polymers 0.000 claims description 8
- 239000002964 rayon Substances 0.000 claims description 8
- 239000002736 nonionic surfactant Substances 0.000 claims description 7
- 108010059892 Cellulase Proteins 0.000 claims description 5
- 108091005804 Peptidases Proteins 0.000 claims description 5
- 239000004365 Protease Substances 0.000 claims description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 5
- 102000004139 alpha-Amylases Human genes 0.000 claims description 5
- 108090000637 alpha-Amylases Proteins 0.000 claims description 5
- 229940024171 alpha-amylase Drugs 0.000 claims description 5
- 229940106157 cellulase Drugs 0.000 claims description 5
- SYELZBGXAIXKHU-UHFFFAOYSA-N dodecyldimethylamine N-oxide Chemical compound CCCCCCCCCCCC[N+](C)(C)[O-] SYELZBGXAIXKHU-UHFFFAOYSA-N 0.000 claims description 5
- 229940048866 lauramine oxide Drugs 0.000 claims description 5
- BDKLKNJTMLIAFE-UHFFFAOYSA-N 2-(3-fluorophenyl)-1,3-oxazole-4-carbaldehyde Chemical compound FC1=CC=CC(C=2OC=C(C=O)N=2)=C1 BDKLKNJTMLIAFE-UHFFFAOYSA-N 0.000 claims description 4
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 4
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 229940068968 polysorbate 80 Drugs 0.000 claims description 4
- 235000017281 sodium acetate Nutrition 0.000 claims description 4
- 229940087562 sodium acetate trihydrate Drugs 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- 229920001213 Polysorbate 20 Polymers 0.000 claims description 3
- 230000002255 enzymatic effect Effects 0.000 claims description 3
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 claims description 3
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 claims description 3
- 229940068977 polysorbate 20 Drugs 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims 1
- 229960001716 benzalkonium Drugs 0.000 claims 1
- CYDRXTMLKJDRQH-UHFFFAOYSA-N benzododecinium Chemical compound CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 CYDRXTMLKJDRQH-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 18
- 230000001954 sterilising effect Effects 0.000 abstract description 12
- 239000004615 ingredient Substances 0.000 abstract description 11
- 230000000052 comparative effect Effects 0.000 description 17
- 238000004140 cleaning Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 208000025721 COVID-19 Diseases 0.000 description 1
- 241000723368 Conium Species 0.000 description 1
- 241000711573 Coronaviridae Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 206010059516 Skin toxicity Diseases 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- -1 benzal Chemical class 0.000 description 1
- MOOAHMCRPCTRLV-UHFFFAOYSA-N boron sodium Chemical compound [B].[Na] MOOAHMCRPCTRLV-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000006196 deacetylation Effects 0.000 description 1
- 238000003381 deacetylation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000438 skin toxicity Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- STZCRXQWRGQSJD-UHFFFAOYSA-M sodium;4-[[4-(dimethylamino)phenyl]diazenyl]benzenesulfonate Chemical compound [Na+].C1=CC(N(C)C)=CC=C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 STZCRXQWRGQSJD-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/02—Amines; Quaternary ammonium compounds
- A01N33/12—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K10/00—Body-drying implements; Toilet paper; Holders therefor
- A47K10/16—Paper towels; Toilet paper; Holders therefor
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0208—Tissues; Wipes; Patches
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2/00—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor
- A61L2/16—Methods or apparatus for disinfecting or sterilising materials or objects other than foodstuffs or contact lenses; Accessories therefor using chemical substances
- A61L2/18—Liquid substances or solutions comprising solids or dissolved gases
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Environmental Sciences (AREA)
- Public Health (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- Toxicology (AREA)
- Biomedical Technology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
Abstract
본 발명은 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물에 관한 것으로, 더욱 상세하게는 벤잘코늄 염화물, 계면활성제, 음이온 흡착제, pH 조절제, 효소세정제 및 정제수 잔량으로 이루어진다.
상기의 성분으로 이루어지는 소독제용 조성물은 계면활성제와 음이온 흡착제가 함유되어 살균 성분인 벤잘코늄 염화물의 원단 흡착률을 낮춰 소독효과가 오랜기간 유지되는 소독티슈를 제공한다.The present invention relates to a disinfectant composition with improved fabric adsorption rate of benzalkonium chloride, and more specifically, consists of benzalkonium chloride, surfactant, anion adsorbent, pH adjuster, enzyme cleaner, and the remaining amount of purified water.
The disinfectant composition composed of the above ingredients contains a surfactant and an anion adsorbent to lower the fabric adsorption rate of benzalkonium chloride, a sterilizing ingredient, and provides a disinfection tissue that maintains the disinfection effect for a long period of time.
Description
본 발명은 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물에 관한 것으로, 더욱 상세하게는 계면활성제와 음이온 흡착제가 함유되어 살균 성분인 벤잘코늄 염화물의 원단 흡착률을 낮춰 소독효과가 오랜 기간 유지되는 소독티슈를 제공하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물에 관한 것이다.The present invention relates to a disinfectant composition with improved fabric adsorption rate of benzalkonium chloride. More specifically, it contains a surfactant and an anion adsorbent to lower the fabric adsorption rate of benzalkonium chloride, a sterilizing ingredient, and maintains the disinfection effect for a long period of time. It relates to a disinfectant composition with improved fabric adsorption rate of benzalkonium chloride, which provides disinfectant tissues.
소독성분이 함유된 소독액 용액을 부직포나, 펄프 또는 순면으로된 원단에 흡착시켜 제조되는 소독티슈는 다양한 목적으로 사용되고 있는 일회용 제품, 식당이나 공공장소에서 인체를 청결하게 유지하기 위해 사용되는 일회용 물수건 및 기타 위생적인 목적으로 사용되는 모든 일회용 제품에 적용될 수 있다.Disinfection tissues, which are manufactured by adsorbing a disinfectant solution containing disinfectant ingredients onto non-woven fabric, pulp, or pure cotton fabric, are disposable products used for various purposes, disposable wet towels used to keep the human body clean in restaurants and public places, and It can be applied to all disposable products used for other hygienic purposes.
종래에는 일반 음식점 등에서 위생 물수건을 공급하였으나 소독이 완전하게 실시되지 않는 등의 문제점이 발생하여 물수건과 같이 피부 세정 용도의 1회용 물티슈가 널리 사용되고 있으며 유아나 환자들의 배설물 등의 처리를 위해 신체의 일부를 위생적으로 세정하기 위한 목적으로 주로 사용되고 있으며, 특히 물티슈는 주로 피부에 직접 접촉한 상태에서 문질러 세정하기 때문에 높은 수준의 부드러움, 피부에 대한 안정성과 피부에 잔재하는 이물질 제거의 개선된 세정력 및 세균에 대한 강력한 항균력이 요구된다.Previously, sanitary wet towels were supplied in general restaurants, but problems such as not completely disinfecting occurred, so disposable wet wipes for skin cleansing, such as wet towels, are widely used, and they are used for disposing of body parts such as excrement of infants and patients. They are mainly used for hygienic cleaning. In particular, wet tissues are mainly cleaned by rubbing while in direct contact with the skin, so they have a high level of softness, stability on the skin, improved cleaning power to remove foreign substances remaining on the skin, and anti-bacterial properties. Strong antibacterial activity is required.
한편, 소독티슈는 물티슈와 유사한 방법으로 제조되지만, 살균 성능을 나타내는 소독제가 사용되어 다양한 용도로 소독 및 세정이 필요한 분야에 사용되고 있는데, 최근 몇년 사이에는 COVID-19로 인해 손세정의 중요성이 강조됨에 따라 소독티슈의 소비량도 급증하고 있다.Meanwhile, disinfectant tissues are manufactured in a similar way to wet tissues, but disinfectants with sterilizing properties are used, so they are used in fields that require disinfection and cleaning for various purposes. In recent years, as the importance of hand washing has been emphasized due to COVID-19, Consumption of disinfectant tissues is also rapidly increasing.
그러나, 종래에 소독티슈는 소독제 성분에 함유된 벤잘코늄 염화물과 같은 살균 성분이 소독티슈 부직포에 흡착되는 비율이 높아 소독티슈의 살균력이 제대로 발휘되지 못하는 문제점이 있었다.However, conventional disinfectant tissues had a problem in that the sterilizing power of the disinfectant tissue was not properly demonstrated due to the high rate at which sterilizing ingredients such as benzalkonium chloride contained in the disinfectant ingredient were absorbed into the non-woven fabric of the disinfectant tissue.
본 발명의 목적은 계면활성제와 음이온 흡착제가 함유되어 살균 성분인 벤잘코늄 염화물의 원단 흡착률을 낮춰 소독효과가 오랜 기간 유지되는 소독티슈를 제조할 수 있는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물을 제공하는 것이다.The purpose of the present invention is a disinfectant with improved fabric adsorption rate of benzalkonium chloride, which contains a surfactant and an anion adsorbent to lower the fabric adsorption rate of benzalkonium chloride, a sterilizing ingredient, and can produce disinfection tissues that maintain the disinfection effect for a long period of time. To provide a composition for use.
본 발명의 목적은 벤잘코늄 염화물, 계면활성제, 음이온 흡착제, pH 조절제, 효소세정제 및 정제수 잔량으로 이루어지는 것을 특징으로 하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물을 제공함에 의해 달성된다.The object of the present invention is achieved by providing a disinfectant composition with improved fabric adsorption rate of benzalkonium chloride, which consists of benzalkonium chloride, surfactant, anion adsorbent, pH adjuster, enzyme detergent, and the remaining amount of purified water.
본 발명의 바람직한 특징에 따르면, 상기 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물은 벤잘코늄 염화물 0.1 내지 0.5 중량%, 양쪽성 계면활성제 0.5 내지 1.5 중량%, 음이온 흡착제 0.05 내지 0.5 중량%, pH 조절제 0.5 내지 2 중량%, 효소세정제 0.1 내지 1.0 중량% 및 정제수 잔량으로 이루어지는 것으로 한다.According to a preferred feature of the present invention, the disinfectant composition with improved fabric adsorption rate of benzalkonium chloride includes 0.1 to 0.5% by weight of benzalkonium chloride, 0.5 to 1.5% by weight of amphoteric surfactant, 0.05 to 0.5% by weight of anion adsorbent, It should consist of 0.5 to 2% by weight of pH adjuster, 0.1 to 1.0% by weight of enzyme detergent, and the remaining amount of purified water.
본 발명의 더 바람직한 특징에 따르면, 상기 계면활성제는 양쪽성 계면활성제 및 비이온성 계면활성제로 이루어지며, 상기 양쪽성 계면활성제는 라우라민옥사이드로 이루어지고, 상기 비이온성 계면활성제는 폴리소르베이트20, 폴리소르베이트80 및 플록사머 407로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the surfactant is composed of an amphoteric surfactant and a nonionic surfactant, the amphoteric surfactant is composed of lauramine oxide, and the nonionic surfactant is polysorbate 20, It shall be composed of one or more selected from the group consisting of polysorbate 80 and floxamer 407.
본 발명의 더욱 바람직한 특징에 따르면, 상기 음이온 흡착제는 키토산으로 이루어지는 것으로 한다.According to a more preferred feature of the present invention, the anion adsorbent is made of chitosan.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 pH 조절제는 아세트산나트륨삼수화물로 이루어지는 것으로 한다.According to an even more preferred feature of the present invention, the pH adjuster is made of sodium acetate trihydrate.
본 발명의 더욱 더 바람직한 특징에 따르면, 상기 효소세정제는 프로테아제, 셀룰라아제, 알파-아밀라이제 및 라파아제로 이루어지는 것으로 한다.According to an even more preferred feature of the present invention, the enzymatic detergent is composed of protease, cellulase, alpha-amylase, and rapase.
또한, 본 발명의 목적은 부직포 원단 100 중량부를 청구항 1 내지 6 중 어느 한 항에 따른 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물 250 내지 350 중량부에 침지시켜 제조되는 것을 특징으로 하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독티슈를 제공함에 의해서도 달성될 수 있다.In addition, the object of the present invention is a benzal product, which is prepared by immersing 100 parts by weight of a non-woven fabric in 250 to 350 parts by weight of a disinfectant composition with improved fabric adsorption rate of benzalkonium chloride according to any one of claims 1 to 6. This can also be achieved by providing disinfecting tissues with improved fabric adsorption of conium chloride.
본 발명의 바람직한 특징에 따르면, 상기 부직포 원단은 친수성 폴리에스터 또는 폴리에스터와 레이온이 5:5 내지 8:2의 중량비율로 혼합되어 이루어지는 것으로 한다.According to a preferred feature of the present invention, the non-woven fabric is made of hydrophilic polyester or polyester and rayon mixed at a weight ratio of 5:5 to 8:2.
본 발명에 따른 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물은 계면활성제와 음이온 흡착제가 함유되어 살균 성분인 벤잘코늄 염화물의 원단 흡착률을 낮춰 소독효과가 오랜 기간 유지되는 소독티슈를 제공하는 탁월한 효과를 나타낸다.The disinfectant composition with an improved fabric adsorption rate of benzalkonium chloride according to the present invention contains a surfactant and an anion adsorbent to lower the fabric adsorption rate of benzalkonium chloride, a sterilizing ingredient, and provides a disinfection tissue that maintains the disinfection effect for a long period of time. It shows excellent effects.
이하에는, 본 발명의 바람직한 실시예와 각 성분의 물성을 상세하게 설명하되, 이는 본 발명이 속하는 기술분야에서 통상의 지식을 가진 자가 발명을 용이하게 실시할 수 있을 정도로 상세하게 설명하기 위한 것이지, 이로 인해 본 발명의 기술적인 사상 및 범주가 한정되는 것을 의미하지는 않는다.Below, preferred embodiments of the present invention and the physical properties of each component are described in detail, but are intended to be described in detail so that those skilled in the art can easily practice the invention. This does not mean that the technical idea and scope of the present invention are limited.
본 발명에 따른 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물은 벤잘코늄 염화물, 계면활성제, 음이온 흡착제, pH 조절제, 효소세정제 및 정제수로 이루어지며, 벤잘코늄 염화물 0.1 내지 0.5 중량%, 양쪽성 계면활성제 0.5 내지 1.5 중량%, 음이온 흡착제 0.05 내지 0.5 중량%, pH 조절제 0.5 내지 2 중량%, 효소세정제 0.1 내지 1.0 중량% 및 정제수 잔량으로 이루어지는 것이 바람직하다.The disinfectant composition with improved fabric adsorption rate of benzalkonium chloride according to the present invention consists of benzalkonium chloride, surfactant, anion adsorbent, pH adjuster, enzyme detergent and purified water, 0.1 to 0.5% by weight of benzalkonium chloride, amphoteric It is preferably composed of 0.5 to 1.5% by weight of surfactant, 0.05 to 0.5% by weight of anion adsorbent, 0.5 to 2% by weight of pH adjuster, 0.1 to 1.0% by weight of enzyme detergent, and the remaining amount of purified water.
상기 벤잘코늄 염화물(Benzalkonium chloride)은 본 발명을 통해 제조되는 소독제용 조성물에 살균효과를 부여하는 역할을 하는데, 코로나 바이러스에 대해서도 우수한 살균효과를 나타내는 소독제 및 소독티슈가 제공될 수 있도록 하는 역할을 한다.The benzalkonium chloride serves to provide a sterilizing effect to the disinfectant composition prepared through the present invention, and serves to provide a disinfectant and disinfectant tissue that exhibits excellent sterilizing effect even against coronavirus. .
상기 벤잘코늄 염화물은 [C6H5CH2N(CH)3R]Cl로 표기되며, R C8H17~C18H37로 주로C12H25및C14H29로 되어 있다. 정량할 때는 환산한 무수물에 대하여 벤잘코늄 염화물(C22H40ClN:354.01로) 95.0~105.0%를 함유한다.The benzalkonium chloride is expressed as [C 6 H 5 CH 2 N(CH) 3 R] Cl, and is composed of RC 8 H 17 ~C 18 H 37 , mainly C 12 H 25 and C 14 H 29 . When quantifying, it contains 95.0 to 105.0% of benzalkonium chloride (C 22 H 40 ClN: 354.01) based on the converted anhydride.
상기 벤잘코늄 염화물의 함량이 0.1 중량% 미만이면 상기의 효과가 미미하며, 상기 벤잘코늄 염화물의 함량이 0.5 중량%를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 제조되는 소독제 조성물의 피부독성이 지나치게 증가되기 때문에 바람직하지 못하다.If the content of benzalkonium chloride is less than 0.1% by weight, the effect is minimal, and if the content of benzalkonium chloride exceeds 0.5% by weight, the effect is not significantly improved and the skin toxicity of the prepared disinfectant composition increases. This is undesirable because it increases excessively.
상기 계면활성제는 0.5 내지 1.5 중량%가 함유되며, 양쪽성 계면활성제 및 비이온성 계면활성제로 이루어지며, 상기 양쪽성 계면활성제는 라우라민옥사이드로 이루어지고, 상기 비이온성 계면활성제는 폴리소르베이트20, 폴리소르베이트80 및 플록사머 407로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것이 바람직한데, 상기의 성분으로 이루어지는 계면활성제가 함유되면 벤잘코늄 염화물과 부직포 원단의 반응이 지연되어 벤잘코늄 염화물이 부직포 원단에 부착되는 비율을 낮춰 소독제 조성물의 살균효과가 유지될 수 있도록 하는 역할을 한다.The surfactant contains 0.5 to 1.5% by weight and consists of an amphoteric surfactant and a nonionic surfactant. The amphoteric surfactant consists of lauramine oxide, and the nonionic surfactant includes polysorbate 20, It is preferably made of at least one selected from the group consisting of polysorbate 80 and floxamer 407. When a surfactant made of the above components is contained, the reaction between benzalkonium chloride and the non-woven fabric is delayed, and the benzalkonium chloride adheres to the non-woven fabric. It serves to maintain the sterilizing effect of the disinfectant composition by lowering the rate.
상기 계면활성제의 함량이 0.5 중량% 미만이면 상기의 효과가 미미하며, 상기 양쪽성 계면활성제의 함량이 1.5 중량%를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 지나친 거품형성 및 소독제 조성물의 피부자극이 증가될 수 있기 때문에 바람직하지 못하다.If the content of the surfactant is less than 0.5% by weight, the effect is minimal, and if the content of the amphoteric surfactant exceeds 1.5% by weight, the effect is not significantly improved, but causes excessive foaming and damage to the skin of the disinfectant composition. This is undesirable because irritation may increase.
상기 음이온 흡착제는 0.05 내지 0.5 중량%가 함유되며, 키토산으로 이루어지는 것이 바람직한데, 상기와 같이 키토산으로 이루어지는 음이온 흡착제는 벤잘코늄 염화물이 부직포 원단에 흡착되기 전에 벤잘코늄 염화물 대신 부직포 원단에 흡착되어 벨잘코늄 염화물이 부직포 원단에 흡착되는 비율을 현저하게 낮춰주는 역할을 한다.The anion adsorbent contains 0.05 to 0.5% by weight and is preferably made of chitosan. As described above, the anion adsorbent made of chitosan is adsorbed on the non-woven fabric instead of benzalkonium chloride before benzalkonium chloride is adsorbed on the non-woven fabric. It plays a role in significantly lowering the rate at which chloride is absorbed into non-woven fabric.
이때, 상기 키토산은 수용성 키토산과 불용성 키토산 모두 사용가능한데, 수용성 키토산을 사용하는 것이 바람직하며, 불용성 키토산의 경우 질량농도가 약 1%인 아세트산에 녹인 후에 사용하는 것이 바람직하다.At this time, the chitosan can be used as both water-soluble chitosan and insoluble chitosan. It is preferable to use water-soluble chitosan, and in the case of insoluble chitosan, it is preferable to use it after dissolving it in acetic acid at a mass concentration of about 1%.
또한, 상기 키토산은 중량평균 분자량이 20000 내지 50000이며, 탈아세틸화도가 80% 이상을 나타내는 것을 사용하는 것이 바람직하다.In addition, the chitosan preferably has a weight average molecular weight of 20,000 to 50,000 and a deacetylation degree of 80% or more.
상기 음이온 흡착제의 함량이 0.05 중량% 미만이면 상기의 효과가 미미하며, 상기 음이온 흡착제의 함량이 0.5 중량%를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 제조비용을 지나치게 증가시키기 때문에 바람직하지 못하다.If the content of the anion adsorbent is less than 0.05% by weight, the effect is minimal, and if the content of the anion adsorbent exceeds 0.5% by weight, the effect is not significantly improved and the manufacturing cost is excessively increased, which is not desirable. .
상기 pH 조절제는 0.5 내지 2 중량%가 함유되며, 아세트산나트륨삼수화물로 이루어지는 것이 바람직한데, 상기의 성분으로 이루어지는 pH 조절제가 함유되면 본 발명을 통해 제조되는 소독제 조성물의 중화되어 피부자극이 낮아질 뿐만 아니라, 소독제 조성물에 함유되어 있는 벤잘코늄 염화물이 부직포 원단에 흡착되는 비율이 낮아지는 효과를 나타낼 수 있다.The pH adjuster is contained in an amount of 0.5 to 2% by weight and is preferably composed of sodium acetate trihydrate. When the pH adjuster composed of the above component is contained, the disinfectant composition prepared through the present invention is neutralized and skin irritation is lowered. , it can have the effect of lowering the adsorption rate of benzalkonium chloride contained in the disinfectant composition to non-woven fabric.
상기 효소세정제는 0.1 내지 1.0 중량%가 함유되며, 프로테아제, 셀룰라아제, 알파-아밀라이제 및 라파아제로 이루어지는 것이 바람직한데, 프로테아제, 셀룰라아제, 알파-아밀라이제 및 라파아제가 2:1:2:1의 중량비율로 혼합되어 이루어지는 것이 더욱 바람직하다.The enzymatic detergent contains 0.1 to 1.0% by weight and is preferably composed of protease, cellulase, alpha-amylase, and rapase. The protease, cellulase, alpha-amylase, and rapase are mixed in a ratio of 2:1:2: It is more preferable to mix them at a weight ratio of 1.
상기의 중량비율로 혼합되어 이루어지는 효소세정제는 소독제 조성물에 세정효과를 부여하여 살균력 뿐만 아니라, 벤잘코늄염화물이 부직포 원단에 흡착되는 비율을 감소시키는 효과를 나타내며, 오염성분에 대해 우수한 세정효과를 나타내는 소독제 조성물이 제공될 수 있도록 하는 역할을 한다.The enzyme cleaner mixed in the above weight ratio imparts a cleaning effect to the disinfectant composition and not only has sterilizing power, but also reduces the rate at which benzalkonium chloride is absorbed into the non-woven fabric. It is a disinfectant that exhibits an excellent cleaning effect on contaminants. It serves to enable the composition to be provided.
상기 효소세정제의 함량이 0.1 중량% 미만이면 상기의 효과가 미미하며, 상기 효소세정제의 함량이 1.0 중량%를 초과하게 되면 상기의 효과는 크게 향상되지 않으면서 제조비용을 지나치게 증가시키기 때문에 바람직하지 못하다.If the content of the enzyme detergent is less than 0.1% by weight, the effect is minimal, and if the content of the enzyme detergent exceeds 1.0% by weight, the effect is not significantly improved and the manufacturing cost is excessively increased, which is undesirable. .
또한, 본 발명을 통해 제조되는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물은 부직포 원단에 도포되어 소독티슈로 제공될 수 있는데, 부직포 원단 100 중량부에 상기 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물 250 내지 350 중량부를 도포하여 제조되는 것이 바람직하다.In addition, the disinfectant composition with improved fabric adsorption rate of benzalkonium chloride prepared through the present invention can be applied to non-woven fabric and provided as a disinfection tissue, and the fabric adsorption rate of benzalkonium chloride per 100 parts by weight of non-woven fabric is It is preferably prepared by applying 250 to 350 parts by weight of the improved disinfectant composition.
이때, 상기 부직포 원단의 종류에 따라서도 상기 소독제용 조성물에 함유된 벤잘코늄 염화물의 흡착비율이 가변적인데, 상기 부직포 원단은 친수성 폴리에스터 또는 폴리에스터와 레이온이 5:5 내지 8:2의 중량비율로 혼합되어 이루어지는 것이 바람직하다.At this time, the adsorption ratio of benzalkonium chloride contained in the disinfectant composition varies depending on the type of the non-woven fabric, and the non-woven fabric has a weight ratio of hydrophilic polyester or polyester and rayon of 5:5 to 8:2. It is preferable that it is mixed with .
상기의 성분으로 이루어지는 부직포 원단은 소독제용 조성물에 함유된 벤잘코늄 염화물에 대한 흡착성능이 낮아 소독효과가 오랜 기간 동안 유지될 수 있도록 하는 역할을 한다.The non-woven fabric composed of the above ingredients has a low adsorption capacity for benzalkonium chloride contained in the disinfectant composition, thereby ensuring that the disinfection effect is maintained for a long period of time.
이하에서는, 본 발명에 따른 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물의 제조방법 및 그 제조방법으로 제조된 소독제용 조성물을 물성을 실시예를 들어 설명하기로 한다.Hereinafter, the method for manufacturing a disinfectant composition with improved fabric adsorption rate of benzalkonium chloride according to the present invention and the physical properties of the disinfectant composition prepared by the method will be described by way of examples.
<제조예 1> 효소세정제의 제조<Preparation Example 1> Preparation of enzyme detergent
프로테아제, 셀룰라아제, 알파-아밀라이제 및 라파아제를 2:1:2:1의 중량비율로 혼합하여 효소세정제를 제조하였다.An enzyme detergent was prepared by mixing protease, cellulase, alpha-amylase, and lapase in a weight ratio of 2:1:2:1.
<실시예 1><Example 1>
폴리에스터와 레이온이 7:3의 중량비율로 혼합되어 이루어진 부직포 원단 100 중량부에 벤잘코늄 염화물 0.4 중량%, 양쪽성 계면활성제(라우라민옥사이드) 0.6 중량%, 음이온 흡착제(키토산) 0.25 중량%, pH 조절제(아세트산나트륨삼수화물) 1.5 중량%, 비이온성 계면활성제(폴리소르베이트80) 0.6 중량%, 상기 제조예 1을 통해 제조된 효소세정제 0.6 중량% 및 정제수 잔량으로 이루어진 소독제용 조성물 300 중량부를 도포하여 소독티슈를 제조하였다.0.4% by weight of benzalkonium chloride, 0.6% by weight of amphoteric surfactant (lauramine oxide), 0.25% by weight of anion adsorbent (chitosan), 100 parts by weight of nonwoven fabric made by mixing polyester and rayon in a weight ratio of 7:3, 300 parts by weight of a disinfectant composition consisting of 1.5% by weight of a pH regulator (sodium acetate trihydrate), 0.6% by weight of a nonionic surfactant (polysorbate 80), 0.6% by weight of the enzyme detergent prepared through Preparation Example 1, and the remaining amount of purified water. Disinfection tissues were prepared by application.
<비교예 1><Comparative Example 1>
폴리에스터와 레이온이 7:3의 중량비율로 혼합되어 이루어진 부직포 원단 100 중량부에 질량농도가 4%인 벤잘코늄 염화물 수용액으로 이루어진 소독제용 조성물 300 중량부를 도포하여 소독티슈를 제조하였다.Disinfecting tissues were prepared by applying 300 parts by weight of a disinfectant composition consisting of an aqueous benzalkonium chloride solution with a mass concentration of 4% to 100 parts by weight of a non-woven fabric made of a mixture of polyester and rayon in a weight ratio of 7:3.
<비교예 2><Comparative Example 2>
상기 비교예 1과 동일하게 진행하되, 상기 소독제용 조성물에 라우라민옥사이드 0.6 중량%를 더 혼합하여 소독티슈를 제조하였다.The same procedure as in Comparative Example 1 was carried out, but a disinfectant tissue was prepared by further mixing 0.6% by weight of lauramine oxide with the disinfectant composition.
<비교예 3><Comparative Example 3>
상기 비교예 2와 동일하게 진행하되, 상기 소독제용 조성물에 키토산 0.25 중량%를 더 혼합하여 소독티슈를 제조하였다.The same procedure as in Comparative Example 2 was carried out, but a disinfectant tissue was prepared by further mixing 0.25% by weight of chitosan with the disinfectant composition.
<비교예 4><Comparative Example 4>
상기 비교예 3과 동일하게 진행하되, 상기 소독제용 조성물에 상기 제조예 1을 통해 제조된 효소세정제 0.6 중량%를 더 혼합하여 소독티슈를 제조하였다.In the same manner as in Comparative Example 3, a disinfectant tissue was prepared by further mixing 0.6% by weight of the enzyme detergent prepared in Preparation Example 1 with the disinfectant composition.
<비교예 5><Comparative Example 5>
상기 비교예 1과 동일하게 진행하되, 폴리에스터와 레이온이 3:7의 중량비율로 혼합되어 이루어진 부직포 원단을 사용하여 소독티슈를 제조하였다.Proceeding in the same manner as Comparative Example 1, a disinfectant tissue was manufactured using a non-woven fabric made of a mixture of polyester and rayon at a weight ratio of 3:7.
<비교예 6><Comparative Example 6>
상기 비교예 2와 동일하게 진행하되, 폴리에스터와 레이온이 3:7의 중량비율로 혼합되어 이루어진 부직포 원단을 사용하여 소독티슈를 제조하였다.Proceeding in the same manner as Comparative Example 2, a disinfection tissue was manufactured using a non-woven fabric made by mixing polyester and rayon at a weight ratio of 3:7.
<비교예 7><Comparative Example 7>
상기 비교예 3과 동일하게 진행하되, 키토산 0.0625 중량%를 혼합하여 소독티슈를 제조하였다.Proceed in the same manner as Comparative Example 3, but disinfection tissues were prepared by mixing 0.0625% by weight of chitosan.
상기 실시예 1 및 비교예 1 내지 7을 통해 제조된 소독티슈의 벤잘코늄 염화물에 대한 흡착률을 측정하여 아래 표 1에 나타내었다.The adsorption rates for benzalkonium chloride of the disinfecting tissues prepared through Example 1 and Comparative Examples 1 to 7 were measured and are shown in Table 1 below.
{단, 벤잘코늄 염화물에 대한 흡착률은 대한민국의 의약품 시험규격인 "대한민국 약전 12개정" 중 벤잘코늄염화물액의 함량시험방법을 이용하였다.{However, the adsorption rate for benzalkonium chloride was determined using the content test method for benzalkonium chloride solution in the "Korean Pharmacopoeia 12th Revision," which is Korea's pharmaceutical testing standard.
더욱 상세하게는 벤잘코늄 염화물로 0.15g 해당량(0.4% 검체 37.5mL)을 정확하게 취하여 물을 넣어 75mL로 하여 녹인 다음 희석시킨 묽은염산(1→2)을 1방울씩 넣어 pH를 2.6 내지 3.4로 조정하고 메틸오렌지시액 1방울을 넣어 액이 빨간색을 나타낼 때까지 0.02mol/L 테트라페닐붕소나트륨액으로 적정하는 방법을 이용하였으며, 계산은 아래와 같다.More specifically, take exactly 0.15 g (37.5 mL of 0.4% sample) of benzalkonium chloride, dissolve it in 75 mL with water, and then add diluted diluted hydrochloric acid (1 → 2) one drop at a time to adjust the pH to 2.6 to 3.4. The method of adjusting and titrating with 0.02 mol/L tetraphenyl boron sodium solution by adding 1 drop of methyl orange solution until the solution appears red was used. The calculation is as follows.
계산) 0.02mol/L 테트라페닐붕소나트륨액 1mL = 7.080mgC22H40ClN}Calculation) 1mL of 0.02mol/L sodium tetraphenylboron solution = 7.080mgC 22 H 40 ClN}
<표 1><Table 1>
상기 표 1에 나타낸 것처럼, 본 발명의 실시예 1을 통해 제조된 소독티슈는 비교예 1 내지 7을 통해 제조된 소독티슈에 비해 벤잘코늄 염화물의 흡착률이 낮은 것을 알 수 있다.As shown in Table 1, it can be seen that the disinfection tissue prepared through Example 1 of the present invention has a lower adsorption rate of benzalkonium chloride compared to the disinfection tissue prepared through Comparative Examples 1 to 7.
또한, 비교예 1 내지 2와 비교예 5 내지 6을 비교해보면, 동일한 성분으로 이루어진 소독제 조성물을 사용하더라도 부직포 원단의 구성성분에 따라. 흡착률이 달라지는 것을 알 수 있으며, 본원발명과 같이 폴리에스터와 레이온이 5:5 내지 8:2의 중량비율로 혼합되어 이루어진 부직포 원단을 사용하는 경우에 흡착률이 더욱 낮아지는 것을 알 수 있다.In addition, when comparing Comparative Examples 1 to 2 and Comparative Examples 5 to 6, even if a disinfectant composition composed of the same ingredients is used, depending on the constituents of the nonwoven fabric. It can be seen that the adsorption rate varies, and when a non-woven fabric consisting of a mixture of polyester and rayon at a weight ratio of 5:5 to 8:2 is used, as in the present invention, the adsorption rate is further lowered.
따라서, 본 발명에 따른 벤잘코늄 염화물의 원단 흡착률이 개선된 소독제용 조성물은 양쪽성 계면활성제와 음이온 흡착제가 함유되어 살균 성분인 벤잘코늄 염화물의 원단 흡착률을 낮춰 소독효과가 오랜 기간 유지되는 소독티슈를 제공한다.Therefore, the disinfectant composition with improved fabric adsorption rate of benzalkonium chloride according to the present invention contains an amphoteric surfactant and an anion adsorbent to lower the fabric adsorption rate of benzalkonium chloride, a sterilizing ingredient, and maintains the disinfection effect for a long period of time. Tissues are provided.
Claims (8)
0.1 to 0.5% by weight of benzalkonium chloride, 0.5 to 1.5% by weight of a surfactant consisting of lauramine oxide and a nonionic surfactant as an amphoteric surfactant, 0.05 to 0.5% by weight of chitosan as an anion adsorbent, 0.5 to 2% by weight of a pH adjuster, A disinfectant composition for disinfecting tissues with improved fabric adsorption rate of benzalkonium chloride, comprising 0.1 to 1.0% by weight of enzyme detergent and the remaining amount of purified water.
상기 비이온성 계면활성제는 폴리소르베이트20, 폴리소르베이트80 및 플록사머 407로 이루어진 그룹에서 선택된 하나 이상으로 이루어지는 것을 특징으로 하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독티슈용 소독제 조성물.
In claim 1,
A disinfectant composition for disinfecting tissues with improved fabric adsorption rate of benzalkonium chloride, characterized in that the nonionic surfactant consists of one or more selected from the group consisting of polysorbate 20, polysorbate 80, and floxamer 407.
상기 pH 조절제는 아세트산나트륨삼수화물로 이루어지는 것을 특징으로 하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독티슈용 소독제 조성물.
In claim 1,
A disinfectant composition for disinfecting tissues with improved fabric adsorption rate of benzalkonium chloride, wherein the pH adjuster consists of sodium acetate trihydrate.
상기 효소세정제는 프로테아제, 셀룰라아제, 알파-아밀라이제 및 라파아제로 이루어지는 것을 특징으로 하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독티슈용 소독제 조성물.
In claim 1,
The enzymatic detergent is a disinfectant composition for disinfecting tissues with improved fabric adsorption rate of benzalkonium chloride, characterized in that it consists of protease, cellulase, alpha-amylase, and rapase.
Benzalkonium, characterized in that it is manufactured by applying 250 to 350 parts by weight of the disinfectant composition for disinfecting tissues with improved fabric adsorption rate of benzalkonium chloride according to any one of claims 1, 3, 5 and 6 to 100 parts by weight of non-woven fabric. Disinfection tissue with improved fabric absorption rate of chloride.
상기 부직포 원단은 친수성 폴리에스터 또는 폴리에스터와 레이온이 5:5 내지 8:2의 중량비율로 혼합되어 이루어지는 것을 특징으로 하는 벤잘코늄 염화물의 원단 흡착률이 개선된 소독티슈.In claim 7,
The non-woven fabric is a disinfectant tissue with improved fabric adsorption rate of benzalkonium chloride, characterized in that it is made of hydrophilic polyester or a mixture of polyester and rayon at a weight ratio of 5:5 to 8:2.
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